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KE KE
(1) 0 T/2 T t 0 T
(3)
KE
0 T/2 T T t
of molecules in the room before and after heating,
then nf ni will be :-
(1) 2.5 1025
(3) 1.61 1023
(2) 2.5 1025
(4) 1.38 1023
Ans. (2)
KE
Sol. Using ideal gas equation
(4) 0 T t PV = NRT
(N is number of moles)
Ans. (2)
P0V0 = NiR 290 ...... (1)
[Ti = 273 + 17 = 290 K]
Vmax V=0
After heating
P0V0 = NfR 300 ...... (2)
Sol. V=0
1
JEE(MAIN)-2017
3. Which of the following statements is false ? 4. The following observations were taken for
(1) A rheostat can be used as a potential divider determining surface tensiton T of water by
(2) Kirchhoff's second law represents energy
capillary method :
conservation
(3) Wheatstone bridge is the most sensitive when Diameter of capilary, D = 1.25 102 m
all the four resistances are of the same order rise of water, h = 1.45 102 m
of magnitude.
(4) In a balanced wheatstone bridge if the cell and Using g = 9.80 m/s2 and the simplified relation
the galvanometer are exchanged, the null point rhg
T= 103 N/m, the possible error in surface
is disturbed. 2
Ans. (4) tension is closest to :
(1) 2.4% (2) 10% (3) 0.15% (4) 1.5%
Ans. (4)
Sol. (1)
rhg
Sol. T 103
On interchanging Cell & Galvanometer. 2
R1 R2
T r h
T
r
h
0
R3 R4 = (0.8 + 0.689)
(2)
= (1.489)
T
100 1.489 %
T
On balancing condition 1.5%
R1 R 2 5. In amplitude modulation, sinusoidal carrier
....(1)
R3 R 4 frequency used is denoted by c and the signal
frequency is denoted by m. The bandwidth (m)
R1 R2 of the signal is such that m << c. Which of the
following frequencies is not contained in the
G modulated wave ?
(1) m + c (2) c m
R3 R4 (3) m (4) c
lense (f = 20 cm)
lense which works as a object for the converging 8. An electron beam is accelerated by a potential
difference V to hit a metallic target to produce
X-rays. It produces continuous as well as
characteristic X-rays.If min is the smallest
possible wavelength of X-ray in the spectrum, the
variation of log min with log V is correctly
represented in :
f = 25 cm f = 20 cm
log min
15 cm
So for converging lens u = 40 cm, f = 20 cm (1)
log V
Final image
1 1 1 log min
V 40 20
(2)
NB
.3 NB = .3 NA
= 60
11. In a common emitter amplifier circuit using an
n-p-n transistor, the phase difference between the
input and the output voltages will be :
NA
(1) 135 (2) 180 (3) 45 (4) 90
also let initially there are total N0 number of nuclei Ans. (2)
NA + NB = N0
Sol. In common emitter amplifier circuit input and out
N
NA 0 put voltage are out of phase. When input voltage
1.3
is increased then ib is increased, ic also increases
Also as we know
so voltage drop across Rc is increased. However
NA = N0et
increase in voltage across RC is in opposite sense.
N0 12. Cp and Cv are specific heats at constant pressure
N 0 e t
1.3
dv 3g
(102) kv 2 =
2
sin
dt
17. Some energy levels of a molecule are shown in
5 10
dv the figure. The ratio of the wavelengths r = 1/2,
v2 = 100 k dt is given by :
10 0
1 1 E
= 100 k (10) 2
5 10 4
E
k = 104 3
15. When a current of 5 mA is passed through a 1
galvanometer having a coil of resistance 15 , it 2E
shows full scale deflection. The value of the 3E
resistance to be put in series with the galvanometer 3 1
(1) r (2) r
to convert it into to voltmeter of range 0 10 V is: 4 3
(1) 2.535 103 (2) 4.005 103 4 2
(3) r (4) r
(3) 1.985 103 (4) 2.045 103 3 3
5
JEE(MAIN)-2017
R
= 2.5 100 = 250 wb
1 1
(1) 81 (2) (3) 9 (4) 20. In a Young's double slit experiment, slits are
81 9
separated by 0.5 mm, and the screen is placed 150
Ans. (3)
cm away. A beam of light consisting of two
Force mg volume density g
Sol. Stress wavelengths, 650 nm and 520 nm, is used to obtain
area A Area
interference fringes on the screen. The least
3
L g distance from the common central maximum to the
Stress =
L2 point where the bright fringes due to both the
Stress L wavelengths coincide is :
22.
