Chapter

1 Measurements

Facts Related to Measurements

m
l d= , Formula for density
V
5 C
l ? C = ( F 32 F) (Converting F to C)
9 F
9 F
l F= ( C) + 32 F (Converting F to C)
5 C
l The total number of digits in the number is called the number of SF.
l All digits are significant except zero at the beginning of the number.
l The zeros to the right of the decimal point are significant.
l In scientific notation every number is written as N 10n such that N is a number with
a single non-zero digit to the left of the decimal point and n an integer, e.g., 2 104.
l Zero at the end of a number and before the decimal point may or may not be significant.
l SI has seven base units from where all other units are derived.
mass (in gms)
l Mol =
molar mass (g mol1 )
l 1 mole of a substance = N 0 molecules
l 1 mole of an element = N 0 atoms
l N 0 (Avogadros number) = 6.023 1023 mol1
atomic mass
l 1 amu =
N0
1
l mass of one H-atom = = 1.66054 1024 g = 1 amu
N0
l mass of one O-atom = 16 amu
l At STP (when temperature is 273 K and pressure is 1 atm), 1 mol of an ideal gas
occupies volume 22.4 L.
348 Practice Book of Chemistry for JEE Main & Advanced

SI Prefixes
Multiple Prefix Symbol Submultiple Prefix Symbol
10 24 yotta Y 101 deci d
21 2
10 zetta Z 10 centi c
1018 exa E 103 milli m
1015 peta P 106 micro
10 12
tera T 109 nano n
109 giga G 1012 pico p
106 mega M 1015 femto f
10 3
kilo k 1018 atto a
102 hecto h 1021 zepto z
1 24
10 deca da 10 yocto y

(a) Derived Units

Physical quantity Unit Symbol
2
Area square metre m
Volume cubic metre m3
Velocity metre per second m s 1
Acceleration metre per second square m s 2
Density kilogram per cubic metre kg m3
Molar mass kilogram per mole kg mol 1
Molar volume cubic metre per mole m3 mol 1
Molar concentration mole per cubic metre mol m 3

(b) Derived Units

Physical quantity Unit Symbol In terms of SI Unit
Frequency hertz Hz s 1
Force newton N kg m s 2
Pressure pascal Pa N m2
Energy joule J kg m2 s 2
1
Power watt (Js ) W J s 1, kg m2 s 3
Electric charge coulomb C As
Electric potential difference volt V J A 1 s 1
Electric resistance ohm VA 1
Format I MCQs with only ONE Correct Option
1. The number of significant figures in 0.00210 is 8 RT 1
11. Average velocity = of O2 gas at 10C in ms
(a) five (b) six M
(c) four (d) three
is
1
2. The decimal equivalent of up to four significant 8 0.0821 10 8 8.314 10
0.6 (a) (b)
32 32
figures may be written as
(a) 1.666 (b) 1.6666 8 8.314 283 8 8314 283
(c) 1.667 (d) 01.666 (c) (d)
32 32
3. 0.00167 is written in three significant figures with
12. Electromotive force (EMF), E of a cell is related to
scientific notation as
standard EMF, E by the equation
(a) 1.67 10 3 (b) 167.0 10 5
0.0591
(c) 16.7 10 4 (d) 1.670 10 3 E = E log K
n
4. 17.675 is rounded off to four significant figures as where, K is reaction quotient and n the number of
(a) 17.68 (b 17.67 electrons. Which is correct graphical representation?
(c) 17.6750 (d) 17.7
E E
5. 20.665 is rounded off to four significant figures as
(a) 20.67 (b) 20.66
(a) (b)
(c) 20.6650 (d) 22.665
6. In which of the following numbers, all the zeros are
not significant? O O
(a) 0.002 (b) 0.0020 log K log K
(c) 0.00200 (d) 0.002000
E E
7. 1 + 2 (17 15.1) = x. Hence, x is equal to
(a) 4.8 (b) 19.9 (c) (d)
(c) 5 (d) 5.0
8. Number of significant figures in the answer of the
following will be O O
log K
log K
(29.2 20.2) (1.79 105)
1.39 13. If x is the slope of the line of the graph in Q. (12)
(a) 4 (b) 3 (c) 2 (d) 1 (above) then
x
9. Which has maximum number of significant figures? (a) n = 0.0591 x (b) n =
0.0591
(a) 0.000010 (b) 0.216 0.0591
(c) 2.1 10 6 (d) 0.021 (c) n = (d) None is correct
x
1.40 2.67 1.93 14. Variation of concentration (in mol L1) with time
10. If = x, then x is
2.800 5.340 1.93 (in second) is given by
(a) 0.2500 (b) 0.0025 10 2
dx
= k [ A]
n
(c) 0.25 (d) 0.250
dt
350 Practice Book of Chemistry for JEE Main & Advanced

where, k is rate constant and n the order of the (b) The population of Mexico city is 8988230
reaction. If n = 2 then, k is expressed in the unit of (c) Both (a) and (b)
(a) L mol1 s 1 (b) mol L1 s 1 (d) None of the above
(c) L2 mol2 s 1 (d) s 1 23. Which has the highest value?
15. x is the same in F and C. x is (a) 100 Tm (b) 1000 Gm
(a) 180 (b) 273 (c) 40 (d) 32 (c) 10 4 Mm (d) 10 6 nm

