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Symbol(s) O, C
R-phrase(s) R5, R8, R20/22, R35
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Page 1 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Emergency Overview
Inhalation
Short Term Effects
May be harmful if inhaled. May cause irritation possibly severe. Additional effects may
include vomiting, diarrhea, shortness of breath, headache, dizziness, numbness, twitching,
lung congestion, convulsions and shock
Long Term Effects
May cause effects as in short term exposure. Additional effects may include tearing.
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Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Skin Contact
Short Term Effects: May cause irritation, possibly severe.
Long Term Effects: Same effects as short term exposure.
Eye Contact
Short Term Effects: May cause burns. Additional effects may include tearing and blindness.
Long Term Effects: May cause effects as in short term exposure. Additional effects may
include eye damage.
Ingestion
Short Term Effects: May be harmful if swallowed. May cause burns. Additional effects may
include fever and chest pain.
Long Term Effects: May cause effects as in short term exposure. Additional effects may
include kidney damage. May also cause tumors.
Carcinogen Status
OSHA: N
NTP: N
IARC: N
Inhalation
Take affected persons out into the fresh air.
Perform artificial respiration if necessary.
Maintain airway, blood pressure and respiration.
Keep warm and at rest. Treat symptomatically and supportively.
Get medical attention immediately.
Qualified medical personnel should consider administering oxygen.
Get medical attention in case of respiratory symptoms.
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Page 3 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Skin Contact
Remove contaminated clothing, shoes, etc. immediately.
Wash with soap or mild detergent and large amounts of water until no evidence of
chemical remains (at least 15-20 minutes).
If burns occur, proceed with the following:
Cover affected area securely with sterile, dry, loose-fitting dressing.
Treat symptomatically and supportively.
Get medical attention immediately.
Eye contact:
Wash eyes immediately with large amounts of water, occasionally lifting upper and lower
lids, until no evidence of chemical remains (atleast 15-20 minutes).
Continue irrigating with normal saline until the pH has returned to normal (30-60 minutes).
Cover with sterile bandages.
Get medical attention immediately.
Ingestion:
If the person is conscious and not convulsing, give 2-4 glasses of water to dilute the
chemical.
Use gastric tube to relieve the pressure caused by evolved oxygen
(Dreisbach, Handbook of Poisoning, 12th Ed.).
Treat symptomatically and supportively.
Intubation should be performed by qualified medical personnel.
Get medical attention immediately.
Note to Physician:
No specific antidote
Treat symptomatically and supportively
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Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Oxidizer:
Oxidizers decompose, especially when heated, to yield oxygen or other gases which will
increase the burning rate of combustible matter. Contact with easily oxidizable, organic, or
other combustible materials may result in ignition, violent combustion or explosion.
Extinguishing Media:
Water only, no dry chemical, carbon dioxide or halon.
(1993 Emergency Response Guidebook, RSPA P 5800.6)
For larger fires, flood area with water from a distance.
(1993 Emergency Response Guidebook, RSPA P 5800.6).
Fire-fighting:
Move container from fire area if you can do it without risk.
Apply cooling water to sides of containers that are exposed to flames until well after fire is
out.
Stay away from ends of tanks.
For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is
impossible, withdraw from area and let fire burn (1993 Emergency Response Guidebook,
RSPA P 5800.6, Guide Page 45).
Use water in flooding amounts as a fog.
Cool containers with flooding quantities of water, apply from as far a distances as possible.
Avoid breathing toxic vapors, keep upwind.
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Page 5 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Occupational Spill.
Keep combustibles(wood, paper, oil,etc.) Away from spilled material.
Do not touch spilled material. Stop leak if you can do it without risk.
Use water spray to reduce vapors.
Do not get water inside container.
For small dry spills, with clean shovel place material into clean, dry container and cover.
Move containers from spill area.
For small liquid spills, flush area with flooding amounts of water.
For larger spills, dike far ahead of spill for later disposal. Keep unnecessary people away.
Isolate hazard area and deny entry.
Storage
Observe all federal, state and local regulations when storing this substance.
Protect against physical damage.
Store in cool, ventilated, non-combustible area in vented containers, remote from
combustible, organic, readily oxidizable materials and catalytic metals (NFPA 49,
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Page 6 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Exposure Limits
OSHA TWA : 1 ppm (1.4 mg/m3)
ACGIH TWA : 1 ppm (1.4 mg/m3)
NIOSH TWA : 1 ppm (1.4 mg/m3) recommended 10
: hours TWA
DFG MAK TWA : 1 ppm (1.4 mg/m3)
5 minute peak, momentary value, 8 times/shift : 2 ppm (2.8 mg/m3)
Ventilation
Provide local exhaust or process enclosure ventilation to meet published exposure limits.
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Page 7 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Eye Protection
Employee must wear splash-proof or dust-resistant safety goggles and a faceshield to
revent contact with this substance.
Clothing
Employee must wear appropriate protective(impervious) clothing and equipment to
prevent any possibility of skin contact with this substance.
Gloves
Employee must wear appropriate protective gloves to prevent contact with this substance.
Respirator
The following respirators and maximum use concentrations are recommendations by the
U.S. Department of Health and Human Services. NIOSH Pocket Guide to Chemical
Hazards; NIOSH criteria documents or by the U.S Department of Labor, 29 CFR
1910 Subpart Z. The specific respirator selected must be based on contamination
levels found in the work place, must not exceed the working limits of the
respirator and be jointly approved by the National Institute for Occupational Safety
and Health and the Mine Safety and Health Administration (NIOSH-MSHA).
Hydrogen Peroxide:
10 ppm Any supplied-air respirator
25 ppm Any supplied-air respirator operated in a continous-flow mode.
50 ppm Any self-contained breathing apparatus with a full facepiece.
Any supplied-air respirator with a full facepiece.
75 ppm Any supplied-air respirator that has a full facepiece and is operated in a
pressure-demand or other positive-pressure mode
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Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Escape- Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or
back-mounted canister providing protection against this compound.
Any appropriate escape-type, self-contained breathing apparatus.
pH No data available
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Page 9 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Reactivity
contact with rough surfaces, alkalies, finely divided metals and many other
substances.
Conditions to Avoid
Incompatibilities
Acetone Explosion
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Page 10 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Ethanol Explosion.
present.
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Page 11 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Hazardous decomposition
Polymerization
Hazardous polymerization is not been reported to occur under normal temperature and
pressures.
Acute Toxicity
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Page 12 of 14
Hydrogen Peroxide
Material Safety Data Sheet
Rev. No. 06, Rev. Date : 2007-05-26
Observe all federal, state and local regulations when disposing of this substance.
Disposal must be in accordance with standards applicable to generators of hazardous
waste, 40 CFR 262. EPA Hazardous Waste Number D002.
100 pound CERCLA Section 103 Reportable Quantity.
To our actual knowledge, the information contained herein is accurate as of the date of this
document. However, DC Chemical Co., Ltd. does not warrant, expressly or impliedly, or accept
any liability in connection with this information or its use. This information is for use by
technically skilled persons at their own discretion and risk and does not relate to the use of this
product in combination with any other substance or any other process. This is not a license of
any patent, trademark or other intellectual property. The user alone must finally determine
suitability of any information or material for any contemplated use, the manner of use and
whether any intellectual property rights are infringed.
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Page 14 of 14