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Composite materials are subjected to low temperatures in service and this has induced the need for a proper knowledge
of low temperature behavior of composites. Most of the research in this field is focused on applying different types of
loading and laminated configurations. This paper discusses the experimental study on the tensile, compressive and in-plane
shear behavior of unidirectional (UD) glass fiber reinforced polymeric composite under static and low temperature loading
conditions. Since UD composite is the basic building block of a composite structure and can be used to make general
laminates. In order to fully characterize UD laminate, several experimental tests are performed using an environmental test
chamber and a universal testing machine. Thermo-mechanical loads are applied to glass/epoxy unidirectional laminates at
room temperature (25C), -20C and -60C. The results of the present study indicate that low temperatures have a
significant effect on composite failure mode. It is also found that the strength and modulus of UD composites both increased
with decreasing the temperature in all cases including tensile, compressive and shear loads. On the other hand, the results
show that strain to failure decreased by decreasing the temperature.
The desire for lower production costs and higher low temperatures, understanding of the thermo-
production rates in high-volume markets such as the mechanical behavior of glass/epoxy laminates at
aircraft and construction industries, combined with low temperatures is of great importance.
the possibility of fast molding processes, high damage Takeda et al.1 examined the thermo-mechanical
tolerance (especially at sub-zero temperatures) and behavior of cracked G-11 woven glass/epoxy laminates
high chemical and environmental resistance make with temperature-dependent material properties under
fiber reinforced composites as very attractive tension at cryogenic temperatures. They found that
materials. Glass fiber reinforced polymer (GFRP) residual thermal stresses have no significant effect on
laminates are candidate materials for the insulation of Youngs modulus and Poissons ratio of G-11 woven
superconducting magnetic coils in future fusion laminates. In contrast, the effect of residual thermal
reactors. The study of composite laminates actually stresses on the stress distributions near the crack fronts
involves many topics, such as manufacturing is more pronounced with decreasing of the
processes, anisotropic elasticity, micromechanics, and temperature. Kim et al.2 studied the tensile properties
fracture and damage mechanics. Residual thermal of a T700/epoxy composite, which had been cycled
stresses develop in these materials when they are with thermo-mechanical loads at low temperatures,
exposed to low temperatures (below 0C). These using an environmental test chamber. They applied
stresses are the result of a difference in the thermo-mechanical tensile cyclic loading (up to 10
coefficients of thermal expansions (CTEs) between cycles) to T700/epoxy unidirectional laminates at
the reinforcement and the matrix. The non-zero state room temperature (RT) to -50 C, RT to -100 C, and
of residual thermal stresses at cryogenic temperatures RT to -150 C (CT), respectively. Results showed that
is the underlying cause of micro cracking in tensile stiffness significantly increased as temperature
composites, and the micro-cracks could have an decreased, while the thermo-mechanical cycling had
important influence on their performance. To secure less influence. Tensile strength, however, decreased as
the structural integrity of composite structures at temperature decreased down to Cold temperature (CT),
while the decreasing rate of strength was reduced
*E-mail: torabizadeh@yahoo.com after CT cycling. Kriz3 analyzed the static behavior
300 INDIAN J. ENG. MATER. SCI., AUGUST 2013
Materials and Specimen Geometry both fiber and matrix directions (longitudinal and
Material properties transverse) according to ASTM D303919. Woven
Unidirectional glass fibers have been used in this glass/epoxy tabs with tapered ends were locally
investigation as reinforcing material, while epoxy bonded on each side of the specimens. These tabs
resin has been utilized as the matrix material. Hand allow a smooth load transfer from the grip to the
lay-up method was used to fabricate thin laminates specimen especially for low temperature test. The
with epoxy resin ML-506 with hardener HA11. geometries of the specimens for longitudinal and
Unidirectional laminates was kept for about a week at transverse tensile tests are shown in Fig. 1.
room temperature for curing. Test specimens were cut Compression test
from laminates according to relevant standard codes. The specimens used for compression test had the
All specimens had a constant cross-section with same material as those of the tensile test except that
tabs bonded to the ends. The fiber volume fraction of these specimens were made of fifteen plies so that the
the composites was 55%. total thickness is 3 mm. Unidirectional compression
Tensile test specimens were cut in the longitudinal and transverse
The unidirectional glass fiber-reinforced epoxy directions for longitudinal and transverse compression
which composed of ten plies was used in this test; the tests and also a fixture is used for the tests according
total thickness of the laminate is 2 mm. Unidirectional to ASTM D341020. The geometries of the specimens
tensile specimens were cut out of the laminates in are shown in Fig. 2. Woven glass/epoxy tabs were
Fig. 1 Geometry of the specimens for longitudinal and transverse tensile tests at different temperatures
Fig. 2 Geometry of the specimens for longitudinal and transverse compressive tests at different temperatures
302 INDIAN J. ENG. MATER. SCI., AUGUST 2013
Fig. 3 Geometry of the specimens for in-plane shear tests at Fig. 4 Experimental set-up for mechanical tests at both room
different temperatures and low temperatures
TORABIZADEH: UNIDIRECTIONAL GLASS/EPOXY COMPOSITES 303
Fig. 7 Failure regions of the composite specimens at different temperatures in longitudinal direction under tensile loading
Fig. 8 Failure regions of the composite specimens at different temperatures in transverse direction under tensile loading
the maximum load28,29, and this behavior was Figs 11 and 12 show failed specimens under
associated to the plastic deformation of the polymeric compressive loading in longitudinal and transverse
matrix. Compressive strength in longitudinal directions at different temperatures, respectively.
