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1/10/2016

Advanced Enhanced Oil Recovery Processes:


Chemical, Miscible and Thermal
(5 days Industry Training Course)

Overview

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Instructor
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Dr. Shedid A. Shedid

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Consultant and Professor


Petroleum Engineering

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 Profile:
 Dr Shedid A. Shedid,
 !& Professor, Petroleum Eng.
Instructors

Consultant

 


 
  Background
Educational

  Assistant, associate, and professor of petroleum engineering


 

 Ph. D. from University of Oklahoma, Norman, Oklahoma, U. S. A..

B. Sc. and M. Sc. of Petroleum Eng., Suez Canal University, Egypt.

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Instructors Profile: Dr Shedid A. Shedid,


Consultant & Professor, Petroleum Eng.

Experience

1. Consultant & Professor of Petroleum Eng. (1999-present).


2. Professor at American University in Cairo (AUC), Egypt (2010-present).

3. Associate Professor at Texas A & M University (2008-2010).

4. Associate Professor, University of Western Australia (UWA), Perth, Australia (2006-2008).


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5. Associate Professor at UAE University (1999-2006).
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 Profile:
 Dr Shedid A. Shedid,
 !& Professor, Petroleum Eng.
Instructors

Consultant




  Technical Consultation:



1.NExT-Schlumberger-USA
International

  (2012-present), Worldwide.

 2. Society of Pet. Eng (SPE), USA (2011-present), Worldwide.

  3. IBC Academy, London, U. K., (2012-present) , Worldwide.


4. Boots & Coots-USA (2008-2010), Hassi Masoud, Algeria.
5. Occidental (OXY)-UAE (2003-2006)
6. ADNOC & ADCO-UAE (2000-2006).
7. Petrolite-USA (1997-1998):

For more details;


Please search Google for Linkedin website: Dr. Shedid A. Shedid
E-mail: shedid72@yahoo.com
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Day 1 Course Outline

Overview

Different EOR Processes Concepts, Limitations & Challenges

Fundamental Science & Engineering behind EOR application-

Screening oil reservoirs for the best EOR method

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Technical constraints of different EOR processes
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Different reservoir characterization techniques

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Day
 !2 Course Outline



Sampling  
  Tools and Techniques
 

  Water flooding and Buckley-Leverett model
 


Screening criteria for chemical EOR methods:

Polymer EOR design and analysis

Alkaline/Polymer EOR process and screening oil

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Day 3 Course Outline

Alkaline/Surfactant/Polymer (ASP) flooding

Screening criteria and actual field study of ASP process

Two Actual field cases of design and result analysis

Pilot design of chemical EOR project

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Day
 !4 Course Outline



   

CO Flooding - Properties, Design & Case Study
2

  Lab determination and calculation of Minimum Miscibility Pressure

  (MMP)

 Actual field case study of USA reservoir

Thermal Recovery Processes


Cyclic Steam Stimulation (CSS)
Continuous Steam Flood
Steam Assisted Gravity Drainage (SAGD)
In-Situ Combustion (Fire)

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Day 5 Course Outline

Reservoir Simulation Steps and Work flow


Types of reservoir simulators
Input data for reservoir simulation
Main steps of a reservoir simulation study

Newly Developed Recovery Processes


Toe to Heel Air Injection (THAI); THAI with Catalyst (CAPRI)
Steam Solvent Based Hybrid Processes
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Other Newly Developed Recovery Processes )"
Microbial Enhanced Oil Recovery (MEOR)
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Enzyme Enhanced Oil Recovery (EEOR)
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Electric EOR, Seismic EOR, and Microwave EOR

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 The
 


! Reservoir

 
  A reservoir is a porous rock which contains fluids
 The reservoir has suitable both porosity and permeability
 
 

 Gas
Oil
Cap rock
Water
Reservoir

Source Migrating hydrocarbons

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Phases and Lifecycle of an Oilfield

Lifecycle of an oil field involves:


1. Exploration: Apply
- Geological,
- Geophysical, and
- Geochemical

2. Appraisal: using possible tools for formation


evaluation

3. Development: Drilling more well to increase


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production


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4. Production: Optimize production
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A. Primary Oil Recovery
B. Secondary Oil Recovery  !
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C. Enhanced Oil Recovery

5. Abandonment/Storage
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OilRecovery
 



Enhanced
! (EOR) Processes

 
  
Enhanced

 oil recovery (EOR)
processes
  include all methods

 that use external sources of

  energy and/or materials to


recover oil that cannot be
produced economically by
conventional means.

