SR - Iit-Z (Iz) Co-Spark Jee Adv Pta-16 (2011 p1) Q'paper

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT-Z (IZ) CO-SPARKPTA-16 Dt: 28-
12-14
JEE-ADVANCE-2011-P1-Model
Time: 3:00 IMPORTANT INSTRUCTIONS Max
Marks: 240
CHEMISTRY
+Ve - Ve
No.of Total
Section Question Type Mark Mark
Qs marks
s s
Questions with Single Correct
Sec I (Q.N : 1 7) 3 -1 7 21
Choice
Questions with Multiple Correct
Sec II(Q.N : 8 11) 4 0 4 16
Choice
Questions with Comprehension Type
Sec III(Q.N : 12 16) 3 -1 5 15
(2 Comprehensions 2 + 3 = 5Q)
Sec IV(Q.N : 17 23) Questions with Integer Answer Type 4 0 7 28
Total 23 80
PHYSICS
+Ve - Ve
No.of Total
Qs marks
s s
Sec I(Q.N : 24 30) 3 -1 7 21
Choice
Sec II(Q.N : 31 34) 4 0 4 16
Choice
Sec III(Q.N : 35 39) 3 -1 5 15
Total 23 80
Narayana IIT Academy 28-12-14_Sr.IIT-Z (IZ) CO-SPARK_JEE-
ADV_(2011_P1)_PTA-16
MATHEMATICS
+Ve - Ve
No.of Total
Qs marks
s s
Sec I(Q.N : 47 53) 3 -1 7 21
Choice
Sec II(Q.N : 54 57) 4 0 4 16
Choice
Sec III(Q.N : 58 62) 3 -1 5 15
Total 23 80
Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 2

ADV_(2011_P1)_PTA-16
CHEMISTRY
SECTION-1
Section-I (Single Correct Answer Type, Total Marks: 21) contains 7 multiple choice questions. Each question has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question you will be awarded 3 marks if you
darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (-1) mark will be awarded.
1.
C is
Ph
A) B)
Ph Ph
C) D)

ADV_(2011_P1)_PTA-16
+
Ph3P = CH2 A (major)
2.
Major product (A) is
CH2
CH
A) B)
HC CH3
C) D)

ADV_(2011_P1)_PTA-16
3. During reduction of an aldehyde by Wolf- Kishner method, the initial condensation
compound formed is
A) RC N B) R2C=NNH2 C) RCH = NH D) RCH = NNH2
4. B NaBD
4
D2 O

2 butanone NaBD4
H 2O
A
NaBH4
D2O
A, B and C are :
CH3 CH CH2CH3 in all cases

A)
OH
OH OD OD
B) CH3 C CH2CH3 , CH3 C CH2CH3 , CH3 C CH2CH3
D D H
OH OH OD
C) CH3 C CH2CH3 , CH3 C CH2CH3 , CH3 C CH2CH3
D D H

ADV_(2011_P1)_PTA-16
D)
5. If all benzenoid aromatic carbonyl compounds having formula C8 H 8O react with

NH 2OH ,the number of different oximes possible are
A) 6 B) 8 C) 10 D)12
6. In the reaction HO CH2 CHO dil . NaOH
how many distinct products (saturated) are possible ?

A) 1 B) 2 C) 3 D) 4
7. Cannizzaro reaction is not given by
NO2 CH3
A) OHC B) OHC
CHO
OH
C) OHC D) OHC

ADV_(2011_P1)_PTA-16
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.
Eachquestionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.Foreach
questionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothecorrect
answer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
oo
O3
A OHC-CH2-CH 2-C-C-CH 2-CH2-CH O , as one of the product. Then A is
8. Me2 S
A) B)
C) D)

ADV_(2011_P1)_PTA-16
9) Fehling solution gives red precipitate with:

A) Aromatic aldehyde B) Aliphatic aldehyde
C) Ketones D) -hydroxy ketones
10) Consider the following reaction