16. The density of silver is 10.5 g/cm . This value in kg/m 3

3 24. Consider following column X (physical quantity) and
would be column Y (unit).
(a) 1.05 10 4 kg / m3 (b) 10.5 10 4 kg / m3
Column X Column Y
(c) 1.05 103 kg / m3 (d) 10.5 102 kg / m3
I. Molar mass A. mol 1
17. The distance between two hydrogen atoms in a II. Avogadros number B. pascal
hydrogen molecule is 74 pm. This distance is also III. Molar volume C. kg mol 1
equal to IV. Energy D. m3 mol 1
(a) 7.4 10 11
m (b) 0.074 nm V. Pressure E. joule
(c) 0.74 (d) All are correct
Correct alternate matching column X with column Y
18. Helium has the lowest boiling point of all the is
element at 452F. This value in degree celsius is
(a) 219C (b) 189C I II III IV V
(c) 269C (d) 226C (a) C A D E B
(b) C D A E B
19. On the Reaumur scale, water freezes at 0R and boils (c) C A E D B
at 80R. Hence, (d) A B C D E
R C R F 32
(a) = (b) = 25. Increasing order of prefix : micro, nano, pico and
80 100 80 180
4 femto is
(c) R = 0.8 C = ( F 32) (d) All of these are correct (a) micro < nano < pico < femto
9
(b) nano < micro < pico < femto
20. Variation of pH of buffer solution of CH3COOH and (c) pico < nano < micro < femto
CH3COO varies as given by equation and (d) femto < pico < nano < micro

[CH3COO ] 26. Multiplication by 103 will convert

pH = pK a + log (a) pico into nano (b) nano into micro
[CH3COOH]
(c) femto into pico (d) All of these
27. 1 Ts in terms of the SI base unit is equal to
pH
(a) 1 103 s (b) 1 10 9 s
(c) 1 1012 s (d) 1 10 12 s
4.74
28. Name and symbol of the prefixes used with SI units
to indicate multiplication by the following exact
O
log
[CH3COO ] quantities 103 , 10 2 , 0.1 and 10 3 respectively are
[CH3COOH] (a) k, c, d, m (b) m, d, c, k
(c) d, k, c, m (d) k, m, d, c
Hence, pH of a mixture containing 0.01 M
(CH3COO)2 Ca and 0.02 M CH3COOH is 29. EMF value is obtained in volt by the following
(a) 4.74 + log 2 (b) 4.74 operation
(c) 4.74 log 2 (d) None of these [Hint : JC 1 is volt]

21. Which ratio is equal to 100? 8.314 J mol1 K 1 298 K

(a)
1 MeV 1 Tm 96500 C mol1
(a) (b)
1 GeV 1 Gm 8.314 107 erg mol1 K 1 298 K
(b)
1 dm 1 L 1F
(c) (d)
1 mm 1 nL 0.0821 L atm mol1 K 1
(c)
96500 C mol1
22. Which of the following statements uses exact
numbers? 2 cal mol1 K 1
(d)
(a) 1 ft = 12 inch 96500 C mol1
Measurements 351

