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(Mirpur Branch)
Pre mock 3
Academic Session: 2016-2017
Name: ______________________________ Full Marks: 50 Score: ________
Instructions
Information
Section A
In diagram 1, one curve, P or Q, corresponds to a temperature higher than that of the other
curve.
In diagram 2, one line, X or Y, corresponds to the activation energy in the presence of a catalyst
and the other line corresponds to the activation energy of the same reaction in the absence of a
catalyst.
higher presence of
temperature catalyst
A P X
B P Y
C Q X
D Q Y
Which pair of reactants, under suitable conditions, will produce this ester?
B The bond strength of the C I bond is less than that of the C Cl bond.
C The carbon atom in the C Cl bond is more + than that in the C I bond.
6 Why does the rate of a gaseous reaction increase when the pressure is increased at a constant
temperature?
7 The molecular energy distribution curve represents the variation in energy of the molecules of a gas
at room temperature.
8 Which reaction will give the best yield of 1-chloropropane?
reagent Y
1-bromopropane compound Q
butanoic acid
X Y
11 The compound leaf alcohol is partly responsible for the smell of new-mown grass.
CH3CH2CH=CHCH2CH2OH
leaf alcohol
What will be formed when leaf alcohol is oxidised using an excess of hot, acidified K2Cr2O7(aq)?
A CH3CH2CH(OH)CH(OH)CH2CO2H
B CH3CH2COCOCH2CO2H
C CH3CH2CH=CHCH2CO2H
12 Primary alcohols can be oxidised to aldehydes using either acidified potassium dichromate(VI) or
acidified potassium manganate(VII). Both these oxidising agents change colour as they are
reduced.
What is the colour of each oxidising agent before and after it has reacted?
14 Which of these factors will not affect the speed of a chemical reaction?
A concentration of reactants
C pressure of reactants
D volume of reactants
3 3
15 In the diagram, curve X was obtained by observing the decomposition of 100 cm of 1.0 mol dm
B adding water
16 The diagram shows the Maxwell-Boltzmann energy distribution curve for molecules of a mixture of
two gases at a given temperature. For a reaction to occur the molecules must collide together with
sufficient energy.
Ea is the activation energy for the reaction between the gases. Of the two values shown, one is
for a catalysed reaction, the other for an uncatalysed one.
Decide whether each of the statements is or is not correct (you may find it helpful to
put a tick against the statements that you consider to be correct).
A B C D
17 How can the rate of reaction between ethanal and aqueous hydrogen cyanide be increased?
1 CH3CH2CH(CH2OH)CH2CH3
2 (CH3)3CCH2CH2OH
3 CH3CH2CH(CH3)CH2CH2OH
21. The rate of any chemical reaction is increased if the temperature is increased.
N um ber
of
m o le c u le s
E n e rg y
[3]
(b) Use your diagram and the idea of activation energy to explain why the rate of a chemical reaction
increases with increasing temperature.
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[4]
(Total 7 marks)
22 Crotonaldehyde, CH3CH=CHCHO, occurs in soybean oils.
(a) In the boxes below, write the structural formula of the organic compound formed when crotonaldehyde is
reacted separately with each reagent under suitable conditions.
If you think no reaction occurs, write 'NO REACTION' in the box.
B PCl 3
C H2 and Ni catalyst
D NaBH4
E K2Cr2O7 / H+
[5]
Draw the displayed formulae of the stereoisomers of crotonaldehyde. Label each isomer.
[3]
(Total 08 marks)
23. Four of the structural isomers of C4H10O are alcohols. One of these isomers is butan-2-ol.
(a) Draw the structural formula E of two other alcohols with molecular formula C 4 H10 O and
name each of these isomers.
Diagrams
Isomer 1 Isomer 2
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[4]
(b) A sample of butan-2-ol, C4H9OH, was heated with a mixture of sulphuric acid and
potassium dichromate (VI).
(i) State the colour change that would be observed during the reaction.
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[1]
(ii) Give the name of the organic product formed, and name the type of reaction
occurring.
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[2]
(Total 7 marks)
24. Consider the reaction scheme below, which shows how the compound methyl methacrylate,
CH2=C(CH3)COOCH3, is prepared industrially from propanone.
Step 1 Step 2
(CH 3 ) 2 C=O + HCN (CH 3 )2 C(OH)CN CH 2 =C(CH 3 )CN
Step 3
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(b) (i) Give the mechanism for the reaction in Step 1 between the hydrogen cyanide and propanone.
[3]
(Total 8
marks)