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Non-Conventional
Hydrocarbon Liquids,
Production, and
Transportation
Non-Conventional hydrocarbons are:
Oil
Heavy Oil
Extra Heavy Oil and Bitumen
Gas
Coal Gas
Tight Gas
Gas Hydrates
Aquifer Gas
The world contains large quantities of non-conventional oil and gas and various oil
substitutes. However, the rapidity of the decline in the production of conventional oil
and gas has attracted interest and investment in non-conventional fluids.
Conventional oil is defined fairly generally as oil produced by primary or secondary recovery methods (specifically: under own pressure, physical lift, water flood,
and water or natural gas pressure maintenance). This definition is not universal, but is
further clarified in the ADDENDUM at the end of this chapter.
This chapter provides concepts and details for modes of transportation of nonconventional oil and specifically provides details on pipeline modes of transportation.
The technology of heavy oil transportation by pipeline is further exemplified through
design requirements and operational controls of a long distance pipeline TCPL
Keystone-XL Heavy Oil Pipeline to highlight design aspects as well as operational
control opportunities.
To complement the transportation techniques, the ADDENDUM to this chapter
further highlights world heavy oil/extra heavy oil resources their recovery techniques,
rheology, and characteristics.
Figure 6-3. T
ypical viscosities of as-produced bitumen and crudes (inset: viscosities for pipeline transportation)
Figure 6-3. T
ypical viscosities of as-produced bitumen and crudes (inset: viscosities for pipeline transportation)
Figure 6-4. R
egional distribution of bitumen, extra heavy oil and heavy oil based on API gravity (data reproduced, [2])
6.3.1 Types/Grouping
Crude oils (heavy or otherwise) cover a wide range in physical properties and chemical
compositions, and it is often important to be able to group them into broad categories
of related oils to associate the appropriate properties and behavior (Newtonian versus
non-Newtonian) for pipeline transportation purposes.
Figure 6-5 signifies properties of heavy oil, in terms of pressure-temperature diagrams in the context of types of oil.
In general, crude oils are commonly classified into the following classifications:
Ordinary black oil (light/medium crude oil or heavy/extra heavy crude oils),
initial gas-oil ratios < 2000 scf/stb, API < 40o (usually between 15o and 40o)
Low-shrinkage crude oil (often referred to as black oil), API < 35o
High-shrinkage (volatile) crude oil (initial gas-oil ratios in the 2000 to
3300 scf/Bbl range), API > 40 (typically 4555 API)
Near-critical crude oil (condensate/Retrograde gas), gas-oil ratio > 3000 scf/
STB
Black oils are made up of a variety of components including large, heavy, and nonvolatile hydrocarbons. The stock tank that contains such oil is usually brown to dark
green in color.
Black oil is often called low shrinkage crude oil or ordinary oil [4]. It is black or
deeply colored.
High shrinkage (volatile) oils contain fewer heavy molecules and more intermediate components (ethane through hexane) than black oils. The color is generally lighter
than black oil brown, orange, or green. This type of crude oil is commonly characterized by a high liquid shrinkage immediately below the bubble-point. Such oil is
greenish to orange in color.
The phase envelope for a volatile oil tends to cover a much narrower temperature
range when compared to a black oil; but like a black oil, the reservoir temperature is
always lower than the critical temperature for the fluid. As the reservoir temperature
approaches the critical temperature a volatile oil will become more gas-like such that
Figure 6-5. Crude oil phase diagram defining the type of oil [3]
Type/Use
Saudi Arabian oil
(Chart)
(Equation)
(6 1)
mob = a {od}b
(6 2)
(6 3)
API
GG
P
Pb
Rs
T
mo
mob
mod
API
Air = 1.000
psia
psia
scf/STB
F
cP
cP
cP
Generally, heavy crude oils and bitumen exhibit non-Newtonian shear thinning
behavior; that is, viscosity (affected by shear mechanical energy) decreases with increasing oscillation frequency or shear rate over temperature ranges of industrial interest for production, storage, and transportation. For such behavior, viscosity correlation
can be generally expressed as [7]:
m = CTA Ln e + K TB
(6 4)
Dilution
Partial upgrading
Heating/steam injection/Inline injection
Water Emulsion
Core annular flow
Surfactants/flow improvers (i.e., use of additives as pour point depressant)
Slurry transportation (oil-solid slurry)
Viscosity reducers
The first two methods are often associated with the same project or process. However, it may be indicated that currently dilution and partial upgrading are primarily
used for transportation of heavy oils to the market.
