ekad

fok; dksM iqfLrdk dksM

H 2016 (I)
A
jlk;u foKku 1
Lke; : 3:00 ?kaVs
izu i= Ikw.kkZad : 200 vad

vuqnsk

1. vkius fgUnh dks ek/;e pquk gS A bl ijh{kk iqfLrdk esa ,d lkS iSarkyhl (20 Hkkx 'A'esa + 50 Hkkx
'B' + 75 Hkkx 'C' esa ) cgqy fodYi izu (MCQ)fn, x, gSa A vkidks Hkkx 'A' esa ls vf/kdre 15
vkSj Hkkx 'B' esa 35 izuksa rFkk Hkkx 'C' esa Lks 25 izuksa ds mRrj nsus gSa A ;fn fu/kkZfjr Lks vf/kd
izuksa ds mRrj fn, x, rks dsoy Hkkx 'A' Lks 15,Hkkx 'B' ls 35 rFkk Hkkx 'C' ls 25 igys mRrjksa dh
tkap dh tk,xh A
2. vks,evkj mRrj i=d vyx Lks fn;k x;k gS A viuk jksy uEcj vkSj dsUnz dk uke fy[kus Lks igys
;g tkap yhft, fd iqfLrdk esa i`B iwjs vkSj lgh gSa rFkk dgha Lks dVs&QVs ugha gSa A ;fn ,slk gS rks
vki bfUothysVj Lks mlh dksM dh iqfLrdk cnyus dk fuosnu dj ldrs gSa A blh rjg Lks
vks,evkj mRrj i=d dks Hkh tkap ysa A bl iqfLrdk esa jQ dke djus ds fy, vfrfjDr iUus
layXu gSa A
3. vks,evkj mRrj i=d ds i`B 1 esa fn, x, LFkku ij viuk jksy uEcj] uke rFkk bl ijh{kk
iqfLrdk dk ekad fyf[k,] lkFk gh viuk gLrk{kj Hkh vo'; djsa A
4. vki viuh vks,evkj mRrj i=d esa jksy uacj] fok; dksM] iqfLrdk dksM vkSj dsUnz dksM ls
lacaf/kr leqfpr o`rksa dks dkys ckWy isu ls vo; dkyk djsaA ;g ,d ek= ijh{kkFkhZ dh ftEesnkjh gS
fd og vks,evkj mRrj i=d esa fn, x, funsZ kksa dk iwjh lko/kkuh ls ikyu djsa] ,slk u djus ij
dEI;wVj fooj.kksa dk lgh rjhds Lks vdwfVr ugha dj ik,xk] ftlls varr% vkidks gkfu] ftlesa
vkidh vks,evkj mRrj i=d dh vLohd`fr Hkh kkfey gS] gks ldrh gS A
5. Hkkx 'A' rFkk Hkkx 'B' esa izR;sd izu ds 2 vad 'C' esa izR;sd izu 4 vad dk gS A izR;sd xyr mRrj
dk _.kkRed ewY;kad 25 % dh nj ls fd;k tk,xk A
6. izR;sd izu ds uhps pkj fodYi fn, x, gSa A buesa Lks dsoy ,d fodYi gh lgh vFkok loks ZRre
gy gS A vkidks izR;sd izu dk lgh vFkok loksRZ re gy <wa<uk gS A
7. udy djrs gq, ;k vuqfpr rjhdksa dk iz;ksx djrs gq, ik, tkus okys ijh{kkfFkZ;ksa dk bl vkSj
vU; Hkkoh ijh{kkvksa ds fy, v;ksX; Bgjk;k tk ldrk gS A
8. ijh{kkFkhZ dks mRrj ;k jQ iUuksa ds vfrfjDr dgha vkSj dqN Hkh ugha fy[kuk pkfg, A
9. dsydwysVj dk mi;ksx djus dh vuqefr ugha gS A
10. ijh{kk lekfIr ij fNnz fcUnq fpfUgr LFkku ls OMR mRrj i=d dks foHkkftr djsaA bfUothysVj dks
ewy OMR mRrj i=d lkSaius ds ipkr vki bldh dkWcZuySl izfrfyfi ys tk ldrs gSaA
11. fgUnh ek/;e@laLdj.k ds izu esa folaxfr gksus@ik;s tkus ij vaxzsth laLdj.k izekf.kd gksxk A
12. dsoy ijh{kk dh iwjh vof/k rd cSBus okys ijh{kkFkhZ dks gh ijh{kk iqfLrdk lkFk ys tkus dh
vuqefr nh tk,xh A

jksy uacj
ijh{kkFkhZ }kjk Hkjh xbZ tkudkjh dks eSa lR;kfir djrk gw A

uke ................................
bfUothysVj ds gLrk{kj
 2

FOR ROUGH WORK

 3

LIST OF THE ATOMIC WEIGHTS OF THE ELEMENTS

Element Symbol Atomic Atomic Element Symbol Atomic Atomic

Number Weight Number Weight
Actinium Ac 89 (227) Mercury Hg 80 200.59
Aluminium Al 13 26.98 Molybdenum Mo 42 95.94
Americium Am 95 (243) Neodymium Nd 60 144.24
Antimony Sb 51 121.75 Neon Ne 10 20.183
Argon Ar 18 39.948 Neptunium Np 93 (237)
Arsenic As 33 74.92 Nickel Ni 28 58.71
Astatine At 85 (210) Nlobium Nb 41 92.91
Barium Ba 56 137.34 Nitrogen N 7 14.007
Berkelium Bk 97 (249) Nobelium No 102 (253)
Beryllium Be 4 9.012 Osmium Os 76 190.2
Bismuth Bi 83 208.98 Oxygen O 8 15.9994
Boron B 5 10.81 Palladium Pd 46 106.4
Bromine Br 35 79.909 Phosphorus P 15 30.974
Cadmium Cd 48 112.40 Platinum Pt 78 195.09
Calcium Ca 20 40.08 Plutonium Pu 94 (242)
Californium Cf 98 (251) Polonium Po 84 (210)
Carbon C 6 12.011 Potassium K 19 39.102
Cerium Ce 58 140.12 Praseodymium Pr 59 140.91
Cesium Cs 55 132.91 Promethium Pm 61 (147)
Chlorine Cl 17 35.453 Protactinium Pa 91 (231)
Chromium Cr 24 52.00 Radium Ra 88 (226)
Cobalt Co 27 58.93 Radon Rn 86 (222)
Copper Cu 29 63.54 Rhenium Re 75 186.23
Curium Cm 96 (247) Rhodium Rh 45 102.91
Dysprosium Dy 66 162.50 Rubidium Rb 37 85.47
Einsteinium Es 99 (254) Ruthenium Ru 44 101.1
Erbium Er 68 167.26 Samarium Sm 62 150.35
Europium Eu 63 151.96 Scandium Sc 21 44.96
Fermium Fm 100 (253) Selenium Se 34 78.96
Fluorine F 9 19.00 Silicon Si 14 28.09
Francium Fr 87 (223) Silver Ag 47 107.870
Gadolinium Gd 64 157.25 Sodium Na 11 22.9898
Gallium Ga 31 69.72 Strontium Sr 38 87.62
Germanium Ge 32 72.59 Sulfur S 16 32.064
Gold Au 79 196.97 Tantalum Ta 73 180.95
Hafnium Hf 72 178.49 Technetium Tc 43 (99)
Helium He 2 4.003 Tellurium Te 52 127.60
Holmium Ho 67 164.93 Terbium Tb 65 158.92
Hydrogen H 1 1.0080 Thallium Tl 81 204.37
Indium In 49 114.82 Thorium Th 90 232.04
Iodine I 53 126.90 Thulium Tm 69 168.93
Iridium Ir 77 192.2 Tin Sn 50 118.69
Iron Fe 26 55.85 Titanium Ti 22 47.90
Krypton Kr 36 83.80 Tungsten W 74 183.85
Lanthanum La 57 138.91 Uranium U 92 238.03
Lawrencium Lr 103 (257) Vanadium V 23 50.94
Lead Pb 82 207.19 Xenon Xe 54 131.30
Lithium Li 3 6.939 Ytterbium Yb 70 173.04
Lutetium Lu 71 174.97 Yttrium Y 39 88.91
Magnesium Mg 12 24.312 Zinc Zn 30 65.37
Manganese Mn 25 54.94 Zirconium Zr 40 91.22
Mendelevium Md 101 (256)
*Based on mass of C12 at 12.000 . The ratio of these weights of those on the order chemical scale (in which oxygen of natural
isotopic composition was assigned a mass of 16.0000) is 1.000050. (Values in parentheses represent the most stable known
isotopes)
 4

