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A PROJECT ON
PETROLEUM TECHNOLOGY I
(CHEN 515)
Submitted by
GROUP C MEMBERS
TO
DR A. SHUWA
JANUARY, 2017.
GROUP C MEMBERS
ABSTRACT
Shale gas is natural gas found in shale formations. It is currently being extracted using
unconventional techniques due to the low permeability of shale rock. The most common of
these techniques is horizontal drilling and hydraulic fracturing. Hydraulic fracturing involves
the injection of mainly water and sand into a shale formation to generate fractures or cracks
in the target rock formation. The sand or proppant holds the fractures open so that the gas in
the shale can flow to the wellbore and thus be produced. This technique, apart from polluting
water supplies, consumes large volumes of water, and so there is a gradual move towards the
use of waterless methods for fracturing such as pneumatic fracturing, fracturing with dynamic
loads, thermal (cryogenic) fracturing, mechanical cutting and so on. Even with the
of methane from cracks, the current trend in countries with abundant shale gas reserves
shows rapid increase in the volume of shale gas produced. The production of shale gas is
expected to increase in the coming years as newer technologies emerge because these
countries would not only want to be self-reliant in energy supply but will also want to
CHAPTER ONE
1.0 INTRODUCTION
Many of the worlds most important oil and gas deposits were originally formed in shale,
known as the source rock. Some of this oil and gas has migrated underground from the shale
into much more porous rocks, such as sandstone. From these formations, the oil and gas can
flow relatively easily into extraction wells, and these are the reservoirs of so-called
conventional oil and gas production. However much of the oil and gas remains in the shale
rock and this is difficult to remove because it is trapped within tiny pore spaces and fixed (or
adsorbed) onto clay mineral particles that make up the shale (Neil et al, 2013)
Due to their highly impermeable nature, shale deposits are unsuitable for conventional
quantities of gas. Fracking uses fluid, usually a mixture of water, sand and chemicals,
pumped at high pressure into the rock to cause narrow fractures to create paths for the gas to
flow to the surface. Although this technique increases production from the wells, it brings
1.1 AIM
The aim of this project is to carry out a research on the technique used for shale gas
1.2 OBJECTIVES
To find out the technique(s) currently used as well as the emerging technologies for shale
gas extraction.
To assess the present and projected future role of shale gas in global energy supply and to
CHAPTER TWO
Natural gas was first extracted from shale in Fredonia, New York in the 1820s, in shallow,
low-pressure fractures, several years before the breakthrough oil discoveries at wells in
Titusville, New York. However, shale gas usage was limited to early and small-scale
operations. It would not play a significant role in Americas energy portfolio for another
development of shale fracturing technologies, gas companies would drill past shale to get to
sandstone deposits underneath. The development of shale gas has revolutionized the North
American natural gas scene, ushering in an abundance of the cleaner-burning fuel. Prior to
1998 there was no commercial shale gas production in the world, but by 2012 production in
the United States of almost 8 trillion cubic feet of shale gas amounted to one-third of that
countrys total gas production, and more than 7% of global gas production. The technological
breakthroughs that have made this possible are readily exportable, and now other countries
are considering whether to develop their shale gas reserves (Robert, 2013).
Shale gas is natural gas formed and held within shale formations. It is a fossil fuel originating
from plant, algal or other remains, and composed primarily of methane (CH 4). Generally,
shale formations are composed of fine-grained (less than 0.0039 mm in diameter) laminated
sedimentary rocks made up of clay minerals (at least 30%), quartz, and small quantities of
fossils, organic matter, carbonates, feldspars and other minerals. Gas shale formations are
normally black due to the high organic matter content, although other colours can occur
and the transport and eventual deposit of fine debris into lakes, lagoons, river deltas and the
sea floor. Vast quantities of dead plankton or aquatic plant material are incorporated into the
deposit, where anaerobic bacteria convert the remains into a waxy substance called kerogen.
Depending on movement in the Earths crust and changes in climate, there are variations in
the rate and type of debris, and other sedimentary rocks such as sandstones or limestone can
be deposited. As sediments are buried deeper underground, they are subjected to increased
temperature due to the Earths subsurface temperature gradient, and increased pressure due to
the weight of accumulated sediments. This causes the sediments to compact and cement into
rock. At temperatures above 50C (122F), kerogen begins converting into oil (catagenesis).