The methods are described below:
6.4.1 Dilution
A method for enhancing heavy crude oils transportation is by blending the oils with
less viscous hydrocarbons such as condensate, naphtha, kerosene, light crudes. Typically, there is an exponential relationship between the resulting viscosity of the mixture
and the volume fraction of the diluents (Figure 6-6).
Figure 6-6. Dilution of heavy oils with condensate for different API (from [8])
Figure 6-8. Viscosity versus AP for typical raw feed and upgraded heavy oil/bitumen [10]
(6 5)
where
u = kinematic viscosity, cSt and T = temperature absolute (K)
m = slope of temperatureviscosity curve and C = constant depending on type of
diluents.
Generally, heavy oils that are required to be shipped to a regional upgrader or major
pipeline terminal without diluents will require a heated/insulated pipeline. An example
is the Enbridge Pipeline system (NPS 12, 35 KM, Operating Temperature 120C) for
transporting bitumen (for PetroCanada) from MacKay River production site to Fort
MacMurray (both in Alberta) where it is blended before being exported through the
extensive network of pipelines to the North American market (Figure 6-9) [11].
It may be noted that the design and construction of a heated pipeline involves
many considerations: including pipelines expanding/extending due to heat, number of
pumping/heating stations, heat losses and hence insulation. Another significant issue
is the corrosion rate of the internal pipe due to the temperature. It is also shown that
heat treatment could induce changes in the colloidal structure of the heavy crude oils
affecting their rheological properties.
Another technique is generally to heat trace the pipe (Figure 6-10). Heating is
provided by a capacitive power-generating facility to maintain the carrier pipe temperature to about 65C. In most cases, two heat tracing cables are installed at 3 and 9
o'clock positions on the pipe and then together with the pipe are wrapped in insulation
Figure 6-10. Typical insulated heat-traced (to 60C) heavy oil pipeline [12]
The technique is stable and the emulsion is relatively easy to prepare. However, it
is costly (for additives and surfactants) and requires skilled personnel for operation.
Figure 6-14. T
ypical fouling in Core Annular Flow (CAF) technique, 1 km long test circuit
transporting heavy Venezuelan crude (ZUATA) [14]
rate in the flow. Mean injection velocities are also key parameters for the flow regime
determination.
In core annular flow water surrounds the lubricated oil core Figure 6-13A. A perfect CAF is shown in Figure 6-13B, small water layer is sheared and the velocity field
is approximately linear if the difference of viscosity between oil and water is large. In
that case, the oil core is nearly like a plug flow. However pressure losses are that of
water transported through a pipeline.
Limitations are fouling, Figure 6-14 and will require high-pressure pumping start
up. It is however indicated that Core Annular Flow (CAF) technique is well established
and that to avoid fouling a chemical type additive (made up of silicate) along with
internal coating can prevent severe fouling.
Flow improvers, also known as Drag Reducers, only improve the flow efficiency
when added to the upgraded bitumen/heavy oils for transportation through pipelines [18].
This is because, generally, oil pipelines operate in laminar region (Figure 6-17). Injection
of DRAs may also reduce the friction factors by forcing the pipeline operation to move into
the region with higher Reynolds numbers, but with smoother flow pattern (Figure 6-18).
Different types of additives can be used in these systems and include surfactants,
fibers, aluminum disoaps, and high polymers. Drag reducing additives are effective
because they reduce the turbulent friction of a solution. This result is a decrease in the
pressure drop across a length of a pipeline or conduit and likewise reduces the energy
required to transport the liquid.