m
s s 0s
h s 0s
e
s s
s 0s
k
c s s
1eV
amu
G
R
y 0s
NA s
0s

R 0s

USEFUL FUNDAMAENTAL CONSTANTS

m Mass of electron
h Planck's constant
e Charge of electron
k Boltzmann constant
c Velocity of Light
1eV
amu
G
Ry Rydberg constant
NA Avogadro's number

R Molar Gas constant

 5

Hkkx \PART 'A' 1.

3. :
2. s
4.
0

3. For a certain regular solid: number of faces +

1. s s0 number of vertices = number of edges+2. For
three such distinct (not touching each other)
s0 s s
objects, what is the total value of faces +
s0 6 vertices edges?
s ? 1. Two 2. Four
3. Six 4. Zero
1. s 0s0s
2. 6 0s0s
4. s 0ss?
3. s0s
4. s0s

1. It takes 2 hours for Tiwari and Deo to do a job.

Tiwari and Hari take 3 hours to do the same
job. Deo and Hari take 6 hours to do the same
job. Which of the following statements is
incorrect?
1. Tiwari alone can do the job in 3 hours
2. Deo alone can do the job in 6 hours
3. Hari does not work at all
4. Hari is the fastest worker
4. What will be the next figure in the following
2.
d , d s 0 d sequence?
s s
d s
1/3 s 0 s 1/2 0
s s s
s ?
1.
d
2. 0
3.
4. s

2. Abdul travels thrice the distance Catherine 5. d A, B, C, D , s AB=5

travels, which is also twice the distance that ., BC=12 ., AC=13 . AD=7 .
Binoy travels. Catherines speed is 1/3 of
Abduls speed, which is also 1/2 of Binoys CD ss :
speed. If they start at the same time then who 1. 9 . 2. 10 .
reaches first? 3. 11 . 4. 14 .
1. Both Abdul and Catherine
2. Binoy
5. A, B, C, D are points on a circle with AB=5
3. Catherine
cm, BC=12 cm, AC=13 cm and AD=7cm.
4. All threetogether
Then, the closest approximation of CD is
1. 9 cm 2. 10 cm
3. 0s: 3. 11 cm 4. 14 cm

0s + 0s =
0s+2
s
(
6. s 0s s 0
)sd
0s+ sd 40 s
0s 0s,? s d 28
0s
 6

s
s s s s 8. A frog hops and lands exactly 1 meter away at
a time. What is the least number of hops
s s s s
required to reach a point 10 cm away?
1. 1
1. 5478 2. 5748 2. 2
3. 8745 4. 8475 3. 3
4. It cannot travel such a distance
6. Choose the four digit number, in which the
product of the first & fourth digits is 40 and the 9. s36 /s ds
product of the middle digits is 28. The
thousands digit is as much less than the unit 8
s s 20
digit as the hundreds digit is less than the tens
s s
s
digit. ?
1. 5478 2. 5748
3. 8745 4. 8475 1. 120 . 2. 280 .
3. 40 . 4. 160 .
7. sd d

s0
d ss0s0s s0s
9. A train running at 36 km/h crosses a mark on
the platform in 8 sec and takes 20 sec to cross
sds ? the platform. What is the length of the
platform?
1. 120 m 2. 280 m
3. 40 m 4. 160 m

10. d 0s 0s
s1ss

0d-ss ?
1.
2.
1. 2 : 1 2. 3 : 4
3. 4 : 1 4. 8 : 1 3.
4.
7. Equilateral triangles are drawn one inside the
other as shown. What is the ratio of the two
shaded areas? 10. When a polynomial is divided by
or or it leaves a remainder of 1.
Which of the following would be the
polynomial?
1.
2.
3.
4.
1. 2 : 1 2. 3 : 4
3. 4 : 1 4. 8 : 1
11. s s d
8. s 1 0 s -
s s 10 s 0s0s s
. d d s
s0s

? 1.
s
2. ss ss
1. 1
2. 2 sss
3. 3
4. 0s
 7

3. d0ss : 1. 40.0 2. 29.4

3. 19.4 4. 11.3

sss
4. ssss 13. d ds AC d D
ss ssss s ,dsBD s
(.)
11. Water is slowly dripping out of a tiny hole at
the bottom of a hollow metallic sphere initially
full of water. Ignoring the water that has
flowed away, the centre of mass of the system
1. remains fixed at the centre of the sphere
2. moves down steadily as the amount of
water decreases
3. moves down for some time but eventually
returns to the centre of the sphere
4. moves down until half of the water is lost
and then moves up
1. 8 2. 6
12. ss s s ss 0.5 . 3. 3 4. 4
s s s 0.1 . s s
13. D is a point on AC in the following triangle
0s ,s 0
d s such that . Then BD (in cm) is
0(sds)s0 0
ss s , s s
0(. )ss?

1. 8 2. 6
3. 3 4. 4

14. ss0s0s
1. 40.0 2. 29.4
3. 19.4 4. 11.3 sssss
0
12. The diagram (not to scale) shows the top view
and cross section of a pond having a square
outline and equal sized steps of 0.5 m width
and 0.1m height. What will be the volume of
water (in m3) in the pond when it is completely
filled?

1. 2.
3. 4.
 8

14. The function is plotted against as 16. A chocolate bar having unit square tiles
shown. Extrapolate and find the value of the is given. Calculate the number of cuts needed
function at . to break it completely, without stacking, into
individual tiles.
1.
2.
3.
4.

17. 0d02s0
R% s 0 (R+10)%

1. 2. 0 s ds 0s 0 d
3. 4. s s s 0 s (R+5)% s
0 ?
15. d : 1. Rs 2.5 lakhs
1.
d 1 0 2. Rs 3.0 lakhs
3. Rs 4.0 lakhs
2.
d 2 0 4. Rs 5.0 lakhs
.
.
.
17. A person paid income tax at the rate of R% for
99 d 99 0 the first Rs 2 lakhs, and at the rate of (R+10)%
100 d 100 0 for income exceeding Rs 2 lakhs. If the total
tax paid is (R+5)% of the annual income, then
s ? what is the annual income ?
1. Rs 2.5 lakhs
1. s 2. s 2. Rs 3.0 lakhs
3.
0ss 4.
s 3. Rs 4.0 lakhs
4. Rs 5.0 lakhs
15. A notebook contains only hundred statements
as under: 18. 0 0
1. This notebook contains 1 false statement. ss00
d
0
d s
2. This notebook contains 2 false statements.
. s0sss
.
. 0 1 2 3 4 5 6
99.This notebook contains 99 false statements. 5 6.1 9.1 13.7 20.6 30.8 41.4
100. This notebook contains 100 false
statements. s0d0 d

-s0 s s
Which of the statements is correct? s
1. 100th 2. 1st
1.
3. 99th 4. 2nd 2.
3.
16. s s s 4.

s

18. An experiment leads to the following set of
, s ,
observations of the variable at different
sss,s0 times .
1.
2. 0 1 2 3 4 5 6
3. 5 6.1 9.1 13.7 20.6 30.8 41.4
4.
 9

Allowing for experimental errors, which of the

following expressions best describes the Hkkx \PART 'B'
relationship between and
1.
2. 21. s18
0sd:
3.
4.

