2014 As Chemistry Chapter 20 Review - Electrochemistry

5/6/2016 2014ASChemistryChapter20Review:ELECTROCHEMISTRY
Name:BiancaEspinoza
Score:36/39points(92%)
2014ASChemistryChapter20Review:ELECTROCHEMISTRY
MultipleChoice
Identifythechoicethatbestcompletesthestatementoranswersthequestion.

B 1.Whichofthefollowingistheprocessinwhichelectricalenergycausesachemicalreaction?
a. hydrolysis b. electrolysis c. oxidation d. electronation
ANSWER:B
POINTS: 1/1

B 2.Thefirstelectrochemicalcell(gavalniccell)wasinventedby______.
a. MichaelFaraday b. AlessandroVolta c. JamesMaxwell d. BenjaminFranklin
ANSWER:B
POINTS: 1/1

A 3.Howcanaredoxreactionbeusedasasourceofelectricalenergy?
a. Twohalfreactionsmustbephysically c. Twohalfreactionsmustinvolvemorethan
separated. oneelectron.
b. Onehalfreactionmustinvolvetwo d. Onehalfreactionmustuseametalwire
metals. electrode.
ANSWER:A
POINTS: 1/1

B 4.Whathappensinanelectrolyticcell?
a. Chemicalenergyischangedtoelectrical c. Electricalenergyischangedtomagnetic
energy. energy.
b. Electricalenergyischangedtochemical d. Magneticenergyischangedtoelectrical
energy. energy.
ANSWER:B
POINTS: 1/1

B 5.Atwhichelectrodedoesreductionoccurinavoltaiccell?
a. anodeonly c. bothanodeandcathode
b. cathodeonly d. eitheranodeorcathode,dependingonthe
metal
http://chemtutorial.net/modern_chem/chapter_20_electrochemistry/concept_review/14_modern_chapter_20_review.htm 1/10
ANSWER:B
POINTS: 1/1

A 6.Whichelectrodehasnegativesigninavoltaiccell?
metal
ANSWER:A
Involtaiccell,theanodelose(orprovides)electronssoithasnegativesign.
POINTS: 1/1

C 7.Inazinccoppercell,Zn/Zn ||Cu /Cu,whichelectrodeispositive?
a. Zn (aq) b. Zn(s) c. Cu d. Cu (aq)
ANSWER:C
Accordingtothecelldiagram,Cuisontherighttherefore,itisthecathodeandit
hasapositivesign.
POINTS: 1/1

C 8.Whatoccursinahalfcell?
a. oxidationonly c. oxidationorreduction,butnotboth
b. reductiononly d. bothoxidationandreduction
ANSWER:C
POINTS: 1/1

A 9.Atwhichelectrodedoesoxidationoccurinavoltaiccell?
metal
ANSWER:A
POINTS: 1/1

A10.TheelectrodeAontheleftiscopperandtheelectrodeBontherightiscalcium.Whichoneis
oxidizedandtheanode?

a. ElectrodeB:calcium b. ElectrodeA:copper
ANSWER:A
Accordingtotheactivityseries,calciumismoreactivethanthecoppersocalcium
loseelectronseasierthancoppertherefore,calciumistheanode.
POINTS: 1/1

B11.Whichletterisasaltbridgeinthefollowingvoltaiccell?

a. B b. E c. D d. C
ANSWER:D
POINTS: 0/1

B12.Inthefigureofavoltaiccellshownbelow,whereareelectronsgained?

a. A b. B c. C d. D
ANSWER:B
POINTS: 1/1

B13.Azinccoppercellisconstructed:Zn/Zn ||Cu /Cu.Whatoccurstothemassofthe
copperelectrodeasthereactionproceeds?(Zincisabovecopperintheactivityseriesofmetals.)
a. Itdecreases. c. Itremainsthesame.
b. Itincreases. d. cannotbedetermined
ANSWER:B
Accordingtotheabovecellnotation,Znisontheleftsoitisoxidized,loses
electronsanditistheanodesotheZnelectrodewillbedestroyed.
TheCuisontherightofthecellnoation,soitisreducedandCuionsgainelectrons
tobecomeCumetal.ThereforeCuelectrodewillgainmoremass.
POINTS: 1/1

C14.Amagnesiumironcellisconstructedanditsredoxreactionisdescribedbelow.Whichmetalis
oxidized(strongerreducingagent)andwhichmetalisthecathode?(Magnesiumisaboveironin
theactivityseriesofmetals.)
Mg+Fe2+ Mg2++Fe
a. Mgisreduced,Ironistheanode c. Mgisoxidized,Ironisthecathode
b. Mgisoxidized,Ironistheanode d. Mgisreduced,Ironisthecathode
ANSWER:C
Accordingtoactivityserriestable,MgismoreactivethantheFeMglosesits
electronseasierthantheFemetalthusMgisoxidizedanditistheanodeandFeis
thecathode.
Wegetthesameresultbyanalyzingtheaboveequation.MgchangestoMg2+soit
itoxidizedthusMgistheanodeandIronisthecathode.
POINTS: 1/1

