MATERIAL SAFETY DATA SHEET

1. CHEMICAL IDENTITY
Chemical Name: Coal Tar Pitch
Chemical Classification: Toxic (Carc.Cat.2)
Trade Name: Extra Hard Pitch, Hard
Medium Pitch
Synonyms: Super Hard Pitch, Binder Pitch, Hard Pitch, Soft Medium Pitch, Soft Pitch
Formula: Not Available
CAS No: 65996-93-2
UN No: 3257
Regulated Identification
Shipping Name: Extra Hard Pitch, Hard Medium Pitch
Hazchem Code: Not
Available
Codes / Label: Class 6.1, Toxic
Hazardous Waste ID No
:
HAZARDOUS INGREDIENTS C.A.S. No.
HAZARDOUS INGREDIENTS C.A.S.
No.
1 Coal Tar Pitch
65996-93-2
3
2
4
2. PHYSICAL / CHEMICAL DATA
The product is liquid above the Softening Point
Boiling Range C: >360
Physical State: Solid
Colour: Black
Softening Pt. C: 30-180
Vapour Pressure at 20C hPa: <0.001
Odour: Characteristic
Density at 20C kg/m3 : 1.15-1.40 Solubility in water at 20C: Immiscible
Others:
3. FIRE / EXPLOSION HAZARD DATA
Flammability
: No
LEL: 33 g/m3
Flash Point C in OC:
>200
TDG Flammability:
UEL: Not Known
Flash Point C in CC: >200
Auto-ignition Temperature C
: 550
Explosion sensitivity to impact
: Stable
Explosion sensitivity to static Electricity : Stable
Hazardous Combustion Products
: Emits toxic fumes of SOX.
Hazardous Polymerization
: Will not occur.
Combustible Liquid
: No
Explosive Material
: Yes
Corrosive
Material: No
Flammable Material
: Yes
Oxidiser
: No
Others:
Pyrophoric Material
: No
Organic Peroxide : No
4. REACTIVITY DATA
Chemical Stability
Conditions to avoid
might occur.
Incompatibility with
other material

: Stable
: Sources of ignition; do not overheat else thermal decomposition
: Strong oxidizing agents

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Dangerous Reactions : The product is incapable of dust explosion in the form supplied.
High dust concentration due to excessive mechanical degradation
causes risk of dust explosion. Can form explosive mixtures in air if
heated above flash point and/or when sprayed or atomized.
Hazardous
: No decomposition if used according to specifications. The substances
arising from Decomposition thermal decomposition ( >400OC ) cannot be accurately
predicted. Any fumes / vapours
Products
are potentially irritant/toxic and suitable protective equipment should
be worn.
DANGEROUS COMPONENTS
CAS:6599693-2
EINECS:266028-2
CAS:91-20-3
EINECS:202049-5
CAS:56-55-3
EINECS:200280-6
CAS:218-01-9
EINECS:205923-4
CAS:205-99-2
EINECS:205911-9
CAS:207-08-9
EINECS:205916-6
CAS:205-82-3
EINECS:205910-3
CAS:50-32-8
EINECS:200028-5
CAS:192-97-2
EINECS:205892-7
CAS:92-52-4
EINECS:202163-5
CAS:53-70-3

Coal Tar Pitch

PBT;T-Carc.Cat.2(R45)

ca.10
0%

Naphthalene
T-Carc.Cat.3(R40), Xn(R22), N(R50/53)

<0.05
%

Benz(a)anthracene
T-Carc.Cat.2(R45), N(R50/53)

<2.0
%

Chrysene
T-Carc.Cat.2(R45)-Muta.Cat.3(R68), N(50/53)

<2.0
%

Benzo(b)fluoranthene, benz(e)acephenanthrylene
T-Carc.Cat.2(R45), N(R50/53)

<2.0
%

Benzo(k)fluoranthene
T-Carc.Cat.2(R45), N(R50/53)

<2.0
%

Benzo(j)fluoranthene
T-Carc.Cat.2(R45), N(R50/53)

<2.0
%

Benzo(a)pyrene
T-Carc.Cat.2(R45)-Muta.Cat.2(R46)-Repr.Cat.2(R60/61), R43,
N(R50/53)
Benzo(e)pyrene
T-Carc.Cat.2(R45), N(R50/53)
Biphenyl
Xi(R36/37/38), N(R50/53)

<2.0
%
<2.0
%
<2.0
%

Dibenz(a,h)anthracene

<0.5

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EINECS:200181-8

T-Carc.Cat.2(R45), N(R50/53)

HAZARDS as per PBT(Persistent Bioaccumulative Toxic) Classification with European INventory of Existing Commercial
chemical Substances(EINECS)

