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DPT-1:

1. The general valence shell electronic configuration of f-block elements is

a) (n 1)f1 14 (n 1) d1 or 0 ns2 b) (n 2)f1 14 (n 1) d0 or 1 ns2
c) (n 3)f1 14 (n 1) d1 or 2 ns2 d) (n 1)d1 to 10 (n 1)s2

2. The position of element with atomic number 44 in the periodic table is

a) 8 th group, 4th period b) 6th group, 5th period
c) 8th group, 5 th period d) 6th group, 4th period

3. If the ionic radii of K+ and F are nearly same i.e. 1.34 A0 , then the atomic radii of K and
F respectively are
a) 1.34 A0 , 1.34A0 b)0.72 A0 , 1.96A0 c) 1.96 A0 , 0.72 A0 d) 1.96 A0 , 1.34A0

4. The first ionisation potentials of four consecutive elements present in the third period of
the periodic table are 5.98 eV, 8.15 eV, 11.0 eV and 10.4 eV respectively. Which one of the
following is the first ionisation potential of phosphorus (in eV) ?
a) 5.98 b) 8.15 c) 10.4 d) 11.0

5. For four elements the IP2 curve is shown. In the graph the elements represented by A, B, C
and D are

D
IP2 B

A C

Atomic no

1) Na, Mg, Al, Si b) Mg, Al, Si, P c) Al, Si, P, S d) Si, P, S, Cl

6. Which of the following is exothermic process ?

N( g) +e - N(-g ) O(-g) +e- O 2- ( g) F( g) +e - F - ( g ) Na( g) Na +( g) +e -
a) b) c) d)

7. I.P. and E.A of Cl are 13.0ev and 4.0 ev respectively E.N of Cl will be
a) 4.03 b) 2.5 c) 3.5 d) 3.03

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8. The bond energies of H H, X X and H X are 104 K.Cal, 38 K.Cal and 138 K.Cal
67 = 8.18



respectiely the electronegativity of X is
a) 3.0 b) 3.5 c) 3.8 d) 1.7

9. Assertion (A) : Electronegativity of phosphorous is greater than that of sulphur

Reason (R) : Phosphorous has stable half - filled configuration in 3p orbitals
a) A and R are true and R is the correct explanation of A
b) A and R are true but R is not correct explanation of A
c) A is true R is false d) A is false R is true

10. The order of acidic nature of oxides

C l 2O7 >SiO2 >P4O10 >SO3 C l 2O7 >SO3 >P4O10 >SiO2
a) b)
SiO2 >P4O10 >SO3 >C l 2O7 SO3 >C l 2O7 >P4O10 >SiO2
c) d)
11. Three elements X, Y and Z belong to the same period. Their oxides are acidic, amphoteric
and basic respectively. The order of these elements in the periodic table is
a) X, Y, Z b) Y, Z, X c)X, Z, Y d) Z, Y, X

12. The strongest oxiding agent and the strongest reducing agent (in aqueous solution) are
a) Cs, F b) F, Cs c) F, Li d) F, O

13. Covalency of P in P4 is
a) 1 b) 2 c) 3 d) 4

14. An atom of an element which exhibits pseudo inert gas configuration is

a) Pd b) Zn2+ c) Ag+ d) Pd (or) Zn2+ (or) Ag+
15.

X Where X is
% ionic character

1 2 3
EN difference
a) 25 b) 35 c) 50 d)
75

16. Which of the following is least ionic

a) CaF2 b) CaCl2 c) CaBr2 d) CaI2

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17. The total energy holding the ion pair in the crystal can be calculated by using the formula
(N = Avagadro Number)
AZ +Z - e2 Be2 AZ +Z - e 2 Be 2
-N +N n -N + n
r r r r
a) b)
+ - 2
AZ Z e B AZ +Z - e 2 NBe 2
- +n - + n
r r r r
c) d)

18. Set I (Position of ion in the unit cell) Set II (No. unit cells sharing the ion)
1) Body centre A) 8
2) Face centre B) 4
3) Edge of a face C) 2
4) Corner D) 1
Correct match is
1 2 3 4 1 2 3 4
a) D C B A b) D B C A
c) D A B C d) D C A B
19. Statement I : Glucose is a polar covalent substance hence soluble in water.
Statement II : Iodine is a non polar covalent substance hence soluble in C6H6.
Statement III : Camphor is soluble in CCl4.
Statement IV : Fructose is Insoluble in C2H5OH.
Correct statement is / are
a) Only I, II & III b) Only I, III & IV c) I, IV only d) All

20. According to VBT, the expected bond angles in NH3 and H2O respectively are
a) 1070, 900 b) 900, 1040.30| c) 1070, 1040.30| d) 900, 900

21. The formal charge of second nitrogen in the following resonance structure is

N(1) N(2) O

a) 2 b) 0 c) 1 d) +1

22. In the following pair of species the central atom undergoes dsp 2 hybridisation and the
shape of the species is square planar

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a) XeF and PdBr 2- b) XeF4 and [Ni(CN)4]2-
4 4
2- 2- d) PdBr42- and SiCl4
c) PdBr4 and [Ni(CN)4]