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EOR Projects in the US

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 EOR



! Vision

 
  

Develop technologies, products and workflows to help increase
 
recovery factors in oil fields.

 is the most integrated activity of the


EOR

  O&G Industry;


Each activity (yellow boxes) has to take
place in a well synchronized manner for
incremental oil to be realized at the stock tank.
If one of them fails there will be no additional
recovery realized;
In the past, EOR projects were designed with
focus mainly on reservoir engineering and
laboratory experiments;
EOR success in the field requires
collaborative integration from all disciplines
(Geoscience-Engineering-Economics)

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Technology Relevance Measurement Scale

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   Overview & Applications
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Laboratory Measurement

  




 
 



Courtesy Cuong Jackson


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Improved Recovery Efficiency Processes

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This course will focus on enhanced oil recovery methods.

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 the World
Why ! Needs EOR Technology
 World 


  daily oil production is roughly 89.84 million barrels per


 day 
The
 billion barrels per year) in 2012.

(32

 EIA estimates that global consumption grew by 1.2 million bbl/d in


 

2013, averaging 90.4 million bbl/d for the year.

EIA expects global consumption to grow 1.2 million bbl/d in 2014
and 1.4 million bbl/d in 2015.

This means every year the oil industry has to find twice the
remaining volume of oil in the North Sea just to satisfy the industry
needs by replacing the depleted reserves.

Source: BP Statistical Review of World Energy," British Petroleum, June 2013. Source: EIA.com

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World Production & Demand (April 2014)

Total World Oil Total World Daily Oil Shortage


Year Demand Production
(MM bbl/day) (MM bbl/day) (MM bbl/day)
2012 89.17 89.84 0.67
2013 90.38 90.37 - 0.01
2014 91.61 (Forecast) 91.78 - 0.17

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2015 92.97 (Forecast) 93.09 - 0.12


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Source: US Energy Information Administration http://www.eia.gov



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  of EOR Processes
 !
Summary

  




 
 



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Oil Recovery: Types and Definitions

Types of Oil Recovery;

1. Primary Oil Recovery: by natural reservoir forces

2. Secondary Oil Recovery, by water flood/gas injection

3. Enhanced Oil Recovery (EOR); includes


A- Chemical,
B- Thermal ,
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C- Gas EOR Injection, and
D- Other EOR: Microbial, Electric, LSW .others )"
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Enhanced Oil Recovery (EOR) 21

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Definition
 ! of EOR Processes



   

Enhanced

 oil recovery (EOR) processes is defined as using
 

different methods injecting one or more external source(s) of

 energy or materials to recover additional oil, which cannot be
 produced, economically using conventional processes.

Enhanced Oil Recovery (EOR) 22

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EOR and IOR Definitions

Enhanced Oil Recovery (EOR)


It is an oil recovery process using injection of gases or chemicals and/or
thermal energy into the reservoir. It is not restricted to a particular phase,
as defined previously, in the producing life of the reservoir.

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Improved Oil Recover (IOR) covers just about anything, including


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- infill drilling
- optimized well placement,

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- better reservoir characterization, and
- other techniques/applications.

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Enhanced Oil Recovery (EOR) 23

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 EOR! and IOR Definitions
  



The
terms EOR and IOR should refer to reservoir processes.
 
 Any practices that are independent of the recovery process itself

  should not be grouped into either EOR or IOR.

Enhanced Oil Recovery (EOR) 24

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Water Flooding

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 Flooding
Water  
 !  Highlights



 
 Process  
   Description
 Water flooding consists of injecting water into the reservoir.

 

Water is injected in patterns or along the periphery of the


reservoir.