30. For each of the following pairs as (P, Q), which 38. Of the following masses, that which is expressed to
quantity is larger in each case? the nearest milligrams is
(a) 32.7 g (b) 32.71 g
Set P Q (c) 32.707 g (d) 32.7068 g
I 24.0 mg 24.0 cg 39. The greatest length of the following group is
II 250 cm 0.25 m (a) 4.0 m (b) 140 inch
III 0.8 nm 8 (c) 12 ft (d) 0.001 km
IV 10 L 6.4 m3 40. Of the following numbers, the one with three
significant figures is
I II III IV (a) 22.03 (b) 0.0260
(a) P Q P Q (c) 0.070 (d) 2000
(b) Q P P= Q Q 41. To the correct number of significant figures, the
(c) Q Q P= Q P result of the calculation 12.11 0.0087 302 = ...
(d) P P P= Q Q (a) 31.8 (b) 31.818
(c) 31.82 (d) 32
31. How many significant figures should be used for the
answer to the following calculation? 42. The highest temperature of the following group is
(a) 217 K (b) 273 K
(0.082056) (298.15) (0.379)
(c) 217F (d) 105C
(0.9480)
43. The largest volume of the following group is that of
(a) 2 (b) 3
(a) 445 g of water at 4C (density = 1g/cm3 )
(c) 4 (d) 5
(b) 600 g of chloroform at 20C (density =1.5 g /cm3 )
32. How many significant figures are there in the answer
(c) 155 cm3 of steel
to the following calculation?
(d) 0.50 L milk
0.0325 + 0.0812 + 0.0631
44. Of the following substances, the greatest density is
(a) 2 (b) 3 that of
(c) 4 (d) 5
(a) 1000 g of water at 4C
33. How many significant figures are there in the answer (b) 100.0 cm3 of chloroform weighing 198.9 g
to the following calculation? (c) a 10.0 cm3 piece of wood weighing 7.72 g
37.596 36.802 (d) an ethyl alcohol-water mixture of density
(a) 1 (b) 2 0.83 g/cm3
(c) 3 (d) 4 45. SI unit of pressure is
29.837 29.241 (a) pascal (b) atmosphere
34. If =x
32.064 (c) metre (d) dyne/cm2
then x (with correct significant figures) is 46. SI unit of EMF is
(a) 0.00186 (b) 0.01860 (a) joule (b) millivolt
(c) 0.0186 (d) 1.86 10 2 (c) volt (d) ampere
732.11 + 6.3 47. SI unit of radioactivity is
35. =x
760.00 (a) curie (b) becquerel
(c) rutherford (d) gray
x is equal to (with correct number of SF)
(a) 0.9716 (b) 0.972 48. For the reaction A Product
(c) 0.97 (d) 9.7 10 2
1 1 1
k =
36. 57.675 is rounded off to in four significant figures as t a x a
(a) 5.768 101 (b) 57.68
where, k is rate constant (in mol 1s 1) and a and
(c) 5.767 (d) 0.5767 102
( a x) are the concentration of A at the start and after
37. 917.65 is rounded off to in four significant figures as time interval t sec. A graph between ( a x) 1 and
(a) 917.6 (b) 917.7 time t is of the type
(c) 917.65 (d) 9.176 101
352 Practice Book of Chemistry for JEE Main & Advanced

P 3 0.0821 27 3 0.0821 300

(a) (b)
2 2
(a x)1

(a x)1
(a) (b) 3 8.3143 300 3 8.3143 3 10 5
(c) (d)
P 2 2
n
O O 53. By ideal gas equation p = RT , pressure of
t t V
0.1 mol O2 in 100 mL flask at 27C is
0.1 0.0821 300 0.1 0.0821 27
(a x)1

(a) atm (b) atm

(a x)1

P 100 100
(c) P
(d)
(c) 0.0821 300 atm (d) 0.0821 27 atm
54. Consider the following unit values of energy
O O
t t A : 1 L atm B : 1 erg C:1J D : 1 kcal

49. If OP = 0.01 mol 1 then initial concentration a is Increasing order of these values is
(a) A = B = C = D (b) A < B < C < D
(in the above question)
(c) B < C < A < D (d) D < A < C < B
(a) 0.01 mol (b) 10 mol
(c) 0.1 mol (d) 100 mol 55. 8 g of a gas at STP occupies 5.6 L hence, number of
moles present in 64 g of the gas will be
50. Following equation gives variation of equilibrium
(a) 1 (b) 2 (c) 3 (d) 8
constant K with temperature T
H 56. The metric unit to measure volume is
log K = log A (a) litre (b) mL
2.303 RT
(c) m3 (d) cm3
Graphically this variation is represented as
57. The abbreviation for the metric unit used to measure
mass is
(a) k (b) m (c) g (d) s
(a) log K (b) log K 58. The SI unit for volume is ... and the metric unit for
volume is ...
(a) L, m3 (b) m3, L
1 1 (c) mL, m3 (d) cm3 , m3
T T
59. Which of the following represents the largest unit?
(a) Decilitre (b) Dekalitre
(c) Kilolitre (d) Megalitre
(c) log K (d) log K
60. Which measurement represents the largest quantity?
(a) 47.3 mg (b) 4730 ng
(c) 4.73 10 4 g (d) 4.73 103 g
1 1
T T 61. Which measurement represents the smallest
quantity?
51. Rate law of a given equation of n th order (a) 2950 ng (b) 2.95 10 4 g
A Product (c) 2.95 103 g (d) 2.95 10 6 kg
dx
= k [ A]
n
is given by 62. When the prefix milli is used in the metric or SI
dt
system, a fundamental unit of measurement is
A straight line is inclined at 45 when a graph multiplied by what factor?
dx (a) 103 (b) 10 3
between log and log [ A] is plotted. Hence, n is
dt (c) 10 6 (d) 10 2
(a) 0 (b) 1 (c) 2 (d) 0.5
63. When the prefix centi is used in the metric system a
3RT fundamental unit of measurement is multiplied by
52. Root mean square velocity u = of H2 gas at 27C
M what factor?
in m s 1 is (a) 102 (b) 10 3
(c) 10 2 (d) 103
Measurements 353

