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(d) S2O72-
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(d) S2O72-
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(ii) N2O4
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1) Oxygen almost invariably exhibits an oxidation state of -2 but the other members
of the family exhibit negative as well as positive oxidation states of +2, +4 & +6.
Why?
2) H2S is a gas whereas H2O is a liquid, why?
3) Why bond angle of H2O is less than NH3?
4) Boiling point of Gr-16 elements increases from H2S to H2Po, why?
5) HF is kept in wax bottles but not in glass bottles, why?
6) HF has a greater electronegativity difference and more ionic character than HCl,
HBr and HI but it is the weakest acid, why?
7) Halogens are strong oxidizing agents, why?
8) Anhydrous HCl is a bad conductor of electricity while aqueous HCl is a good
conductor, why?
9) Bleaching action of chlorine is permanent but that of sulphur dioxide is
temporary, why?
10) XeF2 has a straight linear structure and not easily hydrolyzed, why ?
11) Deep sea divers use a mixture of He and O2 instead of air for breathing, why?
12) Though E.A. of fluorine is less than that of chlorine but fluorine is a better
oxidizing agent, why?
13) Most of the reactions of fluorine are exothermic, why?
3. Draw the structures of ( any five ) : 5X1
(i) XeO3
(ii) H2SO5
(iii) ClF
(iv) SO2
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1(d)
2(a) 3(b)
4(b) 5(d)
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6(c)
7(a)
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8(c)
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HgI2
HgO
Pb3O4
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2
6. Give structure : (i) sodium hexafluorosilicate ( IV)
Potassiumhexacyanoferrate(II)
2
(ii)
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1(a)
5X1
(i) [Co(NH3)6]Cl3 (ii) [Pt(NH3)2Cl(NH2CH3)]Cl (iii) [Ti(H2O)6]3+ (iv) [Co(NH3)4Cl(NO2)]Cl (v) [Mn(H2O)6]2+
(vi) [NiCl4]2 (vii) [Ni(NH3)6]Cl2 (viii) [Co(en)3]3+(ix) [Ni(CO)4]
3. Using IUPAC norms write the formulas for the following: (any five ) 5X1
(i) Tetrahydroxozincate(II)
(ii) Potassium tetrachloridopalladate(II)
(iii) Diamminedichloridoplatinum(II)
(iv) Potassium tetracyanonickelate(II)
(v) Pentaamminenitrito-O-cobalt(III)
(vi) Hexaamminecobalt(III) sulphate
(vii) Potassium tri(oxalato)chromate(III)
(viii) Hexaammineplatinum(IV)
4.Draw the structures of optical isomers of:
2X3
(i) [Cr(C2O4)3]3
(ii) [PtCl2(en)2]2+
(iii) [Cr(NH3)2Cl2(en)]+
5. Explain on the basis of valence bond theory that [Ni(CN) 4]2 ion with square planar structure is diamagnetic and
the [NiCl4]2 ion with tetrahedral geometry is paramagnetic.
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6.[NiCl4]2 is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
7.[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3 is weakly paramagnetic. Explain.
2
2
8.Explain [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex.
9.Predict the number of unpaired electrons in the square planar [Pt(CN) 4]2 ion.
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2
6. Give structure : (i) sodium hexafluorosilicate ( IV)
Potassiumhexacyanoferrate(II)
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(ii)
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(ii) [NH(CH2)NHCO(CH2)4CO]n is a
A
addition polymer B thermosetting polymer C. Homopolymer D.Co-polymer
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(vi)The artificial sweetener containing chlorine that has the appearance and taste as that of sugar and is stable
at cooking temperature is
A
Aspartame B Saccharin C Sucralose
D Alitame
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EXAM ON METALLURGY
F.M. 26 TIME : 45 min
CLASS 12- (3)
_______________________________________________________________________________________________
1.Answer the following questions : 10X1
(a) What is the role of depressant in froth floatation process ?
(b) Differentiate between mineral and ore (c) What do you mean by smelting ? Give
reaction
(d) Define the terms gangue and flux
(e) What is the role of silica in copper extraction
(f) Why is pine oil used in froth floatation process ?
(g) How is cast iron different from pig iron ?
(h) Write the principle of zone refining method
(i) What is the role of cryolite in the extraction of aluminium ?
(j) What is the role of graphite rod in the electrometallurgy of aluminium ?
2. Copper can be extracted by hydrometallurgy but not zinc. Explain.
3. Why is the extraction of copper from pyrite difficult than that from its oxide
through reduction? 2
4. Giving examples, differentiate between roasting and calcination.
5. Write chemical reactions taking place in the extraction of zinc from zinc blende.
2
6. How can you separate alumina from bauxite ore associated with
silica? Give equations. 2
7. What is hydrometallurgy? Explain with an example
8. What is leaching process? How is it used for the concentration of silver and gold
ores? 2
9. Free energies of formation Gf of MgO(s) and CO(g) at 1273K and 2273 K are
given below:
2
Gf [MgO(s)] = 941 KJ mol1 at 1273 K.
Gf [CO(g)] = 439 KJ mol1 at 1273 K.
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3. What is mutarotation ? 2
4. Giving examples, differentiate between roasting and calcination.
5. Write chemical reactions taking place in the extraction of zinc from zinc blende.
2
6. How can you separate alumina from bauxite ore associated with
silica? Give equations. 2
7. What is hydrometallurgy? Explain with an example
8. What is leaching process? How is it used for the concentration of silver and gold
ores? 2
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