Mechanisms that Improve Recovery Efficiency
Water drive
Sweep efficiency
Maintain pressure

26 Copyright 2001-2011 NExT. All rights reserved

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Water Flooding Highlights

Limitations

High oil viscosities result in high mobility ratios resulting in


fingering.

Some heterogeneity is acceptable, but avoid extensive


fractures.

Not-effective in fault barrier


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 Flooding
Water  
 !  Highlights




Challenges  
  
  Poor compatibility between the injected water and the reservoir


 
 rocks may cause formation damage.
 

Subsurface fluid control to divert injected water and to shut off
undesirable produced fluids.

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Currently Used EOR Processes

Group 1: Chemical EOR Methods

1. Polymer Flooding
2. Surfactant/Polymer (SP) Flooding
3. (Caustic) Alkaline/Polymer (AP) Flooding

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4. Alkaline/Surfactant/Polymer (ASP) Flooding


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Enhanced Oil Recovery (EOR) 29

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 Polymer




!  Flooding

 
  

 
 



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Polymer Flooding Highlights

Description
Polymer augmented water flooding consists of adding water
soluble polymers to the water before it is injected into the
reservoir.

Mechanisms That Improve Recovery Efficiency

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Reduction of Mobility Ratio (M), which improves volumetric sweep
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efficiency.

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Shedid, S. A., Influences of Fracture Orientation on Oil Recovery by Water and Polymer Flooding Processes: An Experimental Approach, Journal of Petroleum Science
and Engineering, Volume 50, Issues 3-4, 16 March 2006, Pages 285-292.

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 Flooding



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Polymer Highlights

 
  
Limitations

  1. High oil viscosities require higher polymer concentration.

 

2. Results are normally better if the polymer flood is started
 before the water-oil ratio becomes excessively high.

3. Clays, Gypsum, or Anhydrite increase polymer adsorption.

4. Some heterogeneity is acceptable, but avoid extensive


fractures. If fractures are present, the crosslinked or gelled
polymer techniques may be applicable.

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Polymer Flooding Highlights

Challenges

Lower injectivity than water can adversely affect oil production


rates in the early stages of the polymer flood.

Acrylamide-type polymers loose viscosity due to shear


degradation, salinity and divalent ions.

Xanthan gum polymers cost more, are subject to microbial


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degradation, and have a greater potential for wellbore plugging.
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!
Surfactant/Polymer Flooding

 
  

 
 



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Surfactant/Polymer Flooding Highlights

Description

Surfactant/polymer flooding consists of injecting a slug that contains


water, surfactant, electrolyte (salt), usually a co-solvent (alcohol),
followed by polymer-thickened water.

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Mechanisms That Improve Recovery Efficiency


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Interfacial tension reduction (increasing the Capillary Number, Nc).

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Mobility Ratio (M) Reduction
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   Flooding Highlights
 !
Surfactant/Polymer

  



 An
Limitations
areal sweep of more than 50% for waterflood is desired.

  Relatively homogeneous formation.


 High amounts of anhydrite, gypsum, or clays are undesirable.
  Available systems provide optimum behavior within a narrow
 set of conditions.
With commercially available surfactants, formation water
chlorides should be <20,000 ppm and divalent ions (Ca++ and
Mg++) <500 ppm.

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Surfactant/Polymer Flooding Highlights

Challenges
Complex and expensive system.
Possibility of chromatographic separation of chemicals.
High adsorption of surfactant.
Interactions between surfactant and polymer.
Degradation of chemicals at high temperature.

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 Used
 


!
Currently

EOR Processes

 
  
Group
2: Gas Injection EOR Methods
1. Carbon Dioxide (CO2) Injection
 
 2. Hydrocarbon Gas Injection

  3. Flue gas Injection

4. Nitrogen Gas Injection

5. Water-Alternating-Gas (WAG) Injection.

Enhanced Oil Recovery (EOR) 38

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Miscible Gas Flooding (CO2 Injection)

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Shedid, S. A, Zekri, A. Y.,, and Almehaideb, R. A., Laboratory Investigations of Influences of Initial Oil Saturation and Oil Viscosity on Oil Recovery By CO2 Miscible

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Flooding, Paper SPE 106958, The SPE Europec/EAGE Annual Conference and Exhibition, 11-14 June, London, U. K, 2007.