64. Which choice best describes the degree of 73. Joule can have the dimension of
uncertainty in the measurement of 16.30 g? (a) kg m1 s 1 (b) m kg 1 s 1
(a) The uncertainty cannot be determined without (c) kg m s 2 2
(d) kg m2 s2
additional information
1/ 2
(b) The quantity is exact 3RT
(c) 0.10 g 74. represents
M
(d) 0.01 g
(a) velocity (b) momentum
65. Which choice best describes the degree of (c) energy (d) pressure
uncertainty in the measurement of 4.0032 g?
75. 1 mmHg is equal to
(a) The uncertainty cannot be determined with
(a) 7.502 10 3 N m2 (b) 133.3 N m2
additional information
(b) The quantity is exact (c) 7.502 103 N m2 (d) 0.1333 N m2
(c) The measurement is between 4.002 and 4.004 g 76. The vapour pressure at different temperature is given
(d) The measurement is between 4.0031 and 4.0033 g by the equation
66. What is 0.0970 written in scientific notation? B
log p = A
(a) 970 10 4 (b) 97 10 3 T
(c) 9.70 10 2 (d) 97.0 10 2 where P is in mmHg. This equation in SI unit is
B
67. How many ng are there in 5.2 mg? (a) log p + 133.3 = A
T
(a) 5.2 10 ng
3
(b) 5.2 10 ng
6
B
(b) log p + 2.1249 = A
(c) 5.2 10 ng
9
(d) 5.2 10 9 ng T
B
68. What temperature is 75F on the Kelvin scale? (c) log p 133 = A
T
(a) 24 K (b) 348 K (c) 297 K (d) 215 K B
(d) log p 2.1249 = A
69. If 75.0 g of water at 30C absorbs 900 calories, the T
new temperature will be 77. Area is expressed in the unit of barn. One barn is
(a) 42.0C (b) 105.0C equal to
(c) 70.0C (d) 160.0C (a) 10 12 m2 (b) 10 19 m2
22
70. Least count of an analytical balance is 0.0002 g. (c) 10 2
m (d) 10 23 m2
Which of the following is the correct recorded value? 78. One horse power (HP) is equal to 7.457 102 W.
[Hint Result should be reported upto four decimal places Which represent incorrect relation?
such that fourth decimal digit should be even number (a) 1 HP = 745.7 J s 1 (b) 1 W = 1.341 10 3 HP
(including zero; i.e., 0, 2, 4, 6, 8)]
(c) 1 J s 1 = 1.341 kg HP (d) 1 J s 1 = 1.341 milli HP
(a) 9.3171 g (b) 9.317 g
(c) 9.3175 g (d) 9.3170 g 79. Select the correct relation for a gas.
(a) 1 L = 1 10 3 m3 = 1 dm3 = 1000 cm3
71. The SI unit of electrical resistance is ohm which is
defined as (b) 1 L = 1 10 3 m3 = 1 10 2 dm3 = 1000 cm3
(a) 1 ohm = 1 VA (b) 1 ohm = 1 VA 1 (c) 1 L = 1000 m3 = 1 dm3 = 1 10 3 cm3
(c) 1 ohm = 1 WA (d) 1 ohm = 1 WA 1 (d) 1 L = 1000 m3 = 1 10 3 dm3 = 1 10 3 cm3

72. The SI unit of voltage is volt (V) which is defined as 80. One electron-volt (eV) is equal to
(a) 1 V = 1 WA 1
(b) 1 V = 1 WA (a) 1.6 10 19 J atm1 (b) 9.632 J mol1
(c) 1 V = 1 ohm A (d) 1 V = 1 ohm A 1 (c) 96.32 kJ mol1 (d) 96.32 J mol1

Format II Testing of Numerical Skill

1. How many significant figures are shown in each of 2. Rewrite each of the following numbers to consist of
the following numbers ? If indeterminate, give the four significant figures.
range of significant figures possible. (a) 7218.7 (b) 6.6 103
(a) 625 (b) 320 (c) 319.15 (d) 80 10 5
(c) 0.033 (d) 820.03 (e) 918.74 (f) 186000
(e) 0.04050 (f) 0.007 (g) 35.6050 (h) 312.549
(g) 7820.0 (h) 47000
354 Practice Book of Chemistry for JEE Main & Advanced

