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4th Edition
Paula Yurkanis Bruice
Chapter 18
Carbonyl
Compounds II
Radicals
Irene Lee
Case Western Reserve
University
Cleveland, OH
Nomenclature of Aldehydes
If the aldehyde group is attached to a ring,
If a compound has two functional groups, the one with the
lowest priority is indicated by its prefix
Nomenclature of Ketones
If a ketone has a second functional group of higher
priority,
An aldehyde has a greater partial positive charge on its
carbonyl carbon than does a ketone
• Steric factors contribute to the reactivity of an aldehyde