If the shale formation is buried deeper underground, and reaches a depth where the
temperature is above 150C (302F), oil begins converting into natural gas (metagenesis).
Ongoing burial, rock compaction and earth movement together with continued hydrocarbon
generation causes the migration of oil and natural gas from shale. However, some oil or
natural gas will always be retained within the shale, adsorbed on to kerogen and clay
particles, and filling pore spaces and natural fractures. It is this process that forms a potential
The natural gas contained in shale reservoirs has the same primary chemical composition as
the natural gas contained in conventional reservoirs normally up to 95% methane. The main
difference is in the geological and physical properties of the reservoirs in which the natural
gas is stored rather than the composition of the gas itself (Energy Institute, 2015).
The volume of gas bound within a specific shale (gas-in-place) is known as the gas resource.
The reserves are the volume of gas that can be technically and economically produced.
Reserves are therefore often much smaller than the resource. The ratio of reserves to resource
varies widely between shale formations, with formations at higher pressure having a higher
estimated ultimate recovery. The U.S. Energy Information Administration estimates that 22
per cent of shale resources are technically recoverable. The economically recoverable fraction
may be much smaller as it depends on gas prices and production costs. The factors affecting
the ratio of reserve to resource are mainly geological. However, there are also non-geological
factors that could affect the size of the reserve. These factors include: engineering design
(such as the number of horizontal wells per pad and the techniques used for fracking); the
effect of the new protocols for earthquake mitigation and monitoring; land access;
environmental permit constraints; well costs; and the prices of gas and competing fuels
Table 2.1 shows the top 10 countries with technically recoverable shale gas resources. There
are no European countries among the top 10 countries with technically recoverable shale gas
resources. However, there are significant resources in some European countries like Poland,
Table 2.1 Top 10 countries with technically recoverable shale gas resources
Ran Country Shale gas tcf (tcm)
k
1 China 1,115 (31.6)
2 Argentina 802 (22.7)
3 Algeria 707 (20)
4 US 665 (18.8)
5 Canada 573 (16.2)
6 Mexico 545 (15.4)
7 Australia 437 (12.4)
8 South Africa 390 (11)
9 Russia 285 (8.1)
10 Brazil 245 (6.9)
Others 1,535 (43.5)
World Total 7,299 (206.7)
Source: (EIA, 2013)
The two most common methods to achieve extraction of shale gas are horizontal drilling and
hydraulic fracturing. Other fracturing techniques can be employed, some of which are used to
Horizontal drilling requires drilling a vertical well to a predetermined depth above the shale
gas reservoir. The well is then drilled at an increasing angle until it meets the reservoir
interval in a horizontal plane. Once horizontal, the well is drilled to a selected length, which
could extend to as much as 2500m. Horizontal drilling has a big advantage over vertical
drilling, in that a large amount of the wellbore can come into contact with the reservoir. This
also means that far fewer wells need to be drilled and the wells that are drilled can have many
wells drilled from the same well pad site thus reducing surface impact. Upon completion of
drilling, production casing is placed in the wellbore. A perforating gun is used to create a
series of holes in the casing to connect the rock formation to the wellbore.
The second critical element to the success of shale gas exploration and production is the use
of hydraulic fracturing. This process involves the injection of mainly water and sand, or a
similar proppant into a shale formation to generate fractures or cracks in the target rock
formation. The sand or proppant holds the fractures open so that the gas in the shale can flow
to the wellbore and thus be produced. The fluid, or fracture fluids, are mainly comprised of
water and sand with a small balance consisting of additives that improve the efficiency of the
fracture process. The particulars of each hydraulic fracture are based on the specifics and
characteristics of the rock formation in question. At the completion of the drilling and
fracturing process, the water used in the fracture stimulation process is produced back along
with natural gas. This water requires management to protect surface and ground water
resources, and ideally reduce future demands for fresh water. Stakeholders including local
and federal governments and shale gas operators look for ways to Reduce, Re-use, and
Recycle in order to minimize the impact on the environment and the community. Water
treatment technologies have been developed for use on shale gas produced water so that it
can be re-used.
