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Reference Temperature 25 C

Molar weights Cp values


Dye 378 g/mol 556.8783068783
TCPO 449 g/mol 342.5389755011
water (liquid) 18 g/mol 4200
Water (liquid to steam) 18 g/mol (latent heat) 2260
H2O2 34 g/mol 2620.588235294
Diethyl Phthalate 222 g/mol 1649.099099099
Sodium Bicarbonate 84 g/mol 1043
Acetic acid 60 g/mol 2055
sodium acetate 82 g/mol 974.3902439024
Carbon Dioxide 44 g/mol 843.1818181818

Input values
Desired TCPO mixture flow 200 kg/hr
Desired dye mixture flow 200 kg/hr
Desired pure diethyl phthalate flow 600 kg/hr
J/kg/K
J/kg/K
J/kg/K
Kj/kg
J/kg/K
J/kg/K
J/kg/K
J/kg/K
J/kg/K
J/kg/K

Reagent A
Compositi
Stream 1
Anthracene mass frac
Diethyl phthalate mass frac
Anthracene mass flow
Diethyl phthalate mass flow
Desired dye mix mass flow
Temp
Average Cp
Enthalpy flow
Reagent A -
Composition 4
0.003
0.997
0.6 kg/hr
199.4 kg/hr
200 kg/hr
30 C
1645.822436722 J/kg/K
1645822.436722 J/hr
Stream 2
TCPO mass frac
Diethyl phthalate mass frac
TCPO mass flow
Diethyl phthalate mass flow
Desired TCPO mix mass flow
Average Cp
Enthalpy flow
Temp
Stream 4
Total mass flow
Dye mass flow
TCPO mixture mass flow
Diethyl phthalate mass flow
Average Cp
Enthalpy flow
Temp
Reagent A mass frac %
Dye mixture
TCPO mixture
Diethyl phthalate
0.05
0.95
10 kg/hr
190 kg/hr
200 kg/hr
1583.771092919 J/kg/K
0 J/hr
25 C
Mixer
3A

Mixer 3A
Mass frac Dye mixture
TCPO mixture
Diethyl Phthalate (pure)

1000 kg/hr
200 kg/hr
200 kg/hr
600 kg/hr
1358.623946804 J/kg/K
6593119.73402 J/hr
29.8527922311 C

20 %w/w
20 %w/w
60 %w/w
0.2
0.2
0.6
Stream 3
Diethyl Phthalate mass flow 600 kg/hr
Temp 30 C
Average Cp 1649.099099 J/kg/K
Enthalpy flow 4947297.297 J/hr
Reference Temperature 25 C

Molar weights
Dye 378 g/mol
TCPO 449 g/mol
water (liquid) 18 g/mol
Water (liquid to steam) 18 g/mol
H2O2 34 g/mol
Diethyl Phthalate 222 g/mol
Sodium Bicarbonate 84 g/mol
Acetic acid 60 g/mol
sodium acetate 82 g/mol
Carbon Dioxide 44 g/mol
Nitrogen 28 g/mol
Oxygen 32 g/mol

Input Values
CH3COOH (stream 1) 292.6829268293 kg/hr
NaHCO3 (stream 2) 409.756097561 kg/hr
initial input H2O (Stream 3) 2250.024121654 kg/hr
H2O2 (stream 13) 100 kg/hr

Max water flow rate into Mixer 2 (stream 14) 500 Kg/hr

Error test (temperature) 1 = ERROR


Stream 11 input into mixer 2 0
Stream 12 input into mixer 2 0
Stream 14 input into mixer 2 0
Reactor 1B 0
Cp values
556.8783068783 J/kg/K
342.5389755011 J/kg/K
4200 J/kg/K
(latent heat) 2260 Kj/kg
2620.588235294 J/kg/K
1649.099099099 J/kg/K
1043 J/kg/K
2055 J/kg/K
974.3902439024 J/kg/K
843.1818181818 J/kg/K
1039.285714286 J/kg/K
918.75 J/kg/K

Temp 50
Temp 25
Temp 33.5345698
Temp 25
Reactor 1B
Reactant molar ratio

Product molar ratio

Normalized reagent fl
Limiting reagent

Production rate
Dissipation rate

Rate of production

Total mass flow


Enthalpy of reaction
Enthalpy flow in
Average Cp of inlet streams
Temperature of input reactants
Energy loss during reaction
Average Cp of output
Enthalpy flow out
Temperature of products
Stream 13
H2O mass flow
Average Cp
Enthalpy flow
Temp
Stream 14
H2O2 mass flow
Average Cp
Enthalpy flow
Temp
NaHCO3
CH3COOH
CH3COONa
H2O
CO2
NaHCO3
CH3COOH
2

