CO2

CO Benfield
H2
H2O G
CH4 y1 0.10%
O2

CO2 G 9401.652 kmol/hr

CO yo 11.86403198 %
H2
H2O
CH4
O2
BM benfield
komposisi gas in y1 1
kmol/hr kadar(%) BM CO2 yang terserap
CH4 1.187 0.0126254407 16 benfield yang dibutuhkan
H2 2833.733 30.14079866 2
H20 3216.572 34.212838339 18
CO2 1115.415 11.864031981 44 G
CO 1334.745 14.19691986 28 L
O2 900 9.5727857189 32 rho G
Total 9401.652 100 rho L
Average mol wt 19.021750007 kg/kmol
densitas gas 18.808586032 kg/m3

(L/G)*(rhoG/rhoL)^0.5 0.0620715769
pressure drop 1.5028735908 inch/ft 360.6896618 cm/m packing
G'^2*F**miu^0.2/(rhoG*rhoL*g) 0.1 u/ delta P 1.5
sangat berpengaruh pada D absoeber
Packing=raschig ring, 3 inch (ceramic) ap 69 m2/m3
F= 37
=ratio of the density of water to the density of liquid 0.794269687
miu liquid= 5.6
g= 32.2
rhoGrhoLg 2971.8377833
F bla bla 41.476998186
G'^2 7.165026191
G' 2.6767566552 lb/ft2sec
A 40.386757848 ft2 G actual
D 7.1727330335 ft 2.186275614 m
G actual
delta P flooding= 0.12F^0.7 G actual
delta P flooding= 1.5028735908 inch/ft packing
L
G' 1 yo Hx o
H ln
Ky a HG '
yh Hx h
(1 '
)
L

a 4.549997768
b 3.452312788
c 3.652865573
h 57.37926896 m

MENENTUKAN DIAMETER BAGIAN BAWAH KOLOM ABSORBER

L = massa cairan yang masuk kolom per satuan waktu + massa gas yg terserap per satu
G = massa gas yang masuk kolom per satuan waktu

L= 1720.31652 kmol/hr rho G

96443.6966 kg/hr rho L
26.78991572 kg/s 59.0610482 lb/s

G 9401.652 kmol/hr
176831.7805 kg/hr
49.11993902 kg/s
108.2898176 lb/s

(L/G)*(rhoG/rhoL)^0.5 0.066661579
pressure drop 0.6 inch/ft
G'^2*F**miu^0.2/(rhoG*rhoL*g) 0.09
Packing=raschig ring, 3 inch
F= 37
=ratio of the density of water to the density of liquid 0.794269687
miu liquid= 5.6
g= 32.2
rhoGrhoLg 2971.837783
F bla bla 41.47699819
G'^2 6.448523572 lb/ft2sec
G' 2.539394332 lb/ft2sec G actual 1.7775760322
A 60.91993569 ft2
D 8.809370785 ft 2.685128866 m D bawah
 0.118386948 kmol/m2.s
L'=LK 6.636961697 kg/m2s DL 5.6600090E-005
c 61 mN/m kl 0.0001413246
L 83.8 mN/m
ap 69 m2/m3 ky 0.090879785
miu L 5.6 cp
rho L 1259.01821 kg/m3 Ct=rho/MR
g 9.8 m/s2 Ct 22.4577645032
aw/ap 0.10011699 kx 0.0031738353
aw 6.908072297 m2/m3
0.687049663 kmol/m2.s H* = 0.453
G'=GK 13.06888693 kg/m2s H = H*Ct/P 0.3767913822
miu G 1.5053E-005 Pa.s y= 0.3767913822
rho G 18.80858603 kg/m3 Y= 0.424
DG 3.4553E-06 m2/s Kya 0.021640322
dp 0.036 m
R 0.08205 Latm/molK
T 333 K
kg 0.003365918 kmol/m2.s.atm 5.6cp

Tinggi Absorber

G dX G
Z Y HX X Y Yo Xo
Kya L

integrasi dengan simpson rule

Yo = 0.11864032 X1 = 0.0015
Y1 = 0.01 Xo = 0.692631185
m= 0.424
dY = 0.05432016
Y X Y*
0.11864032 0.0015
0.06432016 -0.31374292
0.01 -0.62898585
-0.0443202 -0.94422877
-0.0986403 -1.2594717
-0.1529605 -1.57471462
-0.2072806 -1.88995755
-0.2616008 -2.20520047
-0.315921 -2.5204434
-0.3702411 -2.83568632
NoG 0.021760534
HoG 5.470664793
Z 0.119044586 m
1/f(x) factor
0.000636 8.474266041
-0.133027 5.067212523
-0.26669 3.614153024
-0.400353 2.808729666
-0.534016 2.296866926
-0.667679 1.94280944
-0.801342 1.683327796
-0.935005 1.484992222
-1.068668 1.328467528
-1.202331 1.201793248
dA
1 8.4742660407
4 20.268850093
2 7.2283060474
4 11.2349186652
2 4.5937338518
4 7.7712377601
2 3.3666555911
4 5.9399688893
2 2.656935056
1 1.2017932478
Tekanan absorber= 27 atm
MENENTUKAN DIAMETER BAGIAN ATAS
L
x1 0.10% L = massa cairan yang masuk kolom per sa
G = massa gas yang masuk kolom per satu

komposisi larutan benfield

BM BM average
K2CO3 30% 138 56.0616 g/mol
DEA 4% 45
V2O5 0.60% 181.6
Air 65.400% 18

packing raschig ring 3 inc

ap 69 m2/m3
rho 561 kg/m3
rich solution
Benfield + CO2 50.8
L
xo

G=Gas yg masuk-gas yg terserap 9280.4729576818

49.0363434864
56.0616 g/mol
%
121.1790423182 kmol/hr
1599.137477446 kmol/hr L=1.4Lmin
89650.20560557 kg/hr 1kg= 2.2046
1m= 3.2808
49.0363434864 kg/s 108.1055229 lb/s
24.9028348904 kg/s 54.9007898 lb/s
18.8085860323 kg/m3 1.174212454 lb/ft3 ket:
1259.018210472 kg/m3 78.6 lb/ft3

