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Abstract
The use of pozzolans, either naturally occurring or artificially made, has been in
practice since the early civilisation. Of the artificial pozzolans, fly ash is the most
commonly used globally. With the rise in the demand for high performance
concrete in recent years, however, the demand for such pozzolanic materials is
also increasing steadily. Perhaps the latest addition to the ash family is palm oil
fuel ash (POFA); a waste material obtained on burning palm oil fibre and palm
kernel shell as fuel in palm oil mill boilers that has recently been identified as a
good pozzolanic material. This paper illustrates some test results on the
performance behaviour of concrete incorporating POFA as a partial replacement
of ordinary Portland cement (OPC). The durability aspects considered in this
study are resistance to heat rise, carbonation, and resistance to aggressive
chemicals like chloride and acid attack. Experimental investigation on resistance
to heat rise demonstrates that the partial replacement of OPC by POFA is
advantageous in controlling temperature rise. As compared with the specimens
prepared form OPC alone, concrete specimens made with POFA exhibited much
better resistance to attack by chloride ions and acid solution. It is the pozzolanic
behaviour of the ash that has been credited for the excellent performance against
such aggressive environments. Interestingly, the depth of carbonation was not
influenced by the replacement of OPC as only a little difference in each value of
carbonation between OPC and POFA concrete specimens has been detected.
2 Experimental programme
2.1 Materials
2.1.2 Cement
Ordinary Portland cement (ASTM Type I) from a single source was used
throughout the study. The detail of the physical properties and chemical
composition of the cement is also presented in Table 1.
2.1.3 Aggregate
Dry mining sand with fineness modulus of 2.4 and crushed granite of 10
mm size were used as fine and coarse aggregate respectively. The specific gravity
and water absorption of fine aggregates were 2.5 and 1.34 percent respectively
while the same for coarse aggregates were 2.61 and 0.76.
Physical Properties:
Fineness - Sp.surface area (m/kg) 314 519
Soundness LeChatelier method (mm) 1 1
Specific gravity 3.28 2.22
Table 2: Mix details of concrete with OPC as control and concrete with 30%
POFA
All the tests were performed in the laboratory where the recorded
temperature was 272 C with relative humidity of 755 %.
40
OPC Concrete
38 POFA Concrete
Temperature (C)
36
34
32
30
0 20 40 60 80 100 120
Time After Casting (hr)
The observations made above suggest that the partial replacement of OPC
by POFA is advantageous for massive structures where potential loss of concrete
strength may occur due to thermal cracking. No other experimental data on the
time-temperature behaviour of concrete with palm oil fuel ash is yet available in
the literature. The available data on other pozzolanic materials like low-calcium
fly ash, rice husk ash, silica fume, slag etc. give similar results obtained in this
study.
3.2 Carbonation
The carbonation tests were carried out on concrete prisms made from OPC
and OPC with 30% POFA. Two objectives were set forward: to evaluate the
effect of partial replacement of OPC by POFA and to determine the influence of
various curing conditions on carbonation of concrete. The latter was considered
because, apart from the water-binder ratio and compressive strength, curing of
concrete containing pozzolanic materials is also known to be a significant factor
controlling the rate of carbonation. Data on carbonation of both OPC and POFA
concrete obtained at different periods and from various exposure conditions are
given in Table 3.
The results presented in Table 3 clearly indicate the importance of initial
moist curing against carbonation of concrete. As expected, concretes cured
continuously in water showed no traces of carbonation. Both OPC and POFA
concrete specimens initially cured for 7 days showed better performance. The
depths of carbonation, however, for specimens cured in air were recorded to be
maximum at all ages. This is expected, as moist curing provides better hydration;
thus improving impermeability of the system resulting from the refinement of
pore structure of the mortar phase of concrete.
10
5
OPC Concrete
POFA Concrete
0
10 20 30 40 50 60
Square Root of Time (hr)
30
Weight Loss (%)
20
10
OPC Concrete
POFA Concrete
0
0 300 600 900 1200 1500 1800 2100
4 Conclusions
On the basis of the results obtained and observations made in the present
study, the conclusions drawn are:
Experimental investigation on resistance to heat rise demonstrates that the
partial replacement of OPC by POFA is advantageous, particularly for mass
concrete where thermal cracking due to excessive heat rise is of great concern.
Generally speaking, concrete with POFA showed somewhat similar depths of
carbonation to concrete with OPC alone. Although the results are not truly
conclusive, POFA concrete appears to be more sensitive to exposure
condition: the dryer the curing condition the deeper the carbonation.
Study on the resistance to chloride ion revealed that the depths of penetration
of chloride ions in concrete containing POFA was much lower than in
concrete with OPC alone. The pozzolanic behaviour of the ash causing a
decrease in permeability resulting from the refinement of pore structure of the
cement matrix has been attributed for the higher resistance to penetration of
chloride ions into concrete.
Like concrete with other fly ashes of low-lime content, POFA concrete
exhibited a commendable resistance to acid attack. The pozzolanic behaviour
as well as its low lime content had been characterised for the resistance to
such acidic environment.
5 References
ASTM Designation C 618-94a (1994) Standard specification for fly ash and raw
or calcined natural pozzolan for use as a mineral admixture in Portland
cement concrete. Annual Book of ASTM Standards. American Society for
Testing and Materials.
Awal, A.S.M.A. (1998) A Study of Strength and Durability Performances of
Concrete Containing Palm Oil Fuel Ash. Ph. D. Thesis, Universiti
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