210 KVPY Stage 1 Exam 2016 17 Paper Solution

KISHORE VAIGYANIK PROTSAHAN YOJANA
(KVPY) 2016
Date : 09-11-2016
Time: 3 Hours
Max. Marks : 160.
STREAM - SB/SX
INSTRUCTIONS
1.
2.
3.
Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen.
Use of pencil is strictly prohibited.
The Test Booklet consists of 120 questions.
There are Two parts in the question paper. The distribution of marks subjectwise in each part is as under for each correct
response.
MARKING SCHEME :
PART-I :
MATHEMATICS
Question No. 1 to 20 consist of ONE (1) mark for each correct response.
PHYSICS
CHEMISTRY
BIOLOGY
PART-II :
4.
5.
6.
7.
8.
MATHEMATICS
Question No. 81 to 90 consist of TWO (2) marks for each correct response.
PHYSICS
CHEMISTRY
BIOLOGY
Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each question.
for Part-I 0.25 marks will be deducted for indicating incorrect response of each question and for Part-II 0.50 marks will be
deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is
indicated for an item in the Answer sheet.
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the candidates are allowed to take away this Test Booklet with them.
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PART-I : (One Marks Questions)
MATHEMATICS
1.
Sol.
2.
Sol.
The number of triples (x, y, z) of real numbers satisfying the equation x 4 + y4 + z4 + 1 = 4xyz is
(A) 0
(B) 4
(C) 8
(D) more than 8
OkkLrfod la[;kvksa esa cuh dqy fdruh (x, y, z) frdfM;k (triples) laHko gS] tks lehdj.k x4 + y4 + z4 + 1 = 4xyz
dks larq"B djrh gS :
(A) 0
(B) 4
(C) 8
(D) 8 ls T;knk
x4 + y4 + z4 + 1 = 4xyz
applying AM GM in L.H.S
x 4 y 4 z 4 1
xyz
4
4
4
4
x + y + z + 1 4xyz
Now equality holds iff
x 4 = y4 = z4 = 1
x = 1, y = 1, z = 1 and xyz = 1
(x, y, z) = (1, 1, 1)
or (1, 1, 1)
or (1, 1, 1)
or (1, 1, 1)
hence 4 triples one possible x option (B)
Let P(x) be a polynomial with real coefficients such that P(sin2x) = P(cos2x), for all x [0, /2]. Consider
the following statements :
(I) P(x) is an even function
(II) P(x) can be expressed as a polynomial in (2x 1)2
(III) P(x) is a polynomial of even degree.
then
(A) all are false
(B) only I and II are true
(C) only II and III are true
(D) all are true
eku yhft, fd P(x) okLrfod xq.kkadksa ls cuk ,d cgqin (polynomial) gS] tks lHkh x [0, /2] ds fy, P(sin2x)
= P(cos2x) dks larq"B djrk gS] fuEu okD;ksa dks i<+sa
(I) P(x) ,d le-Qyu (even function) gS
(II) P(x) dks (2x 1)2 ds cgqin ds :i ds O;Dr fd;k tk ldrk gS
(III) P(x) le-/kkr dk cgqin gS
buesa :
(A) lHkh xyr gS
(B) dsoy I ,oa II lgh gS
(C) dsoy II ,oa III lgh gS
(D) lHkh lgh gS
2
2
P(sin x) = P(cos x); x [0, /2]
or P(t) = P(1 t); t [0, 1]
1
P(t) will be sxm about t =
2
2n
P(x) = K x ; n
2
Hence P(x) can be expressed as a polynomial in (2x 1)2 and it is a polynomial of degree 2n
(i.e., even),
Hence option (C) is correct
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PAGE - 1
3.
For any real number r, let Ar = {eirn : n is a natural number} be a set of complex numbers. Then
(A) A1, A 1 , A0.3 are all infinite sets
(B) A1 is a finite set and A 1 , A0.3 are infinite sets
(C) A1, A 1 , A0.3 are all finite sets
(D) A1, A0.3 are finite sets and A 1 is an infinite set
fdlh Hkh okLrfod la[;k r ds ft, eku yhft, fd Ar = {eirn : n ,d izkd`frd la[;k gS} lfEeJ la[;kvksa dk
leqPp; gS] rc (A) A1, A 1 , A0.3 lHkh vifjfer (infinite) leqPp; gS
(B) A1 ,d ifjfer leqPp; gS vkSj A 1 , A0.3 vifjfer leqPp; gS
(C) A1, A 1 , A0.3 lHkh ifjfer leqPp; gS
(D) A1, A0.3 ifjfer leqPp; gS vkSj A 1 vifjfer leqPp; gS
Sol.
irn
Ar = e ; n N
A1 = ein; n N
= cos(n) + i sin(n)
= cos n
A1 = {1, 1}
Hence A1 is a finite set
A1 = e
1
i .n
A 1 = cos n + i sin n; n is in radish
cos n + i sin n does not repeat it self or it is not having an integer volume of period, as its period is
2
. .
n
Hence A 1 will have infinite no of element
n
i
10
3n
3n
= cos
+ i sin
10
10
20
hence period =
, which has a common multiple with 1 which is 20. n
3n
A0.3 is periodic with period 20 n.
Hence A0.3 contains 20 distinct elements
Hence option (D)
A0.3 = e
4.
Sol.
The number of integers k for which the equation x3 27x + k = 0 has at least two distinct integer roots in
;fn lehdj.k x3 27x + k = 0 ds de ls de nks vfHkUu iw.kkZad ewy gks] rks iw.kkZad k dh fdruh la[;k, laHko gS ?
(A) 1
(B) 2
(C) 3
(D) 4
x3 27x + k = 0
++=0
....... (1)
+ + = 27
........ (2)
= v
.........(3)
sum of roots = 0 and atleast two roots are integers
third root must also be integer
a , and
PAGE - 2
Put = in equation (2)

2
108 3 2
2
+ + 27 = 0 or =
a to be integer,
= 6 = 3 = 3 = 54
= 6 = 3 = 3 = 54
= 3 = 3 = 6 = 54
= 3 = 6 = 3 = 54
= 3 = 6 = 3 = 54
= 3 = 3 = 6 = 54
No of integer value of = 2
hence option (B) correct
If two root are integers, third should also be en integer to make their sum zero.
5.
Sol.
6.
Suppose the tangent to the parabola y = x2 + px + q at (0, 3) has slope 1. Then p + q equals
;fn (0, 3) ij ijoy; (parabola) y = x2 + px + q dh izo.krk (slope) 1 gS] rks p + q dk eku gksxk (A) 0
(B) 1
(C) 2
(D) 3
2
y = x + px + q
at x = 0, y = 3
q=3
dy
= 2x + p
dx
dy
at x = 0,
=1
dx
p=1
p+q=2
Hence option (C)
Let O = (0, 00); let A and B be points respectively on x-axis and y-axis such that OBA = 60. Let D be
a point in the first quadrant such that OAD is an equilateral triangle.
eku yhft, O = (0, 00); x-v{k ij nks fcUnq e'k% A vkSj B ,sls gS fd OBA = 60 gS] eku yhft, fd fcUnq D
igys prqFkkZa'k (quadrant) esa bl izdkj gS fd OAD ,d leckgq f=kHkqt gS] DB dh izo.krk D;k gksxh ?
1
1
(A) 3
(B) 2
(C)
(D)
2
3
y
D
B
30
60
60
30
Sol.
30
30
O
A
E
Circle through O, A and B will also poss through D.
OBA = ODA = 60
OAB = ODB = 30 BOA DOA = BOD = 30
from ODE; E = 30
1
slope of BD = tan 30 =
3
Hence option (D)
PAGE - 3
7.
Suppose the parabola (y k)2 = 4(x h), with vertex A, passes through O = (0, 0) and L = (0, 2). Let D
be an end point of the latus rectum. Let the y-axis intersect the axis of the parabola at P. Then PDA is
equal to
A 'kh"kZ okyk ,d ijoy; (y k)2 = 4(x h), O = (0, 0) ,oa L = (0, 2) ls xqtjrk gSA eku yhft, D ukfHkyEc
(latus rectum) dk vafre fcUnq gS ;fn ijoy; dk v{k y-v{k dks P ij dkVrk gS rks PDA dk eku D;k gS 1
2
4
8
(A) tan1
(B) tan1
(C) tan1
(D) tan1
19
19
19
19
y
L(0, 2)
A
(h,u)
Sol.
P(0, 1)
focus
x
E
2
(y u) = 4(x h) latus rectum = 4 unit
From the figure u = 1 and (0, 0) satisfies the equation
1
u2 = 4h h
4
1
A = , 1
4
or equation will be,
1
(y 1)2 = 4 x
4
y2 2y = 4x
3
3
focus = , 1 D = , 3
4
4
8
and slope of AD = 2
3
8
3 2
= tan1 2
PDA = tan1

16
19
1
3
slope of PD =
Hence option (B) is correct

8.
In a circle with centre O, suppose A, P, B are three points on its circumference such that P is the midarea( AOB)
point of minor are AB. Suppose when AOB = ,
= 5 + 2, If AOB is doubled to 2,
area( APB)
area( AOB)
then the ratio
is
area( APB)
O dsaUnz ds ,d o`k esa rhu fcUnq A, P, B o`k dh ifjf/k ij bl izdkj fLFkr gS fd fcUnq P y?kq pki AB ds e/; esa
{ks=kQy (AOB)
{ks=kQy (AOB)
gS tc AOB = gks rks
= 5 + 2, ;fn AOB dks 2dj fn;k tk, rks
dk
{ks=kQy (APB)
{ks=kQy (APB)
eku D;k gksxk ?
(A)
1
5
(B)
51
(C) 2 3 + 3
(D)
5 1
2
PAGE - 4
B
D
Sol.
Area of AOB
OD
r cos
=
=
Area of APB
DP
r r cos
when =
r cos
r r cos
= ( 5 + 2)
cos
= (( 5 + 2) ( 5 + 2)) cos
2
2
or cos
=
2
5 2
5 3
(1 cos )
94 5
=
2
14 6 5
Now when = ,
r cos
cos
1
ratio =
=
=
r r cos
r cos
5
Hence option (A) is correct
or
9.
Let X = {x R : cos(sin x) = sin(cos x)}. The number of elements in X is

(A) 0
(B) 2
(C) 4
(D) not finite
;fn X = {x R : cos(sin x) = sin(cos x)} rks X esa dqy vo;oksa dh la[;k (A) 0
(B) 2
(C) 4
(D) ifjfer ugha gS
y = (cos(sin x))
sin 1
cos 1
Sol.
O
3 2
2
sin 1
As the two graphs never intersect each other hence no solution.

PAGE - 5
10.
A sphere with centre O sits atop a pole as shown in the figure. An observer on the ground is at a
distance 50 m form the foot of the pole. She notes that the angles of elevation from the observer to
points P and Q on the sphere are 30 and 60, respectively. Then, the radius of the sphere in meters is
fp=k esa n'kkZ, vuqlkj dsaUnz O dk ,d xksyd ,d [kaHks ds 'kh"kZ ij fLFkr gS] ,d O;fDr tehu ij [kaHks ls 50 m hd
nwjh ij [kM+k gS og O;fDr xksyd ds fupys Hkkx P dks 30 mU;u dks.k vkSj fcUnq 60 mUu;u dks.k ij ns[krk gS]
xksyd fd f=kT;k ehVj(m) esa D;k gksxh ?
o Q
60
30
50m
(A) 100 1
(C) 50 1
50 6
(B)
3
(D)
100 6
3
o Q
Sol.
h
60
30
50m
hr
tam 30 =
50
equating value of r,
50
h
h
=
+ 50
3
3
tan60 =
h
50 r
h = 50 r = 50 1
= option (C) is correct
11.
1
sin(2x), 0 x 1 is shown below.
8
Define f 1(x) = f(x), f n+1(x) = f(f n(x)), for n 1.
The graph of the function f(x) = x +
1
y=x
y = f(x)
0.5
0.5
Which of the following statement are true ?

(I) There are infinitely many x [0, 1] for which limn fn(x) = 0.
1
(II) There are infinitely many x [0, 1] for which limn f n(x) =
2
(III) There infinitely many x [0, 1] for which limn f n(x) = 1
(IV) There are infinitely many x [0, 1] for which limn f n(x) does not exist
(A) I and III only
(B) II only
(C) I, II, III only
(D) I, II, III and IV
PAGE - 6
1
sin(2x), 0 x 1 dk vkjs[k uhps n'kkZ;k x;k gS]
8
;fn f1(x) = f(x) vkSj n 1 ds fy, fn+1(x) = f(fn(x)) j fn+1(x) = f(fn(x)),
Qyu f(x) = x +
1
y=x
y = f(x)
0.5
0.5
rc fuEu dFkuksa ?
(I) vuar x [0, 1] laHko gS ;fn limn f n(x) = 0
1
2
(III) vuar x [0, 1] laHko gS ;fn limn f n(x) = 1
(IV) vuar x [0, 1] laHko gS ;fn limn f n(x) dk vfLrRo ugha gS
(A) dsoy I ,oa III
(B) dsoy II
(C) dsoy I, II, III
1
Note that f(x) > x 0 < x <
2
1
and f(x) < x < x 1
2
Also f(x) is increasing
1
1
further f(x)
0x
2
2
1
1
f(x)
x ,1
2
2
(II) vuar x [0, 1] laHko gS ;fn limn fn(x) =
Sol.
(D) I, II, III ,oa IV
1
So x 0,
2
f(f(x)) > f(x)
(f in increasing)
f(f(f(x))) > f(f(x)) > f(x)
Hence f n(x) increases as n increasing for a given x and it has an appear
1
1
1
based , so lim fn(x) =
x 0,
n
2
2
2
1
Similarly for x ,1
2
1
lim f n(1) =
n
2
x
12.
The limit limx x2 e t
x2
dt equals
limx x2 e t
x2
dt dk eku D;k gksxk ?
(A)
1
3
(B) 2
x
Sol.
lim x
t3 x3
(C)
(D)
2
3
dt
PAGE - 7
x 2. e t
form
e
Applying LH Rule,
0
= lim
x3
x 2 .e x 2x e t dt
lim
3x e
x3
1
2
+
.
lim
x 3
3x
t3
dt
ex
1
3
Alter : lim x .
x
e
= lim
t3
t3 x3
dt
form
x3
dt
e /x
Apply LH Rule
3
lim
13.
Sol.
14.
Sol.
ex x4
3
x2 (3x 2 .e x ) e x (2x)
= lim
1
x4
=
4
3
3x 2x
The polynomial equation x3 3ax2 + (27a2 + 9)x + 2016 = 0 has

