Vous êtes sur la page 1sur 38

Sistema: Acetonitrilo(A) Nitrometano(B)

Constantes de Antoine A1 14.2724 14.2043


presin en KiloPa y T en C A2 2945.47 2972.64
A3 224 209

Sistema: Benceno(A) Etilbenceno(B)


Constantes de Antoine A1 13.8858 14.0045
presin en KiloPa y T en C A2 2788.51 3279.47
A3 220.79 213.2

Sistema: 1-Clorobutano(A) Clorobenceno(B)


Constantes de Antoine A1 13.96 13.9926
presin en KiloPa y T en C A2 2826.26 3295.12
A3 224.1 217.55

Sistema: Acetona(A) Acetonitrilo(B)


Constantes de Antoine A1 14.5463 14.2724
presin en KiloPa y T en C A2 2940.46 2945.47
A3 237.22 224

Sistema: n-Pentano(A) n-Heptano(B)


Constantes de Antoine A1 13.8183 13.8587
presin en KiloPa y T en C A2 2477.07 2911.32
A3 233.21 216.64

Sistema: Benceno(A) Tolueno(B)


Constantes de Antoine A1 13.8858 13.9987
presin en KiloPa y T en C A2 2788.51 3096.52
A3 220.79 219.48
Sistema: Benceno(A) Etilbenceno(B)
Constantes de Antoine A1 13.8858 14.0045
presin en KiloPa y T en C A2 2788.51 3279.47
A3 220.79 213.2

Sistema: 1-Clorobutano(A) Benceno(B)


Constantes de Antoine A1 13.96 13.8858
presin en KiloPa y T en C A2 2826.26 2788.51
A3 224.1 220.79

Sistema: n-Pentano(A) n-Hexano(B)


Constantes de Antoine A1 13.8183 13.8216
presin en KiloPa y T en C A2 2477.07 2697.55
A3 233.21 224.37

Sistema: n-Hexano(A) Trietilamina(B)


A1
A2
A3

A2
lnP sat A1
T A3
Sistema: n-Pentano(A)n-Heptano(B) DIAGRAMA T-x,y a Presin constante
Constantes de Antoine A1 13.8183 13.8587
presin en KiloPa y T en C A2 2477.07 2911.32 Ingrese la Presin, KiloPascal, =
A3 233.21 216.64

A2
lnP sat A1
T A3 i
0
P PvB 0.01
xA 1bar= 100 Kpa 0.02
PvA PvB 1atm= 760 mm Hg 0.03
PvA 1atm= 14,696 psi 0.04
yA xA 1atm= 1,01325 bar 0.05
P 1atm= 101,325 Kpa 0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
53.82 0.5045 0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1
DIAGRAMA T-x,y a Presin constante