Figure 6-15. D
RA/Flow improvers in action: A turbulence before DRA injection and B
linear flow pattern after DRA injection (Turboflo, courtesy of FLOWECHEM)
Figure 6-16. Effect of chemical drag reducers (CDR) on pipeline pump pressure and flow rate
Figure 6-17. Moody diagram friction factor for flow of fluids in pipelines [19]
Figure 6-18. D
rag reducing agent /flow improvers; pipeline regime profile (based on Castilla
blend (heavy, 18 API))
Availability of
diluent
Large
Dilution
Technique
Advanced
technique
Extensive
Advantages
Experience
Limitations Concerns
Issues
Transportation
Preparation Method
Normal
....
Surfactants
As designed
Flow improvers
Extensive
Extensive
Extensive
Comercialized
Extensively
Used in
Refineries/plants
....
....
Industrial application
limited
Decloging-Large
restart pressure
Pioneed in 1970,
Conoco Phillips
Improves capacity
Re-injection facilities
after pumps
Injection facilities
Water recycling Oil adhers to pipe walls Viscosity depends on Expensive, third party
& eventual blockage type & ppm added
supply
to be resolved
Large
Electricity
Sources for
Heaters
Normal
Field Refinery
Applied at Plant
Normal
Table 6-2. Heavy oils transportation technologies comparison (from ref. [8])
New
upgrading
Asphaltene
reduction
....
....
....
Normal
Slurry
Figure 6-19. C
omparison of pressure drop versus flow rate for different transport methods,
reproduced from [20]
Figure 6-20. C
omparison of heating, dilution and emulsification (oil and water) for transportation of extra heavy crude [14]
CRW
OSA, OSC
SYN, SSB
LSC
MSC
NSA
HSB
HSC
PAS
SYNBIT
SSB
DILBIT
SSX
=
=
=
=
=
=
=
=
=
=
=
=
=
Condensate
Suncor Oil Sands Blend A or C
Synthetic, Suncor Sweet (Blend)
Light Sour Crude
Medium Sour Crude
Newgrade Premium Synthetic
Husky Synthetic Blend
Heavy Sour Crude
Premium Albian Synthetic
Synthetic Blend
Sycrude Sweet Blend
Diluted Blend (with condensate)
Shell Sweet Blend
density
(kg/m3)
Classification
100350
2099
219
0.41
to 0.3
904940
876903
800875
600799
to 599
Heavy
Medium
Light
Prod. & Condensate.
NGL
Figure 6-21. Density/API gravity of bitumen and typical treated heavy and light oil blends
Figure 6-22. Viscosity of bitumen and typical treated heavy oil blends
Impact from pump station start up, delivery restriction or shutdown (zero delivery)
Pump unit trip/failure
Rapid mainline valve closures including slam shut of a non-return (check) valve
Effect of running the pipeline with minimum flow and maximum pump discharge pressure operating condition
Variation in demand including rapid reduction/curtailment of delivery volumes
Bubble formation/collapse (the transition from slack-line to tight-line flow)
Tight-line/slack-line operation
Unintentional changes in operational position of control valves
Fluid property delivery conditions
Liquid injection assessment
Surge protection including pressure relief/control system evaluation
Restart requirement to avoid slack-line conditions prevalent in hilly/mountainous parts right of way (ROW)
Valve Characteristics
Size and flow characteristics at various openings (Cv versus percentage (%) of
opening)
Valve operator speed and characteristics
Type of check valves, damped or un-damped
Description of pump station discharge or suction control valves for normal
operation and rapid operation (emergency situation)
Pump and Driver Information
Pump performance data (head, efficiency, horsepower, or torque versus flow),
pump type
Number of stages (for specific speed calculation)
Changes expected for increased throughput
Rated conditions (conditions at the best efficiency point for head, flow, speed,
and torque)
Efficiencies, adiabatic, and mechanical
Pump characteristics diagram or synoptic chart (if not available, curves from a
pump of similar speed)
Driver type: variable/constant speed (induction motor, synchronous motor, turbine, etc.)
Driver torque versus speed curve (for pump start-up cases)
Safe current versus time data for electric motors if start-up analysis is to be
performed
Special devices on pump/driver and any auxiliary facilities and appertaining loads
Pump station controls description (minimum flow shutdown, flow discharge
pressure shutdown, suction/discharge pressure control, etc.)