(A) exactly one real root for any real a
(B) three real root for any real a
(C) three real roots for any a 0, and exactly one real root for any a < 0
(D) three real roots for any a 0, and exactly one real root for any a > 0
cgqin lehdj.k x3 3ax2 + (27a2 + 9)x + 2016 = 0 dk
(A) okLrfod a ds fy, dsoy ,d okLrfod e3wy laHko gS
(B) okLrfod a ds fy, rhu okLrfod ewy laHko gS
(C) a 0 ds fy, rhu okLrfod ewy ,oa a < 0 ds fy, dsoy ,d okLrfod ewy laHko gS
(D) a 0 ds fy, rhu okLrfod ewy ,oa a > 0 ds fy, dsoy ,d okLrfod ewy laHko gS
x3 3ax2 + (27a2 + 9)x + 2016 = 0
Let,
3
2
2
y = x 3ax + (27a + 9)x + 2016
dy
>0xR
dx
f(x) is monotonically increasing function
Hence exactly one real root exist for all values of 'a'
The area of the region bounded by the curve y = |x3 4x2 + 3x| and the x-axis, 0 x 3, is
o y = |x3 4x2 + 3x| ,oa x-v{k, 0 x 3 ds chp dk {ks=kQy D;k gksxk ?
37
9
37
(A)
(B)
(C)
(D) 0
6
4
12
3
2
y = |x 4x + 3x|
= |x(x 1)(x 3)|
PAGE - 8
Area =
3
2
( x 4x 3x ) dx +
(x
4 x 2 3 x ) dx
1 4 3
80 104 24

+
4 3 2
4
3
2
5
8
37
+
=
12
3
12
15.
The number of continuous functions f : [0, 1] [0, 1] such that f(x) < x for all x and
f ( x) dx =
0
(A) 0
(B) 1
(C) 2
1
is
3
(D) infinite
1
lrr Qyu f : [0, 1] [0, 1] dh dqy la[;k, D;k gksxh tks x ds lHkh eku ds fy, f(x) < x2 vkSj f ( x) dx =
0
1
dks
3
larq"V djrh gS ?
Sol.
(A) 0
2
f(x) < x
1
(C) 2
(D) infinite
f ( x) dx <
f ( x) dx <
0
dx
(B) 1
1
3
Hence number such function exists

16.
On the real line R, we define two functions f and g as follows :

f(x) = min {x [x], 1 x + [x]},
g(x) = max {x [x], 1 x + [x]},
Where [x] denotes the largest integer not exceeding x. The positive integer n for which
n
(g( x ) f ( x )) dx = 100 is
0
,d okLrfod js[kk R ij nks Qyu f ,oa g bl izdkj ls ifjHkkf"kr gS :

f(x) = min {x [x], 1 x + [x]},
g(x) = max {x [x], 1 x + [x]},
n
tgk [x] vf/kdre iw.kkZad gS tks x ls vf/kd ugha gS (g( x ) f ( x )) dx = 100 esa n dk D;k eku gksxk 0
Sol.
(A) 100
(B) 198
f(x) = min. { x},1 { x}
g(x) = max {{x}, 1 {x}}
g(x) f(x) will be periodic with period = 1
(C) 200
(D) 202
1/2 1
PAGE - 9
shaded area is =
(g( x ) f ( x )) dx
0
1
=
2
n
(g( x ) f ( x )) dx =
0
n
2
n = 200
17.
Let v be a vector in the plane such that | v i | = | v 2 i | = | v j |. Then | v | lies in the interval
;fn ,d ry (plane) esa v ,d ,slk lfn'k gS tks | v i | = | v 2 i | = | v j | dks larq"V djrk gS] rks | v |
dk varjky (interval) D;k gS ?
Sol.
(A) (0, 1]
(B) (1, 2]

|v i | = |v 2 i | = |v i |
Let v = a i + b j
(C) (2, 3]
(D) (3, 4]
(a 1)2 + b2 = (a 2)2 + b2 = a2 = a2 + (b 1)2

on solving we set,
3
3
a=
and b =
2
2
9 9
9
Hence | v | =
=
4 4
2
| v | (2, 3)
18.
A box contains b blue balls and r red balls. A ball is drawn randomly from the box and is returned to the
box with another ball of the same colour. The probability that the second ball drawn from the box is blue
is
,d cDls esa b uhys jax ds vkSj r yky jax ds xsans gSA ;kn`PN :i ls cDls esa ,d xsan fudkyh tkrh gS vkSj mlh jax
dh nwljh xsan ds lkFk okil cDls esa Mky nh tkrh gS bldh izkf;drk D;k gksxh fd nwljh xsan tc cDls ls fudkyh
tk, rks og uhys jax dh gks ?
(A)
Sol.
19.
Sol.
b
r b
(B)
b2
(r b ) 2
(C)
b 1
r b 1
(D)
b(b 1)
(r b)(r b 1)
blue balls b
Re d balls r
Case-I : Blue, Blue
Case-II : Red, Blue
b
(b 1)
r
b
b 2 b rb
b
Prob. =
=
=
(b r )
(b r 1)
(b r )
(b r 1)
(b r )(b r 1) b r
The number of noncongruent integer-sided triangles whose sides belong to the set {10, 11, 12, ...... 22}
is
iw.kkZad Hkqtkvksa okys vlokZaxle (noncongruent) f=kHkqtksa dh dqy la[;k, fdruh gksxh] ;fn mudh Hkqtk, leqPp;
{10, 11, 12, ...... 22} ds vo;o gks ?
(A) 283
(B) 446
(C) 448
(D) 449
13
number of scalene = C3 3 = 283
13
number of isosceles = ( C2 2) 4 = 152
number of equilateral = 13C1 = 13
total no. of D = 448
PAGE - 10
20.
Suppose we have to cover the xy-plane with identical tiles such that no two tiles overlap and no gap is
left between the tiles. Suppose that we can choose tiles of the following shapes : equilateral triangle,
square, regular pentagon, regular hexagon. Then the tiling can be done with tiles of
(A) all four shapes
(B) exactly three of the four shapes
(C) exactly two of the four shapes
(D) exactly one of the four shapes
eku yhft;s fd xy-ry dks ,dleku VkbZyks (tiles) ls bl izdkj <duk gS fd nks VkbZy ,d nwljs dks ugh <+dsa vkSj
muds chp dksbZ [kkyh Lfkku Hkh ugh cpk gks eku yhft, fd vki leckgq f=kHkqt oxZ le-iapHkqt ,oa le-"kVHkqt
vkdkj ds VkbZyks esa ls p;u dj ldrs gS rc iwjs {ks=k dks fuEu izdkj ds BkbZyksa esa ls p;u dj ldrs gS rc iwjs
{ks=k dks fuEu ds VkbZyksa esa Hkjk tk ldrk gS
(A) lHkh pkjksa vkdkj ds VkbZyksa esa
(B) pkj esa dsoy rhu izdkj ds VkbZyksa ls
(C) pkj esa dsoy nks izdkj ds VkbZyksa ls
(D) pkj esa dsoy ,d izdkj ds VkbZy ls
Sol.
We can cover the plane using squares definitely

using equilateral also we can cover the plane as shown below
so on
also regular hexagon is made of equilateral triangle only

But pentagon can not cover the plane because of its shape
PHYSICS
21.
Sol.
22.
Physical processes are sometimes described visually by lines. Only the following can cross :
(A) Streamlines in fluid flow
(B) Lines of forces in electrostatics
(C) Rays in geometrical optics
(D) Lines of force in magnetism
HkkSfrd izf;kvksa dks n`f"Vxr :i ls cgq/kk js[kkvksa ds }kjk of.kZr fd;k tkrk gS] fuEufyf[kr esa ls dsoy ,d izfrPNsn dj ldrh gSA
(A) rjy izokg esa /kkjk js[kk,a
(B) fLFkjfo|qfrdh esa cy js[kk,a
(C) izdk'k T;kfefr esa fdj.ksa
(D) pqEcdRo esa cy js[kk,a
Rays can cut each other.
A uniform ring of radius R is moving on a horizontal surface with speed v and then climbs up a ramp of
inclination 30 to a height h. There is no slipping in the entire motion. Then h is :
f=kT;k R dk ,d leku oy; ,d {kSfrt lrg ij xfr v ls pyrs gq, h WpkbZ ds ,d <ky tks fd 30 dks.k ij >qdh gqbZ gS ij p<+rk
gS] iwjh xfr ds nkSjku oy; dgha Hkh fQlyrk ugha gS] rc h dk eku gksxkA
(A) v2/ 2g
(B) v2/ g
(C) 3v2/ 2g
(D) 2v2/ g
Sol.
1
1
mv 2 cm 2 mgh
2
2
2
1
1
V
mv 2 (mR 2 ) mgh
2
2
R
h=
V2
g
PAGE - 11
23.
Sol.
24.
A gas at initial temperature T undergoes sudden expansion from volume V to 2V. Then
(A) the process is adiabatic
(B) the process is isothermal
(C) the work done in this process is nRTlne(2) where n is the number of moles of the gas
(D) the entropy in the process does not change.
,d xSl] ftldk izkjafHkd rkirku T gS] dks vkdfLed izlkj ds }kjk vk;ru V ls 2V ij yk;k tkrk gS] rc
(A) ;g izf;k :)ks"e gSA
(B) ;g izf;k lerkih gSA
(C) bl izf;k eas fd;k x;k dk;Z nRTlne(2) gS tgkW n xSl ds eksyksa dh la[;k gSA
(D) bl izf;k esa ,UVkWih (entropy) vifjofrZr jgrh gSA
Since the process is very sudden, the process is adiabatic.
Photons of wavelength are incident on a metal. The most energetic electrons ejected from the metal
are bent into a circular are of radius R by a perpendicular magnetic field having a magnitude B. The
work function of the metal is (where symbols have their usual meanings)
rjaxnS/;Z ds QksVksu ,d /kkrq ij vkifrr gksrs gSa] /kkrq ls mRlftZr lokZf/kd tkZ ds bysDVkWu ,d B eku ds
pqEcdh; {ks=k }kjk f=kT;k R ds ,d o`kkdkj pki esa eqM+ tkrk gS] /kkrq dk dk;Z Qyu gksxkA (;gkW lHkh ladsrksa ds
lkekU; vFkZ gSa])
hc
e 2 B2 R 2
(A)
me
2me
Sol.
eBR
hc
e2B 2R2
hc
(C)
mec 2
(D)
2me
2me
2me
hc
hc
P2
P2
hc
2m
2me
and radius of circular path is
mV
P
R
P qBR
qB aB
hc 1
2
(qBR)
2me
qBR
hc
2m
2me
Sol.
KEmax =
25.
eBR
hc
(B)
2me
2me
A container is divided into two equal part and by a partition with a small hole of diameter d. The two
partitions are filled with same ideal gas, but held at temperatures T = 150 K and T = 300 K by
connecting to heat reservoirs. Let and be the mean free paths of the gas particles in the two parts
such that d >> and d >> . Then is close
,d ik=k dks nks leku Hkkxksa vkSj esa ,d foHkktd] ftlesa d O;kl dk ,d NksVk fNnz gS] ls foHkkftr fd;k x;k gS]
nksuksa Hkkx leku vkn'kZ xSl ls Hkjs gq, gSa ijUrq mudks ,d "ek HkaMkj (heat reservoir) ls tksM+dj rkieku
T = 150 K rFkk T = 300 K ij j[kk x;k gS] eku yhft;s fd rFkk nksuksa Hkkxksa esa xSl d.kksa ds ek/; eqDr&iFk
(mean free path) bl izdkj gS fd d >> rFkk d >> rc dk fudVre~ eku gksxkA
(A) 0.25
(B) 0.5
(C) 0.7
(D) 1.0
1
Number of particles
N
, where n =
=
vol.
vol
2 d2n
vol
2d2N
Now PV = nRT, for both the parts P = same, V = same
1
So n
T
Vol
1
where
N
2
T
2 d N
PAGE - 12
So T
1 T1 150
0.5
2 T2 300
Answer should be (B) rather than (C)
If we calculate mean relaxation time :
1
Vol
2
2 d n v
2d2N v
1
as N
and <v> T
T
so T
1
26.
150
1
= 0.7
300
2
A conducting bar of mass m and length l moves on two frictionless parallel rails in the presence of a
constant uniform magnetic field of magnitude B directed into the page as shown in the figure. The bar is
given an initial velocity v0 towards the right at t = 0. Then the :
(A) Induced current in the circuit is in the clockwise direction
(B) velocity of the bar decreases linearly with time.
(C) distance the bar travels before it comes to a complete stop is proportional to R.
(D) power generated across the resistance is proportional to l.

v
R

,d lqpkyd NM+ ftldk nzO;eku m rFkk yEckbZ l gS nks ?k"kZ.k jfgr lekukUrj jsyksa ij ,d fLFkj ,dleku B eku
ds pqEcdh; {ks=k dh mifLFkfr esa py jgk gS] pqEcdh; {ks=k dh fn'kk i`"B ds vUnj dh vksj fp=k esa fn[kk, vuqlkj gS]
NM+ dks t = 0 ij nkW;h vksj ,d vkjfEHkd osx v0 fn;k tkrk gS] ifjiFk dk izfrjks/k R gS] rc

v
R

(A) ifjiFk esa izsfjr /kkjk nf{k.kkorZ fn'kk esa gksxhA
(B) NM+ dk osx le; ds lkFk js[kh; :i ls ?kVsxkA
(C) iw.kZr% :dus ds igys NM+ ds }kjk dh xbZ nwjh R ds lekuqikrh gS]
(D) izfrjks/k esa tfue lkeF;Z (power) l ds lekuqikrh gSA
PAGE - 13
Sol.
V
emf = VB
2 2
VB B
B
Fnet = iB =
V
R R
B2 2
Fnet =
V (m) (a)
R
B2 2
a =
mR
V
B2 2
dV

V
dS
mR
V 0
B2 2
dV
V V0
mR
SR
27.
SS
dS S
S 0
V0mR
B2 2
A particle with total mechanical energy, which is small and negative, is under the influence of a one
dimensional potential U(x) = x4/4 x2/2 J where x is in meters. At time t = 0 s, it is at x = 0.5 m. Then
at a later time it can be found.
(A) anywhere on the x axis
(B) between x = 1.0 m to x = 1.0 m
(C) between x = 1.0 m to x = 0.0 m
(D) between x = 0.0 m to x = 1.0 m.
,d d.k _.kkRed vksj FkksM+h (small) lEiw.kZ ;kaf=kd tkZ ds lkFk ,dfoeh; foHko U(x) = x4/4 x2/2 J ds varxZr
gS] (;gkW x ehVj esa gS]) le; t = 0 s ij ;g x = 0.5 m ij gS] dqN le; ds ckn ;g d.k dgkW ik;k tk ldrk gSA
(A) x v{k ij dgkW Hkh
(B) x = 1.0 m vksj x = 1.0 m ds chp esa
(C) x = 1.0 m vksj x = 0.0 m ds chp eas
(D) x = 0.0 m vksj x = 1.0 m ds chp eas
Sol.
U
x = 1
x = +1
x
x=0
x 2
Total
energy
x 2
Since total energy is small ve and the particle starts from x = 0.5, so the particle can lie anywhere
from x (0 to 2 )
PAGE - 14
28.
A nurse measures the blood pressure of a seated patient to be 190 mm of Hg.

