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Nanofiltration Membrane
Sara Rolfe
Business Development
Eltron Research & Development Inc.
303-530-0263 x115
business@eltronresearch.com
CONTENTS
Executive Summary
Background
Nanofiltration Overview
DurafluxTM Advantage
Applications
DurafluxTM Products
Unfair Advantages
Intellectual Property
Government Funding
Commercialization Strategy
Business Model
Team
Eltron R&D Inc
New Venture
Partners & Advisors
Market
Snapshot
Issues, Opportunities, Trends
Value Proposition
Industry Participants
Market Size
Competitors
Technology & Product Development
Financial Projections
Future Opportunities
The existing market for nanofiltration is approximately $300 million and growing
fast but only represents a fraction of this opportunity. The DurafluxTM nanofiltration
membrane will take market share from the $3B reverse osmosis market and the
$50B produced water market.
Over $1 million (mostly SBIR) has been spent to date developing the technology. An
additional $3 million will be required to reach market entry in 18 months. The first
two years of revenue will see $5M+ in sales from smaller, distributed or mobile,
water treatment systems. Once proven on the smaller scale, significantly increased
revenues will come from large scale municipal or industrial installations resulting in
profitability by year four. An additional $5M investment will be required to reach
this point. An exit opportunity would be expected in year five.
The key difference between nanofiltration and reverse osmosis is that the latter
retains monovalent salts (such as sodium chloride), whereas nanofiltration allows
them to pass but retains divalent salts such as sodium sulphate and multivalent ions
such as calcium. This difference also enables NF membranes to operate at greatly
reduced operating pressures with greatly increased flow rates as compared to
Reverse Osmosis.
The membranes are key to the performance of nanofiltration systems. They are
produced in plate and frame form, spiral wound, tubular, capillary and hollow fibre
formats, from a range of materials, including cellulose derivatives and synthetic
polymers, from inorganic materials, ceramics and from organic/inorganic hybrids.
DurafluxTM Advantage
DurafluxTM performance advantages include high stability under elevated
temperatures, oxidizers, pressure fluctuations, transition metals and organic
solvents. These advantages are expected to make this nanofiltration technology
The membrane will sell for a slight premium but will provide the following cost
savings:
dramatically reduced operating costs due to lower power (pumping)
requirements
smaller plant footprint due to increased flux
reduced pretreatment requirements due to increased stability
longer lifetime due to increased stability and tolerance to cleaning cycles
APPLICATIONS
Nanofiltration membranes are primarily used in the treatment of fresh, process and
waste waters. They are currently in service for the following applications:
Water softening of fresh water
Pulp and paper process water
Brackish water
Desalination pretreatment
Wastewater treatment and reclamation
Grey and black water treatment
Food industry applications are quite numerous. In the dairy sector, NF is used to
concentrate whey, and permeates from other whey treatments, and in the recycle of
clean-in-place solutions. In the processing of sugar, dextrose syrup and thin sugar
juice are concentrated by NF, while ion exchange brines are demineralised. NF is
used for degumming of solutions in the edible oil processing sector, for continuous
cheese production, and in the production of alternative sweeteners.
There are more applications in the whole chemical sector (including petrochemicals
and pharmaceuticals) than in the rest of industry put together. While many of these
applications are at the concept or pilot stage NF is already a valuable contributor to
the totality of the chemicals industry. The production of salt from natural brines
uses NF as a purification process. Most chemical processes produce quite vicious
wastes, from which valuable chemicals can be recovered by processes including NF.
NF membranes are also used for the removal of natural organic matter from water,
especially tastes, odours and colours, and in the removal of trace herbicides from
large water flows. They can also be used for the removal of residual quantities of
disinfectants in drinking water.
DurafluxTM PRODUCTS
Membranes
The DurafluxTM technology has been demonstrated on multiple supports including
industry standard polymer flat sheets which can be used in spiral wound modules
and solid tubular substrates as well.