Dangerous for the

environment
Toxic

Xi

Irritant

Xn
Carc.Cat.
2
Carc.Cat.
3
Muta.Cat
.2

Harmful
Category 2
Carcinogens
Category 3
Carcinogens
Category 2
Mutagens
Category 2
Reproductive
Toxins

Repr.Cat.
2

Chemicals that may present an immediate or delayed danger to one or

more components of the environment
Chemicals that at low levels cause damage to health
Chemicals that may cause inflammation to the skin or other mucous
membranes
Chemicals that may cause damage to health
Chemicals that may cause cancer or increase its incidence
Chemicals that may cause cancer or increase its incidence
Chemicals that induce heritable genetic defects or increase their
incidence
Chemicals that produce or increase the incidence of non-heritable effects
in progeny and/or an impairment in reproductive functions or capacity

R22
R36/37/38
R40
R43

RISK PHRASES
Harmful if swallowed
Irritating to eyes, respiratory system, skin
Limited evidence of a carcinogenic effect
May cause sensitization by skin contact

R45

May cause cancer

R46

May cause heritable genetic damage

Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment
May impair fertility & cause harm to unborn
child
Possible risk of irreversible effects

R50/53
R60/61
R68

S22
S24/25
S26
S27
S28
S36/37
S39/53
S57/61

SAFETY PHRASES
Do not breathe dust/vapours
Avoid contact with skin and eyes
In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice
Take off immediately all contaminated
clothing
After contact with skin, wash immediately
with plenty of soap and water
Wear suitable protective clothing and gloves
Wear eye/face protection and avoid
exposure.
Use apt container & avoid release to the
environment

5. HEALTH HAZARD DATA

Routes of entry: Inhalation, Ingestion, Eyes and Skin
Effects of Exposure / Symptoms:
Short term exposure to high concentrations of dust may cause skin irritation. Exposure to
vapours from hot product may cause irritation of the nose, throat or eyes. Headache and
nausea are also possible. Long term exposure to high concentration of vapours may
result in danger to internal organs.
Emergency Treatment:
Inhalation: Move person to fresh air. Give oxygen or artificial respiration in extreme
cases.
Skin
: Remove clothes and shoes. Flush affected area with plenty of water. If solid,
wash exposed area with non-abrasive soap and water.

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Eyes
: Wash with plenty of water for 15 minutes. Consult eye specialist.
Ingestion : If conscious, first try to induce vomiting and then give plenty of water to
drink. Do not give anything by mouth to an unconscious person. Seek medical aid
immediately.
LD50 (oral-rat) mg/kg: >15000
LD50 (dermal-rat) mg/kg: >5000
ECO mg/l: 1000 (algae)
ECO mg/l: 1000 (daphnia)
ECO mg/l: 1000 (fish)
TLV (ACGIH): 0.2 mg/m3
6. PREVENTIVE MEASURES
Personal Protective :
Do not eat or drink at work place. Wear full body, industrial-type
work clothing including
Equipment
chemical resistant gloves, boots and goggles (face shields if molten).
Use breathing protections against the effects of fumes/dust/aerosol.
Keep away from ignition sources.
Handling
: When handling liquid pitch, avoid any fuming by using only dry
containers. Splashes to the skin are to be avoided as it will cause
thermal burns of skin. Solid pitch is to be handled in such a way so as
to minimize dust generation. Ensure adequate ventilation and guard
against ignition sources and static electricity.
Storage
: Liquid pitch is to be stored between 200-220 OC, keeping away
from open fire and ignition sources, with adequate ventilation and
guarding it against static electricity. Solid pitch can be stored at room
temperature in covered warehouses. Keep away from strong oxidizing
substances.
Precaution
:
Avoid contact with the material. Wash hands thoroughly before
eating, toilet visits and at work end.
7. EMERGENCY / FIRST AID MEASURES
FIRE:
Fire Extinguishing Media: Dry chemical, carbon dioxide, sand, foam, steam or water fog.
Do not use water jet.
Special Hazards
: Incomplete combustion in a fire may result in release of toxic
carbon monoxide. Under certain conditions traces of other toxic gases such as Nitrogen
oxides or Sulphur dioxide can occur.
Unusual Hazards
: When heated may generate vapours that may ignite.
EXPOSURE:
First Aid Measures:
Inhalation: Move person to fresh air. Give oxygen or artificial respiration in extreme
cases.
Skin
: Remove clothes and shoes. Flush affected area with plenty of water. If solid,
wash exposed area with non-abrasive soap and water.
Eyes
: Wash with plenty of water for 15 minutes. Consult eye specialist.
Ingestion : If conscious, first try to induce vomiting and then give plenty of water to
drink. Do not give anything by mouth to an unconscious person. Seek medical aid
immediately.