ngrese la Presin, KiloPascal, = 101.325 1 atm


TsA= 36.03771 C
TsB= 98.425414 puro

T C PsA PsB xA yA diagonal xi ln xi


36.03771 101.325 10.3483689 1 1 1
36.661587 103.503067 10.6462431 0.97654382 0.99753545 0.97654382 -0.1112010861
37.285464 105.717581 10.9511642 0.95364834 0.99499033 0.95364834 -0.1876294759
37.9093411 107.968956 11.2632595 0.93129716 0.99236301 0.93129716 -0.2502706058
38.5332181 110.257608 11.5826575 0.90947441 0.98965184 0.90947441 -0.3037521663
39.1570952 112.583955 11.9094882 0.88816475 0.98685516 0.88816475 -0.3503352591
39.7809722 114.948414 12.2438833 0.86735333 0.98397128 0.86735333 -0.3913871298
40.4048492 117.351408 12.5859756 0.8470258 0.98099847 0.8470258 -0.427833638
41.0287263 119.79336 12.9358995 0.82716827 0.97793502 0.82716827 -0.4603479938
41.6526033 122.274693 13.2937911 0.8077673 0.97477916 0.8077673 -0.4894442584
42.2764804 124.795835 13.6597877 0.78880988 0.97152912 0.78880988 -0.5155292237
42.9003574 127.357212 14.0340281 0.77028344 0.96818309 0.77028344 -0.5389336329
43.5242344 129.959255 14.4166528 0.75217578 0.96473925 0.75217578 -0.5599321566
44.1481115 132.602395 14.8078035 0.73447512 0.96119575 0.73447512 -0.5787568054
44.7719885 135.287065 15.2076234 0.71717003 0.95755074 0.71717003 -0.5956062929
45.3958656 138.013699 15.6162575 0.70024946 0.9538023 0.70024946 -0.6106527833
46.0197426 140.782732 16.033852 0.68370271 0.94994854 0.68370271 -0.6240468893
46.6436196 143.594604 16.4605545 0.66751941 0.94598752 0.66751941 -0.635921457
47.2674967 146.449753 16.8965144 0.6516895 0.94191726 0.6516895 -0.6463944925
47.8913737 149.348619 17.3418824 0.63620327 0.9377358 0.63620327 -0.6555714617
48.5152508 152.291645 17.7968106 0.62105128 0.93344112 0.62105128 -0.6635471267
49.1391278 155.279274 18.2614527 0.60622441 0.92903119 0.60622441 -0.6704070306
49.7630048 158.311951 18.735964 0.59171379 0.92450396 0.59171379 -0.6762287142
50.3868819 161.390123 19.2205011 0.57751085 0.91985736 0.57751085 -0.6810827219
51.0107589 164.514237 19.7152221 0.56360727 0.91508927 0.56360727 -0.6850334425
51.634636 167.684743 20.2202867 0.549995 0.91019758 0.549995 -0.6881398176
52.258513 170.902091 20.735856 0.53666621 0.90518014 0.53666621 -0.6904559438
52.88239 174.166733 21.2620926 0.52361333 0.90003476 0.52361333 -0.6920315872
53.5062671 177.479122 21.7991606 0.510829 0.89475927 0.510829 -0.6929126276
54.1301441 180.839712 22.3472256 0.49830611 0.88935143 0.49830611 -0.693141442
54.7540212 184.248959 22.9064546 0.48603774 0.883809 0.48603774 -0.6927572402
55.3778982 187.70732 23.4770162 0.47401717 0.87812971 0.47401717 -0.6917963573
56.0017753 191.215253 24.0590804 0.46223791 0.87231126 0.46223791 -0.6902925121
56.6256523 194.773217 24.6528186 0.45069364 0.86635134 0.45069364 -0.6882770349
57.2495293 198.381672 25.258404 0.43937824 0.86024761 0.43937824 -0.6857790696
57.8734064 202.04108 25.8760109 0.42828575 0.85399769 0.42828575 -0.6828257538
58.4972834 205.751904 26.5058153 0.41741042 0.84759919 0.41741042 -0.6794423797
59.1211605 209.514607 27.1479944 0.40674663 0.8410497 0.40674663 -0.6756525382
59.7450375 213.329654 27.8027274 0.39628896 0.83434677 0.39628896 -0.6714782485
60.3689145 217.19751 28.4701943 0.38603212 0.82748794 0.38603212 -0.6669400748
60.9927916 221.118643 29.1505771 0.37597099 0.8204707 0.37597099 -0.6620572321
61.6166686 225.093519 29.844059 0.36610058 0.81329256 0.36610058 -0.6568476813
62.2405457 229.122608 30.5508247 0.35641607 0.80595095 0.35641607 -0.6513282163
62.8644227 233.20638 31.2710604 0.34691276 0.79844332 0.34691276 -0.6455145422
63.4882997 237.345304 32.0049537 0.33758609 0.79076707 0.33758609 -0.6394213479
64.1121768 241.539852 32.7526937 0.32843163 0.78291958 0.32843163 -0.6330623707
64.7360538 245.790497 33.5144709 0.31944507 0.77489821 0.31944507 -0.6264504562
65.3599309 250.097711 34.2904771 0.31062222 0.76670029 0.31062222 -0.6195976132
65.9838079 254.461968 35.080906 0.30195904 0.75832312 0.30195904 -0.612515063
66.6076849 258.883743 35.8859521 0.29345155 0.74976399 0.29345155 -0.6052132854
