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Fall 2016
CHEMISTRY 2A
Section D
EXAM 1
Multiple Choice
(Circle one)
Instructions:
CLOSED BOOK EXAM! No books, notes, or additional scrap paper
are permitted.
Place all work in the space provided. If you require additional space,
use the back of the exam. A scientific calculator may be used (if it is
a programmable calculator, its memory must be cleared before the
exam).
(1) Read each question carefully. Exam has 10 pages total.
(2) For problems 1-14, there is no partial credit given and only
answers marked on this cover page will be graded.
(3) The last page contains a periodic table and some useful
information. You may remove it for easy access.
(4) If you finish early, RECHECK YOUR ANSWERS!
Possible Points
# 1-8
(4 points each)
# 9-14
# 15-16
(16 + 16 = 32)
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Fall 2016
/ 32
/ 36
/ 32
/100
CHEM 2A
2. a
3. a
4. a
5. a
Earned Points
1. a
Section D
6. a
7. a
8. a
9. a
10. a
11. a
12. a
13. a
14. a
EXAM 1
Name
Page 2 of 10
b.
c.
The nucleus of an atom occupies an insignificant portion of the volume of the atom.
d.
e.
3.e
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Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 3 of 10
4.e
5. Consider an organic compound made up of carbon, hydrogen and oxygen. If its molecular
formula is C2HxO, the oxidation number of one of the carbon atoms is -3, and the
oxidation number of the other carbon atom is -1, what is the number of hydrogen atoms in
the molecule C2HxO?
a. 1
b. 3
c. 4
d. 5
e. 6
6.
7.
8.
What are the possible reasons that always for a chemical reaction the actual yield is
lower than the theoretical yield?
a. Equilibrium state is reached and the reaction is not complete.
b. A substance is never 100% pure.
c. During isolation product is lost.
TOUPADAKIS
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 4 of 10
a.
b.
c.
d.
Oxygen, 7 neutrons
Phosphorus, 9 neutrons
Carbon, 4 neutrons
Nitrogen, 8 neutrons
e.
Sulfur, 23 neutrons
10. Suppose that element (E) is found in nature as a mixture of three isotopes, E-25, E-27
and E-29. If the atomic mass of the element (E) is 26.793 amu, calculate the isotopic
mass of E-27 by considering the table below.
Isotope
E-25
24.988
Abundance (atom %)
23.0
E-27
E-29
a.
b.
c.
d.
26.333 amu
26.542 amu
26.972 amu
26.123 amu
e.
26.895 amu
TOUPADAKIS
58.0
28.668
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
11.
Page 5 of 10
Consider 100.0 g of ethanol CH3CH2OH. This quantity of ethanol contains oxygen that is
equivalent to (x) moles of ozone (O3).
a. x = 5.60 mol O3
b.
c.
d.
e.
12.
x = 4.50 mol O3
x = 5.50 mol O3
x = 0.72 mol O3
x = 0.45 mol O3
A 3.927 g sample of glycerin was found to contain 1.536 g carbon, 0.345 g hydrogen, and
the rest oxygen. Find the empirical formula of glycerin.
a. C2H8O3
b. C3H7O3
c. C3H8O3
d. C3H8O9
e. C3H5O3
TOUPADAKIS
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 6 of 10
13. Consider the compound C2H6O. How many grams of oxygen are in 5.0 grams of it?
a. 2.7
b. 1.2
c. 5.8
d. 2.5
e. 1.7
TOUPADAKIS
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 7 of 10
(2 points)
(2 points)
(2 points)
(1 point)
(1 point)
(2 points)
(6 points)
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Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 8 of 10
[K+] =
[OH-] =
[I-] =
16. (16 points) In a container we introduce 2.0 moles of K 2Cr2O7, 5.0 moles of SnCl2 and 1.0
mole of HCl. Answer the following questions by considering the balanced equation:
K2Cr2O7 + 3 SnCl2 + 14 HCl 2 CrCl3 + 3 SnCl4 + 2 KCl + 7 H2O
a. Which is the limiting reactant?
