Combustible:

GLP - 60% propano (C3H8) + 40% butano (C4H10)

Tcomb = 298 K
Taire = 300 K
Tgases = 1000 K
kg
m
=5
aire min

Calor transferido por Kmol de combustible:

Q= (ni h i)
(ni h i) gases react

1. Para 100% aire terico

La ecuacin de la Rx de combustin:

0.6C3H8 + 0.4 C4H10 + Xt (O2 + 3.76 N2) a CO2 + b H2O + d N2

C: a=3.4
H: b=4.4
O: Xt=5.6
N: c=21.01

0.6C3H8 + 0.4 C4H10 + 5.6 (O2 + 3.76 N2) 3.4 CO2 + 4.4
H2O + 21.01 N2

a) Q = [ 3.4 h CO2+4.4 h H2O+21.01 h N2 ] - [ 0.6 h +0.4 h
C3H8

C4H10+5.6
h O2+5.6(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T

Q = {3.4 [-393520+ (42769-9364)]+4.4 [-241820+ (35882-

9904)]+21.01 [0+ (30129-8669)]} - {0.6 [-103850+0]+0.4 [-
126150+0]+5.6 [0+0]+ 5.6 (3.76) [0 + 0]}

KJ
Q = - 1 568 911 Kmol
 Kg
- (PM)C3H8 = 44.09 Kmol
Kg
- (PM)C4H10 = 72.15 Kmol

Q 1 568 911 KJ
q= = = - 28 365.77
PM 0.6 ( 44.09 ) +0.4 (72.15) Kg

(aire) 5 kg / min
b) (comb)= m( comb) = 5.6 ( 137.28 ) (55.31)
m(aire)

Kg Kg
( comb ) = 0.36 min = 6.10-3 s

KJ Kg
c) Q= - 28 365,77 Kg x 6.10-3 s

KJ
Q= -170.20 s = -170.20 Kw

d) Temperatura del Rocio

PP = (P)
4.4 4.4
Dnde: = 28.81 PP= 5
28.81 (10 Pa)

PP = 15.27 KPa

Por tabla:
A 15.27 KPa le corresponde T = 54C = 327K

2. Para 90 % de aire terico

La ecuacin de la Rx de combustin:

0.6C3H8 + 0.4 C4H10 + 0.9 (5.6) (O2 + 3.76 N2) a CO2 + b H2O +
c N2 + d CO
C: a=2.28
H: b=4.4
O: d=1.12
N: c=18.95
 0.6C3H8 + 0.4 C4H10 + 0.9 (5.6) (O2 + 3.76 N2) 2.28 CO2
+ 4.4 H2O + 18.95 N2 + 1.12 CO

a) Q = [3.4 h CO2 + 4.4 h H2O + 21.01 h
+ 1.12 h N2 CO ] - [0.6 h

C3H8 + 0.4
h C4H10 + 5.6
h O2 + 5.6(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T

Q = {2.28 [-393520 + (42769-9364)] + 4.4 [-241820 + (35882-

9904)] + 18.95 [0 + (30129-8669)] + 1.12 [-110530 + (30355-
8669)]} - {0.6 [-103850+0] + 0.4 [-126150+0] + 0.9 (5.6)
[0+0] + 0.9 (5.6) (3.76) [0 + 0]}

KJ
Q = - 1 340 174 Kmol

Kg
- (PM)C3H8 = 44.09 Kmol
Kg
- (PM)C4H10 = 72.15 Kmol

Q 1340 174 KJ
q= = = - 25 139.26 (comb)
PM 0.6 ( 44.09 ) +0.4 (72.15) Kg

(aire) 5 kg/min
b) (comb)= m( comb) =
m(aire) 0.9(5.6) ( 137.28 ) (55.31)

Kg Kg
( comb ) = 0.40 min = 6.66x10-3 s

KJ Kg
c) Q= - 25 139.26 Kg x 6.66x10-3 s

Q= -167.43 Kw

d) Temperatura del Rocio

 PP = (P)
4.4 4.4
Dnde: = PP= 5
26.75 26.75 (10 Pa)

PP = 16.45 KPa

Por tabla:
A 16.45 KPa le corresponde T = 56C = 329K

3. Para 80 % de aire terico

La ecuacin de la Rx de combustin:

0.6C3H8 + 0.4 C4H10 + 0.8 (5.6) (O2 + 3.76 N2) a CO2 + b H2O +
c N2 + d CO
C: a=1.16
H: b=4.4
O: d=2.24
N: c=16.85

0.6C3H8 + 0.4 C4H10 + 0.8 (5.6) (O2 + 3.76 N2) 1.16 CO2
+ 4.4 H2O + 16.85 N2 + 2.24 CO

a) Q = [1.16 h CO2 + 4.4 h H2O + 16.85 h N2+ 2.24 h CO] - [0.6
h C3H8 + 0.4 h C4H10 + 0.8(5.6) h O2 + 5.6(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T

