Exmp 11.

fi * 1 kPa P*
Hi* 3076.8 J/g
Si* 10.345 J/g.K
T 300 C 573.15

At P, kPa Hi, J/g Si, J/g.k ln (fi/f*) fi/f* fi i fi*10^-3

10 3076.6 9.282 2.302581 9.999959 9.999959375 0.999996 0.01
100 3074.5 8.2166 4.603179 99.80112 99.80111793 0.998011 0.099801
200 3072.1 7.8937 5.293774 199.0935 199.0934865 0.995467 0.199093
300 3069.7 7.7034 5.697048 297.9865 297.9865469 0.993288 0.297987
600 3062.3 7.374 6.382825 591.5966 591.5966306 0.985994 0.591597
1000 3052.1 7.1251 6.883587 976.121 976.1210349 0.976121 0.976121
2000 3025 6.7696 7.55144 1903.483 1903.482667 0.951741 1.903483
3000 2995.1 6.5422 7.931138 2782.592 2782.592268 0.927531 2.782592
4000 2962 6.3642 8.191697 3610.845 3610.844556 0.902711 3.610845
5000 2925.5 6.2105 8.386748 4388.523 4388.522583 0.877705 4.388523
6000 2885 6.0692 8.539808 5114.362 5114.362074 0.852394 5.114362
7000 2839.4 5.9327 8.663186 5785.942 5785.941543 0.826563 5.785942
8000 2786.8 5.7942 8.764435 6402.441 6402.4407 0.800305 6.402441
(sat.) 8592 2753 5.7 8.840767 6910.289 6910.289348 0.80427 6.910289
10000 6962.05 0.696205 6.962047
l
Vi 25.254
P*10^-3
1.2 10
0.01
9
0.1 1
0.2 8
0.3 7
0.8

fi x 10^-3, kPa
0.6 6
1 0.6 5
i

2 4
3 0.4
3
4
5 2
0.2
6 1
7 0 0
8 0 2
Fig. : Fugacity and 4fugacity coefficient
6 of 8steam at 300
10 C 12
8.592 P x 10^-3, kPa
10
10
fi x 10^-3, kPa

i
fi
ideal gas