Figure 2.1 Illustration for Horizontal Drilling and Hydraulic Fracturing
2.4.2.1 Fracking Fluids
Fluids used for hydraulic fracturing purposes are called fracking fluids or fracturing fluids.
They are injected into drilled boreholes under high pressure, in order to create targeted
fractures and fissures in gas-bearing bedrock. After the fracturing operation, the fracturing
fluid in the wellbore has to be removed, so that natural gas can be produced from the well.
The composition of the fracturing fluid varies from one product to another and the design of
the fluid varies depending on the characteristics of the target formation and operational
objectives. However, the fracturing fluid used in modern slickwater fracturing is typically
comprised of around 98% water and sand (as a proppant) with chemical additives comprising
2%.
Multiple fracturing operations are necessary in order to effectively stimulate the reservoir
rock. This process is called multi-stage fracturing and consists of dividing the horizontal
leg into sections which are then fractured independently. During this operation, each stage
is isolated from the rest of the wellbore using various types of plugs or packers (seals). Upon
completion of all fracture stages, the plugs or packers are removed and all stages of the
This technique makes use of a gas (typically air or nitrogen) to fracture the reservoir rock. It
recognition. Injecting gas underground to exploit hydrocarbons is not new: oil groups have
been injecting CO2 into oil or gas wells for a long time. As it reaches the underground where
temperatures are higher, the gas progressively dilates, making it possible to put pressure on
the hydrocarbons and extract them more easily. In the case of unconventional gas,
heptafluoropropane could make it possible to crack the bedrock where coal and shale oil and
gas are trapped. Unlike hydraulic fracturing, which requires large amounts of water and
Fracturing with Dynamic Loading do not make use of fluids, but rather by inducing a
dynamic loading by detonating explosives placed at the bottom of the well or by applying
electrical impulses.
Problems of wellbore damage, safety hazards, and unpredictable results reduced the relative
number of wells stimulated by high-strength explosives. More recently, studies have shown
that propellants have strong advantages over explosives. Propellants are substances which
Fracturing can be achieved by using a fluid colder than the reservoir. This will create thermal
stresses that could fracture the rock. Even if a fluid is used this is not strictly speaking
hydraulic fracturing in the traditional sense, because it is not the elevated pressure of the fluid
and high injection rates that breaks the rock. (Luca, 2013).
A patent from 2010 by Coleman and Hester presented a method to remove mass from a
formation between two connected wellbores using a flexible cutting cable. According to this
idea, two wellbores are drilled and connected; a cutting cable is inserted into the first well
and fished out from the second; finally, the cable is repeatedly pulled back and forth. This
sawing action removes formation material between the wellbores to form an opening in the
It is reported that shallow biogenic shale gas reservoirs generate gas by microbial activity,
implying that current production to the surface consists of ancient adsorbed gas as well as
within the shale formations to enhance the production of methane as by-product of their
stage for what it concerns in-situ application. The technique has been successfully applied in
laboratory. Further work is required to determine how to stimulate the microorganisms within
the reservoir to consume more of the organic carbon and thus increase gas production rates
(Luca, 2013).
2.6 Environmental Impacts of Shale Gas Extraction
The extraction and use of shale gas can affect the environment through the leaking of
extraction chemicals and waste into water supplies, the leaking of greenhouse gases during
extraction, and the pollution caused by the improper processing of natural gas. A challenge to
preventing pollution is that shale gas extraction varies widely in this regard, even between
different wells in the same project; the processes that reduce pollution sufficiently in one
Natural gas has been referred to as a low-carbon fuel, as its combustion produces
significantly less carbon dioxide emissions than coal and petroleum-based fuels. However, to
understand the implications for climate change, one must look at not only the greenhouse gas
(GHG) emissions from combustion in a vehicle or power plant but also those from production
activities. For natural gas, the primary concern is leakage and venting throughout the supply
In addition to GHGs, fugitive emissions of natural gas can release volatile organic
compounds (VOCs) and hazardous air pollutants, such as benzene. Nitrogen oxides (NOx)
are another pollutant of concern, as drilling, hydraulic fracturing, and compression equipment
typically powered by large internal combustion engines produce these emissions (Alvarez,
2012).