Time = 10 T = 6.65 sec
Answer option 3
The variation of acceleration due to gravity g with
distance d from centre of the earth is best
Then voltage at other points can be written as
shown in figure
Hence voltage across all resistance is zero.
Hence current = 0
represented by (R = Earth's radius): 24. A particle A of mass m and initial velocity v collides
g g m
with a particle B of mass which is at rest. The
2
collision is head on, and elastic. The ratio of the
(1) (2)
d d deBroglie wavelengths A to B after the collision
O R O R is :
g g A 2 A 1
(1) 3 (2) 2
B B
(3) (4) A 1 A
d d (3) (4) 2
O O R B 3 B
Ans. (2) Ans. (4)
Ans. (3)
P
3K
3K r2 r
26. A time dependent force F = 6t acts on a particle Ans. (1)
of mass 1 kg. If the particle starts from rest, the
Sol. It steady state, current through AB = 0
work done by the force during the first 1 sec. will
be : E r
(1) 9 J (2) 18 J (3) 4.5 J (4) 22 J r1
Ans. (3) B A
Sol. F = 6t = ma C
D C
a = 6t r2
dv VAB = VCD
6t
dt
VAB r2 VCD
v 1 r r2
dv 6t dt
0 0
QC = CVAB
v = (3t2)10 = 3 m/s r
CE 2
r r2
8
CODE-B
29. A capacitance of 2 F is required in an electrical 30. A body is thrown vertically upwards. Which
one of the following graphs correctly represent
circuit across a potential difference of 1.0 kV. the velocity vs time?
A large number of 1 F capacitors are available
v
which can withstand a potential difference of
not more than 300 V. (1) t
(3) 2 (4) 16
v
Ans. (2)
(3) t
Sol. To hold 1 KV potential difference
C1
1
4
for one series.
(4)
Ans. (1)
v
t
v = u + at
v = v0 + (g)t
1 KV
v = v0 gt
9
JEE(MAIN)-2017
PART B MATHEMATICS
31. Let k be an integer such that triangle with Sol. We have
n
vertices (k, 3k), (5, k) and (k, 2) has area 28
sq. units. Then the orthocentre of this triangle
x r 1 (x r) 10n
r 1
is at the point : n
B C(2, 2)
D
(5, 2) (1 x 2 ) 1 x 2x (x 1)(x 1)
f (x)
(1 x 2 ) 2 (1 x 2 )2
1
orthocentre is 2, +
2 sign of f(x)
x = 1 x=1
32. If, for a positive integer n, the quadratic
equation, y 1, 1
2
x(x + 1) + (x + 1) (x + 2) + .....
O x
+ (x + n 1 ) (x + n) = 10n (0,0) x = 1
has two consecutive integral solutions, then n
is equal to : 1, 1
2
(1) 11 (2) 12
(3) 9 (4) 10 From above diagram of f(x), f(x) is
Ans. (1) surjective but not injective.