NaHCO3
CH3COOH
CH3COONa
H2O
CO2

NaHCO3+CH3COOH -> CH3COONa + H2O + CO2

of inlet streams
e of input reactants
during reaction

e of products
1837.8048780488
4200
65876829.2682927
33.5346162353
100
2620.5882352941
0
25
Reagent B -
Composition 4

1
1
1
1
1
4.8780487805
4.8780487805
1=NaHCO3, 2=CH3COOH

4.8780487805
4.8780487805
4.8780487805
4.8780487805
4.8780487805
4.8780487805
2952.4390243903
45.68
95688628.4000976
2055
40.7713026605
222829268.292683
3518.9591078067
-127140639.892585
12.762597752
kg/hr
J/kg/K
J/hr
C
kg/hr
J/kg/K
J/hr
C
n4

Stream 1
CH3COOH mass flow
CH3COOH mol flow
Average Cp
Enthalphy flow
Temp

kmol/hr
kmol/hr

kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kmol/hr
kg/hr
kj/mol
J/hr
J/kg/K
C
J/hr
J/kg/K
J/hr
C
Drying unit
Temp in
Desired temp out
Required heating
292.6829268293 kg/hr
4.8780487805 kmol/hr
2055 J/kg/K
15036585.3658537 J/hr
50 C
Stream 5
NaHCO3 mass flow 0 kg/hr
CH3COOH mass flow 0 kg/hr
CH3COONa mass flow 400 kg/hr
H2O mass flow 2337.804878049 kg/hr
Total mass flow 2737.804878049 kg/hr
Average Cp 3728.730512249 J/kg/K
Enthalpy flow -124925968.559 J/hr
Temp 12.762597752 C
12.762597752 C
100 C
5437596700.26623 J/hr

Stream 7
NaHCO3 mass flow 0 kg/hr
CH3COOH mass flow 0 kg/hr
CH3COONa mass flow 400 kg/hr
Total mass flow 400 kg/hr
Average Cp 974.3902439024 J/kg/K
Enthalpy flow 29231707.31707 J/hr
Temp 100 C

Stream 12
NaHCO3 mass flow 0 kg/hr
CH3COOH mass flow 0 kg/hr
CH3COONa mass flow 400 kg/hr
Total mass flow 400 kghr
Average Cp 974.3902439024 J/kg/K
Enthalpy flow 1948780.487805 J/hr
Temp 30 C
Stream 2
NaHCO3 mass flow 409.756097561 kg/hr
NaHCO3 mol flow 4.8780487805 kmol/hr
Average Cp 1043 J/kg/K
Enthalpy flow 0 J/hr
Temp 25 C

Stream 3
H2O mass flow
Average Cp
Enthalpy flow
Temp
Reactor 1
Drying Unit

Cooling unit
Temp in
Desired Temp out
Required cooling

Cooling unit
Mixer 2

Stream 15
NaHCO3 mass flow 0 kg/hr
CH3COOH mass flow 0 kg/hr
CH3COONa mass flow 400 kg/hr
H2O mass flow 500 kg/hr
H2O2 mass flow 100 kg/hr
Total mass flow 1000 kg/hr
Average Cp 2751.81492109
Enthalpy flow 1948780.487805
Temp 25.7081800716
Excess NaHCO3 0
Excess CH3COOH 0
Reagent B mixture mass %
CH3COONa 40 %w/w
H2O 50 %w/w
H2O2 10 %w/w
412.1951219512 Kg/hr
4200 J/kg/K
14775213.7659512 J/hr
33.5345698 C
Stream 4
CO2 mass flow
Average Cp
Enthalpy flow
Temp

Stream 6
H2O (steam) flow rate 2337.8048780488
Latent heat 2260000
Enthalpy flow 5283439024.39024
Temp 100

100 C
30 C
27282926.8292683 J/hr

Stream 10
H2O mass flow 1837.8048780488 Kg/hr
Temp 30 C
Average Cp 4200 J/kg/K
Enthalpy flow 38593902.4390244 J/hr
214.6341463415 kg/hr
843.1818181818 J/kg/K
-2214671.33367 J/hr
12.762597752 C

Condensation unit
kg/hr Temp in
J/kg Desired temp out
J/hr Required cooling
C
Condensation Unit
100 C
30 C
5283439024.39024 J/hr
Stream 11
max H2O mass flow 500 Kg/hr
H2O mass flow 500 Kg/hr
Average Cp 4200 C
Enthalpy flow 10500000 J/kg/K
Temp 30 J/hr
Stream 8
Air inflow 10000 kg/hr
Average Cp 1013.973214286 J/kg/K
Enthalpy flow -152095982.143 J/hr
Temp 10 C

Stream 9
Air outflow 10000 kg/hr
Average Cp 1013.973214286 J/kg/K
Enthalpy flow 5131343042.247 J/hr
Temp 531.062977794 C
Reference Temperature 25 C