3. Perform the following calculations, expressing each (e) The density of gold
number and the answer in exponential form and (f) The area of a football field
with the correct number of significant figures (g) The temperature of a city
(a) 312 601 (b) 213 357 19.21 12. Use exponential notation to express the following
(c) 0.092 0.0300 (d) 0.0150 41.25 0.0078 quantities in terms of the SI base units
4400 13.7 350 0.10 678000 (a) 0.13 g (b) 232 Gg
(e) (f)
0.0090 0.0017 6.3 (c) 5.23 pm (d) 86.3 mg
(e) 37.6 cm (f) 54 g
4. Express the following exponentials as ordinary (g) 1 Ts (h) 2.7 ps
numbers.
(i) 0.15 mK
(a) 5.26 10 4 (b) 4.10 10 6
(c) 16.00 102 (d) 8.206 10 2 13. Give the name and symbol of the prefixes used with
(e) 9.346 103 (f) 9.346 10 3 SI units to indicate multiplication by the following
exact quantities.
5. Express as the following numbers in scientific 103 ; 10 2 ; 0.1; 10 3 ; 1000000; 0.000001
notation.
(a) 6500 14. For each of the following pairs, determine which
(b) 0.00092 quantities is larger.
(c) 860 (assume that this number is measured to 10) (a) 24.0 mg or 24.0 cg (b) 250 cm or 0.25 m
(d) 860 (assume that this number is measured to 1) (c) 0.8 nm or 8 (d) 10 L or 6.4 m3
(e) 186000 15. vant Hoff isochore equation showing variation of log
(f) 0.0516 K p with temperature T is
6. Evaluate. H
log10 K p = + constant
(a) 2.685 log (3.7 10 4 ) 2.303 RT
6.25
(b) x, given log x = If graph between log 10 K p and T 1 gives a straight line
(7.8 102 )
of slope 6.04 103 K, calculate H .
(3.762 + 0.012)
(c) x, given log x =
(8 10 4 ) 16. For the weak acid HA, [H+ ] varies as
[HA ]
7. Round off each of the following numbers to two log [H+ ]= log K a + log A graph between
significant figures. [ A ]
(a) 0.436 (b) 9.000 [HA ]
log [H+ ] and log is a straight line of slope 45
(c) 27.2 (d) 135 [ A ]
(e) 1.497 10 3 (f) 0.445 and making intercept on y-axis 3.6990. Determine
8. (a) An average adult has 5.2 L of blood. What is the the value of K a. What is [H+ ] when [HA] = 0.01 M,
volume of blood in m 3 ? [ A ]= 0.1 M?
(b) The density of silver is 10.5 g/cm3 . Convert the
17. Which represents a larger temperature intervals?
density to units of kg/m3 .
(a) A Celsius degree or a Fahrenheit degree.
9. Indicate the multiple or fraction of 10 by which a (b) A Kelvin degree or a Fahrenheit degree.
quantity is multiplied when it is preceeded by each
of the following prefixes. 18. The density of the lightest metal, lithium (Li), is
(a) M (b) m (c) c (d) k 5.34 102 kg / m 3 . Convert the density to g/cm 3 .
(e) 19. In an experiment, it is found that at NTP, 1 g radium
10. The radius of a hydrogen atom is about 0.37 , and produced 1.07 10 4 mL helium per day. In another
the average radius of the earths orbit around the sun series of experiment 1 g radium was found to emit
is about 1.5 10 8 km. Find the ratio of the average 3.4 10 10 -particles per second. Compute the value
radius of the earths orbit to the radius of hydrogen of Avogadros number from these data.
atom. 20. Convert 1 amu into MeV.
11. Indicate what SI base units would be used to express 21. Convert 5 cal into joule.
each of the following measurements.
(a) The length of a marathon race 22. Rate constant k varies with temperature T ( K) as given
(b) The mass of an automobile by equation
(c) The volume of a swimming pool Ea
log k = log A
(d) The speed of an aeroplane 2.303 RT
Measurements 355

1 24. On the Reaumur scale, water freezes at 0R and boils

A plot between log k ( y-axis) and (x-axis) is a
T at 80R.
straight line. Derive the values of E a and A. (a) What is the relation between a temperature at
Reaumur scale and Celsius scale and also
23. Cesium atoms are the largest naturally occurring
Fahrenheit scale?
atoms. The radius of a cesium atom is 2.62 . How
(b) What is the boiling point of mercury on this scale if
many cesium atoms would have to be laid side by
it boils at 356.6C?
side to give a row of cesium atoms 1.00 inch long?
Assume that the atoms are spherical.

