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JAWAPAN KERTAS 1 MODUL 1

1. D 26. B
2. A 27 C
3. B 28 A
4. C 29 D
5. C 30 B
6. D 31 C
7. D 32 A
8. B 33 C
9. A 34 B
10. D 35 A
11. B 36 C
12. A 37 D
13. D 38 C
14. C 39 D
15. D 40 A
16. A 41 A
17. B 42 B
18. B 43 C
19. D 44 C
20. B 45 A
21. B 46 C
22. C 47 B
23. D 48 B
24. A 49 C
25. C 50 D

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1

ANSWER SCHEME
MODUL 1 PAPER 2

No Sample answer Mark


1 (a) (i) The number of protons in the nucleus of an atom. 1

(ii) 17 1
(b) (i) 2.8.1 // 2, 8, 1 1
(ii) Reacts with water to produce hydrogen and metal hydroxide// 1
Reacts with oxygen to form metal oxide.//
Reacts with chlorine gas to produce metal chloride.

(c) Q and R 1
because they have the same proton number but different nucleon
number// same number of proton but different number of neutrons 1
(d) (i) Correct no of shells 1
Correct e arrangement 1

XX
X
X X
S X
X
X
XX

(ii) To fill advertising light bulb 1


Total 9m

2 (a) Element D 1
Atom D has achieved octet electron arrangement / 8 valence
electrons // atom D does not receive, release or share electrons with 1
other atom
A
(b) 1
G
(c) 1
D, B, A, G, E
(d) 1
Use a small piece of A // use a filter paper to dry A //The gas jar
(e) 1
(i) spoon is quickly placed into a gas jar

(ii) 4 A+ O22 A2O 1


(iii) 4 moles of A : 2 moles of R2O
1
1 moles of A : 0.5 moles of R2O

Mass of R2O = 0.5 x [2(7) + 16 ] 1

= 15 g
[r: answer without unit]

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2

Total 9m

3 (a) Boron oxide 1


(b) In pure copper, the atoms can slide easily. 1
Dalam kuprum tulen, atom-atom boleh mengelungsur dengan
mudah.

In bronze/alloy, tin atoms/foreign atoms disrupt the orderly


arrangement of copper atoms//layers of atoms cannot slide easily 1

Dalam aloi/bronze atom asing atau atom timah menggangu susunan


teratur atom kuprum.//Lapisan atom tidak dapat bergelungsur
dengan mudah

(c) (i) 1
H Cl

| |

CC

| |

H H

(ii) Do not rust//oxidised 1

(d) Reinforced concrete 1


Konkrit yg diperkukuhkan

(e) (i) 2NH3 + H2SO4 (NH4)2SO4


Correct formulae 1
balance 1
(ii) urea 1

% of N in CO(NH2)2 = 14x2 / (12+16+(14x2)+4) x 100

= 46.67% 1

% of N in (NH4)2SO4 = 14x 2 / (14x2)+6+32+(16x4)

= 21.5% 1

Total 11 m

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3

4 (a) (i) Chemical energy to electrical energy 1

(ii) Electrical energy to chemical energy 1

(b)

(c) (i) Zn + Cu2+ Zn2+ + Cu

Correct ionic formula 1


Balance equation 1

(d) (i) become thicker


1
(ii) become thinner 1

(e) (i) No change // blue solution remain unchanged 1

(ii) The rate of copper ionises at anode is the same 1


as the rate of copper ion discharged at cathode
number/concentration of Cu2+ ion in the solution remain 1
Total 10 m

5 (a) (i) Salts is an ionic compound formed when hydrogen ion in an acid 1
is replaced by metal ion or ammonium ion.
(ii)

White solid turns brown when hot and yellow 1+1


when cold
Pepejal putih bertukar perang semasa panas
dan kuning semasa sejuk
Black solid turns brown
Pepejal hitam bertukar perang

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4

Lime water remain unchanged


Air kapur tidak berubah

Lime water turns chalky


Air kapur menjadi keruh

(b) (i) Pb(NO3)2 + Na2CO3 Pb CO3 +2NaNO3

Correct formula of reactant and product 1


Correct balancing 1

(ii) Double decomposition reaction 1

(iv)
Filter the solution mixture using filter funnel and filter paper 1
Rinse the residue 1

c 1. Add 2 cm3 of KI/NaI solution into the test tube contain 2 cm3 of 1
Pb(NO3)2 solution and the test tube is shaken

