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Group 3:
I Sepapradita 1413071003 the man of g-d.
Anil Joseph 1613071021
Komang Sriponi 1613071025
UNIVERSITY OF EDUCATION-GANESH
SINGARAJA
2017
When the reaction rates of the forward and reverse reactions are equal and the
concentrations of the reactants and products are no longer changed as time went on, then
achieved is chemical equilibrium (chemical equilibrium).
Chemical equilibrium is a dynamic process. This can be likened with the skiers at a ski
resort, where the number of skiers is carried up the mountain by using the lift seat is equal to the
number of skiers down skating. So, even though there is a displacement of skiers continue to
occur, the number of people above and the number of people under the mountain did not change.
On the reaction of such substances substances results cannot be mutually reacted again into the
substance of the reactant.
1. The results of the reaction Substances cannot be converted back into a reactant.
2. Among the results of the reactant and yield reaction associated with one-way arrows.
3. The reaction takes place completely. That is, the reaction will stop if one or all of the reagents
is exhausted.
Example:
The reaction can be behind (reversible) can take place in both directions means that the results
of the reaction substances can react to form the substance of the reactant is back.
Example:
If the lead (II) sulfate, a solid white when reacted with aqueous sodium iodide will form deposits
of lead (II) iodide reaction with yellow,
(white) (yellow)
Conversely when the solid lead (II) iodide which is yellow from the reaction of aqueous sodium
sulfate plus the above, then it will return a white precipitate is formed from lead (II) sulfate with
reaction,
(yellow) (white)
Equilibrium Of Homogeneous
The term Homogeneous equilibrium (homogeneous equilibrium) apply to reactions that all
species react to him are on the same phase. An example of a gas-phase equilibrium homogeny is
a decomposition of N2O4. Constant balance, as given in equation is
Kc =
Note that subscripts in the Kof c States that the concentration of the reacting species is expressed
in moles per liter. So for the equilibrium process
Kp =
Heterogeneous Equilibrium
Reversible reactions which involve reactants and products that produce different phase
heterogeneous equilibrium (heterogeneous equilibrium). For example, when calcium carbonate
is heated in a closed container, the following equilibrium is achieved:
Kc=
KP =
The concentration of a reactant or reactants affect the equilibrium shifts. Based on the principle
of Le Chatelier's principle , to note a few, as follows:
a. If there is an addition of reactant concentration on one, then the equilibrium will shift to
the right (in the direction of the product). On the contrary, if any additional product
concentration, then the equilibrium will shift to the left (towards the reactant).
b. If there is a reduction in the concentration of one reactant, then the equilibrium will shift
to the left (towards the reactant). Conversely, if there is a reduction in the concentration
of the product, then there will be a shift in the equilibrium to the right (in the direction of
the product).
When a reaction the number of molecules or particles before and after the reaction the same
volume does not shift the equilibrium of the layout.
The reaction to the number of particles before and after the reaction is not the same then,
when the Volume is magnified the equilibrium will shift towards a number of roads to
the molecules or particles (the amount of reaction coefficient).
When the Volume is minimized at equilibrium will shift towards a number of roads to
the molecules or particles (the amount of reaction coefficient).
PV = n RT
P = (n/V) RT
Of the equation shows that the change in pressure would be the opposite with changes in the
volume, which means that when the pressure is magnified by its effects would be the same when
the volume is reduced, and vice versa when the pressure is reduced will result in the same
volume when enlarged.
The equilibrium for the reaction the number of particles before the reaction is equal to the
number of particles having a reaction, changes in pressure will not shift the equilibrium of
the layout.
The equilibrium for the reaction the number of particles before the reaction is not the same
as the number of particles after the reaction if,
The pressure is magnified the equilibrium will shift to a number of small particles
Minimized Pressure equilibrium will shift to large number of particles.
3. Influence Of Temperature
The influence of temperature on equilibrium shift related to the reactions of endoterm and
eksoterm. According to Le Chatelier principle, when the temperature is raised, then the reaction
of the system is to lower the temperature. As a result, the equilibrium will shift to the reaction
that absorbs heat (endoterm). Conversely, if the temperature is lowered, the equilibrium will shift
to the reaction that releases heat (eksoterm).
Example:
N2(g) + 3 h2(g) 2NH3(g) H =-92.2 kJ
Because the H is negative, then the reaction is the reaction of eksoterm to the right. In contrast,
the reaction to the left is the endoterm reaction.
4. Influence Of Catalyst
REFERENCE
Chang, Raymond. 2008. Basic Chemical Core concepts part 2. Jakarta: Eason.
Hassanudin. 2015. Le Chatelier Principle & the factors that Affect chemical equilibrium. In
http://kimiadasar.com/asas-le-chatelier/ . Downloaded on 4 March
2017.