10
CODE-B
34. The following statement
(p q ) [(~p q) q] is :
(1) a fallacy Sol. x+y=3
(2) a tautology
(3) equivalent to ~ p q y = 1 + x
(1,2) 2
(4) equivalent to p ~q 4y = x
Ans. (2) (0,1)
Sol. (p q) [(~p q) q]
(2,1)
p q ~ p p q ~ p q (~ p q) q (p q) ((~ p q) q)
T F F F T F T
T T F T T T T
(0,0) (1,0) (2,0)
F F T T F T T
F T T T T T T
It is tautology
35. If S is the set of distinct values of 'b' for which
1 2 2
the following system of linear equations x2
Area = (1 x) dx (3 x) dx 4
dx
x+y+z=1
x + ay + z = 1
ax + by + z = 0
=
5
2
0 1 0
36. The area (in sq. units) of the region it is possible when 15a = 3b = 5c
{(x, y} : x 0, x + y 3, x2 4y and y 1 + x}
is : 5c c
b= , a=
3 3
5 59 3 7
(1) (2) (3) (4)
2 12 2 3 a + b = 2c
Ans. (1) b, c, a in A.P.
11
JEE(MAIN)-2017
38. A man X has 7 friends, 4 of them are ladies x2 y2
and 3 are men. His wife Y also has 7 friends, Sol. Equation of hyperbola is 1
a 2 b2
3 of them are ladies and 4 are men. Assume foci is (2, 0) hence ae = 2, a2e2 = 4
X and Y have no common friends. Then the b2 = a2(e2 1)
total number of ways in which X and Y a2 + b2 = 4 ...(1)
together can throw a party inviting 3 ladies and
3 men, so that 3 friends of each of X and Y are
Hyperbola passes through 2, 3
in this party, is : 2 3
1 ...(2)
(1) 484 (2) 485 (3) 468 (4) 469 a 2 b2
Ans. (2) On solving (1) and (2)
a2 = 8 (is rejected) and a2 = 1 and b2 = 3
4 Ladies 3 Ladies
x2 y2
Sol. x y 1
1 3
3 Men 4 Men
2x 3y
Total number of ways Equation of tangent is 1
4C 3C 3C 4C 4 3 3 4 1 3
0 3 3 0 + C1 C2 C2 C1
4 3 3 4 4 3 3
+ C2 C1 C1 C2 + C3 C0 C0 C3 4 Hence 2 2,3 3 satisfy it.
= 485 41. Let a, b, c R. If f(x) = ax2 + bx + c is such
39.
then
10
f(n)
n 1
is equal to :
(1) , (2) ,
2 3 2 2 (1) 255 (2) 330 (3) 165 (4) 190
Ans. (2)
1 1 1 1 Sol. f(x) = ax2 + bx + c
(3) , (4) ,
2 2 2 3 f(1) = a + b + c = 3
Ans. (3) Now f(x + y) = f(x) + f(y) + xy
put y = 1
x6 f(x + 1) = f(x) + f(1) + x
Sol. y = (x 2)(x 3) f(x + 1) = f(x) + x + 3
Now
Point of intersection with yaxis (0, 1) f(2) = 7
f(3) = 12
(x 2 5x 6)(1) (x 6)(2x 5) Now
y
(x 2 5x 6)2 Sn = 3 + 7 + 12 + ..... tn ...(1)
y= 1 at point (0, 1) Sn = 3 + 7 + ......tn 1 + tn ...(2)
Slope of normal is 1 On subtracting (2) from (1)
Hence equation of normal is x + y = 1 tn = 3 + 4 + 5 + ....... upto n terms
1 1
, satisfy it. (n 2 5n)
2 2 tn =
2
40. A hyperbola passes through the point
B
1 25
(1) (2) (3) 2 (4) 5
8 8
C
Ans. (3)
A P
Sol. a 2i j 2k , b i j and | a | 3 Now
tan tan
a b 2i 2j k tan( )
1 tan tan
|ab| 3
Now : ( a b ) c = | a b | | c | sin 30 n
tan tan 1
1 tan tan 2
AB
tan( ) AP
1
tan( )
2
1
|( a b ) c | = 3| c | 2
2 on solving tan =
9
Now : | c a | = 3
Ans. (4)
c2 + a2 2 ca 9
Sol. Total length = r + r + r = 20
4 + 9 2ac 9
20 2r
r
ac 2
1 1 2 3k,
2
Adding (1) and (2)
3
1 2 7
4
2 then k is equal to :-
2I 2 dx
sin x (1) 1 (2) z (3) z (4) 1
4 Ans. (2)
3 Sol. Here is complex cube root of unity
4
R1 R1 + R2 + R3
I cosec 2 x dx
4 3 0 0
2 2
= 1 1
3 / 4
I cot x / 4 2
1 2
dy
46. If (2 sin x) (y 1)cos x 0 and y(0) = 1,
dx = 3(1 ) = 3z k = z
49. The value of
then y is equal to :-
tan x 1 cos x
2 2 Q
lim 2
= x
2 8 x x
2 2 F lies on the plane
1 1 1 2( + 1) + 3(4 2) 4(5 + 3) + 22 = 0
= 1 =
8 2 16 6 + 6 = 0 =1
51.