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SPILLS:
Steps To Be Taken

: Keep away from drains, surface and ground water. Ventilate area
if spill occurs indoors. Keep away from ignition sources and static
electricity.
Waste Disposal Method: If liquid, contain with sand, earth or any other inert material and
allow solidifying. To remove solid pitch, use mechanical means.
Additional information: Disposal should be in accordance with local, state or national
legislation It must not be disposed together with household garbage
or strong oxidizing agents.
8. ADDITIONAL INFORMATION / REFERENCES
The product is harmful for aquatic organisms. It should not be allowed to reach ground
water, water course or sewage system. It is stable in water and in soil and is not the
short-degradable in the short-term. Avoid dust, fumes and vapour emissions.
9. MANUFACTURERS / SUPPLIERS DATA
NAME OF FIRM : BOKARO STEEL PLANT, SAIL
Contact person
MAILING ADDRESS : BOKARO STEEL CITY
in Emergency : Mr. T P RAO
TELEPHONE / TELEX NOS : 06542-273718 / 0628-201
Local Bodies involved : NONE
TELEGRAPHIC ADDRESS : BOKSTEEL
Standard Packing : Gunny bags
FAX : 06542-242099
Trem Card Details / Ref : ICSC
1415
10. DISCLAIMER
Information contained in this material data sheet is believed to be reliable but no
representation; guarantee or warranties of any kind are made as to its accuracy,
suitability for a particular application or results to be obtained from them. Information
contained in this publication or as otherwise supplied to Users is believed to be accurate
and is given in good faith, but it is for the Users to satisfy themselves of the
suitability of the product for their own particular purpose. Bokaro Steel Plant, SAIL
gives no guarantee or warranty as to the fitness of the product for any particular purpose
and any implied guarantee or warranty or condition (statutory or otherwise) is excluded
except to the extent that exclusion is prevented by law. Bokaro Steel Plant, SAIL accepts
no liability for loss or damage, resulting from reliance on this information.

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GLOSSARY
ACGIH The American Conference of Governmental Industrial Hygienists Inc., is an organization open to all
practitioners in industrial hygiene, occupational health, environmental health or safety. Their
website is http://www.acgih.org/.
Asphyxiant An asphyxiant is a substance that can cause unconsciousness or death by suffocation
(asphyxiation). Asphyxiants which have no other health effects and are sometimes referred to as
simple asphyxiants. Asphyxiants work by displacing so much oxygen from the ambient atmosphere
that the hemoglobin in the blood cannot pick up enough oxygen from the lungs to fully oxygenate
the tissues. As a result, the victim slowly suffocates.
O
C
degree Celsius. It is a measure of temperature.
CAS
Chemical Abstracts Service. It assigns a unique identification number in the format XXX-XX-X to all
compounds registered with it. The number allows one to identify a chemical regardless of the
naming system.
CC
Closed Cup
Chemical Classification (Hazardous) The chemicals hazard classification as per the CREFT (corrosive,
reactive, explosive, flammable, toxic) classification.
Codes/Label/Class The classifications identified are those adopted by the United Nations Committee of
Experts on the Transport of Dangerous Goods and on the Globally Harmonized System of
Classification and Labelling of Chemicals, and are as follows:
Class 1: Explosives
Class 2: Gases
Gases which are compressed, liquefied or dissolved under pressure or refrigerated as detailed
below. Some gases have subsidiary risk classes; poisonous or corrosive.
2.1 Flammable Gas: Gases which ignite on contact with an ignition source, such as acetylene and
hydrogen.
2.2 Non-Flammable Gases: Gases which are neither flammable nor poisonous. Includes the
cryogenic gases/liquids (temperatures of below -100 OC) used for cryopreservation and rocket fuels,
such as nitrogen and neon.
2.3 Poisonous Gases: Gases liable to cause death or serious injury to human health if inhaled;
examples are fluorine, chlorine, and hydrogen cyanide.
Class 3: Flammable Liquids
Flammable liquids included in Class 3 are included in one of the following packing groups:
Packing Group I, if they have an initial boiling point of 35 OC or less at an absolute pressure of 101.3
kPa and any flash point, such as diethyl ether or carbon disulfide etc.
Packing Group II, if they have an initial boiling point greater than 35 OC at an absolute pressure of
101.3 kPa and a flash point less than 23 OC, such as gasoline (petrol) and acetone etc.; or
Packing Group III, if the criteria for inclusion in Packing Group I or II are not met, such as kerosene
and diesel.
Class 4: Flammable, Others
4.1 Flammable Solids: Solid substances that are easily ignited and readily combustible
(nitrocellulose, magnesium, safety or strike-anywhere matches
4.2 Spontaneously Combustible: Solid substances that ignite spontaneously (aluminium alkyls,
white phosphorus
Class 5: Oxidizing Agents and Organic Peroxides
5.1 Oxidizing agents other than organic peroxides (calcium hypochlorite, ammonium nitrate,
hydrogen peroxide, potassium permanganate).
5.2 Organic peroxides, either in liquid or solid form (benzoyl peroxides, cumene hydroperoxide).
5.3 Dangerous when wet: Solid substances that emit a flammable gas when wet or react violently
with water (sodium, calcium, potassium, calcium carbide).