(A) the blood pressure at the patient's feet is less than 190 mm of Hg.
(B) the actual pressure is about 0.25 times the atmospheric pressure.
(C) the blood pressure at the patient's neck is more than 190 mm of Hg.
(D) the actual pressure is about 1.25 times the atmospheric pressure.
,d ulZ ,d cSBs gq, ejht dk jDr nkc ekirh gS] og bl nkc dks 190 mm ikjs (Hg) ds nkc ds cjkcj ikrh gS]
fuEufyf[kr esa ls lR; dFku pqfu;sA
(A) ejht ds iSjksa dk jDr nkc ikjs (Hg) ds 190 mm nck ls de gSA
(B) ulZ ds }kjk ekik x;k okLrfod nkc] ok;qeaMyh; nkc dk 0.25 xquk gSA
(C) ejht ds xys dk jDr nkc ikjs (Hg) ds 190 mm nkc ls vf/kd gSA
(D) ulZ ds }kjk ekik x;k okLrfod nkc] ok;qeaMyh; nkc dk 1.25 xqwuk gSA
Sol.
The blood pressure is the gauge pressure (the pressure excess to the atmospheric pressure)
P
19
So P = 19 cm of Hg =
P0 = 0
76
4
P
Absolute pressure of blood = P0+ o = (1.25) P0

4
29.
A particle at a distance of 1m from the origin starts moving such that dr/d = r, where (r, ) are polar
coordinates. Then the angle between resultant velocity and tangential velocity component is :
(A) 30 degrees
(B) 45 degrees
(C) 60 degrees
(D) dependent on where the particle is
,e d.k tks fd ewy fcUnq ls 1m dh nwjh ij gS bl izdkj pykuk izkjEHk djrk gS fd dr/d = r, tgkW (r, )
/kqzoh; funsZ'kkad gSa] rc ifj.kkeh osx rFkk osx ds Li'kZjs[kh; Hkkx ds chp dk dks.k
(A) 30 gSA
(B) 45 gSA
(C) 60 gSA
(D) d.k dh fLFkfr ij fuHkZj djrk gSA
Sol.
dr
dr / dt
r
r
d
d / dt
dr / dt
dr
r
r
dt
Vt=r
Vnet=r 2
=45
Vr=r
30.
Electrons accelerated from rest by an electrostatic potential are collimated and sent through a Young's
double slit setup. The fringe width is w. If the accelerating is doubled then the width is now close to :
fLFkjfo|qr foHko }kjk foJke voLFkk ls Rofjr fd;s x, bysDVkWuksa dks lekukUrfjr djds ;ax f} f>jh (Young's
double slit) ij Mkyk tkrk gS] fat pkSM+kbZ w gS] ;fn Rofjr foHko dks nks xquk fd;k tk;s rks fat pkSM+kbZ dk
fudVre~ eku gksxkA
(A) 0.5 w
Sol.
(B) 0.7 w
(C) 1.0 w
(D) 2.0 w
De-Broglie wavelength of the electron is

h
h
D
=
=
and fringe width =
P
d
2mqV
1
If V 2 times
times fringe width =
1
2
times = 0.7 times
PAGE - 15
31.
A metallic sphere is kept in between two oppositely charged plates. The most a appropriate
representation of the field lines is :
,d /kkrq ds xksys dks nks foijhr vkosf'kr ifV~V;ksa ds chp esa j[kk gS] js[kk&{ks=kksa dk lgh fp=k.k fuEu esa ls fdl fp=k
esa iznf'kZr gSA
(A)
(B)
(C)
(D)
Sol.
The electrical field lines fall on the metal surface normally and (one out of the metal surface also
normally).
So ans. Will be (B)
32.
An electron with kinetic energy E collides with a hydrogen atom in the ground state. The collision will be
elastic.
(A) for all values of E.
(B) for E < 10.2 eV.
(C) for 10.2 eV < E < 13.6 eV only.
(D) for 0 < E < 3.4 eV only
xfrt tkZ E ds lkFk ,d bysDVkWu ewy voLFkk esa ,d gkbMkstu ijek.kq ls la?kV~ (collide) djrk gS] ;g la?kV~
izR;kLFk gksxkA
(A) E ds lHkh eku ds fy,
(B) E < 10.2 eV ds fy,
(C) dsoy 10.2 eV < E < 13.6 eV ds fy,
(D) dsoy 0 < E < 3.4 eV ds fy,
Sol.
If energy of electron is less than 10.2 eV then it will not able to excite the H-electron. So the collision will
be elastic.
33.
The continuous part of X-ray spectrum is a result of the

(A) photoelectric effect
(B) Raman effect
(C) Compton
(D) inverse photoelectric field
fuEu esa dkSulk izHkko X-fdj.k o.kZe ds fujarj (continuous) Hkkx ds fy, mkjnk;h gSA
(A) izdk'koS|qr izHkko
(B) jeu izHkko
(C) dkWEiVu izHkko
(D) O;qRe izdk'koS|qr izHkko
Sol.
The production of continuous X-ray is the inverse process of photo-electric effect.
34.
Thermal expansion of a solid is due to the

(A) symmetric characteristic of the inter atomic potential energy curve of the solid
(B) asymmetric characteristic of the inter atomic potential energy curve of the solid
(C) double well nature of the inter-atomic potential energy curve of the solid.
(D) rotational motion of the atoms of the solid
,d Bksl ds rkih; izlkj ds fy, fuEu esa ls D;k mkjnk;h gksrk gSA
(A) Bksl ds varj&ijekf.od fLFkfrt tkZ vkjs[k dk lefer xq.k
(B) Bksl ds varj&ijekf.od fLFkfrt tkZ vkjs[k dk vlefer xq.k
(C) Bksl ds varj&ijekf.od fLFkfrt tkZ vkjs[k dk f}dwi (double well) Lo:i
(D) Bksl ds ijek.kqvksa dh ph; xfr
PAGE - 16
Sol.
The thermal expansion in the solids occurs because the inter-atomic potential graph is asymmetrical
35.
An electron an a photon have same wavelength of 10 m. If E is the energy of the photon and p is the
momentum of the electron, the magnitude of E/p in SI units is :
,d bysDVkWu vkSj Q+ksVksu dk ,d leku rjaxnS/;Z 109 m gSA ;fn Q+ksVksu dh tkZ E rFkk bysDVkWu dk laosx p
gks rks SI ek=kd esa E/p dk eku gksxk :
9
(A) 1.00 10
Sol.
The De-Broglie wavelength of an electron =
36.
(B) 1.50 10
hc
The wavelength of photon =
E
(C) 3.00 10
(D) 1.20 10
h
P
Since photon = electron

hc h
E
C 3 108 m / sec.
E P
P
If one takes into account finite mass of the proton, the correction to the binding energy of the hydrogen
atom is approximately (mass of proton = 1.60 1027 kg, mass of electron = 9.10 1031 kg)
;fn izksVksu ds ifjfer Hkkj (finite mass) dks lfEefyr djds gkbMkstu ijek.kq dh ca/ku tkZ dk vadu fd;k
tk;s rks ca/ku tkZ ds eku esa la'kks/ku yxHkx gksxkA (izksVksu dk Hkkj = 1.60 1027 kg, bysDVkWu dk Hkkj =
9.10 1031 kg)
(A) 0.06%
Sol.
(B) 0.006%
(C) 0.02%
me
9.1 10 31
% correction in BE =
100%
100%
mp
1.6 10 27
(D) 0.00%
= 0.0568% 0.06%
37.
A monochromatic light source S of wavelength 440 nm is placed slightly above a plane mirror M as
shown. Image of S in M can be used as a virtual source to produce interference fringes on the screen.
The distance of source S from O is 20.0 cm, and the distance of screen from O is 100.0 cm (figure is
not to scale). If the angle = 0.50 103 radians, the width of the interference fringes observed on the
screen is :
,d ,do.khZ izdk'k L=kksr S ftldk rjaxnS/;Z 440 nm gS] dks ,d lery niZ.k M ds ij fp=kkuqlkj
gSA M esa S ds izfrfcEc dks ,d dfYir L=kksr dh rjg mi;ksx djds ijns (screen) ij O;frdj.k
fd;k tk ldrk gSaA L=kksr S dh O ls nwjh 20.0 cm gS rFkk ijns dh O ls nwjh 100.0 cm gS (fp=k
vuqlkj ugha gSA) ;fn dks.k = 0.50 103 jsfM;u gks rks ijns ij ns[kh tkus okyh O;frdj.k fatksa
gksxhA
j[kk tkrk
fat izkIr
vuqikr ds
dh pkSM+kbZ
S
SO = 20.0 cm
(A) 2.20 mm
(B) 2.64 mm
(C) 1.10 mm
Screen
(D) 0.55 mm
PAGE - 17
Sol.
Distance between
S and S
S
20 sin
20 cm
20 sin
S
d = 2 20sin
d = 40 = 40 0.5 103
= 0.02 m
9
D 440 10 1 0.2
Fringe width =
d
0.02
= 2.67 mm
38.
A nuclear fuel rod generates energy at rate of 5 108 Watt/m3. It is in the shape of a cylinder of radius
4.0 mm and length 0.20 m. A coolant of specific heat 4 103 J/(kg-K) flows past it at a rate of 0.2 kg/s.
The temperature rise in this coolant is approximately.
,d ukfHkdh; tkZ NM+ (Nuclear fuel rod) 5 108 Watt/m3 dh nj ls tkZ mRiUu djrh gS] ;g
csyukdkj gS ftldh f=kT;k 4.0 mm rFkk yEckbZ 0.20 m gSA bl ij ls ,d 'khryd] ftldh fof'k"V "ek 4
103 J/(kg-K) gSA 0.2 kg/s dh nj ls bl ij cgrk gSA 'khryd esa rkieku yxHkx fdruk c<+sxk \
Sol.
39.
(A) 2C
(B) 6C
(C) 12C
Rate heat produced = (5 108) (Vol)
= (5 108) (r2) = (5 108) ((4 103)2 0.2)
= 16 102 J/sec.
dQ dm
ST
dt dt
16 102 = (0.2) (4 103)T
T = 2 = 6.286
(D) 30C
A hearing test is conducted on an aged person. It is found that her threshold of hearing is 20 decibels at
1 kHz and it rises linearly with frequency to 60 decibels at 9 kHz. The minimum intensity of sound that
the person can hear at 5 kHz is :
(A) 10 times than that at 1 kHz
(B) 100 times than that at 1 kHz
(C) 0.5 times than that at 9 kHz
(D) 0.05 times than that at 9 kHz
,d cqtqxZ O;fDr dh Jo.k {kerk dk ewY;kadu fd;k tk jgk gSA ;g ik;k tkrk gS fd mudh nsgyh Jo.k {kerk
(threshold of hearing ) 1 kHz ij 20 Msflcy gS vkSj ;g js[kh; :i ls 9 kHz ij 60 Msflcy rd
c<+rh gSA vkokt dh U;wure rhozrk] tks ;g O;fDr 5 kHz ij lqu ldrk gS] fuEUkfyf[kr esa D;k gksxh \
(A) 1 kHz dh rhozrk ls 10 xquk
(C) 9 kHz dh rhozrk ls 0.5 xquk
(B) 1 kHz dh rhozrk ls 100 xquk

(D) 9 kHz dh rhozrk ls 0.05 xquk
Sol.
dB
60 dB
40 dB
20 dB
1kHz
5kHz
9kHz
PAGE - 18
dB = 10 log

20 = 10 log 1
0

40 = 10 log 2
0
Subtracting both the equations:

20 = 10 log 2 log 1
0
0

2 = log10 2 2 10 2 2 = 100 1
1
1
40.
Two infinitely long parallel wires carry currents of magnitude I1 and I2 and are at a distance cm apart.
The magnitude of the net magnetic field is found to reach a non-zero minimum value between the two
wires and 1 cm away from the first wire. The ratio of the two currents and their mutual direction is :
(A) 2 9 , antiparallel
(B) 2 9 , parallel
1
1
(C)
2
3 , antiparallel
1
(D)
2
3 , parallel
1
nks vuar yEcs lekukUrj rkjksa esa tks fd ,d nwljs ls 4 cm nwjh ij gSa e'k% I1 rFkk I2 eku dh /kkjk,a izokfgr gks
jgh gSa] nksuksa rkjksa ds chp esa rFkk igys rkj ls 1 cm nwjh pqEcdh; {ks=k dk eku v'kwU; fuEUkre (non-zero
minimum) ik;k tkrk gS] nksuksa /kkjkvksa dk vuqikr rFkk mudh ikjLifjd fn'kk,a gksaxhA
(A)
2
9 , foijhr
1
(B)
2
9 , leku
1
3 , foijhr
(D) 2 3 , leku
1
1
To achieve a non-zero magnetic field between the wires, the current in the wire should be in opposite
direction :
B
(C)
Sol.
i1
(4 x)
i2
0i1
0 i2
2x 2(4 x)
dB
B will be min. when
0
dx
dB
i
m0 i2
0 12
0
dx
2x
2(4 x)2
B (x) =
i2 4 x
4 1

9
i1 x
1
PAGE - 19
CHEMISTRY
41.
Sol.
42.
The shape of SCl4 is best described as a

(A) Square
(B) Tetrahedron
(C) Square pyramid
(D) See-saw
SCl4 dh vkd`fr (shape) dks lcls vPNs :i esa fuEu izdkj of.kZr fd;k tkrk gS&
(A) oxZ
(B) prq"Qyd
(C) oxZ fijkfeM
(D) <sadqyh (see-saw)
SCl4 has 4 BP and 1 LP, and its shape is described as see-saw :
SCl4, 4 BP rFkk 1 LP j[krk gS rFkk bldh vkd`fr <sdqyh gksrh gSA
Among the following atomic orbital overlaps, the non-bonding overlap is
fn, x, ijekf.od vkWfcZVy vkPNknu (overlap) esa ls dkSu lk vca/kuh; (non-bonding) vkPNknu dks fu:fir
djrk gS&
+
(A)
Sol.
43.
Sol.
(B)
+ +

(C) + +
In (A) lobes of P orbital overlap to each other .