Although water is used in several stages of the shale gas life cycle, the majority of water is
typically consumed during the production stage. This is primarily due to the large volumes of
water (2.35.5 million gallons) required to hydraulically fracture a well. After fracturing a
well, anywhere from 5% to 20% of the original volume of the fluid will return to the surface
within the first 10 days as flowback water. An additional volume of water, equivalent to
anywhere from 10% to almost 300% of the injected volume, will return to the surface as
Concerns over water quality focus on potential drinking water contamination by methane or
fluids from hydraulic fracturing activities. The possible pathways for this contamination
include underground leakage from the wellbore to drinking water aquifers and improper
disposal or accidental leakage of hydraulic fracturing fluids to surface water bodies (EPA,
2014).
It is well known and documented that injecting fluid underground at high pressure can lead to
tremors. Injecting fluid either fractures the rock or enlarges existing fractures. The normal
stress between the two faces of the fracture is reduced due to the hydrostatic pressure of the
fluid in between. Therefore the friction force that keeps the rocks from moving, which is
proportional to the normal force between the two faces, is reduced. This leads to movement
of the two faces relative to each other, which is recorded as seismic activity (Aaron, 2011).
The increase in the extraction of shale gas over the past several years has led to a general
decrease in the price for natural gas mainly due to the large domestic supply of the gas. As
like other free markets, prices for natural gas are significantly driven by supply and demand.
Since there is now considered to be an abundant supply of natural gas coupled with lower
prices, the result has sparked interest in the use of natural gas for electricity production and
Globally, the energy markets of the coming decades will move towards a more competitive
and fragmented order, in which many energy importing countries also utilise significant
domestic resources, and are able to balance their imports with regional exporters and the
major global players. Figure 2.3 shows the rapid increase in projected shale gas production in
the U.S which might see the U.S moving away from being a natural gas importing country to
Figure 2.3 Shale Gas Leads Projected Natural Gas Production in the U.S (Allan. 2014).
CHAPTER THREE
Figure 3.1 Shale Gas Production Facility: Schematic Diagram Illustrating the Hydraulic
Fracturing Technique for Shale Gas Extraction (Cook et al, 2013)
Figure 2.2 Fracking Fluid additives and Proppant Mixing/Blending Unit. (EPA, 2014)
CHAPTER FOUR
4.0 METHODOLOGY
Hydraulic fracturing is the most widely used technique for shale gas production. However,
the process of producing natural gas from shale deposits involves many steps in addition to
hydraulic fracturing. These steps include road and well pad construction, drilling the well,
reclamation.
A well requires a prepared area on the surface, called a pad, that provides a stable base for a
drilling rig, retention ponds, water storage tanks, loading areas for water trucks, associated
piping, and pumping and control trucks. After well completion, the pad serves as the location
of the wellhead and other equipment. Preparing a pad involves clearing and levelling several
acres of land. Its size depends on the depth of the well and the number of wells to be drilled
on the site. In addition to land disturbed for building the well pad, three to four acres are
disturbed per pad for roads and utilities to service the pad (Clark et al, 2013).
4.6.2 Drilling
Most shale gas resources are located at depths of 6,000 feet or more below ground level, and
can be relatively thin (for example, the Marcellus shale formation is between 50200 feet
thick depending on location). The efficient extraction of gas from such a thin layer of rock
requires drilling horizontally through the shale. This is accomplished by drilling vertically
downward until the drill bit reaches a distance of around 900 feet from the shale formation.
At this point, a directional drill is used to create a gradual 90-degree curve, so that the
wellbore becomes horizontal as it reaches optimal depth within the shale. The wellbore then
follows the shale formation horizontally for 5,000 feet or more. Multiple horizontal wells
accessing different parts of the shale formation can be drilled from a single pad (Clark et al,
2013).
At various stages in the drilling process, drilling is stopped and steel casing pipe is installed
in the wellbore. Cement is pumped into the annulus, or void space between the casing and the
surrounding mineral formation. After the wellbore reaches a depth below the deepest
freshwater aquifer, casing and cement are installed to protect the water from contamination
due to the drilling process. Additional casing and cementing along the entire wellbore occurs
after the well has reached its full horizontal length. This process is intended to prevent
leakage of natural gas from the well to the rock layers between the shale formation and the
surface, as well as to prevent the escape of natural gas to the surface through the annulus. The
casing surrounding the horizontal section of the well through the shale formation is then
perforated using small explosives to enable the flow of hydraulic fracturing fluids out of the
well into the shale and the eventual flow of natural gas out of the shale into the well (Clark et
al, 2013).