19. s
d 0d (
)s
899 d sd0
s0d
1. sss
2. 27
3. 29
4. 31
1. A s B 2. B s C
19. The difference between the squares of the ages 3. C s D 4. A s D
(in complete years) of a father and his son is
899. The age of the father when his son was
born 21. Identify the species, those obey the 18
1. cannot be ascertained due to inadequate data. electron rule, from the following:
2. is 27 years.
3. is 29 years.
4. is 31 years.

20. s0s0200 .
s 0dss0s6 .
0sd0
s ,

sss
0(. )s0?
1. 600
2. 1200
3. 3600 1. A and B 2. B and C
4. 1800 3. C and D 4. A and D

20. A bicycle tube has a mean circumference of

200 cm and a circular cross section of diameter 22. s
6 cm. What is the approximate volume of water
(in cc) required to completely fill the tube,
assuming that it does not expand?
1. 600
2. 1200
3. 3600
4. 1800
ss ,
 10

1. s0 25. CpM [Cp is (5-C5H5)] fragment isolobal with

a BH fragment is
2.
1. CpGe 2.CpMn
3. -ss 3. CpRu 4.CpCo
4. s0
26. [Co2Fe2(CO)11(-PPh)2] sd-sd
22. The following transformation
0s
1. 3 2.4
3. 5 4.6

26. The number of metal-metal bonds in

[Co2Fe2(CO)11(-PPh)2] is
is an example of 1. 3 2.4
1. oxidative addition 3. 5 4.6
2. insertion
3. -hydride elimination
4. reductive elimination 27. B2 d s* s
0
23. [NiIIL6]n+ or n-
8500, 15400, s
26000 cm1 ss [NiIIL6]n+ or n-
, *
10750, 17500, s28200 cm 1
ss L 1.
sL ,: 2.
1. OH s N3

3.
2. Cl s I

4.
3. NCS sRCO2

4. H2O sNH3
27. Correct combination for and * orbitals in
B2 molecule is
23. [NiIIL6]n+ or n- shows absorption bands at 8500,
15400, and 26000 cm1 whereas [NiIIL6]n+ or n-, *
at 10750, 17500, and 28200 cm1. L and L 1. Gerade Ungerade
are respectively, 2. Ungerade Gerade
1. OH and N3 3. Gerade Gerade
2. Cl and I 4. Ungerade Ungerade
3. NCS and RCO2
4. H2O and NH3
28. VSEPR ss[TeF5] 0
24. 3
F s 0s
,
1. 3 2.21
3. 9 4.28 1. s
2. 0

24. The number of microstates present in F term 3 3. s0

is 4. d
1. 3 2.21
3. 9 4.28
28. The correct shape of [TeF5] ion on the basis
25. BH CpM [Cp is ( -C5H5)] 5
of VSEPR theory is
1. Trigonal bipyramidal
1. CpGe 2.CpMn 2. Square pyramidal
3. CpRu 4.CpCo 3. Pentagonal planar
4. See-saw
 11

29. P-S sP-P 0s0P4S3 33. 0 POCl3 0 s

: ss0sss0 s
1. 6 s 3 2.4 s 3 ,
3. 3 s 6 4.6 s 2 1. Et3N 2.KCl
3. FeCl3 4.SbCl5
29. The numbers of P-S and P-P bonds in the
33. The compound which dissolves in POCl3 to
compound P4S3 are, respectively,
give a solution with highest chloride ion
1. 6 and 3 2.4 and 3
concentration, is
3. 3 and 6 4.6 and 2
1. Et3N 2.KCl
3. FeCl3 4.SbCl5
30. 0 s0 (Na2S2O3) , 0
s 0 0
d s 34. d ; d
0.1 M s 25 mL x M O2 s 0-


s0
25 mL 0s s ,
x ss
1. 0.2 2.0.1
3. 0.6 4.0.4

30. In the iodometric titration of sodium thiosul-

fate (Na2S2O3) with acidic dichromate solution,
25 mL of 0.1 M dichromate requires 25 mL of
x M thiosulfate. The value of x is
1. 0.2 2.0.1
3. 0.6 4.0.4
34. In the absence of bound globin chain, heme
31. CaCO3 sss group on exposure to O2 gives the iron-oxygen
s 0 s s, species

1. s
2.
3. O2 sCOs1:1
4.

31. Decomposition temperature of CaCO3 in

thermogravimetric analysis will be highest in
dynamic atmosphere of
1. nitrogen 35. s0 d [UO2(NO3)3]
2. synthesis gas
0
0ss0s:
3. 1:1 mixture of O2 and CO 1. 8 s0
4. water gas
2. 5 s 0
32. 56Ba
131

s 3. 8 s
s 4. 5 s ss
1. 54Xe131 2.54Xe 130

3. 56Ce131 4.56Ce130 35. For monoionic complex [UO2(NO3)3], the

correct coordination number and geometry
32. On two sequential electron capture, 56Ba131 respectively, are
will give 1. 8 and hexagonal bipyramidal
1. 54Xe131 2.54Xe130 2. 5 and square pyramidal
3. 56Ce 131
4.56Ce130 3. 8 and square antiprism
4. 5 and trigonal bipyramidal
 12

36. s 38. 0s d0s

1.
d
0 s
2. d
0
s s
3. 0s
4.
s
s s
0ss

36. Chelate effect is

1. predominantly due to enthalpy change 1. 2.
2. predominantly due to entropy change
3. independent of ring size
4. due to equal contribution of entropy
and enthalpy change

37. 0s d0s 3. 4.

1.

2. 38. The major product formed in the following

reaction is

3.

4.

37. The major product formed in the following 1. 2.

reaction is

1. 3. 4.

2.
39. 0s d0s

3.

4.
 13

41. Myrtenal1H NMR d

1. 2. ss , /
(ss0 s()ppm )

3. 4.

39. The major product formed in the following

reaction is 1. 1.35 (s, 3H) s 5.0 (s, 3H)
2. 0.74 (s, 3H) s 1.33 (s, 3H)
3. 1.22 (s, 6H)
4. 0.70 (s, 6H)

41. In the 1H NMR spectrum of myrtenal, the two

methyl groups are expected to display signals
1. 2. at (chemical shift values () in ppm)

3. 4.

40. ,0IR 2150

cm1 ss , 1. 1.35 (s, 3H) and 5.0 (s, 3H)
2. 0.74 (s, 3H) and 1.33 (s, 3H)
3. 1.22 (s, 6H)
4. 0.70 (s, 6H)
1. 2.

42. 0/0 s
3. 4.

0d

0s s s ,
/

40. Among the following, the compound that

displays an IR band at 2150 cm1 is

1. 1. 2.

1. A sB 2.A
3. 4. 3. B 4.B s C
 14

42. Among the following, the compound(s) that 3.

can be classified as terpene derivative is(are)

4.