(A) esa P d{kd dh ikfy;k ,d&nwljs esa vfrO;kfir
(D)
+
+
gksrh gSA
Among the following complexes, the one that can exhibit optical activity is
uhps fn, x, ladqyksa (complexes) esa ls dkSu lk izdk'kh; lf;rk n'kkZrk gS&
3
+
+
(A) [CoCl6]
(B) [Co(en)Cl4]
(C) cis-[Co(en)2Cl2]
(D) trans-[Co(en)2Cl2]
The mirror image is non super imposable .
ni.kZ izfrfcEc vuv/;kjksfir gksrs gSaA

44.
Sol.
The pKa of oxoacids of chlorine in water follows the order

ty esa Dyksjhu ds vksDlks vEyksa ds pKa eku dk lgh e gS&
(A) HClO < HClO3 < HClO2 < HClO4
(B) HClO4 < HClO3 < HClO2 < HClO
(C) HClO4 < HClO2 < HClO3 < HClO
(D) HClO2 < HClO < HClO3 < HClO4
Acidity increases with increase in oxidation number of central atom. Greater the acidity lesser the pKa.
vEyh;rk dsUnzh; ijek.kq dh vkWDlhdj.k la[;k esa o`f) ds lkFk c<+rh gSA vEyh;rk vf/kd gksus ij pKa eku de
gksrk gSA
45.
Sol.
The packing efficiency of the face centered cubic (fcc), body centered cubic (bcc) and simple/primitive
cubic (pc) lattices follows the order
Qyd dsfUnzr ?kuh; (fcc), dk; dsfUnzr ?kuh; (bcc) ,oa ljy@vk| ?kuh; (pc) tkydksa dh ladqyu n{krk (packing
efficiency) fuEu e dk vuqlj.k djrh gS&
(A) fcc > bcc > pc
(B) bcc > fcc > pc
(C) pc > bcc > fcc
(D) bcc > pc > fcc
Based on volume occupied calculation (see text-book).
Volume of atoms in a unitcell
% Packing efficiency =
100
Total volume of a unit cell
Z (no. of atom per unit cell)

Simple cubic
Relation b/w edge

length (a) and radius R
a = 2R
% P.E.
4
1 R3
3
=
100 = 52.33%
3
(2R)
Body centre cubic
3a = 4R
4
2 R3
3
=
100 = 68%
3
4R
Face centered cubic
2a = 4R
4
4 R 3
3
=
100 = 74%
3
4R
Sol.
?ksjs x;s vk;ru ij vk/kkfjr ifjdyu (ikB~; iqLrd ns[ksa)

,d ,dd dksf"Bdk esa ijek.kqvksa dk vk;ru
,d ,dd dksf"Bdk dk dqy vk;ru
% ladqyu n{krk =
100
PAGE - 20
Z (izfr ,dd dksf"Bdk ijek.kq dh la[;k)
ljy ?kuh;
dksj yEckbZ (a) rFkk f=kT;k

R ds e/; lEcU/k
a = 2R
% P.E.
4
1 R3
3
=
100 = 52.33%
3
(2R)
dk; dsfUnzr ?kuh;
3a = 4R
4
2 R3
3
=
100 = 68%
3
4R
Qyd dsfUnzr ?kuh;
2a = 4R
4
4 R 3
3
=
100 = 74%
3
4R
46.
Sol.
47.
48.
Sol.
49.
The ratio of root mean square velocity of hydrogen at 50 K to that of nitrogen at 500 K is closest to
50 K ij gkbMkstu ,oa 500 K ij ukbVkstu ds oxZ&ek/;&ewy osx dk vuqikr yxHkx gSA
(A) 1.18
(B) 0.85
(C) 0.59
(D) 1.40
3RT
Crms =
M
(Crms )H2
TH2 MN2
50 28
= 1.18
(Crms )N2
MH2 TN2
2 500
The molecule with the highest dipole moment among the following is
fuEufyf[kr esa lcls cM+k f}/kqzo vk?kw.kZ (dipole moment) okyk v.kq gSA
(A) NH3
(B) NF3
(C) CO
(D) HF
The most stable Lewis acid-base adduct among the following is

fuEufyf[kr esa lcls vf/kd LFkk;h yqbZl vEy&{kkj ;ksxksRikn (Lewis acid-base adduct) gSA
(A) H2O BCl3
(B) H2S BCl3
(C) H3N BCl3
(D) H3P BCl3
N, the best Lewis doner among N,P,O and S atom.
N,P,O rFkk S ijek.kqvksa esa ls N ijek.kq Js"B yqbZl nkrk gSA
The reaction of D-glucose with ammoniacal AgNO3 produces
D-Xywdkst dk vkseksfu;kd`r AgNO3 ds lkFk vfHkf;k mRiUu djrk gSA
CO2H
CO2H
CHO
OH
OH
H
H
OH
H
H
H
HO
HO
H
HO
OH
OH
(A) H
(B) H
(C*) H
OH
OH
OH
H
H
OH
H
CO2H
CH2OH
CHO
H
HO
(D) H
H
CO2H
OH
H
OH
OH
CHO
Sol.
Only CHO group is oxidized to acid.

dsoyCHO lewg vEy esa vkWDlhd`r gksrk gSA
50.
The reagent(s) used for the conversion of benzene diazonium hydrogensulfate to benzene is/are
csathu MkbZtksfu;e gkbMkstu&lYQsV dks csathu esa ifjofrZr djus ds fy, mi;ksx fd;k tkus okyk vfHkdkjd gSA
Sol.
(A) H2O
(B) H3PO2 + H2O
(C) H2SO4 + H2O
H3PO2 reduces benzene diazonium salt to benzene.
H3PO2 csUthu MkbZ,tksfu;e yo.k dks csUthu esa vipf;r djrk gSA
(D) CuCl/HCl
PAGE - 21
51.
The major product obtained in the reaction of toluene with 1-bromo-2-methyl propane in the presence of
anhydrous AlCl3 is :
futZy ,yqfefu;e (anhydrous AlCl3) dh mifLFkfr esa VkWyqbZu dh vfHkf;k 1-czkseks-2-esfFky izksisu ls djkus ij
izkIr gksus okyk eq[; mRikn gSA

CH3
H 3C
H 3C
(A)
Sol.
(B)
(C)
(D)
H 3C
This reaction is friedel craft alkylation.
;g vfHkf;k fMsy kV ,fYdyhdj.k gksrh gSA

+
Br
52.
AlCl3
H 3C
Toluene
The major product in the following reaction is
fuEufyf[kr vfHkf;k
OH
(CH CO) O
3
2
OH
CH3COOH
esa eq[; mRikn gS

O
OH
(A)
Sol.
CH3
H3C
OH
O
CH3
(B)
OH (C) H3C
O
O
O
Acetylation on phenolic group takes place.
OH
O
O
OH
(D)
OH
O
fQuksfyd lewg ij ,flfVyhdj.k dj.k gksrk gSA

53.
Sol.
54.
The compounds containing sp hybridized carbon atom are

fuEufyf[kr esa ls ,sls ;kSfxd] ftuesa dkcZu ijek.kq sp izladj.k esa gSa] gksxk
H3C
CHO
N
(i)
(ii)
(iii) H3CCN
(iv) H2C=C=CHCH3
CH3
N
(A) (i) and ,oa (ii)
(B) (iii) and ,oa (iv)
(C) (ii) and ,oa (iii)
(D) (i) and ,oa (iv)
H3CCN and H2C=C=CHCH3 has sp hybrid carbon.
H3CCN rFkk H2C=C=CHCH3 , sp ladj ijek.kq j[krs gSA
Upon heating with acidic KMnO4, and organic compound produces hexan-1,6-dioic acid as the major
product. The starting compound is
(A) benzene
(B) cyclohexene
(C) 1-methylcyclohexene
(D) 2-methylcyclohexene
,d dkcZfud ;kSfxd vEyh; KMnO4 ds lkFk xeZ fd;s tkus ij eq[; mRikn ds :i esa gsDlsu-1,6-Mkbvksbd vEy
mRiUu djrk gS] izkjfEHkd dkcZfud ;kSfxd gS&

(A) csathu
(C) 1-esfFkylkbDyksgsDlhu
H
H
H
H
acidic KMnO4
strong oxidising agent
vEyh; KMnO4
izcy vkWDlhdkjd
(B) lkbDyksgsDlhu
(D) 2-esfFky lkbDyksgsDlhu
COOH
COOH
COOH
COOH
PAGE - 22
55.
It takes 1 h for a first order reaction to go to 50% completion. The total time required for the same
reaction to reach 87.5% completion will be
fdlh izFke dksfV vfHkf;k ds 50% iw.kZ gksus esa 1 ?k.Vk le; yxrk gSA mlh vfHkf;k ds 87.5% iw.kZ gksus ds fy,
vko';d dqy le; gksxk&

Sol.
56.
(A) 1.75 h
(B) 6.00 h
t1/2 = 1 hrs
t87.5% = 3 t1/2
= 3 1 = 3hrs
(C) 350 h
(D) 3.00 h
A unit cell of calcium fluoride has four calcium ions. The number of fluoride ions in the unit is
dSfYl;e yksjkbM ds ,dd dksf"Bdk (unit cell) esa pkj dSfYl;e vk;u gS] bl ,dd dksf"Bdk esa yksjkbM vk;uksa
dh la[;k gS \
Sol.
Sol.
(A) 2
(B) 4
CaF2 Fluorite structure
Co-ordination number of compound
8:4
+2
Effective number of Ca ion = 4
Effective number of F ion = 8

CaF2 yksjkbV lajpuk
(C) 6
(D) 8
;kSfxd dh leUo; la[;k

8:4
+2
Ca vk;u dh izHkkoh la[;k = 4
F vk;u dh izHkkoh la[;k = 8
57.
Sol.
58.
The equilibrium constant of a 2 electron redox reaction at 298 K is 3.8 103 . The cell potential E(in V)
and the free energy change G (in kJ mol1) for this equilibrium, respectively, are
298 K ij nks bysDVkWu vip;ksip; (redox) vfHkf;k dk lkE; fLFkjkad 3.8 103 gSA bl lkE;koLFkk ds fy, lsy
foHko E(V esa) ,oa eqDr tkZ ifjorZu G (kJ mol1 esa) e'k% gS&
(A) 0.071, 13.8
(B) 0.071, 13.8
(C) 0.71, 13.8
(D) 0.071, 13.8
G = 2.303 RT log K
G = 2.303 8.314 103 298 log 3.8 103
= 13.8 KJ/mol
G = nFE
G
( )13.8 103
E =
=
= 0.071 V
nF
2 96500
The number of stereoisomers possible for the following compound is
CH3CH=CHCH(Br)CH2CH3
fuEu ;kSfxd ds fy, f=kfoe leko;fo;ksa dh laHkkfor la[;k gS&

Sol.
Sol.
59.
CH3CH=CHCH(Br)CH2CH3
(A) 2
(B) 3
(C) 4
(D) 8
CH3CH=CHCH(Br)CH2CH3 has one geometrical stereo unit and one optical stereo unit on different
location, hence it has 4 possible stereo isomers namely (Z, R), (Z, S), (E, R) and (E, S).
CH3CH=CHCH(Br)CH2CH3 ,d T;kferh; f=kfoe bdkbZ j[krk gS rFkk fHkUu fLFkfr ij ,d izdkf'kd f=kfoe
bdkbZ j[krk gS blfy, ;g (Z, R), (Z, S), (E, R) rFkk (E, S) uke okys pkj lEHko f=kfoe leko;oh j[krk gSA
232
In the radioactive disintegration series 90
Th 208
82 Pb , involving and decay, the total number of
and particles emitted are
(A) 6 and 6
(B) 6 and 4
(C) 6 and 5
(D) 5 and 6
232
208
;fn jsfM;ks&lf; fo[k.Mu Js.kh 90 Th 82 Pb esa dsoy ,oa {k; gksrk gS] rks mRlftZr ,oa d.kksa dh dqy
la[;k gksxh&
(A) 6 and ,oa 6
(B) 6 and ,oa 4
(C) 6 and ,oa 5
(D) 5 and ,oa 6
PAGE - 23
Sol.
232
90
208
Th 82 Pb
232 208
4
232 208
-d.k dh la[;k =
=6
4
A AP
-d.k dh la[;k = [ZP ZR] + R
232 208
= [82 90] +
No. of -particle =
60.
=4
In the following compressibility factor (Z) vs. pressure graph at 300 K, the compressibility of CH4 at
pressures <200 bar deviates from ideal behaviour because
Compressibility
factor (Z)
1.8
CH4
1.0
ideal gas
0.2
0
200
600
1000
pressure (bar)
(A) the molar volume of CH4 is less than its molar volume in the ideal state
(B) the molar volume of CH4 is same as that in its ideal state
(C) intermolecular interactions between CH4 molecules decreases
(D) the molar volume of CH4 is more than its molar volume in the ideal state
300 K ij lEihM~;rk xq.kkad (z) vkSj nkc ds chp ds uhps fn, vkjs[k esa CH4 dh lEihM~;rk 200 bar ls de ncko
ij vkn'kZ O;ogkj ls fopyu fn[kkrh gSA

lEihM~;rk xq.kkad (Z)
1.8
CH4
1.0
vkn'kZ xSl
0.2
0
200
600
1000
nkc (bar)
bldk dkj.k gS %
(A) CH4 dk eksyj vk;ru blds vkn'kZ voLFkk eksyj vk;ru ls de gSA
(B) CH4 dk eksyj vk;ru blds vkn'kZ voLFkk eksyj vk;ru ds leku gSA
(C) CH4 v.kqvksa ds chp vUrj&vkf.od (intermolecular) vU;ksU; f;k, ?kV tkrh gSA
(D) CH4 dk eksyj vk;ru mlds vkn'kZ voLFkk eksyj vk;ru ls vf/kd gSA
Sol.
Sol.
Vm (real)
Vm (ideal)
Vm(real) < Vm(ideal)
V ( okLrfod )
Z= m
Vm ( vkn'kZ )
Z=
Vm(okLrfod) < Vm(vkn'kZ)
PAGE - 24
BIOLOGY
61.
Ans.
62.
Which of the following molecules is a primary acceptor of CO2 in photosynthesis?

(A) Pyruvate
(B) 3-phosphoglycerate
(C) Phosphoenol pyruvate
(D) Oxaloacetate
fuEufyf[kr esa ls dkSulk v.kq izdk'k la'ys"k.k dh izf;k esa CO2 dk izkFkfed xzkgh gS?
(A) ikbZ:osV
(B) 3-QkWLQksfXyljsV
(C) QkWLQksbukWy ikbZ:osV
(D) vkWDtSyks,lhVsV
(C)
Which one of the following pairs of molecules NEVER from a hydrogen bond between them ?
(A) Water and water
(B) Water and glucose
(C) Water and ethanol
(D) Water and octane
fuEufyf[kr esa ls v.kqvksa dk dkSulk ;qXe dHkh Hkh gkbMkstu ca/k ugha cukrk gS \
(A) ikuh vkSj ikuh
(B) ikuh vkSj Xywdkst
(C) ikuh vkSj bFksukWy
(D) ikuh vkSj vkWDVsu
Ans.
(D)
63.
Lactase hydrolyses lactose into

(A) glucose + glucose
(C) galactose + galactose
(B) glucose + galactose

(D) galactose + fructose
ySDVsV fcdj }kjk ySDVkst+ ds ty&vi?kVu ls fuEu esa ls D;k izkIr gksrk gS\
(A) Xywdkst+ + Xywdkst+
(B) Xywdkst+ + xSysDVkst+
(C) xSysDVkst+ + xSysDVkst+
(D) xSysDVkst+ + DVkst+
Ans.
(B)
64.
Which of the following statements INCORRECT regarding biological membrane?

