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MARK SCHEME

CHEMISTRY PAPER 1 MODULE B

NO ANSWER NO ANSWER
1 D 26 D
2 B 27 C
3 B 28 A
4 D 29 B
5 D 30 B
6 D 31 A
7 B 32 A
8 D 33 D
9 D 34 B
10 A 35 A
11 C 36 D
12 B 37 C
13 C 38 A
14 A 39 D
15 C 40 B
16 C 41 A
17 C 42 D
18 D 43 A
19 B 44 D
20 D 45 D
21 D 46 C
22 C 47 B
23 C 48 B
24 B 49 C
25 D 50 A
Answer Paper 2
Question Answer Mark
1 (a) (i) CH2O // B 1

(ii) Chemical formula that shows the simplest whole number ratio of atom 1
of each elements in the a compound
Formula kimia yang menunjukkan nisbah teringkas bilangan atom bagi setiap unsur
dalam satu sebatian.
(iii) Same type of element // C and H//Difference number of atoms 1
Jenis unsur yang sama/ C dan H//Bilangan atom yang berbeza
(iv) 156 gmol-1 1
(b) (i)
HCl + NH3 NH4Cl 1

(ii) Residue :CuO 1

(c) (i) Reactant: Potassium iodide / Lead(II) nitrate


Bahan tindak balas: Kalium iodida / Plumbum(II) nitrat

Product: Potassium nitrate / Lead(II) iodide


Hasil tindak balas : Kalium nitrat / Plumbum(II) iodida 1

(ii) Solid 1
Pepejal
(iii) Yellow 1
Kuning
Total 9

Question Answer Mark


2 (a) (i) D 1
(ii) Q 1
(b) (i) 3 1
(ii) The number of shells filled with electrons are the same/3 1
Bilangan petala terisi elektron adalah sama/3
(c) (i) 2.8.1 1
(ii) Ionic bond 1
Ikatan ion
(iii) 1.No of electron in all shells =11 with nucleus 1
Bilangan elektron dalam setiap petala=11 dan bernukleus 1
2.No of shells = 3 with charges for anion and cation
Bilangan petala=3 dengan cas anion dan kation yang betul
(iv) High melting point // high boiling point/ / conduct electricity when in
liquid or molten // soluble in water 1
Takat lebur/didih tinggi//konduksi elektrik dalam leburan atau larutan//larut dalam
air
Total 9
Question Answer Mark
3 (a) (i) To allow ion pass through and to complete circuit 1
Membenarkan pergerakan ion melaluinya dan melengkapkan litar
(ii) Magnesium electrode. Magnesium is more electropositive than Zinc 1
Elektrod Magnesium Magnesium lebih elektropositif daripada zink 1
(iii) Reduction 1
Penurunan
(b) (i)

Iron ring Silver electrode


Cincin besi Elektrod argentum

AgNO3
1

1.Functional diagram :correct anode and cathode ,shading 1


Rajah berfungsi: anod dan katod betul dan lorekan
2.Label :iron ring ,silver electrode,silver nitrate
Cincin besi dan elektrod argentum,argentum nitrat
(ii) Silver electrode become thinner / grey solid deposited on iron ring 1
Elektrod argentum menipis//enapan kelabu pada cincin
(iii) Ag+ + e Ag 1
(iv) 1.The concentration of silver ion decrease. 1
Kepekatan ion argentumsberkurangan 1
2.Silver ion discharge at cathode to form silver atom
Ion argentum dinyahcas di katod kepada atom argentum
total 10

Question Answer Mark


4 (a) Calcium sulphate : insoluble
Kalsium sulfat :tak terlarutkan 1

Calcium chloride :soluble


Kalsium klorida :terlarutkan 1

(b) (i) Ca(NO3)2 + K2SO4 CaSO4 + 2KNO3

1.Correct formula 1
Formula betul
2.Balance equation 1
Persamaan seimbang
(ii) Precipitation // double decomposition 1
(c) (i) Ag+ + Cl- AgCl 1
(ii) 1.Number of mole AgNO3 = 0.2 X 100 = 0.02 mol 1
1000 1
2. 1 mol Ag : 1 mol Cl

