Parmetros de Antoine

A B
1 14.3145 2756.22
2 16.5785 3638.27

Parmetros de
Sustancia Puras
k Compuesto Rk Qk
1 ch3 (1) 0.9011 0.848
3 oh(5) 1 1.2
2 co(9) 1.6724 1.488

Energa Fraccional
k/l 1 2
1 1 0.0517604663
2 0.625340985 1
3 0.9228171406 0.6103201799

X1 0.00000 0.05000 0.10000

X2 1.00000 0.95000 0.90000
1 0.84800 0.89040 0.93280
2 1.20000 1.14000 1.08000
3 0.00000 0.07440 0.14880
J1 1.82768 1.75505 1.68797
J2 1.00000 0.96026 0.92356
L1 1.55469 1.51273 1.47298
L2 1.00000 0.97301 0.94745
T (C) 60.00000 60.00000 60.00000
 T(k) 333.15000 333.15000 333.15000
s11 3.06915 3.06915 3.06915
s21 0.99594 0.99594 0.99594
s31 1.89387 1.89387 1.89387
s12 1.59841 1.59841 1.59841
s22 1.24389 1.24389 1.24389
s32 1.24389 1.24389 1.24389
1 1.59841 1.67195 1.74548
2 1.24389 1.23150 1.21910
3 1.24389 1.27639 1.30889
R1 1.48599 1.40539 1.33778
R2 0.51855 0.55314 0.59139
C1 0.99540 0.99224 0.99029
C2 1.00000 1.00008 1.00023
1 1.47914 1.39448 1.32479
2 0.51855 0.55318 0.59153
Psat1 115.15569 115.15569 115.15569
Psat2 83.98910 83.98910 83.98910
P 43.55235 52.16723 59.96948
y1 0.00000 0.15391 0.25439
 ACETONA (1) / METANOL (2)

e Datos del Problema

C P (Kpa) 101.33
228.06 T (C) 60
239.5 T (K) 333.15

Frecuencia de Parmetros de
Grupos Funcionales Energa de Interaccin
vk1 vk2 ai1 ai2
2 1 0 986.5
0 1 156.4 0
1 0 26.76 164.5

3
0.2393121547
0.7771369601
1

PRESIN DE BURBUJA
0.20000 0.30000 0.40000 0.50000
0.80000 0.70000 0.60000 0.50000
1.01760 1.10240 1.18720 1.27200
0.96000 0.84000 0.72000 0.60000
0.29760 0.44640 0.59520 0.74400
1.56810 1.46413 1.37309 1.29271
0.85797 0.80109 0.75127 0.70729
1.39944 1.33289 1.27238 1.21713
0.90014 0.85733 0.81841 0.78287
60.00000 60.00000 60.00000 60.00000
333.15000 333.15000 333.15000 333.15000
3.06915 3.06915 3.06915 3.06915
0.99594 0.99594 0.99594 0.99594
1.89387 1.89387 1.89387 1.89387
1.59841 1.59841 1.59841 1.59841
1.24389 1.24389 1.24389 1.24389
1.24389 1.24389 1.24389 1.24389
1.89256 2.03963 2.18671 2.33378
1.19430 1.16951 1.14471 1.11992
1.37389 1.43889 1.50389 1.56888
1.23268 1.15738 1.10337 1.06493
0.67976 0.78562 0.91123 1.05912
0.98893 0.98964 0.99140 0.99353
1.00044 1.00018 0.99921 0.99743
1.21903 1.14539 1.09387 1.05804
0.68007 0.78576 0.91051 1.05641
115.15569 115.15569 115.15569 115.15569
83.98910 83.98910 83.98910 83.98910
73.77004 85.76632 96.26972 105.28305
0.38058 0.46137 0.52339 0.57863
OL (2)

Acetona: CH3-CO-CH3
Metanol: CH3-OH

os de Volmenes Moleculares
q1 q2
teraccin Relativos

ai3 Gk1 Gk2 r1 r2

476.4 1.696 0.848 1.8022 0.9011
84 0 1.2 0 1
0 1.488 0 1.6724 0
3.184 2.048 3.4746 1.9011