b. How many moles of SnCl2 reacted?
c. How many moles of SnCl2 were left unreacted?
d. If the percent yield of the reaction in water is 80.0%, how many moles of
water are actually obtained?
e. What is the average oxidation number of the chromium atoms in K 2Cr2O7 ?
f.
g.
b. Reacted SnCl2
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(1 point)
Fall 2016
CHEM 2A
Section D
EXAM 1
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Page 9 of 10
(1.0 mol HCl)(3 mol SnCl2/14 mol HCl) = 0.21 moles SnCl2 reacted.
c.
Unreacted SnCl2
(1 point)
(Initial moles of SnCl2) - (Reacted moles of SnCl2) = (5.0 - 0.21) moles SnCl2 =
= 4.8 moles unreacted SnCl2
d.
If the percent yield of the reaction in water is 80.0%, how many moles of
water are actually obtained?
(2 points)
0.80 = (Actual moles of water obtained) /(max moles of water could be produced)
0.80 = (Actual moles of water obtained) /(0.50)
Actual moles of water obtained = 0.4
e.
(2 points)
2(+1) + 2x + 7(-2) = 0 x = +6
(6 points)
f.
g.
(2 points)
(y + y)/2 = +6 y = +6
TOUPADAKIS
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 10 of 10
Key
1
Atomic Number
Symbol
Atomic Mass
Electronegativity
He
1.008
2.20
3
Li
Be
6.941
0.98
9.012
1.57
10.81
2.04
12.01
2.55
14.01
3.04
16.00
3.44
19.00
3.98
4.003
10
Ne
20.18
-
11
12
13
14
15
16
17
18
Na
Mg
Al
Si
Cl
Ar
22.99
0.93
24.31
1.31
26.98
1.61
28.09
1.90
30.97
2.19
32.06
2.58
35.45
3.16
39.95
-
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
39.10
0.82
40.08
1.00
44.96
1.36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Rb
Sr
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
Cd
In
Sn
85.47
0.82
87.62
0.95
88.91
1.22
47.90
1.54
91.22
1.33
50.94
1.63
92.91
1.6
52.00
1.66
95.94
2.16
54.94
1.55
(98)
1.9
55.85
1.83
101.1
2.2
58.93
1.88
102.9
2.28
58.70
1.91
106.4
2.20
63.55
1.90
107.9
1.93
65.38
1.65
112.4
1.69
69.72
1.81
114.8
1.78
72.59
2.01
74.92
2.18
78.96
2.55
79.90
2.96
51
52
53
54
Sb
Te
Xe
118.7
1.96
121.8
2.05
127.6
2.1
126.9
2.66
83.80
-
131.3
-
55
56
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
Cs
Ba
Lu
Hf
Ta
Re
Os
Ir
Pt
Au
Hg
Tl
Pb
Bi
Po
At
Rn
132.9
0.79
87
Fr
(223)
0.7
137.3
0.89
88
Ra
(226)
0.9
175.0
1.27
103
178.5
1.3
104
180.9
1.5
105
183.9
2.36
106
186.2
1.9
107
Lr
Unq
Unp
Unh
Uns
(260)
-
190.2
2.2
-
192.2
2.20
109
195.1
2.28
197.0
2.54
200.6
2.00
204.4
2.04
207.2
2.33
209.0
2.02
(209)
2.0
(210)
2.2
(222)
-
Une
-
TOUPADAKIS
Fall 2016
CHEM 2A
Section D
EXAM 1
Name
Page 11 of 10
m
V
1 m = 10 12 pm
TOUPADAKIS
NA = 6.02 x 10 23
Moles
Molarity
Volume
1 lb = 453.59 g
Fall 2016
CHEM 2A
% Yield
Actual Yield
x100
Theoretica l Yield
1 g = 6.022 x 10 23amu
Section D
EXAM 1