(A) It is composed of lipids and proteins
(B) Peripheral proteins are loosely associated with the membrane
(C) Integral proteins span the lipid bilayer
(D) Lipids and membrane proteins do not provide structural and functional asymmetry
fuEufyf[kr esa ls dkSulk dFku tSfod f>Yyh ds fo"k; esa vlR; gS\
(A) ;g izksVhu vkSj fyfiM ls fey dj cuh gksrh gSA
(B) ifj/kh; izksVhu bl f>Yyh ls f'kfFkyrk ls tqM+s gksrs gSaA
(C) vfuok;Z izksVhu fyfiM dh f}Lkrg ds vkj ikj tkrs gSaA
(D) fyfiM vkSj f>Yyh ds izksVhu] lajpukRed vkSj f;kRed vlefefr ugha iznku djrs gSaA
Ans.
(D)
65.
The percentage of sunlight captured by plants is

(A) 2-10%
(B) 10-20%
(C) 60-80%
(D) 100%
ikS/ks lw;Z ds izdk'k dk fdruk izfr'kr xzg.k djrs gS\a

Ans.
66.
Ans.
(A) 2-10%
(A)
(B) 10-20%
(C) 60-80%
(D) 100%
The hard outer layer of pollens, named exine, is made of

(A) cellulose
(B) Tapetum
(C) Sporopollenin
(D) pectin
ijkxd.kksa dh dBksj ck lrg] ,Dt+kbu] fuEu esa ls fdldh cuh gksrh gS\
(A) lSY;wykst+
(B) VSihVe
(C) Liksjksysfuu
(D) isfDVu
(C)
PAGE - 25
67.
Insectivorous plants such as Venus fly trap catch and digest insects in order to supplement the
deficiency of
(A) sulphur
(B) nitrogen
(C) potassium
(D) Phosphorus
dhV Hk{kh ikS/ks] tSls dh ohul ykbZ VSi] fuEufyf[kr esa ls fdldh deh ls iwjk djus ds fy, dhVksa dks idM+ dj
ikpu djrs gSa\
(A) lYQj
(B) ukbVkstu
(C) iksVSf'k;e
(D) QkWLQksjl
Ans.
(B)
68.
Which of the following statements about nucleosome is TRUE ?

(A) It consist of only DNA
(B) It is a nucleus-like structure found in prokaryotes.
(C) It consists of DNA and proteins
(D) It consists of only histone proteins
U;wfDy;kslkse ds lanHkZ esa dkSulk dFku lR; gS \

(A) blesa dsoy DNA ik;k tkrk gSa
(B) ;g iwoZdsanzdh; dksf'kdkvksa esa ik;h tkus okyh dsUnzd tSlh lajpuk gS
(C) blesa DNA vkSj izksVhUl nksuksa gh ik, tkrs gSa
(D) blesa dsoy fgLVksUl ik;s tkrs gSa
Ans.
(C)
69.
Epithelial cells in animals are held by specialized junctions, one of them being "Gap junction". Function
of a "Gap junction" is to
(A) facilitate cell-cell communication by rapid transfer of small molecules
(B) cement the neighbouring cells
(C) stop substances from leaking
(D) provide gaps in the tissue to facilitate uptake of small molecules across tissues
tUrqvksa esa midyk dksf'kdk, vkil esa ,d nwljs ls fo'ks"k izdkj ds tksM+ksa (junctions) tSls dh xSi (gap) tksM+ ls
tqM+s gksrs gSa] xSi tksM+ dk dke D;k gS\

(A) NksVs v.kqvksa ds Rofjr LFkkukUrj.k }kjk dksf'kdkvksa ds e/; lapkj lqyHk djkukA
(B) iM+kslh dksf'kdkvksa dks ,d LFkk ck/ks j[krh gSA
(C) inkFkksZa ds fjlko dks jksdrh gSA
(D) rdksa esa fjfDr (gap) iznku dj muds vkj ikj NksVs v.kqvksa dk mn~xzg.k (uptake) lqyHk djkukA
Ans.
(A)
70.
Which of the following statements is TRUE about glandular epithelium in salivary gland?
(A) It consists of isolated single cells.
(B) It consists of multicellular cluster of cells.
(C) Its secretions are endocrine.
(D) It consists of squamous epithelial cells.
xzafFk;ksa dh xzaFkh; midyk ds fo"k; esa dkSulk dFku lR; gS \

(A) blesa foykfxr ,dy dksf'kdk, gksrh gSA
(B) buesa cgqdksf'kdh;] dksf'kdkvksa ds xqPNs gksrs gSaA
(C) buds ko] var%koh gksrs gSa]
(D) buesa 'kYdh; midyk dksf'kdk, gksrh gSA
Ans.
(B)
71.
Which one of the following ion pairs is involved in nerve impulses?

+
+
+
+
+
2+
(A) Na , K
(B) Na , Cl
(C) K , Cl
(D) K , Ca
fuEufyf[kr esa ls dkSulk vk;u ;qXe] raf=kdk vkosxksa (impulses) esa dk;Zjr gS \
(A) Na+, K+
(B) Na+, Cl(C) K+, Cl(D) K+, Ca2+
(A)
Ans.
72.
Which of the following hormones that controls blood pressure is secreted by human heart?
(A) Erythropoetin
(B) Atrial natriuretic factor
(C) ACTH
(D) Glucocorticoid
fuEufyf[kr esa ls fdl gkWeksZUl] tks fd jDr pki dks fu;af=kr djrk gS] dk ko.k ekuo n; ls gksrk gS \
(A) bfjFkzksiksbZfVu
(B) ,Vh;y uSVh;qjsfVd QSDVj
(C) ACTH
(D) XyqdksdksVhZDok;M
Ans.
(B)
PAGE - 26
73.
Oxytocin and vasopressin are synthesized in

(A) hypothalamus
(B) adrenal gland
(C) pituitary gland
(D) ovary
vkWDlhVkslhu vkSj oSlksizsflu dk fuekZ.k dgk gksrk gS \

(A) gkbiksFkSysel
(B) vf/ko`Dd xzafFk
(C) ih;w"k xzafFk
(D) v.Mk'k;
Ans.
(C)
74.
If you exhale multiple times into a conical flask containing lime water through a single inlet fixed through
a stop cock, lime water will.
(A) become cooler
(B) turn milky
(C) remain unchanged
(D) turn yellow
,d 'kaDokdkj ykLd] ftlesa pwuk ikuh (lime water) gS] ds eq[k ij jks/kuh yxkdj ,dy fuxZe (single outlet) }kjk
dbZ ckj mPNo'ku (exhale) djrs gSa bl izf;k ls pwuk ikuh esa dSlk cnyko vk;sxk \
(A) B.Mk gks tk,xk
(B) nwf/k;k gks tk,xk
(C) dksbZ cnyko ugha gksxk
(D) ihyk gks tk,xk
(B)
Ans.
75.
The path of passage of stimulus when you accidentally touch a hotplate is

(A) receptor brain muscles
(B) muscles spinal cord receptor
(C) muscles brain receptor
(D) receptor spinal cord muscles
vpkud xeZ ros dks Nw ysus ij mn~nhiu ds izokg dk iFk fuEu esa ls dSlk gksxk \
(A) xzkgh efLr"d eklisf'k;k
(B) eklisf'k;k es: jTtw xzkgh
(C) eklisf'k;k efLr"d xzkgh
(D) xzkgh es: jTtw eklisf'k;k
Ans.
(D)
76.
In the presence of glucose and lactose. Escherichia coli utilizes glucose. However, lactose also enters
the cells because
(A) low level of permease is always present in the cell
(B) it uses the same transporter as glucose
(C) it diffuses through the bacterial cell membrane
(D) it is transported through porins
Xywdkst+ vkSj ySDVkst+ dh mifLFkfr esa Escherichia coli , Xywdkst+ dk mi;ksx djrk gS] fQj Hkh ySDVkst+ dksf'kdk ds
vUnj izos'k djrk gS] bldk D;k dkj.k gS \

(A) dksf'kdk ds vUnj ijfe;st+ dh lw{e ek=kk igys ls gh ekStwn gksrh gSA
(B) ySDVkst] Xywdkst ds okgd dk gh mi;ksx djrk gSA
(C) ySDVkst] thok.kq dh dksf'kdk f>Yyh ls vklkuh ls folfjr gks tkrk gSA
(D) ySDVkst dk ogu iksjhu izksVhu ds ek/;e ls gksrk gSA
Ans.
(A)
77.
Passive immunization is achieved by administering

(A) heat killed vaccines
(B) toxoids
(C) live attenuated vaccines
(D) antibodies
fuEu esa ls fdlds lekos'ku ls fuf"; izfrj{kk izkIr dh tk ldrh gS \

(A) "ek&e`r Vhdk
(B) fo"k (toxoids)
(C) thfor {kh.k Vhdk
(D) izfrj{kh
Ans.
(D)
78.
Which of the following anions neutralize the acidic pH of the chyme that enters into the duodenum from
the stomach?
(A) H2PO 4
(B) HSO4
(C) HCO3
(D) CH3 COO
fuEu esa ls dkSulk _.k&vkos'k (anions) vkek'k; ls xzg.kh esa izos'k djus okys vEyh; pH okys dkbZe (chyme) ds
mnklhuhdj.k ds fy, mkjnk;h gS \

Ans.
(A) H2PO 4
(C)
(B) HSO4
(C) HCO3
(D) CH3 COO
PAGE - 27
79.
If 14CO2 is added to a suspension of photosynthesizing chloroplasts, which of the following will be the
first compound to be radioactive?
(A) ATP
(B) NADPH
(C) NADH
(D) 3-phospho glycerate
;fn gfjr yod ds ,d izyacu (suspension) esa] tks izdk'k la'ys"k.k dj jgk gS] 14CO2 feyk;k tkrk gS rks
fuEufyf[kr esa ls dkSu lk izFke jsfM;k/kehZ ;kSfxd gksxk\

Ans.
80.
Ans.
(A) ATP
(D)
(B) NADPH
(C) NADH
(D) 3-QkWLQks fXyljsV
Which of the following species makes the largest true flower in the world?
(A) Amorphophallus titanium
(B) Rafflesia arnoldii
(C) Nelumbo nucifera
(D) Helianthus annuus
fuEu esa ls dkSu lh iztkfr fo'o ds lcls fo'kky lR; iq"i (true flower) dk fuekZ.k djrh gS\
(A) Amorphophallus titanium
(B) Rafflesia arnoldii
(C) Nelumbo nucifera
(D) Helianthus annuus
(B)
PART-II : (Two Marks Questions)
MATHEMATICS
81.
Sol.
The remainder when the polynomial 1 + x2 + x4 + x6 + ..... + x22 is divided by 1 + x + x2 + x3 + .... + x11 is
;fn cgqin 1 + x2 + x4 + x6 + ....... + x22 dks 1 + x + x2 + x3 + .... + x11 ls Hkkx fn;k tk, rks 'ks"k D;k gksxk (A) 0
(B) 2
(C) 1 + x2 + x4 + ....... + x10
(D) 2(1 + x2 + x4 + ...... + x10)
2
4
6
22
1 x x x ...... x
1 x x 2 x 3 ...... x 11
(1 x 24 )(1 x )
=
[G.P. formula]
(1 x 2 )(1 x12 )
1 x12
1 x
remainder on division we get = 2
hence option (B) is corrects
82.
1 1
The range of the polynomial p(x) = 4x3 3x as x varies over the interval , is
2 2
1 1
;fn cgqin p(x) = 4x3 3x, esa x dk eku , vUrjky esa gks rks cgqin dk ijkl (range) fuEu esa ls dkSu lk gS ?
2 2
(A) [1, 1]
(B) (1, 1]
Sol.
(C) (1, 1)
1 1
(D) ,
2 2
+1
1/2
1/2
1
f(x) = 4x3 3x
2
= x(4x 3)
f'(x) = 0
1
1
x= ,
2
2
1 1
if x ,
2 2
f(x) (1, 1)
PAGE - 28
83.
Ten ants are on the real line. At time t = 0, the k-th ant starts at the point K2 and travelling at uniform
speed, reaches the point (11 k)2 at time t = 1. The number of distinct times at which at least two ants
are at the same location is
nl phfV;k ,d okLrfod js[kk ij gS t = 0 le; ij k-phaVh fcUnq K2 ls 'kq: djds leku pky ls pyrs gq, t = 1
le; esa fcUnq (11 k)2 ij igqprh gS fdrus fHkUu le;ksa ij nks phfV;k ,d gh fcUnq ij ikbZ tk,axh ?
(A) 45
(B) 11
(C) 17
(D) 9
Sol.
Initial positions of ants were

(1, 0), (4, 0), (9, 0), ........, (64, 0), (81, 0), (100, 0)
at t = 1
there respective position are
(100, 0), (88, 0), ..........., (9, 0), (4, 0), (1, 0)
84.
A wall is inclined to the floor at an angle of 135. A ladder of length is resting on the wall. As the
ladder slides down. its mid-point traces an are of an ellipse. Then the area of the ellipse is
fp=k esa n'kkZ, vuqlkj ,d nhokj (wall) Q'kZ ls 135 dks.k ij >qdh gS yEckbZ dh ,d lh<+h (ladder) nhokj ij
fLFkj gS tSls-tSls lh<+h fQlyrh gS mldk e/; fcUnq ,d nh?kZ o`k dh pki ds vuqlkj ?kwerh gS nh?kZ o`k dk {ks=kQy
D;k gksxk ?
Eall
Ladder
135
(A)
2
4
(B) 2
(C) 42
(D) 22
y = x
Eall
(v, u)
Sol.
m(,)
135
x
(h, 0)
(h u)2 + u2 = 2
2 = h + u
v
=
k = 2
2
and h = 2 + 2
putting the value of h and k
2
2
2
(h u) + u =
2
2
(2 + 4) + 4 = 2
2
or (x + 2y)2 + y2 =
4
2
or x2 + 5y2 + 4xy =
4
2
or x2 + 5y2 + 4xy =
equation of ellipse
4
area = ab
2
=
4
option (A) is correction
PAGE - 29
85.