Operational Data
However, there must be a complete design and operational strategy devised and
assessments made to combat potential pressure surges and adverse pressure transients
in a system. The transient event may either initiate a low-pressure event (down-surge)
as in the case of a pump power failure, or a high-pressure event (up-surge) caused by
the closure of a downstream valve.
Down-surge can lead to undesirable situations such as the unwanted occurrence of
fluid column separation, which itself can result in severe pressure rises following the
collapse of a vapor cavity. In some systems negative pressures are not even allowed
because of (1) possible pipe collapse or (2) ingress of outside fluid (such as water in
offshore systems) or air.
The means of controlling the transient will in general vary, depending upon
whether the initiating event results in an up-surge or down-surge. For pumping plants,
the major cause of unwanted transients is typically the complete outage of pumps due
to loss of electricity to the motor. For full pipelines, pump start up, usually against a
closed pump discharge valve for centrifugal pumps, does not normally result in significant pressure transients.
The majority of transient problems in pumping installations are associated with
the potential (or realized) occurrence of fluid-column separation and vapor-pocket formation and collapse, resulting from the failure of one or more pumps, with or without
valve action. The pump discharge valve, if actuated too suddenly, can even aggravate
the down-surge problem.
Modeling of the Cushing Extension was however based on the modeling of the
entire Keystone XL pipeline system (from Hardisty to Nederland, Texas) for determining the pipeline capacity and other operating parameters/data (under given conditions)
and then focusing only on the Cushing Extension for the required simulations.
6.6.5.1 Fluid Properties
Fluid properties important to hydraulic simulation are viscosity and density (API gravity) at given reference temperatures.
Generally, the Keystone XL pipeline will transport Heavy DilBit with batches of
Synthetic Crude Oil (SCO).
DilBit is abbreviated for diluted bitumen, meaning bitumen blended with naphtha or condensate or light crude oils. The diluents are added to create a mixture that can
be transported by pipeline (i.e., reduce viscosity).
Synthetic crude oil (SCO) is the processed product from a bitumen/heavy oil upgrader facility.
Figure 6-25 illustrates kinematic viscosities for Dilbit. Typical densities of DilBit
are as follows:
952 kg/m3 at 0oC
922 kg/m3 at 37oC
The properties for SCO depend on the processes used in the upgrading. Typical
values are:
Viscosity
Density
10oC
20oC
30oC
40oC
45oC
4.29 cSt
3.30 cSt
2.83 cSt
2.29 cSt
2.10 cSt
812.9
kg/m3 at 15oC
Viscosity cSt
1400
1200
1000
800
600
400
200
0
2
4
6
8
10
12
15
17
19
21
23
25
27
29
31
33
35
37
39
41
43
45
47
49
51
53
55
57
59
61
63
65
67
69
71
73
75
77
79
81
83
85
87
89
91
93
95
97
99
101
Temperature C
Figure 6-25. Viscosity of heavy Dilbit (typical 1st quarter and 3rd quarter)
Figure 6-26. Steele CityCushing pipeline segment elevation profile and facilities locations
Ground temperature profile (at pipeline burial depth) utilized for hydraulics modeling is shown in Figure 6-29.
Pipeline Facilities Location Along Steele City Cushing Segment of KXL Pipeline
and TLNET Model of the pipeline are, respectively, shown in Figures 6-30 and 6-31.
Figure 6-27. C
-2 M&J valve characteristic used as input into hydraulics modeling NPS 36,
(CV 20,000)
Figure 6-32. Heavy DilBit/synthetic crude oil (SCO) batch travel time cycle
While TLNET can monitor movements of batched products, it is unable to pinpoint the time where a high-pressure event has occurred along the length of the pipeline. However, this can be achieved interactively by observing the pipeline pressure
profile over time. Thus, it was decided to simulate the required dynamic situation (e.g.,
valve closure) when SCO is just arrived before the selected equipment (Figure 6-32).
