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CHRONICLING PROCESS INDUSTRY INNOVATIONS SINCE 1966 VOL.

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CHEMICAL ENGINEERING WORLD

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CEW Contents
CHEMICAL ENGINEERING WORLD
RNI REGISTRATION NO. 11403/66
Chairman Jasu Shah
Publisher & Printer Maulik Jasubhai Shah
Chief Executive Officer Hemant Shetty VOL. 51 | ISSUE NO. 2 | FEBRUARY 2016 | MUMBAI | ` 150
EDITORIAL
Editor Mittravinda Ranjan (mittra_ranjan@jasubhai.com) NEWS
Editorial Advisory Board D P Misra, N G Ashar, Prof. M C Dwivedi
Contributing Editors P V Satyanarayana, Dr S R Srinivasan, Industry News / 6
R B Darji, R P Sharma
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CEW Industry News
India to Build Petrochemical Complex in Iran Soon CIPET, Govt, of Karnataka to set up Advanced
Polymer Lab
New Delhi, India: India proposes to establish Special Economic Zones
(SEZ) in Iran, Turkmenistan and Myanmar as part of the National Bengaluru, India: The Central Institute of Plastic Engineering
Democratic Alliance government move for Reverse SEZ in oil-rich &Technology (CIPET) has signed a memorandum of understanding
countries with dedicated exports back to the country, according to Union (MoU) with the Karnataka Government to set up an Advanced
Minister for Chemicals and Fertilizers Ananth Kumar. Minister said that Polymer Design and Development Research Laboratory-cum-High
India had formed a joint venture with Rashtriya Chemical Fertilizers Learning Centre at Bengaluru.
and Gujarat Narmada Fertilizers Corporation and had several rounds
of meeting with Iran, the latest being in January this year. Negotiations
The MoU was signed in the presence of Union Minister of
were on for fixing the price of gas and on terms of contract.
Chemicals and Fertilizers Ananth Kumar, Karnataka Chief Minister
Siddaramaiah and other dignitaries. An official press release said
He said that the proposed natural gas-based petroleum plant-cum-
the laboratory was being set up at an estimated investment of Rs.
petrochemicals complex would be established in the port city of Chabahar.
87 crore. The State Government will allot the land for the centre
The Minister had had two levels of discussions in this regard with the
and also share 50 per cent of the project cost.
Ambassador of Iran, Indian Ambassador to Iran and Minister for External
Affairs Sushma Swaraj to hasten the process.
The centre will act as a multi-functional one-step facility with
specialization in product development in the polymer sector.
Plastic Market in India has Huge Growth Potential, It will also conduct R&D, product tests and evaluations and
Says Hansraj Ahir commercialization of technology.

Mumbai, India: According to an official statement, Minister of State for


Chemicals and Fertilizers Hansraj Gangaram Ahir said that the Indian G D Yadav, Vice Chancellor, IICT Mumbai Selected for
plastic and petrochemical sector has a huge potential for growth and the Padmashri Award
there is a need for free trade agreement (FTA) and duty inversion to
make cost of manufacture in the country cheaper. Mumbai, India: G D Yadav, vice chancellor of Indian Institute of
Chemical Technology in Mumbai has been selected for Padmashri
He was attending the inauguration of PolyIndia 2016 at the Bombay awards for this year.Yadav was born in a hamlet in the Radhanagari
Exhibition Centre on January 28. The three-day exhibition on plastics tehsil in the Kolhapur district. He completed his education till
and petrochemicals was themed Indian Plastic and Petrochemical sector: class VII in the village.
Potential for Global Manufacturing Hub.
After completing his basic education, he went to Mumbai for higher
studies and completed chemical engineering from the University
The MAGIC Begins Department of Chemical Technology (UDCT), in Mumbai in 1974.
He then worked for green technologies and did further research
Pune, India: The Union Minister for Science & Technology & Earth in nanotechnology and biotechnology.
Sciences, Dr Harsh Vardhan, inaugurated a unique MAGIC [Modular,
Agile, Intensified & Continuous] Process Lab at CSIR-National Chemical He has made innovative contributions to green chemistry and
Laboratory (CSIR-NCL) Pune last evening. engineer ing, catalysis science and engineer ing, chemical
reaction engineering, biotechnology, nano-technology and energy
While inaugurating the facility he announced that ?The MAGIC processes engineering. He has supervised 83 doctoral candidates and 88
and plants will bring about a paradigm shift in the way in which India?s students pursuing their masters.
Fine and Specialty Chemicals industry will operate in the future. Over
the past three decades, the global fine and specialty chemicals industry
has shifted manufacturing base from the western world to countries like India Suspends Agreement with ACRON
India and China.
New Delhi, India: India has shelved its plan to buy 30 per cent
The MAGIC processes developed in CSIR-NCL can radically change stake in Russian fertilizer producer ACRONs USD 2-billion potash
currently practiced process technologies into modern processes that are mine project due to valuation issues. In December 2014, the two
cleaner, greener, safer, compact, scalable and economical. As a result, parties had signed an agreement to buy 30 per cent stake in
the MAGIC processes have the potential to transform the country into ACRONs potash mine project. Potash is a decontrolled fertilizer
a global powerhouse in this important sector, thus enabling the country and government pays fixed subsidy on it. As per the proposal,
to increase its contribution to global production of chemicals from the India was represented by an NMDC-led consortium of four state-
current levels of 3 to 5 per cent over the next few years. run companies and one cooperative

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CEW Industry News
CFCL Technologies Arm to Sell off its Business GoI to Set Up 100 CIPET
Mumbai, India: Chambal Fertilisers & Chemicals - subsidiary New Delhi, India: Union Ministry of Chemicals and Fertilizers decided
company - CFCL Technologies arm have entered into agreements to set up 100 Central Institutes for Plastic Engineering and Technology
for sale of some of its business. ISGN Corporation, USA has (CIPET) in India. The decision was taken in order to meet the need of
entered into a stock purchase agreement to sell and transfer its skilled manpower in the petrochemical sector or plastic processing
entire shareholding in its wholly owned subsidiary - ISGN Solutions industry. The announcement in this regard was made by Minister of
Inc, USA to Firstsource Group USA, Inc. Chemicals and Fertilizers Ananth Kumar at the occasion of National
Awards for Technology in Innovation in Petrochemicals and downstream
Further, ISG Novasoft Technologies has entered into a slump sale Plastics Processing Industry.
agreement to sell and dispose-off part of its business / undertaking
i.e. Business Process Outsourcing business to Firstsource Process Currently, CIPETs are present at 28 locations in India. Department
Management Services, India as a going concern on slump sale of Scientific and Industrial Research (DSIR) recognizes CIPET as a
basis.Chambal Fertilisers & Chemicals is one of the largest private scientific and research organisation in the area of Plastics Engineering
sector fertilizer producers in India. It has three divisions catering and Technology.
agri products, shipping & textiles.

Evonik, ICT Mumbai Ink R&D Pact


No Price-hike for Fertilizers in Next Four Years
Mumbai, India: Evonik Industries and the Institute of Chemical
New Delhi, India: During his visit to Fertulizer Corporation of In- Technology (ICT), Mumbai have sealed a strategic partnership agreement
dias Karimnager plant, Union Minister for Chemicals and Fertil- for the purpose of exploring research topics together, closely in selected
isers Hansraj Gangaram Ahir has said that the prices of fertiliz- fields in the future. Evonik and ICT research partnership agreement
includes Provision of scholarship funds for masters degree and PhD
ers such as urea and DAP (Di-ammonium phosphate) will not be
students; Collaboration in research and development projects in the
increased for next four years.
field of chemical science; Financial support for internships for master,
bachelor and PhD students; Sponsor lectures and/or presentations
Speaking on the occasion, the Minister said all the eight fertilizer by representatives of Evonik at ICT and vice versa. The expansion
plants of national stature which were closed down during the of innovation activities in economically attractive regions supports
previous UPA regime will be reopened. Evoniks growth strategy. The goal is to strengthen local customer
competitiveness with technological services as well as research and
The Minister also mentioned that the works on six plants have application techniques that fit local needs.
already begun, and Prime Minister Narendra Modi will re-com-
mission the FCI factory in Ramagundam during the second week
of next month. South Africa Opens up Opportunities to Indian
Chemical Companies
Johannesburg, South Africa: A number of South African industrial
GSFC is Exploring Global Markets for Nylon-
houses are struggling to succeed and hence looking to sell equity, cre-
6 Fibres ating an opportunity for Indian companies to pursue acquisition, says
Vadodara, India: Gujarat State Fertilizers & Chemicals Ltd Debajit Shome, Director of multinational Union Colours. Shome was ad-
(GSFC) is exploring global export opportunities for its Nylon-6 dressing a networking meeting organised by the Indian Consulate-Gen-
fibres GUJCON-CRF and GUJCON-PRF. eral here for a delegation of 61 members of the Basic Chemicals, Phar-
maceuticals and Cosmetics Export Promotion Council (Chemexcil).
At the launch of the products in Hyderabad, GSFC Chairman
South Africa has long been the leader in chemical production for the
and Managing Director Sudeep Kumar Nanda said that GSFC is
continent, but producers are currently facing poor domestic demand
revolutionising the business of fertilisers and industrial chemi-
and a volatile exchange rate that hampers exports, which has led to a
cals and has innovated and pioneered yet another revolutionary decline in output since 2013, Shome explained. Chemexcil Chairman
product GUJCON-CRF and GUJCON-PRF. Dr B R Gaikwad urged members of his organisation to heed this call and
the offer of further assistance from the Consul-General if they wished
GSFC aims to leverage opportunities in construction and infra- to pursue. Highlighting the Make in India campaign as one which is
structure sectors in India and overseas markets and exploring intended to produce in India for consumers across the globe, Gaikwad
opportunities of export of its products to African countries, Gulf also urged South African manufacturers to use the opportunity of growing
countries including UAE and Dubai, Sri Lanka, Canada. their businesses by partnering with India.

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CEW Industry News
SMEs to Emerge as Key Players in Export Growth CIL Q3 Profit Surges by ` 500 Crores
of Chemical industry
Mumbai, India: Coal India reported a nearly ` 500 crore increase
Mumbai, India: Small and medium enterprises are expected to play in net profit, which touched Rs.3,718.30 crore as compared to
a vital role in the export growth of chemical industry, said Union ` 3262.50 crore a year ago. Total income has increased to `
Commerce Minister Nirmala Sitharaman. She was presenting 20,953.40 crore from ` 19,944.90 crore. This performance came
CHEMEXCIL awards to the winners of export performance in on the back of a 10.7 per cent growth in coal supplies. CIL supplied
various categories during the last four years. She stressed the 137.90 million tonnes between October and December 2015.
need to have a strategy to enhance expor t competitiveness
of SMEs through capacity building, cheaper credit and better The third quarter witnessed production of 143.9 million tonnes with
marketing. The minister said the central government has initiated the company holding its production tempo at 373.51 million tonnes
an all out efforts to nurture budding entrepreneurs across sectors. in the nine months of 2015-16 against 342.38 million tonnes on
a year-on-year comparison, with a 31.13 million tonnes increase
in absolute terms.
Indian Organic Chemical Industry Outlook to 2019
New Delhi, India: A report titled India Organic Chemical Industry
Outlook to 2019 - Driven by Consumer Preferences and Integrated Nippon Paint to Strengthen its Market Presence
Production of Chemicals provides a comprehensive analysis of the in South
various aspects such as market size of the overall organic chemical
market with a focus on methanol and phenol markets. The market Chennai, India: Japanese paint manufacturer Nippon Paint is
is further segmented into consumption and production, end user planning to become a dominant player in the southern market by
industry analysis, import and export and competitive landscape of the end 2019. The expansion plan includes increasing the production
major players operating in methanol and phenol market. Investment volume, introducing more water-based products, penetrating
opportunities, recent trends, drivers and macro economy factors have into Tier-III cities of southern states and rolling out skill training
also been discussed in the market intelligence. programme for painters.

In India, six major organic chemicals, namely, Methanol, Aniline, Alkyl Nippon Paint has a facility at Sriperumbudur with capacity to
Amines and its derivatives like Formaldehyde, Acetic Acid and Phenol, produce 7,000 kilo litre per month. Currently, it operates at 35
have contributed a major proportion to the domestic Organic Chemic per cent of its capacity.
industry. The production of organic chemicals market has increased
marginally at a CAGR of 3.8% over the years during FY2009-FY2014.
This growth has been registered also on account of abolishment of GSFC Awards EPC Contract to Simon India
Industrial Licensing for various sub sectors except the hazardous
chemicals and reduction in the list of reserved chemical items for New Delhi, India: Simon India Limited, a leading EPC company
the production in small scale sector. Poor infrastructure, high cost of and a part of Adventz group, has won a significant contract from
feedstock and under-utilization of installed capacities have acted as Gujarat State Fertilizers & Chemicals Limited (GSFC) for their
a major hurdle in the achievement of optimum operational capacities Caprolactum Quality Project (CQP). The project is for installing
of plant and machinery. Ensuring feedstock availability, stringent new distillation unit of 50,000 MTPY capacity to enhance quality
government regulations against cheap imports, skilled manpower
of Caprolactum produced in old plant and will be set up in GSFCs
and innovating new applications of organic chemicals are the major
existing Fertilizernagar complex in Vadodara, Gujarat.
factors that would drive the growth of this market in the next five years.

Simon India has been awarded this project on EPC basis against
New Plastic Pipe Plant for CRI Pumps competitive bidding. The scope of work includes extended basic
engineering, detailed engineering, procurement, supply, erection &
Chennai, India:To cater to the east and south Indian markets, CRI Pumps construction and commissioning assistance. The project is slated
has opened a plant at Hosur to make non-metallic plastic pipes. The for completion in Q1-2017.
company had been transporting pipes from its plant in Gujarat to markets
in south India leading to the freight cost working out to almost eight per The Bhoomipujan & Foundation stone laying ceremony of the
cent. Hence, it was decided to have a manufacturing unit at Hosur. The CQP project was recently performed by the Honble Chairman &
company had invested ` 125 crore in pipe-making plants at Gujarat and Managing Director - Dr S K Nanda, IAS in an impressive function
Hosur. It had expanded capacity at the Gujarat plant to 20,000 tonnes held at Fertilizernagar complex.
a year. The Hosur plant also had a similar capacity. Turnover from the
pipe-making units in 2016-17 is expected to be ` 150 crore, according This is the second contract awarded to Simon India Limited by
to G Soundararajan, Company Vice Chairman. GSFC and reiterates trust in Simon Indias capabilities.

10 February 2016 Chemical Engineering World


CEW Industry News
Safety Data Base for Registered Chemicals Topsoe Wins Iranian Methanol Plant Contract
Maryland, US: Researchers at Johns Hopkins Bloomberg School of Chabahar, Iran: Denmark-based technology, catalyst and services
Public Health, US, have created a safety database on 10,000 chemicals supplier Haldor Topsoe (Topsoe) has secured a contract from Badr-
registered in Europe for predicting the toxicity of many of the 90,000 e-Shargh Petrochemical Complex to provide licenses, engineering,
or more other substances in consumer products. proprietary equipment, materials and catalyst for a new methanol
plant to be located in Chabahar, Iran.
With the database, explained online in the Alternatives to Animal
Experiments journal, the researchers aim to help regulators, It will be the first plant in a new industrial zone in Chabahar area.
manufacturers and scientists by providing idea about whether The company has also decided to open permanent offices in
chemicals, for which little research is done, are harmful or not. The Tehran with an expectation to tap the petrochemical and refinery
database, created on the basis of 816,000 research studies, also
business in Iran.
inclu includes information about the hazardous nature of the surveyed
chemicals to the humans.
Report Forecast Strong M&A in Chemical Industry
EU Exit would Cause Great Loss to UK Chemical New York, USA: A Deloitte Global report has stated that strong
Market mergers and acquisitions (M&A) activity in the chemical sector
will continue this year. According to Deloitte Touche Tohmatsus
London, UK: The chemical industry in UK could face a EUR 7 (Deloitte Global) 2016 global chemical industry mergers and
billion loss of exports if the country chooses to withdraw from the
acquisitions outlook, companies are showing more interest in
European Union (EU) without signing a new Free Trade Agreement
acquisitions to grow and provide greater shareholder value.
(FTA), according to a report by trade credit insurance group Euler
Hermes. In addition, the report has warned that the machinery
Chemical sectors, such as fertilisers and agriculture chemicals,
and equipment industry would face a loss of EUR 3.5 billion and
have already diversified this year, and industrial gases are also
the automotive industry would face EUR 3 billion loss, if new
expected to see strong M&A activity.
FTA is not agreed. The UKs chemicals, automotive, machinery,
and equipment sectors are known to be highly dependent on the
European market. Deloitte Global M&A chemicals and specialty materials sector
leader Dan Schweller said: Higher deal volumes are likely as
companies use M&A as a tactic to deliver growth to counter
Bertin Technologies to Install Second Sight at challenging business conditions, which are expected to continue
Saudi Aramcos Jazan Refinery in these segments.

Dhahran, Saudi Arabia: Petrofac, a leading service provider to


the international Oil & Gas industry, awarded a contract to Bertin Axiall Turns Down Westlake Chemicals Offer
Technologies, a subsidiary of CNIM group, to supply, install and
commission a pioneering gas leak tracking system, Second Sight, Atlanta, Georgia: Chemicals and building products manufacturer
at the Saudi Aramco owned Jazan refinery. Axiall has turned down a revised USD 1.41 billion acquisition offer
from Westlake Chemical. The US-based company called the bid
This system opens up a new era in gas detection methods for an opportunistic effort to buy its vinyl assets at a cheaper rate.
the Oil & Gas industry. Bertin Technologies has achieved a
major breakthrough by customizing its own gas imaging camera. In the unsolicited cash-and-stock bid, Westlake offered to buy all
Initially developed for defense and civil security applications, the outstanding common shares of Axiall for USD 20 per share,
Second Sight has been adapted to IECEx hazardous area and constituting USD 11.00 in cash and 0.1967 shares of Westlake
Saudi Aramco standards. To enhance the level of safety on site, stock. Westlake offered its bid to buy Axiall last week. After
Bertin Technologies will provide a turnkey solution that detects reviewing the proposal, the company unanimously rejected it.
and monitors explosive gas clouds. Westlake said that previously it had offered USD 11 per share in
cash and 0.1967 of its stock for each Axiall share.
The Second Sight solution has been selected by Saudi Aramco
and Petrofac because it offers several benefits that complement Axiall president and chief executive officer Timothy Mann
conventional gas detection methods. It provides, in real time, a said: We believe that Westlakes proposal is an opportunistic
complete scene visualization. In the case of an alarm activation, attempt to take advantage of challenging public equity market
it localizes the leakage source and direction of the explosive gas conditions, and significantly undervalues Axialls assets and its
cloud in the vicinity. long-term prospects.