B15.Amagnesiumironcellisconstructedanditsredoxreactionisdescribedbelow.Whichdirection
oftheflowofelectron?(Magnesiumisaboveirronintheactivityseriesofmetals.)
Mg+Fe2+ Mg2++Fe
a. ElectronsflowfromFetoMg b. ElectronsflowfromMgtoFe
ANSWER:B
Accordingtotheacticityseriestable,MgismoreactivethantheFeMglosesits
electronseasierthantheFemetalthusMgisoxidizedanditistheanodeandFeis
thecathode.
Wewillgetthesameresultbyanalyzingtheaboveequation.MgchangestoMg2+
soititoxidizedthusMgistheanodeandIronisthecathode.
Therefore,electronsflowfromtheMganodetotheFecathode.
POINTS: 1/1

B16.TheelectrodeAontheleftiscopperandtheelectrodeEontherightiscalcium.Whichisthe
directionofelectronflow?Calciumisastrongerreducingagentthancopper.

a. FromelectrodeA(copper)toelectrode b. FromelectrodeE(calcium)toelectrode
E(calcium) A(copper)
ANSWER:B
Accordingtotheactivityseries,calciumismoreactivethanthecoppersocalcium
loseelectronseasierthancoppertherefore,calciumistheanodeandtheelectron
flowfromthecalciumanodetothecoppercathode.
POINTS: 1/1

D17.WhichofthefollowingfactorsdoesNOTaffectthevoltageproducedinavoltaiccell?
a. metaloftheelectrodes c. temperature
b. concentrationsofions d. pressure
ANSWER:D
POINTS: 1/1

A18.Whatisthecellpotential?
a. thedifferenceinreductionpotentialsofthe c. thesumofreductionpotentialsofthehalf
halfcells cells
b. thedifferenceinoxidationpotentialsofthe d. thesumofoxidationpotentialsofthehalf
halfcells cells
ANSWER:A
POINTS: 1/1

B19.Whatstandardreductionelectrodehasahalfcellpotentialof0.00V?
a. oxygen b. hydrogen c. lithium d. fluorine
ANSWER:B
POINTS: 1/1

B20.Whatsymbolisusedtoshowthestandardreductionpotentialofanoxidationreactioninahalf
cell?
a. E b. E c. E d. E
ANSWER:B
POINTS: 1/1


B21.Amagnesiumironcellisconstructedanditsredoxreactionisdescribedbelow.Whichofthe
followingcellnotationiscorrect?(Magnesiumisaboveirronintheactivityseriesofmetals.)
Mg+Fe2+ Mg2++Fe
a. Mg2+|Mg||Fe2+|Fe c. Fe2+|Fe||Mg2+|Mg
b. Mg|Mg2+||Fe2+|Fe d. Fe|Fe2+||Mg2+|Mg
ANSWER:B
Accordingtotheactivityseriestable,MgismoreactivethantheFeMglosesits
electronseasierthantheFemetalthusMgisoxidizedtoMg2+anditistheanode
andFe2+isreducedtoFemetalsoFeisthecathode.
Wewillhavethesameresultbyanalyzingtheaboveequation.Mgchangesto
Mg2+Therefore,MgisoxidizedsoitistheanodeandFeisthecathode.
POINTS: 1/1

C22.Whatisthestandardcellpotentialofacellmadeofmagnesiumandironiftheelectrodepotentials
are2.38voltand0.04voltrespectively.Thereactionis:
Mg+Fe3+ Mg2++Fe
a. 2.34volt b. 2.42volt c. 2.34volt d. Noneoftheabove
ANSWER:C
Accordingtotheequation,MgchangestoMg2+therefore,Mgisoxidizedsoitis
theanodeandFeisthecathode.
E0cell=E0cathodeE0anode
=E0FeE0Mg
=0.04v(2.38v)=2.34v
POINTS: 1/1

B23.Whatisthestandardcellpotentialofacellmadeofsilverandcalcium?Theelectrodepotentials
are0.80voltand1.66voltrespectively.Thecelldiagramis:
2+||Ag1+|Ag
Ca|Ca
a. 2.46volt b. 0.86volt c. 2.46volt d. Noneoftheabove
ANSWER:B
Accordingtoactivityseriestable,CaismoreactivethannickelortheCaelectrode
isontheleftoftheabovecelldiagramTherefore,Caisoxidizedsoitistheanode
andAgisthecathode.
=E0AgE0Ca
=0.80v(1.66v)=0.86v
POINTS: 1/1

