Académique Documents
Professionnel Documents
Culture Documents
CHEMICAL SPECIES
any chemical compound with a given identity
Identity is determined by the kind, number,
and configuration of that species atoms
aA + bB cC + dD
a b c d
Stoichiometric coefficient ( )
(+) a b reactants
(-) c d products
(0) inerts
aA + bB cC + dD
a b c d
Stoichiometric coefficient ( )
Sum,
= = + + +
aA + bB cC + dD
a b c d
Stoichiometric coefficient ( )
Sum,
= = () + () + () + ()
aA + bB cC + dD
Hence,
+ + = 0
= 0
Consider:
2 + 2 22 (1)
= 2 2 = 1 2 = 2
22 2 2 = 0
+ 0.52 2 (2)
= 1 2 = 0.5 2 = 1
2 0.52 = 0
Consider:
2 + 2 22 (1)
2
= = 1
2 2
+ 0.52 2 (2)
1
= = 1
2 1
Write a chemical reaction in such a way that:
+ 0.52 2
2 + 2 22
Extent of Reaction ()
Quantification of the progress of the reaction
Degree of advancement of reaction
Units: moles extent
,
=
Extent of Reaction ()
The extent of reaction is determined from the
number of moles of any species
, ,
= =
= +
= ,0 +
Extent of Reaction ()
For multiple, independent reactions,
= ,0 +
= ,0 +
NOTATION
For batch reactors:
-- use: n, N [mol]