1. A and B 2.A only

3. B only 4.B and C
44. The major product formed in the following
43. 0 HCl 0s , reaction is
ss0 0
0
0
0 0s
,
1. s s HCls*
2. s s HCls
3. s s HCls*
1.
4. s s HCls

43. The frontier orbital interactions involved in

the formation of the carbocation intermediate
in the reaction of isobutylene with HCl are 2.
1. of olefin and * of HCl
2. of olefin and of HCl
3. of olefin and * of HCl
4. of olefin and of HCl
3.
44. 0s d0s

4.

45. ,- s 0 UV-visible
1.

s0 ds s

1. n-* hypsochromic
2. , -* bathochromic
2. n-* bathochromic
,- * hypsochromic
 15

3. n-* s-* batho- 1.

chromic
4. n-* s-* hypso-
chromic
2.

45. In the UV-visible absorption spectrum of an

, -unsaturated carbonyl compound, with
increasing solvent polarity, 3.
1. n-* transitions undergo hypsochromic
shift, -* undergo bathochromic shift
2. n-* transitions undergo bathochromic
shift, -* undergo hypsochromic shift
3. both n-* and -* transitions undergo 4.
bathochromic shift
4. both n-* and -* transitions undergo
hypsochromic shift

46. 0s d0s
47. 0 Ha sHb s

0s0s0 s ,

1.

2.

1. s
2. s
0s
3. 3.
0
4. s

s

47. In the following compound, the stereo-

chemical descriptor for Ha and Hb is
4.

46. The major product formed in the following

reaction is
1. enantiotopic
2. diasterotopic
3. homotopic
4. constitutionally heterotopic
 16

48. X sY NaNH2 0s 49. The correct statements about conformations X

and Y of 2-butanone are

A. X 0ss Y ds A. X is more stable than Y

B. Y is more stable than X
C. Methyl groups in X are anti
B. Y 0ss X
d s D. Methyl groups in Y are gauche
1. A and D 2.A and C
3. B and C 4.A, C and D
C. X sY s0s
D. X s
Y 50. s 0d 0 0

ds
s0 A s s s

1. A s C 2.A s D
3. B s C 4.B s D

48. The correct statements are about the reaction

of X and Y with NaNH2 are
1. Ph > CN > Me
2. Me > Ph > CN
3. CN > Me > Ph
4. Ph > Me > CN

A. X reacts faster than Y 50. The correct order of the magnitude of A

B. Y reacts faster than X values for the given substituents in
C. X and Y behave as Lewis acids cyclohexane derivatives is
D. X is stronger Bronsted acid than Y
1. A and C 2.A and D
3. B and C 4.B and D

49. 2-0
X s Y
1. Ph > CN > Me
2. Me > Ph > CN
3. CN > Me > Ph
4. Ph > Me > CN

51. 0 X, Y sZ pKa s s

A. YsXs0
B. XsYs0
C. X danti
D. Y dgauche
1. A sD 2.A sC 1. X>Y>Z 2.Y > Z > X
3. B sC 4.A, C s D 3. Z>X>Y 4.Y > X > Z
 17

51. The correct order of pKa values for the 53. The simultaneous eigenfunctions of angular
compounds X, Y and Z is momentum operators and are
1. all of and orbitals
2. only and orbitals
3. only and orbitals
4. only orbital

54.

1. X > Y > Z 2.Y > Z > X s s s0s

0
s
3. Z > X > Y 4.Y > X > Z
s
s
52. s
:
s ss
s 1. ss

s
2. ss

dss
3. s

1. 4 conrotatory s 6 conrotatory
d
2. 4 disrotatory s 6 conrotatory 4.


3. 4 conrotatory s 6 disrotatory d

4. 4 disrotatory s 6 disrotatory
54. An ideal gas is composed of particles of mass
in thermal equilibrium at a temperature in
52. The following transformation proceeds one container. Another container contains
through two consecutive electrocyclic ideal gas particles of mass at a
processes, which are temperature . The correct statement about
the two gases is:
1. average kinetic energy and average
speed will be same in the two cases.
2. both the averages will be doubled in
the second case.
3. only the average kinetic energy will be
1. 4 conrotatory and 6 conrotatory doubled in the second case.
2. 4 disrotatory and 6 conrotatory 4. only the average speed will be doubled in
3. 4 conrotatory and 6 disrotatory the second case.
4. 4 disrotatory and 6 disrotatory
55.
0s
s
2
1. D 2.5D
53. 0 s
1
3. P 4.1D

55. The lowest energy term for the
1. s configuration is
1. 2D 2.5D
2. s 3. P1
4.1D

56. 0s s :
3. s
s
s s
4.
s 0s n
(s
sss
0 ) s
 18

1. 58. The symmetry point group of the most stable

geometry of the following molecule
2. Cl(H)C=C=C(H)Cl is
1. 2.
3. 3. 4.

4. 59. 0
(s
56. If the rates of a reaction are and at s : s s s
concentrations and of a reactant )
respectively, the order of reaction,
n(assuming that the concentrations of all 1. s
other reactants and remain constant) with 2.
respect to that reactant is given by 3.
1. 4. s

2. 59. The eigenfunctions of the Hamiltonian

of a harmonic oscillator are
3. (where and are kinetic energy and
potential energy operators, respectively)
4. 1. eigenfunctions of as well as
2. eigenfunctions of , but not of
3. eigenfunctions of but not of
57. s0 s ss0 0s 4. eigenfunctions of neither nor
0
60. ds 0d
0s s ,
1. 1.
2.
3. 2.
4.
3.
57. Experimentally determined rate law for the
4.
chemical reaction
is sE dssemf sV ds
The rate determining step consistent with the
rate law is s0
1. 60. In a potentiometric titration, the end point is
2. characterised by
3. 1.
4.
2.
58. ds0s
d 3.
Cl(H)C=C=C(H)Cl
1. 2. 4.
3. 4.
where E is the emf of the titration cell and V is
the volume of the titrant added
 19

61. 0 s s 1. [010] s [011]

0 ss

d s 2. [010] s [110]
, 0 (b) 3. [001] s [101]
y-axis s ss (a) x-axis 4. [110] s [011]
0 s
0ss,
63. In a cubic crystal, the plane [100] is equally

inclined to the planes
1. [010] and [011]
2. [010] and [110]
3. [001] and [101]
4. [110] and [011]

64. 0ss0 s
E s
1. s
2. ss0s
s
61. On titrating conductometrically a 3. 0ss
solution with a mixture of and 4. 0ss
solutions, plot of the volume of mixed acid s
added (b) in y-axis against the conductance (a)
in x-axis is expected to look like
64. The standard electrode potential E at a fixed
temperature and in a given medium is
dependent on
1. only the electrode composition
2. the electrode composition and the
extent of the reaction
3. the extent of the electrode reaction
only
4. the electrode reaction and the electrode
composition

65. ds s s 0 0
62. s s s ds 0
1. s s0 : s s
2. 0 s
s d
3. s 1.
2.
4. sss 3.
4.
62. has the dimension of
65. In a titration, the percentage uncertainties in
1. pressure
the measured aliquot volume and the
2. volume
measured titre volume are and
3. temperature
respectively. The percentage error in the
4. heat capacity
calculated concentration of aliquot is
1.
63. 0 [100] s 2.
ssdss , 3.
4.
 20

1. (a)-(ii); (b)-(iii); (c)-(iv); (d)-(i);

66. 300K 2. (a)-(iv); (b)-(ii); (c)-(i); (d)-(iii);
1. 2. 3. (a)-(iii); (b)-(iv); (c)-(i); (d)-(ii);
4. (a)-(i); (b)-(ii); (c)-(iii); (d)-(iv).
3. 4.
69. Match the metal given in Column A with its
medicinal use as a compound in Column B.
66. For an ideal gas at 300K
1. 2. Column A Column B
(a) Gd (i) Cancer
(b) Au (ii) Maniac depression
3. 4. (c) Pt (iii) MRI contrast agent
(d) Li (iv) Arthritis

67. sd s Correct match is

1. 2. 1. (a)-(ii); (b)-(iii); (c)-(iv); (d)-(i);
3. 4.
2. (a)-(iv); (b)-(ii); (c)-(i); (d)-(iii);
3. (a)-(iii); (b)-(iv); (c)-(i); (d)-(ii);
4. (a)-(i); (b)-(ii); (c)-(iii); (d)-(iv).
67. The first excited state of hydrogen molecule is
1. 2. 70. pH 10 ss ,
3. 4.