2.Yellow precipitate formed indicates the presence on Pb2+ ion 1

Total 11 m

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5

6 (a) Hidrogenation // Addition 1

(b) C4H8 + H2 C4H10 1

(c) 1. Put 2 3 drops of bromine into two different test tubes 1


2. Fill 2 cm3 of but-1-ene and 2 cm3 of hydrocarbon Y in the test
tubes with stopper.
1
3. But-1-ene decolourise brown bromine water but in 1
hydrocarbon Y remain unchanged

or

1. Put 2 3 drops of acidified potassium manganate(VII)


solution into two different test tubes
2. Fill 2 cm3 of but-1-ene and 2 cm3 of hydrocarbon Y into the
test tubes with stopper.
4. Shake the test tubes
3. But-1-ene decolourise purple acidified potassium
manganate(VII) solution but in hydrocarbon Y purple colour
remain unchanged

(d) Able to calculate number of mole with unit 1


0.05 mol

Able to calculate mass with unit


Ratio:
1 mol Y 4 mol CO2
0.5 ? 1

0.5 x 4
1
= 2 mol

Or

1 mol Y : 4 mol CO2


0.5 mol : 2 mol CO2

Mass of CO2 1
2 x 44 g // 88 g
[r: answer without unit]

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6

(e) Isomer

Total 11 m

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7

7 acid P : hydrochloric acid/ sulphuric acid/ nitric acid. 1

Acid P/ hydrochloric acid/ sulphuric acid/ nitric acid is a strong acid// 1


ionize completely in water

to produce high concentration of H+ ions. 1

It will cause the pH value to be lower (smaller). 1

acid Q : ethanoic acid. 1

Acid Q/ ethanoic acid is a weak acid // Ionise partially in water 1

to produce low concentration of H+ ions.


1
Hence, pH value is higher (bigger)
1
NH4OH 1

neutralize the acid 1


secreted by ant 1

H2SO4 + 2NaOH Na2 SO4 + 2H2O

Correct formula reactants and products 1


Balance equation 1

Calculation:
Mole of H2SO4

MV = 0.5 X 50 1
10001000

= 0.025 mole 1

Ratio
1 mole of H2SO4 : 2 mole of NaOH 1
0.025 : 0.05

Correct Molarity of NaOH with unit:

n= 0.05 X 1000
25

= 2.0 mol dm-3 1


[r: answer without unit]

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8

mol dm-3/ halved / decrease halved / less halved 1


hydrochloric acid is monoprotic/monobasic acid. 1
sulphuric acid is a diprotic acid / dibasic acid 1
Total 20 m

8 (a) 50
55 1
1. average rate =

2.= 0.909//0.91 cm3 s-1


[r: answer without unit]
1

(b)

Energy
Experiment II

Ea
2H2O2 Ea

2H2O + O2
Experiment III

1.y axis labeled energy 1


2.both curve drawn correctly with label 1
3.energy level labeled with reactant and products [a: exo or endo] 1
4.activation energy labeled correctly 1

(c) Experiment I and Experiment II

1. Rate of reaction of experiment II is higher than experiment 1


I
2. Experiment II use higher concentration of hydrogen 1
peroxide
3. the number of Hydrogen peroxide molecules/reactant
1
particles per unit volume in experiment II is higher.
4 .Frequency of collision between Hydrogen peroxide
molecules of experiment II become higher 1
5. Frequency of effective collision between Hydrogen
peroxide molecules/reactant particles of experiment II
become higher 1

Experiment II and Experiment III


6. Rate of reaction of experiment III is higher than experiment

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9

II 1
7. Catalyst that is Manganese(IV) oxide present in experiment
III
8. Manganese(IV) oxide lower the activation energy of the 1
reaction in experiment III
9. More colliding hydrogen peroxide molecules easily
overcome the lower activation energy in experiment III 1
10. Frequency of effective collision between Hydrogen
peroxide molecules of experiment III become higher 1

1
(d) 1. number of mole of H2O2 = 0.5 x 30 // 0.015 1
1000

2. 2 mole of H2O2 produce 1 mole of O2 1

3. number of mole of O2 = 0.015 // 0.0075 1


2

4.volume of O2 = 0.0075 x 24 dm3 //0.18 dm3 //180 cm3 1


[r: answer without unit]

Total 20 m

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10

9 (a) (i) Ionic compound: W and X // covalent compound : V and X 1+1

(ii)
Ionic compound

w w
x

1
1. Correct charge of ion
1
2. correct number of electron in the shell for each ion
1
3. contain nucleus

