01. The direction of force due to surface tension 08.

If a capillary tube is of square bore of each

acting on a molecule of a liquid surface -- side a and angle of contact of liquid with the
(A) in tangential direction wall of container is zero. The surface tension of
(B) in downward direction the liquid is T. Then height to which liquid
(C) is normal to wall of container column will rise is given by
(D) is zero as it is balanced by intermolecular (A)2T/ag (B) 4T/ ag
force (C)T/ g (D) 4aT/ g
02. Liquid rises up to 4.5cm in a glass capillary 09. If critical temperature of a liquid is 100oC
of radius 0.01cm. The rise of liquid will be up to then the constant in expression of surface
what height if the glass capillary is of radius tension at different temperature is numerically
0.02cm? equal to
(A)9cm (B)2.25cm (A)0.01 (B)100
(C)4.5cm (D)1.125 cm (C)10 (D)boiling temperature
03. A soap film is formed on a rectangular area 10. Liquid rises in a capillary up to 12cm height
4cm x 4cm. If the area of the frame is increased and radius of curvature is R. When capillary is
to 4cm x 5cm then the work done in the process cut at 10cm then liquid will
if the surface tension of soup solution is 3 x 10-2 (A) overflow
N/m (B) come out as fountain
(A)6 x 10-5 J (B)3 x 10-3J (C) rise to 10cm & rad.of curvature will be < R
(C)2.4 x 10-5J (D)1.2 x 10-3J (D)rise up 10cm & rad. of curvature will be > R
04.The diameter of soup bubble which is made 11. The surface tension at 0oC is To. When
up of a solution with surface tension 3.2 x 10-2 temperature rises by 1 the surface tension
N/m and with additional pressure of 51.2N/m2 decreases by 1 and when it rises by 2 the
inside is change is surface tension is 2 then the value of
(A)5cm (B)2mm (C)2.5mm (D)5mm in expression for surface tension is
05. If a soup film formed on a loop is punctured 2 1 1 2
from lower end then the thread will take shape (A) (B)
as shown T0 (1 2 ) T0 (1 2 )
T ( 1 ) 2 1
(C) 0 2 (D)
(1 2 ) T0 (1 2 )
12. An experiment which estimates the surface
tension by capillary rise is taken below and
(A) (B) (C) (D) above the surface of earth by small but equal
distance. The set up is highly sensitive then the
06. The force of attraction between two rise of liquid column in capillary tube is
different molecules of mass m1 and m2 is called (A) same in both cases
as (A) (B) (C) (D)
(B) more when taken below and less for above
(A) adhesive (B) cohesive (C) less when taken below and more for above
(C) gravitation (D) both A and C (D) no rise when taken below
07. . A number of liquid droplets each of radius 13. In an experiment to determine surface
r, liquid density and of specific heat c tension of liquid which has angle of contact as
coalesce to form a drop of radius R the rise in 60o it was observed that h = 5cm, when a
temperature d is capillary of radius 3cm is used if density of liquid
3T 1 1 is 2units and g represents acceleration due to
(A) 2T/rJ (B) gravity then surface tension will be numerically
c. .J r R
equal to
3T 1 1 (A)30g (B)36g
(C) 4T(nr2 R2) (D)
J r R (C)24g (D)16g
14. When insoluble impurity of density 2.1g/cm3 22.A capillary tube made of glass is dipped in to
is added to water, surface tension of water is mercury. Then, mercury
0.561N/m the surface tension of water after (A) rises in a capillary tube
addition may be (B) falls in a capillary tube
(A)0.651N/m (B)0.782N/m (C) rises & flows out of the capillary tube
(C)0.516N/m (D)0.561N/m (D) neither rises nor falls in the tube
15. If two soap bubbles of different radii are
connected by a tube 23.Energy needed in breaking a drop of radius R
(A) air flows from the smaller bubble to the into n drops of radius r, is ( T is surface tension
bigger & P is atmospheric pressure )
(B) air flows from the bigger bubble to the (A) (4 2 42 )
smaller bubble till the sizes are interchanged 4 4
(B) (3 2 3 2 )
(C) air flows from the bigger bubble to the
(C) (42 4 2 )
smaller bubble till the sizes become equal
(D) there is no flow of air. (D) (42 4 2 )
16.Small droplets of a liquid are usually more 24.When a large air bubble rises from the
