Académique Documents
Professionnel Documents
Culture Documents
2
Applications of Coordination Complexes
Now -a- days chelate compounds are utilized in a number of fields. A few of
them are given here.The applications of coordination compounds are of
great importance. These compounds are widely present in the mineral
,plant and animal worlds. They play many important functions in the area of
analytical chemistry, metallurgy, biological functioning, industry and in
medicine.
nickel(II).
b) tris (8-hydroxy quinolinato) Al(III). As yellow coloured solid.
c) Light green coloured bis (quinaldinato) copper(II) or as dull green
coloured bis (salicylaldoximato) copper(II).
2). Solvent extraction and separation of a metal ion through complexation.
Iron(III) and Al(III) form first order complexes with 8-hydroxy quinoline(L).
FeL3 and AlL3. FeL3 is formed at pH 2-10, and is soluble in chloroform.
AlL3 is formed at a higher pH. And is not readily soluble in CHCl 3.
Therefore they can be separated by addition of 8-hydroxy quinoline and
extracting with CHCl3.
3). Spectrophotometric estimation of trace amounts of metal ions. Several
transition metal ions form complexes with intense colours. They can be
determined by measuring the optical density of the complex at optimum
wave length.
Ex: Fe(II) ion forms dark red complexes with dipyridine or o-phenanthroline,
at
pH 2-9; max = 515 m.
Fe(III) ion forms a complex [Fe(SCN)6]-3 in 0.05-0.5M HNO3; max =
480m
Now -a- days chelate compounds are utilized in a number of fields. A few of
them are given here.
i. In medicine:
Heavy metals like lead; mercury iron; copper; nickel; and chromium
are toxic. They form complexes hindering the normal metabolism.
They are eliminated by a suitable chelating agent.
Example:
m.
Fe(III) ion forms a complex [Fe(SCN) 6 ]-3 in 0.05 0.5M HNO3; max =
480m
Structure of EDTA:
Detection and the Determination of the Composition of a Complex:-
Today the coordination chemists are fortunate that they can detect and
determine the structure of complexes. Some of the methods are simpler
which are given briefly in the following paras.
Detection of the complexes:- The formation of the complex may be
indicated by several properties of the system. By careful consideration of
one or more of these properties the formation of a complex compound can
be contended.
1. By the change in solubility of the reaction products:
U
To get the number of ligands bound per metal ion, the following
manipulations are carried out.
Divide equation (1) by C
+ + = 1 ------------- (3)
But = from equation (2)
+ =1 = 1 -------------- (4)
But = ;
= --------------- (6)
(1 )