14 February 2016 Chemical Engineering World


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CEW Industry News
New Dispense Technology for Agricultural Use of Environmental Products and Services Files
Chemicals Lawsuit against Miller Chemicals
Cambridge, UK: A new spray technology that shoots a targeted Pennsylvania, USA: An environmental cleanup company, Environmental
droplet with incredible accuracy could cut agricultural use of Products and Services, has filed a USD 6.9 millionfederal lawsuit against
chemicals by more than 99 per cent, according to Niall Mottram, Adams County, US, based company Miller Chemical and Fertilizer.
head of agrifood product development at developers Cambridge Environmental Products alleged that Miller Chemical has not paid the
Consultants. The technology has the potential to not only group fully for the cleanup work it carried out following a fire that killed
save farmers money, but also help protect the environment by numerous fish in June last year, reports PennLive.
dramatically reducing the amount of chemicals that are applied.
The system uses advanced machine vision algorithms that can During last years incident, a Miller Chemicals warehouse located in
differentiate between healthy and diseased crops, and then apply Radio Road, near Hanover, US was burned down, incurring around USD
a droplet only to the crops that need it. 20 million in property loss to the company.

State and county officials claimed that the fire-fighting and cleanup
Andritz Starts up Semi-chemical Pulp line with measures carried out for days had polluted nearby water bodies and
Green Liquor Pulping Technology killed thousands of fish. Due to the contamination, fishing, boating
and swimming were prohibited in the nearby waterways, where the fire
Moscow, Russia: International technology Group Andritz has occurred, for around a month. The lawsuit filed in US Middle District
started up the pulp line delivered to JSC Arkhangelsk Pulp and Court has mentioned that Miller Chemical hired Environmental Products
Paper Mill (APPM) at the Novodvinsk mill, Russia. to help in proper recovery efforts and to initially provide equipment and
labour support.
The new line features Andritz green liquor technology for efficient
pulp cooking, refining, and washing and produces 1,000 t/day
of semi-chemical pulp for the production of corrugated board Optima Chemical to Expand at DuPont Plant
from birch and aspen, as the company says in the press release
received by Lesprom Network. Semi-chemical pulp is produced Belle, USA: As West Virginias chemical industry waits to see how the
in a combination of mild chemical treatment and subsequent proposed merger between DuPont and Dow Chemical plays out, one
mechanical treatment in which the fibers are liberated from the company is wasting no time opening up shop in the Kanawha Valley.
wood matrix.
Optima Chemical, a Georgia-based company, announced last June that
A major advantage of the Andritz green liquor technology, which it had bought two units at the old DuPont chemical plant in Belle. Seven
is mainly applied for hardwoods and enhances the fiber quality months later, the companys employees are busy bringing those sections
substantially, is the efficient and easy recover y of cooking of the aging plant back to life. In December, Optima received preliminary
chemicals in the adjacent kraft mill. Thus, no additional process approval from the West Virginia Economic Development Authority for a
USD 2.25 million government-subsidized loan to buy new equipment
steps are needed for chemical recovery.
and to upgrade existing infrastructure at the plant, some of which hasnt
been used for more than five years.
ChemChina to Acquire Syngenta
Beijing, China: Chinas gover nment-owned China National Bertschi Opens New Plant at Jurong Island
Chemical Corporation (ChemChina) has agreed to buy the Swiss
Drrensch, Switzerland: Swiss chemical logistics firm Bertschi
agrochemical and seeds company Syngenta for USD 43 billion.
Holding has inaugurated its USD 45 million Jurong Island Chemical
The decision to sell 100 per cent of Syngentas equity came Cluster (JICC) facility in Jurong Island, Singapore.
after the companys board unanimously approved ChemChinas
bid. ChemChinas offered USD 465 per share in cash, and an With its first facility in South-East Asia, Bertschi aims to provide
additional special dividend of Sfr 5 (USD 4.91), which will be paid chemical logistics, processing services, and lean supply chain
immediately before closing the deal. solutions to specialty chemical makers located along the islands
Ethylene Oxide corridor.
The deal is yet to receive anti-trust reviews and approvals from
relevant countries. Upon completion of the deal, ChemChina will The manufacture of specialty chemicals has grown recently in Jurong
retain the operations, management and employees of Syngenta. Island, which is mainly known for its refineries and petrochemical
Syngenta will retain its name and will continue its operation from complexes. Bertschi aims to provide specialised logistics services
its existing headquarters in Basel, Switzerland. to those manufacturers from the companys new facility.

16 February 2016 Chemical Engineering World


CEW Industry News
Green Biologics Named in the 2015 Global Idemitsu to Expand Xarec Resin Production
Cleantech 100 Capacity
Gahanna, Ohio and Abingdon, England: Green Biologics Ltd, a UK Tokyo, Japan: Japan-based Idemitsu Kosan is all set to increase its
based industrial biotechnology and renewable chemicals company, has production capacity for syndiotactic polystyrene resin (SPS) Xarec.
once again been named to the prestigious 2015 Global Cleantech 100, Idemitsu started production of the low-density engineering plastic SPS
produced by Cleantech Group, a leading global research and advisory on an industrialised scale in 1997. The company said it will increase the
firm. Green Biologics was recognized for its Clostridium fermentation production capacity of the SPS manufacturing unit at its Chiba plant due
platform, which converts a wide range of sustainable feedstocks into to increasing demand for the product at an annual rate of around 10 per
high performance green chemicals such as n-butanol and acetone for cent. The production capacity is set to increase from the existing 7,000t
use by the growing consumer and industrial products industries. The per year, to 9,000t per year. Completion is set to take place in April.
Global Cleantech 100 is a comprehensive list of the private companies
poised to make the most significant impact on the cleantech industry
through innovative and promising technologies aimed at addressing
Praxair Introduce Ozone Technology for Water
tomorrows clean technology challenges. The list is collated by sifting
through thousands of nominations and combining proprietary Cleantech
Treatment
Group research data, with weighted qualitative judgments, and specific Mumbai. India: In power plants and the chemical and petrochemical
inputs from a global 100-person Expert Panel. industries, cooling towers determine final heat transfer rates on associated
equipment. During operation, cooling towers are generally exposed to
the ambient conditions from atmospheric microflora as well as impurities
Air Products Builds ASU Trains for Shaanxi and sunlight. This process is prone to microbiological activity leading to
Future Energy Chemical adverse effects like heat exchanger fouling, loss of cooling efficiency,
microbial influenced corrosion and severe localized metal loss due to
Yulin, China: Air Products has brought online its four air separation acid build-up. Conventional microbial control offers many solutions and
unit (ASU) trains built for Shaanxi Future Energy Chemical in Yulin City, the choice depends on water chemistry, types of organisms, compatibility
Shaanxi Province, China. The trains are equipped with air compressors, with treatment chemicals, system design, permits and cost limitations.
as well as design and technology advancements to improve energy Praxairs ozone technology harnesses the powerful biocide action of
efficiency, while helping Shaanxi reduce operational costs. The project ozone to decrease and nearly eliminate microbial growth. Praxairs
was initially announced in December 2011. Together, the units are capable treatment reduces the need for chemical additives to be added to the
of producing 12,000t of oxygen and nitrogen, and compressed dry air cooling tower water. Ozone not only removes and prevents the growth
per day for Shaanxis coal chemical plant. Air Products industrial gases of these organisms but also reduces the contaminant levels through
Asia on-site business development vice-president Phil Sproger said: The direct oxidation. Contrary to conventional halogen-based biocides, ozone
successful execution of this world-scale project is another testimonial of our does not produce unwanted by-products such as halocarbons. The
leading position in large air separation and excellence in safety, reliability blowdown rates are also lowered due to lower water losses and lower
and technology. chemical dosage.

TV SD Supports Iranian Manufacturers and Schwarze-Robitec to Present NxG 2.0 at the


German Importers in Dealing with REACH International Trade Fair Tube 2016

Munich, Germany: Trade sanctions against Iran have now been lifted Cologne, Germany: During the Tube 2016, visitors to the Schwarze-
and companies are building new business relationships. TV SD Robitec booth will have the opportunity to find out more about intelligent
is supporting Iranian chemical product manufacturers and German tube bending solutions. The CNC-controlled system NxG 2.0 allowed
importers in implementing the European chemicals regulation, REACH. us to tie a total package together that consists of software and hardware
Chemicals, petrochemicals and extractive metallurgy are major and that will undoubtedly improve the tube bending production in the
industrial sectors in Irans economy. Now that the trade embargo has not so distant future, says Bert Zorn, General Manager of Schwarze-
been lifted, Iranian manufacturers can export their chemical products Robitec. With the objective to get the bending technology ready for
to the European Union. However, they must observe the provisions of Industry 4.0, the company integrated fundamental modules into the new
the European chemicals regulation, REACH. Under the terms of the control system. In addition to a new operating concept, and besides
regulation, importers must register any substances produced in volumes standard statistical information about the bent component, the further
over the limit of 1 t/a per substance within specific deadlines, explains development of the high-performance NxG makes it also possible
Dr Dieter Reiml, REACH expert at TV SD Industrie Service GmbH. to record and evaluate process data. Integrated sensors provide
Manufacturers can also commission an Only Representative outside the information about wear parts to arrive at conclusions such as the
European Union to carry out registration on their behalf. This option has maintenance requirement of the machine. The advanced software uses
advantages for the entire supply chain, advises Dr Reiml; for example, icons displayed on the desktop, and its new graphical user interface
importers no longer need to register as downstream users. ensures process reliability and intuitive operability.

18 February 2016 Chemical Engineering World


CEW Technology News
G S P C B R e p o r t N e g a t i v e R e s u l t fo r N a n o IICT Researchers Introduce Advanced Water
Oxidation Technology Lab Trials Purification System
Panaji, India: The Goa State Pollution Control Board (GSPCB) Hyderabad, India: A team of researchers lead by Dr S Sridhar,
has found lab trials conducted using the nano oxidation the Principal Scientist for Indian Institute of Chemical Technology
technology, which promises to treat any kind of water for all (IICT) in Hyderabads Membrane Separations Group, introduced
pollutants, to be unsatisfactory for using it to clean up larger a promising water purification systems work on membrane
streams of polluted water bodies like the St Inez creek. However, filtration, remineralisation and pressurised reverse osmosis
it is recommendatory for industries to adopt such technology techniques that allow 1,000 litres of pure drinking water to be
in their effluent treatment plants and for hotels in their sewage generated per hour, at the cost of just 4 paise per litre (and a
treatment plants. one-time investment of around ` 3 lakhs) thats safe from fluoride
and arsenic, two of Indias biggest water pollutants. The pilot
The technology was offered by Ozo Nano Sciences, a Bangalore- projects have a capacity of around 6,000 litres per hour.
based firm, which approached the GSPCB last month with the
The team has also developed nano-filtration and ultra-filtration
proposal to clean up the polluted St Inez creek water. The
techniques for water that has a plethora of uses, including
company claims to remove toxic or non-degradable material
generating medical-grade water.
from water.

It also claims the removal of pesticides, petroleum ingredient


Hybrid Technology to Create Biorenewable Nylon
and VOCs (volatile organic chemicals) by just adding liquid
incinerator into the polluted water that also neutralises bacteria, Iowa, USA: Engineers at Iowa State University have found a way to
reduces chemical toxicity and precipitate heavy metals. combine a genetically engineered strain of yeast and an electrocatalyst
to efficiently convert sugar into a new type of nylon. Previous
attempts to combine biocatalysis and chemical catalysis to produce
INTERSECT16 Held at Karaikudi biorenewable chemicals have resulted in low conversion rates. Thats
usually because the biological processes leave residual impurities
Karaikudi, India: A three-day National Technical and Research that harm the effectiveness of chemical catalysts. The research group
Symposium on Electrochemical and Chemical Technology has created genetically engineered yeast - a microbial factory, - that
2016 (INTERSECT16), a national-level technical symposium ferments glucose into muconic acid. By applying metabolic engineering
and cultural event was organised by the Electrochemical strategies, the group also significantly improved the yield of the acid.
Technologists Association (ETA) in the Council of Scientific and Then, without any purification, Tessonniers group introduced a metal
Industrial Research-Central Electrochemical Research Institute catalyst - lead - into the mixture and applied a small voltage to convert
(CSIR-CECRI) from February 4 to 6 at Karaikudi, Tamil Nadu. the acid. The resulting reaction adds hydrogen to the mix and produces
3-hexenedioic acid.
Inaugurating the conference, M Jayachandran, acting Director,
CSIR-CECRI, said that he always felt happy to work with
young minds as they came up with fresh ideas and advised the
ClearRefining Technologies, Ninth Wing Capital Join
delegates to interact freely with scientists and take up projects Hands for Modular Near-zero Emission Refineries
at CECRI. New York, USA: ClearRefining Technologies, LLC, and Ninth Wing
Capital, LLC, has announced its partnership to establish modular
Ramesh Babu, Dean, Centre for Education-CECRI, explained near-zero emission refineries in major metropolitan areas around the
the unique B.Tech. (Chemical and Electrochemical Engineering) globe to provide a clean alternative diesel fuel, known as GDiesel,
programme offered at the institution. V Ramamoorthi, retired that meets and exceeds government fuel standards. PGA Tour
Dean and Professor, AC Tech., Anna University, Chennai, Professional Billy Hurley III has also agreed to become the first brand
emphasised the role of electrochemical engineering in the ambassador for GDiesel. Over 40 million gallons of clean diesel fuel
present era. Electrochemical engineering was the need of have already been delivered to the Las Vegas and Reno markets,
the hour, he said and cited various real-life applications.The including power generators at a local PGA Tour event there. GDiesel is
conference was a great opportunity for young minds, they said demonstrating tremendous success in lowering vehicle maintenance
adding the technical symposium was being conducted with a costs by almost 50 percent; dramatically reducing both regulated
team of B.Tec.h and research scholars of CSIR-CECRI. It had and unregulated emissions; and increasing by 12 per cent vehicular
events such as oral presentation, poster presentation, science miles per gallon, according to Peter Gunnerman, Managing Partner
quiz, workshops on instrumentation, online competitions and of ClearRefining Technologies, the newly-formed parent company of
designing competitions, they said. Advanced Refining Concepts, LLC.
20 February 2016 Chemical Engineering World
CEW Technology News
Aqdot Bags EUR 5 Million of Fund Chinese Scientists Make Fertilizer from Potato
Effluent
Cambridge, UK: Cambridge-based chemical company Aqdot
has closed a EUR 5 million Series A funding round led by Lanzhou, China: Scientists in China have developed a way
Imperial Innovations Group. Parkwalk Advisors, Cambridge of making fertilizer from waste water discharged by potato
Enterprise the University of Cambridges commercialisation processing plants, solving a pollution problem which has held
arm and Providence Investment Company also participated in back Chinas potato ambitions.
the round. Founded in late 2012, Aqdot, a spin-out company of
the University of Cambridge specialises in producing intelligent China sees potatoes as a new staple food to ensure food security,
encapsulation technology. but protein-rich water discharged by starch processors, a major
buyer of the spuds, has been blamed for polluting rivers and
lakes. Lius team has developed technology that can halve the
Bright Future for Organic Solar Cells chemical oxygen demand (COD) of the effluent by removing
Wako, Japan: Although the amount of energy that organic solar starch, fiber and protein. The processed water does not need to
cells can generate from sunlight is lower than conventional be dumped either, because of its high nitrogen, potassium and
cells, experts say that there is room for improvement, with many phosphorus content make it a perfect irrigation water.
arguing they could be an effective tool for slashing carbon dioxide
emissions, in part, due to their pliable nature.
New Addition to the Periodical Table
Normally, solar cells that people imagine are ones on the roof North Carolina, USA: Four new chemical elements with atomic
that are heavy and firm (but) organic solar cells are very light numbers 113, 115, 117, and 118 have been formally added to the
and flexible, so they can be set up in places where it would be periodic table, completing the tables seventh row.
physically impossible to install regular solar panels, said Itaru
Osaka, a senior research scientist developing organic solar cells The additions have been made following the verification of the
at the state-backed Riken institute. discoveries of the elements by the International Union of Pure and
Applied Chemistry (IUPAC). Scientists in Japan, Russia and the US
Organic solar cells are made from organic compounds or discovered the elements, which are the first to be included in the table
polymers, while regular cells are made primarily of silicon. A since 2011. Elements 114 and 116 were included in the table in 2011.
silicon-based solar panel weighs about 15 to 20 kilograms and is
heated at hundreds of degrees Celsius during the manufacturing All the four elements are super heavy, lab-made, and very radioactive,
process, which actually results in greenhouse gas emissions. with which scientists will be able to create even heavier and synthetic
Osaka said organic solar cells are made by thinly coating the elements in times to come.
polymers on various materials, such as plastic, so they are light.
Also, the cells can be crafted at temperatures of less than 100
degrees, making them more environmentally friendly. Boston Collage Researchers Introduce New
Cross Coupling Chemical Reaction Method
Boston, USA: Researchers at Boston College have developed a
Scientists Invent Process to Directly Convert CO2
new type of cross coupling chemical reaction method, with the help
from Air into Methanol of a third reactant.
California, USA: Scientists at the University of Southern
The reaction has been developed on the basis of a Nobel Prize-
Californias (USC) Loker Hydrocarbon Research Institute have
winning technique, which is known to be one of the most complicated
invented a process to directly convert carbon dioxide (CO2) from
tools available to research chemists. The 2010 Nobel Prize in
the air into methanol at comparatively low temperatures. The
chemistry has the subject of transition metal catalysed cross-coupling
research has been led by GK Surya Prakash and George Olah
reactions. One of the major components of the reaction is known as
of the USC Dornsife College of Letters, Arts and Sciences and
Suzuki-Miyaura coupling, which unites two kinds of reactants, one
is a part of the greater attempt to reduce the amount of CO2 in donor electron and one acceptor electron. The process, developed
the atmosphere. by professor of chemistry at Boston College James P Morken and
his team, uses transition metals to develop a different cross-coupling
The effort also aims to use clean energy to convert greenhouse process that merges two electron donors by reacting with the electron
gas into its flammable sources. Methanol can be used as the acceptor. The team reported in the Science journal that the resulting
internal combustion engines fuel, and as a fuel for fuel cells, conjunctive reaction occurs efficiently and offers a high-degree
as well as raw material to make various petrochemical products. of selectivity.
22 February 2016 Chemical Engineering World
Introducing
a new world class!
VEGA, the world market leader in radar level measurement will
soon be presenting a new star in the galaxy of sensors. Get ready
for the technology of the future. Look forward to a new generation
full of innovative possibilities. Well keep you updated!

www.vega.com
CEW News Features

Purita is working towards the vision of being a


complete water management and solutions company
Started business catering to cooling water treatment programme with its first ever Chlorine Dioxide System for one
of the largest Power Generating Stations in India in 2005, Purita Water Solutions Pvt Ltd has extended its reach into
other sectors like Refinery, Petrochemical, Steel, Fertiliser etc with top-10 companies ruling in these sectors spanning
with nearly 30 happy clients, says Ravindra Wadel, Chairman & Managing Director, Purita Water Solutions Pvt Ltd.
He shares his view on the companys Indigenous Technologies and Precursor Chemicals for Cooling Water, Drinking
Water, Wastewater & Water Recycling applications for various sectors with CEW.