Figure 6-33. A
reas and extent of overpressurization as a consequence of closure of valve
BV 28-1
observed when closing mainline block valve BV 28-1 situated just 11.4 KM downstream of a Cushing Extension pump station (PS 28, KMP 154) (Figure 6-33).
Fluctuation in surge pressure to the maximum of 11789 kPa can be seen in
Figure6-33 as mainline block valve BV 28-1 is closed and upstream pump stations
are shutdown sequentially in 1 minute intervals (Figure 6-34).
It may be noted that the area (i.e., the length 11.4 KM of pipeline affected) is in the
highest elevation location with the Cushing Extension pump station (PS 28) at lower
elevation than mainline block valve BV 28-1. Also, it may be noted that this segment is
filled with the lighter Synthetic Crude Oil (SCO) and is thus more vulnerable to surge
pressure fluctuations as anticipated.
To avoid the pressure surges affecting pipeline integrity in this area, any of the
following can be adapted.
From many simulation runs, it was noted that under the given/assumed conditions,
the pressure surges caused by shutting down any of the pump stations are within the
allowable permitted by the code. Highest pressure recorded (10142 kPa) was noted for
shutting down Pump Station 28 with the batch just upstream of mainline block valve
BV 27-2 (KMP 109) (Figure 6-35). The area corresponds to the location where highest
surge pressure was seen as the case for shutting down mainline block valve BV 28-1.
Figure 6-35. T
ypical example: pressure surges as a consequence of shutting down pump station 28 only (maximum surge pressure 10142 kPa vs. 10923 kPa allowable)
Figure 6-36. Pipeline surge pressure limit violations due to the delivery
6.6.9 Conclusion
Steady-state modeling is limited in providing a realistic system response for adequately
establishing the system design, capability, and for the determination of pipeline control to avoid undesirable situations caused by undue pressures. The use of transient
modeling in the design and operational assessment of a liquid pipeline however provide assurance of the system capability, control, safety, and integrity as well as setting
of pipeline controls through effective SCADA systems for avoiding undue pressure
surges.
The strategies that were derived from hydraulic transient modeling for the Keystone XL included the following:
ADDENDUM to CHAPTER 6
Heavy Oil Resources and Recovery Techniques
Figure A6-1. Location of major Canadian oil sand and heavy oil deposits [31]
Figure A6-2. General global distribution of heavy oil resources (indicated by stars)
Figure A6-3. Distribution of bitumen, extra heavy and heavy oils resources (GBBLS) [33]
Discovered original
HEAVY OIL
North America
South America
Europe
Africa
Transcaucasia
Middle East
Russia
South Asia
East Asia
Southeast Asia and Oceania
Total
BITUMEN
North America
South America
Europe
Africa
Transcaucasia
Middle East
Russia
South Asia
East Asia
Southeast Asia and Oceania
Total
Prospective additional
Total
650
1099
75
83
52
971
182
18
168
68
3366
2
28
0
0
0
0
0
0
0
0
29
651
1127
75
83
52
971
182
18
168
68
3396
1671
2070
17
13
430
0
296
0
10
4
4512
720
190
0
33
0
0
51
0
0
0
993
2391
2260
17
46
430
0
347
0
10
4
5505
Table A6-2. Worlds largest reserves of crude oil in place by type (Recreated from ref. [36])
Figure A6-5. H
eavy oil recovery technique through steam injection (from refs. [37], inset
from refs. [44, 45])
Figure A6-6. C
old simultaneous production process of sand and oil using solution gas (from
ref. [37])
Viscosity reduction can be achieved by thermally reducing the viscosity (heating), by mass transfer (solvent dilution), or by molecular scission (pyrolysis, in-situ
hydrogenation, etc.). Thermal methods cover warm/cold production and all the thermal
process (items 2 through 5 listed above) and include steam-assisted gravity drainage
(SAGD) [46, 47], cyclic steam stimulation (CSS), and in-situ top-down combustion.
The in situ combustion method begins with the injection of heated air into heavy oil
reservoir. Heat is generated as a result of oil oxidation, thus increasing the temperature.