23. In which of the following reactions, there is change in hybridization

A) BF3 + F BF4 B) H2O + H+ H3O+

+ H + NH + D) C H + Cl C2H4Cl2
C) NH3 4 2 4 2
a) A, B, C, D b) A, B, C c) B, D d) A, D
1) B 2) C 3) C 4) D 5) B 6) C 7) D 8) C 9) D 10) B
11) D 12) C 13) C 14) A 15) D 16) D 17) C 18) A 19) A 20) D
21) D 22) C 23) D

DPT- 2:

I 3-
1. The shape of ion is
a) linear b) planar tringle c) tetrahedral d) angular

2. The inter atomic distances of H2 and Cl2 molecule are 0.74A0 and 1.98A0 respectively . The
bond length of HCl is
a) 2.72A0 b) 2.48A0 c) 1.36A0 d) 1.24 A0

3. Average bond energy of C H bond is 416 kJ/mole which of the following is correct
CH 4 + 416 Kj C + 2 H 2 CH 4 C + 4 H + 416 KJ
a) b)
CH 4 +1664 KJ C + 4 H CH 4 C + 4 H +1664 KJ
c) d)
4. The bond angle that would result maximum dipolement for the triatomic molecule XY2, is
a) 900 b) 1200 c) 1500 d) 1800

5. The percentage of ionic character is 12.33 % Bond length is 1.25A0 , the dipole moment is
a) 1D b) 2.2D c) 0.74D d) 0.1D

6. Which of the following species does not have resonating structure ?

CO2 C6 H 6 SiO2 NO3-
a) b) c) d)

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7. The molecular orbital shown in the diagram is

p* p s 2 Pz s * 2 Pz
a) b) c) d)

8. The species having highest bond order is

O2 O2- O2+ O22-
a) b) c) d)

9. The % composition of four hydrocarbons is as follows.

i) ii) iii) iv)
%C 75 80 85.7 92.3
%H 25 20 14.3 8.7
The data illustrates the law of
a) constant proportions b) conservation of mass
c) multiple proportions d) Reciprocal proportions

10. 15 cc of gaseous hydrocarbon required 45 cc of oxygen for complete combustion. If 30 cc of

CO2 is formed, the formula of the gaseous compound is
a) C3 H6 b) C2H2 c) C4 H10 d) C2H4

11. 0.5 gm of an organic compound on combustion produced some gaseous products, which
were passed into caustic potash solution. The increase in weight of potash solution was
found to be 1.5 gms. The percentage of carbon in the compound is nearly.
a) 82 % b) 40 % c) 60 % d) 75 %

xP4 + yOH - + zH 2O aPH 3 + bH 2 PO2-

12. then (x + y + z) -(a + b) is
a) 3 b) 4 c) 7 d) 12

13. One gram - mole of CO2 occupies maximum volume at

a) 273K, 1atm b) 273K, 2atm c) 546K, 1atm d) 546K, 2atm

14. In acidic medium, the number of moles of ferrous oxalate (FeC2O4) oxidised by one mole
of each KMnO4 and K2Cr2O7 are respectively x and y. The relation between x and y is
a) x = y b) x < y c) x > y d) x + y = 1

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15. On complete calcination of 10 grams of Ca CO3, 4 gms of CO2 gas is evolved. The
percentage purity of CaCO3 is
a) 9.09% b) 92.12% c) 88.4% d) 90.9%

16. 10g of Calcium carbonate contains

a) 10 moles of CaCO3 b) 1 gram atom of Calcium
c) 6x1022 atoms of Calcium d) 0.1g of Calcium

17. 0.2 mole of KMnO4 in acid solution oxidises 0.5 mole of AO2 to An+. Here n is
a) 1 b) 3 c) 5 d) 7

18. Four grams of hydrocarbon (CxHy) on complete combustion gave 12 grams of CO2. What
is the empirical formula of the hydrocarbon ?
a) CH3 b) C4H9 c) CH d) C3H8

19. A mixture of Mg metal and Magnesia weighing 20 gm when treated with HCl produced
4.48 litre of H2 at S.T.P. then what is weight percent of Mg in the mixture?
a) 50% b) 64% c) 36% d) 24%

20. In the dichromate titrations the end point is recognised by the formation of ---------
colouration in the presence of indicator -------------.
a) Intense blue , starch solution b) Pale pink , self indicator
c) pale pink , methyl orange d) Intense blue, diphenyl amine

21. Assertion (A) : Boiling point of water is greater than that of hydrogen fluoride
Reason (R) : Molecular weight of water is 18 and that of hydrogen fluoride is 20
a) Both A and R are true, and R is correct explanation of A
b) Both A and R are true, and R is not the correct explanation of A
c) A is true but R is falsed) A is false but R is true

22. Assertion(A): Bond energy of F2 is less than that of Cl2

Reason( R ) : Bond length of F2 is less than that of Cl2
a) Both A and R are true, R properly explain A
b) Both A and R are true, R does not explains A
c) A is true, but R is false d) A is false, but R is true

23. Assertion (A) : Dipolemoment of H2S is greater than that of H2O.

Reason (R): Bond angle in H2S molecule is less than that of H2O.

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a) A and R are true and R is the correct explanation of A.
b) A and R are true and R is not the correct explanation of A.
c) A is true, R is false. d) A is false, R is true.