E
stablished in 2005, Purita Water Solutions CHLORACTIV 3109 which are essential
Pvt Ltd started business catering to raw material required for the production of
cooling water treatment program with its Chlorine Dioxide. We have increased our
first ever Chlorine Dioxide System for one of the reach by offering Japanese world class water
largest Power Generating Stations in India with & wastewater treatment chemicals for various
1600 MW installed capacity and cooling water applications. Hence, we can cover the entire
flow rate of nearly 1,80,000 m3/h. The system spectrum of water conditioning and treatment
was engineered, designed, supplied, installed program including systems and services,
and brought to successful commissioning & in reveals Wadel. Liquid discharge is becoming a common
operation from Year 2006 onwards. We were phenomenon and basic requirement in
privileged to manage the plant O&M from its Success Stories industry, says Wadel.
commissioning date until today which is quite Purita has achieved many first to its credit by
rare as customer showed continued faith in offering technology which is actually replacing We have been part of water & water waste
Puritas capability, says Wadel. the hazardous application of chlorine for business throughout and we really see a
water & wastewater. Our first installation good future ahead for the segment to grow.
Further, we have extended our reach into for a power station was based on techno- However, as the growth showing north, we have
other sectors like Refinery, Petrochemical, economic benefit by which our customer also competition increasing and hence in our
Steel, Fertiliser etc and we are proud to have reduced the operation & maintenance costs opinion, technology edge and related products
worked with top-10 companies ruling in these by nearly 40 per cent from their earlier budget would find its way into this highly competitive
sectors spanning with nearly 30 happy clients, and additionally our environment friendly and growing segment, adds Wadel.
Wadel explains. technology provided way for Chlorine Dioxide
Purita will strive to retain its leadership
use. In consequence our client also benefitted
position in Chlorine Dioxide business and
Indigenous Technologies and Precursor in reducing their time by nearly half in their
eventually enter into other segments of water
Chemicals planned outage and hence offered more
& wastewater businesses.
With a highly experienced team of professionals operating life to the power station. Many of
& experts, Purita offers alternative disinfection our clients have benefitted from this useful Association with Singapore Research
using environment friendly Chlorine Dioxide technology and we would like to maintain Institution
technology replacing hazardous Gas Chlorine our niche in the segment by constantly Purita believes in innovation and we have been
& related chemical applications in Cooling upgrading and innovating our designs, closely working with Singapore based research
Water, Drinking water, Wastewater & Water says Wadel. institute as a continuous evolving process. Our
recycling applications, says Wadel. gain from this research is to upgrade our design
Growth Drivers and safety standards to match with internally
We have launched our UniQu Design with Water has always been essential and precious acceptable standards, reveals Wadel.
portable (system on trailer) systems in 1 kg/h resource which has been underutilised in
to 48 kg/h requirements. These systems are our country putting pressure on Government Future Plan
pre-wired and ready to use for on-site in-situ to subsidise the water distribution and last Working towards a vison of being a complete
Chlorine Dioxide generation, Wadel continues. last 10- 15 years, we have seen continuous water management and solutions company,
evolvement and efficient use of water and Purita is aiming to bring the best water
Purita is a leading manufacturer of Precursor its resources. The more & more use or conditioning and treatment program technology
C h e m i c a l s i . e . C H L O R AC T I V 2 5 0 9 , reuse of water and achieving nearly ZERO effectively for an environment friendly future.
26 February 2016 Chemical Engineering World
CEW Features
Guest Column

The Criticality of Managing Supply Chain Energy Efficiently


Companies today are being energy efficient. There is considerable awareness about going
green and reducing carbon footprint. However, one aspect that they might be overlooking
is the energy spent in the various links of the supply chain. If one can manage supply
chain energy efficiently, carbon footprint reduces drastically, says Shaik Asad Parwez,
Head, Supply Chain, Racold Thermo Ltd.

O
ver the period there has been sharing to identify and improve energy supply chain management are following
a shift in the perspective of the efficiency and industry competitiveness. steps for efficient energy utilisation.
supply chain process. The focus The cost of the goods will decrease
has been shifted from reducing cost to as the supplier will get the benefit of These are some of the initiatives we at
reducing carbon footprint. The modern bulk purchasing of raw material, 100 Racold Thermo take up to ensure the
day manufacturers are looking at ways per cent utilisation of the plant capacity reduction of electric energy usage:
to reduce carbon emission. They have a and energy to run the plant, elimination Provide sufficient ventilation in the
broader target of reducing cost using the of wastage etc. On the other hand plant
energy efficiently, reducing the wastage companies can also reduce the carbon Introduce air ventilators for effective
having better productivity etc. footprint by initiating certain practices on exhaust system
the distribution front. Use transparent sheets on the roof for
In the coming years if the organisations proper sunlight
think out of the box and in collaboration Today, most of the companies operate Use induction lamp instead of MHL
with the supply chain of the other out of dedicated facilities and have a etc.
organisation, then there are opportunities dedicated logistic supplier taking care Solar water heaters for heating water
of reducing the carbon emission using the of operations. The companies can also Solar panels for generating electricity
best technology generating better profits. look for 3PL suppliers who can handle which can be used in production line
Piggy Bank issues: Where and What multiple account from the same facilities
to Save? hence the concept of shared resources From a futuristic point of view, the
can be utilised by doing so the company companies need to engage leading
In supply chain there is a great scope can reduce the overall logistics cost manufacturing companies to identify
for promoting energy efficiency, reducing as the warehouse facility, manpower, high-quality suppliers for pilot supply
costs & decreasing the environmental transportation, electricity are on sharing chain energy efficiency improvements.
footprint of consumer goods. The energy basis and this will also reduce the They can also create one or more sector-
& commercial efficiency can be achieved carbon footprint. based collaborations for improving supply
by engaging leading companies to identify chain energy efficiency by assembling
high quality suppliers. There can be a Tips of Energy Saving groups of peer manufacturers.
single supplier for many companies and Organisations need to list down their
he would do the manufacturing activity desire of reducing energy costs through There are several leading companies that
of all the companies under the same supply chain management. They also follow a regulated process to ensure an
roof. The supplier will follow the SOP need to be aware of the regulations to energy efficient supply chain keeping
for each and every company as defined follow and permits to take to ensure that those in mind, companies must follow suit.
by them. This will create sector-based all personnel involved in the process of They need to see the larger picture an
collaborations for improving supply chain
Supply chain teams have centralised and are managing the complexities
energy efficiency by assembling groups of
peer manufacturer within a supply chain of global supply chain. Supply chain network design incorporates
and using benchmarking and process variety of factors ranging from production purchase, warehousing,
capability analysis and best practice inventory and transportation.
30 February 2016 Chemical Engineering World
CEW Features
In a country like India where there is a different tax structure and rules order to adhere to the regulations and
and regulation for doing business in each and every state. In order to permits involved we have to increase the
operations in various states increasing
adhere to it the companies are forced to maintain warehouse in each
the cost of operations and carbon
and every state. footprint even though you can manage
energy efficient process and organisation Keep measuring the results, with less locations thereby reduced
is loved by the people, and with the that will help improve the carbon footprint as with each increased
saving costs operations can be improved. entire process location we incur additional layer of
It is a win-win situation. warehouses, transportation, and other
Reducing Carbon Footprints/Carbon related infrastructure and all these
Reducing Costs through Supply Chain Emissions lead to increased carbon footprint for
Management the environment.
Companies have realised that carbon
Supply chain teams have centralised and management in the supply chain plays
are managing the complexities of global VAT for doing local billing.
a vital role. Working in partnership can
supply chain. Supply chain network design CST billing is costly as the liability in
improve vehicle utilisation and reduce
incorporates variety of factors ranging on the company in case C Forms are
carbon emissions for all the companies.
from production purchase, warehousing, not submitted.
Appended below are few essential steps
inventory and transportation. It has Road permits for different states.
towards reducing carbon footprints:
driven many companies to redesign Octroi etc.
Using right metrics for carbon
and reconfigure their supply chains, Stock transfers between
management like improving
resulting to reduction in costs and giving locations to balance the
communications with suppliers to
effective outcome. inventory levels.
deliver performance
Optimise truckloads
Supply chain can examine ways to reduce With the advent of new tax regime GST
Utilise non-polluted/environment
costs by coordinating transportation business will become simpler and thereby
friendly vehicles
inventory and vendor strategies. For the companies can do business in the
Utilise rail or multimodal transportation
example: most cost effective manner with lesser
Delivering as per the vendor/ Optimise warehouse space utilisation, number of locations thereby helping
customers requirements, will avoid e.g. vertical storage reduce the overall carbon footprint.
adding up to the costs of back-and-
forth transportation Regulations and Permits involved in the
Understand the customer/vendors Process of Supply Chain Management
needs and define the supply chain In a country like India where there is a
strategy different tax structure and rules and
Getting a clear understanding of the regulation for doing business in each
process first and then only define the and every state. In order to adhere to
systems it the companies are forced to maintain
Using multiple suppliers avoids costly warehouse in each and every state.
delays in receiving products Doing business is complex. Hence in

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Industry teams today must comprehend and leverage a massive volume of information delivered by control
technologies. A process automation system can inform and enlighten plant personnel at all levels with context-
rich information. Last in a series of three, this paper explains the new operational insight that can be delivered
to plant operations after meeting basic needs for reliable, secure performance.

T
his paper focuses on how modern, Plant: Impact of Evolving Operations, Enhanced Engineering Tools
process automation systems Technology, and Workforce Changes Remedying production problems based
can enhance existing control and The Protected Plant: How an on root-cause analysis is a key role
technology. The goal is not just to inform Automation System Mitigates Risks to that systems engineers play while
plant personnel, but to enlighten them with Operational Integrity. increasing production value and managing
context-rich information delivering new constraints. Their work environment
levels of operational insight for operators, Operational Adjustments comprises a large variety of systems, each
systems engineers, project engineers, Plants will continue to grow larger and more of which may be from a different vendor
maintenance technicians, safety team complex. Operators will struggle to handle and each of whose technologies may be
members, and managers. the increased load. More instrumentation changing rapidly. These engineers need to
will need to be managed, more data will understand those systems well enough to
Information without context is noise. need to be processed, and, as a result, the diagnose production problems quickly, and
When surveyed, many of todays process potential for more human error will grow. then scale immediately to make necessary
industry engineers and operators indicate Unlike their predecessors, who viewed a improvements. Timing is critical. They no
that they have all the information they panel board to determine at a glance what longer have the time to analyse detailed
need, but want help in figuring out what to was going on in the plant, modern operators sequential flow charts, ladder logic,
do with it. The best way to filter that noise rely on workstation screens. They access function block diagrams, or structured text
is to ensure that each plant function has and absorb much more information at a to determine what is really taking place
clear, up-to-date information that enables faster speed. More steps are required in the system. These are abstractions of
safe, successful operation of the business. in order to properly assess and resolve the actual process and in many cases,
Although each job role operates within a problem. abstractions not created by the engineer
multiple contexts, automation systems who encounters them. Intuitive, easier-
can assist process plants most in the Modern systems will be designed to counter to-use interfaces are required for these
following areas: this gap between system complexity and engineers to complete their tasks.
human operator capability. For example,
Increasing production value new situational libraries based on One approach that offers engineers a
Reducing costs of raw materials modelling tools provide operators with the means for addressing these challenges
and energy content they need to adjust set points or is based on an enhanced version of
Improving plant safety and security otherwise respond with maximum speed. Scientific Apparatus Manufacturers
Improving environmental integrity and Pre-configured templates can improve Association (SAMA) configuration
regulatory compliance operator effectiveness, shorten response tools that are especially popular in the
Empowering the plant workforce time, reduce human error and fatigue, power industry. These tools present a
and ensure that all actions are consistent more accurate representation of the
This paper, the third in a series of three, with company procedures, policies, and relevant proportional-integral-derivative
focuses on how automation system strategies. In addition, critical information (PID) blocks and data flows. Such an
users can adjust to information overload can be displayed on smart phones and implementation can also include dynamic
and can incorporate new tools that will tablets for operation from almost anywhere, filters, which help engineers focus more
help them to simplify tasks in a more at any time, depending on the process directly on the control mode in which they
complex environment. The other papers and the intrinsic safety parameters of the are working. Users report that the intuitive
in this series include The Future-proof devices involved. modelling of such SAMA tools, combined
34 February 2016 Chemical Engineering World
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with the dynamism built into them, can attacks and must do so at the lowest awareness concept). Maintenance alerts
reduce engineering workloads by as much cost, but without the slightest increase could be programmed to prioritise based
as 60 per cent. in risk exposure. As discussed in The on achieving those same objectives. An
Protected Plant: How an Automation operator interface could warn of safety
Project Engineering Productivity System Mitigates Risks to Operational risks that might be introduced by changes
Project engineers must deliver new and Integrity, the second white paper in this in operations, and workflow engines could
major upgrades on time and on schedule. series, the role that a modern system plays connect all relevant functions.
They need real-time awareness of in maintaining the operational integrity of a
changing requirements and need to assess plant includes safety. In addition to the individual productivity
the cost of the technology required. improvements that a new system can bring
When a process automation system to each function, aligning everyone on the
Their productivity improves when they combines with a safety system, those same strategic page yields unmatched
can access an automation system that managing plant controls can work with competitive advantage to those companies
decouples the configuration layer from enhanced information regarding how and that implement it. Some of the references
the runtime layers, enabling significant where emergency shutdown capability is at the end of this paper provide more detail
portions of the system to be configured being deployed throughout the plant. To on how that alignment can be achieved.
and tested in the cloud. This speeds change these deployments, they go to a
project delivery by enabling engineering in separate interface or request modifications Object Model Future-Proof Benefits
the context of a hypothetical future state. from an engineer dedicated to the safety Many of the applications that will be
Such a system also supports engineering system but they have the information needed to manage the future have not yet
workbench and project management tools, they need to work in full awareness of been developed or even imagined, which
which can be deployed in the cloud to the safety protection levels in operation. is why it is critical to build on an open yet
enable project engineers to work in real- Dashboards can provide further context on secure system platform. Much like the case
time collaboration with colleagues around a companys risk profile and provide users with smartphone or tablet apps, adherence
the globe. the maximum flexibility of an integrated to common object models means users can
experience without jeopardising safety. benefit from future managing applications
Downtime Control still to be developed. The more closely
Maintenance technicians working to Managing in Context these applications adhere to the standards,
minimise downtime are also challenged For plant executives and managers, the the more easily users can incorporate and
with increasing volume and complexity future will demand more on-the-spot benefit from them.
of information. Systems generate an decision-making that could have serious
unprecedented quantity of alarms. The implications for plant profitability, safety, In addition to simplifying the delivery
systems that the technicians work on are and security. Managers will guide the of advanced tools and critical run-time
sourced from many different vendors who setting of strategies and polices that applications, a component object-based
use multiple protocols to communicate will make these decisions easier, but architecture and layered design can
and who provide unique toolsets and they must be confident that the entire enable easy plug-in of applications built
instruction manuals. plant is executing accordingly. A future- to open computing standards, such as the
ready automation solution must provide following:
One solution is a maintenance response an effective perspective across the
centre that can display maintenance enterprise, facilitating better and faster a. Simulation, modelling and software,
alert dashboards comparable to the business decisions. which supports operator training,
alarm management systems that real-time online optimisation, and
operators use. When maintenance alerts A modern system should provide all multivariable process control
sound, the dashboard helps technicians components necessary to integrate b. Enterprise manufacturing intelligence,
determine where to start drilling deeper execution of plant strategies at every level. which delivers real-time insight into
into procedures, inventory and other A template of the operator situational trends in production and operation
information they need to solve the problem. awareness library, for example, could c. Corporate energy management, which
Integration of workflow management helps display real-time monitoring of performance helps management deal with fluctuating
maintenance technicians synchronise their against one or more of the objectives energy costs and supply
activities with others who may be working mentioned earlier, such as reducing raw d. SCADA applications that are customised
on, or be affected by, a problem. material or energy costs (see Schneider for well-field, pipeline, water/
Electric white paper How Human Machine wastewater, and other applications
Security Enhancement Interface (HMI) Impacts Business e. Enterprise asset management software,
Safety team members must secure the Performance in Industrial Sites for more which reduces costs through improved
plant from safety breaches and cyber information regarding the situational diagnostics, inventory management,
36 February 2016 Chemical Engineering World
Unit II : Plot No. 4/18, Sector No. 10, PCNTDA, Bhosari,
EMJAY B/102,
Pune Shubh Sarita
411026,
ENGINEERS, CHS,
Mr.Tel. No.Near
Jayant Shrikirshna
: (020)
Joshi Nagar,
66146033.
st@koerting.de
Your vacuum drying
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III : J-414, MIDC, Bhosari, Pune - 411026 B/102,Appasaheb
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ADVERTISE TO EXPAND
CEW Features
and preventive and predictive maintenance
f. Mobile applications, which deliver real-time procedure guidance
to field workers and enable real-time reporting

Conclusion
In the final analysis, automation does not solve problems; people ` VOL. 49 NO. 3 March 2014 US $ 10 ` 150

do. While a future-ready, future-proof process automation system


can deliver tremendous competitive and protective benefits,
the real strength of the control system is in its application, not
its technology. That application is in the hands of the people
who use it.

Automation has traditionally meant replacing human activity. Now, EPCM Special
recent advances in automation technology and the demands of the 28-31 January
rry 2015, Mumbai, India
ChemTECH World Expo 2015
28-31 January 2015, Mumbai, India

future have moved the industry into a new age. It is an age in which
automation is not replacing operational roles or dumping raw data
on people in the plant. Instead, it is enlightening plant personnel
with the context-rich information they need, and thus helping them
perform their roles better, more safely, and with greater gain for
themselves, their employers, and the consumers of their products.

References
1. Martin, Peter G., Walt Boyes, and Kaoru Maruta, Real Time
Control of the Industrial Enterprise, New York, NY: Momentum
Press, 2013.

2. Martin, Peter G., Bottom-Line Automation, 2nd ed., Research


Triangle Park, NC: International Society of Automation, 2006.