C6 H 5 CHO NaOH aq C6 H 5CH 2OH C6 H 5COONa
Choose the correct statement(s)
A) If a very high concentration of NaOH is used , hydride transfer occur mainly from
a dioxoanion shown below.
O
C6 H 5 C H
O
B) If reaction is carried out in D2O using NaOD , C6 H 5CHDOH is produced.
C) If some C6 H 5CDO is added to above reaction mixture , some C6 H 5CD2OH will be
formed.
D) This reaction does not show kinetic isotopic effect.
11) Which of the following reactions is /are correct to get cinnamic acid
ADV_(2011_P1)_PTA-16
A) C6 H 5CHO
( CH 3CO )2 O / CH 3COONa
B) C6 H 5CHO
1) CH 2 ( COOC2 H 5 ) 2 , pyridine
2) H 3O ,

C) C6 H 5CHO
CH CHO / OH3
H / Zn /
D) C6 H 5CHO
1) BrCH2) HCOOC2
O / H /
2
2 5

SECTION-3
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeofthe
paragraphs2multiplechoicequestionsandbasedontheotherparagraph3multiplechoice
questionshavetobeanswered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)out
ofwhichONLYONEiscorrect.Foreachquestionyouwillbeawarded3marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksifnobubbleisdarkened.
In allothercases,minusone(1)markwillbeawarded.
Paragraph-I:
The conversion of aldehyde having no alpha hydrogen to a mixture of carboxylic acid
and primary alcohol is known as Cannizzaro reaction. The most important feature of
this reaction is the conjugate base of hydrate of aldehyde.

ADV_(2011_P1)_PTA-16
12. Which step is rate determining step
A) Step-I B) Step-II C) Step-III D) Step-I and II both
13. In the given reaction final product is

ADV_(2011_P1)_PTA-16
A) B)
C) D)
Paragraph-II: 14 to 16

ADV_(2011_P1)_PTA-16
14) Structure of molecule B is
A) B) C) D)
15) Structure of F is
A) B) C) D)
16) Identify the incorrect statement

ADV_(2011_P1)_PTA-16
A) Structure of E is identical to B B) Structure of A is
C) G is D) Structure of D is
SECTION-4
SectionIV(IntegerAnswerType,TotalMarks:28)contains7questions.Theanswertoeachofthe
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrect
answeristobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksotherwise.Thereareno
negativemarksinthissection.
17. How many of the following compounds will give haloform reaction
a) CH 3COOCH 3 b) CH 3CHO c) CH 3CH (OH )CH 2CH 3
d) CH 3CH 2OH e) C6 H 5COCH 3 f) CH 3COCOCH 3
CH 3CH 2COCH 2CH 3
g) g)
h) CH 3COOH i) CH 3COCH 2COCH 3
18) Which of the following will give positive Fehlings test

ADV_(2011_P1)_PTA-16
d ) HCOOH e) CH 3COCOCH 3 f ) CH 3CH (OH )COCH 3
19)
Double bond equivalent in compound B formed is
20) The number of compounds theoretically possible for the formula C3 H 6O excluding
stereo isomers
21) .
The number of iodoform molecules produced per molecule of the reactant in above
reaction is/are
22) How many of the following are more reactive than acetaldehyde towards nucleophilic
addition?
FCH2CHO, O2N CH2CHO , CH3CH2CHO, CH3COCH3, PhCHO, PhCOCH3

ADV_(2011_P1)_PTA-16
23) Number of moles of RMgX consumed per molecule with the following reactant is.
COOH
OH
OHC
CH3
PHYSICS
SECTION-1
SectionI(SingleCorrectAnswerType,TotalMarks:21)contains7multiplechoicequestions.Each

ADV_(2011_P1)_PTA-16
questionhasfourchoices(A),(B),(C)and(D)outofwhichONLYONEiscorrect.Foreachquestion
youwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingtothecorrectanswerand
zeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwillbeawarded.
24. A potential difference V is applied across an X-ray tube. If e / m is the charge to mass
ratio of an electron and c the speed of light in vacuum, the ratio of the de Broglie
wavelength of the incident electrons to the shortest wavelength of X-rays produced is
given by
1 eV 1 eV 1 2eV 2 eV
A) B) C) D)
c 2m c m c m c m
25. The magnitude of the magnetic moment of the electron in the nth the energy state of a
hydrogen atom is proportional to
1 1
A) B) C) n D) n2
n n
26. If elements with principal quantum number n 4 were not allowed in nature, the
number of possible elements would be
A) 60 B) 32 C) 4 D) 64