BM 19.02175001 kg/kmol
P 27 atm
R 0.082 atmm3/kmolK
T 333 K
densitas gas 18.80858603 kg/m3

y y
L min G 0 h

y0
xh
H

y y
L min G 0 h

y0
cp xh
H
xh= 0.10%
G= 9401.652 kmol/hr
yo= 0.1186
yh= 0.001
2.6767566552 lb/ft2sec H= 0.1224
D atas Kya= 0.151 kmol/m3dtk
13.0688869323 kg/m2s Lmin 1142.241055 kmol/hr
0.687049663 kmol/m2s
G
0.1183869475 kmol/m2s
xo xh yh yo
L
xo 0.692631185

Ca* 0.016609857 kmol CO2/m3 solution

P 0.0053 atm
H* 0.319087639
H=H*

gas yg terserap per satuan waktu

1.1742124537
78.6

Menghitung Diffusivitas Liquid

1
7,4.10 8.(B .M B ) 2 .T
D AB .10 4
B .V A
R.Tb
VA
P

cp 1
MB=berat molekul solven 56.0616
 R 0.08205 Latm/molK
Tb 194.5 K
P 27 atm
lb/ft2sec miu 0.0056 kg/(ms)
VA 0.034 m3/kgmol
DAB 5.6600E-005 m2/s

Menghitung Diffusivitas Gas

Diffusivitas Biner dapat dihitung dengan persamaan Chapman-Enskog

0,001858.T 1,5 M ij 0,5

Dij 2
10 4
P. ij . D

1 1
M ij
BM i BM j

1
ij ( i j )
2
4 ,909 0,1
kT
kT 1,575
D 44 ,54. 1,911 .
ij ij

0,5
ij j
i .
k k k
dengan :
T : suhu, K
P : tekanan, atm
Mij : berat molekul gabungan
ij : diameter tumbukan gabungan
ij : karakteristik Lennard-Jones gabungan, K
(Perry)

Hasil perhitungan koefisien difusivitas antara CO2 melalui masing-m

Tabel 3. Koefisien difusivitas gas CO2 melalui campuran gas umpan
ij
Komponen ij Mij
k
CO2 H2 3.0955 84.9706 0.5227
CO2 - CH4 3.8495 170.3136 0.0851
CO2 CO 3.793 144.568 0.0584
CO2 - H2O 3.291 397.412 0.0782

DCO2-gas 3.4553E-06 m2/s

 Menghitung Koefisien Trnasfer Massa

aw
0 , 75

0 ,1
LK 2 a p
0 , 05
LK 2
0, 2

1 exp 1,45 c LK
ap a L g
2 a
L p L L L p
0, 7 1
GK G 3 a p DG
k g 5,23. (a p d p ) 2
a p . G G DG RT

2 1 1
LK 3 L 2
0 ,4 L 3
k l 0,0051. (a p d p )
aw L L DL L .g
k y kg P
m2/s
m/s k x kl Ct
1
1 1
K xa
k x mk y
kmol/m2.s aw

kgmol/m3 dengan : Indeks L menunjukkan cairan

kmol/m2.s Indeks G menunjukkan gas
aw : interfacial area efektif, m2/m3
atmm3/kmol C : tegangan muka kritis untuk bahan packing
L : tegangan muka cairan pada suhu 70C
X D : koefisien difusivitas, m2/s
kg : koefisien transfer massa pada film gas, kmol/m2.
kmol/m3.s ky : koefisien transfer massa pada film gas, kmol/m2.
kl : koefisien transfer massa pada film cairan, m/s
kx : koefisien transfer massa pada film cairan, kmol/m
Kya : koefisien transfer massa overall volumetric, kmo
0.056 p Po : tekanan uap, kg/cm2
0.056 g/cm.s miu gas = 15.0531 mP.s
0.0056 kg/m.s ap 38 in2/in3

tekanan upa dapat dihitung dengan persamaan Antoine

o 3103,39
PCO exp 22,5898
2
T 0,16
ETER BAGIAN ATAS KOLOM ABSORBER

masuk kolom per satuan waktu

asuk kolom per satuan waktu - massa gas yg terserap per satuan waktu
FCH4out = 1.187 kmol/hr
FH2out = 2833.733 kmol/hr
FH2Oout = 3216.572 kmol/hr
FCO2out = 1115.415 kmol/hr
FCOout = -1334.745 kmol/hr
O2 = 16.000 kg/s
FO2out = 900.000 kmol/hr
Tgas out = 1200.457 C
design reaktor
Diameter Reaktor = 3.500 m
Pressure Drop = 0.501 bar

kmol/hr
kg/s

1727068.47564138

lb 0.366640888
ft

cek lagi
 1ft= 0.3048 m
30.48 cm

4275.843835 gmol/ft3sec 9.406856 lbmol/ft3sec

2/m3 solution
 333 K
27 atm
0,001858.T 1,5 M ij 0,5
Dij 2
10 4
P. ij . D

2
melalui masing-masing komponen penyusun gas umpan, dapat dilihat pada tabel berikut :

D Dij
0.8845 3.5671E-06
1.1153 7.3810E-07
1.013 6.9339E-07
1.6467 6.5566E-07
0 , 05
LK 2
0, 2


a
L L p

uk bahan packing, untuk metal c = 61 mN/m

da suhu 70C 83.800 mN/m for water chemicalogic

pada film gas, kmol/m2.s.atm

pada film gas, kmol/m2.s
pada film cairan, m/s
pada film cairan, kmol/m2.s
overall volumetric, kmol/m3.s

1.50531E-005 Pa.s (Coulson and Richardson, 1983)

128 m2/m3

rsamaan Antoine
3103,39
T 0,16
bmol/ft3sec
hemicalogic
function secref
%clc,clear
global FH2OO FCH40 FCOO FCO2O FH2o Di Dp VOID RHOB TR Do DReaktor Dekv RI FO20

DReaktor=3.5;%m nilai Re sekitar 4700an dan dP cukup baik

Di=DReaktor;
L=15;%panjang reformer m

RHOB=1070;%densitas bulk kg/m3 taken from topsoe

Dp=0.0118;%diameter partikel m taken from topsoe
VOID=0.38+0.073*(1+(Di/Dp-2)^2/(Di/Dp)^2);%void fraction froment bischoff

FH2OO=0.3860;%kgmol/s
FCH40=0.3860;%kgmol/s 1389.6
FCOO=0.0224;%kgmol/s
FCO2O=0.453;%kgmol/s
FH2o=0.0233;%kgmol/s
FO20=0.5;%kgmol/s
FO=FH2OO+FCH40+FCOO+FCO2O+FH2o+FO20;%kgmol/s