3.Mass of AgCl = 0.02 X (108 +35.5) = 2.87 g 1


(iii) Calcium sulphate 1
Kalsium sulfat
total 10

Question Answer Mark


5 (a) Size of reactant // Concentration // Temperature // Catalyst 1
Saiz bahan//kepekatan//suhu//mangkin
(b) (i) Rate of reaction for Exp II is higher than Exp I // Concentration of H+ 1
ions in experiments II is higher.
Kadar tindak balas eks II lebih tinggi daripada Eks I//
Kepekatan ion hidrogen dalam eks II lebih tinggi
(ii) Increase the temperature of solution (acid) 1
Meninggikan suhu larutan(asid)
(c) 1.Hydrochloric acid is a monoprotic acid; sulphuric acid is a diprotic
acid. 1
Asid hidroklorik adalah monobes dan asid sulfurik adalah dwibes
2.The number of moles of H+ ions in Experiment II is double. 1
Bil mol ion hidrogen dalam eks II adalah dua kali ganda
(d) (i) Zn + H2SO4 ZnSO4 + H2 1+1
(ii) 1.No. of moles of H2SO4 = 25 0.1 // 0.0025 1
Bil. mol H2SO4 1000

2.Volume of gas = 0.0025 24 dm3 // 0.06 dm3// 60 cm3 1


isipadu
(iii)
Mass of zinc / g

Time / s
1
1.axes label with unit
Paksi berlabel dengan unit
2.correct curve shape
Bentuk lengkung betul
1
total 11

Question Answer Mark


6 (a) (i) Heat change / released when 1 mol of silver is displaced from silver 1
nitrate solution by copper
Perubahan/ Pembebasan haba apabila 1 mol argentum disesarkan daripada larutan
argentum nitrat oleh kuprum
(b) The colourless solution turns blue // a grey solid is formed // copper 1
powder dissolves into the solution
Larutan jernih bertukar biru // pepejal kelabu terbentuk // serbuk kuprum larut ke
dalam larutan
(c) 1.Add ammonia solution until in excess 1
Tambah larutan ammonia secara berlebihan
2.Blue precipitate formed 1
Mendakan biru terbentuk
3.Blue precipitate dissolves in excess ammonia solution to form dark 1
blue
olution
Mendakan biru larut dalam larutan ammonia berlebihan membentuk larutan biru
gelap

(d) (i) Mol of Ag+ =50 x 1.0 / 1000 = 0.05 mol 1


(ii) Heat Change = 105000 x 0.05 J//5250 J (with unit) 1
(iii) Temperature change =5250 / (50 x 4.2 ) = 250C (with unit) 1
(e) 1. 12.50C/half 1
2. concentration of Ag+ is half 1
Kepekatan ion Ag+ separuh
3. Number of mol of Ag+ per unit volumeis half 1
Bilangan mol Ag+ per unit isipadu adalah separuh
total 11

Question Answer Mark


7 (a) 1.acid R : hydrochloric acid/ sulphuric acid/ nitric acid. 1
Asid Hidroklorik/asid sulfurik/asid nitrik

2.Acid R is a strong acid// ionize completely in water 1


Asid R adalah asid kuat//mengion lengkap dalam air

3.to produce high concentration of H+ ions. 1


Menghasilkan kepekatan ion hidrogen yang tinggi

4.It will cause the pH value to be lower (smaller). 1


Menyebabkan pH menjadi rendah

5.acid S : ethanoic acid. 1


Asid Etanoik
6.Acid S is a weak acid // Ionise partially in water 1
Asid S adalah asid lemah//mengion separa dalam air

7.to produce low concentration of H+ ions. 1


Menghasilkan kepekatan ion hidrogen rendah
1
8.Hence, pH value is higher (bigger)
pH menjadi tinggi
(b) 1.sodium bicarbonate 1
Natrium bikarbonat
2. neutralise
meneutralkan 1
3.hydrogen ion react with carbonate ion 1
Ion hidrogen bertindak balas dengan ion karbonat