Explanation

Ionic compound

Electron arrangement of an atom of element W is 2.8.1


2 Atom W donates one electron each to achieve the stable electron
arrangement which is 2.8
2 W ion, W+ is formed
Electron arrangement of atom X is 2.6
Electrons from atom W are transferred to an atom of X
Atom X receives TWO electrons to achieve the stable electron
arrangement which is 2.8.
W ion, X2-is formed
The W ion, W+ and X ion X2- , formed are attracted to one another
to form an ionic compound, W2X
The strong electrostatic forces between the opposite-charged ions
is called ionic bond.
Any 7 points

7
marks

1 mark
Any physical state

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11

x v x

Covalent bond

Atom V has four valence electrons, with an electron arrangement


of 2.4
It needs four more electrons to achieve the stable electron
arrangement
One atom of X contributes 2 electrons for sharing
Atom Xhas SIX valence electrons, with an electron arrangement of
2.6
It needs two more electron to achieve the stable electron
arrangement
One atom of v share a pair of electrons with two atoms of x
Covalent compound of VX2 is formed
7
marks

Any physical state 1 mark

1. correct number of electron for each atom combined


2. contain nucleus
3. correct the position ( share the electron + shell)

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12

bi Substance Y is glacial ethanoic acid // gas hydrogen chloride 1


1
Solvent Z is tetrachloromethane//ethanol//any organic solvent

ii Solution I

Substance Y dissolve in water 1


1
The ions in water dissociate and move freely

Solution II

Substance Y do not dissolve 1


1
Exist as neutral covalent molecules
Max 5
Total 20 m

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13

Question No Mark Scheme Marks


10 (a) elementsC : H :O
mass/g64.9 : 13.5 : 21.6
no of mole5.4 : 13.5 : 1.35 1
ratio4 : 10 : 1 1

C4 H9OH 1
butanol 1

(b) From glucose:

Process
Fermentation 1

Step
50 cm 3 glucose solution is added with yeast into a conical flask 1
Left for 3 days
The product is then purified by fractional distillation 1

Chemical equation
C6H12O6 2C2H5OH + 2CO2 1

From ethene:
Process
Hydration // addition reaction 1

Step
A mixture of ethene and water vapour/ steam are passed over
phosphoric acid as the catalyst 1
1
At temperature of 300 C and pressure of 60 atm 1+1

Chemical equation
C2H4 + H2O C2H5OH
1

(c) Name any suitable alcohol 1


Name any suitable carboxylic 1
Mix alcohol and carboxylic acid (same volume) 1
In round bottom flask 1
Add a few drops of sulphuric acid concentrated 1
Heat the mixture in bath bath under reflux 1

Total 20 m
END OF MARK SCHEME

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MODULE 1 PAPER 3 MARKING SCHEME

Q ANSWER SCORE
1 a [able to measure diameter of dents accurately and correctly]
Sample answer:
[able to state any two variables correctly] 2
[able to state any one variable correctly] 13
Copper : 2.0,or
No response 2.1, 2.1 response
wrong 0
Brass : 1.9, 1.8, 1.9

[able to measure diameter of dents without two decimal place] 2


Q ANSWER
[able to state four diameter of dents correctly] SCORE
1
1 e [able to state or
No response operational definition correctly]
wrong response 0
Sample answer
3
Smaller dent is produced when 1kg of weight is dropped on the block.
Q ANSWER SCORE
1 b [able
[able to
to construct table with
state operation correct
definition label
less and unit]
correctly]
Sample
Sample answer:
answer
2
Type ofdent
Smaller blocks Diameter
is produced of dentsis(cm)
when weight dropped on the blockAverage diameter of dents
llllll (cm) 3
2.002.102.10 2.06
Copper
[able to state operation definition]
1.901.801.90 1.87
Brass answer
Sample
1
The
[ableharder block has
to construct the atable
smaller dentcorrect label or unit]
without 2
[able to construct idea of table] 1
No response or wrong response 0

1Q f [able
ANSWERto state observation correctly] SCORE
1 Sample
[able to answer
state hypothesis correctly]
c 3
Sample answer
The average diameter of dent become smaller
[able to state observation less correctly] 3
When brass is used, the diameter of dent is smaller //
Sample answer
When copper is used, the diameter of dent is bigger
2

The
[abledent become
to state smallerless correctly]
hypothesis 2
[able
[able to state idea of
to state idea of observation]
hypothesis] 1
Sample answer
No response or wrong response 0