24. Assertion (A) : Para hydroxy benzaldehyde has a lower boiling point than ortho hydroxy
benzaldehyde.
Reason (R): Ortho hydroxybenzaldehyde has intramolecular hydrogen bonding.
a) (A) and (R) are true and (R) is the correct explanation of (A).
b) (A) and (R) are true but (R) is not the correct explanation of (A).
c) (A) true, (R) false d) (A) false, (R) true

25. Assertion (A) : In a redox reaction, the oxidation number of oxidant decreases while that
of reductant in creases
Reason ( R) : Oxidant gains electron (s) and reductant loses electron (s)
a) Both A and R are correct. R is the correct explanation of A.
b) Both A and R are correct. R is the not correct explanation of A.
c) A is true, but R is false d) A is false, but R is true

26. Assertion (A) : The equivalent weights of nitric acid and crystalline oxalic acid are same
Reason (R) : The basicity of nitric acid and oxalic acid are same
The correct answer is
a) A and R are true and R is the correct explanation of A.
b) A and R are true and R is not the correct explanation of A.
c) A is true, R is false. d) A is false, R is true.

HNO
3
27. Assertion (A) : acts as an oxidising agent, but not as reducing agent.
Reason (R) : Compound of an element, where the element is in its maximum oxidation
state undergo reduction, but can not undergo oxidation.
a) A & R are correct. R is the correct explanation of A
b) A & R are correct. R is not the correct explanation of A
c) A is true, R is false d) A is false, R is true

28. Assertion (A):Balancing of gaseous phase equations always requires conservation of

volumes
Reason (R):When gases combine they do so by simple ratio of their volumes
a) Both A and R are true, and R is correct explanation of A
b) Both A and R are true, and R is not the correct explanation of A
c) A is true but R is false d) A is false but R is true

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29. Assertion (A) : One mole of water at S.T.P. occupies 22.4 lit
Reason (R) : One mole of water contains 12.046 x 1023 atoms of hydrogen
a) Both A and R are true, and R is correct explanation of A
b) Both A and R are true, and R is not the correct explanation of A
c) A is true but R is false d) A is false but R is true

30. Assertion (A) : Oxidation state of carbon in C6H12O6 is zero

Reason (R) : Oxidation state of carbon in all organic compounds is zero
a) Both A and R are correct, R is the correct explanation of A
b) A and R are correct, R is not the correct explanation of A
c) A is true but R is false d) A is false but R is true
1) A 2) C 3) C 4) A 5) C 6) C 7) D 8) C 9) C 10) D
11) A 12) A 13) C 14) B 15) D 16) C 17) C 18) D 19) D 20) D
21) B 22) B 23) D 24) D 25) A 26) C 27) A 28) D 29) D 30) C

DPT-3:

1. 0.5 mole of HCl is allowed to react with 0.5 mole of Sodium Carbonate the number of mole
of Carbondioxide formed is
1) 0.25 2) 0.5 3) 1.0 4) 1.25

2. 10 litres of H2 and 20 litres of Cl2 are mixed and exploded. The volume of the mixture will
be

1) 10 litres of Cl2 2) 30 litres of HCl

3) 10 litres of Cl2 & 20 litres of HCl 4)10 litres of Cl2 & 30 litres of HCl

3. 200ml of dry Oxygen is subjected to electric discharge. Only 15% of O2 is

converted to O3. The volume of ozonized Oxygen is

1) 200ml 2) 230ml 3) 190ml 4) 220ml

4. If one litre of a gas at S.T.P weights 1.165gm. Then the gas may be
1) Acetylene 2) CO 3) Oxygen 4)Methane

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5. A gas mixture containing 7g of CO & 11 g of CO2 was passed over and hot coke. Then the
volume of gas mixture at STP is
1) 22.4 lit 2) 16.8 lit 3) 11.2 lit 4) 5.6 lit

6. Assertion (1): The basicity of Ortho Phosphorus acid is 2

Reason (R) : In Phosphorus acid molecule three hydrogen atoms are attached to

phosphorus through oxygen atoms

1) Both A and R are correct and R is the correct explanation of A

2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
7. In which of the following compounds Fe exhibits lowest oxidation state

1) K4[Fe(CN)6] 2) K3[Fe(CN)6] 3) Fe(CO)5 4) FeSO4

8. In the balanced equation H2SO4 + XHI H2S + YI2 + ZH2O. The values of X,Y,Z
respectively are

1) X = 3, Y = 5, Z = 2 2) X = 8, Y = 4, Z = 4

3) X = 4, Y = 8, Z = 5 4) X = 5, Y = 3, Z = 4

9. 4g of a sample containing Mg + MgO is treated with excess of dil HCl acid. Then the S.T.P.
volume of H2 gas liberated is 2.24 lit. Then the percentage of 'Mg' metal in the given
sample is

1) 90% 2) 80% 3) 70% 4) 60%

10. The orbital angular momentum for a 2p electron is

3h 6h 2h
1) 2) 3) Zero 4)
11. Two elements X and Y have atomic weights of 14 and 16. They form a series of compounds
P, Q, R, S and T. The ratio of weight of 'Y' which combined with 14g of 'X' in these
compounds is 1 : 2 : 3 : 4 : 5. If the compound P has 28 parts by weight of X and 16 parts by
weight of Y, then the compound Q will have 14 parts by weight of 'X' and