1.
68. sssd s
s
d 0ss
1. ss s
2. s
3. dss
4. 2.

68. When river water containing colloidal clay

flows into the sea, the major cause of silting is
1. accumulation of sand at the bottom
2. flocculation and coagulation
3. decreased salinity of sea water
4. micellization
3.
69. A sd0sB
0 00

A B
(a) Gd (i)

(b) Au (ii) 4.
(c) Pt (iii) MRI s

(d) Li (iv) s

s
 21

70. At pH 10, tryptophan exists as 4 2

3. A2g Eg
2 4
1. 4. Eg A2g

72. sdss

s
d
1. F-C-F > F-C-O s C-F > C-O
2. F-C-F > F-C-O s C-F < C-O
2. 3. F-C-F < F-C-O s C-F > C-O
4. F-C-F < F-C-O s C-F < C-O

72. Choose the correct option for carbonyl fluoride

with respect to bond angle and bond length
1. F-C-F > F-C-O and C-F > C-O
2. F-C-F > F-C-O and C-F < C-O
3. F-C-F < F-C-O and C-F > C-O
3. 4. F-C-F < F-C-O and C-F < C-O

73. BrF3 s/AsF5

0ss /?
1. XeF6 2.XeF6 s XeF4
3. XeF6 s XeF2 4.XeF4 s XeF2

4.
73. Which of the following react(s) with AsF5 in
liquid BrF3?
1. XeF6 only 2.XeF6 and XeF4
3. XeF6 and XeF2 4.XeF4 and XeF2

74. 0ss?
N2O4
A NOCl + Sn

Hkkx \PART 'C' B NOCl + AgNO3

C NOCl + BrF3
D NOCl + SbCl5
71. sd[Cr(bipyridyl)3]3+, 0s0sd
0s[NO]+ ,
s
d s , 1. A sB 2. C s D
3. A s C 4. B s D
4 4
1. T2g A2g
4 4
2. T1g A2g 74. Consider the following reactions:
4 2 N2O4
3. A2g Eg A NOCl + Sn
2 4
4. Eg A2g B NOCl + AgNO3

71. Complex [Cr(bipyridyl)3]3+, shows red C NOCl + BrF3

phosphorescence due to transition D NOCl + SbCl5
4 4
1. T2g A2g
4 4 Reactions which will give [NO]+ as a major
2. T1g A2g product are:
 22

1. A and B 2. C and D 1. a > b > c 2. b > c > a

3. A and C 4. B and D 3. c > b > a 4. a > c > b

75. dd0 0s 78. Correct order of M-C bond length of

metallocenes (a-c)
ss , a. [Fe(5-Cp)2] b. [Ni(5-Cp)2]
1. [Cu(H2O)6]2+ 2.[Ni(H2O)6] 2+ c. [Co(5-Cp)2]is
3. [Co(H2O)6]2+ 4.[Cr(H2O)6] 2+
1. a > b > c 2. b > c > a
3. c > b > a 4. a > c > b
75. The complex that shows orbital contribution
to the magnetic moment, is
1. [Cu(H2O)6]2+ 2.[Ni(H2O)6] 2+ 79. 100 mL 0 Bi(III) s Cu(II)
3. [Co(H2O)6]2+ 4.[Cr(H2O)6] 2+
02.5 103 M ,s745 nm 0.1
M EDTA ss0 ds 0s 0s
76. KF, SnF4 sSbF5, 0 BrF3,
ds s
BrF4 sss s / , /
A. EDTA 0s0dd0
1. KF
5 mL
2. KF sSnF4
B. 3 mL EDTA Bi(III) ds
3. SnF4 s SbF5
s2 mL Cu(II)
4. KF, SnF4 s SbF5
0s

76. Among KF, SnF4 and SbF5, solute(s) that C.

0s
d 02.5 mL EDTA s
increase(s) the concentration of BrF4 in BrF3, 0s
is/are D. ds
Cu(II)
1. KF only
2.KF and SnF4 s
3. SnF4 and SbF5
4.KF, SnF4 and SbF5 1. A s B 2. A s C
3 A, B s C 4. B, C s D
77. KMnO4 106 cm3mol1
dd
0d sss , 79. A 100 mL solution of 2.5 103 M in Bi(III)
1. and Cu(II) each, is photometrically titrated at
2. d00
00s0s 745 nm with 0.1 M EDTA solution. Identify
correct statements for this titration.
3. dd0d A. Total volume of EDTA solution used is 5 mL
4. s

d
d B. 3 mL of EDTA is required to complex
Bi(III) and 2 mL for Cu(II)
77. Paramagnetic susceptibility of the order of C. 2.5 mL of EDTA is used for each metal ion
106 cm3mol1 observed for KMnO4 is due to D. First break in titration curve is for Cu(II)
1. random spin alignment Correct statements are
2. antiferromagnetic exchangeinteraction 1. A and B 2. A and C
3. paramagnetic impurity 3 A, B and C 4. B, C and D
4. temperature independent
paramagnetism 80. 10
B
ss10 m s
16 2 1

0 s
d s ,s3 %
78. (a-c) M-C ss
3 x 107 s 0ss 10B


0s d


a. [Fe(5-Cp)2] b. [Ni(5-Cp)2]
c. [Co(5-Cp)2] (barns )
1. 1000 2. 3000
3. 10,000 4. 30,000
 23

80. On continuous exposure of 10B sample to a 84. Al(BH4)3 3c-2e 0s

slow neutron flux of 1016 m2s1, its 3 % weight
1. s 2.
fraction disappears in 3 x 107 s. Cross section
for neutron capture (in barns) by 10B is 3. : 4.
0
1. 1000 2. 3000
3. 10,000 4. 30,000 84. The number of 3c-2e bonds present in
Al(BH4)3 is
81. [Ru(4-C8H8)(CO)3] 23 C , 1H 1. four 2. three
3. six 4. zero
NMR

ss
s
s (140 C) 85. 0 C2B3H5, C2B4H6, s B5H9


0s s
0s0:
1. 8 2. 6 1. 10, 12 s12 2.12, 14 s 14
3. 4 4. 2 3. 10, 12 s 14 4.12, 14 s 12

81. The 1H NMR spectrum of [Ru(4- 85. The numbers of skeletal electrons present in
C8H8)(CO)3] at 23 C consists of a sharp the compounds C2B3H5, C2B4H6, and B5H9
single line. The number of signals observed at are, respectively,
low temperature (140 C) in its spectrum is 1. 10, 12 and 12 2.12, 14 and 14
1. 8 2. 6 3. 10, 12 and 14 4.12, 14 and 12
3. 4 4. 2
86. VO(acac)2 [0 0s