%harga awal
To=600+273.15;%suhu umpan masuk K
TR=298.15;%suhu referensi K
Po=30;%tekanan atm
y1o=0;
y2o=0;
y3o=0;
y0=[y1o y2o To Po y3o 0];
Lspan=[0:L/100:L];
[z,y]=ode15s(@persamaan,Lspan,y0);
y(end,end)
y1=y(:,1);
y2=y(:,2);
y3=y(:,5);

FH2O=FH2OO*(1-y2-2*y3)+2*FCH40*y1;%kgmol/s
FCH4=FCH40-FH2OO*((y2+y3));%kgmol/s
FCO=FCOO+FH2OO*y3;%kgmol/s
FCO2=FCO2O+FH2OO*y3+FCH40*y1;%kgmol/s
FH2=FH2o+FH2OO*(3*y2+4*y3);%kgmol/s
FO2=FO20-FCH40*y1;%kgmol/s
Fsisa=FCH4(end)*3600;
Tgout=y(end,3)-273;

fprintf('FCH4out = %6.3f kmol/hr\n',Fsisa)

fprintf('FH2out = %6.3f kmol/hr\n',FH2(end)*3600)
fprintf('FH2Oout = %6.3f kmol/hr\n',FH2O(end)*3600)
fprintf('FCO2out = %6.3f kmol/hr\n',FCO2(end)*3600)
fprintf('FCOout = %6.3f kmol/hr\n',FCO(end)*3600)
fprintf('O2 = %6.3f kg/s\n',FO20*32)
fprintf('FO2out = %6.3f kmol/hr\n',FO2(end)*3600)
fprintf('Tgas out = %6.3f C\n',Tgout)
disp('design reaktor')
fprintf('Diameter Reaktor = %6.3f m\n',Di)
fprintf('Pressure Drop = %6.3f bar\n',Po-y(end,4))

%plotting hasil
figure(1)
hold on
plot(z,FH2O*3600,'k-',z,FCH4*3600,'b-',z,FCO*3600,'r-',z,FCO2*3600,'c-',z,FH2*3600,'g',z,FO2*3600,'m
xlabel('panjang, z')
ylabel('flow komponen, kgmol/hr')
legend('flow H2O','flow CH4','flow FCO','Flow CO2','Flow H2','FLow O2')

figure(2)
hold on
plot(z,y(:,3))
xlabel('panjang, z')
ylabel('suhu,K')

figure(3)
hold on
plot(z,y(:,4))
xlabel('panjang, z')
ylabel('pressure,atm')

function dydz=persamaan(z,y)
global FH2OO FCH40 FCOO FCO2O FH2o Di Dp VOID RHOB TR Do DReaktor Dekv RI FO20

%reaksi total combution

%CH4+2O2-->CO2+2H2O dH=-802700 kJ/kmol
y1=y(1);
y2=y(2);
y3=y(5);
T=y(3);
P=y(4);
FH2O=FH2OO*(1-y2-2*y3)+2*FCH40*y1;%kgmol/s
FCH4=FCH40-FH2OO*((y2+y3));%kgmol/s
FCO=FCOO+FH2OO*y2;%kgmol/s
FCO2=FCO2O+FH2OO*y3+FCH40*y1;%kgmol/s
FH2=FH2o+FH2OO*(3*y2+4*y3);%kgmol/s
FO2=FO20-2*FCH40*y1;%kgmol/s
FTOT=FH2O+FCH4+FCO+FCO2+FH2+FO2;%kgmol/s
%fraksi
yH2O=FH2O/FTOT;
yCH4=FCH4/FTOT;
yCO=FCO/FTOT;
yCO2=FCO2/FTOT;
yH2=FH2/FTOT;
yO2=FO2/FTOT;
y=[yH2O,yCH4,yCO,yCO2,yH2,yO2];
%pressure parsial
PH2O=yH2O*P;%bar
PCH4=yCH4*P;%bar
PCO=yCO*P;%bar
PCO2=yCO2*P;%bar
PH2=yH2*P;%bar
PO2=yO2*P;%bar
%property viscosity
miuCH4=[3.844 4.0112e-1 -1.4303e-4];
miuCO=[2.3811e1 5.3944e-1 -1.5411e-4];
miuCO2=[1.1811e1 4.9838e-1 -1.0851e-4];
miuH2=[27.758 2.1200e-1 -3.2800e-5];
miuH2O=[-3.6826e1 4.2900e-1 -1.6200e-5];
miuO2=[44.224 5.62e-1 -1.13e-4];
konsmiu=[miuH2O;miuCH4;miuCO;miuCO2;miuH2;miuO2];
miunya=konsmiu(:,1)+T.*konsmiu(:,2)+(T^2).*konsmiu(:,3);
miuavg=y*miunya*1e-7;%kg/m/s
%data kinetika reaksi
A=[1.17E15;5.43E5;2.83E14];%konstanta tumbukan
Er=[240100;67130;243900];%energi aktivasi
M=[18.015 16.043 28.01 44.01 2.016 31.999];%BM masing2 zat
R=8.3145;%kj/kmol/K
%perhitungan konstanta laju reaksi
AK1=A(1)*exp(-Er(1)/R/T)*1e-3;%kgmol/kgcat/s
AK2=A(2)*exp(-Er(2)/R/T)*1e-3;%kgmol/kgcat/s
AK3=A(3)*exp(-Er(3)/R/T)*1e-3;%kgmol/kgcat/s
%perhitungan konstanta adsorpsi CO
AKCO=8.23E-5*exp(8497.71/T);
AKH2=6.12E-9*exp(9971.13/T);
AKH2O=1.77E5*exp(-10666.35/T);
AKCH4=6.65E-4*exp(4604.28/T);
%perhitungan konstanta keseimbangan
AKP1=exp(-26830/T+30.114);
AKP2=exp(4400/T-4.063);
AKP3=AKP1*AKP2;
%term adsorption
DEN=1+AKCO*PCO+AKH2*PH2+AKCH4*PCH4+AKH2O*PH2O/PH2;
DEN=DEN^2;
%kinetika kecepatan reaksi
r2=AK1*((PCH4*PH2O-PH2^3*PCO/AKP1)/DEN/PH2^2.5);
r3=AK2*((PCO*PH2O-PH2*PCO2/AKP2)/DEN/PH2);
r4=AK3*((PCH4*PH2O^2-PH2^4*PCO2/AKP3)/DEN/PH2^3.5);
RJ=8.3145;%kJ/kgmol/K

k1a=8.11e5*exp(-86000/RJ/T)*1e-3;%kgmol/kgcat/s
k1b=6.82e5*exp(-86000/RJ/T)*1e-3;%kgmol/kgcat/s
KCCH4=1.26e-1*exp(27300/RJ/T);%bar-1
KCO2=7.78e-7*exp(92800/RJ/T);%bar-1
ohm=1+KCCH4*PCH4+KCO2*PO2;
r1=k1a*PCH4*PO2/ohm^2+k1b*PCH4*PO2/ohm;