Let AB be a sector of a circle with centre O and radius d, AOB = , and D be a point on OA
2
such that BD is perpendicular OA. Let E be the midpoint of BD and F be a point on the are AB such that
EF is parallel to OA. The the ratio of length of the are AF to the length of the are AB is
eku yhft, fd O dsUnz ,oa d f=kT;k okys ,d o`k dk f=kT;k[k.M (sector) AB gS] AOB = , ,oa OA ij
2
D ,d ,slk fcUnq gS ftlls OA, BD ds yacor gks tkrh gS eku yhft, fd fcUnq E, BD dk e/; fcUnq gS vkSj F, AB
ij ,d ,slk fcUnq gS tks EF ,oa OA dks lekUrj cukrk gS pki AF ,oa pki AB ds yEckb;ksa dk vuqikr D;k gksxk ?
1
sin 1 sin
1
1
2
(A)
(B)
(C) sin
(D)
2
2
2
B
E
Sol.
GA
In OBD
BD
sin =
d
BD = d sin
d sin
ED =
= FG
2
In OFG
Let GOF =
FG
dsin
sin =
=
OF
2d
sin
sin =
2
or
sin
a = sin1
sin
sin1
AF
=
=
AB
Hence option (D) is correct
86.
Sol.
Let f(x) be a non-negative differentiable function no [0, ) such that f(0) = 0 and f'(x) 2f(x) for all x > 0.
Then, on [0, )
(A) f(x) is always a constant function
(B) f(x) is strictly increasing
(C) f(x) is strictly decreasing
(D) f'(x) changes sign
eku yhft, fd f(x) tks fd [0, ) ij ,d v_.kkRed vodyuh; Qyu bl izdkj gS fd f(0) = 0 vkSj lHkh x > 0
ds fy, f'(x) 2f(x), rks [0, ) esa
(A) f(x) ges'kk fLFkj Qyu gS
(B) f(x) dsoy c<+rk gS
(C) f(x) dsoy ?kVrk gS
(D) f'(x) fpUg (sign) cnyrk gS
As f(0) = 0
and f'(x) 2f(x)
as x = 0 + h,
f'(h) 2f(h)
f'(h) 0
But f'(h) cannot be () ive as f(x) is a (+)ive function
f'(h) = 0
Hence f(x) must be a const function
Hence option (A) is ocrrect
PAGE - 30
87.
For each positive real number , let A be the set of all natural numbers n such that |sin ( n 1 ) sin
( n )| < . Let A c be the complement of Ain the set of all natural numbers. Then
(A) A 1 , A 1 , A 2 are all finite sets
(B) A 1 is a finite set but A 1 , A 2 are infinite sets
5
C
1
2
C
1
2
(C) A , A , A
C
2
5
are all finite sets
(D) A 1 , A 2 are finite sets and A 1 is an infinite set

5
gj /kukRed okLrfod la[;k ds fy, eku yhft, fd A mu lHkh izkd`frd la[;kvksa n dk leqPp; gS tks
|sin ( n 1 ) sin ( n )| < dks larq"V djrh gS ;fn A c izkd`frd la[;kvksa ds leqPp; esa Adk iwjd gS rks (A) A 1 , A 1 , A 2 lHkh ifjfer (finite) leqPp; gS
2
(B) A 1 ifjfer leqPp; gS fdUrq A 1 , A 2 vifjfer (infinite) leqPp; gS

2
C
1
2
C
1
2
(C) A , A , A
C
2
5
lHkh ifjfer leqPp; gS
(D) A 1 , A 2 ifjfer leqPp; gS vkSj A 1 vifjfer leqPp; gS

5
Sol.
As n
|sin x 1 sin x |
there exists infinite natural number for which
|sin x 1 sin x | < > 0
Hence A 1 , A 1 and A 2 all are
2
infinite sets
2
88.
Let f be a continuous function defined on [0, 1] such that f ( x ) dx = f ( x ) dx . Then the range of f
0
0
(A) has exactly two points

(B) has more than two points
(C) is the interval [0, 1]
(D) is a singleton
eku yhft, fd [0, 1] varjky esa f ,d lrr Qyu bl izdkj gS fd

(range)
(A) esa dsoy nks fcUnq gS
(C) [0, 1] dk varjky gS
rc f dk ijkl
(B) esa nks ls vf/kd fcUnq gS

(D) ,dy gS
2
Sol.
f ( x ) dx = f ( x ) dx
0
0
( f ( x)) dx = f ( x ) dx
0
0
holds for a const function only when f(x) = u,
2
L.H.S. = ( f ( x ))2 dx = u
0
2
R.H.S = f ( x ) dx = u
f(x) contains only one element in its range

hence option (D) is corrects
PAGE - 31
89.
Sol.
Three schools send 2, 4 and 6 students, respectively, to a summer camp. The 12 students must be
accommodated in 6 rooms numbered 1, 2, 3, 4, 5, 6 in such a way that each room has exactly 2
students and both from the same school. The number of ways, the students can be accommodated in
the rooms is
rhu Ldwy e'k% 2, 4 ,oa 6 fo|kfFkZ;ksa dks xzh"e f'kfoj (summer camp) esa Hkstrs gS bu 12 fo|kfFkZ;ksa dks 6 dejks
ftudk ukedj.k 1, 2, 3, 4, 5, 6 gS] esa bl rjg ls Bgjkuk gS fd izR;sd dejs esa mlh Ldwy ds dsoy nks fo|kFkhZ
fuokl djsa dqy fdrus izdkj ls fo|kfFkZ;ksa dks dejksa esa Bgjk;k tk ldrk gS ?
(A) 60
(B) 45
(C) 32400
(D) 2700
School - 2 student
School 4 students
School III 6 students
First form 6 groups of 2 member each
6!
2! 4!

2
!
2
!
2
!
2
!
2
!
2
!
3
!
2
!

= 1 3 15 = 45 ways
now total number of ways to arrange = 45 6! = 45 720 = 32400
90.
Sol.
za
Let a be a fixed nonzero complex number with |a| < 1 and w =
. Where z is a complex number.
1 az
Then
(A) There exists a complex number z with |z| < 1 such that |w| > 1
(B) |w| > 1 for all z such that |z| < 1
(C) |w| < 1 for all z such that |z| < 1
(D) There exists z such that |z| < 1 and |w| = 1
eku yhft, fd a ,d fuf'pr v'kwU; lfEeJ la[;k (complex number) bl izdkj gS fd |a| < 1 vkSj
za
w=
tgk z ,d lfEeJ la[;k gS] rks 1 az
(A) |z| < 1 esa lfEeJ la[;k z bl izdkj laHko gS fd |w| > 1
(B) |z| < 1, esa lHkh z ds fy, |w| < 1 gSA
(C) |z| < 1, esa lHkh z ds fy, |w| < 1 gSA
(D) z dk ,slk eku laHko gS tks |z| < 1 vkSj |w| = 1 dks larq"V djs
za
w=
1 aZ
arg(z) = + arg ( a z) = +
arg(a) =
=
|za|
|w| =
| 1 az |
| z |2 | a |2 2 | z || a | cos
1 | a |2 | z |2 2 | a || z | cos
2
|z| + |a| 1 |a| |z|

= |z|2(1 |c|2) (1 |c|2)
f |a| < 1 and |z| > 1
2
2
2
2
|z| + |a| 1 |a| |z| < 0
2
2
2
2
or |z| + |c| < 1 + |c| |z|
or |z|2 + |a|2 2|z| |a| cos < 1 + |c|2 |z|2 2|c||z|cos
|w| < 1 |z| < 1
PAGE - 32
PHYSICS
91.
A light balloon filled with helium of density He is tied to a long light string of length l and the string is
attached to the ground. If the balloon is displaced slightly in the horizontal direction from the equilibrium
and released then :
(A) The ballon undergoes simple harmonic motion with period 2
air
air He
(B) The ballon undergoes simple harmonic motion with period 2
air He
air
(C) The ballon undergoes simple harmonic motion with period 2
He
air He
(D) The ballon undergoes conical oscillations with period 2
air He
air He
,d gYds xqCckjs He ?kuRo dh ghfy;e xSl Hkjh gqbZ gS] bl xqCckjs dks tehu ij ca/ks gq, l yEckbZ ds gYds /kkxs ls
tksM+k tkrk gS] ;fn xqCCkkjs dks {kSfrt fn'kk esa mlds lkE;koLFkk ls foLFkkfir djds NksM+k tk;s rks
(A) xqCckjk 2
air
l
air He g
vko`fk ls ljy vkorZ xfr djrk gSA
(B) xqCckjk 2
air He l
air
g
(C) xqCckjk 2
He l
air He g
(D) xqCckjk 2
air He l
air He g
Sol.
B mg air
He
mg air 1
He
(....)cos
mg
(....)sin
Net restoring force
Fnet mg air 1 sin
He
x
Fnet mg air 1 where =
He
x
Fnet mg air 1
which is comparable
He

with F = kx
So T 2
m
m
2
k
mg air
1
He
T 2
He
air He g
PAGE - 33
92.
Consider a cube of uniform charge density . The ratio of electrostatic potential at the centre of the
cube to that at one of the corners of the cube is.
,d le:i vkos'k ?kuRo okys ?ku gS esa dsUnz ij yxus okys fo|qr foHko rFkk ?ku ds ,d dksus esa yxus okys
fo|qr foHko dk vuqikr D;k gksxk \
Sol.
(A) 2
(B) 3 / 2
(C) 2
(D) 1
Assume that potential due to uniform solid cube of side a at centre is V1 and at the corner is V2. Lets
divide the cube into 8 equal cubical pieces. For every cubical piece, the central point (C) will act like a
corner point.
V2
C
V1
Potential at the corner

kq
V2 some number
a
Since side of the small piece is that of complete cube and charge of the small piece is
1
that of
8
complete cube
So potential of the small piece will be 1/4th that of complete cube
pot. at the centre due to all 8 pieces
v
= 8 2 v 1
4
=
93.
V1
2
V2
Two infinitely long wires each carrying current along the same direction are made into the geometry as
shown in the figure. The magnetic field at the point P is.
nks vuar yEckbZ ds lqpkyd rkjksa esa ,d gh fn'kk esa /kkjk izokfgr gks jgh gS] bu rkjksa ls fp=k esa n'kkZ;h gqbZ vkfr cukbZ tkrh gSA
pqEcdh; {ks=k dk eku fcUnq P ij D;k gksxk \
I
r
P
I
(A)
0
r
(B)
0 1 1
r 4
(C) zero
(D)
0
2r
PAGE - 34
Sol.
wire(1) i
i
i
wire(2)
i
i
The magnetic field due to quarter circular arcs will be cancelled out. So B at the centre will be only due
to wire (1) and wire (2)
i i
i
Bnet 0 0 0
4r 4r 2r
94.
Sol.
A photon of wavelength is absorbed by an electron confined to a box of length (35h / 8mc . As a

result, the electron makes a transition from state k = 1 tot he state n. Subsequently the electron transits
from the state n to the state m by emitting a photon of wavelength = 1.75. Then
,d (35h / 8mc yEckbZ ds ckWDl esa ifj:) (confined) bysDVkWu ,d rjaxnS/;Z ds QksVksu dks vo'kksf"kr djrk gSA ;gk lHkh
ladsrksa ds lkekU; vFkZ gS] blds dkj.k bysDVkWu viuh voLFkk k = 1 ls n voLFkk esa lae.k djrk gSA rRi'pkr~ bysDVkWu voLFkk n ls
voLFkk m esa lafer gksrk gS vkSj bl izf;k esa = 1.75 rjaxnS/;Z dk QksVksu mRlftZr djrk gS] rc
(A) n = 4; m = 2
(B) n = 5; m = 3
(C) n = 6; m = 4
(D) n = 3; m = 1
If De-Broglie wavelength of electrons is , then according to quantum mechanics,
length of the box = n (loop length)
2L
h
L=n =
=
2
n
p

nh
p2
pnE=
n2
2L
2m
so energy of electron confined in the box will be E n2
To send the electron from n = 1 to n = n
hc
Erequired n2 (1)2 =
.
.........(1)
When the electron falls from n = n to n = m

hc
4hc
Ereleased n2 m2 =
=
.........(2)
1.75
7
Dividing equation (1) and equation (2)
4
n2 m2
=
2
7
n 1
the options which satisfy this relation is n = 6 and m = 4
P=
PAGE - 35
95.
Consider two masses with m1 > m2 connected by a light inextensible string that passes over a pulley of
radius R and moment of inertia about its axis of rotation. The string does not slip on the pulley and the
pulley turns without friction. The two masses are released from rest separated by a vertical distance 2h.
When the two masses pass each other, the speed of the masses is proportional to.
m1 vkSj m2 nzO;eku ds nks fiaMks (m1 > m2) dks vrU; gYdh Mksjh ls tksM+k tkrk gSA ;g Mksjh ,d iqyh (pulley)] ftldh f=kT;k R
rFkk mlds ?kw.kZu v{k ds lkis{k tM+Ro vk?kw.kZ gS] ds ij ls xqtjrh gS] Mksjh iqyh ij fQlyrh ugha gS vkSj iqyh fcuk ?k"kZ.k ds ?kwerh gS]
bu fiaMks dks foJkekoLFkk ls ,d nwljs ls /okZ/kj pkbZ 2h ls NksM+k tkrk gSA tc nksuksa fiaM ,d nwljs ds ikl ls xqtjrs gS rks mudh
xfr fuEu esa ls fdlds lekuqikrh gksxh \
m1 m2
(A)
(B)
m1 m2 2
R
(m1 m2 )(m1 m2 )
(C)
m1 m2 2
R
m1 m2
R2
m1 m2
(D)
R2
m1 m2
Sol.
T1
T2
m1
2h
a
m2
m1g T1 = (m1)(a)
T2 m2g = (mr) (a)
(T1 T2) R = I
a
where =
R
Solving we will get
m1 m2 g
a=
I
m1 m 2 2
R
To find the velocity when the blocks cross each other