ADV_(2011_P1)_PTA-16
27. Photoelectric effect experiments are performed using three different metal plates p,q
and r having work functions p 2.0eV .q 2.5eV and r 3.0eV , respectively. A light
beam containg wavelength of 550nm, 450 mm and 350 nm with equal intensities
illuminates each of the plates. The correct I-V graph for the experiment is
A) B)
C) D)
28. Binding energy per nucleon versus mass number curve for nucle is shown in figure W,
X , Y and Z are four nuclei indicated on the curve. The process that would release
energy is
A) Y 2Z B) W X Z C) W 2Y D) X Y Z

ADV_(2011_P1)_PTA-16
29. A radioactive element of mass number 208 at rest disintegrates by emitting an -
particle. If E is the energy of the emitted -particle, the energy of disintegration is
52 51
A) E B) E C) 52E D) E
51 52
30. A positron with kinetic energy 1 MeV and an electron with kinetic energy 1MeV meet
each other moving in opposite directions. They annihilate each other by emitting two
photons. If the rest mass energy of an electron is 0.51 MeV, the wavelength of each
photon is
0 0 0 0
A) 5.110 3 A B) 10.2 10 3 A C) 8.2 103 A D) 6.2 103 A
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.
Eachquestionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.For
eachquestionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothe
correctanswer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
31. When a point light source, of power W emitting monochromatic light of wavelength
is kept at a large distance a from a photosensitive surface of work function , and
area S, we will have ( The surface faces the source)
W S
A) Number of photons striking the surface per unit time as
4 hca 2
1
B) The maximum energy of the emitted photoelectrons as hc

C) The stopping potential needed to stop the most energetic emitted photoelectrons as
hc
e

ADV_(2011_P1)_PTA-16
D) Photoemission occurs only if lies in the range 0 h c /
32. The intensity of X-rays from a Coolidge tube is plotted against wavelength as shown
in figure. the minimum wavelength found is c and the wavelength of K line is k . If
the accelerating voltage is increased
A) C Decreases
B) K increases
C) K c increases
D) C and K both decrease but K C remains unchanged

33. For a certain radioactive substance, it is observed that after 4 hours, only 6.25% of the
original sample is left undecayed. It follows that
A) The half life of the sample is 1 hour
B) The mean life of the sample 1/(ln 2) hour
C) The decay constant of the sample is ( ln 2) hour-1

ADV_(2011_P1)_PTA-16
D) After a further 4 hours, the amount of the substance left over would be only 0.39%
of the original amount
34. Which of the following statement (s) is/are correct?
A) The rest mass of a stable nucleus is less than the sum of the rest masses of its
separated nucleons
B) The rest mass of a stable nucleus is greater than the sum of the rest masses of its
separated nucleons
C) In nuclear fusion energy is released by fusing two nuclei of medium mass
(approximately 100 amu)
D) In nuclear fission, energy is released by fragmentation of a very heavy nucleus
SECTION-3
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeofthe
paragraphs2multiplechoicequestionsandbasedontheotherparagraph3multiplechoice
questionshavetobeanswered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)out
ofwhichONLYONEiscorrect.Foreachquestionyouwillbeawarded3marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksifnobubbleisdarkened.In
allothercases,minusone(1)markwillbeawarded.
Paragraph-I:
Hydrogen is the simplest atom of nature. There is one proton in its nucleus and an
electron moves around the nucleus in a circular orbit. According to Niels Bohr, this
electron moves in a stationary orbit, it emits no electromagnetic radiation. The angular
momentum of the electron is quantized, i.e., mvr = (nh / 2), where m = mass of the
electron, v = velocity of the electron in the orbit, r = radius of the orbit, and n = 1, 2,
3 when transition takes place from Kth orbit to Jth orbit, energy photon is emitted. If
1 1 1
the wavelength of the emitted photon is , we find that
R 2 2 , where R is
J K
Rydbergs constant.
ADV_(2011_P1)_PTA-16