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1) 16 parts by weight of Y 2) 32 parts by weight of Y

3) 48 parts by weight of Y 4) 8 parts by weight of Y

12. When 2.7g. of Aluminium metal on heating with excess of oxygen, gives how many grams
of alumina ?
1) 2.86 g 2) 5.1 g 3) 2.42 g 4) 10.3 g

13. The period having elements of all blocks and the longest group in periodic table respectively
are
1) 1st , zero 2) 6th , IIIB 3) 7th & IIB 4) 6th , IA

14. Identify the correctly matched set among the following

1) Zinc-d-block-Representative element
2) Lanthanum -d-block-Inner transition element
3) Cerium-f-block-Transition element 4) Actinium-d-block-Transition element

15. Eka silicon belongs to .... and .... in long form of periodic table
1) Group 14 and fourth period 2) Group 14 and third period
3) Group 4 and third period 4) Group 16 and fourth period

16. Assertion (A) : Fluorine atom has less electron affinity than Chlorine atom
Reason (R) : Additional electrons are repelled more strongly by 3p electrons in Chlorine
atom than by 2p electrons in Fluorine atom
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
17. The electronic configuration of element (x) in its ground state is [Ar]3d 54s1 . The position of
element just below it in modern periodic table is
1) 4th period ; VI B group 2) 6th period ; VI B group
3) 5th period ; VI B group 4) 4th period ; IV B group
18. Which one of the following is correct
1) EN of Chlorine > EN of Fluorine 2) EA1 of oxygen > EA1 of sulphur
3) EA1 of silicon > EA1 of sulphur 4) EA1 of Chlorine > EA1 of Fluorine
19. The radii of F-1,F, O and O2- are in the order

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O 2- >F1- >O>F O 2- >F1- >F>O F>O 2- >F1- >O O 2- >O>F1- >F
1) 2) 3) 4)
20. Some statements related to IP2 are given among them the incorrect statements is
1) IP2 of Na > IP2 of Mg 2) IP2 of oxygen > IP2 of nitrogen
3) IP2 of Be > IP2 of B 4) IP2 of Ne > IP2 of Fluorine
21. When Ionisation energy and Electron affinity of an element are expressed in
K.J./mole, the electronegativity in the Pauling scale is given by
I.E.+E.A I.E.+E.A I.E.+E.A I.E.+E.A
2 5.6 125 544
1) 2) 3) 4)

l
22. Assertion (1) : For n = 3, may be 0, 1, 2 and m may be 0; (+ 1and 0 ); (+2, + 1 and 0)
l l
Reason (R) : For each value of n, possible values of are 0 to (n-1).For each value of ,
l l
the possible values of m are - ..0.+
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
23. In hydrogen atom, the kinetic energy of electron is 82KJ / mole. The distance of that
electron from the nucleus is
1) 2.116A 2) 2.116nm 3) 8.464nm 4) 8.464A
24. The wave number of the 4th line in the Lyman series of hydrogen spectum is
24 25 25R 24R
cm -1 cm -1 cm -1 cm -1
25R 24R 24 25
1) 2) 3) 4)
25 Velocity of electron in 3rd orbit of Li+2 ion is
1) 3 times the velocity of electron in first orbit H-atom
2) 1/3 times the velocity of electron in first orbit H-atom
3) Equal to velocity of electron in first orbit of He+ ion
4) Equal to velocity of electron in second orbit of He+ ion
26. In an atom, the kinetic energy of the electron is 4.55x10 - 25 J. Then its de Broglie wavelength
is

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1) 1000A0 2) 6500A0 3) 7250A0 4) 8650A0
27. List-A (orbital) List-B (Nodal Planes)
A. 2Px 1. Zero
B. 3dxy 2. yz-plane
3d x 2 -y2
C. 3. yz & xz-planes
D. 2s 4. z axis
5. Two planes at 90 each other and which make 45 to X and Y axis
The correct match is
A B C D A B C D
1) 2 3 4 5 2) 2 3 5 4
3) 2 3 5 1 4) 3 4 2 5

28. In the radial probability distribution curve for the 2s orbital of the hydrogen atom, the first
maximum, the second maximum and the node respectively occur at the following distances
from the nucleus
1) 1.1A0, 0.53 A0 & 2.6 A0 2) 0.53 A0 ,1.1A0 & 2.6 A0
3) 2.6 A0 , 1.1A0 & 0.53 A0 4) 0.53 A0 , 2.6 A0 &1.1A0
29. The electron configuration of which of the following is not correct
1) 2, 8, 13, 1 2) 2, 8, 18, 1 3) 2, 8, 18, 2 4) 2, 8, 14, 1
30. The difference in angular momentum associated with the electron in two successive orbits
of hydrogen is
h h 3h 3h
2 2
1) 2) 3) 4)
31. Assertion (A) : CuCl is more covalent than KCl

Reason (R) : Cu+ ion has pseudo inert gas configuration

1) Both A and R are correct and R is the correct explanation of A

2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
32. The number of unpaired electrons present in the first excited state of chlorine atom is

1) 3 2) 5 3) 7 4) 1

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33. The uncertainty in the momentum of an electron is 1x10 - 5 kg ms- 1. The uncertainty in the
position will be