(c) (i) H2SO4 + 2NaOH Na2 SO4 + 2H2O

1.Correct formula reactants and products 1


2.Balance equation 1

Calculation:
Mole of H2SO4

MV = 0.5 X 50
1000 1000

= 0.025 mole 1

Ratio
1 mole of H2SO4 : 2 mole of NaOH 1
0.025 : 0.05 1

Correct Molarity of NaOH with unit:

n= 0.05 X 1000
25

= 2.0 mol dm-3 1


[r: answer without unit]

(ii) 1. 1 mol dm-3/ half 1


1 mol dm-3/ separuh
2.hydrochloric acid is monoprotic acid andsulphuric acid is a diprotic acid 1
Asid hidroklorik adalah monobes dan asid sulfurik adalah dwibes
3.concentration of H+ ion of HCl is half of H2SO4. 1
Kepekatan ion H+ ion dalam HCl adalah separuh drp H2SO4.

Total 20
Question Answer Mark
8 (a)
Picture A Picture B
Gambar A Gambar B
Substance used :propane Substance used :propene 1+1
Bahan yang digunakan :propana Bahan yang digunakan :propana

Saturated hydrocarbon Unsaturated hydrocarbon 1+1


Hidrokarbon tepu Hidrokarbon tak tepu

(b) (i) 1.Propane/propena


\1
3 x 12 x 100 = 36 x 100 = 81.82%
(3x12) + (8 x1) 44
1
2.Propene/ propena

3 x 12 x 100 = 36 x 100 = 85.71%


(3x12) + (6 x1) 42
1
3.Propene have higher percentage of carbon
Propenamempunyaiperatuskarbon yang lebihtinggi
(ii) 1.Correct reactant and product 1
2.Balanced equation 1

C3H8 + 5O2 3 CO2 + 4H2O


1
3.Number of mole propane = 8.5 = 0.2 mol
44 1
4.Ratio
1 mol propane : 5 mol oxygen gas //
0.2 mol propane : 1 mol oxygen
1
5.Volume of oxygen = 1 x 24 = 24 dm3
(c) (i) Dehydration 1
dehydration
Glass wool +
propanol
Wulkaca+ propanol

Propene
Propena

1
2.Functional diagram :clamp,stopper,shading
1
Rajah berfungsi :pengapit,gabus,lorekan
3.Correct labelled : glass wool,propanol,water,heat
Label betul : wul kaca,propanol,air,panaskan
(ii) 1. C3H6 + H2O C3H7OH 1

Catalyst/ mangkin : phosphoric acid / asid fosforik 1+1


Pressure/ tekanan : 60 atm
Temperature / suhu : 300 0C
(any two/mana-mana dua)
(iii) Polypropene 1
polipropena

H H
|
1
CC
| |
H CH3 n
Total 20

Question Answer Mark


9 (a) (i) 1. 2.4 1
2. Period 2 and group 14 1
Kala 2 Kumpulan 14
(ii) 1. Electron arrangement of atom R is 2.6 1
Susunan elektron bagi atom R ialah 2.6
2. An atom W contribute four electrons and each atom R contribute 1
two electrons for sharing
Satu atom W menyumbangkan empat elektron dan setiap atom R
menyumbangkan dua electron untuk dikongsi.
3. One atom W shares 4 pairs of electron with two atom R. 1
Satu atom W berkongsi 4 pasang electron dengan dua atom R.
4.Both atom achieved octet electron arrangement 1
Kedua-dua atom mencapai oktet
5. Two double covalent bond form covalent compound with the 1
molecular formula is WR2
Dua ikatan kovalen ganda dua membentuk sebatian kovalen dengan
formula molekul WR2.