With the continuation of the oxidation process, the temperature reaches the ignition
point when combustion occurs. Cold air is then injected to continue the process. The
combustion front thus displaces any trapped fluids in the reservoir up through the producing well.
The viscosity of heavy oil that is in the reservoir can be reduced by dilution or the
mass transfer of a light hydrocarbon solvent into the heavy oil as in the case of vapor
extraction (VAPEX) or NSolv. VAPEX is considered the solvent analog to SAGD).
Both NSolv and VAPEX involve injecting a solvent into a heavy oil reservoir to reduce the viscosity of the heavy oil via mass transfer. The solvent-enhanced live oil
then drains via gravity drainage and is produced through a lower horizontal production
well [44].
A typical representation of a thermal and solvent recovery method using horizontal wells is indicated in Figures A6-7 and A6-8.
Solvent or steam is injected into the upper well where the following actions can
assist the recovery of heavy oil/bitumen:
A. Steam Injection: the steam condenses on the cold bitumen surface, reducing the viscosity of the bitumen through heat conduction (steam assisted gravity drainage SAGD, or other thermal steam processes). Steam-Assisted
Figure A6-7. Thermal recovery process through steam injection (known as huff npuff [48]
Gravity Drainage (SAGD) generally uses paired horizontal wells. Steam, which
is continuously injected through the upper well, creates a steam chamber along
the walls of which the heated bitumen flows and is produced in the lower well
(Figure A6-8). Several variations of this process have been developed. One
variation uses a single horizontal well, with steam injection through a central
pipe and production along the annulus. Another variation involves steam injection through existing vertical wells and production through an underlying
horizontal well.
Figure A6-8. T
ypical solvent based method for the recovery of heavy oil through two horizontal wells (from ref. [44])
Table A6-3. Heavy oil production techniques versus location resources summary [40]
Figure A6-9. A typical phase (p-T) diagram for a crude oil (from [3])
REFERENCES
[1] Barillas, J. l. M., Dutra, T. V., and Mata, W., 2008, Improved Oil Recovery Process For Heavy
Oil: A Review, Brazilian Journal of Petroleum and Gas, 2(1), pp. 4554.
[2] Alboudwarej, H., 2006, Fluid Property Measurement: A Challenge for Heavy Oil, Heavy Crude
Oil Symposium, Galveston, TX, USA, Oct. http://webdelprofesor.ula.ve/ingenieria/mabel/
HeavyCrudeTransport.pdf.
[3] Ahmed, T., 2000, Reservoir Engineering Handbook, 2nd edition, Gulf Professional Publishing,
Houston TX, USA.
[4] Fekete Harmony, 2011, Reservoir Fluid Types, http://www.fekete.com/software/feketeharmony/
media/webhelp/Harmony/Reservoir_Fluid_Types.htm.
[5] Bennison, T., 1998, Prediction of Heavy Oil Viscosity, Presented at IBC Heavy Oil Development
Conference, London, UK, Dec 24. http://www.ecltechnology.com/subsur/reports/pvt_tgb.pdf.
[6] Bergman, D. F., and Sutton, R. P., 2009, A Consistent and Accurate Dead-Oil-Viscosity Method,
Society of Petroleum Engineers Reservoir Evaluation & Engineering (SPE Res Eval & Eng),
12(6), pp. 815840. SPE-110194-PA. doi:10.2118/110194-PA.
[7] Tovar, J., Salazar, A., and Salzar, N., 2006, The Impact of Non-Newtonian Fluid Behavior on
Well Performance For the Orinoco Belt Reservoir, SPE/IBP Workshop on Artificial Heavy Oil
Offshore, Armaca de Buzios, Brazil, May 28.
[8] Saniere, A., Henaut, I., and Argillier, J. F., 2004, Pipeline Transportation of Heavy Oils, a Strategic, Economic and Technological Challenge, Oil & Gas Science and Technology, IFP (Institut
France du Petrole), 59(5), pp. 455466.
[9] Galvin, J., 2006, A New Approach to Heavy Oil and Bitumen Upgrading, Heavy Oil Symposium, Galveston, TX, Oct.