% k1a=3.287e2*exp(-30800/RJ/T)*1e-3%kgmol/kgcat/s
% KCCH4=2.02e-3*exp(36330/RJ/T)%bar-1
% KCO2=7.4e-5*exp(57970/RJ/T)%bar-1
% ohm=1+KCCH4*PCH4+KCO2*abs(PO2)^0.5
% r1=k1a*PCH4*abs(PO2)^0.5/ohm^2

%CPdT tiap zat chem prop handbook, cp dalam kJ/kmol/

CPCH4=34.942*(T-TR)-3.9957E-2/2*(T^2-TR^2)+1.9184E-04/3*(T^3-TR^3)-1.5303E-07/4*(T^4-TR^4
CPCO=29.556*(T-TR)-6.5807E-03/2*(T^2-TR^2)+2.0130E-05/3*(T^3-TR^3)+1.2227E-08/4*(T^4-TR^4
CPCO2=27.437*(T-TR)+4.2315E-02/2*(T^2-TR^2)+1.9555E-05/3*(T^3-TR^3)+3.9968E-09/4*(T^4-TR
CPH2=25.399*(T-TR)+2.0178E-02/2*(T^2-TR^2)-3.8549E-05/3*(T^3-TR^3)+3.1880E-08/4*(T^4-TR^4
CPH2O=33.933*(T-TR)-8.4186E-03/2*(T^2-TR^2)+2.9906E-05/3*(T^3-TR^3)-1.7825E-08/4*(T^4-TR^
CPO2=29.526*(T-TR)-8.8999e-03/2*(T^2-TR^2)+3.8083E-05/3*(T^3-TR^3)-3.2629E-08/4*(T^4-TR^4
%panas reaksi chem prop handbook, kJ/kmol
DHR2=206200+(CPCO+3*CPH2-CPCH4-CPH2O);
DHR3=-41100+(CPCO2+CPH2-CPCO-CPH2O);
DHR4=164900+(CPCO2+4*CPH2-CPCH4-2*CPH2O);
DHR1=-802700+(CPCO2+2*CPH2O-CPCH4-2*CPO2);
%CP kJ/kgmol/K
CPaCH4=34.942-3.9957E-2*T+1.9184E-04*T^2-1.5303E-07*T^3+3.9321E-11*T^4;
CPaCO=29.556-6.5807E-03*T+2.0130E-05*T^2+1.2227E-08*T^3+2.2617E-12*T^4;
CPaCO2=27.437+4.2315E-02*T+1.9555E-05*T^2+3.9968E-09*T^3-2.9872E-13*T^4;
CPaH2=25.399+2.0178E-02*T-3.8549E-05*T^2+3.1880E-08*T^3-8.7585E-12*T^4;
CPaH2O=33.933-8.4186E-03*T+2.9906E-05*T^2-1.7825E-08*T+3.6934E-12*T^4;
CPaO2=29.526-8.8999e-03*T+3.8083E-05*T^2-3.2629E-08*T^3+8.8607E-12*T^4;

%menghitung Cp campuran
CPa=[FH2O FCH4 FCO FCO2 FH2 FO2]*[CPaH2O;CPaCH4;CPaCO;CPaCO2;CPaH2;CPaO2];
CPa=CPa/FTOT;%kj/kmol/K

%data perhitungan pressure drop+koef perpan overall

MAVG=M*[FH2O;FCH4;FCO;FCO2;FH2;FO2];%kg/kgmol
MAVG=MAVG/FTOT;%berat molekul rata-rata
mtot=FTOT*MAVG;%kg/s
G=mtot/(pi*Di^2/4);%kg/m2/s
RI=0.082;%m3atm/kgmol/K
RHOG=P*MAVG/T/RI/1.01325;%kg/m3
REP=Dp*G/miuavg;%bil Re partikel

%persamaan differensial
dy1=r1*pi*Di^2*RHOB/4/2/FCH40;%/m
dy2=(r2-r3)*pi*Di^2*RHOB/4/FH2OO;%/m
dy3=((r1+r3+r4)*pi*Di^2*RHOB/4-FCH40*dy1)/FH2OO;%/m
dT=(-FH2OO*(dy2*DHR2+dy3*(DHR3+DHR4))-FCH40*dy1*DHR1)/(FTOT*CPa);%K/m
dP=-((150*(1-VOID)/REP+1.75)*G.^2/RHOG/Dp*(1-VOID)/VOID.^3)/1e5;%bar/m
DHR=(-FH2OO*(dy2*DHR2+dy3*DHR3)-FCH40*dy1*DHR1);
dydz=[dy1;dy2;dT;dP;dy3;DHR];
Dekv RI FO20
2*3600,'g',z,FO2*3600,'m')

Dekv RI FO20
 .5303E-07/4*(T^4-TR^4)+3.9321E-11/5*(T^5-TR^5);
1.2227E-08/4*(T^4-TR^4)+2.2617E-12/5*(T^5-TR^5);
)+3.9968E-09/4*(T^4-TR^4)-2.9872E-13/5*(T^5-TR^5);
3.1880E-08/4*(T^4-TR^4)-8.7585E-12/5*(T^5-TR^5);
-1.7825E-08/4*(T^4-TR^4)+3.6934E-12/5*(T^5-TR^5);
.2629E-08/4*(T^4-TR^4)+8.8607E-12/5*(T^5-TR^5);
H2;CPaO2];
 yh
xh
L' 1 ln H
h
Kx a L' yo
(1 ) xo
HG '
H

x h xo
G m i n L
H xh

L'
y yo x xo
G'

steam+CO2

yh
G

steam
yo 0
G

komposisi liquid in
BM kmol/hr kadar
benfield 56.0616 491.524991968 30.7369%
CO2 44 1107.61248548 69.2631%
total 47.7073597028 1599.13747745