82. Ce3+ (4f1) s Pr3+ (4f2) g s
0] 77 K EPR

:
[ I (51V) = 7/2] s
1. 3/7 s 2/5 2. 5/7 s 4/5
A. g 2s
3. 6/7 s 3/5 4. 6/7 s 4/5
B. 8 s
82. The g values for Ce3+ (4f1) and Pr3+ (4f2) are, C. g sss
respectively D. ,
0 8
1. 3/7 and 2/5 2. 5/7 and 4/5 s
3. 6/7 and 3/5 4. 6/7 and 4/5

83. Cu(II) d s s 1. A s D 2. A s C
d
0 (eff BM ) 1.73 3. B s C 4. B s D
0 0s0ss ,
86. Identify correct statements for the EPR
spectrum of VO(acac)2 [with square pyramidal

1. eff = s geometry at vanadium] at 77 K [ I (51V) =
2. eff = 7/2].
3. eff = A. It has two g values.
B. It has 8 lines only.
4. eff =
C. It has one g value.
D. It has two patterns of 8 lines each.
83. The room temperature magnetic moment (eff
in BM) for a monomeric Cu(II) complex is Correct statements are
greater than 1.73. This may be explained using 1. A and D 2. A and C
the expression: 3. B and C 4. B and D

1. eff = s
2. eff = 87. d Ph3P11BH3 1H s 11B NMR
3. eff =
BH3 s ss s0 0 s
4. eff =
0s : [I (11B) = 3/2; I (31P) = ]
1. 8 s 8. 2. 4 s 8.
3. 3 s 6. 4. 6 s 3.
 24

87. The numbers of lines shown by the BH3 part 3. s N-sd

of the molecule Ph3P11BH3 in the 1H and 11B
4. s0s O-sd
NMR spectra are, respectively [I (11B) = 3/2; I
(31P) = ]
1. 8 and 8. 2. 4 and 8. 90. In human body cis-platin hydrolyzes to a
3. 3 and 6. 4. 6 and 3. diaqua complex and modifies the DNA
structure by binding to
1. N-atom of guanine base
88. Fe s
s


2. O-atom of cytosine base
s X s 0 3. N-atom of adenine base
0s ss X, 00 s
(Y) 4. O-atom of thymine base

s - s s
91. s s Fe(CO)5 (s

0 X s Y
) 0 CO d s 0
:
0s
1. 57
Fe, -
2. 57
Co, - 2
3. 57
Co, e
CO 5
57
Fe, e CO
4.
1
OC Fe
88. To record Mssbauer spectrum of Fe 4
containing samples, a source X is used. X 3 CO
after a nuclear transformation (Y), gives - CO
radiation used in Mssbauer spectroscopy. X
and Y respectively, are 1. 2 s 5; 3 s 4
1. 57Fe, -emission 2. 2 s 3; 4 s 5
2. 57Co, -emission
3. 57Co, e capture 3. 2 s 3; 1 s 5
4. 57Fe, e capture. 4. 1 s 2; 4 s 5

89. sd 0- d (sd 0 91. For fluxional Fe(CO)5 (structure given below)

s 0 ) 0 in solution, the exchange of numbered CO
groups will be between
0sss0
1. s5-00ss6-00 2
2. 5-00s: 6-
00 CO 5
3. :5-00s6-00 CO
1
4. s5-00s6-00 OC Fe
4
3 CO
89. Correct combination of number and size of
rings present in a metal ion-porphine complex CO
(including metal ion bearing chelate rings) is
1. four 5-membered and four 6-membered 1. 2 and 5; 3 and 4
2. two 5-membered and six 6-membered 2. 2 and 3; 4 and 5
3. six 5-membered and two 6-membered 3. 2 and 3; 1 and 5
4. five 5-membered and three 6-membered 4. 1 and 2; 4 and 5

90. s cis-
92. 0s
ss d DNA s

,
1. ssN-sd
sdtc = s0sss
2. ss O-sd
tds = s0 s
s
 25

P, R sS s Cp = 5-C5H5 CO Li CO
CO CO
O OCH3
1. OC Cr C and OC Cr C
P R S OC C6H5 OC C6H5
1. Et2dtcK+ Et4tds CpMo(Et2dtc)(CO)2 CO CO
2. EtdtcK+ Et3tds CpMo(Et3dtc)(CO)2
CO Li CO
3. Et4dtcK+ Et2tds CpMo(Et4dtc)(CO) CO CO
4. EtdtcK+ Ettds CpMo(Etdtc)(CO) 2. OC Cr C6H5 and OC Cr CH3
OC OC
92. In the following reaction sequence CO CO
CO Li CO
CO CO
OC6H5
where dtc = dithiocarbamate and tds = 3. OC Cr C C6H5 and OC Cr C
thiuramdisulfide. OC OC CH3
CO O CO
Identify P, R and S. Cp = 5-C5H5 CO CO
Li CO
CO OC6H5
and OC Cr C
P R S 4. OC Cr C6H5
OC CH3
1. Et2dtcK+ Et4tds CpMo(Et2dtc)(CO)2 OC
CO CO
2. EtdtcK+ Et3tds CpMo(Et3dtc)(CO)2
3. Et4dtcK+ Et2tds CpMo(Et4dtc)(CO)
4. EtdtcK+ Ettds CpMo(Etdtc)(CO)
94. [(5-C5H5)Mo(CO)3]2
[(5-C5H5)Mo(CO)2]2 s CO 2
93. Cr(CO)6 LiC6H5 0s A d
0
s s
[Me3O][BF4] A0sB s A 0s MoMo

sB s0: s ,
1. 2 3 2. 1 2
CO Li CO 3. 1 3 4. 2 4
CO CO
O OCH3
1. OC Cr C and OC Cr C 94. Heating a sample of [(5-C5H5)Mo(CO)3]2 results
OC C6H5 OC C6H5 in the formation of [(5-C5H5)Mo(CO)2]2 with
CO CO
elimination of 2 equivalents of CO. The MoMo
CO Li CO bond order in this reaction changes from
CO CO
and OC 1. 2 to 3 2. 1 to 2
2. OC Cr C6H5 Cr CH3
3. 1 to 3 4. 2 to 4
OC OC
CO CO
CO 95. C6H5CC-C6H4 -p-Me [(tBuO)3WCtBu]
CO Li
CO CO
OC6H5
000s
3. OC Cr C C6H5 and OC Cr C
0d0d0
OC OC CH3
CO O CO

CO CO
Li CO
CO OC6H5
and OC Cr C
4. OC Cr C6H5
OC OC CH3
CO CO

93. Reaction of Cr(CO)6 with LiC6H5 gives A

which reacts with [Me3O][BF4] to give B. The
structures of A and B respectively, are
 26

1. 2.

3. 4.

95. A plausible intermediate involved in the self

metathesis reaction of C6H5CC-C6H4 -p-Me
catalyzed by [(tBuO)3WCtBu] is
97. 0s d0

t

s
C6H4-p-Me Bu

C C
t t
1. ( BuO)3W
t
C Bu 2. ( BuO)3W C C6H4-p-Me

C C

C6H5 C6H5

t C6H5
Bu

C t
Bu C
C C6H4-p-Me
4. ( BuO)3W
t 1. 2.
3. (tBuO)3W C
C C
C C6H4-p-Me

But C6H5 p-Me-C6H4 C6H5

3. 4.
96. 0s
d 0
s

97. The major product formed in the following

reaction sequence is

1. 2.

3. 4.

1. 2.

96. The major product formed in the following

reaction is

3. 4.
 27

98. 0s d0s 2.

3.

1.

4.

2.

99. 0s sA sB
3.

1.
4.

2.

3.

98. The major product formed in the following

reaction is
4.

99. The major products A and B in the following

reaction sequence are

1.
 28

1. 1.

2. 2.

3.
3.

4.
4.

100.
0s d
0

s 101. 0s sA sB

1.