3. Martin, Peter G., Real-Time Strategic Empowerment for


Improved Profitability, white paper, Invensys Operations
Management, 2012.

4. Martin, Peter G., Real-Time Profit Control: Driving Profitability


in the Dynamic Industrial Environment, white paper, Invensys
Operations Management, 2011.

Authors Details

Dr Peter G Martin
Vice President Strategic Ventures
and Marketing
Schneider Electric

Grant Le Sueur
Director Product Management
Schneider Electric
38 February 2016 Chemical Engineering World
Features CEW
Technical Article

What Unnecessary Risks are You Taking?


What would you think if you saw someone using a shopping trolley as a car jack? Or a newspaper and sunglasses
as an improvised welding mask? You would probably ask yourself why anyone would put themselves in that kind
of danger. Here, the author explains why companies should never take any chances, especially where testing
and analysis are concerned.

S
trict Legislation frequent testing can also help extend the Only as the fluid approaches the end
The Dangerous Substances life of thermal fluid. More importantly, of its practical working life, there is a
and Explosive Atmospheres a timely reaction to early warnings can gradual curve which eventually drops
Regulations (DSEAR) of 2002 and the help you avoid replacement of costly off very sharply. This sudden change in
Explosive Atmosphere Directive (ATEX equipment and even save lives. In the quality of thermal fluids is one of the
137) set the minimum requirements environments where the risks are so high, reasons why regular and preventative
for protection against risks from fire, no expense should be spared to ensure maintenance is so important.
explosions and similar events arising legislation is respected and thorough
from dangerous substances used efforts are made to keep employees and Diluting the thermal fluid by topping up is
or present in the workplace. The premises safe. a cost effective and durable option only
legislation introduced more rigorous while the fluid is in the early part of the
testing for operators, including What Risk? degradation curve. After the condition of
regular and representative analysis of In a nutshell, the dangers caused by the fluid has significantly deteriorated,
thermal fluids. the lack of preventative maintenance dilution is no longer a viable alternative.
are rooted in the degradation of thermal It would have the same effect as putting
Respecting The Dangerous Substances fluid. Over time, heat transfer fluid breaks a new torch battery into a two battery
and Explosive Atmospheres Regulations down through a process called thermal torch alongside a battery that has already
(DSEAR) guidelines helps companies cracking. The fluids molecules are been used for some time. It would not
identify early warnings regarding process broken down into smaller particles and be a long term solution and would result
problems, helps maintain a safe and several types of fractions are released in the system not operating at optimum
efficient working environment and save from this chemical reaction. The first side capacity. That being said, the best thing
costs. Preventative maintenance and products of thermal cracking are light to do when the thermal fluid reaches the
ends that have a low boiling point and are end of its lifespan is to flush and clean
very volatile. the system, prior to refilling it with a fresh
charge of heat transfer fluid.
The second category of thermal cracking
decomposition products are heavy Hot, Closed and Circulating
ends, which recombine to form heavy Despite the clarity of existing legislation
polyaromatic molecules that usually and the dangers of neglecting thermal
cause fouling of the heat transfer system. fluid analysis, companies often fail to
As a result, carbon molecules will stick to perform the sampling DSEAR requires
the system internals and reduce process and carry out irrelevant tests, including
efficiency, unless cleaned and flushed lube oil tests. These are sometimes non-
in time. applicable and do not always provide the
necessary information.
It is crucial to remember that thermal
fluid does not go from being fit for use Sample methodology is crucial incorrect
to needing replacement overnight. sampling give inaccurate flash point
There is a grey area where fluids can be results, which can have very dangerous
managed against what specialists call consequences. Unless the fluid samples
Preventive maintenance and frequent testing helps the degradation curve. Degradation is are collected when the oil is hot and
maintain a safe and efficient working environment, save
cost and extend the life of thermal fluid. steady if a system is operated properly. circulating, they will reveal artificially
Chemical Engineering World February 2016 39
CEW Features
this spread takes place is the samples
flash point. Because closed cup tests give
lower flash point values (between five and
ten degrees Celsius difference), they are
a better approximation to the temperature
at which the vapour pressure reaches the
lower flammable limit. To ensure final
result accuracy, a Seta open cup flash
test is also performed on the fluid sample.

An acidity level test identifies the amount


of additive depletion, oxidation or acidic
contamination, in a thermal fluid sample.
The acid number is determined by the
amount of Potassium Hydroxide (KOH)
base required to neutralise the acid in
one gram of an oil sample.

These three main areas of testing are


It is crucial to remember that thermal fluid does not go from being fit for use to needing replacement overnight complemented by additional checks,
including appearance, viscosity, water
high flash point values. This incorrect Best Practice Sampling and ferrous content, particulate quantities
sampling will lead to the conclusion After the samples have been taken correctly, and fire point testing. The data from the
that the system is safe, when in reality the interpretation of data is essential eleven tests forms the basis of a holistic
it might not be. Inaccurate samples and this is where Global Heat Transfers analysis based on trend data, which
can have negative consequences, experience and eleven-point test takes results in an accurate thermal fluid
including decreased energy efficiency, the best-practice cake. As opposed to evaluation. Parameters for action, caution
unmanageable flash points and a most companies, that only provide a and satisfactory levels are the key factors
dangerous working environment with risks seven point test, GHT looks in detail at when conducting the result analysis.
of explosions. key data to ensure the results completely
reflect reality. The complexity of thermal fluid testing
The sample also needs to be closed so might seem intimidating, but the
that no potential atmospheric particles The three main checks that Global Heat importance of the process cannot be
can contaminate it or distort the results. Transfer focuses on are carbon level stressed enough. Respecting legal
An open sample would also allow light and amount of insoluble particles, a regulations, performing preventative
ends to flash off to the atmosphere, closed flash point test and the acidity maintenance and frequent testing are the
instead of remaining in the sample, which level (TAN). best ways to ensure your company is not
produces unreliable readings. taking any unnecessary risks. Otherwise,
The Ramsbottom Carbon Residue test you might as well be using newspaper
Test Often and Well (RCR) is a method of calculating the and sunglasses instead of personal
Frequent sampling is crucial. DSEAR says carbon residue in a fluid. If the carbon protective equipment.
manufacturers must show they are taking level (heavy ends) is too high, build-ups
appropriate measures to mitigate health can occur, which will reduce the efficiency
and safety. GHT encourages its clients of the system, make pumps work harder
to perform the eleven point test at least and result in higher running costs for
twice a year, every three months ideally, the company.
and even more frequently than that in
some applications. Global Heat Transfer performs both
Authors Details
types of flash point measurement: open
Finally, testing in an accredited lab, and closed cup. The Pensky-Martens
in the correct conditions is the key to closed flash test involves the heating of Andy Burns
getting accurate results. As with general test specimens in a covered brass cup at Technical Business
maintenance, identifying a problem regular intervals until a flash point that Manager
early helps avoid complications without spreads throughout the inside of the cup Global Heat Transfer
excessive cost or efforts. is identified. The temperature at which carolinel@globalgroup.org

40 February 2016 Chemical Engineering World


Features CEW
Technical Article

Process Intensification - An Insight


The concepts of Process Intensification (PI) in chemical industry has started evolving quite strongly in the
past 15 years with interestingly novel hardware and software applications being reported in bio-processing and
fine chemicals. This article talks about the need for PI and its advantages. Principles and Barriers of Process
Intensification are also discussed.

T
he process economies of chemical column packed with catalyst. 1 In the 10 th conference on PI for chemical industry
industry are fraught with two Annual Research Meeting of Institute of was organized in Antwerp, Belgium by
major challenges namely, capital Chemical Engineers (IChemE) on process UK-based BHR Group, a technology
investment and operational expenses. intensification held in the same year, the organization in fluids engineering. 2
While one could be reduced at the cost first research paper from South Africa Towards late nineties PI technologies
of the other, simultaneous reduction in was based on intensive underground were developed in research labs across
both the costs would result in an optimal processing of gold ore. 3 A total of 16 the world such as microreactors in USA
solution. Improving process efficiency papers concerning the fields of mineral (Massachusetts Institute of Technology)
to lower the equipment volumes and and Germany (Institut fur Mikrotechnik,
processing, heat transfer, chemical
simultaneously combining a number Mainz), high-gravity processing in
reactor and plant design with control were
China (Beijing University), compact heat
of unit operations in an equipment presented in the aforesaid meeting. 3 On
transfer in France (Greth CEN Institute)
would bring down associated capital a commercial scale, Eastman Chemicals
and centrifugal adsorption in The
investment. Process Intensification set up a reactive distillation tower in
Netherlands (TU Delft). 5 The concepts
typically addresses these aspects of cost 1980s with multifunctional capabilities of PI in chemical industry has started
optimisation either by miniaturisation reducing 80 per cent energy requirements evolving quite strongly in the past 15
of equipment or by synergizing various as compared to conventional operations. 4 years with interestingly novel hardware
process steps. Process Intensification Throughout the next two decades, mostly and software applications being reported
(PI) can be defined as a set of innovative within United Kingdom, a lot of improvised in bio-processing and fine chemicals. 5,6
technologies that focuses on minimisation versions of PI sprung up utilizing the
of plant profile thus reducing capital concepts of centrifugation, enhanced Why Process Intensification?
costs and their integration to achieve heat transfer based on spatial domain The cardinal principle governing process
high capacity, reduced footprint (area), and micromixing. In 1995, the first full intensification has been improved
increased selectivity and enhanced heat
and mass transfer rates. 1 It involves
constant miniaturisation and integration of
engineering methods and equipment. 7 Its
approach towards design of sustainable
chemical processing plants is based
on four dimensions namely, structure,
energy, synergy and time. 2

The term, Process Intensification was


introduced in 1960s by an East-European
publication on Metallurgy. In 1983,
Prof. Colin Ramshaw, widely regarded
as the father of process intensification
(PI), developed first set of innovations
related to the subject in separation
processes. 1,2 His work analysed the effect
of high gravity field in distillation and a
hybrid strategy to combine separation
with reaction processes in a single Figure 1: Main advantages of process intensification

Chemical Engineering World February 2016 41


CEW Features

Source of Energy Intensified Element Intensification changing the kinetics


Factor* Improving conversions & selectivity
Avoiding unwanted side products
High gravity field Reaction time 1000
Improving number & frequency of
Static electric field Interfacial area (by emulsification) 500 collisions
Microwaves Reaction time (for liquid-phase 1250 Better understanding of equipment
catalytic reaction) & flow geometry for improved
Ultrasound irradiation Reaction time 25 orientation of molecules in the
Supersonic flow Gas-liquid mass transfer coefficient 10 moment of collisions & their energy
Capacity (for fluidized-bed reactor) 2.25 Designing uniform products with
minimum waste
*Reported possible improvement (as number of times) in comparison to conventional technology Macroscopic residence time
Table 1: Process intensification effects of the alternative sources and forms of energy 10
distribution, reduction in dead
zones & bypassing
Technologies Benefits Commercial Meso & micro-mixing
Feedstock Capital cost Energy implementation*
cost requirements 2. Optimizing driving forces & maximizing
Reactive distillation 20-80% 20-80% >150 specific area
DWC distillation 10-30% 10-30% >100 Improving transport rates
across interfaces by maximizing
Reverse flow reactor >20% Low >100
interfacial area from millimetre to
Microchannel reactor Yes Yes Only in fine the micrometre scale of channel
(for small scale) chemicals and dimensions
pharmaceutical Maximizing driving force
sector (concentration difference) not
*In terms of number of units commercialised6, 9 always required
Table 2: Process intensification in petrochemical industry and their benefits 9

3. Maximizing synergistic effects from


utilisation of molecular interactions to attain gross efficiency enhancement
partial processes
under optimised conditions of driving of chemical and biochemical processes. 8
Multifunctionality on the macroscale
forces and synergistic effect of different PI gains momentum in commercial
Reaction-cum-separation by
unit operations. While gradient- operations for reduced requirement
removing products from the reaction
free temperature and concentration for consumables as well as waste
environment
profiles are achieved with reduction management. The benefits of reduction in
in residence time, 2 lower pressure plant economics and energy requirements
Process intensification differs from process
level can be maintained with minimum as achieved in the petrochemical industry
optimization (defined as performance
energy requirements thus ensuring high have been summarized in Table 2 by
the researcher from Shell Technology improvement of existing concepts) and
level of safety in chemical plants. The process system engineering (defined as
Solutions, The Netherlands. 9 As per an
combination of different unit operations multi-scale integration of existing and
European publication 10 in 2008, the overall
results in better process control with new concepts). Table 3 on the next page
energy savings across industrial sectors
lower degrees of freedom. 2 Adopting PI gives brief description of each process.
(namely bulk & fine chemicals and food
techniques results in nearly 20 per cent of
processing) on use of PI technologies
total plant cost. 1 Operating costs largely Barriers to Process Intensification
such as multifunctional equipment, micro-
comprise of the consumables, process While several PI technologies have
reactors, microwaves and high gravity
utilities and level of plant maintenance. field (spinning tube reactor) is estimated achieved success on a lab scale, they
These parameters can be optimised with (on current trends) to reach nearly are still at infancy as long as their
improved output yield and turnaround 100 x 10 15 Joules per year by 2050. industrial applications are concerned.
time achieved through PI techniques. The industrial adoption of PI is faced with
The opportunities offered by PI are Principles of Process Intensification several barriers:
summarised as shown in Figure 1 on the The major principles that drive the Lack of in depth knowledge and know-
previous page. process intensification are as follows: how in PI among process engineers
1. Maximizing effectiveness of intra & Inadequacy in pilot scale facilities for
Table 1 summarises various alternative intermolecular events PI for the existing production lines
sources and forms of energy that can The processes not limited by their High stakes (both technical and
be utilised for PI technologies in order inherent kinetics but governed by financial) in prototype development
42 February 2016 Chemical Engineering World
Features CEW
as well as in retrofitting of existing
process
Lack of awareness among the top
management about the potential
benefits of PI technologies
Non-availability of process control
systems catering to novel PI modules

The R&D efforts in chemical industry


primarily focus on new products
(chemistry) and much less on the new
manufacturing methods (chemical
engineering). The chemical manufacturers
are not interested in developing novel
types of equipment or processing
techniques and simultaneously the
Figure 2: Broad technology applications for process intensification. 7
equipment manufacturers and engineering
companies are not sufficiently active in crystallization and compact heat the plant. It involved elimination of a
process intensification.
exchangers. PI has been successfully few number of condensers and reboilers
applied for scale-up of continuous involving the sub-mixtures that resulted
Other barriers include high cost to retrofit
reactors and also for alternative retrofit in a reduction of 23 per cent in energy
PI technologies in current plants thus
methods for existing processing plants. costs when compared to the existing plant
increasing the risks of commercializing
Figure 2 presents common classification design layout. 11
breakthrough technology. Scaling up of PI
for PI technologies as suggested by
techniques from lab to pilot to commercial
Stankiewicz and Moulijn. 7 Numerous case Micro-reactors: Micro-reactors is a class
scales poses major challenges. PI
studies elaborate the advances in PI of chemical reactors at sub-millimeter
technologies warrant long development
over the past three decades that started level that can achieve reduced volume,
path, which calls for effective IP
off with the reactive distillation process higher product selectivity and higher
cooperation among various R&D labs,
developed in 1983. 1,2 reaction rate. 2,5 It helps in complete mixing
universities and industries.
even for highly viscous fluids at large flow
The merits of reactive distillation include rates. Alternative reaction pathways are
Process Intensification Select
reduced equipment size thus lowering made possible due to higher heat and
Technologies
capital cost, less energy use, and higher mass transfer rates and precise control of
The technology application for PI broadly
reaction volume under consideration. 5,12
includes micro-reactors, simulated product yields. 4 Recently, M. Errico et al.
Figures. 3 (a) and (b) (shown on the next
moving bed reactor, oscillatory baffled suggested a retrofit to existing distillation
page) are schematic representations of
reactor, tube-in-tube reactor, reactive systems through thermal coupling
pioneering attempt on an integration of
distillation, membrane or ultra-sound technique to minimize physical size of
automated process controls and micro-
reactors for homogeneous catalysis. 13
Process Optimisation Process Systems Process
Engineering Intensification
Typical applications include catalysis,
Aim Performance Multi-scale Development of new steam reforming, organic synthesis
improvement of existing integration of existing concepts of process
and multiphase reactions. 13,14 A recent
concepts and new concepts steps and equipment
example has been the use of cross-flow
Focus Model, numerical method Model, software Experiment, micro-channel reactors for reversible
phenomenon, polymerization at 90 oC to form poly(vinyl
inter-phase butyral), a high-demand product for
Interdisciplinary Weak (interface with Modest (mostly Strong (chemistry the manufacture of safety glasses in
applied mathematics) applied mathematics & catalysis, applied automobile industry. 13 It involves viscous
and informatics, physics, mechanical fluids such as poly(vinyl alcohol) and
chemistry) engineering, n-butanal in presence of acid catalyst.
materials science, Conventionally the batch process has
electronics etc.) lower rate of reaction with a product yield
Table 3.0: Basic Features of Three Areas of Chemical and Process Engineering of 20 to 30 per cent (expressed in terms
Chemical Engineering World February 2016 43
CEW Features
utilises temperature and flow reversals
on alternate basis to control variations
in water flux and salt concentration
profile. It uses a thin Teflon (TS22)
active stratum and polypropylene (PP22)
support layer of overall thickness 175 m,
effective surface area 89 cm 2, pore size
0.22 m and porosity of 70 per cent. The
pre-filtered water is fed at 1.6 Lits/min
at 50 oC and the distillate is highly pure
water devoid of non-volatiles collected at
room temperature.