Q = {1.16 [-393520 + (42769-9364)] + 4.4 [-241820 + (35882-

9904)] + 16.85 [0 + (30129-8669)] + 2.24 [-110530 + (30355-
8669)]} - {0.6 [-103850+0] + 0.4 [-126150+0] + 0.8 (5.6)
[0+0] + 0.8 (5.6) (3.76) [0 + 0]}

KJ
Q = - 1 092 078 Kmol

Kg
- (PM)C3H8 = 44.09 Kmol
 Kg
- (PM)C4H10 = 72.15 Kmol

Q 1 092078 KJ
q= = = - 19 744.67 (comb)
PM 0.6 ( 44.09 ) +0.4 (72.15) Kg

(aire) 5 kg/min
b) (comb)= m( comb) =
m(aire) 0.8(5.6) ( 137.28 ) (55.31)

Kg Kg
( comb ) = 0.45 min = 7.49x10-3 s

KJ Kg
c) Q= - 19 744.67 Kg x 7.49x10-3 s

Q= -147.98Kw

d) Temperatura del Rocio

PP = (P)
4.4 4.4
Dnde: = PP= 5
24.65 24.65 (10 Pa)

PP = 17.85 KPa

Por tabla:
A 17.85 KPa le corresponde T = 59C = 332K

4. Para 200% aire terico

La ecuacin de la Rx de combustin:

0.6C3H8 + 0.4 C4H10 + 2 (5.6) (O2 + 3.76 N2) a CO2 + b H2O + c

N2 + d O2
C: a=3.4
H: b=4.4
O: c=42.11
N: d=5.6
 0.6C3H8 + 0.4 C4H10 + 2 (5.6) (O2 + 3.76 N2) 5.4 CO2 +
4.4 H2O + 42.11 N2 + 5.6 O2

a) Q = [3,4 h CO2 + 4.4 h H2O + 42.11 h
+ 5.6 h O2] - [0.6 h
N2

C3H8 + 0.4
h C4H10 + 2(5.6)
h O2 + 2(5.6)(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T

Q = {3.4 [-393520+ (42769-9364)]+4.4 [-241820+ (35882-

9904)]+42.11 [0+ (30129-8669)] + 5.6 [0 + (31389-8682)]} -
{0.6 [-103850+0]+0.4 [-126150+0]+2(5.6) [0+0]+ 2(5.6)
(3.76) [0 + 0]}

KJ
Q = - 1 030 486 Kmol

Kg
- (PM)C3H8 = 44.09 Kmol
Kg
- (PM)C4H10 = 72.15 Kmol

Q 1030 486 KJ
q= = = - 18 631.10
PM 0.6 ( 44.09 ) +0.4 (72.15) Kg

(aire) 5 kg /min
b) (comb)= m( comb) = 2( 5.6) ( 137.28 ) (55.31)
m(aire)

Kg Kg
( comb ) = 0.18 min = 3x10-3 s

KJ Kg
c) Q= - 18 631.10 Kg x 3x10 -3
s

Q= -55.89 Kw

d) Temperatura del Rocio

PP = (P)
 4.4 4.4
Dnde: = PP= 5
39.51 39.51 (10 Pa)

PP = 11.14 KPa

Por tabla:
A 11.14 KPa le corresponde T = 49C = 322K

5. Para 300% aire terico

La ecuacin de la Rx de combustin:

0.6C3H8 + 0.4 C4H10 + 3 (5.6) (O2 + 3.76 N2) a CO2 + b H2O + c

N2 + d O2
C: a=3.4
H: b=4.4
O: c=63.17
N: d=11.2

0.6C3H8 + 0.4 C4H10 + 3 (5.6) (O2 + 3.76 N2) 3.4 CO2 +

4.4 H2O + 63.17 N2 + 11.2 O2

a) Q = [3.4 h CO2 + 4.4 h H2O + 63.17 h
+ 11.2 h O2] - [0.6 h
N2

C3H8 + 0.4
h C4H10 + 3(5.6)
h O2 + 3(5.6)(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T

Q = {3.4 [-393520+ (42769-9364)]+4.4 [-241820+ (35882-

9904)]+63.17 [0+ (30129-8669)] + 11.2 [0 + (31389-8682)]} -
{0.6 [-103850+0]+0.4 [-126150+0]+3(5.6) [0+0]+ 3(5.6)
(3.76) [0 + 0]}

KJ
Q = - 451 379.2 Kmol

Kg
- (PM)C3H8 = 44.09 Kmol
Kg
- (PM)C4H10 = 72.15 Kmol
 Q 451 379.20 KJ
q= = = - 8 160.90
PM 0.6 ( 44.09 ) +0.4 (72.15) Kg