Format III Comprehension Based MCQs

Example 1 One cubic millimeter of oil is spread on the 2. Units can be expressed in parts of or multiples of
surface of water so that the oil film has an area of 1 square (a) 1000 (b) 100
metre. (c) 10 (d) 0.1
Answer the following questions.
3. 1 nm is equal to
1. Thickness of the film in unit is (a) 10 12 m (b) 10 9 m
(a) 1 (b) 10 (c) 10 10 m (d) 10 8 m
(c) 100 (d) 0.1
2. How much area in square meters will one litre of Example 3 Read the following passage and answer the
point cover of it is brushed out to a uniform thickness questions at the end of it.
of 100 microns? It is inconvenient to be limited to decimal representations of
(a) 10 m2 (b) 1 m2 numbers. In chemistry, very large and very small numbers are
(c) 0.1 m2 (d) 0.01 m2 commonly used. The number of atoms is about 12 grams (g) of
carbon is represented by 6 followed by 23 zeros. Atoms
Example 2 Read the following short write-up and answer typically have dimensions of parts of nanometers, i.e., 10
the questions at the end of it. decimal places. A far more practical method of representation
The standardised measurement units used in science and is called scientific or exponential notation. A number expressed
technology today are known as the metric system. It was in scientific notation is a number between 1 and 10 which is
originally established in 1790 by the French National then multiplied by 10 raised to a whole number power.
Academy, and has undergone changes since then. The 1. The number of atom in 12 g of carbon is equal to
fundamental units of the modern metric system (SI for Le 12
(a) 12 N 0 (b)
Systeme. International d Unites) are found in given table. N0
N
Fundamental Units of the Modern Metric System (c) N 0 (d) 0
12
Fundamental Quantity Unit Name Symbol 2. The number between 1 and 10 indicated above is
Length metre m called
Mass kilogram kg (a) coefficient (b) exponential factor
Temperature kelvin K (c) logarithm (d) linear function
Time second s
Amount of substance mole mol
3. The factor of 10 raised to a whole number power is
Electric current ampere A called
Luminous intensity candela cd
(a) coefficient (b) linear function
(c) logarithm (d) exponential
1. Non-SI units of length, volume and energy in 4. The number 4578 in scientific notation is expressed
common use are as
(a) , L and cal (a) 457.8 (b) 45.78 102
(b) nm, L and joule
(c) 4.578 103 (d) 4.6 103
(c) m, m3 and joule
(d) mm, L and erg
356 Practice Book of Chemistry for JEE Main & Advanced

Format IV Matrix Matching

1. Match the physical quantity in Column I with SI unit 5. Match the equation given in Column I with the type
in Column II. of graph in Column II.
Column I Column II Column I (Equation) Column II (Graph)
(Physical quantity) (SI unit)
A. Force 1. N m2 A y = mx 1.
2 3 .
B. Energy 2. kg m s
C. Pressure 3. J A 1s 1
D. Electric potential difference 4. kg m s 2 B y = mx + c 2.
5. As .
6. kg m2s 2

2. Match the different unit value of energy in Column I C y = mx + c 3.

with corresponding values in cals in Column II. .

Column I Column II
(Energy unit) (Equivalent value in cal)
D y = mx c 4.
A. 1 erg 1. 0.24 .
B. 1 L atm 2. 2.4 108
C. 1J 3. 24.4 6. Match the multiple in Column I with SI prefix in
D. 1 eV 4. 3.85 10 20 Column II.
Column I (Multiple) Column II (Prefix)
3. Match the multiple in Column I with SI prefix in
Column II. A. 1024 1. M
B. 1015 2. Z
Column I (Multiple) Column II (Prefix) C. 1021 3. E
D. 1018 4. P
A. 1015 1. y
E. 106 5. Y
B. 1021 2. a 6. G
C. 1024 3. z 7. T
D. 1018 4. f
7. Match the concentration form in Column I with unit
5. m in Column II.
6. d
Column I Column II
4. Match the physical quantity in Column I with SI unit A. Molality 1. mol dm3
in Column II. B. Molarity 2. mol kg 1
Column I Column II C. Mole fraction 3. kg dm3
(Physical quantity) (SI unit) D. Density 4. unitless

A. Frequency 1. VA 1 8. Match the parameter in Column I with the unit in

B. Power 2. N m2 Column II.
1 1
C. Electric charge 3. JA s Column I Column II
D. Electric resistance 4. s 1 A. Frequency () 1. s 1
5. As B. Energy 2. Joule
6. kg m2s 3 C. c / 3. cal.
D. Force 4. Newton
Measurements 357

9. Second order rate constant k is given by Graphically

1 1 1
k =
t a x a 45
A
Graphically pH
4.0

O
30 [Conjugate base]
A log
(a x)1 [Acid]
L mol1 0.05 Compare the parameter in Column I with the values
O in Column II (Assume K a is constant in all cases).
time/sec
Column I Column II
Match the kinetic parameter in Column I with the
values obtained from graph in Column II. A. pH when buffer is 0.01 M in 1. 2.0
CH3COOH and 0.005 M in
Column I Column II (CH3COO)2 Ca
A. k (L mol 1 s 1 ) 1. 230.92 B. Ionisation constant K a 2. 5.0
B. 1
a (mol L ) 2. 0.0866 C. pH when butfer is 0.01 M 3. 6.0
each in benzoic acid and
C. rate at start (mol L1 s 1 ) 3. 0.5773 sodium benzoate
D. half-life (sec) 4. 20.0 D. 0.1 mol CH3COONa and x g 4. 4.0
of CH3COOH in 100 mL
10. pH of a buffer solution is given by solution gives a buffer of pH
[conjugate base] 4. In this case x is
pH = pK a + log
[acid]