B24.Usethetableofstandardreductionpotentialsbelowtoanswerthefollowingquestions.
Halfreaction E0 (volts)
0.913
0.447
0.4030
+1.06
CalculateE0cellforthefollowingreaction.Willthisreactionoccurspontaneouslyaswritten?

a. 1.973V,nonspontaneousbecausethe c. 1.973V,nonspontaneousbecausethe
cellvoltageispositive cellvoltageisnegative
b. 1.973V,spontaneousbecausethecell d. 1.973V,spontaneousbecausethecell
voltageispositive voltageisnegative
ANSWER:B
Accordingtotheaboveequation,CrchangestoCr2+therefore,Crisoxidizedand
itistheanodeandBr2isthecathode.
=E0BrE0Cr
=+1.06v(0.913v)=1.973v
POINTS: 1/1

D25.Whichofthefollowingistrueaboutfuelcells?
a. Theycanproduceelectricalenergyas c. Theyarebatteries
longasreactantspresent
b. Theyareaspecialvoltaiccell d. Alloftheabove
ANSWER:D
POINTS: 1/1

D26.Batteryisanapplicationofwhichreaction?
a. electrolyticreactions c. autooxidationreactions
b. fuelcellreactions d. galvanicreactions
ANSWER:D
POINTS: 1/1

B27.Inadrycell,theelectrolyteisa______.
a. solid b. paste c. liquid d. gas
ANSWER:B
POINTS: 1/1

B28.Whatelectrolyteisusedinaleadstoragebattery?
a. hydrochloricacid b. sulfuricacid c. leadacetate d. leadnitrate
ANSWER:B
POINTS: 1/1

C29.Whenarechargeablecellproduceselectricalenergy,itactsasa(n)_____.
a. electrochemicalcell. c. voltaiccell.
b. electrolyticcell. d. halfcell.
ANSWER:C
POINTS: 1/1

B30.Whenelectricalenergyisprovidedtoarechargeablebatteryfromanexternalsource,thecellacts
asa(n)____.
a. electrochemical b. electrolyticcell. c. voltaiccell. d. halfcell.
cell.
ANSWER:B
POINTS: 1/1

D31.Whenanautomobilebatteryischarging,_____.
a. heatenergyisconvertedtoenergyof c. chemicalenergyisconvertedtoelectrical
motion. energy.
b. energyofmotionisconvertedtoheat d. electricalenergyisconvertedtochemical
energy. energy.
ANSWER:D
POINTS: 1/1

A32.Howisaleadstoragebatteryrecharged?
a. Adirectcurrent(DC)fromanalternatorisc. Alternatingcurrent(AC)isforced
appliedtoit throughit.
b. Amagnetisheldclosetoit. d. Thepressureonitisincreased.
ANSWER:A
POINTS: 1/1

D33.Whichofthefollowingistrueaboutanelectrolyticcell?
a. Itchangeselectricalenergyintochemical c. Itusesanelectriccurrenttomakea
energy. nonspontaneousreactiongo.
b. Itisthetypeofcellusedinelectroplating. d. alloftheabove
ANSWER:D
POINTS: 1/1

A34.Atwhichelectrode(anodeorcathode)doesoxidationoccurinanelectrolyticcell?
a. anode b. cathode c. both d. neither
ANSWER:A
POINTS: 1/1

A35.Electroplatingisanapplicationofwhichreaction?
a. electrolyticreactions c. autooxidationreactions
b. electrochemicalreactions d. voltaicreactions
ANSWER:A
POINTS: 1/1

B36.Whatoccursinelectroplating?
a. depositionofasaltlayeronametal c. decompositionofametallayer
b. depositionofametallayeronamaterial d. decompositionofasaltlayer
ANSWER:B
POINTS: 1/1

B37.Inelectroplating,theobjecttobeelectroplatedisplaced_____.
a. attheanode c. ateithertheanodeorcathode
b. atthecathode d. inbetweentheanodeandthecathode
ANSWER:B
POINTS: 1/1

C38.Whatisthesourceofenergyforanelectrolyticcell?
a. thereactionoccurringintheelectrolytic c. ionmigrationintheelectrolyte
cell
b. anexternaldirectcurrentsource,suchas d. electronmigrationintheelectrolyte
abattery
ANSWER:B
POINTS: 0/1


A39.Inanelectroplatingcell,theobjecttobeplatedisthe______.
a. externalcircuit. b. electrolyte. c. anode. d. cathode.
ANSWER:D
POINTS: 0/1


2014 As Chemistry Chapter 20 Review - Electrochemistry

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