Académique Documents
Professionnel Documents
Culture Documents
Q1 CORRECT ANSWER: E
This question tests students on the understanding of ideal gas behavior and the
application of the ideal gas equation of state, as well as the mass, mole and molar mass
relations. First step is using the ideal gas equation of state to calculate the number of
moles of the unknown gas as follows:
n = (PV)/(RT) = (98130/101325)(0.125)/(0.08205)(293.15) = 5 x 10-3. The molar mass
can be calculated from the relation: M = 0.1727/n = 0.1727/(5 x 10-3) = 34.3 The
unknown gas is then identified as O2 which has a molar mass of 32, nearest to the
calculated value.
Common mistakes here are: using the incorrect values for pressure, volume, the R
constant, and/or temperature.
Q2 CORRECT ANSWER: D
The stoichiometry of the reaction shows that 1 mole of CO2 will be absorbed by 1 mole
of Li2O. So the number of moles of CO2 that can be absorbed by 1 kg of Li2O is
1000/29.8 = 33.56, where 29.8 is the molar mass of Li2O. The volume of CO2 absorbed
can then be calculated using the ideal gas equation of state as follows:
(33.36)(0.08205)(298.15)/(1) = 821 L. Again, common mistakes students make here are
the use of incorrect values of the R constant, and the use of incorrect units for pressure
and volume.
Q3 CORRECT ANSWER: C
This question tests knowledge of reaction stochiometry and manipulation of chemical
formulae.
First calculate the number of mols (n) of Ag+.
The molar mass (g mol–1) of MCl3 = mass (g)/ n (mols) = 0.100 g / 5.5 x 10–4 mols =
181.8 g mol–1.
The group 5A element with a molar mass closest to 75.5 g mol–1 is arsenic (74.9 g mol–1).
(A), (B), (D) and (E) are incorrect because they are the other group 5A elements.
Q4 CORRECT ANSWER: E
From the stoichiometry of the equations, one mole of Na2SO4 should ideally yield two
moles of NaHCO3. However, since there is only a 90% yield for each step, for every
mole of Na2SO4, there will only be 0.93×2.0 = 1.458 moles of Na2SO4 yielded.
The molar mass of Na2SO4 is 142g/mol, hence 100kg is equivalent to 704.23 moles of
Na2SO4. This will yield 1.458×704.23 = 1026.76 moles of NaHCO3. Since the molar
mass of NaHCO3 is 84g/mol, the final amount NaHCO3 yielded in mass is
0.084×1026.76 = 86.2 kg.
Q5 CORRECT ANSWER: D
Most of the volume of an atom IS empty space. Alpha particles are only deflected back
if they hit the nucleus.
Q6 CORRECT ANSWER: E
None of the statements are true. The mass of a proton or a neutron is not exactly 1
a.m.u. Hence the mass number would not be equal to the mass of the nucleus, also an
atom of a stable isotope actually weighs less than the sum of the masses of
electrons, protons and neutrons from which it is built. Note also, that there are actually 3
isotopes of the hydrogen atom ( 11 H, 21 H, 31 H ).
Q7 CORRECT ANSWER: A
According to the Aufbau principle, in the process of building up an atom, electrons are
filled in the atomic orbitals according to this order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d,
5p, 6s, 4f, 5d, 6p, 7s…
Q8 CORRECT ANSWER: C
Ionization energies generally increase as we move up and to the right on the periodic
table. Be is above Mg and to the right of Li. Second ionization energies are greater than
the first ionization energies as a rule, since we are removing an electron from an atom
which already has a charge of +1.
(A), (B), (D) and (E) are wrong. The student does not have a clear idea of first and/or
second ionization energies.
Q9 CORRECT ANSWER: A
In an ionic bond, one atom has donated electron(s) to the other. The two resulting ions
have opposite charges and form an ionic bond based on their electrical attraction for each
other.
(B) In a polar covalent bond, two atoms share electrons, although they share
unequally.
(C) Electrons are not donated in hydrogen bonds.
(D) In a nonpolar covalent bond, two atoms share electrons equally.
(E) Obviously incorrect.
(A) Most students will choose this answer. We are talking about the electron
geometry in this question, so the 3 lone pairs of electrons have to be taken into
account. If the question asked for molecular geometry, then it would be linear
shape.
(B) The student did not take into account 2 bond pairs.
(D) A total of 5 pairs of electrons for triiodide. Trigonal pyramidal is a shape for
molecules with a total of 4 pairs of electrons.
(E) A total of 5 pairs of electrons for triiodidie. Octahedral is a shape for molecules
with a total of 6 pairs of electrons.
Because no lone pair exists, choices (B) and (C) should be ruled out.
