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Paper II
Time Allowed : 75 Minutes] [Maximum Marks : 100
Note : This Paper contains Fifty (50) multiple choice questions, each question
carrying Two (2) marks. Attempt All questions.
1 [P.T.O.
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12. The major axis of symmetry of a 15. On the basis of the following
molecule is 6 and it has nC2 axes information for the reaction,
perpendicular to this axis. The value 4 2
Al + O2 Al O
of n is : 3 3 2 3
(A) 1 G = 827 kJ . mol1
The minimum EMF to be applied for
(B) 2 the electrolysis of Al2O3 is :
(C) 3 (A) 8.56 V
(B) 6.42 V
(D) 6
(C) 4.28 V
13. The co-ordination number of a (D) 2.14 V
cation, in an ionic solid in which the 16. What are the values of the mean
arrangement of the anions around and median of the following six
it is cubic, is : burette readings ?
19.4, 19.5, 19.6, 19.8, 20.1, 20.3
(A) 4
(A) 19.7, 19.7
(B) 6 (B) 19.8, 19.6
(C) 8 (C) 19.8, 19.7
(D) 19.7, 19.8
(D) 10
17. IUPAC name of the following
14. In the rotational spectra of diatomic compound is :
molecules, the spacing between
successive lines is equal to :
h
(A)
4 2Ic
h
(B) 2 2
4 Ic
h
(C) (A) Cis-bicyclo[3.3.0]decane
4 2Ic2
(B) Trans bicyclo[4.4.0]decane
4h (C) Cis-bicyclo[2.2.0]decane
(D)
2Ic (D) Cis-bicyclo[4.4.0]decane
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according to Cahn-Ingold-Prelog
rule is :
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rearrangement example of :
rearrangement (
Al OCHMe2 )
3
(C) Only Curtius rearrangement Isopropanol
rearrangement
Sodium silicate
24. HCHO + CH3CHO
300C
H2C=CHCHO
is an electrophile.
reduction
(B) Above reaction is a Perkin
a nucleophile.
(B) Oppenauer oxidation
(C) Above reaction is an Aldol
5 [P.T.O.
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gives :
O
(A) Benzaldehyde
(A)
(B) Benzene
O
in the presence of peroxide gives :
(C)
(A) 2-Bromo-2-phenylpropane
(B) 1-Bromo-1-phenylpropane
(C) 2-Bromo-3-phenylpropane
(D)
(D) 2-Bromo-1-phenylpropane
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29. The products formed in the following 32. A compound shows M + 1 peak with
reaction are :
9.997% intensity. Therefore, the
(i) O3 number of carbons in the molecular
H3CCH=CH2 ?
(ii) Zn, H2O
formula is :
(A) 2 moles of acetaldehyde (A) 10
(B) 2 moles of formaldehyde
(B) 09
(C) 1 mole of acetaldehyde and
(C) 08
1 mole of formaldehyde
(D) 11
(D) 1 mole of acetone and 1 mole
of formaldehyde 33. Azurin is a copper containing
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(A) CaCl2
(D) 1.01
(B) CaF 2
40. Frenkel defects are usually observed 42. [(NH 3)4Rh(-OH)2Rh(NO2)4] and
[(NH 3 ) 2 (NO 2 ) 2 Rh(-OH) 2 (NH 3 ) 2
in : (NO2)2] are examples of :
3+
order of stability of the complexes
(
(A) Cr H2O
6
)
(en = ethylenediamine, trien =
2+
triethylenetetramine) : (
(B) Fe H2O
6
)
(A) [Cu(en)2]Cl2 > [Cu2(en)2](NO3)2 2+
(
(C) Cu H2O
6
)
> [Cu(en)2]SO4
2+
(B) [Cu(trien)]Cl2 > [Cu(en)2]Cl2 > (
(D) Zn H2O
6
)
[Cu(NH3)4]Cl2 44. The ground state value of J for 3F
term for V3+ is :
(C) [Ag(NH3)2]Cl > [Au(NH3)4]Cl >
(A) 0
[Cu(NH3)4]Cl
(B) 1
(D) [Cr(en)2]Cl2 > [Cu(en)2]Cl2 > (C) 2
[Zn(en)2]Cl2 (D) 4
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45. The H-A-H bond angle in the 48. pH of the buffer solution of 0.2M
following hydrides with general
CH3COONa and 0.1M CH3COOH
formula AH3 follows the order :
(Ka = 105) is :
(A) AsH3 > PH3 > NH3
(A) 5.30
(B) PH3 > AsH3 > NH3
(B) 0.53
(C) NH3 > AsH3 > PH3
46. Both NF3 and NCl3 are covalent but (D) 2.53
they do not undergo hydrolysis
49. Which of the following metal ions
similarly because :
can form bent metallocene ?
(A) NF3 is more stable than NCl3
(A) Zr2+
(B) Dipole moment of NF3 is more
than NCl3 (B) Fe2+
(C) Electronegativity of F is greater
(C) Ru2+
than Cl
(D) Co2+
(D) Cl can expand its octet by using
d-orbitals 50. Which of the following will form
47. In which of the following bonds does clathrates ?
H carry -ve charge ?
(A) K
(A) F-H
(B) He
(B) O-H
(C) Kr
(C) B-H
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ROUGH WORK
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ROUGH WORK
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