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Gas 
Flooding

Miscible

!  (CO Injection) 2

 
  
CO flooding consists of injecting large quantities of CO
Description
(15% or

2 2

 more hydrocarbon pore volumes) in the reservoir to form a miscible



 flood.

Mechanisms That Improve Recovery Efficiency
CO2 extracts the light-to-intermediate components from the oil,
and, if the pressure is high enough, develops miscibility to
displace oil from the reservoir.
Viscosity reduction / oil swelling.

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Miscible Gas Flooding (CO2 Injection)

Limitations
1. Very low Viscosity of CO2 results in poor mobility control.

2. Availability of CO2

3. Surface Facilities

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 Flooding





Miscible Gas
!  (CO Injection) Highlights

 
 

Challenges

 Early breakthrough of CO causes problems. 2

 

Corrosion in producing wells.
 The necessity of separating CO2 from saleable hydrocarbons.
Repressuring of CO2 for recycling.

A large requirement of CO2 per incremental barrel produced.

42 Copyright 2001-2011 NExT. All rights reserved

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Miscible Gas Flooding (Hydrocarbon Injection)

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 Gas Flooding
(Hydrocarbon
Miscible

! Injection) Highlights

  



Hydrocarbon
Description


gas flooding consists of injecting light hydrocarbons

 through the reservoir to form a miscible flood.

 

Mechanisms that Improve Recovery Efficiency

Viscosity reduction / oil swelling / condensing or vaporizing gas


drive.

Shedid, S. A., Zekri, A. Y., Almehaideb, R. A., Optimization of Carbon Dioxide Flooding For a Middle-Eastern Heterogeneous Oil Reservoir, Canadian International
Petroleum Conference (CIPC)/SPE, Calgary, Alberta, Canada, 16- 19 June, 2008.

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Miscible Gas Flooding (CO2 Injection)

Limitations
Minimum depth is set by the pressure needed to maintain the
generated miscibility.
The required pressure ranges from about 1,200 psi for the LPG
process to 3,000-5,000 psi for the High Pressure Gas Drive,
depending on the oil.

A steeply dipping formation is very desirable - permits gravity


stabilization of the displacement that normally has an
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unfavorable mobility ratio.
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Gas 
Flooding

Miscible

!  (CO Injection) 2

 
  
Challenges


  Viscous fingering results in poor vertical and horizontal sweep

 

efficiency.

 Large quantities of expensive products are required.

Solvent may be trapped and not recovered.

46 Copyright 2001-2011 NExT. All rights reserved

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Nitrogen / Flue Gas Flooding

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/ Flue 
 Gas Flooding Highlights
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Nitrogen 

  



 Nitrogen
Description
 or flue gas injection consists of injecting large quantities of


gas that may be miscible or immiscible depending on the pressure
 and oil composition.
  Large volumes may be injected, because of the low cost.


Nitrogen or flue gas are also considered for use as chase gases in
hydrocarbon- miscible and CO2 floods.
Mechanisms that Improve Recovery Efficiency
Vaporizes the lighter components of the crude oil and generates
miscibility if the pressure is high enough.
Provides a gas drive where a significant portion of the reservoir
volume is filled with low-cost gases.

48 Copyright 2001-2011 NExT. All rights reserved

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Nitrogen / Flue Gas Flooding Highlights

Limitations

Miscibility can only be achieved with light oils at high pressures;


therefore, deep reservoirs are needed.

A steeply dipping reservoir is desired to permit gravity stabilization


of the displacement, which has a very unfavorable mobility ratio.

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/ Flue 
 Gas Flooding Highlights
 !
Nitrogen 

  



Challenges

  Viscous fingering results in poor vertical and horizontal sweep

 efficiency.

  Flue gas injection can cause corrosion.

Non hydrocarbon gases must be separated from saleable gas.