0.60000 0.70000 0.80000 0.90000 1.00000

0.40000 0.30000 0.20000 0.10000 0.00000
1.35680 1.44160 1.52640 1.61120 1.69600
0.48000 0.36000 0.24000 0.12000 0.00000
0.89280 1.04160 1.19040 1.33920 1.48800
1.22121 1.15722 1.09959 1.04743 1.00000
0.66818 0.63316 0.60163 0.57310 0.54714
1.16647 1.11986 1.07684 1.03700 1.00000
0.75029 0.72032 0.69264 0.66701 0.64322
60.00000 60.00000 60.00000 60.00000 60.00000
333.15000 333.15000 333.15000 333.15000 333.15000
3.06915 3.06915 3.06915 3.06915 3.06915
0.99594 0.99594 0.99594 0.99594 0.99594
1.89387 1.89387 1.89387 1.89387 1.89387
1.59841 1.59841 1.59841 1.59841 1.59841
1.24389 1.24389 1.24389 1.24389 1.24389
1.24389 1.24389 1.24389 1.24389 1.24389
2.48085 2.62793 2.77500 2.92208 3.06915
1.09512 1.07033 1.04553 1.02074 0.99594
1.63388 1.69888 1.76388 1.82888 1.89387
1.03812 1.02010 1.00877 1.00250 1.00000
1.23208 1.43308 1.66525 1.93180 2.23599
0.99564 0.99747 0.99885 0.99971 1.00000
0.99484 0.99145 0.98733 0.98253 0.97713
1.03360 1.01752 1.00761 1.00220 1.00000
1.22573 1.42083 1.64414 1.89805 2.18485
115.15569 115.15569 115.15569 115.15569 115.15569
83.98910 83.98910 83.98910 83.98910 83.98910
112.59382 117.82164 120.44370 119.81015 115.15569
0.63427 0.69615 0.77070 0.86694 1.00000
135

115
 135

115

95

75
Presion

55

35

15
0.00000 0.10000 0.20000 0.30000 0.40000 0.50000 0.60000 0.70000 0.80000 0.90000 1.

x -y
 X1
Y1

000 0.80000 0.90000 1.00000

 Parmetros de Antoine
A B
1 16.0692 3448.66
2 16.262 3799.89

Parmetros de
Sustancia Puras
k Compuesto Rk Qk
1 ch3 (1) 0.9011 0.848
2 ch2(1) 0.6744 0.54
3 oh(5) 1 1.2
4 h2o(7) 0.92 1.4

Energa Fraccional
k/l 1 2
1 1 1
2 1 1
3 0.625340985 0.625340985
4 0.4063683469 0.4063683469

P
X1 0.00000 0.05000 0.10000
X2 1.00000 0.95000 0.90000
1 0.00000 0.04240 0.08480
2 0.00000 0.05400 0.10800
3 0.00000 0.06000 0.12000
4 1.40000 1.33000 1.26000
J1 3.53250 3.13547 2.81867
J2 1.00000 0.88761 0.79793
 L1 2.23429 2.10441 1.98881
L2 1.00000 0.94187 0.89013
T (C) 60.00000 60.00000 60.00000
T(k) 333.15000 333.15000 333.15000
s11 2.67841 2.67841 2.67841
s21 2.67841 2.67841 2.67841
s31 1.29979 1.29979 1.29979
s41 0.45219 0.45219 0.45219
s12 0.56892 0.56892 0.56892
s22 0.56892 0.56892 0.56892
s32 2.78473 2.78473 2.78473
s42 1.40000 1.40000 1.40000
1 0.56892 0.67439 0.77987
2 0.56892 0.67439 0.77987
3 2.78473 2.71048 2.63624
4 1.40000 1.35261 1.30522
R1 9.33485 5.59302 3.85679
R2 1.00000 1.01256 1.04308
C1 1.92047 1.54310 1.33576
C2 1.00000 1.00527 1.01684
1 17.92727 8.63059 5.15174
2 1.00000 1.01789 1.06065
Psat1 20.29847 20.29847 20.29847
Psat2 19.92372 19.92372 19.92372
P 19.92372 28.02563 29.47610
y1 0.00000 0.31255 0.35477
 1-PROPANOL (1) / AGUA (2)

e Datos del Problema

C P (Kpa) 101.33
204.09 T (C) 60
226.35 T (K) 333.15

Frecuencia de Parmetros de
Grupos Funcionales Energa de Interaccin
vk1 vk2 ai1 ai2
1 0 0 0
2 0 0 0
1 0 156.4 156.4
0 1 300 300

ccional
3 4
0.0517604663 0.0191361532
0.0517604663 0.0191361532
1 0.3460805955
1.98909194 1