2
2
Vrel
a rel
2arel Srel
2
(2v) = 0 +2 (2a) (2h)
m1 m2 g
V = 2ah = 2ah 2h
I
m1 m2 2
R
So V
m1 m2
m1 m2 2
R
So Ans. should be (A) rather than (C)
PAGE - 36
96.
An ideal gas is reversibly around the cycle a-b-c-d-a as shown on the T (temperature)
S (entropy) diagram
,d vkn'kZ xSl dks mRe.kh; p a b c d a ds vuqlkj ys tk;k tkrk gS] bl izf;k dks fp=k esa T (rki)
S (,UVkih) vkjs[k ij fn[kk;k x;k gSA
T
The most appropriate representation of above cycle on a U (internal energy) V (volume) diagram is.
mijks ph; izf;k dk lcls mi;q U (vkrafjd tkZ) V (vk;ru) vkjs[k fuEu esa ls dkSu lk gS \
U
U
(A)
(B)
d
a
a
V
(C)
(D)
a
V
Sol.
T
T
b
isothermal
c
T=constant
c
adiabatic
a
1
V2 / f
1
V2/ f
d
PAGE - 37
97.
Sol.
The heat capacity of one mole an mole an ideal is found to be CV = 3R(1 + RT)/2 where a is a
constant. The equation obeyed by this gas during a reversible adiabatic expansion is.
(A) TV3/2eaRT = constant
(B) TV3/2e3aRT/2 = constant
3/2
(C) TV = constant
(D) TV3/2e2aRT/3 = constant
,d eksy vkn'kZ xSl dh "ek /kkfjrk] CV = 3R(1 + RT)/2 gS] ;gk a ,d fLFkjkad gS] ;g xSl mRe.kh; :)ks"e izlkj ds nkSjku
fuEUk esa ls fdl lehdj.k dk ikyu djrh gSA
3/2 aRT
3/2 3aRT/2
(A) TV e = fLFkjkad
(B) TV e
= fLFkjkad
(C) TV3/2 = fLFkjkad
(D) TV3/2e2aRT/3 = fLFkjkad
dQ = dw + du
3R
0 = Pdv + n CVdT, here C V
1 aRT
2
3R
Pdv = n
1 aRT dT , where P = nRT
2
V
3R
nRT
(1+aRT)dT
dV n
2
V
dV
3 dT
aRdT
V
2 T
3
3
n V + nT aRT cons tan t
2
2
VT 3 / 2 e 3 / 2aRT = constant
so no answer is correct
98.
If the input voltage Vi to the circuit below is given by Vi(t) = Acos(2ft), the output voltage is given by
V0(t) = Bcos(2ft + )
uhps n'kkZ, x, fo|qr ifjiFk dk fuso'k foHko] Vi(t) = Acos(2ft) rFkk fuxZe foHko V0(t) = Bcos(2ft + ) }kjk
fn;k tkrk gSA

C
Vi(t) ~
V0(t)
Which one of the following four graphs best depict the variation of vs f ?
fuEu esa ls dkSu lk vkjs[k dk f ds lkFk lcls mi;q ifjorZu fn[kkrk gS ?
(A)
(B)
(C)
(D)
f
PAGE - 38
i
C
Sol.
i
C
Vi = V0 cos(t)
The resistance of capacitor in complex number is.
i
1
Xc =
C iC
The resultant of R and C which are in parallel
1
1
1
R

z1
z1 R 1/ iC
1 i(RC)
The resultant impedance of the entire circuit.
R
i
zeq = R
+ 1 i(RC)
C
3RC i[(RC)2 1]
C iR(C)2
solving zeq =
(i) for 0
zeq i
so Arg(zeq) = 90
V
=
so Arg() = +90
zeq
Voltage across R (v out) = z, for 0
vout = R Arg (vout) = +90
z1 R
(ii) For , Arg (z) 0

So Arg() 0
R
for
z1 =
1 i(CR)
Arg (z1) = Arg(R) Arg (1 + i(CR))
Arg (z1) = 0 90 = 90
so v out = z1 Arg (vout) = Arg() + Arg (z1)
Arg (vout) = 0 + (90) = 90
Hence the graph should be
+90
90
PAGE - 39
99.
A glass prism has a right-triangular cross section ABC, with A = 90. A ray of light parallel to the
hypotenuse BC and incident on the side AB emerges grazing the side AC. Another ray, again parallel to
the hypotenuse BC, incident on the side AC suffers total internal reflection at the side AB. Which one of
the following must be true about the refractive index of the material of the prism ?
,d dkap ds fizTe dk vuqizLFk dkV ABC ledks.k f=kHkqt gS ftlesa fd A = 90] d.kZ BC ds lekukUrj ,d izdk'k fdj.k Hkqtk AB
ij vkifrr gksrh gS vkSj Hkqtk AC ls i`"BLIk'khZ gksrh gqbZ fudy tkrh gS] ,d nwljh izdk'k fdj.k tks fd d.k BC ds lekuUrj gS] Hkqtk
AC ij vkifrr gksdj Hkqtk AB ls iw.kZr% vkarfjd ijkofrZr gksrh gSA fizTe ds viorZukad ds ckjs esa fuEu esa ls D;k lR; gS \
(A)
Sol.
3
2
2
(B) 3
(C)
3
2
(D)
2 3
(i)
(1) sin = sin (90 ic)
sin = cos i
B
90
90ic
ic
1
sin = 1
sin =
=
2 1
1 sin2 , 1 sin 2
1 and
min
(ii)
so from Ist observation , 1 2

(1) sin(90 ) = sinr
cos = sin r
here sin =
2 1 so cos =
90
1 sin2
max
2 2
90r
r
C
A
90
2 2 =sinr sinr =
2 2
For TIR at the surface AB

90r > ic sin (90 r) > sinrc
1
2 2 2
1
3
>
2
2
Taking the common solution from observation (i)and observation (ii)
3
2
2
cosr >
PAGE - 40
100.
A smaller with side b (depicted by dashed lines) is excised from a bigger uniform cube with side as
shown below such that both cubes have a common vertex P. Let X = a/b. If the centre of mass of the
remaining solid is at the vertex O of smaller cube then X satisfies.
Hkqtk a okys ,d cM+s ?ku ls Hkqtk b dk ,d NksVk ?ku bl izdkj dkVk tkrk gS fd nksuksa ?kuksa dk ,d mHk;fu"B 'kh"kZ P gS] eku yhft;s fd
X = a/b ;fn cps gq, Bksl dk nzO;eku dsUnz O ij gks rks X fuEUk esa ls fdl lehdj.k dks larq"B djrk gS \
P
b
O
Sol.
(A) x3 x2 X 1 = 0
(B) x2 x 1 = 0
3
2
3
2
(C) x X X 1 = 0
(D) X X X + 1 = 0
Assume vertex P as origin. All the three coordinates are symmetrical, so we can deal only with xcoordinate
m x m2 x 2
xcm = 1 1
m1 m2
a
b
(a3 ) (b3 )
4
4
2
2 2b = a b
b=
3
3
3
3
a b
a b
2b =
a ba b a 2 b 2 a b a 2 b 2
a ba 2 ab b 2 a 2 ab b 2
a3 a2b ab2 b3 = 0, dividing by b3

3
a
a
a
1 0
b
b

b
3
2
x x x 1=0
CHEMISTRY
101.
X, Y and Z in the following reaction sequence are
fn, x, vfHkf;k Js.kh
O2
H
Y+Z
H2O
esa X, Y ,oa Z e'k% gS \
Sol.
(A) X =
OOH
Y=
(B) X =
OOH
Y=
(C) X =
OH
Y=
(D) X =
OOH
Y=
OH
Z=
OH
Z=
OOH
Z=
OH
Z=
Given reaction illustrate the formation of phenol from cumene.
nh xbZ vfHkf;k D;wfeu ls fQukWy ds fuekZ.k dks Li"V djrh gSA

OOH
O2
H2O
OH
PAGE - 41
102.
The reagents required for the following two-step transformation are

CN
(A) (i) HBr, benzoyl peroxide ; (ii) CH3CN

(B) (i) HBr ; (ii) NaCN
(C) (i) Br2 ; (ii) NaCN
(D) (i) NaBr ; (ii) NaCN
fuEufyf[kr f}pj.k :ikUrj.k (two-step transformation)
CN
ds fy, vko';d vfHkdeZd gSa&

(A) (i) HBr, csatks;y ijkDlkbM; (ii) CH3CN
(B) (i) HBr ; (ii) NaCN

(D) (i) NaBr ; (ii) NaCN
CN
(C) (i) Br2 ; (ii) NaCN

Br
HBr
Sol.
103.
NaCN
In the reaction sequence

CHO
1. conc.KOH
H
2.H3O
CHO
the major products X and Y, respectively, are
CH2OH
(A)
CH2OH
O
and
CO2H
(B)
and
CO2H
CH2OH
(C)
CHO
O
and
(D)
CO2H
and
CH2OH
fn, x, vfHkf;k Js.kh esa

CHO
1. conc.KOH
H
eq[;
2.H3O
CHO
mRikn X ,oa Y, e'k%
gSa&
CH2OH
(A)
rFkk
CO2H
(B)
Sol.
CHO
O
rFkk
(D)
CO2H
rFkk
CO2H
CH2OH
(C)
CH2OH
rFkk
CH2OH
It is example of intramolecular cannizaro reaction followed by esterification.
;g vUr%v.kqd dsfutkjks vfHkf;k blds i'pkr~ ,LVjhdj.k dk mnkgj.k gSA

CHO
CHO
CH2OH
1. conc.KOH
2.H3O
CO2H
PAGE - 42
104.
In the following reactions

O
+
phosphoric
acid
anhyd. AlCl
3
Y
O
X
O
X and Y, respectively, are
O
CO2H and
(A)
(B)
and
O
O
CO2H and
CO2H
(C)
OH
(D)
and
uhps nh x;h vfHkf;kvksa esa

O
futZy AlCl3
QkWLQksfjd vEy
O
Y
X
X ,oa Y e'k% fuEu gSa&

O
O
CO2H
(A)
(B)
rFkk
rFkk
O
O
CO2H
CO2H
(C)
rFkk
O
O
phosphoric
acid
CO2H
anhyd. AlCl
3
O
QkWLQksfjd vEy
CO2H
futZy AlCl3
O
105.
Sol.
O
O
(D)
rFkk
Sol.
OH
Copper (atomic mass = 63.5) crystallizes in FCC lattice and has density 8.93 g.cm3.
The radius of copper atom is closest to
dkWij (ijek.kq nzO;eku = 63.5) Qyd dsfUnzr ?kuh; (FCC) tkyd esa fLVyhd`r gksrk gS] ftldk ?kuRo
8.93 g.cm3 gS] dkWij ijek.kq dh f=kT;k yxHkx gS&
(A) 361.6 pm
(B) 511.4 pm
(C) 127.8 pm
(D) 102.8 pm
Z M
d=
2a 4R
NA a3
8.93 =
4 63.5
6.023 1023 (2 2R)3

R = 127.8 pm.
a = 2 2R
PAGE - 43
106.
Given the standard potentials E(Cu2+/Cu) and E(Cu2+/Cu) as 0.340 V and 0.522 V respectively, the
value of E(Cu2+/Cu+) is
2+
2+
2+
+
E(Cu /Cu) ,oa E(Cu /Cu) ds ekud foHko e'k% 0.340 V ,oa 0.522 V fn;k x;k gS] rc E(Cu /Cu ) dk
eku gksxk&
(A) 0.364 V
(B) 0.158 V
(C) 0.182 V
E
G
E1 = 0.340
G1
E2 = 0.522
Sol.
+2
Cu + 2e Cu
Cu + 2e Cu+1 + e
_________________________
Cu+2 + e Cu+1
(D) 0.316 V
G03
E3 ?
G3 = G1 + G2
FE3 = 2 F 0.340 + F 0.522
E3 = 0.158 V
107.
Sol.
For electroplating, 1.5 amp current is passed for 250 s through 250 mL of 0.15 M solution of MSO4.
Only 85% of the current was utilized for electrolysis. The molarity of MSO4 solution after electrolysis is
closest to
[Assume that the volume of the solution remained constant]
fo|qrysiu ds fy, MSO4 ds 250 mL 0.15 M ?kksy ls 1.5 amp dh /kkjk 250 s rd izokfgr dh tkrh gSA /kkjk dk
ek=k 85% fo|qr vi?kVu ds fy, mi;ksx fd;k tkrk gSA fo|qr vi?kVu ds i'pkr~ MSO4 ?kksy dh eksyjrk yxHkx
gS (?kksy dk vk;ru fu;r eku yhft;s)
(A) 0.14
(B) 0.014
(C) 0.07
(D) 0.035
Charge supplied
izokfgr vkos'k
Q = it
= 1.5 250
Net charge supplied
izokfgr dqy vkos'k

85
1
= 1.5 250
F
100 96500
= 3.3 103
M+2 + 2e M
+2
2F charge consumers = 1 mol M
+2
2F vkos'k miHkksx djrs gS = 1 mol M
1
3
3
3.3 10 F charge consumers = 3.3 10
2
1
3
3
3.3 10 F vkos'k miHkksx djrs gS = 3.3 10
2
3
+2
= 1.65 10 mol M
After electrolys molarity
oS|qrvi?kVu ds i'pkr eksyjrk

1.5 250
1000
=
1.65 10 3
= 0.14
1000
250
108.
The hybridisation of the central atom and the shape of [IO2F5]2 ion, respectively, are
dsUnzh; ijek.kq dk izladj.k ,oa [IO2F5]2 vk;u dh vkd`fr e'k% gS&
3 3
2 4
2 4
sp d
3 3
sp d
sp d
sp d
2
O
F
(A)
I
F
(B)
I
F
O
F
(C) O
(D)
FF
F
O
PAGE - 44
sp3d3
2
O
F
Sol.
F
here oxygen occupy the axial position. ;gk vkWDlhtu v{kh; fLFkfr dks ?ksjrh gSA
F
F
O
109.
Sol.
Sol.
110.
Sol.
2.33 g of compound X (empirical formula CoH12N4Cl3) upon treatment with excess AgNO3 solution
produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X,
respectively, are
[Given : Atomic mass : Co = 59, Cl = 35.5, Ag = 108]
;kSfxd X (ewykuqikrh lw=k CoH12N4Cl3) dk 2.33 g AgNO3 ?kksy ds vkf/kD; ls vfHkf;k dj 1.435 g 'osr vo{ksi
mRiUu djrk gSA ;kSfxd X esa dksckYV dh izkFkfed ,oa f}rh; la;kstdrk e'k% gS
[fn;k x;k gS] ijek.kq nzO;eku : Co = 59, Cl = 35.5, Ag = 108]
(A) 3, 6
(B) 3, 4
(C) 2, 4
(D) 4, 3
1.435
nAgCl =
= 0.01
143.5
[Co(NH3)4Cl2]Cl [Co(NH3)4Cl2]+1 + Cl
Primary valency = oxidation state of central atom = 3
Secondary valency = Co-ordination number = 6.
1.435
nAgCl =
= 0.01
143.5
[Co(NH3)4Cl2]Cl [Co(NH3)4Cl2]+1 + Cl
izkFkfed la;kstdrk = dsUnzh; ijek.kq dh vkWDlhdj.k voLFkk = 3
f}rh;d la;kstdrk = leUo; la[;k = 6.
The specific conductance () of 0.02 M aqueous acetic acid solution at 298 K is 1.65 104 S cm1. The
degree of dissociation of acetic acid is
[Given : equivalent conductance at infinite dilutuion of H+ = 349.1 cm2 mol1 and CH3COO = 40.9 S
cm2 mol1]
298 K ij ,flfVd vEy ds 0.02 M tyh; ?kksy dh fof'k"V pkydrk ()1.65 104 S cm1 gSA ,flfVd vEy dh
fo;kstu ek=kk gksxh& fn;k x;k gS] vuUr ruqrk ij rqY;kadh pkydRo % H+ = 349.1 cm2 mol1 rFkk CH3COO
= 40.9 S cm2 mol1]
(A) 0.021
(B) 0. 21
(C) 0.012
(D) 0.12
M , M = 349.1 + 40.9 = 390