(aire) 5 kg/ min

b) (comb)= m( comb) = 3 (5.6) ( 137.28 ) (55.31)
m(aire)

Kg Kg
( comb ) =0.12 min = 2x10-3 s

KJ Kg
c) Q= - 8 160.90 Kg x (2x10 -3
s )

Q= -16.31 KW

d) Temperatura del Rocio

PP = (P)
4.4 4.4
Dnde: = 82.17 PP= 5
82.17 (10 Pa)

PP = 5.36 KPa

Por tabla:
A 5.46 KPa le corresponde T = 34C = 307K

Combustible:
Diesel C12H26
Tcomb = 298 K
Taire = 300 K
Tgases = 900 K
kg
m
= 10
aire min

1. Para 100% aire terico

La ecuacin de la Rx de combustin:

C12H26 + Xt (O2 + 3.76 N2) a CO2 + b H2O + c N2

C: a=12
H: b=13
O: Xt=18.5
N: c=69.56

C12H26 + 18.5 (O2 + 3.76 N2) 12 CO2 + 13 H2O + 69.56

N2

h
a) Q = [ 12 h +13 h H2O+69.56 h N2 ] - [
CO2 C12H26 +18.5 h

O2+18.5(3.76)
h N2 ]

Sabemos que h = h f + ( h )P,T

Q = {12 [-393520+ (37405-9364)]+13 [-241820+ (31828-

9904)]+69.56 [0+ (26890-8669)]} - {[-291066+0]+18.5
[0+0]+ 18.5 (3.76) [0 + 0]}

KJ
Q = - 5 687 047 Kmol

Kg
- (PM)C12H26 = 170 Kmol

Q 5 687 047 KJ
q= PM
=
170 = - 33 453.22 Kg

(aire) 10 kg / min
b) (comb)= m( comb) = 18.5 ( 137.28 ) (170)
m(aire)
 Kg Kg
( comb ) = 0.67 min = 0.011 s

KJ Kg
c) Q= - 33 453.22 Kg x 0.011 s

Q= 373.21 Kw

d) Temperatura del Rocio

PP = (P)
13 13
Dnde: = PP= 5
94.56 94.56 (10 Pa)

PP = 13.75 KPa

Por tabla:
A 13.75 KPa le corresponde T = 53C = 326K

2. Para 90 % de aire terico

La ecuacin de la Rx de combustin:

C12H26 + 0.9 (18.5) (O2 + 3.76 N2) a CO2 + b H2O + c N2 + d CO

C: a=8.3
H: b=13
O: d=3.7
N: c=62.60

C12H26 + 16.65 (O2 + 3.76 N2) 8.3 CO2 + 13 H2O + 62.60 N2 +

3.7 CO

a) Q = [8.3 h CO2 + 13 h + 62.60 h
H2O N2 + 3.7 h ]-[ h
CO C12H26

h N2 ]
+ 16.65 h O2 + 16.65(3.76)

Sabemos que h = h f

+ ( h )P,T
 Q = {8.3 [-393520+ (37405-9364)]+13 [-241820+ (31828-
9904)]+62.60 [0+ (26890-8669)] + 3.7 [-110530 + (27066-
8669)]} - {[-291066+0]+16.65 [0+0]+ 16.65 (3.76) [0 + 0]}

KJ
Q = - 4 902 267 Kmol

Kg
- (PM)C12H26 = 170 Kmol

Q 4 902 267 KJ
q= PM
=
170 = - 28 836.87 Kg (comb)

(aire) 10 kg /min
b) (comb)= m( comb) =
m(aire) 0.9(16.65) ( 137.28 ) (170)

Kg Kg
( comb ) = 0.83 min = 0.0138 s

KJ Kg
c) Q= - 28 836.87 Kg x 0.0138 s

Q= -397.17 Kw

d) Temperatura del Rocio

PP = (P)
13 13
Dnde: = PP= 5
87.60 87.60 (10 Pa)

PP = 14.84 KPa

Por tabla:
A 14.84 KPa le corresponde T = 54C = 327K

3. Para 80 % de aire terico

La ecuacin de la Rx de combustin:

C12H26 + 0.8 (18.5) (O2 + 3.76 N2) a CO2 + b H2O + c N2 + d CO

 C: a=4.6
H: b=13
O: d=7.4
N: c=55.65

C12H26 + 14.8 (O2 + 3.76 N2) 4.6 CO2 + 13 H2O + 55.65 N2 +

7.4 CO

a) Q = [4.6 h CO2 + 13 h + 55.65 h H2O N2 + 7.4 h CO ] - [ h

C12H26 + 14.8
h O2 + 14.8(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T
Q = {4.6 [-393520+ (37405-9364)]+13 [-241820+ (31828-
9904)]+55.65 [0+ (26890-8669)] + 7.4 [-110530 + (27066-
8669)]} - {[-291066+0]+14.8 [0+0]+ 14.8 (3.76) [0 + 0]}