The initial product offering with the greatest differentiation and advantages in the
market is anticipated to be the solid tubular form factor. Qualitative product
specifications are as follows (more quantitative data provided in Technology &
Product Development section below):
2 to 10x water flux over conventional NF
Higher thermal stability than conventional NF (80 C versus 50 C)
Improved stability to transition metals and oxidizers
Extended shelf life (> 2 years dry)
Longer service lifetime
Resistant to mechanical erosion
Compatible with steam cleaning or chemical solvent cleaning
Veolia/HPD CeraMem Pall Corporation Membralox Jiangsu Jiuwu Hitech Co., LTD
Large Systems
Once mature and proven, DurafluxTM membranes will be the work horse in large
scale projects such as water treatment plants.
UNFAIR ADVANTAGES
Intellectual Property
The process by which the DurafluxTM membrane is fabricated involves over 35
different parameters, variables and non-intuitive tricks most of which cannot be
discerned by analyzing the product. This provides a very defensible intellectual
property position. Eltron has applied a protection strategy involving partial patent
coverage complemented by a significant collection of trade secrets.
Government Funding
Eltron has developed this nanofiltration technology on government funding from
the Department of Defense (Army) and The Department of Energy. To date, over
$1,000,000 has been spent developing this technology. Another funding
opportunity available through DOEs SBIR Phase II program is currently providing
an additional $750,000 for technology development which started in late 2010.
COMMERCIALIZATION STRATEGY
As mentioned previously, Eltrons commercialization strategy with the DurafluxTM
membrane technology is to create a new venture. Eltron will retain an equity stake
in the new venture and be entitled to licensing fees and royalties as negotiated with
the new entitys stakeholders.
Business Model
It is proposed that the new venture be a product company supplying DurafluxTM
membrane modules to distributors of filtration systems and project developers of
large filtration facilities. The success of this model will depend upon:
i) the economics of revenues passing through the distributors and
ii) such partners willingness to adopt and sell DurafluxTM membranes.
Membrane Sales
The following companies sell membrane modules for other manufacturers and
would be likely suppliers of DurafluxTM membrane modules.
There may be a valuable opportunity for the new venture to produce and sell its
own skid mounted systems in competition with these companies. This should be
investigated further. While greater revenues may be realized this way, it will
require significantly different skill sets and resources. In addition to membrane
excellence, the new venture would need to provide: Process System Design, Systems
Fabrication, Project Management, Installation Support, Document Preparation,
Validation/Qualification, Risk Analysis, Operator Training, Spare Parts, Service
Contracts and After-Market Service. At this time it is assumed that such
competencies may be added later but will not be required business functions at
start-up.
MARKET
Snapshot
The market for membrane-based water filtration and separations is comprised of
microfiltration, ultrafiltration, nanofiltration and reverse osmosis. Similar variants
include membrane distillation, pervaporation and forward osmosis. These
membrane technologies cover the filtration spectrum from particulate removal to
seawater desalination and solvent separations.
The largest market is desalination served by RO membranes which is a $3B
market having a demonstrated annual growth in excess of 10% (membranes and
Pretreatment and antiscaling additives are used to increase the potential water
recovery. Pretreatment methods can include precipitation and UF removal of low-
solubility salts.
Existing products (flat sheet RO) have extensive manufacturing and installation
infrastructure investments behind them. A significantly different product will have
Ceramic UF membranes and sintered metal filters are used for hot filtration of
particles and large molecules (proteins, polymers), but desalination capabilities are
not yet available on the market.
Industry Participants
Membrane manufacturers with products NOT DIRECTLY competing with Duraflux
(polymeric, flat sheet, spiral-wound, hollow fiber for RO & NF applications)
DOW-Filmtec Sepro
Koch Membrane Systems Sparex
Hydranautics/Nitto Denko Pall Corp.
GE-Osmonics Synder
Toray Osmosis Technologies
TriSep Parker Advanced Filtration
Porex Filtration
There are a number of smaller startup companies producing unique membrane
products for RO, NF and FO.
Market Size
The market size for water filtration membranes is approximately $2.5 billion and
expected to more than double over the next five years. Nanofiltration membranes
capture less than 10% of that market but are the fastest growing segment. The
following reports are available (at a cost) for more complete market summaries.