e
+
+ m
ze F
v n
rn
On a different planet, the hydrogen atoms structure was somewhat different from
ours. There the angular momentum of electron was P = 2n(h / 2), i.e. an even
multiple of (h / 2).
Answer the following questions regarding the other planet based on above passage :
35. The minimum permissible radius of the orbit will be
2 0 h 2 4 0 h 2 0 h 2 0 h 2
A) B) C) D)
me 2 me 2 me2 2me 2
36. In our world, the velocity of electron is v0 when the hydrogen atom is in the ground
state. The velocity of electron in this state on the other planet should be
A) v0 B) v0 / 2 C) v0 / 4 D) v0 / 8
37. In our world, the ionization potential energy of a hydrogen atom is 13.6 eV. On the
other planet, this ionization potential energy will be
A) 13.6 eV B) 3.4 eV C) 1.5 eV D) 0.85 eV

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PASSAGE-II
A radioactive elements decays by beta emission. A detector records n beta particles in
the first 2 seconds and 0.75 n beta particles in the next 2 seconds
38. The decay constant of the element is
1
4 1
3 1 3
A) ln B) ln C) ln 2 D) ln 2
2 3 2 4 2 4
39. The mean life of the element is (given ln(2)=0.693 and ln(3)=1.1)
A) 5 s B) 6 s C) 7 s D) 8 s
SECTION-4
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrect
answeristobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarken
ONLYthebubblecorrespondingtothecorrectanswerandzeromarksotherwise.Thereareno
negativemarksinthissection.
40. Hydrogen gas in its ground state is excited by means of monochromatic radiation of
0
wavelength 975 A . How many different lines are possible in the resulting spectrum?
The ionization energy of hydrogen atom is 13.6 eV.
41. A hydrogen-like atom of atomic number Z is in an excited state of quantum number
n=6. This excited atom makes a transition to the first excited state by successively
emitting two photons of energies 10.20 eV and 17.00 eV respectively. Find the value
of Z. The ionization energy of hydrogen is 13.6 eV.
ADV_(2011_P1)_PTA-16
r
42. The electric potential between a proton and an electron is given by V V0 ln where
r
0
V0 and r0 are constants and r is the radius of the electron orbit around the proton.
Assuming Bohrs model to be applicable, it is found that r is proportional to n x ,
where n is the principal quantum number. Find the value of x.
43. An element of atomic number 9 emits k photon of wavelength . Find the atomic
number of the element which emits K photon of wavelength 4 . (Assume screening
number for K transition is equal to 1)
44. A sliver sphere of radius 1 cm and work function 4.7 eV is suspended from a
insulating thread in free-space. It is under continuous illumination of 200nm
wavelength light. As photoelectrons are emitted , the sphere gets charged and acquires
a potential. The maximum number of photoelectrons emitted from the sphere is A10 z
( where 1 A 10 . The value of Z is (Neglect electron cloud around the sphere)

ADV_(2011_P1)_PTA-16
dN t
45. To determine the half life of radioactive element, a student plots a graph of ln
dt
dN t
versus t. Here is the rate of radioactive decay at time t. If the number of
dt
radioactive nuclei of this element decreases by a factor of p after 4.16 years, find the
value of p.
46. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second,
whose mean life is 109 s. the mass of an atom of this radioisotope is 1025 kg . The mass
(in mg) of the radioactive sample is

ADV_(2011_P1)_PTA-16
MATHEMATICS
SECTION-1
SectionI(SingleCorrectAnswerType,TotalMarks:21)contains7multiplechoicequestions.Each
questionhasfourchoices(A),(B),(C)and(D)outofwhichONLYONEiscorrect.Foreachquestion
youwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingtothecorrectanswerand
zeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwillbeawarded.
47. n positive integers taken at random are multiplied together then the probability that
the last digit of the product is zero is__
10n 4n 10n 8n 5n 10n 5n 4n 10n 8n 5n 4n
A) B) C) D)
10n 10n 10n 10n
48. If A,B,C are three events such that
P A 0.3, P B 0.4, P C 0.8, P A B 0.08, P A C 0.28 , P A B C 0.09 ,
P B C x . If probability of getting atleast one event of A,B,C is greater than or
equal to 0.75 then
A) 0.23 x 0.48 B) 0.58 x 0.72 C) 0.28 x 0.52 D) 0.27 x 0.56
49. An urn contains 2 white 2 black balls. A ball is drawn at random and if it is white it is
not replaced into urn, otherwise it is replaced along with other ball of same colour. The
process is repeated, then the probability that the third ball drawn is black is
42 46 48 34
A) B) C) D)
60 60 60 60