67.231562 263.363511 36.7058119 0.28509593 0.74102014 0.28509593 -0.5977020602
67.855439 267.901749 37.540683 0.27688844 0.73208881 0.27688844 -0.5899905053
68.4793161 272.498932 38.3907644 0.26882546 0.72296719 0.26882546 -0.5820871119
69.1031931 277.15554 39.2562568 0.26090345 0.71365246 0.26090345 -0.5739997759
69.7270701 281.872049 40.1373619 0.25311898 0.70414178 0.25311898 -0.5657358271
70.3509472 286.648939 41.0342832 0.24546873 0.69443227 0.24546873 -0.5573020555
70.9748242 291.486689 41.9472255 0.23794944 0.68452103 0.23794944 -0.5487047352
71.5987013 296.38578 42.8763947 0.23055795 0.67440512 0.23055795 -0.5399496458
72.2225783 301.346691 43.8219985 0.22329122 0.66408161 0.22329122 -0.5310420918
72.8464553 306.369904 44.7842457 0.21614623 0.6535475 0.21614623 -0.5219869196
73.4703324 311.4559 45.7633467 0.2091201 0.64279979 0.2091201 -0.5127885325
74.0942094 316.605162 46.7595131 0.20220999 0.63183546 0.20220999 -0.5034509039
74.7180865 321.818173 47.7729579 0.19541316 0.62065144 0.19541316 -0.4939775878
75.3419635 327.095414 48.8038956 0.18872693 0.60924465 0.18872693 -0.4843717284
75.9658405 332.43737 49.8525418 0.1821487 0.59761198 0.1821487 -0.474636066
76.5897176 337.844525 50.9191138 0.17567592 0.58575029 0.17567592 -0.4647729427
77.2135946 343.317362 52.0038299 0.16930614 0.57365643 0.16930614 -0.4547843045
77.8374717 348.856367 53.1069099 0.16303695 0.5613272 0.16303695 -0.4446717012
78.4613487 354.462023 54.2285749 0.15686602 0.54875939 0.15686602 -0.434436285
79.0852257 360.134818 55.3690475 0.15079106 0.53594976 0.15079106 -0.4240788049
79.7091028 365.875235 56.5285513 0.14480986 0.52289504 0.14480986 -0.413599599
80.3329798 371.68376 57.7073115 0.13892026 0.50959194 0.13892026 -0.4029985836
80.9568569 377.560881 58.9055544 0.13312015 0.49603713 0.13312015 -0.3922752381
81.5807339 383.507082 60.1235077 0.1274075 0.48222727 0.1274075 -0.3814285859
82.2046109 389.52285 61.3614003 0.1217803 0.46815899 0.1217803 -0.3704571709
82.828488 395.608671 62.6194626 0.11623661 0.45382888 0.11623661 -0.3593590278
83.452365 401.765033 63.897926 0.11077454 0.43923353 0.11077454 -0.3481316455
84.0762421 407.992422 65.1970234 0.10539224 0.42436948 0.10539224 -0.3367719237
84.7001191 414.291325 66.5169888 0.10008792 0.40923324 0.10008792 -0.3252761183
85.3239962 420.662229 67.8580576 0.09485983 0.39382133 0.09485983 -0.3136397766
85.9478732 427.10562 69.2204662 0.08970625 0.37813019 0.08970625 -0.3018576572
86.5717502 433.621986 70.6044525 0.08462552 0.36215629 0.08462552 -0.2899236325
87.1956273 440.211814 72.0102556 0.07961602 0.34589602 0.07961602 -0.2778305681
87.8195043 446.875591 73.4381156 0.07467618 0.32934579 0.07467618 -0.2655701737
88.4433814 453.613804 74.888274 0.06980445 0.31250195 0.06980445 -0.2531328169
89.0672584 460.426939 76.3609735 0.06499932 0.29536085 0.06499932 -0.2405072877
89.6911354 467.315484 77.856458 0.06025934 0.27791878 0.06025934 -0.227680497
90.3150125 474.279925 79.3749725 0.05558306 0.26017204 0.05558306 -0.214637087
90.9388895 481.320749 80.9167633 0.05096911 0.24211688 0.05096911 -0.2013589168
91.5627666 488.438442 82.4820777 0.04641613 0.22374953 0.04641613 -0.1878243726
92.1866436 495.63349 84.0711643 0.04192278 0.2050662 0.04192278 -0.1740074204
92.8105206 502.90638 85.6842728 0.03748777 0.18606306 0.03748777 -0.1598762707
93.4343977 510.257597 87.3216542 0.03310985 0.16673627 0.03310985 -0.1453914364
94.0582747 517.687627 88.9835603 0.02878778 0.14708196 0.02878778 -0.1305027975
94.6821518 525.196956 90.6702444 0.02452037 0.12709621 0.02452037 -0.1151449454
95.3060288 532.786068 92.3819606 0.02030644 0.10677511 0.02030644 -0.0992293372
95.9299058 540.455448 94.1189644 0.01614485 0.0861147 0.01614485 -0.0826299551
96.5537829 548.20558 95.8815121 0.01203449 0.06511101 0.01203449 -0.0651539556
97.1776599 556.036949 97.6698614 0.00797426 0.04376002 0.00797426 -0.0464703111
97.801537 563.950039 99.4842708 0.00396311 0.0220577 0.00396311 -0.0258741262
98.425414 571.945333 101.325 0.00 0.00 0
DIAGRAMA P-x,y a Temperatura constante