1) 1.05x10-28m 2) 1.05x10-26m 3) 5.27x10-30m 4) 5.25x10-28m

34. Lattice energy of NaCl is X. If the ionic size of A+2 is equal to that of Na+ and B-2 is equal
to that of Cl- , then lattice energy associated with the crystal AB is
1) X 2) 2X 3) 4X 4) 8X
35. If positive ion is present at the body center of the unit cell in FCC lattice, the negative ions
are present .
1) Only at face centers 2) Only at corners
3) Only at the center of edges 4) At corners and also at face centers
36. Identify incorrect statement among the following
1) Ionic nature is in the order of NaCl < KCl < RbCl < CsCl
2) Melting temperature are in the order of NaCl < KCl < RbCl < CsCl
3) Crystal lattice energy is in the order of NaCl > KCl > RbCl > CsCl
4) The co-ordination numbers of metal ions in NaCl = KCl = RbCl < CsCl
37. Assertion (A): BF3 molecule is planar and NF3 molecule is pyramidal in shape
Reason (R): Nitrogen atom is smaller than boron atom
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct

I-3 I-3
38. The geometrical arrangement of hybrid orbitals in and shape of are respectively
1) Trigonal bipyramidal and linear 2) Octahedral and linear
3) Planar triangular and Planar triangular 4) Tetrahedral, Pyramidal
39. Which of the following statements is not correct from the view point of molecular orbital
theory.

1) Be2 is not a stable molecule 2) He2 is not stable but He+ is expected to exist

3) Bond strength of N2 is maximum amongest the homonuclear diatomic molecules

4) The order of energies of molecular orbitals in F2 molecule is

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2S 2S
*
2PX 2PY 2PZ 2P
*
X 2P
*
Y

Ekk* < E <E <E =E <E <E =E < E

*
2PZ

40. Following molecules of atoms of A and X have SP 3 hybridisation of the central atom A. If
E is the lone pair, bond angle is minimum for
1) AX2E2 2) AX3E 3) AX4 4) Equal in all
41 List-I (Molecules) List-II (overlappings)
The correct match is
1) C2H4 A) p p and sp-p
2) C6H6 B) sp2 sp2, sp2 s and p p
3) PCl5 C) sp2 sp2, sp2 s and sp p
4) CO2 D) sp3d p
1) 1 B 2 C 3D 4A 2) 1B 2C 3A 4D
3) 1 B 2 B 3D 4A 4) 1 B 2A 3C 4D
42. Some statements are given below. Among them, the correct statements are
A) O - hydroxybenzaldehyde is steam volatile
B) P - hydroxybenzaldehyde is more soluble than O-hydroxybenzaldehyde in water
C) The B.P. of O-hydroxybenzaldehyde is greater than that of P-hydroxybenzaldehyde
1) All are correct 2) Only A and B are correct
3) Only B and C are correct 4) Only A and C are correct
43. In a polar molecule, the Ionic charge is 4.8 x 10 10 esu. The Inter Ionic distance is 1A 0. The
Dipolemoment is _____ Debyes

1) 4.8 2) 0.48 3) 5.4 4) 2.4

44. Identify the iso structural pairs in the following ?

[NF3 ,NO3- ]&[BF3 ,H3O + ] [NF3 ,HN 3 ]&[NO3 ,BF3 ]

1) 2)

[NF3 ,H 3O ]&[HN 3 ,BF3 ] [NF3 ,H3O ]&[NO3 ,BF3 ]

3) 4)

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45. The correct increasing order of bond lengths
O +2 <O-2 <O2-2 <O 2 O 2 <O-2 <O 2-2 <O +2 O +2 <O 2 <O-2 <O 22- O +2 <O 2 <O 22- <O-2
1) 2) 3) 4)

1 1 2 3 3 3 4 1 5 2 6 3 7 3 8 2 9 4 10 4

11 1 12 2 13 2 14 4 15 1 16 3 17 3 18 4 19 1 20 3

21 4 22 1 23 4 24 4 25 4 26 3 27 3 28 4 29 4 30 2

31 1 32 1 33 3 34 3 35 4 36 2 37 2 38 1 39 4 40 1

41 3 42 2 43 1 44 4 45 3

DPT- 4:

1. Geometrical isomerism is not exhibited by

Ph Ph
N N N N
OH OH OH OH
a) b) c) d)

2. A group which deactivates the benzene ring towards electrophilic substitution but directs
the incoming group towards o - and p - positions is

a) NH2 b) Cl c) NO2 d) C2H5

Zn + Alcohol Na 2CH3I

excess A excess B C + 2Nal
3. Westron

C on reduction with sodium in liquid ammonia gives

a) Cis 2 butene b) Trans 2 butane

c) 1 butyne d) 2 butyne

4. Which of the following statements is wrong

a) Benzene does not decolourise alkaline potassium permanganate solution

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b) Benzene is aromatic hydrocarbon

c) Benzene has delocalised electron cloud

d) Benzene does not undergo substitution reactions

5. Assertion (A) : Acetylene is used in oxyacetylene flame

Reason (R) : At a temperature of 200 - 400C in presence of silver and air ethylene forms
epoxide

a) Both (A) and (R) are correct. (R) is the correct explanation of (A).

b) Both (A) and (R) are correct. (R) is not the correct explanation of (A).