of cos4x is :-
(1)
7
(2)
3
(3)
1
If 5(tan2x cos2x) = 2cos 2x + 9, then the value
(4)
2
F (2, 2, 8)
PQ = 2 PF = 2 42 .
9 5 3 9
53. The distantce of the point (1, 3, 7) from the
Ans. (1) plane passing through the point (1, 1, 1),
having normal perpendicular to both the lines
1 t
Sol. 5 t = 2(2t 1) + 9 {Let cos2 x = t}
x 1 y 2 z 4 x 2 y 1 z 7
t and , is :-
1 2 3 2 1 1
5(1 t t2) = t(4t + 7)
9t2 + 12t 5 = 0 10 20
(1) (2)
9t2 + 15t 3t 5 = 0 74 74
(3t 1) (3t + 5) = 0 10 5
(3) (4)
1 5 83 83
t = as t .
3 3
Ans. (3)
1 1
cos 2x = 2 1 = Sol. Normal vector
3 3
2
1 7 i j k
cos 4x = 2 1 =
3 9 1 2 3 = 5i 7j 3k
52. If the image of the point P(1, 2, 3) in the plane, 2 1 1
2x + 3y 4z + 22 = 0 measured parallel to line,
x y z So plane is 5(x 1) + 7(y + 1) + 3(z + 1) = 0
is Q, then PQ is equal to :-
1 4 5
5x + 7y + 3z + 5 = 0
(1) 6 5 (2) 3 5
(3) 2 42 (4) 5 21 21 5 10
42 Distance =
25 49 9 83
Ans. (3)