Format V Integer Answer Type

1. Prefix tera X prefix nano = 10 x 5. In how many significant figures, answer of the
what is the value of x? following calculation will be expressed?
0.58 324.65
2. How many significant figures are there in
0.00409100? 6. How many kJ are in 2.58 10 3 kW hour?
7. How many watts are contained in 5.362 10 3 horse
3. 5 pm = 5 10 x nm
power?
What is the value of x?
8. Radioactivity is measured in the unit of curie,
4. Density of alcohol is 0.8 g/mL. What is the weight of Rutherford. (Ru)
5 mL of alcohol? 1 Ru = 1 10 x dps.
What is the value of x?

Check your Solutions

Format I MCQs with only ONE Correct Option 6. (a)
1. (d) 2. (c) 3. (a) 7. (c) Least value of SF is one, thus final result is reported in
one SF.
4. (a) 17.675 This is last digit.
8. (b) 9. (b) 10. (d)
This is odd number thus 7 rounded off to 8
11. (d) Result is to be reported in m s 1 (SI unit)
5. (b) 22.665 This is last digit R = 8.3143 J mol K 1, T = 283 K
This is even number thus no change in 6
358 Practice Book of Chemistry for JEE Main & Advanced

m = 32 g mol 1 = 32 10 3 kg mol 1 (CH 3COO)2 Ca = 0.01 M (given)

0.0591 [CH 3COO ] = 0.02 M
12. (b) E = E log K
n [CH 3COOH] = 0.02 M (given)
y = c mx (equation for a straight line) pH = pK a = 4.74
Thus, given equation can be compared with standard 1 MeV 10 6 eV
equation. 21. (a) = = 10 3
1 GeV 10 9 eV
When, x = 0, y = c (+ve intercept on y-axis) Thus, false
c
and when y = 0, x = (+ve intercept on x-axis) 1 Tm 1012 m
m (b) = 9 = 10 3
1 Gm 10 m
As x increases, mx increases, thus (c mx ) or y decreases.
Thus, false
Thus, on increasing log K , E decreases 1 dm 10 1 m
0.0591 (c) = 3 = 10 2
13. (c) Slope = m = 1 mm 10 m
n Thus, true
0.0591
m= 22. (c)
n
0.0591 23. (a) 100 Tm = 1014 m (b) 1000 Gm = 1012 m
Given, slope = x =
n (c) 10 4 Mm = 1010 m (d) 10 6 nm = 10 3 m
0.0591
Thus, n= 24. (a) 25. (d)
x
dx 26. (d) (a) pico (10 12 ) 10 3 = 10 9 (nano)
14. (a) = k [ A]2
dt (b) nano (10 9 ) 10 3 = 10 6 (micro)
conc (mol L1 ) (c) femto (10 15 ) 10 3 = 10 12 (pico)
= k (mol L1 )2
time (s) 27. (c) 28. (a) 29. (a)
k = L mol 1 s 1
30. (b) Set P Q Result
x 32 x
15. (c) = I. 24.0 mg = 24 10 3 g 24.0 cg = 24.0 10 2 g Q > P
180 100
II. 250 cm 0.25 m = 25 cm P> Q
5( x 32 ) = 9 x
x = 40 III. 0.8 nm = 0.8 10 9 m 8 = 8 10 10 m P= Q
IV. 10 L = 10 10 3 m 3 6.4 m 3 Q> P
10.5 g 10.5 10 3 kg
16. (a) = = 10.5 10 3 kg m 3 31. (b) 32. (c) 33. (c) 34. (d) 35. (c)
cm 3 10 6 m 3
= 1.05 10 4 kg m 3 36. (b) 37. (a) 38. (c) 39. (a) 40. (b)
17. (d) 74 pm = 74 10 12 m = 7.4 10 11 m 41. (d) 42. (d) 43. (d) 44. (b) 45. (a)
Thus, (a) is true. 46. (c) 47. (b) 48. (c)
= 74 10 3 10 9 m
49. (d) Since, OP = 0.01 mol 1, hence
= 0.074 10 9 m = 0.074 nm
1
Thus, (b) is true = 0.01 mol 1
= 74 10 2 10 10 m a
a = 100 mol
= 0.74 10 10 m = 0.74
Thus, (c) is true
50. (a) This represents a straight line y = c mx
F 32 C dx
18. (c) = 51. (b) = k [ A]
n
180 100 dt
452 32 C
= dx
9 5 log = n log [ A] + log k
dt
C = 268.888 = 269 C
19. (d) y = mx + c
[CH 3COO ] Hence, m (slope) = n = tan 45 = 1
20. (b) pH = pK a + log n =1
[CH 3COOH]
y = c + mx 52. (d) Take the values in SI (MKS) unit
When x = 0, y = c R = 8.314 J mol 1 K 1
[CH 3COO ] [CH 3COO ] M(H 2 ) = 2 g mol 1 = 2 10 3 kg mol 1
Thus, when log = 0 that is =1
[CH 3COOH] [CH 3COOH]
53. (c)
then, pH = pK a = 4.74
Measurements 359