MENENTUKAN DIAMETER BAGIAN BAWAH KOLOM STRIPPER

L = massa cairan yang masuk kolom per satuan waktu
G = massa gas yang masuk kolom per satuan waktu - massa gas yg terserap per satuan waktu
L 1599.13747745 kmol/hr
BM liquid 47.7073597028
L 76290.6268507 kg/hr
21.1918407919 kg/s
46.7195322098 lb/s
Gmin 55.4435785987 lb/s G actual=1.3Gmin
1897.74812006 kmol/hr G actual 83.1653678981
2846.6221800829
xh xo
G m i n L
H xh

rho G 1.9867 kg/m3 0.1240288812 lb/ft3

rho L 1259.01821047 kg/m3 78.6 lb/ft3

(L/G)*(rhoG/rhoL)^0.5 0.154588089
delta P=0.12F^0.7 1.5028735908 ich/ft

packing=raschig ring ring, 3 inch

F 37
G'^2*F**miu^0.2/(rhoG*rhoL*g) 0.2
=ratio of the density of water to the density of liquid 0.794269687
miu liquid= 5.6
g= 32.2
rhoGrhoLg 313.907175895
F bla bla 41.476998186
G'^2 1.5136446205
G' 1.230302654 lb/ft2sec
A 67.5974871921 ft2
D bawah 9.2796254586 ft 2.8284642339 m

MENENTUKAN DIAMETER BAGIAN ATAS KOLOM ABSORBER

L = massa cairan yang masuk kolom per satuan waktu + massa gas yg terserap per satuan waktu
G = massa gas yang masuk kolom per satuan waktu

L 1812.4981827 kmol/hr
86469.5027625 kg/hr
24.0193063229 kg/s
52.9529627195 lb/s
rho L 78.6 lb/ft3

Gmin 62.8409920158 lb/s G actual 81.6932896205

rho G 0.1240288812 lb/ft3

(L/G)*(rhoG/rhoL)^0.2 0.178370872
delta P=0.12F^0.7 1.5028735908
packing=raschig ring, 3 inch
F 37 37
G'^2*F**miu^0.2/(rhoG*rhoL*g) 0.03
=ratio of the density of water to the density of liquid 0.794269687
miu liquid= 5.6
g= 32.2
rhoGrhoLg 313.907175895
F bla bla 41.476998186
G'^2 0.2270466931
G' 0.476494169
A 171.44656732
D 14.7784732118 ft 4.5045334101 m
 benfield+CO2 L 1599.137 kmol/hr
(rich benfield) xh 69.26%

CO2 yang terserap steam 213.36070525 kmol/hr

lean benfield
L
xo 50.00%
1kg= 2.2046 lb
1m= 3.2808 ft
komposisi gas in
BM
steam 18 P 4 atm
CO2 44 T 175 C
448 K

satuan waktu
 xo 50.00% L'
xh 69.26% y y o ' x xo
G
yo 0
H 0.234354 H 0.0000736 kmol/m3KPa 0.00745752
R 0.08205 Latm/molK
T 383 K
lb/s H 0.2343536846
kmol/hr
yh 0.1082137801

cp

per satuan waktu

lb/s
cp
mol/Latm
PERHITUNGAN DIAMETER DAN TINGGI KOLOM ABSORBER

Kondisi Operasi Aborber

P tinggi, T rendah
P 27 atm
T 60 C
333 K

Packing=Raschig ring, 3 inch

F 37
ap 102 m2/m3
rho 561 kg/m3

Komposisi Gas Masuk

BM flow,kmol/hr y BM average
CO2 44 274.146 0.048174559 2.11968
CO 28 936.794 0.164618991 4.60933
H2O 18 2426.313 0.426366093 7.67459
CH4 16 0.099 1.73969E-005 0.00028
H2 2 2053.328 0.36082296 0.72165
O2 32 0 0 0.00000
total 5416.534 1 15.12553
BM Gas 15.12553 kg/kmol
5690.68
Larutan penyerap=MDEA yang diaktivasi dengan piperazine
Komposisi MDEA
komponen x,wt mol BM x,mol
CO2 0.0000 0 44
MDEA 0.3700 0.0030789458 120.171 0.0838200534
 piperazine 0.0300 0.0003482824 86.137 0.0094815076
H2O 0.6000 0.0333055787 18.015 0.906698439
0.0367328069
BM DMEA 27.266 g/mol
Henry, H 0.43993734

x y X Y
0.0000 0.0000 0.0000 0.0000
0.1000 0.0440 0.1111 0.0460
0.2000 0.0880 0.2500 0.0965
0.3000 0.1320 0.4286 0.1520
0.4000 0.1760 0.6667 0.2136
0.5000 0.2200 1.0000 0.2820
0.6000 0.2640 1.5000 0.3586

slope 0.267 xo 0.189561082

yo 0.05061281 slope itungan 0.266026066
y1 0.00018462
x1 0 5403.491779
23101.78856

y y
L min G 0 h

y0
xh
H

Diameter atas
L = massa cairan yang masuk kolom per satuan waktu
G = massa gas yang masuk kolom per satuan waktu - massa gas yg terserap per satuan waktu
G 5416.534 kmol/hr 0.392962926 G
Lmin 20360.9145 kmol/hr kmol/m2.s
L=2*Lmin
L 28505.2803 kmol/hr L
rho L 63.3660414 lb/ft3
rho G 0.74915517 lb/ft3

(L/G)*(rhoG/rhoL)^0.5 1.0315074764
G'^2*F**miu^0.2/(rhoG*rhoL*g) 0.023
delta P 1.17398511 inc/ft
F=
=ratio of the density of water to the density of liquid
miu liquid=
g=
rhoGrhoLg
F bla bla
G'^2
G'
A
D

1.17398511 delta P

Tinggi absorber

G dX G
Z X Y Yo Xo
Kya Y HX L

integrasi dengan simpson rule Kya

Yo 0.05061281 Kya harusnya segini
Y1 0.00018462
Xo 0.00958229
X1 0 K y a KG a * P
m 0.267
dY 0.00504282 1 1 H

KG kG kL

Y X Y* 1/f(x) factor
0.05061281 0.00958229 0.0025584727 20.80977661 1
0.04556999 0.00862407 0.0023026254 23.11210796 4
0.04052717 0.00766584 0.0020467782 25.98726065 2
0.03548435 0.00670761 0.0017909309 29.67938435 4
0.03044153 0.00574938 0.0015350836 34.59435566 2
0.02539871 0.00479115 0.0012792364 41.46026705 4
0.0203559 0.00383292 0.0010233891 51.72635039 2
0.01531308 0.00287469 0.0007675418 68.74962079 4
0.01027026 0.00191646 0.0005116945 102.4741024 2
0.00522744 0.00095823 0.0002558473 201.142832 4
0.00018462 0 0 5416.534 1
jumlah

