The following non-linear equation is encounter in the design ofchemical reactor.

dc/d=c/(1+c) , at c(0)=1 & =0.15

Develope the relationship of c with the diffrential value of by eular method,
runge kutta 2nd & 4th order method & compare all the result.f=2.5

(a) Euler Method

Ci 1 Ci hf (i , Ci )
i 1 i h
C ' f (i , Ci )
h ( f min . ) / n

C1= 1
i= 0
f= 2.5
h= 0.25
= 0.15

i c c'
1 0.25 1.217391 1.029412
2 0.5 1.474744 1.207607
3 0.75 1.776646 1.402803
4 1 2.127347 1.612724
5 1.25 2.530528 1.834275
6 1.5 2.989097 2.063774
7 1.75 3.50504 2.297248
8 2 4.079352 2.530768
9 2.25 4.712044 2.760737
10 2.5 5.402228 2.984105
(c) Runge Kutta 4th Oder Method

K 1 hf (i , Ci )
K 2 hf (i 0.5h, C1 0.5 K 1)
K 3 hf (i 0.5h, C1 0.5 K 2)
K 4 hf (i h, Ci K 3)
Ci 1 Ci K
K ( K 1 2 K 2 2 K 3 K 4) / 6
C1= 1
i= 0
f= 2.5
h= 0.25
= 0.15

i C K1 K2 K3 K4
1 0.25 1.217391 0.257353 0.279985 0.281941 0.306011
2 0.5 1.474744 0.301902 0.326746 0.32875 0.354872
3 0.75 1.776646 0.350701 0.377475 0.379474 0.407301
4 1 2.127347 0.403181 0.431495 0.433436 0.46253
5 1.25 2.530528 0.458569 0.487954 0.489788 0.519652
6 1.5 2.989097 0.515943 0.545887 0.547577 0.577699
7 1.75 3.50504 0.574312 0.604303 0.605824 0.635715
8 2 4.079352 0.632692 0.66226 0.663601 0.69283
9 2.25 4.712044 0.690184 0.718927 0.720088 0.748302
10 2.5 5.402228 0.746026 0.773628 0.774617 0.801552
(b)Runge Kutta Second Order Method

K1 hf (i , Ci )
K 2 hf (i h, Ci k )
Ci 1 Ci K

C1= 1
i= 0
f= 2.5
h= 0.25
= 0.15

i c c' K1 K2
1 0.25 1.217391 1.029412 0.257353 0.301902
2 0.5 1.497019 1.222502 0.305626 0.35474
3 0.75 1.827202 1.434134 0.358533 0.411515
4 1 2.212226 1.661037 0.415259 0.471172
5 1.25 2.655441 1.899028 0.474757 0.532517
6 1.5 3.159078 2.143402 0.535851 0.594331
7 1.75 3.724169 2.389393 0.597348 0.655479
8 2 4.350583 2.632589 0.658147 0.714998
9 2.25 5.037155 2.869237 0.717309 0.772134
10 2.5 5.781877 3.096414 0.774104 0.826358
K
1.687216
1.967764
2.2719
2.595574
2.933705
3.280571
3.630283
3.977243
4.316515
4.644067
K
0.279627
0.330183
0.385024
0.443216
0.503637
0.565091
0.626414
0.686572
0.744721
0.800231
The gas having the following composition is at temprature of 502c.

Component Composition(%) Xi
SO2 7.09 0.0709
O2 10.55 0.1055
SO3 0.45 0.0045
N2 81.91 0.8191
Sum.

Gas a b*103
SO2 24.7706 62.9481
O2 26.0257 11.7551
SO3 22.0376 121.624
N2 29.5409 -5.141

Calculate the heat content of 1kmol of gas mixture over 25c using heat capacity data given below

C po a bT cT 2 dT 3
Delta= 23.85

X SO2 O2
298 39.8931566774 29.305
321.85 40.8166562864 29.5476681753
345.7 41.7020227712 29.7862465713
369.55 42.5501614458 30.0214964897
393.4 43.3619776245 30.2533721599
417.25 44.1383766212 30.4818278116
441.1 44.8802637502 30.7068176744
464.95 45.5885443255 30.9282959779
488.8 46.2641236613 31.1462169519
512.65 46.9079070717 31.3605348258
536.5 47.5207998707 31.5712038294
560.35 48.1037073725 31.7781781921
584.2 48.6575348913 31.9814121438
608.05 49.183187741 32.1808599139
631.9 49.6815712359 32.3764757322
655.75 50.1535906901 32.5682138282
679.6 50.6001514176 32.7560284315
703.45 51.0221587327 32.9398737718
 727.3 51.4205179493 33.1197040788
751.15 51.7961343816 33.2954735819
775 52.1499133438 33.4671365109
mprature of 502c.

Cpi
22429.03
15030.09
30342.65
14290.155
82091.925

c*106
-44.2582
-2.3426
-91.8673
13.1829

re over 25c using heat capacity data given below.

dT 3

SO3
50.768
 XiCpi
1590.218
1585.674
136.5419
11705.07
15017.5

d*109
11.122
-0.5623
24.3691
-4.968

KJ/Kmole

N2
29.098