c) (A) is true, but (R) is false d) (A) is false, but (R) is true

6. Carcinogenic polynuclear hydrocarbon, 1,2benzanthracene is

a) b)

CH3

CH3
c) d)

7. o,pdirecting nature of CH3 group on benzene ring is due to

a) Hyper conjugation b) Mesomeric effect

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c) Inductive effect d) +Electromeric effect

anhyd. AlCl

3
dark,cold

8. + Excess of chlorine X

The correct statements of the following

I) 'X' is aromatic compound II) 'X' is benzene hexachloride

III) 'X' is used as insecticide IV) 'X' is hexa chloro benzene

a) I and II b) II and III c) III and IV d) I and IV

9. The reactivity order of the following towards dehydrohalogination is

A) (CH3)3C-Br B) CH3CH2CH2Br C) (CH3)2CH-Br

a) A > B > C b) C > B > A c) A > C > B d) A = B = C

10. Assertion (A) : Peroxide effect is observed in the addition of HBr to unsymmetrical

alk enes, but not observed in the addition of HCl

Reason (R) :HBr bond is cleaved by free radical whereas HCl bond is not cleaved

byfree radical because of more bond energy

a) (A) is true, but (R) is false b) (A) is false, but (R) is true

c) Both (A) and (R) are correct. (R) is the correct explanation of (A). d)
Both (A) and (R) are correct. (R) is not the correct explanation of (A)

11. 2butanol is converted to acetaldehyde by which of the following sequence of reactions?

a) Dehydration followed by oxidation with Baeyer's reagent

b) Dehydration followed by ozonolysis in the presence of zinc

c) Dehydration followed by oxidation with acidified KMnO4

d) Dehydration followed by addition of H2 in the presence of Lindler's catalyst

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12. Which of the following is non-aromatic?

O
a) b) c) d)

13. Set-I Set-II

A) Sodium benzoate 1) Red hot iron tube

B) Phenol 2) dil. HCl

C) Acetylene 3) anhydrous AlCl3

D) Benzene sulphonic acid 4) Zinc dust,

5) Soda lime,

Correct matching to get benzene is

a) A-3, B-4, C-1, D-5 b) A-2, B-5, C-1, D-3 c) A-5, B-4, C-1, D-2 d) A-2, B-4, C-1, D-3

14. Ethylene is reacted with Br2 in CCl4 to form 'x'. When 'x' is reacted with alcoholic KOH
'y' is formed 'x' and 'y' are respectively

a) Br-CH2-CH2-Br and C2H2 b) C2H5Br and C2H4

c) C2H5Br and C6H6 d) C2H3Br3 and C2H4

15. The formation of product in the following reactions follows Markovnikov's rule

a) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br

Major Minor

b) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br

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Minor Major
(C H CO) O
2 2
6
5
c) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br

Major Minor
(C H CO) O
6 2
5 2

d) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br

Minor Major

16. Which of the following gas decolourises alkaline KMnO 4 but does not give white
precipitate with ammonical silver nitrate ?

a) C2H2 b) C2H4 c) CH4 d) C2H6

17. Polyethene can be produced from calcium carbide by the following reactions

CaC2 + 2H2O Ca(OH)2 + C2H2

C2H2 + H2 C2H4

n(C2H4) (C2H4)n

The mass of polyethene obtained from 20 kgs of CaC2 is

a) 5.65 Kgs b) 8.75 Kgs c) 12 Kgs d) 20 Kgs

18. The correct sequence of steps in electrophilic substitution reaction of benzene is

I) Formation of sigma complex II) Removal of proton

III) Generation of electrophile IV) Formation of arenium ion

a) I, II, III, IV b) III, I, II c) IV, I, II d) II, III, IV

i)Iodoform + Ag

X redhot iron
ii) X Y
(powder) tube
19.
The correct statement about 'X' and 'Y' are

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a) Both 'X' and 'Y' form same ozonide

b) Both 'X' and 'Y' form white precipitate with Tollen's reagent

c) 'X' is a cyclic trimer of 'Y'

d) The ozonolysis products of 'X' and 'Y' are same

20. Which of the following has more acidic behavior?

a) 1Butyne b) 2Butyne c) Acetylene d) Propyne

21. Wrong statement of the following is

a) The straight chain alkenes have higher boiling point than branched chain alkenes

b) Trans-But-2-ene has zero dipolemoment

c) Dehydrohalogination of alkyl halides is an example of elimination reaction

d) (CH3)2C=CHC2H5 will show geometrical isomerism

Excess alc.KOH Alcolic Zn

B
44. A BrCH2CH2Br

'A' and 'B' can be distinguished using

a) Baeyer's reagent b) Bromine in CCl4 c) Tollen's reagent d) Fehling's solution

45. The type of overlappings involved in the formation of ethyne molecule are

sp 2 s sp 2 sp 2 p p
a) Four , one and one
sp s sp sp p p
b) Two , one and two
sp s sp sp p p
c) Two , two and two

sp 2 s sp 2 sp 2 p p
d) Four , two and one

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1) 2) 3) 4) 5) 6) 7) 8) 9) 10)

11) 12) 13) 14) 15) 16) 17) 18) 19) 20)

21) 22) 23) D 24) B 25) B 26) D 27) B 28) B 29) A 30) D
31) C 32) C 33) B 34) C 35) C 36) A 37) A 38) B 39) B 40) B
41) D 42) C 43) D 44) C 45) B