Ingrese laTemperatura, C = 100


PsA= 592.493223 Kpascal puro
PsB= 106.089558 puro

i P, Kpa PsA PsB xA yA


0 106.089558 592.493223 106.089558 0 0
0.01 110.953595 592.493223 106.089558 0.01 0.05340009
0.02 115.817632 592.493223 106.089558 0.02 0.10231486
0.03 120.681668 592.493223 106.089558 0.03 0.14728663
0.04 125.545705 592.493223 106.089558 0.04 0.18877371
0.05 130.409742 592.493223 106.089558 0.05 0.22716601
0.06 135.273778 592.493223 106.089558 0.06 0.26279737
0.07 140.137815 592.493223 106.089558 0.07 0.29595528
0.08 145.001852 592.493223 106.089558 0.08 0.32688864
0.09 149.865888 592.493223 106.089558 0.09 0.35581406
0.1 154.729925 592.493223 106.089558 0.1 0.3829209
0.11 159.593961 592.493223 106.089558 0.11 0.40837544
0.12 164.457998 592.493223 106.089558 0.12 0.43232429
0.13 169.322035 592.493223 106.089558 0.13 0.4548972
0.14 174.186071 592.493223 106.089558 0.14 0.47620944
0.15 179.050108 592.493223 106.089558 0.15 0.49636375
0.16 183.914145 592.493223 106.089558 0.16 0.51545201
0.17 188.778181 592.493223 106.089558 0.17 0.53355662
0.18 193.642218 592.493223 106.089558 0.18 0.5507517
0.19 198.506255 592.493223 106.089558 0.19 0.56710411
0.2 203.370291 592.493223 106.089558 0.2 0.58267431
0.21 208.234328 592.493223 106.089558 0.21 0.59751712
0.22 213.098365 592.493223 106.089558 0.22 0.61168235
0.23 217.962401 592.493223 106.089558 0.23 0.62521536
0.24 222.826438 592.493223 106.089558 0.24 0.63815755
0.25 227.690475 592.493223 106.089558 0.25 0.65054678
0.26 232.554511 592.493223 106.089558 0.26 0.66241776
0.27 237.418548 592.493223 106.089558 0.27 0.67380233
0.28 242.282584 592.493223 106.089558 0.28 0.68472979
0.29 247.146621 592.493223 106.089558 0.29 0.69522712
0.3 252.010658 592.493223 106.089558 0.3 0.70531924
0.31 256.874694 592.493223 106.089558 0.31 0.71502917
0.32 261.738731 592.493223 106.089558 0.32 0.7243782
0.33 266.602768 592.493223 106.089558 0.33 0.7333861
0.34 271.466804 592.493223 106.089558 0.34 0.74207119
0.35 276.330841 592.493223 106.089558 0.35 0.75045054
0.36 281.194878 592.493223 106.089558 0.36 0.75853999
0.37 286.058914 592.493223 106.089558 0.37 0.76635435
0.38 290.922951 592.493223 106.089558 0.38 0.7739074
0.39 295.786988 592.493223 106.089558 0.39 0.78121204
0.4 300.651024 592.493223 106.089558 0.4 0.78828033
0.41 305.515061 592.493223 106.089558 0.41 0.79512356
0.42 310.379097 592.493223 106.089558 0.42 0.80175229
0.43 315.243134 592.493223 106.089558 0.43 0.80817648
0.44 320.107171 592.493223 106.089558 0.44 0.81440543
0.45 324.971207 592.493223 106.089558 0.45 0.82044792
0.46 329.835244 592.493223 106.089558 0.46 0.82631219
0.47 334.699281 592.493223 106.089558 0.47 0.83200601
0.48 339.563317 592.493223 106.089558 0.48 0.83753672
0.49 344.427354 592.493223 106.089558 0.49 0.84291121
0.5 349.291391 592.493223 106.089558 0.5 0.84813602
0.51 354.155427 592.493223 106.089558 0.51 0.85321732
0.52 359.019464 592.493223 106.089558 0.52 0.85816093
0.53 363.883501 592.493223 106.089558 0.53 0.86297237
0.54 368.747537 592.493223 106.089558 0.54 0.86765689
0.55 373.611574 592.493223 106.089558 0.55 0.87221943
0.56 378.47561 592.493223 106.089558 0.56 0.87666469
0.57 383.339647 592.493223 106.089558 0.57 0.88099715
0.58 388.203684 592.493223 106.089558 0.58 0.88522104
0.59 393.06772 592.493223 106.089558 0.59 0.88934039
0.6 397.931757 592.493223 106.089558 0.6 0.89335904
0.61 402.795794 592.493223 106.089558 0.61 0.89728064
0.62 407.65983 592.493223 106.089558 0.62 0.90110865
0.63 412.523867 592.493223 106.089558 0.63 0.90484639
0.64 417.387904 592.493223 106.089558 0.64 0.90849701
0.65 422.25194 592.493223 106.089558 0.65 0.91206353
0.66 427.115977 592.493223 106.089558 0.66 0.91554882
0.67 431.980014 592.493223 106.089558 0.67 0.91895562
0.68 436.84405 592.493223 106.089558 0.68 0.92228655
0.69 441.708087 592.493223 106.089558 0.69 0.92554412
0.7 446.572123 592.493223 106.089558 0.7 0.92873073
0.71 451.43616 592.493223 106.089558 0.71 0.93184868
0.72 456.300197 592.493223 106.089558 0.72 0.93490015
0.73 461.164233 592.493223 106.089558 0.73 0.93788725
0.74 466.02827 592.493223 106.089558 0.74 0.94081199
0.75 470.892307 592.493223 106.089558 0.75 0.94367632
0.76 475.756343 592.493223 106.089558 0.76 0.94648207
0.77 480.62038 592.493223 106.089558 0.77 0.94923104
0.78 485.484417 592.493223 106.089558 0.78 0.95192492
0.79 490.348453 592.493223 106.089558 0.79 0.95456536
0.8 495.21249 592.493223 106.089558 0.8 0.95715392
0.81 500.076527 592.493223 106.089558 0.81 0.95969214
0.82 504.940563 592.493223 106.089558 0.82 0.96218145
0.83 509.8046 592.493223 106.089558 0.83 0.96462326
0.84 514.668636 592.493223 106.089558 0.84 0.96701892
0.85 519.532673 592.493223 106.089558 0.85 0.96936972
0.86 524.39671 592.493223 106.089558 0.86 0.9716769
0.87 529.260746 592.493223 106.089558 0.87 0.97394169
0.88 534.124783 592.493223 106.089558 0.88 0.97616522
0.89 538.98882 592.493223 106.089558 0.89 0.97834862
0.9 543.852856 592.493223 106.089558 0.9 0.98049297
0.91 548.716893 592.493223 106.089558 0.91 0.9825993
0.92 553.58093 592.493223 106.089558 0.92 0.98466861
0.93 558.444966 592.493223 106.089558 0.93 0.98670188
0.94 563.309003 592.493223 106.089558 0.94 0.98870003
0.95 568.17304 592.493223 106.089558 0.95 0.99066397
0.96 573.037076 592.493223 106.089558 0.96 0.99259458
0.97 577.901113 592.493223 106.089558 0.97 0.99449268
0.98 582.765149 592.493223 106.089558 0.98 0.9963591
0.99 587.629186 592.493223 106.089558 0.99 0.99819462
1 592.493223 592.493223 106.089558 1 1
g
RT

-0.05600153 120.00 Diagrama a P cte


-0.09803911
110.00
-0.13474217
-0.16794415 100.00
-0.19851524 V
90.00
-0.22696752
-0.25363895 80.00
-0.27876937 L + V
T 70.00
-0.30253782
-0.32508297 60.00
-0.34651534
50.00
-0.36692499
-0.38638671 40.00 L
-0.40496349
30.00
-0.42270909
-0.43966988 20.00
-0.45588621 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.47139349 x, y
-0.48622296
-0.50040242
-0.51395667
-0.52690796 700 Diagrama a T cte
-0.53927634
-0.55107993
600
-0.56233514
-0.57305692
-0.58325884 500
-0.59295332
400 L
-0.60215168
-0.6108643 P
-0.61910066 300
-0.62686946 L + V
-0.63417864
200
-0.64103548
-0.64744664 V
-0.65341819 100
-0.65895568
-0.66406413 0
-0.66874809 0 0.1 0.2 0.3 0.4 0.5
x,y 0.6 0.7 0.8 0.9 1
-0.67301167
-0.67685855
-0.680292 1 Diagrama composicin
-0.68331491 0.9
-0.6859298
-0.68813881 0.8
-0.68994376
0.7
0.6