Small dent
Q ANSWER SCORE
1 d [able to state all the variables]
Q Sample answer
ANSWER SCORE
1 g [able to state inference correctly]
Sample answer
1. Manipulated variable : type of materials / blocks// copper and brass 3
3
2. Responding variable : diameter / size of dents
Brass3.isFixed variable
the harder : size
than / diameter and mass of steel ball bearing// height of
copper
the weight // mass of the weight
[able to state inference less correctly] 2

21

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Sample answer

Brass is the harder


[able to state idea of inference]
Sample answer
1

Brass is the hard // copper is soft


No response or wrong response 0

h [able to state situation correctly]


Sample answer
3
Iron bar rust , steel bar do not rust

[able to state situation less correctly]


Only 1 bar stated 2
[able to state idea of situation]
1

No response or wrong response 0

i 1.65 cm 3
Antara 1.55 hingga 1.75 cm 2
Antara 1.45 hingga 1.55cm // 1.75 hingga 1.85 cm 1
Wrong responr // no respon 0

j [able to classify all correctly]


Alloy Pure metal
Duralumin Tin
Pewter Gold
Manganese
Magnesium 3

[able to classify 5 correctly] 2


[able to classify 4 correctly] 1
Other respon 0

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Question Rubric Score
Able to give the statement of the problem correctly

Sample answer : 3
How does the temperature of sodium thiosulphate solution affect the rate
of reaction?
Able to give the statement of the problem incorrectly

3(a) 2
Sample answer :
How does the temperature of solution affect the rate of reaction?
Able to give an idea of statement of the problem

1
Sample answer :
To determine the rate of reaction by the temperature of solution
No response or wrong response 0

Question Rubric Score


Able to state all variables correctly

Sample answer :
Manipulated variable :The temperature of sodium thiosulphate solution
Responding variable : Rate of reaction//The time taken for the X mark to 3
disappear
3(b) Constant variable : Volume and concentration (sodium thiosulphate) /
(hydrochloric acid) // sodium thiosulphate // acid//
size of conical flask
Able to state any two variables correctly
Able to state any one variable correctly 2
No response or wrong response 1
0

Question Rubric Score


Able to state the relationship between the manipulated variable and the
responding variable correctly

3
Sample answer :
The higher the temperature of sodium thiosulphate solution , the higher the
rate of reaction
Able to state the relationship between the manipulated variable and the
responding variable incorrectly
3(c) 2
Sample answer :
The rate of reaction increases when the temperature of solution increase
Able to state an idea of hypothesis

1
Sample answer :
The temperature of reactant affect the rate of reaction
No response or wrong response 0

Question
Rubric Score

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Able to state
give the
fourlist
steps
of the
of procedures
apparatus and
correctly
materials correctly and
completely 2
Steps 2, 4, 5, 8
Answer:
Able to state two steps of procedures correctly
1
Apparatus:
Steps 2, 5 3
conical flask, measuring cylinder, thermometer, stopwatch, white paper,
No response or wrong response 0
wire gauze, tripod stand, Bunsen bunner

Question Rubric Score


Material:
Able to exhibit the tabulation of data that includes the following
[0.1 1.0] mol dm-3 sodium thiosulphate solution,
information.
[ 0.1-1.0] mol dm-3 hydrochloric acid
Able to give the list of the apparatus and materials correctly but not
completely
1. Headings
2. With unit
Answer:
3(d) Sample answer : 22
Apparatus:
Temperature/
conical oCTime/s
flask, thermometer, stopwatch, white paper, Bunsen bunner
30
35
Material: 40
Sodium thiosulphate
45 solution, hydrochloric acid
3(f)
Able to give
50 two materials and at least one apparatus
Able to tabulate the data incompletely
Sample answer :

1. Titles without unit


Material: 1
Sodium thiosulphate solution, hydrochloric acid
Sample answer : 1
Apparatus:
[container] Temperature Time
No response or wrong response 0

Question No response given / wrong


Rubricresponse Score 0
Able to state all procedures correctly

Sample answer : END OF MARKING SCHEME


1. Draw an X on a white paper.
2. Pour [20-100] cm3 of [0.1 1.0] mol dm-3 sodium thiosulphate
solution into a conical flask.
3. Record the temperature of solution.
4. Place the conical flask on the X.
5. Pour [5 10] cm3 of [0.1 1.0] mol dm-3 hydrochloric acid 3
3(e) solution.
6. Swirl the conical flask and start the stopwatch immediately.
7. Stop the stopwatch when the X is no longer visible. Record the
time taken.
8. Repeat steps 2 to 7 using 35oC, 40oC, 45oC and 50oC temperature
of sodium thiosulphate solution.

65

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