Reduced distillate conductivity estimates


Figures 3: (a) Schematic view of microreactors as printed circuit boards 14 (b) Numbered-up approach of multiple
microreactors 14 (c) Comparison of product yield (% in terms of acetalisation degree (AD) or butyral group content) for
the quantitative reduction in salt
the reversible polymerization reaction at a mass concentration ratio of n-butanal to PVA of 0.8 and an aging time () of concentration. Membrane distillation at
3 hours 13
lower temperature difference of 20 oC over
ambient resulted in higher water flux and
salt concentration at membrane interface
of TS22 membrane as shown in Figure
4.0. Cold feed water at 15 oC is used at
periodic interval to reduce scaling thereby
lowering membrane maintenance costs. 16
An intensification factor of 16 in terms of
surface area requirements in comparison
to conventional evaporation ponds for
concentrated salt solutions has been
possible. The above technique when
integrated with low grade heat sources
and environment tax benefits, can
achieve high-quality water production at
Figure 4: (a) Schematic process flow diagram of a typical membrane distillation unit (b) Variation of total solids content
(TDS) in pre-filtered brackish water samples at feed side for different types of membrane material (PP22 and TS22) at
an optimized cost of USD 0.57 per cubic
temperature difference of 20 oC 16 metre of pure water produced. 16

of butyral group content) resulting in Membrane Distillation: Role of


High Gravity Processing: The
precipitation problems and phase change. membrane technology in enhancing mass
application of high gravity field using
On using 1000 m length x 500 m wide transfer efficiencies has been significant
a high-speed rotor allows counter-
micro-channels made of stainless steel by reduction in capacity and energy current gas-liquid flow through a rotating
and PTFE (Teflon) in cross-flow pattern requirements. It is a hybrid technique packed bed where one of the phases is
submerged in water, a well-controlled combining membrane separation and fed continuously. It requires minimal
reaction takes place at 50 oC within less conventional distillation. 7 Desalination area requirements, less maintenance,
than 56 seconds and the product yield units based on osmotic pressure
has been reported as high as nearly 75 reduced equipment weight and provides
difference cover nearly 60 per cent of short contact time over rotor packing with
per cent after an hour of aging. 13
existing plants all over world. 15 enhancement in heat and mass transfer
The optimized flow-rate at 5 per cent rates. 5 The need for de-aerated seawater
But their performance suffers due in oil fields for re-injection purposes to
PVA solution for a maximum limit of
to brackish feed water with high salt avoid blocked pipe-works near oil-bearing
80 ml/min resulted in good mixing
performance as shown in Figure 4.0 (c). 13 content. Recently, direct contact rocks could be met through high-gravity
The resultant process optimisation for membrane distillation with conductive processing (Higee) technique. Otherwise
catalyst can lead to reduction of working heat transfer is reported to have a conventional vacuum stripper of 3 m
capital for different utilities. Some of its achieved nearly 100 per cent inorganic diameter and 10 m height with large
major limitations include insignificance salt rejection with no additional energy auxiliaries would be required to reduce
of gravity forces, scale formation due consumption. 16 The technique developed oxygen content to parts per billion (ppb)
to material incompatibility and micro- by Hickenbottom and Cath for feeds with concentration level. 17 To achieve effective
fabrication costs. very high total dissolved solids (TDS) momentum transfer to feed seawater
44 February 2016 Chemical Engineering World
Features CEW

Figure 5: Schematic Diagram of Higee Unit

(500 m 3/hour), the requisite minimum


pressure is of 2.2 bar for Higee deaeration
operation. The energy requirements for
Figure 6: (a) Operating principle of spinning Disc Reactor (SDR) (b) Comparison of particle size distribution between plant
Higee technology primarily depends on material obtained from conventional batch process and that from spinning disc reactor (SDR) 18
the process time required for tip speed
of rotor to be nearly equivalent to liquid intermediate (Darzens reaction) useful ventilation and cooling (HVAC) systems
velocity over radial direction. in drug development. It occurs within and heat pumps. 19 During the last decade,
a second at 20 oC with less than 0.1 two notable CHE designs evolved namely,
An intensification factor of 1000 in terms of per cent impurity when compared to an Compabloc from Alfa Laval, Sweden and
oxygen concentration in treated seawater operating temperature of 0 oC with nearly Marbond heat exchanger from Chart
samples is estimated. 17 Use of 400 RPM, 1.5 per cent impurity in conventional Marston, UK. 1,19,20 Compabloc is a laser-
2.8 m length, 1.0 m diameter rotor with a batch reactors. 18 welded plate heat exchanger comprising
cost-effective packing of reticulated metal corrugated plates with an alternate
foam reported a reduction of 90 per cent in Another reaction demonstrated in SDR cross-flow pattern at high turbulence
energy consumption. Major drawbacks in is based on re-crystallization of like with multi-pass arrangement as shown in
this virtual separation column with evenly mesylate salt solution using hot acetic Figure 8 (b) on the next page.
spread bubbles maintained throughout 10 acid in tert-butyl methyl ether (an anti-
mm thick packing are the resultant high solvent) to form an active pharmaceutical A reduced plant footprint is achieved
pressure drop and backmixing problems. ingredient useful for various formulations. by an intensification factor of 3.5 when
PTFE coating over the spinning disc compared to conventional shell-and-tube
Spinning Disc Reactor provides better control of particle size heat exchangers for the same thermal
Spinning Disc Reactor (SDR) technology distribution with a maximum limit of load. On industrial implementation,
finds application where the problem of 3 m as illustrated in Figure 6 (b) and Compabloc technology has been utilized
backmixing as in stirred tank reactors prevent mass clusters. 18 Some of the for an evaporator unit in ammonium nitrate
and higher energy requirements as in major limitations include control of production plant in Slovakia from 2001
high-gravity field process reactors are turbulence of thin liquid film, process onwards that resulted in enhancement of
eliminated with the utilisation of thin liquid stability, maintaining vacuum conditions heat transfer rates, lower fouling problems
film formation specific to its spin disc and material compatibility. and a large reduction in energy consumption
design. It focuses on the intensification (~5 MW) for steam. 20 Marbond heat
of spatial domain to obtain uniform mixing Compact Heat Exchangers exchanger, almost of the size of a lap-top
in laminar region (assumed) and very Compact heat exchangers (CHE) provide has been developed with hydraulic channels
short residence time. 5,18 A typical SDR increased available heat transfer area to of sub-millimeter diameter and high voidage
design involves a liquid film of micrometer exchanger volume thus lowering size and making it suitable for multiphase chemical
thickness over a spinning disc that is capital cost.5 Its values range between systems. A significant reduction in capacity
subject to high circumferential velocity 300 to 700 m 2/ m 3 for liquid phase and by about 95 per cent can be achieved when
(up to 1000 RPM) over spiral grooves even higher for gas phase. Typical compared to existing conventional shell-
under an inert atmosphere, mostly examples include plate or plate-fin heat and-tube heat exchangers if corrosion-free
nitrogen below 1 bar pressure. 16 Coolants exchangers and hybrid combination of environment is maintained. 19 Some of the
such as ethylene glycol or water are used reactors and heat exchangers fabricated demerits of CHE technology include poor
to maintain disc operating temperatures. on printed circuit boards for enhancement involvement of inertial forces, high pressure
An example is a multiphase reaction of heat transfer rates. 19 This class of heat drop on use of highly viscous fluids and
for development of an alkyl cyanate ion exchangers finds applications in heating, fouling problems.
Chemical Engineering World February 2016 45
CEW Features
intensification in existing units.10,21,22 Presently,
the major challenges exist in the commercial
implementation of several PI technologies that
have evolved over the past three decades.
The primary reason hindering adoption of PI
technology by industries could be attributed to
an apprehension on delay over achievement
of production targets accompanied by a risk
of loss in market share. To ensure specific
production requirements and smoother
implementation of PI, industries need to
partner with R&D or academic institutions at
an early stage with investment in research to
succeed commercially.

References:
1. Costello Rocky, Process intensification -
think small, Innovations in Pharmaceutical
Technology, 2012, 126-132.
Figure 7: Comparison of different heat exchanger types in terms of hydraulic diameter (in mm) and area density (in m 2
per m 3) 19. PHE: Plate heat exchanger, S+THX: Shell-and-tube heat exchanger, PFHE: Plate-fin heat exchanger, PCHE: 2. Process Intensification, An online M.Sc.
Printed-circuit heat exchanger
Course offered by TU Delft, The Netherlands,
2012.
3. Proceedings of 10th Annual Research
Meeting of Institute of Chemical Engineers
(IChemE) held at University of Manchester
Institute of Science and Technology
(UMIST), Manchester, UK, 1983. http://
archive.icheme.org
4. Harmsen Jan G, Reactive distillation:
The front-runner of industrial process
intensification: A full review of commercial
applications, research, scale-up, design
and operation, Chemical Engineering and
Processing: Process intensification, 2007,
46, 774-780.
5. Staankiewicz Andrej, Moulijn Jacob A, Re-
Figure 8: (a) Comparison of Alfa Lavals Compabloc and conventional shell-and-tube heat exchangers for the same heat
transfer duty (b) Section view of Compabloc heat exchanger 20 engineering the chemical processing plant,
Marcel Dekker, USA, 2004, ISBN: 0-8247-
Conclusion their disposal methods. One of the feasible 4302-4.
Process intensification offers an effective options could be the induction of renewable 6. Excerpts from H. L. Roy Memorial Lecture
approach in optimizing raw materials, land, energy sources like solar, wind or bio-energy delivered by K V Raghavan, at Chemcon
utilities, energy input and capital costs in PI technology applications to further offset 2015, Indian Institute of Technology,
resulting in efficient operating conditions CO2 gas emissions and energy consumption. Guwahati, India.
for significant reduction in working capital While addressing cleaner aspects of process 7. Stankiewicz A I and Moulijn J A, Process
and simultaneously maximizing output. The technologies, PI strategies in reducing energy intensification: transforming chemical
minimization of physical size of the plant consumption (both temperature & pressure) engineering, Chemical Engineering
by PI helps in better process control and and enhancing product yield would also improve Progress, 2000, 96(1), 22-34.
sustenance of overall plant inventory. The safety concerns of the chemical industry. In 8. Stankiewicz A, Energy Matters: Alternative
recent advances in PI concepts in chemical India, dedicated efforts on micro-reactors sources and forms of energy for intensification
reactors, membrane separation and heat and membrane separation are underway of chemical and biochemical processes,
exchangers infer the quality of research work at various Government funded academic Chemical Engineering Research and Design,
being carried out across the world. There institutions and research laboratories. On 2006, 84 (A7), 511-521.
is a need to address environmental issues analysing the energy use data, it is estimated 9. Harmsen Jan, Process intensification in the
associated with innovative PI technologies that the Indian chemical sector could have petrochemical industry: Drivers and hurdles
such as control over carbon footprint10, reduced energy consumption by more than for commercial implementation, Chemical
accumulation of unwanted by-products and 20 per cent in 2014 by adopting overall plant Engineering and Processing: Process

46 February 2016 Chemical Engineering World


Features CEW
intensification, 2010, 49, 70-73.
10. Reay D A, The role of process intensification in cutting greenhouse gas
emission, Applied Thermal Engineering, 2008, 28, 20112019.
11. Errico M, Rong Ben-Guang, Tola Giuseppe, Turunen Illka, Process
intensification for the retrofit of a multicomponent distillation plant-An
industrial case study, Industrial and Engineering Chemistry Research,
2008, 47, 1975-1980.
12. Worz O, Jackel K P, Richter T., Wolf A, Microreactors, a new efficient
tool for optimum reactor design, Chemical Engineering Science, 2001,
56, 1029-1033.
13. Xi Yan Lin, Ji Song Zhang, Guang Sheng Luo, Process intensification
of the synthesis of poly(vinyl butyral) using a microstructured chemical
system, Industrial and Engineering Chemistry Research, 2015, 54,
3582-3588.
14. Jensen Klavs F, Microreaction engineering-is small better?, Chemical
Engineering Science, 2001, 56, 293-303.
15. Drioli E., Stankiewicz A. I., Macedonio F., Membrane engineering in
process intensification, Journal of Membrane Science, 2011, 380, 1-8.
16. Hickenbottom K. L., Cath Tzahi Y., Sustainable operation of membrane
distillation for enhancement of mineral recovery from hypersaline
solutions, Journal of Membrane Science, 2014, 454, 426-435.
17. Peel J., Howarth C. R., Ramshaw C., Process intensification: Higee
seawater deaeration, Chemical Engineering Research and Design,
1998, 76, 5, 585-593.
18. Oxley P., Brechtelsbauer C., Ricard F., Lewis N., Ramshaw C.,
Evaluation of spinning disk reactor technology for the manufacture of
pharmaceuticals, Ind. Eng. Chem. Res., 2000, 39, 2175-2182.
19. Reay D. A., Compact heat exchangers, enhancement and heat pumps,
International Journal of Refrigeration, 2002, 25, 460-470.
20. Official website of Alfa Laval Corporate AB, Lund, Sweden. Available
online at: http://www.alfalaval.com
21. Industrial Energy Consumption in the UK, UK Department of Energy &
Climate Change, 2015.
22. Energy Statistics 2015, Central Statistics Office, National Statistical
Organisation, Ministry of Statistics and Programme Implementation,
Government of India.

Authors Details

Raghu Krishna Moorthy


B.Tech (Hons.) - Government Engineering College, Calicut
Currently studying M.Tech at NIT-Trichy
raghukmoorthy@gmail.com

Sangeeta Baksi
Scientist in TIFAC
sangeetabaksi@gmail.com

Soumitra Biswas
Adviser/Scientist-G in TIFAC
soumitra2000@gmail.com

Chemical Engineering World February 2016 47


CEW Market Insights

Water Treatment Additives Market to Hit


35.2 Billion USD by 2020

A
ccording to the report, the water treatment additives market
is estimated to reach USD 35.2 Billion by 2020 at a high
CAGR. Published by IndustryARC, the report states that
high rates of Industrialisation in APAC coupled with Government
regulations driving the Global Water Treatment Additives Market to
reach USD 35.2 Billion by 2020

The key factors driving demand for water treatment additives


are the demand for clean water, rapid industrialization,
environment, government policies and increasing population.
The market has been segmented into the type of additives
being used which include scale inhibitors, corrosion inhibitors,
Figure 1: Water Treatment Additive Market Share by Geography, 2014 (%) (Source: Industry
oxygen scavengers, Defoamer, biocides, organic polymer ARC Analysis)
and others.
Market Overview, Market Landscape, Market Forces, Strategic
The organic polymers segment accounted for a market share of Analysis, etc are some of the points the report covers from
around 26 per cent in the global revenue and 25 per cent in the the additive market. It also covers the additive market by type
global volume as of 2014. Scale inhibitors have an equal revenue of water treatment, by type of additives, by application and
share as organic polymers but the volume share is slightly by geography.
higher at around 29 per cent. With increasing water scarcity and
government regulations upon safe water usage, the requirement
Water treatment additives are used to treat drinking
of water treatment additives has been increasing. The investment
opportunities in developing countries tend to increase in future and water, industrial water and wastewater and also
there is scope for new entrants in the market. public utility waste water. The key factors that led to
increasing demand for water treatment additives are
The Water Treatment Additives Market in 2015 was USD 26.4 the demand for clean water, rapid industrialization,
Billion according to research conducted by IndustryARC, and environment, government policies and increasing
is dominated by Asia-Pacific (APAC) with more than 35 per cent
population. The consumption of water treatment
market revenue share. Asia-Pacific is the most encouraging market
for water treatment additives owing to the increasing demand from additives depends on source of water and the quality
countries such as China and India, and is estimated to reach 38 per of water depends on hardness, pH and alkalinity.
cent of the global market by 2020. China, among all the countries is Organic polymers and biocides are the major additives
the most promising market with rising demand for water treatment that are used in water treatment processes. Organic
sector due to severe water shortages resulting from large population polymers are used to purify low quality water either for
and water pollution caused by rapid economic growth. The global
drinking or industrial purposes. Oxygen scavengers
market revenue is estimated to reach USD 35.2 Billion by 2020 with
a CAGR of 5.9 per cent during the forecast period 2015-2020.
are formulated to combat the effects of oxygen related
corrosion in industrial boiler systems to reduce
Water treatment is the process of removal of existing water maintenance costs, maintain boiler efficiency and
contaminants from water that becomes fit for its desired end-use equipment life. The efficacy of the water treatment
such as drinking, industry or medicinal purposes. Usage of water additives depends on dosage rate and duration of the
treatment additives is necessary to achieve an optimized process.
additives presence in water.
They have a wide range of applications in pulp and paper industry,
power industry, Oil and Gas industry, food and beverage industry,
water industry, wastewater industry, electronics, chemicals
Source: Industry ARC
and others.
48 February 2016 Chemical Engineering World
Market Insights CEW

Producing Bio-Rubber with Bio-Butadiene


from Sugars

V
ersalis (Eni), a European producer in the polymers
Global Synthetic & Bio-based Butadiene Market is Likely to
and elastomers industry, and Genomatica, a leader in
Reach USD 23.45 Billion in 2023
bioengineering solutions have successfully advanced to pilot-
scale production of bio-butadiene (bio-BDE) from fully renewable Last year, a report by Transparency Market Research has suggested
feedstock. Versalis used this bio-BDE to make bio-rubber, that the Global Synthetic & Bio-based Butadiene market is anticipated
specifically, bio-polybutadiene (bio-BR). These accomplishments to reach US$ 23.45 Billion by 2023, expanding at a CAGR of 4.9
represent a remarkable milestone for the rubber industry, by per cent between 2015 and 2023. Butadiene is one of the major
enabling an improved technological and sustainability footprint; and petrochemical and holds significant importance in end-user industries
to the broader industry for butadiene, one of the most widely-used such as automotive and tire. High demand from tire and automotive
industries is driving demand for synthetic & bio-based butadiene
chemicals in the world, with over ten million tons produced per year.
during the last few years. Butadiene derivatives such as SB rubber,
ABS, and butadiene rubber are used in the processing of tires and
The success of this innovative undertaking results from a newly-
automotive parts. SB rubber products such as S-SBR and E-SBR are
developed process for the on-purpose production of butadiene
primarily consumed raw materials in the production of tires. These
which uses various types of sugars as feedstock, rather than the
materials provide low rolling resistance and better grip, thus resulting
traditional use of hydrocarbon feedstocks. The project started with
in reduced CO2 emissions and improved fuel economy. Rise in demand
the establishment of a technology joint venture between Versalis for ABS in Asia Pacific, especially in China and Southeast Asia, is
and Genomatica in early 2013. The joint venture with Versalis another key factor propelling growth of the market for synthetic &
having the majority stake has developed a complete process to bio-based butadiene.
make bio-BDE and plans to license the resulting technology. The
joint venture uses the proven and complementary strengths of both Furthermore, development of innovative technological processes for
companies. Versalis and Genomatica together determined that the production of bio-based butadiene is likely to fuel the butadiene
1,3-butanediol (1,3-BDO) was the most suitable intermediate to market in the near future. However, volatility in raw material prices
produce bio-BDE. coupled with stringent environmental regulations are expected to hinder
the market growth during the forecast period. Synthetic butadiene was
Genomatica applied its whole-process systems approach to the largest product segment, accounting for a significant share of the
bioengineering to develop a microorganism that produces 1,3-BDO global synthetic & bio-based butadiene market in 2014. Synthetic
in a way that enables cost-efficient, scalable fermentation, recovery butadiene is produced from a mixture of C4 feedstock and is further
and subsequent process operations. Versalis leverages its industrial processed to obtain derivatives such as ABS, SB rubber, and SB latex.
process engineering and catalysis capabilities, plus expertise in These derivatives are employed in tire and automotive industries.
overall polymer production, to purify the 1,3-BDO, dehydrate it and
then purify the resulting butadiene. Versalis has produced several Bio-based butadiene is likely to be the fastest-growing product
kilograms of butadiene from 1,3-BDO made in 200 litre fermenters segment of the synthetic & bio-based butadiene market in the next
at their research centres at Novara and Mantova, and then made few years. Stringent regulations are primarily boosting growth of the
bio-polybutadiene, at the Ravenna R&D centre, using both anionic bio-based butadiene market. Alignment towards eco-friendly and cost-
and Ziegler-Natta catalysis. Initial testing of the bio-BDE and bio-BR competitive production is estimated to drive the market growth during
demonstrates good compatibility with industry standards. Versalis is the forecast period. In terms of demand, butadiene rubber has been
continuing to test the bio-BDE within its other proprietary rubber and dominating the synthetic & bio-based butadiene market in the past
plastics downstream technologies such as SBR (Styrene-Butadiene years. Butadiene rubber is primarily used in tire production; however,
Rubber), SBS (Styrene-Butadiene-Styrene Rubber) and ABS it is also used as an additive in plastics such as polystyrene and ABS.
SB rubber accounted for the second-largest share of the synthetic &
(Acrylonitrile Butadiene-Styrene). The accomplishments demonstrate
bio-based butadiene market in 2014. SB rubber is a synthetic rubber
the common vision of the partners on the potential of this project:
obtained through copolymerization of butadiene and styrene and is
access to on-purpose butadiene from renewables will establish a
used in the production of tire and its products. ABS and adiponitrile
competitive advantage and will ensure a strategic raw material from
are considered to be among the fastest-growing application segments
alternative feedstock, contributing at the same time to drive a greater
of the synthetic & bio-based butadiene market. A similar trend is
sustainability profile for downstream applications in the plastics and
anticipated to continue during the forecast period.
rubber businesses.
Chemical Engineering World February 2016 49
Marketing Initiative