ADV_(2011_P1)_PTA-16
Consider f x x ax bx c . Parameters a,b,c are chosen respectively by throwing a
3 2
50.
die three times, then the probability that f x is increasing function is____
5 8 4 1
A) B) C) D)
36 36 9 3
If three numbers are chosen randomly from the set 1,3,3 ,.......,3 without replacement
2 n
51.
then the probability that they form an increasing geometric progression is
3 3
A) if n is odd B) if n is even
2n 2n
3n 3n
C) if n is even D) 2 n 2 1 if n is odd
n 1
2

52. Numbers are selected at random one at a time, from the number 00,01,02 99 with
replacement. An event E occurs if and only if the product of two digits of a selected
number is 18. If the four numbers are selected, then the probability that E occurs at
least 3 times
97 86 93 96
A) B) C) D)
390625 390625 390625 390625
53. Two persons A and B agree to meet at a place between 10 am to 11 am. The first one
to arrive waits for 10 minutes and then leave. If the time of the arrival be independent
and random, then is the probability that A and B meet is
5 11 4 1
A) B) C) D)
9 36 9 3

ADV_(2011_P1)_PTA-16
SECTION-2
SectionII(MultipleCorrectAnswersType,TotalMarks:16)contains4multiplechoicequestions.Each
questionhasfourchoices(A),(B),(C)and(D)outofwhichONEorMOREmaybecorrect.Foreach
questionyouwillbeawarded4marksifyoudarkenALLthebubble(s)correspondingtothecorrect
answer(s)ONLYandzeromarksotherwise.Therearenonegativemarksinthissection.
54. Let A and B are two events such that P A 3 / 4 P B 5 / 8 then
A) P A B 3/ 4 B) P A B 1/ 4
C) 3 / 8 P A B 5 / 8 D) 1/ 8 P A B 3/ 8
55. Probability of n heads in 2n tosses of a fair coin can be given by
n
Cr
n 2
2
n
2r 1 n
nr n
Cr
n
A) r1 B) r1 C) D) r 0
2n
2r 2r r 0 2n

r 0
2n
Cr
56. One of 10 keys open the door. If we try the keys one after the other then
1
A) Probability that the door opened in the first attempt is
10
1
B) Probability that the door opened in the second attempt is
10
1
C) Probability that door opened in 10th attempt is
10
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D) Probability that the door opened in 5th attempt is 1/3
57. A rifleman is firing at a distant target and has only 10% chance of hitting it(
log10 3 0.4771 ), then which of the following are correct?
A) The number of rounds required in order to have more then 50% chance to hit the
target atleast once is 7.
81
B) When two attempts are made, the probability that both are failures is
100
C) When two attempts are made, the probability of hitting the target at least once is
21
100
D) When two attempts are made, the probability to hit the target exactly one time is
18
100

ADV_(2011_P1)_PTA-16
SECTION-3
SectionIII(ParagraphType,TotalMarks:15)contains2paragraphs.Basedupononeoftheparagraphs
2multiplechoicequestionsandbasedontheotherparagraph3multiplechoicequestionshavetobe
answered.Eachofthesequestionshasfourchoices(A),(B),(C)and(D)outofwhichONLYONEis
correct.Foreachquestionyouwillbeawarded3marksifyoudarkenONLYthebubblecorrespondingto
thecorrectanswerandzeromarksifnobubbleisdarkened.Inallothercases,minusone(1)markwill
beawarded.
Paragraph-I:
A circle of radius r touches the lines x 2 4 xy y 2 0 at A,B whose centre is C in
first quadrant (O is origin).
58. If a point is selected in quadrilateral OACB, then the probability that the point is
from the smaller sector CAB is

A) B) C) D)
2 3 3 3 3 3

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59. A point is selected from the quadrilateral OACB and it is known that the point is
selected from the le OAC , then the probability that the point lies in le ABC is
1 1 3 2
A) B) C) D)
3 4 8 3
PASSAGE-II
Each face of cubical die is marked with different letters of the word SINDHU. The die
is rolled 12 times and letters on the upper face of the die are noted.
60. What is the probability of getting the letters to form the word SINDHU one time (Not
necessarily in order)?
362 461 231 361
A) B) C) D)
3094 6188 3094 6188
61. What is the probability of getting the letters to form the word SINDHU two times
(Not necessarily in order)?
1 1 1 2
A) B) C) D)
3094 6188 1547 1547
62. What is the probability of getting the letters, not to form the word SINDHU (Not
necessarily in order)?

