ANDHERI / BORIVALI / DADAR / THANE / POWAI / CHEMBUR / NERUL / KHARGHAR

IIT JEE: 2017 CRASH COURSE (C - 2) DATE:18/11/16

TIME: 2HRS MAIN MARKS: 120
TOPIC: CHEMICAL EQUILIBRIUM, IONIC EQUILIBRIUM, CHEMICAL KINETICS

SECTIONI (Single Choice Questions)

This section contains 30 Multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct. (+4, 1)

1. A B, K1 1011 e3000/T
X Y , K2 1010 e2000/T
If the two reactions have all the reactants at unit molarity each, at what temperature their initial rates
will be equal?
1000
(A) 2000K (B) 3000K (C) 1000K (D) K
2.303
2. The pH of a weak monoacid base at 80% neutralization with a strong acid in a dilute solution is 7.40.
The ionization constant, of the base is:
(A) 1.0 106 (B) 1.6 107 (C) 1.0 105 (D) None of these

3. At 250 C , the pH of 0.01M KOH is 12. If the temperature of this solution is raised to 500 C without
changing the volume, which of the following is correct?
(A) Both pH and pOH will remain constant
(B) pH will decrease while pOH will remain constant
(C) pH will increase while pOH will remain constant
(D) pH will increase while pOH will decrease.

4. In the following hypothetical reaction A 3B 2C D, initial moles of A is twice that of B. If at

equilibrium moles of B and C are equal, % of B reacted is:
(A) 10% (B) 20% (C) 40% (D) 60%

5. An acid base indicator HIn is a buffer of pH pK In 1 is ionized to the extent of

(A) 90.9% (B) 9.1% (C) 10% (D) 90%

6. Ammonium carboamate dissociates on heating as:

NH2COONH4 s 2 NH3 g CO2 g
The K P for the reaction, at some temperature is 3.2 105 atm2 . The partial pressure of NH3 in the
equilibrium system at the same temperature:
(A) 2.0 102 atm (B) 4.0 102 atm (C) 3.2 102 atm (D) 6.4 102 atm

7. In a spontaneous process X 2Y Z , the activation energy of forward and reverse reaction is the
same, then
(A) G 0, S 0, H 0 (B) G 0, S 0, H 0
(C) G 0, S 0, H 0 (D) G 0, S 0, H 0
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8. The exothermic reaction is represented by the graph:

nKp nKp

(A) 1T (B) 1T

nKp nKp

(C) 1T (D) 1T

9. In most cases, for a rise of 10 K temperature the rate constant is doubled to tripled. This is due to the
reason that:
(A) collision frequency increases by a factor of 2 to 3
(B) fraction of molecules possessing threshold energy increases by a factor of 2 to 3
(C) activation energy is lowered by a factor of 2 to 3
(D) None of these

10. Rate of disappearance of the reactant A in the reversible and one step reaction A B at two
temperatures is given by:
d A
2.0 103 s 1 A s.0 104 s 1 B (at 270 C )
dt
d A
8.0 102 s 1 A 4.0 103 s 1 B (at 1270 C )
dt
The enthalpy change of the reaction in the given temperature range is:
2.303 8.314 300 400
(A) log 5J
100
2.303 8.314 300 400
(B) log 50J
100
2.303 8.314 300 400
(C) log 5J
100
100
(D) log 5J
2.303 8.314 300 400

11. Ice and water are placed in a closed container at a pressure of 1 atm and 273. 15 K. If pressure of the
system is increased to 2 atm while keeping temperature constant, which of the following would be
correct observation?
(A) The liquid phase disappears completely
(B) The amount of ice decreases
(C) The solid phase (ice) disappears completely.
(D) Volume of the system increases.

12. For the reversible reaction N2 O2 2NO, activation energy of the forward reaction is greater than
that of backward reaction. The slope of nK vs 1 T (abscissa) graph will be:

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 H H H
(A) Zero (B) (C) (D)
2.303R 2.303R R
13. The correct order of increasing solubility of AgCl in (A) water, (B) 0.1M NaCl, (C) 0.1 M
BaCl2 and (D) 0.1 M NH3 is:
(A) A B C D (B) B C A D (C) C B D A (D) C B A D

14. At temperature T K, PCl5 is 50% dissociated at an equilibrium pressure of 4 atm. At what pressure it
would dissociate to the extent of 80% at the same temperature?
(A) 0.50 atm (B) 0.60 atm (C) 0.75 atm (D) 2.50 atm

15. The following data were obtained at certain temperature for the decomposition of NH 3 over
tungsten.
PNH3 torr 50 100 200
t1/2 min 5.64 2.82 1.41
Units of rate constant of the reaction would be :
(A) mol1 L1 min 1 (B) min 1 (C) L mol1 min 1 (D) L2 mol2 min 1

