1.

(a) 1 mol ZnS 1 mol SO2;

ZnS = 97;
48.5 10 3
97 = 500;
3
Vol of SO2 500 24 = 12000 dm ; 4

3
(b) (i) 1000 (dm )/same volume; 1
3
(ii) 500 (dm )/half volume; 1
[6]

2. (a) CuO + H2SO4 CuSO4 + H2O; 5

64 + 16 = 80
2 + 32 + (16 4) = 98
98 / 10 = 9.8
80 / 10 = 8.0
if 9.8 of H2SO4 is used, then 8.0g of CuO is the maximum mass
that can be used

3. (a) A calculation to include:

230
1. moles of CO2 = 24000 = 0.00958;
2. moles of CaCO3 = 0.00958;
3. mass of CaCO3 = 0.00958 100 = 0.958 (g); 3

(b) gas volume expanded on heating; 1

[4]

4. (a) (i) A description to include:

1. same number of protons;
2. different number of neutrons; 2
[Ignore same atomic no / different mass number]

(ii) A calculation to include:

10 19.7 11 80.3
;
1. 100 100
2. = 10.803 / 10.8; 2

(b) A calculation to include:

either
1. mass of oxygen = 10.0 3.14 = 6.86 g ;

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 11
2. 11 g boron + 6.86 3.14 = 24 g oxygen
24
1 atom boron : 26 = 1.5 atoms of oxygen;
3 2 atoms boron : 3 atoms oxygen;
4. B2O3;
or
1. mass boron : mass oxygen = 6.86 g [mass of oxygen]
3.14 6.86
2. 11.0 16.0 [ Ar]
= 0.285; = 0.428;
3. 1 : 1.5 ; [ ratio]
4. B2O3; [ratio formula] 4
[8]

5.
(a) 2NaOH (aq) + H2SO4 (aq) Na2SO4 (aq) + 2H2O (l)
reactants,
products,
balancing correct formulae;
state symbols for any three of these four species; 4
(b) (i) pipette / burette; 1
(ii) burette; 1
(iii) phenolphthalein / methyl orange / suitable indicator; 1
[Reject litmus / universal]
(iv) pink (for phenolphthalein) /
yellow (for methyl orange) /
colours for allowed indicator; 1
(v) colourless (for phenolphthalein) [Reject clear] /
pink or red or orange (for methyl orange) /
colours for allowed indicator; 1
(c) A calculation to include:
25.0 0.200
1. moles of NAOH = 1000 = 0.005 (mol);
2. moles of HNO3 = 0.005 (mol);
0.005
3. concentration of HNO3 = 42.3 1000 = 0.118 /
3
0.12 (mol dm );
[Reject incorrect unit] 3
[12]

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