DPT-5:

46. The ratio of the sp, sp2 and sp3 hybrid orbitals in the compound CH3-CH=CH-CC-CH3

a)1:1:1 b)2:3:2 c)1:2:2 d)2:3:4

s p
47. The ratio of & bonds in benzene is

a)4:1 b)2:3 c)3:2 d)1:4

C2 H 5

CH 3 CH CH 2 CH CH 3

C2 H 5

48. IUPAC name of the compound is

a)2,4 - Diethyl pentane b)2-Ethyl-4-methyl hexane

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c)3,5 Di methyl heptane d)4-Ethyl-2-methyl-hexane

49. Pick out the incorrect statement

a) Alkyl group on Benzene ring is ortho and para directing because of hyperconjugation

b) In Dumas method Nitrogen is estimated

c) P-Nitrophenol and O-nitrophenol are separated by steam distillation

d) In paper chromatography, mobile phase is liquid and stationary phase is solid

50. Match the following

List I List II

A. Prussian blue 1. [Fe(SCN)]+2

B. Violet 2. AgCl

C. Blood red 3. Fe4[Fe(CN)6]3

D. Pale yellow 4. Na4[Fe(CN)5NOS]

5. AgBr

The correct matching is

A B C D A B C D

a) 3 4 1 5 b) 4 1 3 2

c) 3 1 5 2 d) 4 5 1 3

51. In kJehldahls estimation of nitrogen, the ammonia evolved from 0.5gm of an organic compound
neutralized 10ml of 1M H2SO4.The percentage of nitrogen in the compound is

a)28 b)56 c)42 d)84

52. Which of the following is a pair of functional Isomers?

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a) Maleic acid and Fumeric acid b) 2-Butene and 1-Butene

c) Propionaldehyde and Acetone d)2-pentanone and 3-pentanone

53. Which of the following orders about stability is correct?

a) CH3+ > CH3CH2+ > (CH3)2CH+ > (CH3)3C+

CH3 CH 2 CH3 2 CH 3 3 C

CH 3 CH
b)

c) CH3- < CH3CH2- < (CH3)2CH- < (CH3)3C-

d) Ethene > Propene > 1-Butene > 2-Butene

54. Which of the following is not a nucleophile

a) OH- b) HSO3- c) NH3 d) BF3

55. Both methane and ethane may be obtained separately in one step from

a)CH3I b)CH3COONa c)C2H5Cl d)both a and b

56. Energy barrier between staggered and eclipsed conformations of ethane is

a)0.6 K.cal/mole b)2.9 K.cal/mole c)12 K.cal/mole d)16 K.cal/mole

57. Which of the following has maximum boiling point

a) b)

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c) d)

d)

HCl S2Cl2
Zn
C2 H 5Cl A B C.
5000 C
58. Here C is

a) Westron b) Ethylene glycol c)Mustard gas d)Westrol

59. In the chlorination of ethane in the presence of sunlight, which one of the following is also formed
in minute quantity?

a)CH4 b)C6H6 c)C4H10 d)C2H6

60. n- Hexane and n- Heptane, when passed through Cr 2O3 supported over alumina at 6000C
respectively give

a) Benzene and heptane b) Heptane and toluene

c) Benzene and Benzene d)Benzene and toluene

61. In the following sequence of reactions, the compound B is

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O3 H 2O / Zn

CH3CH=CHCH3 A B

a)CH3CH2CH2CHO b)CH3CHO c) CH3COCH3 d) CH3CH2CHO

62. Acetylene and Ethylene react with cold and dilute alk.KMnO 4 to respectively give

a)Acetic acid and Ethylene oxide b) Oxalic acid and epoxy ethane

c) Oxalic acid and ethylene glycol d) Ethyl alcohol and Acetaldehyde

HBr
X (Major)

CH3CH=CH2

HBr/Peroxide
Y (Major)

63.

Incorrect statement among the following is

a) Formation of X is electrophilic addition and Y is free radical addition.

b) X and Y are positional Isomers.

c)X gives propene with alc.KOH.

d) Y gives 2,3-Dimethyl Butane on Wurtz reaction.

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KMnO4
64. The compound which decolourises dilute alkaline and does not give precipitate to
ammonical cuprous chloride is

a)Ethane b)Benzene c)Ethene d)Ethyne

65. Which of these will not react with acetylene

Cl
a)NaOH b)Na c)Tollens reagent d)H

66. Which of the following reacts with an aqueous solution of [Ag(NH 3)2]+OH-

a) CH3 CH= CH2 b) CH3 C CH

c) CH3 CH = CH CH3 d) CH3 C C CH3

67. Two organic compounds A and B both containing C and H yield on analysis, the same percentage
composition by weight. A decolourises bromine water but B does not. Which among the following
will be the correct formulae of A and B

a) A = C2H2 B= C6H6 b) A = C6H6 B= C2H2

c) A = C2H4 B= C2H6 d) A = C2H2 B= C3H8

68. Match the following

List-I (Reagent used with Ethyne) List-II(Product)