15
JEE(MAIN)-2017
56. A box contains 15 green and 10 yellow balls.
1
54. If for x 0, , the derivative of If 10 balls are randomly drawn, onebyone,
4 with replacement, then the variance of the
6x x number of green balls drawn is :-
tan 1 3 is x g(x) , then g(x) equals :- 6 12
1 9x (1) (2) (3) 6 (4) 4
25 5
3 9 3x x 3x Ans. (2)
(1) 3 (2) 3 (3) 3 (4)
1 9x 1 9x 1 9x 1 9x3 Sol. We can apply binomial probability distribution
Variance = npq
Ans. (2)
3 2 12
6x x 1 = 10 =
Sol. Let y = tan1 3 where x
0, 5 5 5
1 9x 4
57. The eccentricity of an ellipse whose centre is
2.(3x 3 / 2 )
= tan1 3 / 2 = 2 tan
1 (3x3/2) 1
1 (3x ) at the origin is . If one of its directices is
2
3 x= 4, then the equation of the normal to it at
As 3x3/2 0,
8 3
1, is :-
dy 1 3 2
=2 3 3 x1/2
dx 1 9x 2 (1) x + 2y = 4 (2) 2y x = 2
9 (3) 4x 2y = 1 (4) 4x + 2y = 7
= x Ans. (3)
1 9x 3
1
9 Sol. Eccentricity of ellipse =
g(x) = 2
1 9x3
55. The radius of a circle, having minimum area,
which touches the curve y = 4 x2 and the lines,
y = |x| is :- (0, 0)
(1) 4 2 1 (2) 2 2 1
x = 4 x=4
(3) 2 2 1 (4) 4 2 1
Ans. (4) a 1
Now, =4 a=4 =2
Sol. Given curves are y = 4 x2 and y = |x| e 2
(0, 4) 1
b2 = a2(1 e2) = a2 1 = 3
4
(0,4r)
Equation of ellipse
x2 y2
+ 1
4 3
x 2y 3x
+ y' = 0 y' =
2 3 4y
There are two circles satisfying the given 3 2 1
y ' |(1,3 / 2)
conditions. The circle shown is of least area. 4 3 2
Let radius of circle is 'r' 3
co-ordinates of centre = (0, 4 r) Equation of normal at 1,
2
circle touches the line y = x in first quadrant
3
0 (4 r) y = 2(x 1) 2y 3 = 4x 4
2
=r r4=r 2
2 4x 2y = 1
4
r= = 4 ( 2 1)
2 1
16
CODE-B
58. If two different numbers are taken from the set
1
{0, 1, 2, 3, ......., 10), then the probability that = P(C) + P(A) 2P(C A) =
4
their sum as well as absolute difference are both
multiple of 4, is :- Adding all, we get
7 6 3
(1) (2) 2P(A) 2P(A B) =
55 55 4
12 14 3
(3) (4) P(A) P(A B) =
55 45 8
Ans. (2) 1
Now, P(A B C) = (Given)
Sol. Let A {0, 1,2 ,3 ,4 ......, 10 } 16
n(s) = 11C2 (where 'S' denotes sample space) P(A B C)
Let E be the given event = P(A) P(A B) + P(A B C)
E {(0, 4), (0, 8), (2, 6), (2, 10), (4, 8), (6, 10)}
n(E) = 6 3 1 7
= + =
59.
P(E) =
6
55
For three events A, B and C,
60.
8 16
2 3
If A
16
events occurs, is :- 2 3
Sol. Given A =
3 7 7 7 4 1
(1) (2) (3) (4)
16 32 16 64
16 9
Ans. (3) 3A2 =
P(exactly one of A or B occurs) 12 13
1 24 36
= P(A) + P(B) 2P(A B) = 12A =
4
48 12
P(Exactly one of B or C occurs)
72 63
1 3A2 + 12A =
= P(B) + P(C) 2P(B C) = 84 51
4
P(Exactly one of C or A occurs)
51 63
adj (3A2 + 12A) =
84 72
17
JEE(MAIN)-2017
PART C CHEMISTRY
61. Which of the following compounds will 63. The increasing order of the reactivity of the
significant amont of meta product during following halides for the S N1 reaction is
mono-nitration reaction ? CH3CHCH2CH3 CH3CH2CH2Cl
OH OCOCH 3 Cl
(I) (II)
(1) (2)
p-H3COC6H4CH2Cl
NH2 NHCOCH 3 (III)
(1) (III) < (II) < (I) (2) (II) < (I) < (III)
(3) (4) (3) (I) < (III) < (II) (4) (II) < (III) < (I)
Ans. (2)
Ans. (3) Sol. For any S N1 reaction reactivity is decided by
Sol. (i) Nitration is carried out in presence of ease of dissociation of alkyl halide
concentrated HNO3 + concentrated H2SO4.
R X
R X
(ii) Aniline acts as base. In presence of H2SO4
NH2
+
NH3 HSO4
its protonation takes place and anilinium
ion is formed
Higher the stability of R (carbocation) higher
would be reactivity of S N1 reaction.
Since stability of cation follows order.