NoG = dX/3*dA
NoG 12.3103358
HoG=G/Kya
HoG 2.39793414
Z 29.5193744 m

tinggi packing 35.4232492909 m

ln H=20.267-1.383*10^4/T +0.069*10^5/T2-0.016*10^11/T3+0.012*10^13/T4
ln H -54.8347915
H 1.5330E-024

komposisi mdea
komponen Mr X kmol/hr x
CO2 44.010 0.0002 273.15 0.0095
MDEA 120.171 2390.86 0.0830
piperazine 86.137 270.45 0.0094
H2O 18.015 25862.39 0.8981
 500ppm=500mg/L
0.0005

Komposisi Gas Keluar

flow,kmol/hr y
0.050612809 Yo CO2 CO2 1 0.0001845858
CO 936.794 0.1729188963
H2O 2426.313 0.4478629945
CH4 0.099 0.000018274
H2 2053.328 0.3790152494
O2 0 0
5417.534 1
CO2 yang terserap 13.156259214
 Ca* = 0.01661 kmolCo2/m3 solution
P= 0.0053 atm(dari data kelarutan CO2 di udara)
H= 0.319088 atm.m3/kmol 0.4000
H= H*Ct/P 0.439937 f(x) = 0.2673197736x
y= 0.439937 x 0.3500
Y= 0.278 X 0.3000
Ct=rho/BM(liquid)
rho L 1015 kg/m3 63.36604 lb/ft3 0.2500
BM L 27.266 kg/kmol 0.2000
Ct 37.22585 kmol/m3
0.1500

0.1000
rho G 12 kg/m3
0.749155 lb/ft3 0.0500

0.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
1kg= 2.2046 lb
1m= 3.2808 ft

Diameter bawah
L = massa cairan yang masuk kolom per satuan waktu
rserap per satuan waktu G = massa gas yang masuk kolom per satuan waktu
81927.92747 kg/hr G 5416.534
22.75775763 kg/s 81927.927467
50.17175247 lb/s 22.75775763
28505.28034 kmol/hr 2.068023 50.171752471
777224.9737 kg/hr kmol/m2.s L 28523.699101
215.895826 kg/s 777727.17968
475.9639381 lb/s 216.03532769
476.27148342
(L/G)*(rhoG/rhoL)^0.5
G'^2*F**miu^0.2/(rhoG*rhoL*g)
26 pall ring, 2 inch (metal) delta P
0.794269687 F=
2 cp =ratio of the density of water to the density of liquid
32.2 miu liquid=
1528.566117 g=
23.72178336 rhoGrhoLg
1.482056393 lb/ft2.s F bla bla
1.217397385 lb/ft2.s G'^2
41.21230511 ft2 G'
7.245671241 ft A
2.20850745 m D

G
xo xh y h yo
L aw c
0 , 75

0 ,1
LK 2 a p
1 exp 1,45 LK
ap L a





2
L g
xo 0.013415 p L

xo 0.189561
kalo pake x0=yo/slope L' 56.386722564
c 75
0.021640322 L 83.8
0.085 ap 102
0.3 miu L 0.001
rho L 1015
g 9.8

a -1.33423072
b 1.8804321512
c 1.1875727239
d 0.2054985181
dA e -0.612290488
20.80977661 aw/ap 0.4578922452
92.44843185 aw 46.705009008
51.9745213
118.7175374
69.18871132 Ct=rho/MR
165.8410682 Ct 37.225849043
103.4527008
274.9984831 k y kg P
204.9482048
804.5713281 k x kl Ct
5416.534
7323.484764 kx 0.021427584

1
1 1
Kxa
k x mk y
aw

Y 0.267

Kya 0.1638756128
10^13/T4

X
0.0096
0.0001846199 y1 CO2

kmol/hr
= 0.2673197736x

Column D
Linear (Column D)

.2000 0.4000 0.6000 0.8000 1.0000 1.2000 1.4000 1.6000

g masuk kolom per satuan waktu + massa gas yg terserap per satuan waktu
masuk kolom per satuan waktu
kmol/hr G actual=0.8*Gflooding
kg/hr G actual
kg/s
lb/s
kmol/hr 20374.07 kmol/hr
kg/hr 28523.7 kmol/hr
kg/s 216.0353 kg/s
lb/s 476.2715 lb/s
1.03217399
hoG*rhoL*g) 0.021
1.17398511
26
y of water to the density of liquid 0.79426969
2
32.2
1528.56612
23.7217834
 1.35318192
1.16326348
43.1301707 ft2
7.41234731 ft
2.25931093 m

0, 7 1
0 , 75

0 ,1
LK 2 a p
0 , 05

0, 2
GK G 3
c 2
5,23.
5 LK LK kg
a p . G
(
a a G DG
g
2
L p L L L L p

kg/m2.s 56.38672 kmol/hr G' 5.9437710736 kg/m2.s

mN/m miu G 1.50531E-005 Pa.s
mN/m rho G 12 kg/m3
m2/m3 DG 3.45527E-006 m2/s
kg/m.s dp 0.0508 m
kg/m3 R 0.08205 Latm/molK
m/s2 T 333 K

a 1698.1922625
b 0.7133802351
c 0.0372453648
d 1.28991E-005 0.000582021
kg 0.0005820215 kmol/m2.s.atm
0.4578922452
m2/m3
2 1
LK 3 L 2
k l 0,0051. ( a p d p ) 0 ,4
aw L L DL
kmol/m3 DL 5.77416E-010 m2/s
a 0.5782457341
b 0.0242090228
c 1.9310145832
d 0.0212938085
kl 0.0005756104 m/s
kmol/m2.s ky 0.0157145794 kmol/m2.s

1
117, 3.10 18.(B .M B ) 2 .T
DAB
B .VA0,6

X

kmol/m3.s MB=berat molekul solven
R
Tb
P
miu
VA
DAB
 0, 7 1
G 3 a p DG
(a p d p ) 2
G DG RT

/m2.s.atm

1 1
L 2
0 ,4 L 3
(a p d p )
DL L .g

0.00057561

2.26
27.266 kg/kmol
0.08205 L.atm/molK
 194.5 K
27 atm
0.001 kg/m.s
0.034 m3/kmol
5.7742E-010 m2/s
 y0 L0 x x0