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Class 6: Toxic and Infectious Substances

6.1 Toxic substances which are liable to cause death or serious injury to human health if inhaled,
swallowed or by skin absorption (potassium cyanide, mercuric chloride).
6.2 Bio hazardous substances; the World Health Organization (WHO) divides this class into two
categories: Category A: Infectious; and Category B: Samples (virus cultures, pathology specimens,
used intravenous needles
Class 7: Radioactive Substances
Class 8: Corrosive Substances
Class 9: Miscellaneous
cP
centi Poise. It is a measure of viscosity.
Flammable Limits Flammable limits apply generally to vapours and are defined as the concentration range
in which a flammable substance can produce a fire or explosion when an ignition source (such as a
spark or open flame) is present. The concentration is generally expressed as percent fuel by
volume.
a. Above the upper flammable limit (UFL) the mixture of substance and air is too rich in fuel
(deficient in oxygen) to burn. This is sometimes called the upper explosive limit (UEL).
b. Below the lower flammable limit (LFL) the mixture of substance and air lacks sufficient
fuel (substance) to burn. This is sometimes called the lower explosive limit (LEL).
Any concentration between these limits can ignite or explode -- use extreme caution! Being
above the upper limit is not particularly safe, either. If a confined space is above the upper
flammable limit and is then ventilated or opened to an air source, the vapor will be diluted and the
concentration can drop into the flammable limit range.
Flash Point The flash point of a volatile liquid is the lowest temperature at which it can vaporize to form an
ignitable mixture in air in the presence of an ignition source. Depending on the test method used,
the values given are either Tag closed cup (C.C.) (ASTM D56) or Cleveland open cup (O.C.) (ASTM
D93). The values give an indication of the relative flammability of the chemical. In general, the
open cup value is about 5.5O to 8.5OC higher than the closed cup value.
Hazchem Code Emergency Action Codes (EACs), also known as Hazchem, are for the use of the
emergency services in conjunction with Emergency Action Code Cards. EACs indicate to the
emergency services actions that may be necessary, during the first few minutes of an incident
involving dangerous goods, should the officer in charge of the incident deem it necessary to take
immediate actions. The code uses one of the numerals 1, 2, 3 or 4 followed by one or two letters.
ICSC
International Chemical Safety Cards
ID
Identification. Hazardous Waste Identification number as indicated under categories of Wastes in the
Schedule of the Hazardous Wastes (Management and Handling) Rules 1989.
LC50 Lethal Concentration-The concentration of a substance in air that kills 50% of the test population
LD50 Lethal Dose-The dose of a substance administered by any route (other than inhalation) that causes
death to 50% of the test population
LEL
Lower Explosive Limit in air, % by volume
N
Normal. It is the concentration of a solution expressed in gram equivalents of solute per litre.
NFPA National Fire Protection Association (USA)
OC
Open Cup
OSHA Occupational Safety and Health Administration (USA)
PEL
Permissible Exposure Limit is the maximum amount or concentration of a chemical that a worker
may be exposed to under local regulations
pH
potential of Hydrogen-negative 10 base log of the positive Hydrogen ion concentration, measure of
acidity
ppm parts per million. Parts of a substance per million parts of air. It is a measure of concentration by
volume in air. mg/litre
SAIL Steel Authority of India Limited
SOX
Sulphur Oxides

Page 7 of 8

STEL Short-Term Exposure Limit (generally 15 minutes)

Synonyms The other name by which the chemical is known
TDG Transport of Dangerous Goods. This term is based on Classifications of Dangerous Goods by the
U.N. Committee of experts on Transport of Dangerous Goods. The Classes indicated are 2
(flammable), 3, 4 and 5.
TLV
Threshold Limit Value. These are guidelines prepared by ACGIH to assist industrial hygienists in
making decisions regarding safe levels of exposure to various hazards found in the workplace.
Trem Transport Emergency (Card)
TWA Time-Weighted Average (8 hour)
UEL
Upper Explosive Limit in air, % by volume
UN
United Nations. Numbers are four-digit numbers used world-wide in international commerce and
transportation to identify hazardous chemicals or classes of hazardous materials. These numbers
generally range between 0000 and 3500 and are ideally preceded by the letters "UN" (for example,
"UN1008") to avoid confusion with other number codes.

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