+
CH3 CH 2 CH 2
H
H2SO4 CH 3 CH CH 2 CH3
(iii) Anilinium ion is strongly deactivating p H 3CO C 6 H 4 CH 2
group and meta directing in nature so it
Hence correct order is
give meta nitration product in significant
amount. II I III
+
NH2 NH3 HSO4 64. The radius of the second Bohr orbit for
hydrogen atom is :
conc.H2SO4
+ conc. HNO3 (Plank's const. h = 6.6262 1034 Js ; mass of
18
CODE-B
65. pKa of a weak acid (HA) and pKb of a weak Total weight of person = 75 kg
base (BOH) are 3.2 and 3.4, respectively. The
pH of their salt (AB) solution is 10
Mass due to 1H is = 75 7.5kg
(1) 7.2 (2) 6.9 100
(3) 7.0 (4) 1.0 1H atoms are replaced by 2H atoms.
Ans. (2) So mass gain by person =7.5 kg
Sol. Given
68. Which of the following , upon treatment with
pKa (HA) = 3.2 tert-BuONa followed by addition of bromine
pKb (BOH) = 3.4 water, fails to decolourize the colour of
As given salt is of weak acid and weak bas bromine ?
O C6H5
1 1
pH = 7 + pK a pK b (1) (2)
2 2 Br Br
O
1 1 O
=7+ (3.2) (3.4)
2 2 (3) (4)
Br Br
66.
= 6.9
The formation of which of the following
polymers involves hydrolysis reaction ?
(1) Nylon 6 (2) Bakelite
Ans. (1)
68. Ans.(1)
O O
(3) Nylon 6, 6 (4) Terylene tert-BuONa
HN ( CH2 )5 C
n
Nylon-6
O O
67. The most abundant elements by mass in the tert-BuONa
body of a healthy human adult are :
Br
Oxygen (61.4%) ; Carbon (22.9%), Hydrogen (it decolorises bromine
(10.0%) ; and Nitrogen (2.6%). The weight solution due to
which a 75 kg person would gain if all 1H atoms unsaturation)
are replaced by 2H atoms is
(1) 15 kg (2) 37.5 kg
(3) 7.5 kg (4) 10 kg O O
Ans. (3) tert-BuONa
Sol. Mass in the body of a healthy human adult
Br
has :-
(it decolorises bromine
Oxygen = 61.4%, Carbon = 22.9%, solution due to
Hydrogen = 10.0% and Nitrogen = 2.6% unsaturation).
19
JEE(MAIN)-2017
69. In the following reactions, ZnO is respectively
CH3
acting as a/an : CH3
(a) ZnO + Na2O Na2ZnO2 Br H
H Br
(b) ZnO + CO2 ZnCO3 H 3C H
H CH3
(1) base and acid (2) base and base Et
(3) acid and acid (4) acid and base Et
(I) (II)
Ans. (4)
Sol. Although ZnO is an amphoteric oxide but in CH3 CH3
given reaction.
Br H H Br
(A) ZnO + Na2O Na2ZnO2 H CH3 H3 C H
acid base salt
Et Et
(B) ZnO + CO2 ZnCO3
(III) (IV)
base acid salt
70. Both lithium and magnesium display several 72. A metal crystallises in a face centred cubic
similar properties due to the diagonal structure. If the edge length of its unit cell is
relationship ; however, the one which is 'a', the closest approach between two atoms in
incorrect is :
(1) Both form basic carbonates
(2) Both form soluble bicarbonates
(3) Both form nitrides
metallic crystal will be :-
(1) 2a (2) 2 2 a
a
(4) Nitrates of both Li and Mg yield NO2 and (3) 2a (4)
2
O2 on heating
Ans. (1) Ans. (4)
Sol. Mg can form basic carbonate like Sol. In FCC unit cell atoms are in contant along face
5Mg + +2
6CO32 + 7H2O diagonal
4MgCO3 . Mg(OH)2 . 5H2O + 2HCO3 So, 2 a 4R
[Ag(NH3)2]OH
Tollens reagent
CHO CO2H
+
H /CH 3OH (2)
(esterification)
C (3)
O OCH3
CH3MgBr
CH3
(4)
H 3CCCH 3
Ans. (1)
OH
21
JEE(MAIN)-2017
Sol. (1) Ester in presence of Aqueous KOH solution 78. Which of the following reactions is an example
give SNAE reaction so following reaction takes of a redox reaction ?