A) H2 in the presence of Ni I) Benzene

B) 40% H2SO4+1% /HgSO4 II) Ethene

C) Red hot copper tube III) Ethane

D) H2 in the presence of Lindlars catalyst IV) Ethanal

A B C D A B C D

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a) III IV II I b) III IV I II

c) IV III I II C) IV I II III

X

Zn

69. Sodium benzoate C6H6; C6H5OH Y. Here X and Y are respectively

a) NaOH + CaO and C6H5CHO b) Zn and C6H6

c) NaOH + CaO and C6H6 d) Zn and C2H6

70. The function of anhydrous AlCl3 in Friedel crafts reaction is

a) To absorb water b) To absorb HCl

c) To produce attacking electrophile d) To produce nucleophile

71. The heat of hydrogenation of Benzene is 51K.cal/mole, while its resonance energy is 36K.cal/mole.
Then the heat of hydrogenation of cyclohexene is

a) 14K.cal/mole b) 22K.cal/mole c)29K.cal/mole d)36K.cal/mole

C2 H 2
Re

d not
Fe tube
A Fu min g
H 2 SO4
B
72. . In this sequence B is

a)Benzene b)Benzene Sulphonic acid c)Phenol d) C2H2

Cl2 / h
A

C6H6

Cl2 / FeCl3
B

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73.

A and B respectively are.

a) Hexa chloro cyclohexane & Hexa chloro benzene

b) Chloro benzene & Hexa chloro cyclohexane

c) Hexa chloro cyclohexane & Chloro benzene

d) Hexa chloro benzene & Hexa chloro cyclohexane

74. Nitration of Benzene with Nitration mixture at 1000C gives

a) 1,3,5 Trinitro benzene b)m-Dinitro benzene

c)O-Dinitro benzene d)P- Dinitro benzene

75. The correct order of reactivity of the following compounds towards electrophilic substitution is

A)Nitrobenzene B)Benzene C) Phenol

a) A>C>B b) A>B>C c) B>C>A d) C>B>A

76. When an aqueous solution of sodium acetate is electrolysed, the possible products are/is
a) C2H6 b) CO2 c) NaOH d) All the above
77. The correct order of acidic nature of

A) C2H2 B) CH3 C CH and C) CH3C C CH3 is
a) C>A>B b) B>A>C c) C>B>A d) A>B>C

78. Incorrect statement among the following is

( H2 )
a) The isotopic abundance of normal hydrogen is 99.98%

b) Tritium is radioactive and emits low energy radiations only

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c) H2 and D2 bondlengths are same

d) Tritium is more reactive than deuterium due to high activation energy

79.Purest form of hydrogen is obtained by

a) Electrolysis of aq. Ba(OH)2 solution b) Reduction of steam with coke

c) Watergas shift reaction d)Reaction of Zinc with aq. alkalies

80. Electron precise compound among the following is

a) NaH b) NH3 c) CH4 d) ZrH2

81. Which of the following has highest boiling point

a) CH4 b) NH3 c) H2O d) HF

82. Incorrect statement among the following

H 2O 40 C
a)The density of is maximum at

H 2O D2O
b)The dielectric constant of is higher than that of

D2O H 2O
c)Ionic product of is higher than that of

NaCl H 2O D2O
d) is more soluble in than in

83. In Clarks method, the substance which is used to remove temporary hardness of water is

a) Na2Al2Si2O8.xH2O b)Na2[Na4(PO3)6] c) RNH3OH d)Ca(OH)2

84. Exhausted anion exchange resin is revived by using a solution of

a) NaOH b) Na2CO3 c) H2SO4 d) Both a & b

85. Which of the following has greater degree of hardness

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a) Water with 1mg CaCl2 per litre b) Water with 1mg CaSO4 per litre

c) Water with 1mg MgSO4 per litre d) all have equal value

86. In the following reactions which is deuterolysis

I) Al4C3+12D2O 3CD4+4 Al(OD)3 II) SO3+D2O D2SO4

III) SiCl4+2H2O SiO2+4 HCl IV) NaOH+D2O NaOD+ HOD

a) Only I and II b) Only I, II and IV c) Only I d) Only III

87. The product obtained at anode, when 50% H2SO4 aq. solution is electrolysed

a) H2O2 2) H2 c) H2S2O8 d) H2SO3

88. Study the following reactions carefully

HOCl + H 2O 2 H 3O + + Cl - + O 2 PbS + 4H 2O 2 PbSO 4 + 4H 2O

A. B.

Mark the correct statement

a) In A HOCl is reduced and in B PbS is oxidised b) In A HOCl is oxidised and in B PbS is

reduced

c) In both A and B, HOCl and PbS are reduced d) In both A and B,

HOCl and PbS are oxidised

89. The volume strength of 1N H2O2 is

a) 2.8V b) 5.6V c) 11.2V d) 22.4V

90. H2O2 reduces

MnO4
a) FeSO4 / H+ b) KI / H2O c) / H+ d) All the above

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1) d 2) a 3) c 4) d 5) a 6) b 7) c 8) b 9) d 10) d
11) b 12) a 13) c 14) c 15) d 16) b 17) c 18) d 19) c 20) a
21) b 22) a 23) b 24) c 25) c 26) c 27) b 28) c 29) b 30) d
31) d 32) d 33) d 34) a 35) c 36) c 37) c 38) d 39) d 40) a
41) c 42) c 43) a 44) b 45) c

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