y 0.5
0.4
1 Diagrama composicin
0.9
0.8
0.7
-0.6913461
-0.69234697 0.6
-0.69294717
y 0.5
-0.69314718
-0.69294717 0.4
-0.69234697
-0.6913461 0.3
-0.68994376 0.2
-0.68813881
-0.6859298 0.1
-0.68331491 0
-0.680292
0 0.1 0.2 0.3 0.4 0.5
x 0.6 0.7 0.8 0.9 1
-0.67685855
-0.67301167
-0.66874809
-0.66406413
-0.65895568
-0.65341819
0
-0.64744664 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
-0.64103548
-0.63417864 -0.1
-0.62686946
-0.61910066
-0.6108643 -0.2
-0.60215168
-0.59295332
-0.58325884 -0.3
-0.57305692
-0.56233514
-0.55107993 -0.4
-0.53927634
-0.52690796
-0.51395667 -0.5
-0.50040242
-0.48622296
-0.47139349 -0.6
-0.45588621
-0.43966988
-0.42270909 -0.7
-0.40496349
-0.38638671
-0.36692499
-0.8
-0.34651534
-0.32508297
-0.30253782
-0.27876937
-0.25363895
-0.22696752
-0.19851524
-0.16794415
-0.13474217
-0.09803911
-0.05600153
0.8 0.9 1

120.0

110.0

100.0

90.0

80.0

T, C70.0

60.0

50.0

8 0.9 1 40.0

30.0

20.0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, y
8 0.9 1

0.7 0.8 0.9 1


0.8 0.9 1
Sistema: Acetona(A) Benceno(B) DIAGRAMA T-x,y a Presin con
Constantes de Antoine A1 14.5463 13.8859
presin en KiloPa y T en C A2 2940.46 2788.51 Ingrese la Presin, KiloPascal,
A3 237.22 220.79
P B PvB
xA A2
A PvA B PvB lnP sat A1
T A3
A PvA
yA xA
P
alfa= 0.405
beta= 0.405
L
ln
x 1bar= 100 Kpa
A 2


1 A
1atm= 760 mm Hg
xB
1atm= 14,696 psi
L 1atm= 1,01325 bar
ln 2
B

xB 1atm= 101,325 Kpa

1
x A

DIAGRAMA P-x,y a Temperatur

Ingrese la Temperatura en C =
DIAGRAMA T-x,y a Presin constante

ngrese la Presin, KiloPascal, = 101.325 1 atm


TsA= 58.9594747 puro
TsB= 80.0991171 puro

T C PsA PsB xAsupuesto A B xA calculado


80.099 196.316074 101.324635 1.8927E-006 1.499300201 1 0.00
79 190.094377 97.9400528 0.01843644 1.477282341 1.0001376699 0.018436444
78 184.568624 94.9380788 0.03644856 1.456468555 1.0005381863 0.036448571
76 173.896029 89.1512274 0.07654814 1.412511254 1.0023759633 0.076548143
72 154.010161 78.4118452 0.17795897 1.314793132 1.0129087123 0.177958972
70 144.765216 73.4401804 0.24319555 1.261075534 1.0242425365 0.243195546
68 135.964876 68.7213633 0.32192362 1.204679997 1.0428653834 0.321923625
66 127.593905 64.2462118 0.41824916 1.146903596 1.0734176307 0.41824916
64 119.637316 60.0057041 0.53756232 1.09046988 1.1241578363 0.537562319
62 112.080375 55.9909819 0.68681617 1.040523618 1.2105141211 0.686816167
61 108.44724 54.0655677 0.77562968 1.020597792 1.27589586 0.775629678
60 104.908609 52.1933538 0.87663813 1.006182384 1.3651171327 0.87663813
59 101.462716 50.3732805 0.99471213 1.000011324 1.492911365 0.994712135
58.9594747 101.325 50.3006057 0.99999999 1 1.4993024879 1.000000003

DIAGRAMA P-x,y a Temperatura constante

ngrese la Temperatura en C = 70
PsA= 144.765216 puro
PsB= 73.4401804 puro

P Kpa PsA PsB xAsupuesto A B xA calculado


73.45 144.765216 73.4401804 0.000068379 1.499219463 1.0000000019 6.8383E-005
77 144.765216 73.4401804 0.02543196 1.469117764 1.0002619821 0.025431959
81 144.765216 73.4401804 0.05564184 1.435027475 1.0012546723 0.055641836
85 144.765216 73.4401804 0.08775345 1.40079296 1.003123639 0.087753446
90 144.765216 73.4401804 0.13087771 1.357882213 1.0069613532 0.13087771
95 144.765216 73.4401804 0.17774176 1.31498333 1.0128770178 0.177741758
100 144.765216 73.4401804 0.22886254 1.272310397 1.0214397128 0.228862539
105 144.765216 73.4401804 0.28482548 1.230163652 1.033401563 0.284825482
115 144.765216 73.4401804 0.41393123 1.14924824 1.0718566381 0.413931227
125 144.765216 73.4401804 0.57081183 1.077455245 1.1410622067 0.57081183
130 144.765216 73.4401804 0.66168214 1.047447115 1.1940112273 0.661682136
135 144.765216 73.4401804 0.76234891 1.023137213 1.2653847467 0.762348907
140 144.765216 73.4401804 0.87521835 1.006325961 1.3637426926 0.875218347
144.5 144.765216 73.4401804 0.99239791 1.000023406 1.4901334993 0.99239791
Raoult-Dalton
yA xA yA
0.00 0 0
0.051096744 0.03673129 0.068911045
0.096699171 0.071258311 0.129800625
0.185566516 0.143652145 0.246538739
0.355639567 0.30309081 0.460686548
0.438171709 0.390954165 0.558564658
0.520396851 0.484859215 0.650617547
0.604053365 0.585321839 0.737068828
0.692137758 0.692909261 0.818137715
0.790506449 0.808245829 0.894038941
0.847248745 0.869032351 0.93011754
0.913254001 0.932019502 0.964982678
0.996075372 0.997304419 0.998659904
0.999999989 1.000000001 1.000000001