ADV_(2011_P1)_PTA-16
2863 462 4613 3612
A) B) C) D)
3094 3094 6188 6188
SECTION-4
questionsisasingledigitinteger,rangingfrom0to9.Thebubblecorrespondingtothecorrectansweris
tobedarkenedintheORS.Foreachquestionyouwillbeawarded4marksifyoudarkenONLYthe
bubblecorrespondingtothecorrectanswerandzeromarksotherwise.Therearenonegativemarksin
thissection.
63. A bag contains n white and n black balls, pairs of balls are drawn without
replacement until the bag is empty. The probability that each pair contains one white,
2
one black is then n
5
64. A bag contains a white and b black balls. Two players A and B alternately draw a
ball from the bag replacing the ball each time after the draw till one of them draws a

ADV_(2011_P1)_PTA-16
white ball and wins the game. If A begins the game then probability of A winning is
a
three times that of B then is__
b
65. A natural number x is chosen at random from first 100 natural numbers, then the
100 b
probability for the inequality x 50 to be true is then a b ___(H.C.F of a,b
x a
is1)
66. If a 0, 2 then find the probability that the graph of function
p
f x 16 x 2 8 a 5 x 13a 23 is strictly above the x-axis is then pq
q
(H.C.F of p,q is1)
67. In a 3 3 matrix the entries aij are randomly selected from the digits {0,1,2 __9} with
replacement. The probability that the numbers of the form xyz where x,y,z are the
7 K1.13K 2
elements in each row will be divisible by 11 is then K1 K 2 ____
109
68. Two number x, y are chosen at random from the numbers 1,2,3,4,5,6,7,8,9. Then the
a b
probability that x3 y 3 is divisible by 3 is (H.C.F of a,b is1) then =______
b a
69. 64 players play in a knockout tournament. Assuming that all the players are of equal
1
strength, the probability that P1 loses to P2 and P2 becomes the eventual winner is ,
abc
where abc is a three digited number, then a b c is

3

SR - Iit-Z (Iz) Co-Spark Jee Adv Pta-16 (2011 p1) Q'paper

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NARAYANA IIT ACADEMY

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 2

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 3

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 4

CH3 CH CH2CH3 in all cases

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 5

5. If all benzenoid aromatic carbonyl compounds having formula C8 H 8O react with

how many distinct products (saturated) are possible ?

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 6

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 7

9) Fehling solution gives red precipitate with:

10) Consider the following reaction

The conversion of aldehyde having no alpha hydrogen to a mixture of carboxylic acid

this reaction is the conjugate base of hydrate of aldehyde.

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 9

12. Which step is rate determining step

A) Step-I B) Step-II C) Step-III D) Step-I and II both

13. In the given reaction final product is

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 10

Sr.IIT-Z(IZ)_P1_Advanced space for rough work Page 11

14) Structure of molecule B is

16) Identify the incorrect statement

A) Structure of E is identical to B B) Structure of A is

CH 3CH 2COCH 2CH 3

18) Which of the following will give positive Fehlings test

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d ) HCOOH e) CH 3COCOCH 3 f ) CH 3CH (OH )COCH 3

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wavelength of the incident electrons to the shortest wavelength of X-rays produced is

hydrogen atom is proportional to

number of possible elements would be

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D) C and K both decrease but K C remains unchanged

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Assuming Bohrs model to be applicable, it is found that r is proportional to n x ,

where n is the principal quantum number. Find the value of x.

number of the element which emits K photon of wavelength 4 . (Assume screening

number for K transition is equal to 1)

insulating thread in free-space. It is under continuous illumination of 200nm

( where 1 A 10 . The value of Z is (Neglect electron cloud around the sphere)

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where abc is a three digited number, then a b c is

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