54. (c) R = 0.0821 L atm mol 1 K 1 7. (a) 0.44 (b) 9.0 (c) 27 (d) 1.4 10 2 (e) 1.5 10 3
= 8.314 10 7 ergs mol 1 K 1 (f) 0.44
= 8.314 J mol 1 K 1 8. (a) 5.2 10 3 m 3 (b) 10.5 10 3 kg / m 3
= 0.002 kcal mol 1 K 1 9. (a) 10 5 (b) 10 4 (c) 10 3 (d) 10 2 (e) 10 7
= x (assume) 21
x 10. 4.054 10
1 L atm = =A
0.0821 11. (a) m (b) kg (c) m 3 (d) m/s (e) kg/m 3 (f) m 2 (g) K
4
1 erg =
x
=B 12. (a) 1.3 10 kg (b) 2.32 10 8 kg (c) 5.23 10 12 m
8.314 10 7
x (d) 8.63 10 5 kg (e) 3.76 10 1 m (f) 5.4 10 8 kg
1J= =C
8.314 (g) 1.0 1012 s (h) 2.7 10 12 s (i) 1.5 10 4 K

1 kcal =
x
=D 13. 10 3 : kilo, k. 10 2 : centi, 0.1 : deci, d 10 3 : milli, m
0.002 1000000 : mega, M, 0.000001 : micro,
Thus, B < C < A < D, 14. (a) 24 cg (b) 250 cm (c) equal (d) 6.4 m 3
55. (b) 5.6 L = 8 g 15. 115.65 kJ mol 1 16. 5 10 4 M
22.4 L = 32 g mol 1 (at STP) 17. (a) F (b) F 18. 0.534 g / cm 3
64
64 g gas = = 2 mol 19. 6.1 10 23 = N0 20. 933.75 MeV
32
21. 1 cal = 4.18 joule 22. log A = intercept on y-axis
56. (a) 57. (c) 58. (b) 59. (d) 60. (a)
7 z F 32
61. (a) 62. (b) 63. (c) 64. (d) 65. (d) 23. n = 4.85 10 atoms 24.
180
66. (c) 67. (b) 68. (c)
69. (a) Heat absorbed = 900cal Format III Comprehension Based MCQs
specific heat of water = 1 cal g 1 C 1
Ex. 1 1. (b) 2. (a) Ex. 2 1. (a) 2. (c) 3. (b)
heat lost = mS = 75 1
75 = 900 = 12 Ex. 3 1. (c) 2. (a) 3. (d) 4. (c)
(t 30 ) = 12 C
t = 42 C Format IV Matrix Matching
70. (d) 71. (b) 72. (a) 73. (c) 74. (a)
1. A(4); B(6); C(1); D(3)
75. (b)
76. (b) 1mmHg =133.32 Pa 2. A(2); B(3); C(1); D(4)

77. (d) 78. (c) 79. (a) 80. (c) 3. A(4); B(3); C(1); D(2)
4. A(4); B(6); C(5); D(1)
Format II Testing of Numerical Skill 5. A(3); B(1); C(2); D(4)
6. A(5); B(4); C(2); D(3); E(1)
1. (a) Three (b) Two or three (c) Two (d) Five (e) Four
7. A(2); B(1); C(4); D(3)
(f) One (g) Five (h) Two to five
2. (a) 7219 (b) 6.600 10 3 (c) 319.2 (d ) 8.000 10 4 8. A(1); B(2,3); C1; D(4)
5 9. A(3); B(4); C(1); D(2)
(e) 918.7 (f) 1.860 10 (g) 35.60 (h) 312.5
5 6 3
3. (a) 1.88 10 (b) 1.46 10 (c) 2.8 10 10. A(4); B(4); C(2); D(3)
3 6 9
(d) 4.8 10 (e) 6.7 10 (f) 2.2 10
4. (a) 52600 (b) 0.00000410 (c) 1600 (d) 0.08206 Format V Integer Answer Type
(e) 9346 (f) 0.009346
5. (a) 6.5 10 3 (b) 9.2 10 4 (c) (8.60 0.1) 10 2 Questions 1 2 3 4 5 6 7 8
Answers 3 6 3 4 2 9 4 6
(d) (8.60 0.01) 10 2 (e) 1.86 10 5 (f) 5.16 102
6. (a) 1.88 (b) 1.019 (c) 0.99989