1.

2.
2.

3.

3.

4.

4.

101. The major products A and B in the following

reaction sequence are
100. The major product formed in the following
reaction sequence is
 29

1. 3.

2. 4.

3. 103. 0ss
s0

4.

102. 0s d0s 1. i. NaBH4, CeCl3, MeOH, 0 oC;

ii. H2, [Ir(COD)(py)P(Cy)3]PF6;
iii. Ph3P, PhCO2H, DEAD;
iv. LiAlH4.
2. i. Li, NH3;
ii. H2, [Ir(COD)(py)P(Cy)3]PF6;
iii. Ph3P, PhCO2H, DIAD;
1. iv. NaBH4, CeCl3, MeOH, 0 oC.
3. i. H2, Pd/C; ii. LiAlH4, -78 oC.
4. i. H2, Pd/C; ii. Li, NH3.

2. 103. The correct reagent combination to effect the

following reaction is

3.

4.
1. i. NaBH4, CeCl3, MeOH, 0 oC;
ii. H2, [Ir(COD)(py)P(Cy)3]PF6;
iii. Ph3P, PhCO2H, DEAD; iv. LiAlH4.
2. i. Li, liquid NH3;
102. The major product in the following reaction is
ii. H2, [Ir(COD)(py)P(Cy)3]PF6;
iii. Ph3P, PhCO2H, DIAD;
iv. NaBH4, CeCl3, MeOH, 0 oC.
3. i. H2, Pd/C; ii. LiAlH4, -78 oC.
4. i. H2, Pd/C; ii. Li, liquid NH3.

104.
0sd
0
s
1.
A s B

2.
 30

1. 1.

2.
2.

3.
3.

4.
4.

105. Structures of the intermediate A and the major

product B in the following reaction sequence are
104. The major products A and B in the following
reaction sequence are

1.

1. 2.

3.
2.

4.
3.

106.
s P-S I-IV s
s
4.
Reactions

Q
105. 0s 0A s

d
0
sB s0
R
 31

Reactions
S
P

Q
0s: I. -
II. sI
III. s0 s R
s-
IV. sII S
1. P-II; Q-IV; R-III; S-I
2. P-II; Q-IV; R-I; S-II
3. P-IV; Q-II; R-III; S-I
4. P-IV; Q-II; R-I; S-III s s: I. s
II. Nazarov s
106. The correct match for the following transfor-
mations P-S with the processes I-IV is III. s
IV.
s
Reactions 1. P-IV; Q-I; R-II; S-III
2. P-II; Q-I; R-IV; S-III
P 3. P-IV; Q-II; R-III; S-I
4. P-II; Q-I; R-III; S-IV
Q
107. The correct match for the reactions P-S with
the names of cyclizations I-IV is
R
Reactions

P
S

Processes: I. Diels-Alder
II. Norrish Type I R
III. photocycloaddition followed by
Diels-Alder
S
IV. Norrish Type II

1. P-II; Q-IV; R-III; S-I Names of cyclizations: I. halocyclization

2. P-II; Q-IV; R-I; S-II
II. Nazarov cyclization
3. P-IV; Q-II; R-III; S-I
4. P-IV; Q-II; R-I; S-III III. radical cyclization
IV. electrocyclization

107. 0sP-S sss I-IV 1. P-IV; Q-I; R-II; S-III

2. P-II; Q-I; R-IV; S-III
ss
3. P-IV; Q-II; R-III; S-I
4. P-II; Q-I; R-III; S-IV
 32

108.
0ss 2.

0 s ,s

3.

4.
1. 2.

3. 4.

109. The major product formed in the following

reaction is

108. The correct structure of the intermediate,

which leads to the product in the following
reaction is

1.

2.

1. 2.

3.

3. 4.

4.

109. 0s d0s

110. 0s d0s
1.
 33

111. 0s d0s
1. A s B

2.

1.

3.

2.

4.

3.

110. The major product formed in the following 4.

reaction is

111. The major products A and B formed in the

following reaction sequence are

1.

1.

2.
2.

3. 3.

4.
4.
 34

112. 0s d0s
3.

4.

1. 2. 113. The intermediate A and the major product B

in the following reaction sequence are

3. 4.

1.

112. The major product formed in the following

reaction is 2.

3.

4.
1. 2.

114. 13C NMR DEPT-135 s

3. 4. s0s
13
C NMR DEPT-135: s
30.2, 31.9,
130.4 ppm
61.8, 114.7 ppm;s

113. 0s 0A s
d
0
sB 1.

2.

1. 3.

2. 4.
 35

114. The correct structure of the compound, which

shows following 13C NMR DEPT-135 data is 3. 4.
13
C NMR DEPT-135: negative peaks at
30.2, 31.9, 61.8, 114.7 ppm; positive peak at
130.4 ppm

116. 0s d0
1.
sA sB

2.

1.
3.

2.
4.

3.

115. 0ss
0s 4.
1
IR: 1690 cm
1
H NMR: 2.5 (s, 3H), 3.8 (s, 3H), 6.9 (d, J = 8
Hz, 2H), 7.8 (d, J = 8 Hz, 2H) ppm 13C NMR:
197, 165, 130, 129, 114, 56, 26 ppm 116. The major products A and B formed in the
following reaction sequence are

1. 2.

3. 4.
1.

2.
115. A compound displays the following spectral
data. The correct structure of the compound is
IR: 1690 cm1 3.
1
H NMR: 2.5 (s, 3H), 3.8 (s, 3H), 6.9 (d, J =
8 Hz, 2H), 7.8 (d, J = 8 Hz, 2H) ppm 13C
NMR: 197, 165, 130, 129, 114, 56, 26 ppm
4.

1. 2.
 36

117. 0s d0s 118. 0s d0s

1.

1.
2.

2.
3.

4. 3.

117. The major product formed in the following 4.

reaction is

118. The major product formed in the following

reaction is
1.

2.

3. 1.

4. 2.
 37

3. 1.

4.
2.

3.
119.
0s
d 0
s

4.

120. 0s d0s
1.

2.

1. 2.

3.

3. 4.

4.

120. The major product formed in the following

reaction is

119. The major product formed in the following

reaction is
 38

123. NMR 2.5T s d

1. 2. 1H s d

100 MHz
00
0
d
0 s
90

3. 4.

1. 2.
3. 4.

123. In an NMR spectrometer containing a 2.5T

121. 0 magnet, Larmor precession frequency of 1H is
100 MHz. The radiofrequency used in this
, ss s spectrometer has an associated magnetic field
s0 0 s 0 s strength of . The duration of a
s ,: 0s 90 pulse in this instrument is
1. 2. 1. 2.
3. 1 4. 3. 4.

121. The single-particle translational partition 124.

d
d
0 s ,

function for an ideal gas in a fixed volume s
s 3
depends on the thermal Broglie
wavelength as where s s s s
s
1. 2.

s
3. 1 4. s

0s(J)
1. 0 2. 1
122. 15 s I s0 4 3. 2 4. 3
0s0s s0s
124. Upon application of a weak magnetic field, a
s0 s
s
line in the microwave absorption spectrum of
rigid rotor splits into 3 lines. The quantum
number (J) of the rotational energy level from
which the transition originates is
1. 0 2. 1
3. 2 4. 3

125. 0 s ss s0s 0s
1. II 2. III :
3. IV 4. V

122. 15 particles are distributed among 4 levels as

shown in state I. Heat is given to the system
and no work is done. The final state could be

s OA, AC s AB
:
s . 0 s s
1. II 2. III :300 K s3 kJ mol1 ,
3. IV 4. V 0 s
1. 10 2. 10

3. 10 4. 10
 39

125. Phase diagram of a compound is shown 127. d 0s

below:

d
s
s ,
1. 2.
3. 4.