Even though the well casing is perforated, little natural gas will flow freely into the well from
the shale. Fracture networks must be created in the shale to allow gas to escape from the
pores and natural fractures where it is trapped in the rock. This is accomplished through the
process of hydraulic fracturing. In this process, typically several million gallons of a fluid
composed of 9899.5% water and proppant (usually sand) is pumped at high pressure into the
well. The rest of the fracking fluid (0.52% by volume) is composed of a blend of chemicals,
often proprietary, that enhance the fluids properties. These chemicals are listed and their
functions has been list in Table 2.2. This fluid pushes through the perforations in the well
casing and forces fractures open in the shale-connecting pores and existing fractures and
creating a pathway for natural gas to flow back to the well. The proppant lodges in the
fractures and keeps them open once the pressure is reduced and the fluid flows back out of
During production, gas that is recovered from the well is sent to small-diameter gathering
pipelines that connect to larger pipelines that collect gas from a network of production wells.
Once a well no longer produces at an economic rate, the wellhead is removed, the wellbore is
filled with cement to prevent leakage of gas into the air, the surface is reclaimed (either to its
pre-well state or to another condition agreed upon with the landowner), and the site is
abandoned to the holder of the lands surface rights (Clark et al, 2013).
CHAPTER FIVE
5.1.1 Hydraulic Fracturing: The Most Commonly Used Technique for Shale Gas Extraction
Hydraulic fracturing or fracking as it is sometimes called is the most commonly used shale
gas extraction technique. This is because of the ready availability and relative cheapness of
the fluid used for this operation. The fluid consists of 98-99.5% of sand and water, the
Leakages and venting of greenhouse gases such as methane at the production facility,
enormous water requirement, pollution of water resulting from chemicals used for hydraulic
fracturing, and induced seismic activity are environmental challenges of great concern.
The large quantity of water used during the hydraulic fracturing process has raised public
concerns, and in addition to this, the problem of water pollution which reduces the quality of
potable drinking water may force companies involved in large scale shale gas production to
look towards waterless shale gas extraction techniques such as the pneumatic fracturing,
fracturing with dynamic loads, Thermal (cryogenic) fracturing, Mechanical cutting and so on.
The production of shale gas will no doubt increase tremendously in future. Several factors
reserves of shale gas are likely to go into massive production to cater for the ever
increasing demand of natural gas, and to move from being natural gas importing countries
6.0 CONCLUSION
Shale gas is an unconventional natural gas but it has same composition with conventional
natural gas (consisting mainly of methane). It differs from conventional natural gas only in
Unconventional techniques are used for the extraction of shale gas with the most common
technique being horizontal drilling and hydraulic fracturing. This method requires large
volumes of water and there may also be leakage of chemical into water supplies due to
However, with the attendant problems associated with hydraulic fracturing, there is a gradual
shift towards the use of waterless fracturing techniques such as the pneumatic fracturing,
fracturing with dynamic loads, Thermal (cryogenic) fracturing, Mechanical cutting and so on.
In additional to the impact of shale gas extraction on water supplies, leakage of greenhouse
gases such as methane at the production site, and induced seismic activity caused by
Against all odds, the production of shale gas is expected to increase as current and emerging
techniques supports large scale production. Countries blessed with this resource apart from
wanting to be self-reliant in energy production would also want to move from being
7.0 RECOMMENDATIONS
1. Understanding the shale rock formation of the well, by way of collecting core data about
their, porosity, permeability and mechanical properties will help in determining how
much shale gas they hold and how well the can fracture.
2. Utilization of advanced technologies during Hydraulic fracturing Production logging,
reservoir drainage and also ensures that the fracturing operation remains confined to the
targeted zone.
3. Government of countries involved in shale gas extraction should enact stricter laws that
would help mitigate the adverse environmental impacts of shale gas extraction both in
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