50 Copyright 2001-2011 NExT. All rights reserved

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Currently Used EOR Processes

Group 3: Thermal EOR Methods

- Steam-Based Thermal Processes:


A. Cyclic Steam Injection (Huff and Puff)
B. Continuous Steam Stimulation (CSS)
C. Steam Assisted Gravity Drainage (SAGD)

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- Non-Steam Based Thermal Processes
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A. In-Situ Combustion Flood includes

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(i) Dry (without water) In-Situ Combustion

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(ii) Wet (with water) In-Situ Combustion

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B. Surface Mining Processes

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Enhanced Oil Recovery (EOR) 51

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  (Steam Flooding)
Thermal
 !



   


 
 



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Steam Flooding Highlights

Description
Steamflooding consists of injecting about 80% quality steam to
displace oil.
Normal practice is to precede and accompany the steam drive by a
cyclic steam stimulation of the producing wells (called huff and
puff).

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Mechanisms That Improve Recovery Efficiency
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Viscosity reduction / steam distillation.
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Thermal expansion.

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Supplies pressure to drive oil to the producing well.
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 Flooding
Steam  
 !  Highlights




   

1.Limitations

  Applicable to viscous oils in massive, high permeability

 sandstones or unconsolidated sands.

  2. Oil saturations must be high, and pay zones should be > 20
feet thick to minimize heat losses to adjacent formations.

3. Steam flooded reservoirs should be as shallow as possible,


because of excessive wellbore heat losses.

54 Copyright 2001-2011 NExT. All rights reserved

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Steam Flooding Highlights

More Limitations

Steamflooding is not normally done in carbonate reservoirs.


Since about 1/3 of the additional oil recovered is consumed to
generate the required steam, the cost per incremental barrel of oil
is high.
A low percentage of water-sensitive clays is desired for good
injectivity.
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Challenges
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Adverse mobility ratio and channeling of steam.

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 Fire
  Flooding
 !
  




Dry combustion
Injection of compressed

  air and normally some


thermal energy


Wet combustion
 Simultaneous injection
of air and water
Water acts as scavenger
of heat, converts into
steam

56 Copyright 2001-2011 NExT. All rights reserved

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Fireflood Highlights

Description
Fire flooding process is initiated by injecting air for a short period,
so as to establish a continuous gas phase between the injector
and producer.
The gas saturation at a distance ahead of the front is high enough
to allow the combustion gases to flow to the production end
without undue pressure drop
Some distance beyond the front, water is condensing, and the oil
is swept forward by the gas and steam to form a oil bank
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Mechanisms That Improve Recovery Efficiency
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Viscosity reduction / in-situ upgrading.

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Thermal expansion.
Supplies pressure to drive oil to the producing well.
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 (Steamflooding)




!
Thermal Highlights

 
 Limitations


 Fire flooding has found less success than steam processes

 
 because of the difficulty in controlling the process
 
 Fire front tend to advance much erratically than steam front, and it
is much harder to obtain an even sweep of the reservoir

58 Copyright 2001-2011 NExT. All rights reserved

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Heavy Oil Recovery Processes

Recovery Processes Surface Mining


In-situ

Primary Thermal Non-Thermal

Cold Production Steam-Based Combustion Water Flooding


CHOPS CSS Fire Flooding Chemical (ASP)
Flooding THAI Miscible/Immiscible
SAGD CAPRI VAPEX

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Steam-Solvent Based Hybrid Processes
 
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CHOPS Cold Heavy Oil Production with Sands


CSS Cyclic Steam Stimulation


SAGD Steam Assisted Gravity Drainage

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THAI Toe-to-Heel Air Injection

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VAPEX Vapour Extraction
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Screening
 Criteria for EOR Methods
 !
Summary

of 




METHOD

OIL PROPERTIES


  
Waterflood
Gravity, API
>25
Viscosity, cp
<30
Composition
N.C.
Oil Saturation
>10% mobile oil

  Hydrocarbon >35 <10 High % of C2-C7 >30% PV

  GAS
Nitrogen & >24
 INJECTION <10 High % of C1-C7 >30% PV

Flue Gas >35 for N2
METHODS
Carbon Dioxide >26 <15 High % of C5-C12 >30% PV
Surfactant / Light intermediate
>25 <30 >30% PV
CHEMICAL Polymer desired
FLOODING Polymer >25 <150 N.C. >10% PV
METHODS Above waterflood
Alkali 13-35 <200 Some organic acids
residual
<40 (10-25 Some asphaltic
THERMAL Combustion normally) <1000 components
>40-50% PV
METHODS
Steamflooding <25 >20 N.C. >40-50% PV
60 Copyright 2001-2011 NExT. All rights reserved

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Summary of Screening Criteria for EOR Methods (contd.)