Molar weights Cp values


Dye 378 g/mol 556.87830688
TCPO 449 g/mol 342.5389755
water (liquid) 18 g/mol 4200
Water (liquid to steam) 18 g/mol (latent heat) 2260
H2O2 34 g/mol 2620.5882353
Diethyl Phthalate 222 g/mol 1649.0990991
Sodium Bicarbonate 84 g/mol 1043
Acetic acid 60 g/mol 2055
sodium acetate 82 g/mol 974.3902439
Carbon Dioxide 44 g/mol 843.18181818

Input values
Desired TCPO mixture flow 800 kg/hr
Desired dye mixture flow 200 kg/hr
Desired pure diethyl phthalate flow 0 kg/hr
J/kg/K
J/kg/K
J/kg/K
Kj/kg
J/kg/K
J/kg/K
J/kg/K
J/kg/K
J/kg/K
J/kg/K

Reagent A -
Composition 9
Stream 1
Anthracene mass frac 0.003
Diethyl phthalate mass frac 0.997
Anthracene mass flow 0.6 kg/hr
Diethyl phthalate mass flow 199.4 kg/hr
Desired dye mix mass flow 200 kg/hr
Temp 30 C
Average Cp 1645.8224367 J/kg/K
Enthalpy flow 1645822.4367 J/hr
Stream 2
TCPO mass frac 0.05
Diethyl phthalate mass frac 0.95
TCPO mass flow 40 kg/hr
Diethyl phthalate mass flow 760 kg/hr
Desired TCPO mix mass flow 800 kg/hr
Average Cp 1583.771 J/kg/K
Enthalpy flow 0 J/hr
Temp 25 C

eagent A -
mposition 9
Mixer 3A

Mixer 3A
Mass frac

Stream 4
Total mass flow 1000 kg/hr
Dye mass flow 200 kg/hr
TCPO mixture mass flow 800 kg/hr
Diethyl Phthalate mass flow 0 kg/hr
Average Cp 969.1645 J/kg/K
Enthalpy flow 1645822 J/hr
Temp 26.69819 C
Reagent A mass frac %
Dye mixture 20 %w/w
TCPO mixture mass flow 80 %w/w
Diethyl Phthalate mass flow 0 %w/w
Stream 3
Diethyl Phthalate mass flow
Temp
Average Cp
Enthalpy flow

Dye mixture 0.2


TCPO mixture 0.8
Diethyl Phthalate (pure) 0
0 kg/hr
30 C
1649.0990991 J/kg/K
0 J/hr
Reference Temperature 25 C

Molar weights
Dye 378 g/mol
TCPO 449 g/mol
water (liquid) 18 g/mol
Water (liquid to steam) 18 g/mol (latent heat)
H2O2 34 g/mol
Diethyl Phthalate 222 g/mol
Sodium Bicarbonate 84 g/mol
Acetic acid 60 g/mol
sodium acetate 82 g/mol
Carbon Dioxide 44 g/mol
Nitrogen 28 g/mol
Oxygen 32 g/mol

Input Values
CH3COOH (stream 1) 292.68292683 kg/hr Temp
NaHCO3 (stream 2) 409.75609756 kg/hr Temp
initial input H2O (Stream 3) 2250.0241217 kg/hr Temp
H2O2 (stream 13) 300 kg/hr Temp

Max water flow rate into Mixer 2 (stream 14) 300 Kg/hr

Error test (temperature) 1 = ERROR


Stream 11 input into mixer 2 0
Stream 12 input into mixer 2 0
Stream 14 input into mixer 2 0
Reactor 1B 0
Cp values
556.87830688 J/kg/K
342.5389755 J/kg/K
4200 J/kg/K
2260 Kj/kg
2620.5882353 J/kg/K
1649.0990991 J/kg/K
1043 J/kg/K
2055 J/kg/K
974.3902439 J/kg/K
843.18181818 J/kg/K
1039.2857143 J/kg/K
918.75 J/kg/K

50
25
25
25
Reactor 1B
Reactant molar ratio NaHCO3
CH3COOH
Product molar ratio CH3COONa
H2O
CO2
Normalized reagent flow NaHCO3
CH3COOH
Limiting reagent 2

Production rate
Dissipation rate NaHCO3
CH3COOH
Rate of production CH3COONa
H2O
CO2
Total mass flow
Enthalpy of reaction NaHCO3+CH3COOH -> CH3COONa + H2O + CO2
Enthalpy flow in
Average Cp of inlet streams
Temperature of input reactants
Energy loss during reaction
Average Cp of output
Enthalpy flow out
Temperature of products
Stream 13
H2O mass flow 2037.8048780488
Average Cp 4200
Enthalpy flow 70076829.2682927
Temp 33.1877119489
Stream 14
H2O2 mass flow 300
Average Cp 2620.5882352941
Enthalpy flow 0
Temp 25
Reagent B - Composition 9