Nonpolymeric membranes to outpace polymeric types. Polymeric membrane materials will continue to dominate the
market as they have lower initial costs and greater product flexibility than nonpolymeric materials. However, polymer-
based membranes are subject to an increasing level of competition from nonpolymer membranes because of
performance limitations, including poor performance in extreme temperatures, intolerance to a number of chemicals and
a tendency toward biological fouling and clogging. Demand for nonpolymeric materials, including ceramic, metal and
composite types, is expected to record double-digit growth through 2012, due to their better performance in extreme
temperatures and greater pH ranges, as well as generally lower maintenance costs since they are better able to
withstand the high pressure backwash and/or chemicals involved in cleaning the membrane.
Global Markets Direct estimates that the membrane treatment market for industrial water and wastewater is expected to
grow at a Compound Annual Growth Rate (CAGR) of 13% from $2.3 billion in 2008 through 2015 to reach $5.5 billion.
Increasing volume production and technological improvements have reduced capital cost of membrane systems and
operating cost to the point that membrane treatment is now seen as a viable alternative in many water and wastewater
applications. Declining costs are stimulating the membrane treatment growth in the industrial sector.
Nanofiltration is a pressure-driven, membrane-based separation process whose characteristics fall between those of
ultrafiltration and reverse osmosis.
The growing interest in the utilization of nanofiltration membranes primarily stems from their unique physical properties,
making them particularly well suited for specific applications, as a low-cost alternative (both in terms of unit price and
operating costs) to reverse osmosis.
HIGHLIGHTS
The global market for nanofiltration membranes increased from $89.1 million in 2006 to an estimated $97.5
million by the end of 2007. It should reach $310.5 million by 2012, a compound annual growth rate (CAGR) of
26.1%.
The water treatment sector is projected to account for 72.7% of total revenues in 2007, worth an estimated
$70.9 million in 2007 and expected to reach $238.2 million by 2012, a CAGR of 27.4%.
Continued growth in regulations aimed at protecting the environment will positively affect the future expansion
of the nanofiltration membranes market.
Contrary to the popular opinion that membrane filtration of aqueous solutions is a thoroughly researched area with little
scope for innovative technological achievements, there have been a spate of exciting changes in the relatively new
nanofiltration market. Nanofiltration will encourage significant technical innovations, thereby increasing market share in
the coming years. Nanofiltration of aqueous solution is primarily affected by the increasing demand for water, notes the
analyst of this research. Water scarcity necessitates greater focus on domestic water processing or desalination of
brackish water. Additionally, there is a high demand for industrially processable water, which promotes installation of
systems for water recovery. Nanofiltration is also being increasingly deployed for the separation of organic solutions at
moderate conditions and relatively low cost.
Hydranautics
ESNA1-LF-4040/ESNA1-LF. Significantly reduces operating costs and provides
optimum hardness rejection for softening applications, available in 4-inch and 8-
inch diameter configurations.
ESNA1-LF2. Designed to provide high rejection of natural organic materials and
moderate rejection of total hardness, while running below 100 psi, offering energy
and cost savings.
TriSep
TriSep offers two different nanofiltration (NF) membrane chemistries, the TS80
and the XN45. Both are based on proprietary and patented technology developed by
DuPont. The unique chemistries of these membranes allow them to have lower
organic fouling.
Dow - FilmTec
FILMTEC NF90 Elements: Removal of TOC, nitrates, pesticides, herbicides, hardness,
iron, salts.
FILMTEC NF270 Elements: Removal of color, TOC, medium to low calcium passage,
high salt passage.
FILMTEC NF200 Elements: Removal of TOC, atrazine, medium calcium passage,
medium to high salt passage.
FILMTEC NF Elements: Purification of non-water process streams and concentration
of valuable substances.
While greater analysis of these competitive products is needed, Eltron believes the
DurafluxTM performance advantages (high stability under elevated temperatures,
oxidizers, pressure fluctuations, transition metals and organic solvents) provide a
step change improvement over all of them.
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MONTHS