1 y0 G0 1 x 1 x0
y
y0 L0 x x0
1
1 y0 G0 1 x 1 x0

Z l x x0
Ls dx

Z 0
dZ
Kl a
x xl
y0 Ls x x
( ) (
1 1 y0 Gs 1 x 1
(1 x ) ( x
2

H y0 Ls x
1 [( ) (
1 y0 Gs 1 x 1

Kondisi Operasi Stripper

Stripper beroperasi pada tekanan rendah dan suhu tinggi
P 2 atm
T 115 C
388 K

Larutan MDEA yang sudah jenuh dengan CO2, distripper dengan steam superheated
P steam 4 atm
T steam 175 C

Bahan Isian Packing

Pall ring ceramic dengan diameter 2 inch (0.0508 m)
F 20
ap 102 m2/m3
rho 353 kg/m3

Komponen Rich Solution

Rich solution :
komponen Mr x, wt kmol x,mol
CO2 44.010 0.088 2.553 0.00014 x
MDEA 120.171 0.35 2390.86 0.08382 0.084
piperazine 86.137 0.029 270.45 0.00948 0.009
H2O 18.015 0.533 25862.39 0.90670 0.907
massa 777224.9737 kg/hr 28523.7 1.00000 27.22389845
MR solven 27.22389845 kg/kmol

Tekanan uap dapat dihitung dengan persamaan Antoine

o 3103,39 P01=(exp(140.54-(4735/T1)-(21
PCO exp 22,5898
dengan : 2
T 0,16 EXP(94,4914-6789,04/A4-11,45
 o 3103,39
PCO exp 22,5898
2
T 0,16
P : tekanan uap, mmHg
T : suhu, K

Po 2849.08751 366.62288986
y 1424.543755 183.31144493

y x X Y
0 0 0 0.0000
0.1 0.00054552 0.000545817 0.1111
0.2 0.00109104 0.001092231 0.2500
0.3 0.00163656 0.001639242 0.4286
0.4 0.00218208 0.002186851 0.6667
0.5 0.0027276 0.002735059 1.0000
0.6 0.00327312 0.003283867 1.5000
0.7 0.00381864 0.003833276 2.3333
0.8 0.00436416 0.004383287 4.0000
0.9 0.00490968 0.004933901 9.0000

jumlah steam stripping: mGm/Lm = 0.7 sd 0.8

ambil m.Gm/Lm = 0.7 (Colburn)
berdasar pengalaman :
Gm/Lm = 0.033471714 taken from stripper Kaltim 3
Lm = 28523.7 kmol/hr
Gm = 954.7371371 kmol/hr
massa Gm = 17199.85685 kg/hr 4.7777380143 kg/s

P0=(exp(140.54-(4735/T)-(21.268*log(T))+(4.0909E-2*T)))*9.869233E-6;
po = 366.6228899 atm
m= 183.3114449
mGm/Lm = 0.7
Lm = 28523.7 kmol/hr
Gm = 108.921677 kmol/hr
massa Gm = 1962.25451 kg/hr 0.545070697 kg/s

menghitung diameter menara

LTOTAL gas
FLV
GTOTAL cair
rho L = 1283 kg/m3
rho steam = 1.988 kg/m3
FLV 1.176025953
dari grafik didapat
K4 0.7 diambil percentage flooding 80%
K4 baru 0.448
0 ,1
2 cair
42, 9.GK .Fp.
cair
K4
gas ( cair gas )

miu L = 0.001 kg/m.s

rho gas(rho cair-rho gas) 2546.65186
42.9 bla 210.215445
GK^2 5.42728927
GK, kg/m2/s = 2.32965432 kg/m2.s 0.1293154658 kmol/m2.s
A = G/GK 2.0508356 m2
D= 1.61633209 m D bawah
LK,kg/m2/s = 96.0081802 kg/m2.s 3.5266139542 kmol/m2.s

Perhitungan Tinggi Menara

Diffusivitas Liquid

1
117, 3.10 18.(B .M B ) 2
.T
DAB
B .VA 0,6
R.Tb
VA
P

Indeks A menunjukkan solute

Indeks B menunjukkan solvent
MB : berat molekul solven, gr/gmol 27.224 kg/kmol
VA : volume molar solute pada titik didihnya, cm3/gmol
Tb : suhu didih solute, K = 194.5
B : konstanta, untuk cairan (air) B = 2,26
R= 0.08206 L.atm/gmol/K
VCO2 = 0.034 m3/kgmol
miuB = 0.001 kg/m/s
DAB = 2.7150E-09 m2/s
Diffusivitas CO2 dalam gas
Difusivitas biner dapat dihitung dengan menggunakan persamaan Chapman-Enskog sebagai

0,001858.T 1,5 M ij 0,5

Dij 2
10 4
P. ij . D

1 1
M ij
BM i BM
j
1
ij ( i j )
2
4 ,909 0,1
kT 1,575
kT
D 44 ,54. 1,911.
ij ij

0 ,5
ij j
i .
k k k

dengan :
T : suhu, K
P : tekanan, atm
Mij : berat molekul gabungan
ij : diameter tumbukan gabungan
ij : karakteristik Lennard-Jones gabungan, K
(Perry, 1997)
Hasil perhitungan koefisien difusivitas antara CO2 melalui masing-masing komponen penyusu
Tabel 3. Koefisien difusivitas gas CO2 melalui campuran gas umpan

ij
Komponen ij Mij D Dij
k
CO2 - H2O 3.291 397.412 0.0782 1.6467 1.11326E-005

*---Koefisien Transfer Massa---

Koefisien transfer massa fasa gas dan cair ditentukan menggunakan
metode Onda, yang dinyatakan dalam bentuk persamaan sebagai berikut :
aw c
0 , 75
LK
0 ,1
LK 2 a p
0 , 05
LK 2
0, 2


1 exp 1,45
ap a 2g L L a p
L p L L
0, 7 1
GK G 3 a p DG
kg 5,23. (a p d p ) 2
a p . G G DG RT