Customized solutions-High Vacuum LRVP

T
he Toshniwal HIGH VACUUM LRVP Shut off vacuum less than 5 mbar with
is utilized primarily in production of Roots vacuum pump
fine chemicals, pharmaceuticals wet Oil free vacuum pump
process like distillation, drying, evaporation Can work under corrosive media upto
and reaction under vacuum. Depending on 3.5 pH
process condition, it can be operated with Wide range of sealing medium like
once-through/ closed loop circulation for water ,oil and solvent etc
service fluid. In the closed loop circulation Environmentally safe
system allows to re-use the condensate
which are recovered from suction gas without Roots Pump: It is provided with inbuilt
external contamination. bypass (Over flow) valve suitable for
high pressure operation. The benefits
STANDARD CONFIGURATION are Roots / Booster pump can be started
The standard Toshniwal HIGH VACUUM at the same time as the backing pump,
LRVP system composed of Liquid ring and Roots / Booster is protected from
pump with closed loop circulation system overloads resulting from inadvertent
for service liquid, a special spiral coil heat operation at high pressure.
exchanger mounted vertically for vapor / poor degassing, and process interruption
liquid separation and a collection tank. A Gas Ejector: The suction pressure
The solution is Hybr id LRVP since it
special post condenser with clean condensate range of liquid ring pump will be further
can provide required high vacuum under
recovery tank provided. Also included are reduced by pre connected gas ejector.
polluted process situation.
all connecting pipe / flanges and control T h e c o n t i n u o u s i n f l o w o f m o t i ve -
instruments including thermometer, vacuum gas prevents liquid ring pump from
Product Distillation: Oil Ring Pumps
gauge are mounted on a single steel operating cavitations range The motive
generally are used in wet process pumps
fluid of gas ejector is part of the gas
structure base. to handle vapours along with air load which
exhausted by the Liquid Ring Pump.
leads to oil contamination drop in vacuum,
The combination of Double stage LRVP, Gas frequent replacement of consumables etc
Waste Oil Purification: The criticality
ejector, roots pump can obtain oil-free low to get required lower operating pressure
of the application is to handling sticky
residual pressure and each component is (example 10 mbar).In order to provide
material emanating during recuperation.
optimally designed with correct staging ratio required high vacuum under polluted
All kind of vacuum systems including
for perfect fit. process situation, Toshniwal Hydrid LRVP
dry pump fails for these application, but
is the best solution.
Hybrid LRVP with sealant as purified oil is
Variport Liquid Ring Pump- Pompetravaini
the solution, the oil as sealant in regular
Italy- Hydro pack compact Vacuum packages-
interval being replaced by fresh oil.
ensure full recovery of service liquid - No
contamination of central cooling water-
Toothpaste Degassing: Tooth paste has
variported vacuum pump can work entire
to be degassed to remove entrapped gas
pressure range 1013 mbar - 33 mbar unlike content before packing.
conventional double stage vacuum pump
Authors Details
which has limitation in working pressure range Since suction of air has to be done in
Variport offer minimal water consumption and p r e s e n c e o f h i g h d e n s e wa t e r va p o r Toshniwal Instruments
an innovative impeller design that assure ,evacuation need to be handled by Liquid (Madras) Pvt Ltd
extremely quite operation and extending its ring pump during initial phase and Double 267, Kilpauk Garden Road
life even under harsh condition stage vacuum pump during final phase. Chennai - 600010
Contact: +91 44 26445626, 26448983
Shut off vacuum less than 10 mbar with Tooth paste mist entering into vacuum E: sales@toshnwial.net
air ejector system, and oil contamination resulted in W: www.toshniwal.net

50 February 2016 Chemical Engineering World


Marketing Initiative

Electromech Engineering Enterprises


(Third Party Inspection Agency)

W
e are in the field of Third Preparing of bar chart after discussing mention below. Several types of equipment
Party Inspection and with the vendor and the client are frequently inspected by us at various
t e c h n i c a l m a n p owe r s u p p l i e r Material identification based on Mill / vendor locations and our team is well
for constr uction super vision and site manufacturing certificate or testing at conversant with it. These equipment are
inspection, since 1990. Our customers laboratories Blower, Centrifuges, Pumps, Glass lined
include reputed companies like Gujarat Stamp transfer on all pressure & non reactor, FRP Tanks, Sparkler filters, Tray
State Fertilizer Limited, Hindustan Organic pressure parts (parts coming in contact dryer, PP & PVDF lined fittings, Conveyor,
Chemicals Ltd, Nocil India Limited, Larsen with process fluid) ANFD, FBD, Nauta mixer, Double cone
& Toubro Ltd, Asian Paints (India) Ltd, dryer(RCVD), Blender, Co-mill, Pipe &
Approval of welding procedure
Rallis India Ltd, Godrej Industries Limited, Tube inspection, Pipe fittings, Explosion
specification & welders qualification
Perrigo API India Limited, Voltas Limited,
test cladded plate etc.
etc. We have ongoing projects with the
Witness of all physical tests at various
SRF Limited, Dr Reddys Laboratories
NABL approved testing laboratories
Ltd, Glenmark Generics Limited, Shasun
Phar maceuticals Limited, Cheminova All set up of long seams & circ-seams,
India Limited, Apcotex Industries Limited, nozzles set up, Manhole hand hole &
Syngenta India Ltd, Nitrex Chemicals India pads set up
Ltd, Orchid Chemicals & Pharmaceuticals C h i p - b a ck D P Te s t a f t e r o n e s i d e
Ltd, and Emcure Pharmaceuticals Ltd, to welding
name a few. Review of Radiography films & witness
of Ultrasonic test & Liquid Penetrant
We follow ASME, TEMA & API codes test as per requirement
for Pressure Vessels, Heat Exchangers, Tube sheet inspection of drilled holes,
Storage Tanks, Valves, and Pumps etc. We ligaments, grooves and layout
can support you with engineers who are Mock up test of tube sheet to tube
trained in NDT methods like Ultrasonic, joint for pullout load test & detecting
Liquid Penetrant Test and Radiography minimum leak path
with Level II certification. Air running trial with dummy support
for checking alignment, assembly of
We a l s o p r o v i d e fo l l o w - u p s e r v i c e s
agitators and to assure the Vibration,
right from Drawing stage till completion,
Noise level within acceptable limits
involving material identification, stage
Hydraulic test at specified pressures
fabr ication, visiting sub vendors and
Pneumatic test of mechanical seal at
a s s i s t a n c e w i t h m o n t h l y ex p e d i t i n g
working pressure
reports, vendors reports and inspection
reports. We would be pleased to associate R u n n i n g t r i a l i n s i d e t h e ve s s e l a t
with you as our esteemed client. We hope working pressure
Contact Details
you give us an appointment at a mutually Final dimensions and visual inspection
convenient time, so that we can discuss Final inspection after pickling and
Mr Jayant Joshi
the above mentioned services at length. passivation of Stainless steel and
B- 102, Shubh Sarita, Appasaheb Sidhaye
painting of carbon steel parts
Marg, Shri Krishna Nagar, Borivali (E),
SCOPE OF WORK Packing & supporting of agitator shaft PIN: 400066
Stages of Inspection for Reaction Vessel inside the vessel & dispatch instruction. T: +91 22 2897 5275
Heat Exchanger / Pressure Vessel. Submission of final documents M: +91 98199 82801, +91 91676 62735
Approval of detailed fabr ication E: info@electromechengineering.com,
drawings submitted by the vendor after We have experienced engineers to carry E: divya@electromechengineering.com
detailed discussion with the client out inspection of specialized equipment as W: www.electromechengineering.com

Chemical Engineering World February 2016 51


Marketing Initiative

A Revolutionary Vacuum Drying Philosophy


Planex System : A multi-patented paddle dryer with ZeroFriction planetary movement eccentric agitator.

I
talvacuum, one of the most known mixing. This approach is par ticular ly Planex System is safe for operators, the
manufacturers of vacuum dryers and effective when processing small batches. environment and the product, because it is
va c u u m p u m p s fo r t h e p r o d u c t i o n designed and manufactured in compliance
processes of chemical, pharmaceutical Moreover Planex System , thanks to with European Union ATEX Directives
and cosmetics industries, has recently its agitators ZeroFr iction planetar y and CE marking requirements, as well
introduced on the market an innovative movement, prevents the product from as with the increasingly stringent US
h o r i zo n t a l p a d d l e d r ye r. I t i s P l a n ex being rubbed against the drying chamber FDA standards and cGMP Current Good
S y s t e m , a m u l t i - p a t e n t e d m a c h i n e walls and thus heating up due to friction, Manufacturing Practice Regulations.
which is conquering the most demanding a typical problem in conventional paddle
operators from all around the world, by systems. In addition, the rotation of the Manufacturing Materials
guaranteeing results that were unthinkable paddles tangentially to the chamber All the parts of Planex System that come
till now with conventional systems, both w a l l s , c o nvey s t h e p r o d u c t i n t o t h e into contact with the product are made
horizontal and vertical. small clearance between the agitator of AISI 316L stainless steel, but other
and the chamber surface, preventing weldable materials such as Alloy C-22
Designed to dry wet feed from filtration and lumps for mation and guaranteeing and AISI 904L are available on request.
centrifuging processes Planex System an even more effective dr ying and a The drying chamber walls, the agitator
i s i d e a l fo r t h e p r o d u c t i o n o f a c t i ve controlled final particle size distribution, shaft and the access hatch are heated
pharmaceutical ingredients (API), fine w h i c h i s i m p o s s i bl e t o a c h i eve w i t h by diathermal fluid circulation to prevent
chemicals and intermediates. conventional dryers. c o l d s p o t s t h a t c o u l d c a u s e s o l ve n t
condensation or product buildup. Internal
The major added-value of Planex The minimum clearance between agitator surfaces of the drying chamber are lapped
System is the eccentric agitator with profile and chamber walls not only prevents or electropolished to optimize corrosion
two independent movements that can p r o d u c t bu i l d u p s, bu t i t a l s o m a ke s resistance, reduce adhesion and friction
simultaneously revolve around its own discharge significantly easier. In addition, on the product, improve powder flow
axis and rotate tangentially to the there is a specific automatic program behavior and facilitate cleaning operations.
drying chamber. fo r t h e d i s c h a r g e o p e r a t i o n s. T h e s e The shaft of the agitator is complete with
operations are even more effective thanks a double mechanical seal system, studied
The combined rotations of the agitator to the pendulum movement of the agitator to guarantee the perfect vacuum tightness
and its small size compared to the drying (the agitator pendulum movement), which and the absolute purity of the dried batch,
chamber diameter, ensures the perfect swings by 90 degrees in the discharge avoiding any risk of contamination of the
mixing of the entire batch, and allows area. As a result, the amount of product product. The mechanical seal may be of
consuming at least three times less energy left in the Planex System chamber after conventional type with wet flushing or run
than conventional dryers with a concentric discharge is truly minimal, averaging less dry with nitrogen immission.
agitators. This means a threefold reduction than 1 per cent of the volume.
in mechanical and thermal stresses on the Cleaning
batch being dried . As a result, even the Planex System also features outstanding Planex System is designed and developed
most delicate and temperature-sensitive loading flexibility. The system is available to make cleaning operations outstandingly
products are treated with maximum care. with total volumes ranging from 150 to fast and effective. This is an important
3,200 liters. Maximum loading capacity consideration for any machine, and one
But there is more. The Planex System depends on the product to be processed, that is absolutely essential for a dryer
control software allows to automatically and can vary from 15 to 80 per cent of the that customers from all around the world
command the agitator movements with chamber volume. The system can meet all have selected for its versatility and ability
the Stop & Swing program. In this way, the production needs of the pharmaceutical to be used in multi-product assets. Ease
the agitator swings back and forth, thus and chemical industries, as it is capable of cleaning, in fact, means that all the
remaining all the time immersed in the of processing small amounts of product as operations involved in washing the interior
product, and guaranteeing its continuous well as large batches. of the dryer, removing the internal parts,

52 February 2016 Chemical Engineering World


Marketing Initiative

insp ecting the u nit an d clea ning t he can be pressurized and kept separate from c. no build up
exterior are simple and straightforward. the technical area d. guaranteed final particle size
4. Ideal for processing also small batches,
Inter nal washing: The fully accessible Pilot Trials thanks to the automatic Stop & Swing
chamber interior, with no hard-to-reach In its factory Italvacuum has a range of program
zones or areas that could trap product pilot systems which allow to carry out 5. Easy total discharge thanks to:
residues, ensures that the entire dryer can semi-industr ial scale dr ying tests on a. minimum clearance between agitator
be perfectly cleaned. To make the washing customers products. During pilot trials, paddles and fully machined dr ying
operation even more effective, the dryer product samples can be taken for analysis chamber walls
is equipped with an efficient C.I.P. system without breaking the vacuum and the b. special automatic program
with retractable rotating washing head. process parameters can be modified at 6. Fa s t e r d r y i n g t i m e s t h a n k s t o t h e
Equipping Planex System with the C.I.P. any time in order to reach the ideal drying combined rotations of the agitator,
washing unit not only guarantees perfect process. In this way customers can choose which increases the product surface
cleaning, it also provides significant the Italvacuum system that best meets exposed to evaporation
savings: the agitators off-centered position their needs. 7. Very high final vacuum levels
enables it to rotate during washing, thus 8. Easy cleaning of interior and exterior,
reducing the amount of liquid needed. Turnkey Systems with practical access for inspection and
In addition to the dr yer, Italvacuum is swab testing
Inter nal par ts removal: Thanks to its the only manufacturer in the world that 9. Simple agitator paddles dismantling
special structure, the agitator can be can design and produce internally all the and removal, without long machine
readily disassembled into removable auxiliary units vacuum system included downtimes
sectors, thus making cleaning operations ensuring that they are sized to meet any 10.Full system automation guarantees
even more effective. This is an exclusive processing requirements: batch-to-batch process
feature that makes Planex System a one- Saurus939 high vacuum pump
of-a-kind dryer: in conventional systems, Vacuum condensation unit for drying
the agitator is made of a single structure time reduction and extracted solvent
and removing it requires the use of bulky recovery
equipment and long system downtimes. Exter nal cyclone filter, designed in
order to prevent pressure drop and
Internal inspection: The big front-opening condensation, for full vacuum line
hatch provides full access to the entire protection
drying chamber. Other advantages include H e a t i n g / c o o l i n g u n i t s fo r s y s t e m
the agitators off-centered position. This temperature regulation
allows the operator to have more room to PLC control system with CFR 21
work, making it even faster and easier to Par t 11 cer tified software, able to
carry out swab testing. guarantee reproducible dried batches
and interface with centralized control
External cleaning: The exterior of Planex systems.
System is also easy to clean. The entire
machine is housed in a sealed external Strengths
casing (cGMP particle-free configuration) 1. Energy consumption three times lower
which encloses the insulation and all than in conventional dryers
electrical, hydraulic and pneumatic circuits. 2. Threefold reduction in mechanical
In addition, no support to the machine and thermal stresses, to the benefit of
is present in the clean room, as the product purity
dr ying chamber is flange-mounted on 3. Eccentric agitator with ZeroFriction
the wall. In this way the chamber exterior planetary movement:
can be cleaned quickly and effectively, a. n o l o c a l i z e d f r i c t i o n o n t h e
avoiding product accumulations in slots or product
junctions. These features, combined with b. p o s s i b i l i t y t o p r o c e s s v e r y
the partitioning approach, permit clean delicate temperature-sensitive
room installation, so that the clean area products

Chemical Engineering World February 2016 53


CEW Products

NIR Moisture Sensor and Analyser Rack Monitor


Toshniwal mixer is a new generation OPW Engineered Systems offers
powder mixing equipment that helps RM140W rack monitor to its complete
to meet the customers modern times line of terminal solution offerings. Built
demand such as reduced source for truck or rail loading in petro-chemical
and achieve excellency in quality applications, the RM140W protects
improvement; low power consumption against overfills and continuously
- higher yield and short time operation monitors the grounding connection,
with reduced maintenance cost. increasing safety at the point of transfer.

These mixers are suited to handle solids, powders, flaky In addition to being universally compatible, the RM140W
materials, etc. It is widely used in food, animal feed, meets or exceeds the requirements of multiple organizations
construction, chemical, refractory industry, etc. Apart as an explosion-proof device. This perfectly aligns with OPW
from hematogenous mixing, it also helps in achieving the Engineered Systems belief of fostering a safe and productive
desired technical performance in the final product and its work environment. The RM140W rack monitor replaces the
subsequent application. Opti-Therm 8500 Series.

