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Article history: In this work, the effect of solid oxidizer (AP) mixed fuel grain (HTPB) on regression rate and performance
Received 13 October 2014 in GOX hybrid rocket motors is numerically studied. Here the pyrolysis products of AP and the fuel forms
Received in revised form 3 April 2015 a premixed ame very close to the grain surface in addition to the fueloxygen diffusion ame located
Accepted 10 April 2015
further away from the grain surface. The presence of premixed ame increases heat feedback to the
Available online 16 April 2015
grain and consequently increases the local regression rate throughout the grain length. This is contrary
to the locally limited inuence observed while using other regression rate enhancement techniques like
swirling oxidizer, or transverse diaphragms/protrusions. Scaling of motors with AP mixed grain of a given
composition follows that of a pure fuel grain where the grain geometry and the inlet oxidizer mass ux
need to be maintained.
2015 Elsevier Masson SAS. All rights reserved.
1. Introduction and improve the heat transferred to the fuel. Improved injector de-
signs enable enhanced radial transport in the combustion chamber
Hybrid rocket motors are a combination of solid and liquid that improves the heat feedback to the fuel surface. The energetic
rocket motors. A hybrid rocket has fuel and oxidizer in different additives to the solid fuel can be either metallic [10] or non-
phases (generally solid fuel and either liquid or gaseous oxidizer). metallic [9,11]. Metallic additives enhance the heat transfer to the
Hybrid rocket motors offer a promise of being reliable, extremely fuel grain surface by means of enhanced radiation. Non-metallic
safe and cheap launch vehicles. However, the commercial viabil- additives are typically solid oxidizers that enhance heat transfer to
ity of the hybrid rockets is marred by certain disadvantages, of the solid grain surface by means of additional energy release by
which the most important ones are the low regression rate and reacting with the fuel vapor close to the grain surface. The addi-
low combustion eciency. Regression rate is a measure of solid tives are added and mixed thoroughly with the solid grain during
fuel consumption in a hybrid motor and is expressed in terms of casting of the grain. The quantity of solid oxidizer used is usu-
fuel thickness consumed per unit time. In a hybrid rocket combus- ally very low up, at most, 30%. It was experimentally observed [9]
tion chamber, gaseous oxidizer and vaporized fuel mix and form that hybrid rockets with 30% AP mixed HTPB grains sustained the
a diffusion ame front. A portion of heat from this ame front is startstop capability up to an operating pressure of 43 bar.
used for further pyrolysis of the fuel and for sustaining the com- In the present work, a systematic numerical study is attempted
bustion. Thus, a successful regression rate enhancement technique to assess the effect of AP content in the solid HTPB grain (ex-
pressed in percentage) on the regression rate and performance of
must employ a way to increase the heat feedback from the diffu-
hybrid rockets of various grain sizes.
sion ame to the fuel surface.
Typical regression rate enhancement techniques involve heat
transfer improvement at the fuel surface by means of perturbed 2. Numerical model
ow [13], improved injector design [47] or energetic additives
to the solid fuel [811]. Disturbances in the ow eld are typi- The numerical model in the present study is explained in detail
cally caused by obstructions like diaphragms that form recircula- in [3]. Hence the model is only briey discussed here. The typ-
tion zones downstream of them. These recirculation zones bring ical computation domain used in the present work is presented
hot products from the combustion zone closer to the fuel surface in Fig. 1. The different boundaries of the computation domain are
marked and the types of boundary conditions used in these bound-
aries are provided in curved braces. Magnied view of mesh in
three separate regions marked by dashed boxes is shown in Fig. 1
* Corresponding author.
(lower).
E-mail address: guru.palani@gmail.com (P.K. Chidambaram).
1
Ph.D. Research Scholar. The transport processes occurring in a hybrid rocket combus-
2
Professor. tion chamber can be described adequately by the basic ow equa-
http://dx.doi.org/10.1016/j.ast.2015.04.005
1270-9638/ 2015 Elsevier Masson SAS. All rights reserved.