2 1 1
LK 3 L 2
0 ,4 L 3
k l 0,0051. (a p d p )
aw L L DL L .g
 2 1 1
LK 3 L 2
0 ,4 L 3
k l 0,0051. (a p d p )
aw L L DL L .g
k y kg P

k x kl Ct Ct=rho/MR
1
1 k
K ya aw
k y kx

Po
k
P
dengan : Indeks L menunjukkan cairan
Indeks G menunjukkan gas
aw : interfacial area efektif, m2/m3
C : tegangan muka kritis untuk bahan packing, untuk metal c = 75 mN/m
L : tegangan muka cairan pada suhu 70C
D : koefisien difusivitas, m2/s
kg : koefisien transfer massa pada film gas, kmol/m2.s.atm
ky : koefisien transfer massa pada film gas, kmol/m2.s
kl : koefisien transfer massa pada film cairan, m/s
kx : koefisien transfer massa pada film cairan, kmol/m2.s
Kya : koefisien transfer massa overall volumetric, kmol/m3.s
Po : tekanan uap, kg/cm2
miu steam = 15.0531 mP.s 1.50531E-005 kg/m/s
Tekanan uap dapat dihitung dengan persamaan Antoine
o 3103,39 ...(55)
PCO exp 22,5898
dengan : 2
T 0,16
P : tekanan uap, mmHg
T : suhu, K

aw c
0 , 75

0 ,1
LK 2 a p
0 , 05
LK 2
0, 2

1 exp 1,45 LK
ap a L g
2 a
L p L L L p
c 75 mN/m
L 64.009 mN/m
LK 96.00818016 kg/m2.s
miu L 0.001 kg/m.s
ap 102 m2/m3
rho L 1283 kg/m3
g 9.8 m/s2
a -1.63299793
b 1.983219603
c 0.867514741
d 0.256041509
aw/ap 0.512934023
aw 52.31927038 m2/m3

2 1 1
LK 3 L 2
0 ,4 L 3
k l 0,0051. (a p d p )
aw L L DL L .g
DL 2.7150E-09 m2/s
a 16.02778
b 0.05902
c 1.93101458
d 0.01969396

kL 0.00171574 m/s

1
1 k
K ya aw Kxa 0.5106844625 kmol/m3.s
ky k x

Integrasi dengan simpson rule

xo = 0.00014 yo = 0H 1424.5437552
x1 = 0.000 Xo = 0.000139019
dx = 0.0000139
Tinggi Stripper

Z l x x0
Ls dx

Z 0
dZ
Kl a
x xl y0 L x x0
( ) s ( )
1 1 y G 1 x 1 x0
(1 x ) ( x
2 0 s

H y0 Ls x x0
1 [( ) ( )]

1 y0 Gs 1 x 1 x0

x X f(x) 1/f(x) factor dA

0.000 0 2.661E-006 375743.0487 1 375743.04873
0.000 1.3900E-005 1.629E-005 61369.14704 4 245476.58818
0.000 2.7801E-005 2.993E-005 33414.0756 2 66828.151208
0.000 4.1702E-005 4.356E-005 22957.14839 4 91828.593558
0.000 5.5603E-005 5.719E-005 17485.40278 2 34970.805551
0.000 6.9505E-005 7.082E-005 14120.11747 4 56480.469871
0.000 0.000083407 8.445E-005 11841.24845 2 23682.4969
0.000 9.7309E-005 9.808E-005 10195.82054 4 40783.28218
0.000 0.000111212 0.00011171 8951.951386 2 17903.902771
0.000 0.000125116 0.00012533 7978.629608 4 31914.518432
0.000 0.000139019 0.00013896 7196.245021 1 7196.2450214
992808.1024

Luas = dx/3*(Total)
luas 4.60001087
HoG 6.90566135
Z 31.7661173 m
 Ls x x0
( )
Gs 1 x 1 x0

Ls x x0
) ( )]
Gs 1 x 1 x0

CO2 yang terbawa steam

2.553 kmol/hr

Lean Solution
rho massa x,wt htng kmol x, mol
0 0.000 0.000 0.000
272028.7408 0.384 2263.678 0.089
22539.52424 0.032 261.671 0.010
414260.911 0.584 22994.975 0.901
708829.176 25520.323

xp(140.54-(4735/T1)-(21.268*log(T1))+(4.0909E-2*T1)))*9.869233E-6;
4,4914-6789,04/A4-11,4519*LN(A4)-0,010454*A4)
 P01=(exp(140.54-(4735/T1)-(21.268*log(T1))+(4.0909E-2*T1)))*9.869233E-6;
EXP(94,4914-6789,04/A4-11,4519*LN(A4)-0,010454*A4)

10.0000
9.0000
8.0000
7.0000
6.0000
5.0000
Column E
4.0000
3.0000
2.0000
1.0000
0.0000
0 0.001 0.002 0.003 0.004 0.005 0.006

dalam atm
Diamter atas stripper
L = massa cairan yang masuk kolom per satuan waktu + massa gas yg terserap per satuan
G = massa gas yang masuk kolom per satuan waktu
Lm 28526.253 kmol/hr
Gm 954.7371371 kmol/hr
massa Gm 17199.85685 kg/hr 4.7777380143 kg/s
rho L 1283 kg/m3
rho steam 1.988 kg/m3
FLV 1.176131212
dari grafik didapat
K4 0.4 diambil percentage flooding 80%
K4 baru 0.32
GK^2 4.845793993
GK 2.201316423 kg/m2.s
A=G/GK 2.170400386 m2
D atas 1.662781181 m
pman-Enskog sebagai berikut :

ng komponen penyusun gas umpan, dapat dilihat pada tabel berikut :

LK 2
0, 2


L L a p

c = 75 mN/m
64.009 mN/n for water

(Coulson and Richardson, 1983)

0, 7 1
GK G 3 a p DG
kg 5,23. ( a p d p ) 2
a p . G G DG RT

GK 2.3296543246 kg/m2.s
miu G 1.50531E-005 kg/m.s
rho G 18.015 kg/m3
DG 1.11326E-005
R 0.08205 Latm/molK
T 388 K
dp 0.0508 m
 a 881.55100604
b 0.4218222661
c 0.0372453648
d 3.56686E-005
kg 0.0004940097 kmol/m2.s.atm

k y kg P
ky 0.0009880194 kmol/m2.s

k x kl Ct
Ct=rho/mr
Ct 47.127710323 kmol/m3
kx 0.0808590795 kmol/m2.s

x0
)
x 1 x0

x x0
)]
x 1 x0
Lean Solution
x,wt mol x, mol
0 0 0.00000
0.37 0.003078942 0.08382
0.03 0.0003482829 0.00948
0.6 0.033305061 0.90670
assumsi hanya CO2 yang terstripping
0.0367322859
))*9.869233E-6;

Column E

0.006
sa gas yg terserap per satuan waktu