For details contact: For details contact:


Toshniwal Dover India Pvt Ltd PSG
267 Kilpauk Garden Road, Chennai 600 010 40 Poonamallee By-pass, Senneerkuppam
Tel: 044-26448983, 26448558 Chennai 600 056
Fax: 91-044-26441820 Tel: 044-26271020, 25271023
E-mail: sales@toshniwal.net E-mail: sales.psgindia@psgdover.com
or Circle Readers Service Card 1 or Circle Readers Service Card 2

Structural Analysis and Design


New version provides an organized, simple approach to structural analysis and design. Intergraph Process, Power & Marine (PP&M),
part of Hexagon offers Intergraph GT STRUDL 2016, the most advanced tool for structural engineers to quickly analyze designs
and deliver the most accurate structural analysis to build safe and cost-effective structures. GT STRUDL 2016 increases business
productivity, eliminates design errors and provides safe, dependable analytical results on which firms can stake their reputation.
GT STRUDL 2016 provides more efficient user experience with better organization of the structural engineers desktop into docked
dialogs and tabbed workspaces; creates more efficient workflow by decreasing the number of steps needed to execute a function
compared to the previous GT STRUDL version; allows for faster 3D modeling in an AutoCAD-based modeler with an increased display
speed; and expands the large library of compliance codes already within GT STRUDL so that work stays accurate, even in the face
of new rulings and editions.

Intergraph CADWorx & Analysis Solutions offerings allow design and engineering to share relevant information seamlessly, thereby
maintaining accuracy and improving efficiency. These include CADWorx Plant Design Suite, for AutoCAD-based intelligent plant
design modeling, process schematics and automatic production of plant design deliverables; CADWorx DraftPro, a free solution
for intelligent 2D design and layout; CAESAR II, the worlds most widely used pipe stress analysis software; PV Elite, for vessel
and exchanger design and analysis; TANK, for the design and analysis of oil storage tanks; GT STRUDL, one of the most trusted,
adaptable and fully-integrated structural analysis solutions in the world; and Visual Vessel Design, a comprehensive pressure vessel,
shell and tube exchanger, and boiler design and analysis solution.

For details contact:


Intergraph Corp
19 Interpro road
Madison, AL 35758, U.S.A
E-mail: jerry.felts@intergraph.com
or Circle Readers Service Card 3

54 February 2016 Chemical Engineering World


Products CEW

AdvanceBio Columns Improve Laboratory Workflows


Agilent Technologies Incs new technology is designed to help
scientists achieve the reproducible results they need to develop
effective biopharmaceuticals. The new line of AdvanceBio SEC
columns represent a significant advance in size-exclusion
chromatography, a key technology used to quantify aggregation
in biotherapeutics such as monoclonal antibodies. Quantifying
aggregation is a vital factor in developing and producing safe,
effective biologics. AdvanceBio SEC columns deliver higher resolution for more accurate
quantitation as well as higher sensitivity to quantitate aggregates, even at low levels.

AdvanceBio SEC columns deliver reproducible resultscolumn to column, batch to batch and
lab to lab. Agilents new silica particle provides the resolution and stability to run shorter columns
at higher flow rates, giving laboratories the right result in a quarter of the time. This product
line will enable laboratories to control costs by eliminating sample rework, simplifying method
transfers and improving lab productivity.

For details contact:


Agilent Technologies India Pvt Ltd
CP-11 Sector 8, Technology Park, IMT Manesar, Haryana 122 051
Tel: 0124-4863000
E-mail: cag_india@agilent.com
or Circle Readers Service Card 4

Natural Gas-Operated Double-Diaphragm Pumps


Wilden, part of PSG, offers a new line of CSA-certified
natural gas-operated double-diaphragm pumps. These new
pumps have been certified by CSA International to be used
in applications where natural gas is the energy source to
drive the pump. Ideal for upstream and midstream oil and
gas applications, Wilden CSA-certified natural gas-operated
pumps are available in Wilden Original (clamped), Advanced
(bolted) and Advanced FIT Models, and come equipped with either the patent-pending
Wilden Pro-Flo SHIFT Air Distribution System (ADS), which is CSA-certified ANSI LC
6-2008, or the Wilden Pro-Flo X ADS, which is CSA-certified for the ANSI LC 6-2008
and TIL R-14. Wilden CSA-certified pumps are offered in 13 mm (1/2) clamped and
25 mm (1), 38 mm (1-1/2), 51 mm (2) and 76 mm (3) bolted configurations. Wilden
CSA-certified pumps also comply with all CE and ATEX requirements, and feature
extreme shear sensitivity, high-viscosity handling, dry-run capability, superior anti-
freezing and no deadhead damage. The max flow rate is 993 lpm (246 gpm) for the 76
mm (3) Model, and the max discharge pressure is 6.9 bar (100 psig) for all Models.
Wetted paths are aluminum or SS, and available diaphragm materials are Buna-N,
PTFE or Wil-Flex.

For details contact:


Dover India Pvt Ltd PSG
40 Poonamallee By-pass, Senneerkuppam, Chennai 600 056
Tel: 044-26271020, 25271023
E-mail: sales.psgindia@psgdover.com
or Circle Readers Service Card 5

Chemical Engineering World February 2016 55


CEW Products

Screw Pumps
Blackmer offers S Series screw pumps with or without external timing gears and bearings, are self-priming
double-ended positive displacement pumps. Blackmers twin and triple screw designs provide complete
axial balancing of the rotating screws and their timing technologies eliminate metal-to-metal contact with
the pump. S Series pumps are ATEX-certified for use in explosive or dangerous environments, and have
been designed to address the difficult pumping challenges found in the oil and gas, process and marine
industries. S Series pumps provide solutions that can meet the toughest application challenges regardless
of temperature, viscosity or pressure.

S Series pumps are offered in four distinct lines, each having multiple model configurations and sizes: S Series twin screw pumps
(WTG) are double-suction, self-priming twin screw pumps with external bearings and timing gear transmissions. They are suited for
the delivery of fluids free of solid substances and/or with little abrasives. S Series twin screw pumps with non-timing gear (NTG)
transmission feature a single-suction design for transferring lubricating fluids with higher viscosities, such as bitumen and residual
oil, at medium or high temperatures. S Series multi-phase twin screw pumps have been designed for medium- to low-pressure
applications and built to last within the water and oil and gas industries. Multi-phase pumps are commonly used in the oilfields that
have untreated streams and are ideal for higher differential and suction pressure applications. S Series triple screw pumps are
designed for handling clear, lubricating liquids without solid content in the most demanding applications.

For details contact:


Dover India Pvt Ltd PSG
40 Poonamallee By-pass, Senneerkuppam, Chennai 600 056
Tel: 044-26271020, 25271023
E-mail: sales.psgindia@psgdover.com
or Circle Readers Service Card 6

LPG Natural Gas Regulators


Mesura of France, a leading manufacturer of gas regulators, systems and services for regulating and measuring
of natural gas, and Nirmal Industrial Controls Pvt Ltd, Indias leader in the field of high pressure regulators,
slam shut valves and gas conditioning, pressure regulating and metering stations set up JV, Mesura Nirmal Gas
Controls Pvt Ltd, offers highly accurate, ruggedly constructed, attractively priced and ex-stock delivery of LPG
and natural gas regulators. Safety shut-off devices can be supplied in a gas train.

Regulators are well-protected against corrosion with consistent powder coating. It has extreme temperature-resistant
diaphragms, SS screws and bolts, and 1/4 connections for inlet pressure gauge of 1 to 17 Bar/outlet pressure gauge of 0.5 to 4 Bar,
100 Nm 3/hr of LPG flow, and 1 x 1 NPTF end-connection. It is also suitable for liquid LPG. Flows tested in accordance with UL144.
The Cavagna Groups top-line of LPG regulators for residential, commercial and industrial use is also offered by the JV.

It is the 1 st stage regulator for residential gas banks. Suitable for commercial use in hotels, malls, hospitals, IT parks, educational
institutes and ideal for use in industrial LOT/VOT for LPG bulk installation and bullets. It finds application in hot air generators,
furnaces, gas engines, burners and boilers, painting, powder coating, glass and ceramic, food, agriculture, automobile and foundry
industry.

For details contact:


Mesura Nirmal Gas Controls Pvt Ltd
Plot No: 39-40, Savli GIDC, Alindra
Vadodara, Gujarat 391 775
E-mail:tawde@nirmalindustries.com
vrushank.shukla@mesuranirmal.com
or Circle Readers Service Card 7

56 February 2016 Chemical Engineering World


Products CEW

Energy-efficient Heat Transfer Solutions


HRS Process Systems Ltd (HRS PSL), part of HRS Group, UK,
offers wide range of innovative and energy efficient heat transfer
solutions widely used in process industries like chemicals,
pharmaceuticals, petrochemicals and many more.

Ecoflux corrugated tube heat exchangers (CTHE), HRS flagship


product is based on corrugated tube technology developed by
HRS for a range of processes like heating, cooling, condensation, chilling for various
products, utility, steam, oil, water and other heat transfer applications. HRS Funke plate
heat exchangers (PHE) are used for processes like water cooling, oxygen cooling and
heat recovery. These heat exchangers have also proven to give enhanced benefits in
terms of performance efficiency when integrated into heat exchanger based systems.
These systems (HES) are skids which ensure optimum utilization of energy with controlled
heating and cooling which avoids wastage in process, thus making it much more
environmentally efficient.

For details contact:


HRS Process Systems Ltd
201/202 Karan Selene, 851 Bhandarkar Institute Road
Pune, Maharashtra 411 004
Tel: 020-25663581, 66047894
E-mail: info@hrsasia.co.in
or Circle Readers Service Card 8

Scrapper Mechanism Filters


Scrapper mechanism self-cleaning filters are widely used for continuous
filtration requirement without any replacement of filter consumables
and without exposure of operators. Scrapper mechanism self-cleaning
filter is used wherein one cannot introduce any additional substance for
back washing.

Because of automatic continuous on-line filtration, the filtration process


becomes smooth. The gear motor runs against the spring actuated scraper
and the concentrated solids are drained off by the system, thereby keeping
the function of the cartridge well. PLC control function means differential pressure cleaning,
scheduling of cleaning process and manual cleaning. The differential-pressure is an important
parameter for operation and can be connected with the central control room. Validated by
practice, this filtration process is highly effective and using the wedge cartridge, it can be
easily cleaned with less abrasion. In many fields, this filter can replace the traditional filters
like sand filters, filter press, etc.

For details contact:


Filter Concept Pvt Ltd
302 Aalin, B/h Jet Airways Office, Ashram Road
Ahmedabad, Gujarat 380 014
Tel: 079-27541602 | Fax: 91-079-27540801
E-mail: info@filter-concept.com
or Circle Readers Service Card 9

Chemical Engineering World February 2016 57


CEW Products

High-specification Process O2 Analyser Flow Control Valves


The SERVOTOUGH OxyExact Cipriani Harrisons flow control valves made
high specification oxygen analyser from forged SS-316L, are highly polished
offers an unrivalled combination of and come standard with FDA EPDM seats
precision, flexibility and performance and seals. These valves have self-draining
for optimum process and safety machined bodies with a round shape that
control. The OxyExact can be allows for minimum resistance to flow.
configured with a safe or hazardous area control unit with The valve body, yoke and actuator are
up to six transmitters. Zone 1 Certified to ATEX Cat 2, IECEx assembled with clamps enabling quick and easy assembly and
and FM.CSA Class 1 Div 1. Three enclosure systems allow disassembly. Available in sizes 1-2.5 with sanitary clamp and
sampling of any flammable gas up to 100 per cent O 2 and butt-weld end connections as standard. The valve is operated
pressures of up to 40 psi. by means of a manual handle which moves a conical plug
gradually up or down. The plug has a calibrated profile that
High temperature version eliminates the need to condense allows for fine flow control. The plug can be fixed in the desired
hot sample prior to analysis. portion with locking arrangement.

For details contact: For details contact:


Spectris Technologies Pvt Ltd Cipriani Harrison Valves Pvt Ltd
Plot No: A-168 MIDC 1901, GIDC, Phase IV, Vallabh Vidyanagar
Thane-Belapur Road Vitthal Udyognagar, Gujarat 388 121
Khairnae, Navi Mumbai 400 710 Tel: 02692-235082, 23512
Tel: 022-39342700 Fax: 91-02692-236385
E-mail: MEI_Sales@servomex.com E-mail: info@harisonengineers.com
or Circle Readers Service Card 10 or Circle Readers Service Card 11

Temperature Control Systems for Labs & Industrial Applications


JULABOs new PRESTO Models W50 and W50t provide a high dynamic temperature control system that can handle
temperature ranges of -50 0C to +250 0C for applications such as reactors, mini-plants, pilot plants, material testing
stands, micro-reactors, and material and component tests in the auto industry, for example. The new water-cooled
PRESTO Models are available in two versions: the W50 and the W50t with increased heating capacity. The PRESTO
W50 provides a heating capacity of 6-kW, while the W50t provides 12-kW. Both have a cooling capacity of up to 7.5-
kW. They are suited for compensating exothermic and endothermic reactions extremely quickly and have impressive,
very rapid heat-up and cool-down times.

High-performance pumps deliver up to 3.2 bar or 76 l/min. Both Models guarantee high flow rates at constant pressure and can
interactively compensate changes in the viscosity of the tempering medium. The integrated 5.7 industrial colour touchscreen
provides high functionality and intuitive user guidance. Extensive interfaces allow flexible usage, such as control and regulation
via USB interface, data logging via USB or SD Card, integration in process bus solutions (ie, Profibus), remote control via Ethernet
networks or wireless control through JULABOs WirelessTEMP application. Competent advising, a collaborative search process
for suitable solutions with the customer and many other customer services ensure that JULABO users find the ideal temperature
control solution.

For details contact:


JULABO GmbH
Eisenbahnstr 45, Seelbach
Baden Wrttemberg 77960 Deutschland, Germany
Tel: +49 (7823) 51-21 | Fax: +49 (7823) 2491
E-mail: m.ketterer@julabo.de
or Circle Readers Service Card 12

58 February 2016 Chemical Engineering World


Oil & Gas World Expo 2016 ChemCon Europe 2016
Concurrent Events: SMP World Expo, Dates: 14 18 March 2016
EnerTECH World Expo Venue: Amsterdam, Netherlands
Details: Technical or commercial services
Dates: 3 5 March 2016
linked with the chemical industry.
Venue: BC&EC Mumbai, India Organiser: ARC Advisory Group
Details: Platform to showcase services, Contact: +31(0)88 348 88 88
technologies, innovations and current Email: office@chemcon.net
& future trends of entire value chain of Website: www.chemcon.net
hydrocarbon industry.
Contact: +91 22 40373636
Email: sales@jasubhai.com
Website: www.chemtech-online.com

India Chem 2016 Best Practices for Chemicals

Dates: 1 3 September, 2016 Dates: 14 16 March 2016


Venue: Bombay Exhibition Centre, Mumbai Venue: Texas, USA
Details: Event of chemicals and Details: The premier industry conference
petrochemicals industry in India in its 9th for organizations using SAP.
edition Organisers: SAP, The Eventful Group and
Organiser: FICCI ASUG
Contact: +91 22 2496 8000 Contact: +1 877 411 4675
Email: vishal.ganju@ficci.com Email: sarah.carr@theeventfulgroup.com
Website: www.indiachem.com Website: www.sapforindustries.com

Chemspec 2016 ORPEC 2017


Dates: 7 8 April, 2016 Dates: 13 15 May 2017
Venue: Bombay Exhibition Centre, Venue: Muscat, Oman
Mumbai Details: Designed to deliver key buyers to
Details: Meeting and networking with Omans growing refining and petrochemical
existing and potential partners and industries creating a forum aligned with the
business facilitators governments growth plans
Organiser: Quartz Businesss Media Ltd, Organiser: OMANEXPO LLC
Contact: +91 22 240 44472 Contact: Mr Ebrahim Taher
Email: rohit@chemicalweekly.com Email: info@omanexpo.com
Website: www.chemspecevents.com Website: www.omanexpo.com

Automation 2016 The 2016 Automation Summit

Dates: 22 25 August 2016 Dates: 27 30 June, 2016


Venue: Bombay Exhibition Center, Venue: Las Vegas, USA
Mumbai Details: Siemens Automation Summit
Details: Automation 2016, a four day A User Conference. All areas of industrial
automation event is set to introduce new automation will be covered including
and upcoming technology this year factory, process, motion, and drives.
Organiser: IED Communications Ltd Organiser: Siemens Industry, Inc
Contact: 91 22 22079567 Contact: +1 800 241 4453
Email: jyothi@iedcommunications.com Email: rich.chmielewski@siemens.com
Website: www.iedcommunications.com Website: usa.siemens.com/summit

Chemical Engineering World February 2016 59


CEW Project Update

New Contracts/Expansions/Revamps

The following list is a brief insight into the latest new projects by various companies in India.