16. The molecular mass of PCl5 is 208.32 but when heated to 2300 C , it is reduced to 124. The extent of
dissociation of PCl5 at this temperature will be:
(A) 6.8% (B) 46% (C) 64% (D) 68%

17. pH of two solutions:

I: 50 ml of 0.2 M HCl 50ml of 0.2 M HA Ka 1.0 105 and
II: 50 ml of 0.2 M HCl 50ml of 0.2 M NaA, will be respectively.
(A) 0.7 and 2.85 (B) 1 and 2.85 (C) 1 and 3 (D) 3 and 1

18. In the manufacture of NH3 by Habers continues flow process involving the reaction
Fe2O3
N2 g 3H2 g 2 NH3 g ,
H 22.08Kcal
The favorable conditions are:
(A) High pressure and low temperature due to low activation energy Ea
(B) Low temperature and low pressure due to low Ea.
(C) High pressure and elevated optimum temperature due to high Ea.
(D) None of these

19. The equilibrium constant for the reaction NH4OH aq H aq NH4 aq H2O is 1.80 109
Hence equilibrium constant for the ionization NH3 H2O NH4 aq OH aq is:
(A) 5.55 1010 (B) 1.8 109 (C) 1.8 105 (D) 1.8 105

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20. Select the rate law that conforms to the following data for the reaction : A B Product
Ex. No. [A] [B] Initial rate
(mol/L) (mol/L) (mol/L/s)
1. 0.0012 0.0035 1104
2. 0.024 0.070 8 103
3. 0.024 0.035 1103
4. 0.012 0.070 8 103
d A d A
(A) k A B (B) k A B
2 2

dt dt
d A d A
(C) k A B (D) k B
3 3

dt dt

21. pH of a solution obtained by mixing 50 ml of 0.1 M NaCN and 50 ml of 0.2 M HCl will be ( pKa of
HCN 9.40 ):
(A) 1.30 (B) 1.00 (C) 9.40 (D) 9.10

22. If I is the intensity of absorbed light and C mol/L is the concentration of AB for the photo-chemical
process AB h AB* , the rate of formation of AB* (activated AB molecules) varies
proportionately to :
(A) CI (B) I 2 (C) C (D) I

23. In which of the following cases pH is greater than 7?

(A) 50 ml of 0.1 M HCl + 50 ml of 0.1 M NaCl
(B) 50 ml of 0.1 M H 2SO4 + 50 ml of 0.2 M NaOH
(C) 50 ml of 0.1 M CH3COOH + 50 ml of 0.1 M KOH
(D) 50 ml of 0.1 M HNO3 50 ml of 0.1M NH3 .

24. A catalyst lowers the energy of activation by 25%. Temperature at which rate of uncatalysed reaction
will be equal to that of the catalysed one at 27o C is :
(A) 400o C (B) 127oC (C) 300o C (D) 227o C

25. Ksp of Ca OH 2 is 4.0 106 . At what minimum pH, Ca 2 ions start precipitating in 0.01M CaCl2 ?
(A) 12 log 2 (B) 12 log 2 (C) 2 log 2 (D) 2 log 2

26. For the reaction R X OH R OH X , the rate of reaction is given as :

Rate 5.0 105 R X OH 0.20 105 R X
What percentage of R X react by SN 2 mechanism when OH 102 M ?
(A) 96.1% (B) 3.9% (C) 80% (D) 20%

27. The rate constant of a reaction at 27oC is 2.3 103 min 1 and at this temperature 0.001% of the
reactant molecules are able to cross over the energy barrier existing between the reactants and the
products. What can the maximum value of rate constant be achieved on raising the temperature?
(A) 23.0 min 1 (B) 2.3 102 min 1 (C) 115.0min1 (D) 230.0 min1

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28. The pH of blood is 7.4. If the buffer in blood is CO2 and HCO3 , calculate the ratio of conjugate base
to acid H 2CO3 to maintain the pH of the blood. Given K1 of H2CO3 4.5 107
(A) 8.5 (B) 10.0 (C) 11.25 (D) None of these

29. The Ag ion concentration in a solution containing 0.02 mol of AgNO3 and 0.14 mol of NH3 in

1L K d for Ag NH3 2 1.0 108 is:

(A) 2 107 M (B) 1.0 108 M (C) 2 108 M (D) 2 109 M

30. At 227oC, the presence of catalyst causes the activation energy of a reaction to decrease by
4.606 Kcal. The rate of the reaction will be increased by
(A) 2 times (B) 10 times (C) 100 times (D) 1000 times

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