P.K. Chidambaram, A. Kumar / Aerospace Science and Technology 45 (2015) 1016 11
Nomenclature
As, A g Arrhenius pre-exponential factor for solid fuel pyroly- m Mass ow rate (kg s1 )
sis, gas phase reactions n Order of the gas phase reactions
C Characteristic velocity (m s1 ) r Cylindrical coordinate in radial direction
D Grain port diameter (mm)
rb Local regression rate (mm s1 )
Dj Diffusivity of species j (m2 s1 )
v Gas velocity in a given cell
E as , E g Arrhenius activation energy for solid fuel pyrolysis, gas
phase reactions Yi Mass fraction of species i
G OX Local mass ux, inlet oxidizer mass ux (kg m2 s1 ) Thermal diffusivity of solid fuel (m2 s1 )
L Grain port length (mm) , s Density of gas, solid (kg m3 )
C4 H6 + 4.4(NH3 + HClO4 )
1.4CO + 2.6CO2 + 0.7Cl + 3.7HCl + 0.65H2 + 8.9H2 O
+ 2.2N2 + 0.8OH + 0.65O2
A g = 4 109 ; E g = 120 kJ/mol; n = 1 [13]
R4: Reaction between butadiene and AP decomposition prod-
ucts
Fig. 1. Computation domain with boundary types specied (upper gure) and typi- C4 H6 + 4.4(1.5H2 O + 1.25O2 + HCl + 0.5N2 )
cal mesh shown in the selected regions of the domain (lower gure).
1.4CO + 2.6CO2 + 0.7Cl + 3.7HCl + 0.65H2 + 8.9H2 O
tions of continuity, momentum and energy along with the equa- + 2.2N2 + 0.8OH + 0.65O2
tions modeling turbulence and transport equations for species. The
A g = 5 105 ; E g = 60 kJ/mol; n = 1.6 [13]
combustion chamber in a single port hybrid rocket motor is as-
sumed to be axially symmetric. The governing equations consid- The composition of products for the reactions is obtained us-
ered are expressed in 2D axi-symmetric coordinates [3]. ing the chemical equilibrium code NASA SP273 [12]. The product
species considered here constitute more than 95% of all the pre-
2.1. Chemical kinetics dicted species. Note that this modied model is a 14 species sys-
tem as compared to the 4 species system of the original global
gas-phase chemistry model used in [3]. Thus, an additional 10
Combustion model with detailed chemistry is desired for accu-
transport equations are solved in the simulations carried out with
rate predictions. However, proper reaction mechanism and related
this modied model.
kinetics are not readily available in the literature. Nevertheless,
The pyrolysis of the solid fuel (HTPB grain) was modeled by
thermodynamic effect of multi species can be readily incorpo-
zeroth order Arrhenius equation following [14]. The mass of fuel
rated [12]. For simulations involving AP mixed solid grains, the
released by pyrolysis is given by
single step gas phase chemistry used in [3] is insucient. Rama-
( REuasT s )
krishna et al. [13] carried out a numerical study in composite AP = s rb = A s e
m (1)
based sandwich propellant. Their model consists of ve step re-
action kinetics of which two reactions approximate solid pyrolysis 2.2. Boundary conditions
(one each for AP and HTPB) and three reactions approximate gas
phase chemical reactions. The pyrolysis of AP is incorporated in As mentioned before, the various boundary types are shown in
the existing boundary condition (which already incorporates pyrol- Fig. 1. These include mass ow boundary for oxidizer at the head
ysis of HTPB). The three gas phase reactions between fuel vapors end of the grain port, supersonic exit at the nozzle exit and axi-
and products of AP pyrolysis and AP decomposition are added symmetric boundary at the axis. The boundary condition at the
to the existing single step gas phase chemistry model (reaction fuel surface (or fuelgas interface) was enforced by applying local
between butadiene and gaseous oxygen). Thus, the modied gas mass (total and components) and energy balance [3]. The equa-
phase chemistry model used in the present numerical study has tions of mass and energy balance at the interface are
four steps as given below.
T T
R1: Oxidation of butadiene eff s s rb h s ( vh) g
r g r s
C4 H6 + 5.5O2 2.6CO + 1.4CO2 + 0.47H + 0.41H2 + 1.85H2 O
N
Y j
+ D j hj = 0 (2)
+ 0.6O + 1.01OH + 1.06O2 r
1
A g = 8.8 1011 ; E g = 126.37 kJ/mol; n = 2 [14] = s rb = v
m (3)
12 P.K. Chidambaram, A. Kumar / Aerospace Science and Technology 45 (2015) 1016
Table 1
A comparison of chamber pressure, regression rate and enhancement in regression rate between the experiment values reported and the predictions with the present
numerical model.
Fig. 3. (A) Reaction rate contours and (B) volumetric heat released due to the reactions, along the radius at an axial location of 75 mm from the head end of the combustion
chamber (Insets: Magnied views for individual reactions closer to the fuel surface).
Fig. 4. Effect of AP content in the solid grain on the average regression rate, overall Fig. 5. Effect of AP content in the solid grain on the local regression rate prole
O/F ratio and other the characteristic velocity C . along the grain length for a motor with grain port diameter of 30 mm and grain
length of 750 mm.