gE g
Raoult-Dalton
yA xA yA RT x i ln xi RT
0.000202051 0 0 2.769333E-005 -0.0007242 -0.00069651
0.070244114 0.049909819 0.093833841 0.0100379957 -0.11848555 -0.10844756
0.142705563 0.105991109 0.189429948 0.021281058 -0.21480354 -0.19352248
0.209355052 0.162072399 0.276028775 0.0324213753 -0.29730907 -0.2648877
0.28585744 0.232174012 0.373452455 0.0460682376 -0.3880518 -0.34198356
0.356164262 0.302275625 0.460621011 0.0591905984 -0.46795188 -0.40876128
0.42153342 0.372377237 0.539072711 0.0714762133 -0.53789828 -0.46642206
0.483077323 0.44247885 0.610052821 0.0824984703 -0.59745325 -0.51495478
0.59883672 0.582682075 0.73349649 0.0982498274 -0.67825746 -0.58000764
0.712272888 0.7228853 0.837189172 0.0992192023 -0.68308475 -0.58386555
0.771795757 0.792986913 0.883053243 0.0906628492 -0.63991342 -0.54925057
0.836407885 0.863088526 0.925519975 0.0733750857 -0.54835723 -0.47498215
0.910733428 0.933190138 0.964953369 0.0442305327 -0.37634506 -0.33211453
0.994242631 0.99628159 0.998110168 0.0030554406 -0.04466624 -0.0416108
Diagrama a P cte
82

80

78

76

74

72
T
70

68

66

64

62

60

58
0.00 0.10 0.20 0.30 0.40 x, y 0.50 0.60 0.70 0.80 0.90 1.00

Diagrama a T cte
143
138
133
128
123
118

P 113
108
103
98
93
88
83
78
73
0 0.1 0.2 0.3 0.4 x, y0.5 0.6 0.7 0.8 0.9 1

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.1

-0.2

-0.3

-0.4
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.1

-0.2

-0.3

-0.4

-0.5

-0.6

-0.7

-0.8
Sistema: Acetato etilo(A) Etanol(B) Ingrese la Presin,mm Hg =
Constantes de Antoine A1 7.10179 8.1122
presin en mm Hg y T en C A2 1244.951 1592.864
A3 217.881 226.184

P B PvB alfa= 0.8552


xA beta= 0.7526
A PvA B PvB
A PvA
yA xA A2
P lnP sat A1
T A3

L
ln 2
A
x

1 A
x
B

L
ln 2
B
xB

1
x A

1bar= 100 Kpa
1atm= 760 mm Hg
1atm= 14,696 psi
1atm= 1,01325 bar
1atm= 101,325 Kpa

DIAGRAMA P-x,y a Temperatur

Ingrese la Temperatura en C =
ngrese la Presin,mm Hg = 760
TsA= 77.0628423
TsB= 78.2981919

T C PsA PsB xAsupuesto A B xA calculado


78.2 788.905689 757.052483 0.00270263 2.339546792 1.0000070929 0.00270263
78 783.759626 751.078377 0.00834781 2.314215216 1.0000675683 0.008347806
77.5 771.010955 736.314933 0.02335769 2.249134199 1.0005269676 0.023357686
76.6 748.478604 710.350812 0.05425903 2.124892724 1.0028230998 0.054259029
76 733.750009 693.469667 0.07842394 2.036104197 1.0058681682 0.07842394
75.5 721.653008 679.659233 0.10143982 1.957735668 1.0097762649 0.101439818
75 709.71516 666.079346 0.12784643 1.874633872 1.0154623807 0.127846432
74.5 697.934972 652.726976 0.1587438 1.785798799 1.0237395609 0.158743804
74 686.310961 639.599122 0.19589362 1.689730759 1.0360101126 0.195893618
73.5 674.841647 626.692812 0.24244397 1.583898211 1.0549824699 0.242439695
73 663.525559 614.005098 0.30515057 1.463134088 1.0869830311 0.305150574
72.5 652.361233 601.53306 0.40749809 1.309251315 1.1558444397 0.407498094
72.4 650.146451 599.064279 0.44271277 1.2664581 1.1845939756 0.442712712
72.3 647.937669 596.603985 0.50755857 1.198907881 1.2448226435 0.507558574
72.29 647.717121 596.358422 0.53105323 1.177663384 1.2690981992 0.531053233
72.2888 647.690659 596.32896 0.52902065 1.179438237 1.2669445113 0.534135788
72.3 647.937669 596.603985 0.56425551 1.150286321 1.3057530072 0.564255509
72.4 650.146451 599.064279 0.6267744 1.106398228 1.3826801065 0.626774402
72.5 652.361233 601.53306 0.65985226 1.08685531 1.4278378083 0.659852256
72.7 656.808845 606.49618 0.70562671 1.063613398 1.4958066627 0.705626707
73 663.525559 614.005098 0.75375663 1.043564133 1.5746266816 0.753756628
74 686.310961 639.599122 0.85299629 1.014941605 1.7637321508 0.852996288
75 709.71516 666.079346 0.91556442 1.004830612 1.903798989 0.915564423
76 733.750009 693.469667 0.96163412 1.000984401 2.018613181 0.961634119
77 758.427474 721.79442 0.99795903 1.00000276 2.1167846458 0.997959029