(b) 1. Melting point of copper(II) chloride is higher than 1


tetrachloromethane. //
Melting point of tetrachloromethane is lower than copper(II)
chloride.
Takat lebur kuprum(II) klorida lebih tinggi daripada tetraklorometana.// Takat
lebur tetraklorometana lebih rendah berbanding kuprum(II) klorida. 1

2. Electrostatic force between the ion in copper(II) chloride is


stronger.//
Force attraction between molecule in tetrachloromethane is weaker.
1
Daya elektrostatik antara ion-ion di dalam kuprum(II) klorida adalah lebih kuat.//
Daya tarikan antara molekul dalam tetraklorometana lebih lemah.

3. More heat energy needed to overcome the force.// Less heat is


needed to
overcome the force.
Lebih banyak tenaga haba diperlukan untuk mengatasi daya tarikan.// Tenaga
haba yang lebih rendah diperlukan untuk mengatasi daya tarikan tersebut.
(c) 1.P = lead(II) bromide 1
Plumbum(II) bromide
2.Q= naphthalene 1
Naftalena

carbon

compound
crucible sebatian
mangkuk pijar

Heat
panaskan
1
3.Functional diagram and shading
Rajah berfungsi dan lorekan 1
4.Label as diagram
Label seperti rajah 1
5. A crucible is half filled with solid lead(II) bromide.
Sebuah mangkuk pijar diisi separuh penuh dengan pepejal
plumbum(II) bromida.
1
6. Two carbon electrodes are immersed into solid lead(II) bromide
Dua elektrod karbon dicelupkan ke dalam pepejal plumbum(II)
bromide
7.The carbon electrodes are connected to the bulb and to battery using 1
connecting wire.
Elektrod karbon disambungkan ke mentol dan ke bateri dengan
menggunakan wayar penyambung. 1
8.The observation are recorded.
Pemerhatian dicatat. 1
9.Lead(II) bromide is heated strongly until melt and the observation is
recorded again.
Plumbum(II) bromida dipanaskan dengan kuat sehingga melebur dan
pemerhatian dicatat sekali lagi 1
10.The above steps are repeated by using naphthalene
Langkah di atas diulang dengan menggunakan Naftalena

Total 20

Question Answer Mark


10 (a) 1. Reaction I is not a redox reaction 1
Tindak balas I bukan redoks
2. reasons: no changes in oxidation number in any elements 1
alasan : nombor pengoksidaan setiap unsur tidak berubah
3. Reaction II is a redox reaction 1
Tindak balas II adalah redoks
4. reason: oxidation number of Zn increases from 0 to +2 and Cu 1
reduced from +2 to 0
alasan : nombor pengoksidaan Zn bertambah dari 0 ke +2 dan Cu berkurang
dari +2 ke 0

(b) 1.zinc is more electropositive than iron 1


Zink lebih elektropositif daripada besi
2.zinc is oxidize 1
Zink dioksidakan
3.zinc protect iron from rusting 1
Zink melindungi besi daripada kakisan
4.iron is more electropositive than tin 1
besi lebih elektropositif daripada stanum
5. iron is oxidize 1
besi dioksidakan
6.tin speed up iron rusting
Stanum mempercepatkan kakisan besi 1
(c) 1. Chemical: iron (II) sulphate, bromine water , iron (III) sulphate, 1
zinc powder
Bahan :ferum(II) sulfat ,air bromine ,ferum(III) sulfat,zink

[Change iron (II) to iron (III)]

2. 2cm3 iron (II) sulphate solution is poured into a test tube. 1


3
2cm larutan ferum(II) sulfat dimasukkan ke dalam tabung uji
3. 2 drops Bromine water is added to the solution 1
2 titik air bromine ditambahkan ke dalam larutan
4. the test tube is warmed gently 1
tabung uji dipanaskan
5. Overall equation : 2Fe2+ + Br2 2Fe3+ + 2Br- 1
Persamaan keseluruhan
6.Observation : The colour changes from green to brown 1
Pemerhatian :larutan hijau berubah perang

[Change iron (III) to iron (II)]