PRESIN DE BURBUJA
0.20000 0.30000 0.40000 0.50000
0.80000 0.70000 0.60000 0.50000
0.16960 0.25440 0.33920 0.42400
0.21600 0.32400 0.43200 0.54000
0.24000 0.36000 0.48000 0.60000
1.12000 0.98000 0.84000 0.70000
2.34484 2.00739 1.75484 1.55874
0.66379 0.56826 0.49677 0.44126
 1.79193 1.63053 1.49579 1.38163
0.80202 0.72977 0.66947 0.61837
60.00000 60.00000 60.00000 60.00000
333.15000 333.15000 333.15000 333.15000
2.67841 2.67841 2.67841 2.67841
2.67841 2.67841 2.67841 2.67841
1.29979 1.29979 1.29979 1.29979
0.45219 0.45219 0.45219 0.45219
0.56892 0.56892 0.56892 0.56892
0.56892 0.56892 0.56892 0.56892
2.78473 2.78473 2.78473 2.78473
1.40000 1.40000 1.40000 1.40000
0.99081 1.20176 1.41271 1.62366
0.99081 1.20176 1.41271 1.62366
2.48774 2.33925 2.19075 2.04226
1.21044 1.11566 1.02088 0.92610
2.35274 1.73740 1.42818 1.25329
1.13554 1.25449 1.39270 1.54862
1.13565 1.05364 1.01826 1.00363
1.04511 1.07080 1.09020 1.10286
2.67188 1.83060 1.45426 1.25784
1.18676 1.34331 1.51832 1.70791
20.29847 20.29847 20.29847 20.29847
19.92372 19.92372 19.92372 19.92372
29.76279 29.88206 29.95812 29.78011
0.36445 0.37305 0.39414 0.42868
GUA (2)

roblema
101.33 1-Propanol: CH3-CH2-CH2-OH
60 Agua: H2O
333.15

Volmenes
armetros de
q1 q2 Moleculares
a de Interaccin
Relativos
ai3 ai4 Gk1 Gk2 r1
986.5 1318 0.848 0 0.9011
986.5 1318 1.08 0 1.3488
0 353.5 1.2 0 1
-229.1 0 0 1.4 0
3.128 1.4 3.2499

0.60000 0.70000 0.80000 0.90000 1.00000

0.40000 0.30000 0.20000 0.10000 0.00000
0.50880 0.59360 0.67840 0.76320 0.84800
0.64800 0.75600 0.86400 0.97200 1.08000
0.72000 0.84000 0.96000 1.08000 1.20000
0.56000 0.42000 0.28000 0.14000 0.00000
1.40206 1.27401 1.16738 1.07723 1.00000
0.39690 0.36065 0.33047 0.30495 0.28309
 1.28365 1.19865 1.12421 1.05847 1.00000
0.57452 0.53648 0.50316 0.47374 0.44757
60.00000 60.00000 60.00000 60.00000 60.00000
333.15000 333.15000 333.15000 333.15000 333.15000
2.67841 2.67841 2.67841 2.67841 2.67841
2.67841 2.67841 2.67841 2.67841 2.67841
1.29979 1.29979 1.29979 1.29979 1.29979
0.45219 0.45219 0.45219 0.45219 0.45219
0.56892 0.56892 0.56892 0.56892 0.56892
0.56892 0.56892 0.56892 0.56892 0.56892
2.78473 2.78473 2.78473 2.78473 2.78473
1.40000 1.40000 1.40000 1.40000 1.40000
1.83461 2.04556 2.25651 2.46746 2.67841
1.83461 2.04556 2.25651 2.46746 2.67841
1.89377 1.74527 1.59678 1.44829 1.29979
0.83131 0.73653 0.64175 0.54697 0.45219
1.14703 1.07970 1.03642 1.01009 1.00000
1.72471 1.92903 2.18083 2.52611 3.08704
0.99860 0.99783 0.99863 0.99959 1.00000
1.10943 1.11083 1.10802 1.10185 1.09303
1.14543 1.07736 1.03500 1.00968 1.00000
1.91344 2.14283 2.41641 2.78340 3.37424
20.29847 20.29847 20.29847 20.29847 20.29847
19.92372 19.92372 19.92372 19.92372 19.92372
29.19937 28.11605 26.43595 23.99094 20.29847
0.47776 0.54446 0.63577 0.76885 1.00000
OH

Volmenes
Moleculares
Relativos
r2
0

0
0.92
0.92
 31

29

27

25

23
Presion

21

19

17

15
0.00000 0.20000 0.40000 0.60000 0.80000 1.00000

x -y
 X1
Y1

80000 1.00000