M
=
M
1000K 1000 1.65 10 4
1
=
=
= 0.021
0.02
390
M
M M
PAGE - 45
BIOLOGY
111.
Match the following organelles in Group I with the structures in Group II. Choose the correct
combination.
P.
Q.
R.
S.
Group I
Mitochondrion
Golgi
Chloroplast
Centrosome
i.
ii.
iii.
iv.
Group II
Cisternae
Cristae
Thylakoids
Radial spokes
lewg I esa dksf'kdkvksa ds mnkgj.k vkSj lewg II esa dksf'kdk lajpk;sa crkbZ x;h gSa] mudk fo'ys"k.k djrs gq, lgh
la;kstu combination dk p;u dfj;sGroup I
P.
Q.
R.
S.
Ans.
112.
Ans.
113.
Group II
i.
ii.
iii.
iv.
Lwk=kdf.kdk
xkWYthdk;
gfjr yod
Rkkjddk;
(A) P-ii, Q-i, R-iii, S-iv

(C) P-iv, Q-i, R-ii, S-iii
(A)
flLVuhZ
fLVs
FkkbZysDok;M
jsfM;y LiksDl
(B) P-iii, Q-i, R-ii, S-iv

(D) P-iv, Q-ii, R-i, S-iii
A human population containing 200 individuals has two alleles at the 'T' locus, named T & t. T, which
produces tall individuals, is dominant over t, which produces short individuals. If the population has 90
TT, 40 Tt and 70 tt genotypes, what will be the frequencies of these two alleles in this population?
,d 200 O;fDr;ksa okyh ekuo vkcknh esa fdlh 'T' xq.klw=k fcanq (locus) ds nks vyhy T & t gS] T yacs O;fDr;ksa dks
mRiUu djrk gS tks fd NksVs O;fDr;ksa dk mRiUu djus okys t ij izHkkoh gS- ;fn vkcknh esa 90 TT, 40 Tt vkSj 70 tt
thu izk:i (genotypes) gSa] rks blh vkcknh esa bu nks vyhyksa dh vko`fk;k fdruh gksxh\
(A) T, 0.50 : t, 0.50
(B) T, 0.55, t, 0.45
(C) T, 0.45 : t, 0.35
(D) T, 0.90 : t, 0.10
(B)
Which of the following graphs best describes the oxygen dissociation curve where pO2 is the partial
pressure of oxygen ?
;fn pO2 vkWDlhtu ds vkaf'kd nkc dks fu:fir djrk gS rks fuEufyf[kr esa ls dkSulk js[kkfp=k vkWDlhtu ds fo?kVu
o dks lcls lVhd rjhds ls n'kkZrk gS\
Ans.
(A)
(B)
(C)
(D)
(D)
PAGE - 46
114.
Ans.
115.
Which of the following best describes the DNA content and the number of chromosomes at the end of S
and M phases of the cell cycle in mitosis, if the DNA content of the cell in the beginning of cell cycle (G1
phase) is considered as C and the number of chromosomes 2N?
(A) 2C and 2N for S phase ; 2C and 2N for M phase
(B) 2C and N for S phase ; 2C and N for M phase
(C) 2C and 2N for S phase ; C and 2N for M phase
(D) C and N for S phase ; C and 2N for M phase
;fn dksf'kdk p dh 'kq:vkr G1 voLFkk esa DNA dh ek=kk 'C' vkSj xq.klw=kksa dh la[;k '2N' Fkh] rks lelw=kh foHkktu
dh S-voLFkk vkSj M-voLFkk ds i'pkr~ budh lgh n'kk dh O;k[;k fuEu esa ls dkSulk fodYi djrk gS\
(A) S-voLFkk esa 2C vkSj 2N ; M-voLFkk esa 2C vkSj 2N
(B) S-voLFkk esa 2C vkSj N ; M-voLFkk esa 2C vkSj N
(C) S-voLFkk esa 2C vkSj 2N ; M-voLFkk esa C vkSj 2N
(D) S-voLFkk esa C vkSj N ; M-voLFkk esa C vkSj 2N
(C)
Study the following graph of metabolic rate of various terrestrial mammals as a function of their body
mass and choose the correct option below.
fn, x, vkjs[k esa fofHkUu Fkyh; Lru/kkfj;ksa ds mikip;h nj vkSj muds 'kkjhfjd Hkkj ds laca/k dks n'kkZ;k x;k gSbldk v/;;u dj fuEu esa ls lgh fodYi dk pquko dfj;s-
(A) Animals are distributed throughout the curve with the smaller animals towards the left and
progressively bigger animals towards the right.
(B) The smallar animals below a certain critical mass cluster at the left end of the curve and the larger
animals above the critical mass cluster on the right end.
(C) Animals are distributed throughout the curve with the larger animals towards the left and
progressively smaller animals towards the right.
(D) The larger animals above a certain critical mass cluster at the left end of the curve and the smaller
animals below the critical mass cluster on the right end.
(A) izk.kh] o esa lHkh txg ekStwn gSa] tgk NksVs izk.kh ck;ha rjQ gSa] ogha cM+s izk.kh fujarj nk;ha rjQ dh vksj c<+
jgs gSa(B) ,d kafrd Hkkj ls de Hkkj okys NksVs izk.kh ,d xqPNs esa o ds ck;ha rjQ vkSj bl kafrd Hkkj ls T;knk Hkkj
okys cM+s izk.kh o ds nk;ha rjQ gSa(C) izk.kh] o esa lHkh txg ekStwn gSa- tgk cM+s izk.kh ck;ha rjQ gSa] ogha NksVs izk.kh fujarj nk;ha rjQ dh vksj c<+
jgs gSa(D) ,d kafrd Hkkj ls T;knk Hkkj okys cM+s izk.kh ,d xqPNs esa o ds ck;ha rjQ vkSj bl kafrd Hkkj ls de Hkkj
okys NksVs izk.kh o ds nk;ha rjQ gSaAns.
(A)
PAGE - 47
116.
Match the human disorders shown in Group I with the biochemical processes in Group II. Choose the
correct the combination.
Group I
Group II
P.
i.
Phenylketonuria
Melanin synthesis
Q.
ii.
Albinism
Conversion
of
Phe
nylalanine to Tyrosine
R.
iii.
Homocystinuria
Tyrosine degradation
S.
iv.
Argininemia
Methionine metabolism
v.
Urea synthesis
lewg I esa ekuo fofr;ksa ds mnkgj.k gSa vkSj lewg II esa tSo jlk;u izf;k;sa gSa- mudk fo'ys"k.k djrs gq, lgh
la;kstu combination dk p;u dfj;slewg I
lewg II
P.
i.
fQukby dhVksuwfj;k
feySfuu la'ys"k.k
Q.
ii.
jatdghurk
fQukby ,ykuhu dk VkbZjkslhu
esa ifjorZu
R.
iii.
gkseksflLVhuwfj;k
VkbZjkslhu fo?kVu
S.
iv.
vkthZfuuhfe;k
esfFkvksuhu mikip;
v.
;wfj;k la'ys"k.k
Ans.
117.
Ans.
118.
Ans.
(A) P-ii, Q-i, R-iv, S-v

(C) P-ii, Q-i, R-v, S-iii
(A)
(B) P-i, Q-iv, R-ii, S-v

(D) P-v, Q-iii, R-i, S-ii
An mRNA is transcribed from a DNA segment having the base sequence 3'-TACATGGGTCCG-5'.
What will be the correct order of binding of the four amino acyl-tRNA complexes given below translation
of this mRNA?
DNA ds ,d [k.M ftldk {kkj vuqe 3'-TACATGGGTCCG-5' gS] ls ,d nwr okgd RNA dk izfrys[ku
(transcription) gks jgk gS] vuqoknu (translation) dh izfrf;k ds nkSjku] uhps fn[kk;s x;s pkj vehuks&,lkby
tRNA ladqyksa ds ca/ku dk lgh e dkSulk gS\
(A) a,b,c,d
(D)
(B) b,a,c,d
(C) c,d,a,b
(D) b,a,d,c
If the initial number of template DNA molecules in a PCR reaction is 1000, the number of product DNA
molecules at the end of 20 cycles will be closest to
;fn fdlh ikyhesjst J`a[kyk vfHkf;k (PCR) dh 'kq:vkr] DNA ds 1000 v.kqvksa ls dh x;h rks 20 pksa (cycle) ds
i'pkr~ mRikfnr DNA v.kqvksa dh la[;k dk fudVre eku fdruk gksxk\
(A) 103
(B) 106
(C) 109
(D) 1012
(C)
PAGE - 48
119.
The allele for black hair (B) is dominant over brown hair (b) and the allele for brown eye (E) is dominant
over blue eye (e). Out of the offsprings obtained upon mating a black-haired and brown-eyed individual
(BbEe) with a brown-haired and brown-eyed individual (bbEE), the ration of brown-haired and browneyed individuals to black-haired and brown-eyed individuals is
tgk] ckyksa ds dkys jax dk vyhy (B) ckyksa ds Hkwjs jax ds vyhy (b) ij izHkkoh gS ogha vk[kksa ds Hkwjs jax dk vyhy
(E), vk[kksa ds uhys jax ds vyhy (e) ij izHkkoh gS] ;fn ,d dkys ckyksa vkSj Hkwjh vk[kksa (BbEe) okys izk.kh dk
ladj.k Hkwjs ckyksa vkSj Hkwjh vk[kksa (bbEE) okys izk.kh ls djkrs gSa rks izkIr larfr;ksa esa Hkwjs cky vkSj Hkwjh vk[k okyh
larfr;ksa vkSj dkys ckyksa vkSj Hkwjh vk[k okyh larfr;ksa ds chp esa D;k vuqikr gksxk\
Ans.
120.
(A) 2:1
(C)
(B) 3:1
(C) 1:1
(D) 1:2
In an experiment represented in the schematic below, a plant species was grown in different day and
night cycles and its photoperiodic flowering behaviour was noted. This species is a
uhps fn[kk;h x;h :ijs[kk esa ,d iz;ksx n'kkZ;k x;k gS] tgk ,d ikni iztkfr ds fofHkUu fnu&jkr ds p dk
iznhfIrdkfyrk ls izHkkfor iq"iu ds izHkko dks ekik x;k gSa] bl vk/kkj ij bl ikni iztkfr ds ckjs esa dkSulk dFku
lR; gS\
Ans.
(A) short day plant and actually measures day length to flower
(B) short day plant and actually measures night length to flowers
(C) long day plant and actually measures night length to flower
(D) long day plant and actually measures day length to flower
(A) ;g iztkfr] vYi iznhfIrdkyh ikS/kk gS vkSj okLro esa fnu dh vof/k] iq"i ls ekirk gS(B) ;g iztkfr] vYi iznhfIrdkyh ikS/kk gS vkSj okLro esa jkr dh vof/k iq"i ls ekirk gS(C) ;g iztkfr] nh?kZ iznhfIrdkyh ikS/kk gS vkSj okLro esa jkr dh vof/k iq"i ls ekirk gS(D) ;g iztkfr] nh?kZ iznhfIrdkyh ikS/kk gS vkSj okLro esa fnu dh vof/k iq"i ls ekirk gS(B)
PAGE - 49
PAGE - 50

210 KVPY Stage 1 Exam 2016 17 Paper Solution

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KISHORE VAIGYANIK PROTSAHAN YOJANA

Max. Marks : 160.

Resonance Eduventures Ltd.

PART-I : (One Marks Questions)

(B) A1 is a finite set and A 1 , A0.3 are infinite sets

(C) A1, A 1 , A0.3 are all finite sets

(D) A1, A0.3 are finite sets and A 1 is an infinite set

(B) A1 ,d ifjfer leqPp; gS vkSj A 1 , A0.3 vifjfer leqPp; gS

(C) A1, A 1 , A0.3 lHkh ifjfer leqPp; gS

(D) A1, A0.3 ifjfer leqPp; gS vkSj A 1 vifjfer leqPp; gS

A 1 = cos n + i sin n; n is in radish

Put = in equation (2)

Hence option (B) is correct

Let X = {x R : cos(sin x) = sin(cos x)}. The number of elements in X is

As the two graphs never intersect each other hence no solution.

= option (C) is correct

The graph of the function f(x) = x +

Which of the following statement are true ?

(II) vuar x [0, 1] laHko gS ;fn limn fn(x) =

(D) I, II, III ,oa IV

The limit limx x2 e t

dt dk eku D;k gksxk ?

The polynomial equation x3 3ax2 + (27a2 + 9)x + 2016 = 0 has

Hence number such function exists

On the real line R, we define two functions f and g as follows :

,d okLrfod js[kk R ij nks Qyu f ,oa g bl izdkj ls ifjHkkf"kr gS :

(a 1)2 + b2 = (a 2)2 + b2 = a2 = a2 + (b 1)2

We can cover the plane using squares definitely

also regular hexagon is made of equilateral triangle only

A nurse measures the blood pressure of a seated patient to be 190 mm of Hg.

Absolute pressure of blood = P0+ o = (1.25) P0

De-Broglie wavelength of the electron is

times fringe width =

times = 0.7 times

The continuous part of X-ray spectrum is a result of the

The production of continuous X-ray is the inverse process of photo-electric effect.

Thermal expansion of a solid is due to the

The De-Broglie wavelength of an electron =

Since photon = electron

(B) 1 kHz dh rhozrk ls 100 xquk

The shape of SCl4 is best described as a

In (A) lobes of P orbital overlap to each other .

ni.kZ izfrfcEc vuv/;kjksfir gksrs gSaA

The pKa of oxoacids of chlorine in water follows the order

Z (no. of atom per unit cell)

Relation b/w edge

Body centre cubic

Face centered cubic

?ksjs x;s vk;ru ij vk/kkfjr ifjdyu (ikB~; iqLrd ns[ksa)

Z (izfr ,dd dksf"Bdk ijek.kq dh la[;k)

dksj yEckbZ (a) rFkk f=kT;k

dk; dsfUnzr ?kuh;

Qyd dsfUnzr ?kuh;

The most stable Lewis acid-base adduct among the following is

Only CHO group is oxidized to acid.

izkIr gksus okyk eq[; mRikn gSA

This reaction is friedel craft alkylation.

;g vfHkf;k fMsy kV ,fYdyhdj.k gksrh gSA

The major product in the following reaction is

esa eq[; mRikn gS

fQuksfyd lewg ij ,flfVyhdj.k dj.k gksrk gSA

The compounds containing sp hybridized carbon atom are

mRiUu djrk gS] izkjfEHkd dkcZfud ;kSfxd gS&

strong oxidising agent