1
7. 2 cm3 iron (III) sulphate solution is poured into a test tube.
2 cm3 larutan ferum(III) sulfat dimasukkan ke dalam tabung uji
1
8. Half a spatula of zinc powder is added to the solution
Separuh spatula serbuk zink dimasukkan dalam larutan
1
9.Heat the mixture then, filtered
Campuran dipanas dan dituras
1
10.Overall ionic equation : 2Fe2+ + Zn 2Fe3+ + Zn2+
Persamaan keseluruhan
1
11.Observation : The colour changes from brown to green
Pemerhatian :larutan perang berubah hijau Max:10
Total 20
SKEMA JAWAPAN MODUL B. Paper 3
QUESTION MARK SCHEME MARK
1(a)(i) 3
Able to state one observation correctly

Answer:

A yellow precipitate is formed

2
Able to state one observation less correctly

Sample Answer:

A white precipitate is formed//precipitate

Able to give an idea of observation 1

Sample answer:

Residue is formed

0
No response or wrong response

(a)(ii) 3
Able to make inference correctly.

Answer

Sulphur is formed

2
Able to make inference less correctly

Sample answer:

Yellow solid is formed

Able to give an idea of inference 1

Sample answer:

insoluble

0
No response or wrong response

(b) (i) 3
Able to state the three variables correctly

Sample answer

Manipulated Variable

Temperature of sodium thiosulphate solution

Responding Variable

Rate of reaction// time taken for mark X to disappear

Constant variable

Concentration and volume of sodium thiosulphate solution//


Concentration and volume of hydrochloric acid// size of conical flask

Able to state any two variables correctly 2

Able to state any one variables correctly 1

0
No response or wrong response

3
Able to state the relationship between the manipulated variable
and the responding variable and state the direction correctly

Sample answer

The higher the temperature of sodium thiosulphate solution, the


higher the rate of reaction with hydrochloric acid.

2
Able to state the relationship between the manipulated variable
and the responding variable without stating the direction

Sample answer

The temperature of sodium thiosulphate solution, affects the rate of


reaction with hydrochloric acid

1
Able to give an idea of hypothesis.

Sample answer

Different temperature different rate of reaction

No response or wrong response 0


(d) 3
Able to give the operational definition for the rate of reaction
correctly with the following aspects

1. What you do
2. What you observe

Sample answer
Time taken for the X mark to disappear from sight
2
Able to give the operational definition for the rate of reaction
incompletetly with any one of the following aspects

1. What you do
2. What you observe

Sample answer
Time taken// mark X disappear from sight

1
Able to give an idea of operational definition for the rate of
reaction

Sample answer:
Formation of precipitate

0
No response or wrong response

(e)(i) Able to complete the table correctly 3

Sample answer

Set I II III IV V
Temperature(0C) 28 38 48 58 68
Time (s) 55 36 23 17 13
1/time(s-1) 0.018 0.028 0.043 0.059 0.077
2
Able to complete the table less correctly
Sample answer

Set I II III IV V
Temperature(0C) 28 38 48 58 68
Time (s) 55 36 23 17 13
1/time(s-1) 0.018 0.028 0.04 0.059 0.07
1
Incomplete table

Sample answer

Set I II III IV V
0
Temperature( C) 28 38 48 58 68
Time (s) 55 36 23 17 13
-1
1/time(s )
0
No response or wrong response

(ii) Able to plot graph of temperature against 1/time with the 3


following
aspects:

1 Label axis with unit


2 All five points are transferred correctly.
3. Best straight line

Able to plot graph of temperature against 1/time with the 2


following
aspects:

1 All three points are transferred correctly.


2. Best straight line

1
Able to give an idea to sketch a straight line

0
No response or wrong response

3
(f)(i) Able to state the relationship between the temperature of sodium
thiosulphate solution and the rate of reaction correctly.

Sample answer

The higher the temperature of sodium thiosulphate solution, the


higher is the rate of reaction

Able to state the relationship between the temperature of sodium 2


thiosulphate solution and the rate of reaction less correctly.