DIAGRAMA P-x,y a Temperatura constante

ngrese la Temperatura en C = 74
PsA= 686.310961 puro
PsB= 639.599122 puro

P mm Hg PsA PsB xAsupuesto A B xA calculado


639.6 686.310961 639.599122 0.000000001 2.351844698 1 9.0056E-007
655 686.310961 639.599122 0.01648538 2.278528967 1.0002629519 0.016485383
685 686.310961 639.599122 0.05327036 2.128675932 1.0027217467 0.053270361
715 686.310961 639.599122 0.09864023 1.966962349 1.009248633 0.098640229
735 686.310961 639.599122 0.13604175 1.850224184 1.0174873522 0.136041752
775 686.310961 639.599122 0.243447859 1.581777909 1.0554360798 0.243447895
800 686.310961 639.599122 0.3701849 1.359909533 1.1282666265 0.370184901
805 686.310961 639.599122 0.41639424 1.298000494 1.1628535938 0.41639424
802 686.310961 639.599122 0.38666528 1.336824657 1.1400882546 0.38666528
798 686.310961 639.599122 0.69723435 1.067559219 1.4828506379 0.697234353
130 686.310961 639.599122 0.66168214 1.085843461 1.4304306092 4.625890856
135 686.310961 639.599122 0.76234891 1.040429631 1.5895375077 2.913555606
140 686.310961 639.599122 0.87521835 1.010684974 1.8114961932 2.190665412
144.5 686.310961 639.599122 0.99239791 1.000038347 2.1012968168 1.823898751
Diagrama a P cte
79
yA
0.006563414
0.019922581 78
0.053295706
0.113546783 77
0.154164076
0.188572065
0.223807973 76
0.260333866
0.298913235 T
75
0.340978456
0.389800488
0.457955362 74
0.479634572
0.518790025 73
0.533004666
0.531743107
0.553351894 72
0.593226202 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, y
0.615592036
0.648610853
0.686743178
0.781799774
0.859116884
0.929333733
0.995896889

gE g
yA RT x i ln xi RT
2.5236E-009 7.702E-007 -1.344E-005 -1.267E-005
0.039358012 0.01383479 -0.08402588 -0.07019109
0.11361235 0.04281902 -0.20803429 -0.16521527
0.186236592 0.0750272 -0.32208494 -0.24705774
0.235033712 0.09868518 -0.39771253 -0.29902735
0.341012814 0.15245194 -0.55502176 -0.40256983
0.431876592 0.18980923 -0.65905401 -0.46924479
0.460791676 0.1966587 -0.67910145 -0.48244275
0.442339977 0.19265949 -0.66723303 -0.47457354
0.640160383 0.16486113 -0.61318945 -0.44832832
3.793099328 -0.91700537 Err:502 Err:502
4.032307673 -0.77134905 Err:502 Err:502
4.336357935 -0.68415455 Err:502 Err:502
4.713631009 -0.61171994 Err:502 Err:502
0.7 0.8 0.9 1
Sistema: Metanol(A) Agua(B) Ingrese la Presin,mm Hg =
Constantes de Antoine A1 18.5875 18.3036
presin en mm Hg y T en K A2 3626.55 3816.44
A3 -34.29 -46.13

P B PvB alfa= 0.83 373.15


xA beta= 0.51 372.15
A PvA B PvB 371.15
A PvA 370.15
yA xA A2 369.15
P lnP sat A1 368.15
T A3
367.15
366.15
L 365.15
ln 2
A
x 364.15

1 A
363.15
x
B
362.15
L 361.15
ln 2
B
xB 360.15

1
x A 359.15

358.15
1bar= 100 Kpa 357.15
1atm= 760 mm Hg 356.15
1atm= 14,696 psi 355.15
1atm= 1,01325 bar 354.15
1atm= 101,325 Kpa 353.15
352.15
351.15
350.15
349.15
348.15
347.15
346.15
345.15
344.15
343.15
342.15
341.15
340.15
339.15
338.15
337.66
DIAGRAMA P-x,y a Temperatur

Ingrese la Temperatura en C =
ngrese la Presin,mm Hg = 760
TsA= 337.660831 64.51083135
TsB= 373.152101 100.00210124

