Preparation and Standardization of Acid and Base

I. Preparation of 1 Liter 0.1M NaOH

Trial Wt. KHP (g) Vol. NaOH (mL) M NaOH

1 0.3014 15.6 0.0946
2 0.3120 16.2 0.0943
3 0.3009 15.6 0.0944
Average 0.0945

II. Preparation of 1 Liter 0.1M HCl

Trial Wt. Na2CO3 (g) Vol. HCl (mL) M HCl

1 0.1043 29.1 0.0676
2 0.1067 29.9 0.0673
3 0.1085 30.45 0.0672
Average 0.0674
Using a pH Electrode for an Acid-Base Titration
Wt. Tris (g) = 2.041
FW Tris = 121.14
Vol Tris (mL)= 50
M Tris = 0.3370

Trial 1 Trial 1 Trial 1

Volume (mL) pH Volume (mL) pH Volume (mL) pH
0 ---- 0 10.354 0 ----
5 9.151 10 8.754 10 8.887
10 8.771 20 8.201 20 8.254
15 8.556 30 7.814 30 7.857
20 8.306 40 7.334 40 7.381
25 8.037 45 6.911 45 6.964
30 7.815 46 6.779 46 6.834
35 7.604 47 6.597 47 6.676
40 7.332 48 6.292 48 6.412
45 6.907 48.5 6.057 48.5 6.211
46 6.779 49 5.438 49 5.829
47 6.603 49.5 3.641 49.5 4.294
48 6.325 50 3.280 50 3.447
49 5.581
50 3.310

Trial 2
10
9
8
7
6
5
pH

4
3
2
1
0
10 20 30 40 45 46 47 48 48.5
Volume (mL)
 Trial 1
10
9
8
7
6
5
pH

4
3
2
1
0
5 10 15 20 25 30 35 40 45 46 47 48 49 50
Volume (mL)

ial 2 Trial 3
10
9
8
7
6
5
pH

4
3
2
1
0
46 47 48 48.5 49 49.5 50 10 20 30 40 45 46 47 48 48.5
olume (mL) Volume (mL)
 47 48 49 50

Trial 3

46 47 48 48.5 49 49.5 50
Volume (mL)