KJ
Q = - 3 917 741 Kmol

Kg
- (PM)C12H26 = 170 Kmol

Q 3 917 741 KJ
q= PM
=
170 = - 23 045.53 Kg (comb)

(aire) 10 kg /min
b) (comb)= m( comb) =
m(aire) 0.8(14.8) ( 137.28 ) (170)

Kg Kg
( comb ) = 1.046 min = 0.0174 s

KJ Kg
c) Q= -23 045.53 Kg x 0.0174 s
Q= - 401.72 Kw

d) Temperatura del Rocio

 PP = (P)
13 13
Dnde: = PP= 5
80.65 80.65 (10 Pa)

PP = 16.12 KPa

Por tabla:
A 16.12 KPa le corresponde T = 58C = 331K

4. Para 200% aire terico

La ecuacin de la Rx de combustin:

C12H26 + 2(18.5) (O2 + 3.76 N2) a CO2 + b H2O + c N2 + d O2

C: a=12
H: b=13
O: c=139.12
N: d=18.5

C12H26 + 2 (18.5) (O2 + 3.76 N2) 12 CO2 + 13 H2O +

139.12 N2 + 18.5 O2

a) Q = [12 h CO2 + 13 h H2O + 139.12 h N2 + 18.5 h O2 ] - [ h

C12H26 + 2 (18.5)
h O2 + 2(18.5)(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T
Q = {12 [-393520+ (37405-9364)]+13 [-241820+ (31828-
9904)]+139.12 [0+ (26890-8669)] + 18.5 [0 + (27928-8682)]}
- {[-291066+0]+18.5 [0+0]+ 18.5 (3.76) [0 + 0]}

KJ
Q = - 4 063 543.5 Kmol

Kg
(PM)C12H26 = 170 Kmol
 Q 4 063 544 KJ
q= PM
=
170 = - 23 903.2 Kg

(aire) 10 kg /min
b) (comb)= m( comb) = 2( 18.5) ( 137.28 ) (170)
m(aire)

Kg Kg
( comb ) = 0.335 min = 5.58x10-3 s

KJ Kg
c) Q= - 23 903.2 Kg x 5.58x10-3 s

Q= -133.34 Kw

d) Temperatura del Rocio

PP = (P)
13 13
Dnde: = PP= 5
182.62 182.62 (10 Pa)

PP = 7.12 KPa

Por tabla:
A 7.12 KPa le corresponde T = 40C = 313K

5. Para 300% aire terico

La ecuacin de la Rx de combustin:

C12H26 + 3(18.5) (O2 + 3.76 N2) a CO2 + b H2O + c N2 + d O2

C: a=12
H: b=13
O: c=208.68
N: d=37

C12H26 + 55.5 (O2 + 3.76 N2) 12 CO2 + 13 H2O + 208.68

N2 + 37 O2

a) Q = [12 h CO2 + 13 h
+ 208.68 h N2+ 37 h
H2O O2 ]-[ h C12H26

+ 2 (18.5) h O2 + 2(18.5)(3.76) h N2 ]

Sabemos que h = h f

+ ( h )P,T
Q = {12 [-393520+ (37405-9364)]+13 [-241820+ (31828-
9904)]+208.68 [0+ (26890-8669)] + 37 [0 + (27928-8682)]} -
{[-291066+0]+55.5 [0+0]+ 55.5 (3.76) [0 + 0]}

KJ
Q = -2 439 780 Kmol

Kg
- (PM)C12H26 = 170 Kmol

Q 2 439 780 KJ
q= PM
=
170 = - 14 351.65 Kg

(aire) 10 kg /min
b) (comb)= m( comb) = 3 (18.5) ( 137.28 ) (170)
m(aire)

Kg Kg
( comb ) = 0.223 min = 3.72x10-3 s

KJ Kg
c) Q= - 14 351.65 Kg x 3.72x10-3 s

Q= -53.37 Kw

d) Temperatura del Rocio

PP = (P)
13 13
Dnde: = PP= 5
270.68 270.68 (10 Pa)

PP = 4.80 KPa

Por tabla:
A 4.80 KPa le corresponde T = 31C = 304K
GRAFICAS
Calor Transf. vs % Aire terico (Diesel)
0
50 100 150 200 250 300 350
-5000

-10000

-15000

-20000

-25000

-30000

-35000

Calor Transf. vs % Aire terico (GLP)

0
50 100 150 200 250 300 350
-5000

-10000

-15000

-20000

-25000

-30000

-35000