RESERVOIR CHARACTERISTICS

METHOD Formation Type


Net
Thickness
Permeability Depth Temp.
(md) (ft) (F)
(ft)
Waterflood Sandstone or Carbonate

Hydrocarbon Sandstone or Carbonate


GAS
INJECTION Nitrogen & Flue Gas Sandstone or Carbonate
METHODS Carbon Dioxide Sandstone or Carbonate

Surfactant / Polymer Sandstone or Carbonate


CHEMICAL
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>10
#
)"
Sandstone preferred;
FLOODING Polymer N.C. <9000 <200

 $, "
Carbonate possible (normally)

 &"
METHODS
Alkali Sandstone preferred N.C. >20

<9000

 !
<200


Sand or Sandstone with >150
Combustion
+
>10 >10 >500

 *
THERMAL high porosity preferred
 &N.C.
METHODS Steamflooding
Sand or Sandstone with
high porosity
>20

 >200

300-
5000
!

 )
61

 '! ( !
Copyright 2001-2011 NExT. All rights reserved

 
 %&
  "#$
Technical

 Constraints
 ! 




  of EOR Constraints (I-DOE NIPER 527)



Classification
Classification

  Explanation

Mobility Control Gas channeling related to mobility rather than
 

heterogeneity; breakdown of polymer bank due to

  bacterial degradation
 Operation Problems with oil treating, corrosion, scale,
artificial lift, compression, formation plugging
unrelated to injectant quality
Reservoir Refers to reservoir fluid conditions such as oil
Condition saturation, thickness of oil column, reservoir drive
mechanism, etc. As defined, reservoir conditions
are a subset of reservoir description

62 Copyright 2001-2011 NExT. All rights reserved

31
1/10/2016

Technical Constraints

Classification of EOR Constraints (I-DOE NIPER 527)

Classification Explanation

Reservoir Description Refers to rock related description such as depositional


environment, rock composition, faulting, heterogeneity,
continuity, etc.

$%
Reservoir Areal or vertical permeability variations, faults, directional flow


#
Heterogeneity trends, depositional environments, etc. )"
   $, &"
"
 !
Process Design Inadequate or incomplete investigation of different areas
known to be important in the EOR processes.
   &+
)*   !
63

 '!
(!
Copyright 2001-2011 NExT. All rights reserved

 
 %&
  "#$
Technical

 Constraints
 ! 




 of EOR Constraints (I-DOE NIPER 527)



Classification
Classification

  Explanation
 
 Chemical Loss

Loss of injected fluid due to chemical, mechanical, or microbial
 degradation; chemical loss due to adsorption, ion exchange, or

 entrapment.

Downhole Completion Completion techniques; equipment; production problems


unrelated to corrosion, scale, or artificial lift.

Facility Design Surface injection or production facilities.


Gravity Segregation Gravity override in Steam; potential may exist for override in situ
combustion or gas injection projects

64 Copyright 2001-2011 NExT. All rights reserved

32
1/10/2016

Technical Constraints

Classification of EOR Constraints (I-DOE NIPER 527)


Classification Explanation

Injectivity Process specific to gas injection projects. Low


polymer injectivity in chemical projects was
considered inherent to the polymer process.

Injection Control Formation pressure parting; injected fluid flow out


of intended zone; inadequate monitoring of
$%

injection. #
)"
Injectant Quality
 
Steam quality at sandface; injection well plugging $, &"
"

 & 
related to poor mixing (polymer) or injection 
  +!
  !
system contaminants (rust, lubricants).

)*
65

 '!
(!
Copyright 2001-2011 NExT. All rights reserved

 
 %&
  "#$
  
 !
  




 
 



Copyright 2001-2011 NExT. All rights reserved

33

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