direction increases significantly by decreasing The main failure mode of specimens in this case is
temperature (from 570.37 MPa at room temperature micro buckling of fibers in shear or extensional
to 731.94 MPa at -60C). mode. Also, in this case, there is a small amount of
Fig. 10 depicts stress-strain curves of unidirectional tab de-bonding near the gauge area for room
composite under transverse compressive loading at temperature specimens. The change in the mechanical
different temperatures. Again significant increase in response with decreasing temperature is associated
strength of composite was observed by decreasing with a change in failure modes. As shown in Fig. 11,
temperature (from 122.12 MPa at room temperature failure occurred at the middle of specimen under
to 186.22 MPa at -60C). Typical behavior was micro-buckling failure mode. The difference is that, in
reported by Gonzalez and Lorca30 for glass-epoxy low temperature cases, more fiber pull-out was
composites. But in this case against other directions of occurred. Also, extensive de-bonding between fibers
loading, by decreasing temperature, transverse and the matrix was also observed because of weaker
compressive stiffness was decreased and strain to fiber and matrix bonding at low temperatures. In this
failure was increased significantly. case, only at low temperatures failed specimens
fractured in two separate parts.
In the case of compression failure in the transverse
direction at low temperature, the failure area is much
more than the room temperature specimens. Also at
room temperature, specimen is not fractured in two
separate parts. This is because of major effects of low
temperature on mechanical properties of epoxy matrix
of composites. In this case, there is no significant
change in failure mechanism for specimens at -20C
and -60C. It is found that the role played by two
dominant damage mechanisms (de-cohesion at the
interface and shear band formation in the matrix) in
Fig. 10 Typical stress-strain behavior of unidirectional
controlling the composite strength. On the other
laminate under compressive loads in transverse direction at room hand, if de-cohesion is inhibited, failure took place
temperature, -20C and -60C by the development of shear bands in the matrix
Fig. 11 Failure regions of the composite specimens at different temperatures in longitudinal direction under compressive loading
Fig. 12 Failure regions of the composite specimens at different temperatures in transverse direction under compressive loading
306 INDIAN J. ENG. MATER. SCI., AUGUST 2013
which propagated through the microstructure at angle room temperature, both the in-plane shear modulus
of 45o with respect to the plane perpendicular to the and strength increased significantly.
compression axis30. The compressive strength was For metallic materials, the linear region of the
slightly higher than the matrix strength under stress-strain curve corresponds to elastic deformation
compression due to the additional strengthening and the nonlinear region to plastic deformation.
provided by the fibers. Parametric studies showed that However, when working with non-crystalline
other factors (such as the matrix friction angle, the substances (such as epoxy), the glass transition
interface fracture energy and the thermo-elastic temperature (Tg) determines whether a material can
residual stresses) exerted a secondary influence on the exhibit viscous, or non-linear behavior. Below the
compressive strength of PMC under transverse glass transition temperature a non-crystalline material
compression30. But the matrix is more susceptible to is considered an amorphous solid, above it a rubbery
the formation of shear bands. The angle formed solid and, as the temperature increases, a viscous
between the failure plane and in-plane loading liquid34. A non-crystalline material such as a polymer
direction is slightly above 45and typical values can only exhibit viscous behavior above Tg, below Tg,
reported31-33 are in the range 50-56. the material will fail before it plastically deforms. All
of the tests in the current study were conducted well
In-plane shear test results below Tg for the epoxy resin (157C). This indicates
Fig. 13 shows the stress-strain behavior of that the nonlinear regions of the shear stress-shear
modified specimen under in-plane shear loadings at strain curves generated by the tests at room and low
room temperature, -20C and -60C. As shown, this temperatures are not the result of viscous or plastic
behavior is highly nonlinear for all temperature tests. deformation24. This nonlinear behavior is thought to
Also, as temperature decreases to -60C from the be the result of micro-crack accumulation throughout
the matrix. The extensive nonlinear region displayed
in the room temperature stress-strain curves would
correspond to a high density of micro-cracks
throughout the material (Fig. 13). The more limited
nonlinear region in the curves generated from the tests
done at low temperatures imply that there is a
progressive decrease in micro-crack accumulation
within the specimen with decreasing temperature.