Fig. 6. Effect of grain length on (A) average regression rate, overall O/F ratio, and (B) characteristic velocity, for grains of selected AP content in solid grain.
is a heat feedback to the grain surface from the premixed ame length in a grain with large port diameter. Correspondingly, the
all along the grain surface. Thus the local regression rate continues overall O/F ratio increases with increase in grain port diameter. As
to increase till the end of the grain. Therefore, the enhancement in seen in the previous section (Section 3.2), with increase in AP con-
regression rate due to the presence of AP in the grain is not local tent in the solid grain, the average regression rate increases and
and occurs throughout the length of the solid grain unlike those overall O/F ratio decreases.
seen due to swirl in oxidizer ow or diaphragms/protrusions. Con- Fig. 7(B) presents C variation for the simulations illustrated in
sequently, the average regression rate is enhanced for grains of all Fig. 7(A). Interestingly the variation in C with increase in grain
lengths (see Fig. 6(A)). With increase in regression rate, the over- port diameter is only marginal. As C is dependent on overall O/F
all O/F ratio decreases with increase in grain length as seen in the ratio, the slight variation in O/F ratio is believed to have caused a
inset in Fig. 6(A). marginal decrease in C with increasing grain port diameter. How-
Interestingly, C shows a different increasingdecreasing trend ever, C increased marginally due to better mixing in larger grains.
with increase in grain length as shown in Fig. 6(B). C is strongly This indicates that the scaled up motors, with the same composi-
dependent on the average gas temperature and attains maximum tion of the solid grain as for the small motor, are expected to yield
at a location closer to where oxygen depletes. Interestingly even similar performance when the grain geometry and inlet G OX are
with 30% AP in the grain, the oxygen depletion and consequently maintained.
the peak C occurs for grain L/D ratio of about 18 compared to L/D
ratio of 20 for pure HTPB grain. This is because the presence of AP 3.4. Effect of oxidizer mass ux on regression rate of mixed fuel grain
in fuel grain has two effects, rst is reduction in the amount of fuel
present in the grain and the second is increase in heat transfer to Lastly we look at the effect of G OX on regression rate which, so
fuel grain from the premixed ame. Both of these favor a shorter far was taken to be constant at 132 kg/(m2 s) in the above simu-
motor L/D at which peak C is expected to occur. lations. The dependence of average regression rate on G OX is one
Therefore, it should be noted that while it is possible to en- of the important aspects sought after in hybrid rocket studies. In
hance the local and average regression rates using longer AP mixed the previous study by the authors [16] for pure HTPB grain with
fuel grain, it must be done at the expense of decrease in C port L/D of 15, the G OX exponent was found to be 0.72. Here we
which has a maximum for L/D = 18. In case further enhancement ask how this exponent is affected in an AP mixed fuel grain. Fig. 8
of regression rate is required by incorporation of other regression shows the variation of average regression rate with G OX for the
rate enhancement techniques, the L/D for such grain must be less same grain dimensions but with 30% AP in the grain. The G OX ex-
than 18. ponent is about 0.64, slightly lower than 0.72 for pure HTPB grain.
Now coming to the scaling of AP mixed fuel grains, simulations This G OX exponent for grains with lower AP content is expected to
were carried out for grains of xed port L/D ratio and xed inlet lie between 0.72 and 0.64.
G OX . As C enhancement is feasible only for short grains, a repre- The slight decrease in the G OX exponent is expected because
sentative L/D ratio of 10 was chosen for the simulations. The inlet in the presence of premixed APHTPB ame close to the surface,
G OX was 132 kg/(m2 s) supplied at 300 K. Fig. 7(A) presents the av- the inuence of diffusion ame (O2 -HTPB) is reduced. However,
erage regression rate and overall O/F ratio for grains of L/D ratio 10 the heat transfer from the diffusion ame still dominates (thus a
and various port diameters (30 mm, 60 mm and 120 mm) and AP hybrid motor).
content (from 0% to 30%). For a given grain, the average regression
rate decreases (in a decreasing rate) with increase in grain port di- 4. Conclusion
ameter. In a grain of large port diameter the increase in local mass
ux due to fuel addition is lower because of larger port area. Thus In this work, performance enhancement of a hybrid rocket mo-
the local regression rate increases at a slower rate along the grain tor using AP impregnated grain was numerically studied for the
P.K. Chidambaram, A. Kumar / Aerospace Science and Technology 45 (2015) 1016 15
Fig. 7. Effect of grain port diameter on (A) average regression rate, overall O/F ratio, and (B) characteristic velocity, and combustion eciency for grains of selected AP content
in solid grain.
References