place
(1) XeF4 + O2F2 XeF6 + O2
HOCH2 CH2OH HOCH2 CH2OH (2) XeF2 + PF5 [XeF]+PF6
O Aq. KOH O O
O AE
SN + MeCO (3) XeF6 + H2O XeOF4 + 2HF
OCMe O
OH OH
(4) XeF6 + 2H2O XeO2F2 + 4HF
Based on the above thermochemical equations, 80. The major product obtained in the following
the value of rH at 298 K for the reaction reaction is :-
C(grahite) + 2H2(g) CH4(g) will be :-
Br
(1) +74.8 kJ mol1 (2) +144.0 kJ mol1 H
C6H 5 BuOK
(3) 74.8 kJ mol1 (4) 144.0 kJ mol1
C6H 5
Ans. (3)
Sol. CO2(g)+2H2O() CH4(g)+2O2(g);rH= 890.3
(1) C6 H5 CH O t Bu CH2 CH 6 H5
fH 393.5 285.8 ? 0
(2) C6H5CH=CHC6H5
rH = ( H)
f products ( f H)Re actan ts
(3) (+)C6H5CH(OtBu)CH2H5
890.3 1 ( f H) CH4 2 0 1 (393.5) 2(285.8)
(4) ()C6H5CH(OtBu)CH2C6H5
( f H)CH 4 890.3 965.1 74.8 kJ / mol Ans. (2)
22
CODE-B
Sol. Elimination reaction is highly favoured if Sol. NO One unpaired electron is present in *
(a) Bulkier base is used molecular orbital.
(b) Higher temperature is used CO No unpaired electron is present
Hence in given reaction biomolecular O2 Two unpaired electrons are present in *
ellimination reaction provides major product. molecular orbitals.
(4) Na2C2O4
i = 1 Here is degree of association
2
Ans. (4)
Tf iK f m
Sol.
0.2
1 5.12 60
0.45= 2 20
1000
1 0.527
2
= 0.945
% degree of association = 94.5%
84. Which of the following molecules is least
resonance stabilized ?
82. Which of the following species is not
paramagnetic :-
(1) (2)
(1) NO (2) CO O
(3) O2 (4) B2
Ans. (2) (3) (4)
N O
Ans. (4)
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JEE(MAIN)-2017
Number of Cl present in ionization sphere =
O Mole of ion precipitated with exess AgNO3 0.02
2
mole of complex 0.01
Sol. (4) is nonaromatic and hence least It means 2Cl ions present in ionization sphere
complex is [Co(H2O)5Cl]Cl 2.H2O
86. The major product obtained in the following
reasonance stabilized reaction is :-
O
O
(1) Benzene is aromatic
DIBAL H
(3)
N
pyridine is aromatic
(1)
COOH
CHO
Ans. (4)
COOH
Molarity volume(ml)
Sol. Moles of complex =
1000
CHO
100 0.1 (4)
= = 0.01 mole
1000 CHO
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CODE-B
87. A water sample has ppm level concentration of 89. Given
following anions
E oCl / Cl
o
1.36 V, E Cr 3
/ Cr
0.74 V
2
the anion/anions that make / makes the water E oCr O2 / Cr3 1.33 V, E oMnO / Mn2 1.51V .
2 7 4
E oCr 3 / Cr 0.74
..(iii)
..(iv)
M 84.3 gm/mol
25