The molecule consists of three oxygen and a sulfur atoms, therefore, (D) and (E) cannot
be the answer.
(B) This will be correct if Br has no lone pairs, and have five covalent bonds
with the F atoms.
(C) Student is not familiar with VSEPR theory. This structure does not exist in
VSEPR theory.
(D) and (E) Student is probably making a random choice.
(A) Student realizes correctly that VSEPR electron pair geometry is trigonal
bipyramidal but does not realize where to place the lone pair. (B) is more
favourable as lone pair takes up more space and is more favourable in the
equatorial position.
(C) Student got the VSEPR electron pair geometry wrong.
(D) Student mistakenly thinks that there is no lone pair at the central atom.
(E) Student is probably making a random guess.
= 36.7 dm3
(A) Incorrect because 8.3143 J K−1 mol−1 was used for the gas constant, R.
(C) Incorrect because 1 mol of N2 was used in the calculation.
(D) Incorrect because the temperature was not converted to kelvin, K.
(E) Incorrect because 1.00 × 105 Pa was used for the units of pressure, p, in the
calculation.
Q19 CORRECT ANSWER: A
The volume of an ideal gas is given by V0 = nRT/P. The new volume at 0.5T and 2P is V1
= nR(0.5T)/(2P). The ratio between V0 and V1 gives V1 = 4V0.
(B) and (C) Student may have misplaced or omitted in the equation, the -2 oxidation
state change
(D) and (E) Student did not understand the molar concept as applied to electronic
charges.
In order to obtain the spontaneous direction, the reaction with the more negative half-cell
potential must be subtracted from the reaction with the more positive half-cell potential.
The E0cell must be positive in order for the reaction to be spontaneous. This is because the
ΔG will be negative (ΔG0 = –nFE0cell).
(B) Incorrect because it is the answer that would be obtained if the half-cell potential
for the Co/Co2+ system was divided by the number of electrons (2). The number
of electrons transferred in the reaction does not affect the potential.
(C) Incorrect because it is simply the difference in potential between the two written
reactions (–0.28 – –0.34).
(D) Incorrect because it is simply the difference in potential between the two written
reactions and it is negative.
(E) Incorrect because the sign is incorrect.
(A) Doubling of A will not double the rate of reaction, it will only push the
equilibrium of the reversible reaction to the right, thus forming more X2.
(B) Doubling [B] will double rate of reaction, but by doubling [A] and [B], the rate of
reaction will not increase by 8 times.
(C) There cannot be intermediates (A2) as part of the rate equation.
(E) The students may be guessing the answer.
(A) The student made a mistake at the end where he forgets to square the partial
pressure of NO2, therefore (2/3)/(1/3) = 2
(C) The student doesn’t know that when 1 mole of N2O4 is 50% dissociated, he will
get 1 mole of NO2. Using 0.5 mol as the amount of NO2, (0.5)2/(0.5) = 0.5
(D) The student balanced the equation to be 1 N2O4 : 2 NO2.
Upon dissociation, he gets 0.5 mole of N2O4 : 3 NO2.
Using the equation for equilibrium constant, he gets (3)2/(0.5) = 18
(E) The student balanced the equation to be 1 N2O4 : 2 NO2.
Upon dissociation, he gets 0.5 N2O4 : 2.5 NO2.
ln[A] = −kt + C
ln
[A] = − kt .
[A]0
Q34 CORRECT ANSWER: D
When a reaction is described as being zero order with respect to a particular reactant, it
means the rate of reaction is independent of that reactant concentration. Hence choice (D)
is correct.
CH3
2 1
H3 C 4 3 CO2H
Br
(A) Incorrect because molecular weight does not correlate with basicity.
(B) The hydrogen atoms in the ethyl group cannot hydrogen bond as they are on
carbon which is not electronegative – but even if they did, would that affect the
nitrogen lone pair?
(D) There is no delocalization in either molecule – no pi-bonds
(E) This choice is not relevant
I Will not because the product will have an extra carbon atom
C N CH2NH2
II Will not give any product because the ammonia is a nucleophile and cannot react
with benzene; in addition, in the presence of sulfuric acid, the ammonia will be
converted to ammonium sulfate
III Will give aminobenzene. This is a standard methjod to reduce nitro groups to
make amino groups
IV The compound shown will undergo hydrolysis upon heating with sodium
hydroxide to give aminobenzene and sodium acetate.
(A) α-proton of ketone is more acidic compared with normal aliphatic protons, but
less than that of 1,3-diketone.
(B) β-proton of ketone is not acidic.
(D) The same solution with Choice A.
(E) Students may be making a wild guess.