Sample answer

The rate of reaction is directly proportional to the temperature of


sodium thiosulphate solution.
1
Able to give an idea of the relationship between the temperature
of sodium thiosulphate solution and the rate of reaction

Sample answer

Rate of reaction is higher// temperature increase

0
No response or wrong response

(f)(ii) 3
Able to predict the time accurately with unit shown on graph

Answer:

1/0.08 = 12.5s

2
Able to predict the time accurately without unit

Answer

12.5

Able to give an idea of predicting time. 1

Sample answer

less than 13s

0
No response or wrong response

(g) 3
Able to explain relationship between base area of conical flask
and amount of sulphur formed correctly.

Sample answer

The smaller conical flask has a smaller base area. Thus the thickness
of the sulphur is increased

Able to explain relationship between base area of conical flask 2


and amount of sulphur formed less correctly

Sample answer

Smaller conical flask, more sulphur formed


1
Able to give an ideaof relationship between base area of conical
flask and amount of sulphur formed.

Sample answer
Thick sulphur formed

0
No response or wrong response

(h) 3
Able to classify all the four ions correctly

Sample answer

Anions Cations
Chloride ion, Cl- Hydrogrn ion,H+
Thiosulphate ion, S2O32- Sodium ion,Na+
2
Able to classify three ions correctly

Able to classify two ions correctly 1

0
No response or wrong response

MARK SCHEME
Questions Mark Scheme Mark
2(a) 3
Able to state the problem statement correctly.
Sample answer

Is bronze harder than pure copper?

2
Able to state the problem statement less correctly.

Sample answers

1. Is bronze harder?
2. To investigate the hardness of copper and bronze

1
Able to give an idea of problem statement.

Sample answer

Metals easily knocked

0
No response or wrong response

Questions Mark Scheme Mark


2(b) 3
Able to state all the variables correctly.
Sample answer

Manipulated variable:Types of materials

Responding variable: Diameter of dent produced

Fixed variable:Height of weight, mass of weight, diameter of


steel ball bearing
2
Able to state any two variables correctly.

1
Able to state any one variable correctly.

0
No response or wrong response

Questions Mark Scheme Mark


2(c) 3
Able to state the relationship between the manipulated
variable and the responding variable with direction correctly

Sample answer

Bronze is harder than copper//


Bronze/copper diameter of the dent smaller/ bigger.

2
Able to state the relationship between the manipulated
variable and the responding variable correctly.

Sample answer

1.The smaller the dent, the harder is the material

2.Type of material affect hardness/ diameter of dent

1
Able to state an idea of hypothesis.

Sample answer

Investigate hardness of metal/copper/alloy/ material

0
No response or wrong response

Questions Mark Scheme Mark


2(d) 3
Able to list all the materials and apparatus correctly.

Sample answers

Bronze block, copper block, weight, steel ball bearing, ruler,


retort stand

2
Able to list the minimum materials and apparatus.

Sample answers
Bronze block, copper block, weight, steel ball bearing.

1
Able to give any material and apparatus

Sample answers

Gangsa/kuprum, pemberat,

0
No response or wrong response

Questions Mark Scheme Mark


2(e) Able to state all the steps of procedure correctly 3

Sample answers

1. A steel ball bearing is taped on surface of copper/ bronze


block.

2. A 1-kg weight is hung at a height of (0.5- 1.0) meter from


the surface of copper/ bronze.

3. The weight is dropped.

4. The diameter of the dent is measured and recorded.


.
5. Repeat the experiment using a bronze/ copper block.

2
Able to state the minimum steps of experiment.

Sample answers

Step 3,4 and 5.

1
Able to state the idea steps of experiment.

Sample answers

Step 3 or 4.
0
No response or wrong response

Questions Mark Scheme Mark


2(f) Able to tabulate the data with the following aspects 2
1 Correct headings
2 List all metals
Sample answer

Blok Diameter (cm/mm)


Copper
Bronze

1
Able to state the idea of tabulation of data.

Sample answer

Block Diameter
Copper
Kuprum

0
No response or wrong response

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