ALUMNO: GUTIERREZ GUTIERREZ, Miguel Angel

PROBLEMA 02
A un reactor ingresa una mezcla de gas de 8% de CO2, 12% O2 y 80% de N2, en la que ocurre una reaccin
quimica
_(2())+1/2 _(2())
_(3())
Calcule la composicion en el equilibrio a una presin constante de 2atm y kp = 160 atm

()=((1000.5)^(1/2))/((8)(120.5)^(1/2) 2)160

UTILIZANDO EL MTODO REGULA - FALSi

EPS =
i a b f(a) f(b) c f(c)
0 7.8 7.9
1 7.8 7.9 -65.011989 32.9580217 7.86635907 -16.366813378
2 7.8 7.86635907 -65.011989 -16.366813 7.88868578 13.0413872166
3 7.88868578 7.86635907 13.0413872 -16.366813 7.87878476 -1.3369598301
4 7.88868578 7.87878476 13.0413872 -1.3369598 7.87970539 -0.0998149507
5 7.88868578 7.87970539 13.0413872 -0.099815 7.87977361 -0.0073995897
6 7.88868578 7.87977361 13.0413872 -0.0073996 7.87977866 -0.0005482663
7 7.88868578 7.87977866 13.0413872 -0.0005483 7.87977903 -4.0621749E-05
8 7.88868578 7.87977903 13.0413872 -4.0622E-05 7.87977906 -3.0097086E-06
9 7.88868578 7.87977906 13.0413872 -3.0097E-06 7.87977906 -0.000000223
10 7.88868578 7.87977906 13.0413872 -2.2299E-07 7.87977906 -1.6521511E-08
 Codigo: 17125873

0.001
x f(x)
7 -143.32226 Chart Title
7.1 -141.15381 50
7.2 -138.44111
7.3 -134.95088
0
7.4 -130.29432 6.8 7 7.2 7.4 7.6 7.8
7.5 -123.77156
SOLUCIN 7.6 -113.9829 -50

SOLUCIN 7.7 -97.662366

SOLUCIN 7.8 -65.011989 -100
SOLUCIN 7.9 32.9580217
SOLUCIN -150

-200
t Title

7.4 7.6 7.8 8

ALUMNO: GUTIERREZ , Miguel Angel
PROBLEMA 03
Calcular el volumen molar con la ecuacin de V.D.W para el CO2 a T = 80C y R = 0.08205 cuya
constante a=3.599 y b=0.04267 utilizando el metodo de Regula-False y Newton-Raphson

(+ /^2 )()= ..

()=^3(+ ) ^2+
P = 10 T = 353.15
()=3^22(+)+ b = 0.04267
a= 3.599
Metodo de REGULA-FALSi R = 0.08205
EPS =
i a b f(a) f(b) c f( c )
0 2 3
1 2 3 -30.566199 16.0195132 2.65612819 -10.640117
2 2 2.65612819 -30.566199 -10.640117 3.00648711 16.6525031
3 3.00648711 2.65612819 16.6525031 -10.640117 2.79271676 -1.6103214
4 3.00648711 2.79271676 16.6525031 -1.6103214 2.81156592 -0.2083401
5 3.00648711 2.81156592 16.6525031 -0.2083401 2.81397445 -0.0263912
6 3.00648711 2.81397445 16.6525031 -0.0263912 2.81427907 -0.0033341
7 3.00648711 2.81427907 16.6525031 -0.0033341 2.81431754 -0.0004211
8 3.00648711 2.81431754 16.6525031 -0.0004211 2.8143224 -5.3174E-05
9 3.00648711 2.8143224 16.6525031 -5.3174E-05 52927.2227 1.4826E+15
10 3.00648711 52927.2227 16.6525031 1.4826E+15 0.18054265 -0.403346

Metodo de NEWTON-RAPHSON
calculando el punto inicio P = 10 T = 353.15
b = 0.04267
_=/=(0.0205(273.15+80))/10=2.89
a= 3.599
R = 0.08205
EPS = 0.001
i Vo f(Vo) f(Vo) Vi f(Vi)
0 2.89
1 2.89 6.04929496 84.2146397 2.81816813 0.29193743
2 2.81816813 0.29193743 76.1378838 2.81433381 0.00081014 SOLUCIN
3 2.81433381 0.00081014 75.7154571 2.81432311 6.2998E-09 SOLUCIN
4 2.81432311 6.2998E-09 75.7142795 2.81432311 2.1122E-14 SOLUCIN
5 2.81432311 2.1122E-14 75.7142795 2.81432311 -7.2997E-15 SOLUCIN
6 2.81432311 -7.2997E-15 75.7142795 2.81432311 -7.2997E-15 SOLUCIN
7 2.81432311 -7.2997E-15 75.7142795 2.81432311 -7.2997E-15 SOLUCIN
0.001 x f(x)
0 -0.1535693 Chart Title
1 -15.957227 8000
2 -30.566199 7000
3 16.0195132
6000
4 183.799911
5000
5 532.774993
6 1122.94476 4000
7 2014.30921 3000
SOLUCIN 8 3266.86835 2000
SOLUCIN 9 4940.62217
1000
10 7095.57068
0
0 2 4 6 8
-1000
 Chart Title

4 6 8 10 12