CHEMICALS has applied for Amendment in Environmental Clearance dated 26th


Panoli Intermediates (India) proposes an expansion of its specialty September 2012 for change in fuel from LDO to agro waste briquettes
chemicals manufacturing unit and a new 10-MW coal-based captive and addition of one raw material, ie, phosphoric acid and generation
power project in Unit-III, GIDC Nandesari, district: Vadodara, Gujarat. of dilute phosphoric acid (25 per cent basis) as by-product.
The estimated cost of the project is ` 100-million. The current status
of the project could not be ascertained. According to MoEF sources, Bohra Industries is implementing an expansion of its chemical and
the total plot area is 15,480-sq m. The capacity of isomers and fertilizer manufacturing unit at Umarda, district: Udaipur, Rajasthan
DNCB such as 2:4 DCNB, 2:6 DCNB, 2:5 DCNB is to be augmented on 14,500-sq m of existing land. The project will entail expansion of
from 200-TPM to 2,200-TPM, ortho anisidine/para anisidine from single super phosphate capacity from 400-TPD to 600-TPD, granulated
100-TPM to 1,100-TPM, ortho nitro aniline/para nitro aniline from super phosphate from 200-TPD to 300-TPD and addition of new
300-TPM to 2,300-TPM, isomers of DCA from 80-TPM to 1,080- products namely 150-TPD triple super phosphate, 550-TPD synthetic
TPM, isomers and DCNB such as 2:3 DCNB, 2:5 DCNB. isomers gypsum, 30-TPD Di-calcium phosphate, 160-TPD phosphoric acid,
of DCNB such as 2:3 DCNB, 2:5 DCNB, 3:4 DCNB from 200-TPM
0.3-TPD potassium fluoride, 150-TPD H2SO4 and 0.3-TPD Sodium Tri
to 2,200-TPM, H-acid from 50-TPM to 500-TPM and addition of a
Polyphosphate (STPP). Machinery has been ordered from China. Civil
new product namely, 1,500-TPM derivatives of nitro phenol and a
work is in progress. The project is scheduled for completion in 2018.
new 10-MW coal-based CPP. 10-MW power requirement is to be
met from MGVCL and 10-MW from the CPP. The effluent will be
Ami Lifesciences proposes expansion of its synthetic organic
treated in proposed effluent treatment plant.
chemicals manufacturing unit (viz, pharmaceutical bulk drugs and
drug intermediates) from 65.70-TPM to 131.60-TPM in Padra, district:
Saras Plywood Products is planning a 60-TPM urea formaldehyde
Vadodara, Gujarat.The estimated cost of the project is ` 87.046-million.
resin manufacturing plant in New GIDC Gundlav, district: Valsad,
Environmental Consultant to this project is Envisafe Environment
Gujarat. The existing land area is 1.5 acres. The estimated cost of the
project is ` 7.5-million. Kalyan Industries is the equipment supplier. Consultants. According to MoEF sources, total plot area is 23,760-sq
The project is waiting for environmental clearance. Civil work will m (existing 10,270-sq m and 13,490-sq m for expansion). The unit
commence in 3 months. The project is planned for completion in currently manufactures 2-TPM 1-Acetyl Naphthalene, 1-TPM 2-Acetyl
this year. According to SEIAA sources, the company has proposed Naphthalene, 6-TPM Itopide HCl, 1.20-TPM Loxapine Succinate, 0.30-
primary treatment plant followed by evaporator for treatment of TPM Amoxapine, 6-TPM Venlafaxine, 6-TPM Progunil HCl, 6-TPM
industrial effluent and has also proposed a multi-cyclone separator. CB-2-L-Valine, 0.60-TPM Nateglinide, 0.60-TPM Quetiapine, 24-TPM
Carbomazepin and 12-TPM Oxacarbomazepin. The expansion will
FMC India is planning an expansion of its chemical manufacturing involve addition of new products. Water requirement from ground
unit at IDA Patancheru, district: Medak, Telangana. The estimated water source will be increased from 34.53-cu m/day to 181-cu m/day
cost of the project is ` 17.5-million. As of September the project after expansion. Effluent generation will be increased from 9.35-cu
was waiting for the environmental clearance. According to MoEF m/day to 79.5-cu m/day after expansion. Highly concentrated effluent
sources, the plot area is 4.027 acres. The company proposes to will be sent to captive incinerator for incineration. Remaining effluent
manufacture 50-TPM of products as part of the expansion. Green belt (70-m3/day) will be treated in the ETP comprising primary, secondary
on 33 per cent of the land area will be developed and maintained. and tertiary treatment. Treated effluent will be sent to CETP for further
Power requirement will be made available through SPCPDCL. The treatment. ETP sludge, inorganic residue and incineration ash will be
project will be completed within 2 years. sent to TSDF. Spent carbon, organic residue will be sent to incinerator.

Globex Laboratories (R&D) proposes a pigments manufacturing Adi Finechem is planning a 40-TPA specialty products manufacturing
unit at village: Dabhasa, district: Vadodara, Gujarat. According to project on a 2-acre land at an estimated cost of ` 400-million in village:
MoEF sources, the project will come up in the existing land on Chekhala, district: Ahmedabad, Gujarat. The project is waiting for
9,312-sq m. Kadam Environmental Consultants, Vadodara is the environmental clearance.
environmental consultant. The project will entail manufacture of
40-TPM red pigments, 40-TPM yellow pigments and 450-TPM dilute RSPL is planning a 1,500-TPD soda ash plant and 40-MW captive
phosphoric acid. Environment clearance has been obtained for the power project in village: Kuranga, district: Jamnagar, Gujarat. Land
products red pigments and yellow pigments. Construction work acquisition is in progress. 85 per cent of land has been acquired. The
has begun, as EC and NOC have been received. Effluents generated project is waiting for environmental clearance. The entire project is
will be treated in effluent treatment plant having MEE. The company planned for completion in 5 years from zero date.

60 February 2016 Chemical Engineering World


Project Update CEW
Superhouse is planning an expansion of its chemical mix-manufacturing project from 200-kg/
day to 500-kg/day in UPSIDC Industrial Area, district: Unnao, Uttar Pradesh. The product will
be used in leather tanneries. The project will involve installation of containers. The project is
in planning stage.

MINING
Metabluu Power, a sister concern of Minera Udyog India, is planning a 75,000-TPA iron ore
mining project in village: Devikonda, district: Karimnagar, Telangana. The project is awaiting
Government approval.

Aryan Ispat & Power is planning an expansion of its coal washery in village: Bamoloi,
district: Sambalpur, Odisha. The project will come up in the existing 204.65-acre integrated
steel plant premises. The capacity of the project is to be augmented from 0.70-MTPA to
5.70-MTPA. The cost of the project is ` 600.7 million. The project is awaiting environmental
clearance and planned for completion in 1-year from zero date. According to MoEF sources, the
expansion is based on heavy media cyclone (wet process) technology. The washery will produce
washed coal of an average ash around 34% (GCV 4,350-Kcal/kg), middling (ash content about
58%) of GCV around 2,350-Kcal per kg useable as fuel in FBC boilers. The proposed expansion
will be the state-of-the-art with close circuit water system, classifying cyclone, high frequency
screens, thickener and multi-roll belt press filters. Power requirement of 5-MVA will be sourced
from its own power plant connected with the Grid Corporation of Odisha.

NTPC is planning the Kudanali-Luburi coal mining project in district: Angul, Odisha. The company
has signed an agreement on June 15, 2015 with Jammu and Kashmir State Power Development
Corporation (JKSPDCL) for promoting a joint venture company with 67:33 equity participation It is time to Migrate to an advanced
Structural Analysis Software
for undertaking exploration, development and operation of jointly allocated Kudanali-Luburi Coal
Block at Odisha by the Ministry of Coal.
Easy User Interface
DSP Associates is planning a 15,17,600-TPA sand (minor mineral) mining project in the Conformancee to nuclear industry QA/QC - NRC
mines of Tikola-1 Sand Unit at village: Tikola, district: Gurgaon, Haryana. Mining lease area Integration with smartPlant 3D / Tekla / STAAD.Pro
is 42.50-hectare. The estimated cost of the project is ` 55-million. The project is waiting for
environmental clearance. Mining work is expected to commence soon. According to MoEF Validation & verication for more than
sources, out of the total area, 31.50-hectare area falls in the river bed and 11-hectare area falls 5000+test problems
in agricultural land (outside river bed). Method of mining will be opencast semi-mechanized
Base plate modeling & analysis
without drilling and blasting. The mine will be excavated out in layers up to a depth of 3-m in
riverbed and 9-m in agricultural field. Letter of Intent (LoI) for mining contract has been granted Linear and Non linear Static-Dynamic analysis
for a period of 9 years. Steel Frame & reinforced concreate design
CIS/2 analysis data interface
NON-CONVENTIONAL ENERGY
Hubli Electricity Supply Company is planning solar RTPV grid connected power plants in Comprehensive & detailed user documentation
district: Belagavi, Karnataka. E-tenders have been floated to design, manufacture, supply, Offshore structure analysis & deisgn
installation, testing and commissioning of solar RTPV grid connected power plants on roof-tops
of 31 HESCOM office buildings in Belagavi Zone Jurisdiction for total load of 136-KWp including
operation and maintenance for a period of five years. The approximate amount put to tender is
` 18.62-million.

Karnataka Renewable Energy Development is planning a 10-MW solar power project at an


estimated cost of ` 600-million (approximately) in village: Tingloor, taluka: Madhugiri, district: Tumkur,
Karnataka. Surana Telecom And Power has received Letter of Award (LoA) for development of
the project. Email: sales@iges.in

Maharashtra State Power Generation Company is planning a


50-MWp solar photo voltaic power project in Gangakhed, district: Parbhani, Maharashtra. The company www.iges.in
is scouting for land. Other details are yet to be finalized. TOLL FREE : 1800 102 4437

Chemical Engineering World February 2016 61


CEW Book Shelf

Chemical Process Safety: Fundamentals with


Applications (3 rd Edition)
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62 February 2016 Chemical Engineering World


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Chemical Engineering World February 2016 63


CEW Interview

Turning India into a


Manufacturing Hub
by Rising above
Hurdles
I n d i a s g r o w t h d r i v e r w i l l b e i t s
population; states A M Tiwari, Managing
Director, Gujarat Alkalies
and Chemicals Limited
(GACL) in conversation with
Mittravinda Ranjan. He
comments on the chlor-
alkali market outlook in India
as compared to the Chinese
market which is slowing
down or the Middle Eastern
market which sees low
energy costs. He also speaks
about the competition in the
market, anti-dumping duties, potential
investments GACL may be making, etc.
Here are the excerpts.

64 February 2016 Chemical Engineering World


Interview CEW
According to a recently released report, material is available at an inexpensive price in recent months it has not dumped caustic
the Chlor-Alkali market is estimated to in India, it is a challenge when it comes to the soda into India because of the Tianjin port
witness a CAGR of 6.0 per cent between actual production cost. India is bogged down closure due to NaCN blast. The electricity
2014 and 2019 in terms of value and is by many ideological issues and pressure cost in China is greater or at par with India.
anticipated to generate a global market groups which is hurting our competitiveness. Apart from this, India is geographically
value of USD 93936 million by 2019. How However, making world scale plants with better placed than China to cater to the
do you see the market dynamics play up captive downstream units to produce further global market.
in the years to come in India and globally? value added chemicals shall be the key
The chlor-alkali industry is expected to remain to success. Focus on various chlor-alkali In another decade, the African market is
at a range CAGR from 6-7 per cent. It may products like caustic soda (lye, flakes & prills), going to grow significantly and as of today
even improve as the GDP growth of India is chlorine, chloromethanes, hydrochloric acid
the countrys export to Africa is fairly good.
expected to be more than 7 per cent in coming to African and European countries shall help
But India would require major capacity
years as also growth in other user sectors like the Indian chlor-alkali industry to remain on
expansions to meet the export requirements.
Alumina is estimated at more than 10 per cent the growth track through economies of scale.
This is possible if India can explore having
and more than 8 per cent in the paper and tie-ups with companies like SABIC or Iranian
pulp sector. The most robust growth driving What are your thoughts on Comparison
petrochemical manufacturers from where we
factor for India would be its population which with Middle East?
bring in investments and natural gas, carry
is growing at 1.5 per cent. It is true that the cost of energy is very low
out cracking and conversion into ethylene and
in the Middle East but that is mainly due to
propylene and sell it in market for further value
Where does the Indian chlor-alkali industry the fact that Middle Eastern countries make
addition. This way, the foreign companies will
stand globally in comparison with China, use of low priced natural gas for power
get access to the growing Indian market and
where the industry enjoys economies of generation which is not the case in India.
On the other hand, the cost of salt in the still be able to earn a reasonable profit. There
scale and with the Middle East where the
Middle East is ` 4000 per tonne or higher are two ways of doing this, either we go and
energy cost is very low?
but the same will cost not more than ` 800- set up plants in countries like Iran or convince
Comparison with China them to jointly set up plants in India. Such an
900 in India. Similarly, raw water is very
China is completely focused on design based arrangement will ensure better realisation in
expensive there.
processing which cannot be easily done in export markets for Indian firms and assured
India due to a number of serious bureaucratic availability of critical inputs. Such steps
hurdles. One way of improving processes and Middle East will have little chance of
competing with us if gas based value can work in favour of the country provided
technology is through research jointly done
addition is done there, the material is decisions are taken quickly.
by the academic institutions and industry.
brought here, then converted with some
Although India was a step ahead of China in
value addition and exported to rest of the PCPIRs have been under the planning
setting up institutes of CSIR, but China did a
world. Dahej in Gujarat is ideally suited for stage for a very long time. How would
better job when it set up these institutions. It
value added export due to its proximity to these reverse SEZs you speak of work?
ensured every institute partnered with some
the Middle East and easy availability of key PCPIR concept is on the verge of failure due to
industry or the other and there was a lot of
domestic inputs. But India does not have the the unreasonable attitude of so called Anchor
research jointly done by the institutes and
port infrastructure to support such a move. Units that are not willing to share the basic
the industry. Also, in China, the 1st stage of
Also, the bureaucracy needs to be a little
development was export oriented and they building blocks with the downstream units and
more proactive to such suggestions from the
set up plants that were of global scale and by doing this, they will single-handedly kill this
industry as various issues concerning Dahej
had to be super-efficient. The whole taxation good initiative. Lack of focus on infrastructure
are already known but no concrete move to
structure, financial institutions, logistics, et al like good port, efficient rail connectivity,
address them is being taken up.
was driven with exports in mind. logistics handling agencies, reliable utility
suppliers, etc. are adding up huge capital
Please share your views on the impact of
In India, the basic chemical industry was costs that are taking away the advantage of
low growth posted by China on the overall
always focused on the domestic market and port based locations of the PCPIRs. Iran is
market dynamics of chlor-alkali industry
as a result our industrial units were smaller and the impact on Indian industry? In the 2nd largest producer of natural gas and
in size rather being able to serve the market your view, how can our domestic industry when it comes to connectivity, Dahej is only
on a global scale. Between 1970s and 1990s, leverage on the opportunity? a day or twos journey from Iran. Crackers
the plants set up were small in size and now Historically, many of products have been can be set up in Dahej and ethane can be
the country faces a problem where majority dumped to India from China. High man transported across the Arabian Sea via ships.
of our plants are not on par with the global power cost, internal government policy, If this is planned and executed well, it can be
standards. If we take the example of caustic low operation capacities are some of the a viable solution for huge downstream value
soda, China buys salts from India but can still challenges that India needs to work on. addition and export and the problem created
manage to be competitive. Although the raw Even after the low growth posted by China by Anchor Units can also be resolved.
Chemical Engineering World February 2016 65
CEW Interview
What kind of competition across Indian chlor-alkali GACL witnessed a jump in gross income during the period 2011-
manufacturing industry do you see? How does GACL maintain 12 from 2070 crores to 2432 crores and after which the growth has
its competitive edge? What are the various steps a company plateaued till 2014. Can you please share some insights into the
has to take towards improving top and bottom line margins? companys performance during this period?
Chlor-alkali is nothing more than an ordinary commodity. This 2011-12 was a remarkable year for the chemical industry and most of
industry does not have any competitive technology on which it can the companies made a good profit. I was in GNFC in those days and
can thrive. There is no differentiation factor for caustic soda as it made the 2nd highest profits in that year. We wrongly believed that it
every competitor will sell the same product and it is an everyday was due to the efforts the team had put in but the year after we realised
struggle to market the product at a reasonable price. that the same success story could not be repeated. 2011-12 was an
exceptional year for GACL as well and thereafter the prices kept on
In India, 200-300 tonne capacity caustic soda plants are set up declining. Market realisations were not in proportion with the costs due
every 200-300 kilometres; be it in Odisha, Bihar, Andhra Pradesh, to sluggish demand in the market for main products. But if you do a peer
Tamil Nadu, Gujarat, Punjab and Rajasthan. Gujarat has a higher group analysis, GACL performed much better during this period than
concentration of the industry as it has raw material available in its peers. The vision at the time was to bring in internal efficiency rather
plenty. It is a wonder for us how in Europe or America a distance of than taking up new projects. Also, at the time, plants were not being run
500-1000 kilometres is not much from the point of view of logistics.
at full capacity because the natural gas and alternative energy costs
Abroad, a company could make a product in one place and sell it as
had gone up. This situation was stabilised at our Dahej complex in next
far as 1400 kilometres with ease. In India, this does not turn out to
three years. GACL had to also tackle the problem of energy sourcing.
be a viable solution as someone has set up a small plant closer to
The R-LNG and APM natural gas run power plant in Dahej had to be shut
the customer and has the price advantage there. GACL has found
down due to a number of hurdles, such as increasing gas cost, policy
a solution to this issue by setting up a pipeline to the Dahej railway
changes, etc. A number of crucial projects are in the pipeline but would
station and leased rakes to transport the product from the West to
Nalco, etc. Ship was one of the options GACL tried to explore, but take some extensive planning and timely execution for them to be set
there are complexities like the bunker fuel tax which make sending in motion.
the product through ship freight within India an expensive affair.
In comparison world over, ship transport is the cheapest option, According to GACLs annual report for the year 2013-14, high
followed by rail and road. The situation is reverse in India due to crude oil and natural gas prices impacted top and bottom line
random policies. Road transport would mean sending 250 trucks margins of the company. With the current fall in crude oil and
whereas the same amount can be sent at once through rail which natural gas prices, what kind of improvement is anticipated for
also saves on time. the current financial year?
In 2013-14, GACL was adversely impacted by the depreciating rupee
Some of the measures GACL is considering to improve margins as this badly affected our gas based power plant in Dahej. The company
are outsourcing value added products, compatible expansion plans, retained its profitability with downstream products like hydrogen
improvement in the capacity of existing plants, broadening the base peroxide, phosphoric acid and the plants were running at full capacity.
of products baskets, optimisation of energy and operating costs, The idea was to bring down the energy cost and we expanded our wind
focus on exports, penetrate eastern region market to balance over power program. Today, we have 156 MW wind power turbines with
supply in the western region market. plans of setting up more to ensure energy efficiency.

Does the Indian market provide level playing field for What are the future investment plans?
competition between Indian and international players? What
We have been working on debottlenecking of chloromethane which
is the structure of anti-dumping duty for various chlor-alkali
would see an investment of ` 120 crores. The plants capacity would
products to protect the domestic market?
be 170 tonnes per day (TPD) as compared to its previous capacity of
Some products have the anti-dumping support. But it may be a
110 TPD. Basic engineering has been completed and civil work is to
temporary call till the Indian industry can achieve the level playing
start soon. GACL would be making an investment of ` 40 crores in
capabilities to compete with the global players, some of which are
debottlenecking the caustic potash plant. Currently, the plant has a
deliberately hitting at small Indian producers and the industry must
capacity of 80 TPD which would increase to 140 TPD. Also, we would
be able to face the international imports/ dumping threats all the
time. We have started working on how we can live without anti- be setting up a wind farm of 31 MW with an investment of about ` 190
dumping duty. Chemical sector cannot rely on anti-dumping duty crore. The total investment would be of about ` 350 crores.
beyond 5-6 years. But the important question that remains is What
after that? In the next 2-3 years the company is planning numerous capacity
additions to the downstream products viz. chloromethanes, phosphoric
So far, major imports are from Iran wherein anti-dumping duty acid and hydrazine hydrate, etc. GACL would also be setting up a
is negligible. After lifting of sanctions, Iran will channelize their joint venture with NALCO for an 800 TPD CS plant and a 100MW
products in nearby markets of European and Middle Eastern imported coal based power plant for an estimated investment of about
countries and thus caustic soda export to India will reduce. ` 1790 crores.
66 February 2016 Chemical Engineering World
R.N.I. No. 11403/1966 Date of Publication: 29 th of every month. Postal Registration No: MCS/095/2015-17
Posted at Patrika Channel Sorting Ofce, Mumbai 400001, on 29th & 30th of every month. Total Pages No.:68

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