127. The point group obtained by adding symmetry

operation to the point group is
1. 2.
3. 4.
The slopes of the lines OA, AC and AB are
and , respectively. If
melting point and of melting are 300 K 128. m s 0ss s
1
and 3 kJ mol respectively, the change in
ds0 2a s a ,
volume on melting is
1. 10 2. 10

s s s
s:
3. 10 4. 10
1. 2.

3. 4.
126. sss 0
00s
128. For a particle of mass m confined in a
s 0s0s ,
rectangular box with sides 2a and a, the
energy and degeneracy of the first excited
state, respectively, are
1. 2.

3. 4.

129. s sd s
0 s 13.6 eV
1. AB 2. BC
3. DC 4. AD
s s
1. 54.4 eV 2. 27.2 eV
3. 13.6 eV 4. 108.8 eV
126. The figure below describes how a Carnot
engine works. It starts from the adiabatic 129. The ionization energy of hydrogen atom in its
compression step denoted by ground state is approximately 13.6 eV. The
potential energy of , in its ground state is
approximately
1. 54.4 eV 2. 27.2 eV
3. 13.6 eV 4. 108.8 eV

130. D3 d s
0

D3 E 2C3 3C2
A1 1 1 1 x2+y2, z2
1. AB 2. BC A2 1 1 1 z, Rz
3. DC 4. AD E 2 1 0 (x, y), (x2y2, xy),
(Rx, Ry) (xz, yz)
 40

d
1. 2.
3. 4.

1. s 131. Suppose are wavefunctions of an
IR-0s,s anharmonic oscillator and are
wavefunctions of a harmonic oscillator with
2. IR-0s ss0
increasing order of energy. The subscripts
s0 denote vibrational quantum numbers in both
3. ss sIR-0 the cases. Given
s0
4. IR-0s 0ds
,ss

130. The character table for the D3 point group is

provided below: the FORBIDDEN electric dipole (assuming
the dipole operator is linear in normal
D3 E 2C 3C coordinates) transition among the following is
3 2 1. 2.
A1 1 1 1 x2+y2, z2 3. 4.
A2 1 1 1 z, Rz
E 2 1 0 (x, y), (x2y2, xy), 132. 0V s Ts U
(Rx, Ry) (xz, yz)
ss , ( s :
For this point group, the correct statement sss0ds )
among the following is: 1. CP 2. CV
1. It is possible to have a totally symmetric 3. 4.
normal mode of vibration which is IR-
active. 132. If U is a function of V and T, is equal to
2. All IR-active normal modes are
( and are the internal pressure and the
necessarily Raman inactive
coefficient of thermal expansion,
3. All Raman-active normal modes are
respectively.)
necessarily IR-active
1. CP 2. CV
4. It is possible to have a pair of IR-active
normal modes that are degenerate. 3. 4.

131. s s 133. C3v d s

0 s
s


ss
E 2C3 3v
s
0ss 0s A1 1 1 1
A2 1 1 1
E 2 1 0
6 0 2

s
1.

(FORBIDDEN) 2.
3.
(
s 4.
s s)
 41

133. The character table of C3v point group is 135. If experimentally observed rate constant is
provided below, along with an additional greater than the maximum value of rate
reducible representation, constant obtained using hard-sphere model of
collision theory, then relation between the
E 2C3 3v impact parameter (b) and sum of the radii of
A1 1 1 1 two reactants is
A2 1 1 1 1. 2.
E 2 1 0 3. 4.
6 0 2
136. 0C s ss
0
is given by 0s
s 0d
1. 1. 2.
2.
3. 3. 4.
4.
136. Half-life for a third order reaction
134. 00 ss00s products, where is the initial concentration
of C, will be
1. 2.

3. 4.

137. 0 s
1. sss0ss s
s s ss


2. s
ss0ss
0 0, ds s
s ss ,
3. 0s
ssss0s 1. 51/2 2. 71/2
3. 111/2 131/2
s s
4.

4. 0
ss 137. For a simple cubic lattice, the ratio between
the unit cell length and the separation of two
134. For the chemical reaction in aqueous solution adjacent parallel crystal planes can NOT have
a value of
1. 51/2 2. 71/2
1/2
3. 11 4. 131/2

138. A, B sC s
the correct statement is:
1. Increase of pressure increases the rate
s00s s
constant. s
2. Increase of dielectric constant increases the
rate constant.
3. Increase of ionic strength decreases the rate
constant.
4. The entropy of activation is positive

135. 0 ss 0s s s 0
s s -s s
0s s
ss
s(b) s 0s
1. A > B > C 2. B > A > C
00 3. C > A > B 4. C > B > A
1. 2.
3. 4.
 42

138. Adsorption isotherm of three gases A, B and C 3. is hermitian

are shown in the following figure, where is 4. the state is bound and stationary
the percentage of surface coverage.
141. A 0H
s
0 s ,s
A s s Hs
sA
0
s
1. s

0
The correct order of the extent of adsorption 2.
0
of these gases is
0
1. A > B > C 2. B > A > C
3.
0
3. C > A > B 4. C > B > A

0
139. 0 H s ss0 s s s 4. s
0
ds,s sss

0s 0s s
141. For a hermitation operator A, which does
(s) s
s
NOT commute with the Hamiltonian H, let
3 s(s) s be an eigenfunction of A and be an
s0 s eigenfunction of H. The correct statement
regarding the average value of the commutator

s,
of A with is:
1.
1. Both and
2.
3.
are non-zero
4. 2. Only is zero, but
is non-zero
139. Choosing some Hamiltonian H and an 3. Only is zero, but
orthonormal basis, a linear variation is carried is non-zero
out to get approximate energies . With 2 4. Both and
basis functions, one obtains . are zero
Taking 3 basis functions, similarly three
ordered energies are 142. ss s
found. The relation which holds from the

s
following is? s0s p k-mer
1.
2.

3. 1. 2.
4. 3. 4.

142. The condensation of a hydroxy acid produces

140. 1-d ss
a polyester with the probability of linkage at
ss0
0 both ends being p. The mole fraction of k-mer
1. chain formation is
2. 1. 2.
3. 3. 4.
4.
s
s
143. s d
140. Average value of momentum for the ground s ds s
state of a particle in a 1-d box is zero because ss
1.
s sd s
0
2.
 43

d 0 145. NaCl, CaCl2 s LaCl3 0 0, s0

s s s 0 0s ds (ln ) s
ss , s
s(c)
0
s
1. 2.
3. 4.

143. In simple molecular orbital theory of

hydrogen molecule, bonding and anti-
bonding molecular orbitals are constructed
as linear combinations of atomic orbitals of
two hydrogen atoms. The spatial part of a

purely covalent singlet wavefunction is
obtained by NaCl CaCl2 LaCl3
1. 2. 1. C B A
3. 4. 2. A B C
3. A C B
4. C A B

144. 0 1:1 0d-0 s0 A s B 145. Aqueous solutions of NaCl, CaCl2 and LaCl3
:
s , s sss show the following plots of logarithms of
mean ionic activity coefficient (ln ) vs.
s s s0s s
molar concentration (c):
,0
1. s
2. s
3. s
4. s

144. Two aqueous 1:1 electrolyte systems A and B

are at different temperatures and and
and concentrations, respectively. Their The correct option is then
Debye lengths will be equal if
1. and NaCl CaCl2 LaCl3
2. and 1. C B A
3. and 2. A B C
3. A C B
4. and
4. C A B

\
 44

FOR ROUGH WORK