In addition, Fc-containing polymers

have emerged, as an important class of the metal-containing polymers, with unique

electrical, magnetic and optical
properties and thus much considerable attention has been
paid for the application of these polymer systems.

Most
state-of-the-art
composite
solid
propellants
(CSPs)
are
composed
of
a
combination
of
chemical
ingredients, namely, hydroxyl-terminated polybutadiene (HTPB; prepolymer), a diisocyanate
(curative),
plasticizer,
antioxidants,
a
burning-rate
(BR)
modifier,
a catalyst, and an ammonium perchlorate (AP) oxidizer. 17 The cured polymer, in addition to
being
a
fuel,
acted
as
a
binder
for
the
particulate
AP
to
achieve
good
mechanical
properties.
Among
various
types
of
catalysts, transition-metal oxides, ferrocene, and ferrocene derivatives 810 have been widely
used
to
enhance
the BRs of CSPs. A large number of polymeric ferrocene derivatives produced from different
precursor
monomers are also found in the literature 20

The
ferrocene-based
burn-rate
catalysts have more advantages, such as better microscopic distribution, better fluidity, and
better
ignitability
of
the
propellant,
compared
with
other
conventional
burn-rate
catalysts.15
However,
the
migration
of
ferrocene
derivatives
in
the
propellants
which
occurred
upon
curing
and
during
storage
may
lead
to
malfunctioning
of
the
propellant
in
rocket
flights.16,17
The
immobilization
of
ferrocene
moiety
to
the
propellant
binder
by
covalently
linking
is an effective way to avoid this problem 21

OLID propellant is one of the most signi in rockets. The burning rate of propellant is a vital

parameter
for
ficant
rocket
design.
A
promising
method
to
propellants
is
to
use
burning-rate
become
increasingly
important
and
recently
due
to
their
successful
use
enhancement 22

ingredients
used
enhance
the
burning
rate
of
promoters
(BRPs).
BRPs
have
are
receiving
more
attention
in
solid
propellant
burning-rate

Research
activities
to
explore
the
secrets
of
the
have
never
stopped.
In
order
to
overcome
gravity
fly in the sky, people invented fire balloons, planes, rockets and so on 10

universe
and
to

A
propulsion
exploration
is
in
fact
one
of
great
significance
to
the
aerospace
industrial
development.
Basically,
a
propellant
is
the
most
important
ingredients
to
provide
a
driving
force
for rockets to hit the target.

Composite
solid
propellants
are
chemical energy in space vehicles and missiles

the

major

source

of

The
history
of
solid
composite
propellants
can
be
traced
back
to
the
thirteenth
century,
when
human
ancestors
utilized
black
powder
to
increase
the
range
of
arrows.[1]
Modern
propellant
technology
was
developed
after
the
synthesis
and
application
of
nitrocellulose
and
nitroglycerine.
During
the
1910s
to
1950s,
propellant
technology
played
quite
a
significant
role
and
rapidly
developed.
Afterwards,
along
with
other
high
technologies,
solid
propellant
technology
was
applied
not
only
in
the
military
but
also
in
the
civil
field.
In
the
twenty-first
century,
the
development
of
missiles,
aviation
and
spaceflight
required
solid
propellant
technology
to
meet
more
complex standards, which further promoted its development. 7

Exploration
of
Various
methods
in
the
sky
and rockets. 1

secrets
of
the
of
conquering
the
have
been
invented,

universe
force
of
such
as

cannot
gravity
fire

be
and
balloons,

stopped.
to
fly
planes