Stream 1
CH3COOH mass flow 292.6829268293
CH3COOH mol flow 4.8780487805
Average Cp 2055
Enthalphy flow 15036585.3658537
Temp 50

1
1
1
1
1
4.8780487805 kmol/hr
4.8780487805 kmol/hr
1=NaHCO3, 2=CH3COOH

4.8780487805 kmol/hr
4.8780487805 kmol/hr
4.8780487805 kmol/hr
4.8780487805 kmol/hr
4.8780487805 kmol/hr
4.8780487805 kmol/hr
2952.4390243903 kg/hr
45.68 kj/mol
92719589.7680975 J/hr
2055 J/kg/K
40.2819487252 C
222829268.292683 J/hr
3518.9591078067 J/kg/K
-130109678.524585 J/hr
12.4768250827 C

Stream 5
NaHCO3 mass flow
CH3COOH mass flow
CH3COONa mass flow
H2O mass flow
Total mass flow
Average Cp
Enthalpy flow
Temp
Drying unit
Temp in 12.4768250827
Desired temp out 100
Required heating 5440514021.01517

Stream 7
NaHCO3 mass flow
CH3COOH mass flow
CH3COONa mass flow
Total mass flow
Average Cp
Enthalpy flow
Temp

kg/hr
J/kg/K
J/hr
C

Stream 12
NaHCO3 mass flow
CH3COOH mass flow
CH3COONa mass flow
Total mass flow
Average Cp
Enthalpy flow
Temp

kg/hr
J/kg/K
J/hr
C
Stream 2
NaHCO3 mass flow 409.75609756
NaHCO3 mol flow 4.8780487805
Average Cp 1043
Enthalpy flow 0
Temp 25

kg/hr
kmol/hr
J/kg/K
J/hr
C
Reactor 1

0 kg/hr
0 kg/hr
400 kg/hr
2337.8048780488 kg/hr
2737.8048780488 kg/hr
3728.7305122495 J/kg/K
-127843289.3079 J/hr
12.4768250827 C
C Drying Unit
C
J/hr

0 kg/hr
0 kg/hr
400 kg/hr
400 kg/hr
974.3902439024 J/kg/K
29231707.317073 J/hr
100 C

Cooling unit
0 kg/hr
0 kg/hr
400 kg/hr
400 kghr
974.3902439024 J/kg/K
1948780.4878049 J/hr
30 C

Mixer 2

Stream 15
NaHCO3 mass flow 0
CH3COOH mass flow 0
CH3COONa mass flow 400
H2O mass flow 300
H2O2 mass flow 300
Total mass flow 1000
Average Cp 2435.9325681
Enthalpy flow 1948780.4878
Temp 25.800014136
Excess NaHCO3 0
Excess CH3COOH 0
Reagent B mixture mass %
CH3COONa 40
H2O 30
H2O2 30
kg/hr
kmol/hr
J/kg/K
J/hr
C

Stream 3
H2O mass flow 212.1951219512 Kg/hr
Average Cp 4200 J/kg/K
Enthalpy flow 7606175.13395121 J/hr
Temp 33.5345698 C
Stream 6
H2O (steam) flow rate
Latent heat
Enthalpy flow
Temp

Cooling unit
Temp in 100 C
Desired Temp out 30 C
Required cooling 27282926.8292683 J/hr

Stream 10
H2O mass flow 2037.8048780488
Temp 30
Average Cp 4200
Enthalpy flow 42793902.4390244
kg/hr
kg/hr
kg/hr
kg/hr
kg/hr
kg/hr

%w/w
%w/w
%w/w
Stream 4
CO2 mass flow 214.63414634 kg/hr
Average Cp 843.18181818 J/kg/K
Enthalpy flow -2266389.2167 J/hr
Temp 12.476825083 C

Condensation unit
2337.8048780488 kg/hr Temp in
2260000 J/kg Desired temp out
5283439024.39024 J/hr Required cooling
100 C
Condensation Unit

Kg/hr
C
J/kg/K
J/hr
Stream 8
100 C Air inflow 10000
30 C Average Cp 1013.973214286
5283439024.39024 J/hr Enthalpy flow -152095982.143
Temp 10
ation Unit

Stream 9
Air outflow 10000
Average Cp 1013.973214286
Enthalpy flow 5131343042.247
Temp 531.062977794

Stream 11
max H2O mass flow 300 Kg/hr
H2O mass flow 300 Kg/hr
Average Cp 4200 C
Enthalpy flow 6300000 J/kg/K
Temp 30 J/hr
kg/hr
J/kg/K
J/hr
C

kg/hr
J/kg/K
J/hr
C