Reduction the nonlinear region of stress-strain curves
at low temperatures also confirmed by a suitable
candidate model to study the nonlinear behavior of
composites under shear loading. Parameter of material
nonlinearity decreased from 1.76 10-8 MPa-3 at room
temperature to 1.33 10-8 MPa-3 at-60 C.
Fig. 13 Typical stress-strain behavior of unidirectional
laminate under in-plane shear loading at room temperature, -20C Fig. 14 shows tested specimens and failure regions
and -60C under in-plane shear loading at different temperatures.
As shown in the figure, more damaged area was Decreasing temperature, in this case, has lower
observed with decreasing temperature from room effect on the final failure mode of the compression
temperature to -60C. tests of the unidirectional plies in longitudinal and
Fig. 15 shows the experimental values of transverse directions at various temperatures in
tensile and compressive strengths for unidirectional comparison with the previous one. Experimental
laminates at different temperatures in longitudinal and magnitudes of shear strength and modulus at different
transverse directions with their calculated standard temperatures are compared in Fig. 17. In the case of
deviations. shear loading, low temperature has major effect on
In each case in Fig.15 (a, b), by a polynomial curve mechanical properties of composites.
fitting to experimental data, the increasing trend of Temperature effects on mechanical properties of
strengths by decreasing the temperature is shown. UD composites which are plotted in Figs 15-17 can be
However, the increasing rate of compressive strength assessed also using a regression function defined by
by decreasing temperature is more for that of the Torabizadeh35:
tensile strength in both longitudinal and transverse
M (T ) = T 2 T + , (1)
directions.
Fig. 16 shows experimental values of tensile
where M and T are the mechanical property and
modulus for unidirectional laminates at different
temperature, respectively. Also , and are the
temperatures in longitudinal and transverse directions.
Both longitudinal and transverse tensile modulus
increased by decreasing temperature to -60C.
Table 1Material constants and correlation coefficients against other nonlinear curves, positive
-60C T 25C curvature was observed.
Material constants R (iii) The laminate under in-plane shear loading
Longitudinal 0.0093 1.5706 604.05 0.9575 behaves highly nonlinear for all temperature
compressive strength tests until final failure. Again, in this case, both
Transverse 0.0121 0.3784 124.04 0.9678 shear strength and stiffness increased by
compressive strength decreasing temperature in about 32% and 70%
Longitudinal 0.0098 0.3808 718.52 0.9642 respectively. Also nonlinear region decreased by
tensile strength
decreasing temperature due to increasing
Transverse 0.0010 0.0789 70.390 0.9622
brittleness of epoxy matrix.
tensile strength
In-plane shear strength 0.0058 0.0341 65.339 0.9682 (iv) Failure type of laminates under various loadings
Longitudinal modulus 0.0011 0.0326 22.800 0.9666 was affected by low temperature. It was found
Transverse modulus 0.0007 0.0420 6.1913 0.9920 that, by decreasing temperature a small amount
In-plane shear modulus 0.0002 0.0184 2.477 0.9769 of tab debonding occurred near the gauge area of
specimens in longitudinal tensile loading. Also,
material constants. The values for , , and R because of the interface between fiber and
(the correlation coefficient) are given in Table 1. matrix was much weaker at low temperature,
fibers debond the matrix in all test cases.
Conclusions Therefore, it may be concluded that the low
Mechanical behavior of glass/epoxy unidirectional temperature affects the micro mechanisms of
composite material under static loadings at low damage in composite specimen.
temperatures was experimentally investigated. For (v) From general master curves (Figs 15-17) and
this reason, tests were performed at room temperature, illustrated regression function, mechanical
-20C and -60C. Effects of low temperature on the properties of unidirectional glass fiber polymeric
strength, stiffness, strain to failure and failure type of composites at temperature range of -60C to
unidirectional composite specimens under tensile, 25C can be evaluated.
compressive and in-plane shear loading were
(vi) The unidirectional lamina is the basic building
investigated. Based on the test results of the present
block of a composite structure, which is
study, the following conclusions are drawn:
generally made of several unidirectional plies
(i) The stress-strain behavior of laminate under stacked at various angles. Therefore, the results
tensile loads in longitudinal direction was linear of the present study can be used as input data for
elastic until breakage and the slope of the stress- a progressive damage modeling of laminated
strain curve and the strength increased about glass/epoxy composites at temperature range of -
12% as the temperature decreased to -60 C. On 60C to 25C.
the other hand, by decreasing temperature, strain
to failure decreased slightly about 10%. References
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