T C PsA PsB xAsupuesto A B xA calculado


100 2657.90261 759.943012 0.000009974 2.293256947 1.0000000001 1.0681E-005
99 2575.02917 733.220887 0.00525633 2.261224957 1.0000370766 0.005256327
98 2494.27059 707.282589 0.01084648 2.228103344 1.0001567857 0.010846483
97 2415.58638 682.110221 0.01681473 2.193847278 1.0003740512 0.016814726
96 2338.93651 657.686159 0.02319895 2.158416959 1.000706519 0.023198949
95 2264.28141 633.993046 0.03004205 2.121773348 1.0011751133 0.030042049
94 2191.58198 611.013792 0.03739271 2.083879383 1.0018047122 0.037392703
93 2120.79957 588.731576 0.0453063 2.044701133 1.0026249754 0.045306296
92 2051.896 567.129842 0.05384599 2.004209122 1.0036713661 0.053845991
91 1984.83355 546.192298 0.06308397 1.962380425 1.0049863987 0.063083967
90 1919.57495 525.902915 0.07310282 1.919201448 1.0066211583 0.073102825
89 1856.0834 506.245925 0.08399719 1.874670877 1.0086371747 0.083997194
88 1794.32256 487.20582 0.09587546 1.828804328 1.011108657 0.095875462
87 1734.25655 468.767351 0.10886161 1.781639621 1.0141251827 0.108861615
86 1675.84996 450.915527 0.12309706 1.733243431 1.0177948488 0.123097058
85 1619.06783 433.635612 0.13874217 1.68371975 1.0222478306 0.13874217
84 1563.87565 416.913122 0.15597728 1.633219327 1.0276402759 0.155977282
83 1510.2394 400.733829 0.17500253 1.581950586 1.034158187 0.175002528
82 1458.12548 385.083753 0.19603581 1.530190824 1.0420207647 0.196035805
81 1407.50077 369.949163 0.21838039 1.480264348 1.0510904544 0.219016222
80 1358.33261 355.316577 0.24505435 1.426706168 1.0628318227 0.245054347
79 1310.58878 341.172757 0.27350175 1.375944593 1.0763876726 0.273501748
78 1264.23754 327.504709 0.30485157 1.326603562 1.0924880309 0.304851575
77 1219.24757 314.29968 0.33926043 1.279316905 1.1114747031 0.339260431
76 1175.58803 301.545157 0.37682189 1.234717958 1.1336727037 0.376821883
75 1133.22853 289.228867 0.41755406 1.19338851 1.159368601 0.417554063
74 1092.1391 277.338771 0.46139729 1.155808805 1.1887924665 0.461397283
73 1052.29026 265.863063 0.50822321 1.122320601 1.2221076599 0.50822321
72 1013.65295 254.79017 0.55785379 1.093111058 1.2594110887 0.557853792
71 976.198562 244.10875 0.61008481 1.068219702 1.3007424444 0.610084814
70 939.898938 233.807688 0.6647087 1.047562849 1.3460992459 0.664708704
69 904.726355 223.876092 0.72153243 1.03096699 1.3954533047 0.721532428
68 870.653534 214.303297 0.78038889 1.018202787 1.4487653624 0.78038889
67 837.653632 205.078857 0.84114221 1.009014178 1.5059962242 0.841142214
66 805.700245 196.192546 0.90368842 1.00314027 1.5671139824 0.903688421
65 774.767402 187.634354 0.96795321 1.000329991 1.6320978918 0.967953211
64.51 759.975104 183.557644 0.999999 1 1.6652901512 1.000054802
DIAGRAMA P-x,y a Temperatura constante

ngrese la Temperatura en C = 74
PsA= 1.827E-073 puro
PsB= 2.325E-119 puro

P mm Hg PsA PsB xAsupuesto A B xA calculado


639.6 1.827E-073 2.325E-119 0.000000001 2.293318734 1 1.5269E+075
655 1.827E-073 2.325E-119 0.01648538 2.195708643 1.0003596861 1.6332E+075
685 1.827E-073 2.325E-119 0.05327036 2.006882264 1.0035956661 1.8687E+075
715 1.827E-073 2.325E-119 0.09864023 1.81850982 1.0117237614 2.1525E+075
735 1.827E-073 2.325E-119 0.13604175 1.692007964 1.0214486319 2.3782E+075
775 1.827E-073 2.325E-119 0.243447859 1.429760347 1.0620975318 2.9676E+075
800 1.827E-073 2.325E-119 0.3701849 1.242114987 1.1296430099 3.5261E+075
805 1.827E-073 2.325E-119 0.41639424 1.194474628 1.1586145529 3.6896E+075
802 1.827E-073 2.325E-119 0.38666528 1.224104144 1.1397317363 3.5869E+075
798 1.827E-073 2.325E-119 0.69723435 1.037506575 1.3740871518 4.2109E+075
130 1.827E-073 2.325E-119 0.66168214 1.048579176 1.3435314147 6.7874E+074
135 1.827E-073 2.325E-119 0.76234891 1.021680886 1.4321957741 7.2340E+074
140 1.827E-073 2.325E-119 0.87521835 1.005399565 1.5390260773 7.6235E+074
144.5 1.827E-073 2.325E-119 0.99239791 1.000018217 1.6573709816 7.9108E+074
yA
7.9992E-005
0.040271236
0.07931478
0.117247953
0.154102085
0.18990892
0.224700298
0.258508287 Diagrama a P cte
0.291365519 104
0.323305222
0.354361208 99
0.384568478
0.413963096
94
0.442582632
0.470466587
89
0.497656568
0.524196937
0.550135213 84
T
0.575522504
0.598670647 79
0.624869733
0.648953995 74
0.672736025
0.696289193 69
0.719689975
0.743016519
64
0.766346895
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.789756825 x, y
0.813317976
0.837096193
0.86115042
0.885532011
0.910284471
0.935443539
0.961037392
0.98708693
0.999966242

gE g
yA RT xi ln xi RT
6.5493E-085 1.267E+075 Err:502 Err:502
1.0094E-077 1.284E+075 Err:502 Err:502
2.8507E-077 1.295E+075 Err:502 Err:502
4.5825E-077 1.262E+075 Err:502 Err:502
5.7204E-077 1.200E+075 Err:502 Err:502
8.2036E-077 8.821E+074 Err:502 Err:502
1.0499E-076 3.347E+074 Err:502 Err:502
1.1286E-076 1.125E+074 Err:502 Err:502
1.0780E-076 2.562E+074 Err:502 Err:502
1.6558E-076 -1.18E+075 Err:502 Err:502
9.7487E-076 -1.68E+074 Err:502 Err:502
1.0538E-075 -2.44E+074 Err:502 Err:502
1.1481E-075 -3.25E+074 Err:502 Err:502
1.2545E-075 -4.00E+074 Err:502 Err:502
cte

0.6 0.7 0.8 0.9 1