spherical in shape than larger drops of the same bottom of a lake to the surface, its radius
liquid because doubles. If the atmospheric pressure is equal to
(A) force of surface tension is equal and opposite that of a column of water of height H, then
to the force of gravity depth of the lake is
(B) force of surface tension predominates the (A) H (B) 2H (C) 7H (D) 8H
force of gravity 25.A spherical drop of radius R is divided into
(C) force of gravity predominates force of eight equal droplets. If surface tension is T, then
surface tension the work done in this
(D) force of gravity & force of surface tension (A)22 (B)32
act in the same direction and are equal. (C)4 2
(D)2 2
17.A liquid doesnt wet the sides of a solid, if 26.The work done in blowing a soap bubble of 10
the angle of contact is cm radius is (in J) ( surface tension of soap
(A) zero (B) obtuse solution is 0.03 Nm-1 )
(C) acute (D) 900 (A) 37.68 x 10-4 (B) 75.36 x 10-4
18.The surface tension of soap solution is . (C) 126.82 x 10 -4 (D) 75.36 x 10-3
What is the work done in blowing soap bubble of 27.A spherical drop of water has 1 mm radius. If
radius r the surface tension of water is 70 x 10-3 N/m,
(A) 2 (B) 2 2 the difference of pressure between inside &
(C) 4 2 (D)8 2 outside of the drop is ( in N/m2)
19.The radius R of the soap bubble is double (A) 35 (B) 70 (C) 140 (D) 0
under isothermal condition. If T be the surface 28.Suppose W is the work done when a bubble of
tension of soap bubble, the work done in doing volume V is formed from a soap solution. How
so is given by much work is required to be done to form a
bubble of 2V
(A) 322 (B) 242
(A) W (B) 41/3 W (C) 21/3W (D) 2W
(C)82 (D)42
29.Excess pressure of one soap bubble is four
20.In a capillary tube, water rises to 3mm. The
times the other soap bubble. Then ratio of
height of water that will rise in another capillary
volume of first bubble to the other is
tube having one-third radius of the first is
(A) 1:64 (B) 1:4 (C) 64:1 (D) 1:2
(A) 1 mm (B) 3 mm
30.If the surface tension of water is 0.06 N/m
(C) 6 mm (D) 9 mm
the capillary rise in a tube of diameter 1 mm
21.The force of cohesion is maximum in
is( = 00 )
(A) solids (B) gases
(C) liquids (D) All of these (A) 1.22cm (B) 2.44cm
(C)3.12cm (D)3.86cm
31. The force of attraction between two 40.At the boiling point of a liquid, surface
molecules of the different substances is tension
(A) adhesive force (B) molecular force (A) is zero
(C) cohesive force (D) intermolecular force (B) is infinite
32.The maximum distance up to which the (C) is same as that of any other temperature
intermolecular forces are effective is (D) cannot be determined
(A) molecular range 41. If the maximum force in addition to the
(B) radius of the molecule weight, required to pull a wire frame 5.0 cm
(C) sphere of influence of that molecule long from a water frame 5.0 cm long from a
(D) molecular force water surface at a temperature of 20OC is 720
33.An imaginary sphere drawn with molecular dyne, the surface tension of water will be
range as radius and molecule as centre is a (A) 72.0 dyne/cm (B) 145 dyne/cm
(A) range of molecular attraction (C) 7.28 dyne/cm (D) 7.28 N/m
(B) sphere of influence of that molecule 42. A capillary tube of uniform bore is dipped
(C) diameter of that molecule vertically in water which rises by 7 cm in tube.
(D) radius of molecular attraction Then the radius of capillary tube is
34.When the adhesive force between a liquid (S.T. of water is 70 dyne/cm, g = 1000 cm/s2,
and glass is greater than the force between the = 0O)
liquid molecules, the meniscus of the liquid in a (A) 0.2 mm (B) 2 mm
capillary tube is (C) 0.2 cm (D) 2 cm
(A) convex (B) concave 43.Water rises to a height of 2 cm in a capillary
(C) plane (D) horizontal tube. If its diameter is made (2/3)rd, the water
35.If the force of cohesive is equal to the force will now rise to a height of
of adhesive, then the liquid surface will be (A) 6 cm (B) 3 cm
(A) convex (B) concave (C) 2/3 cm (D) 3/2 cm
(C) plane (D) cylindrical 44.A capillary tube when immersed vertically in
36.The dimensions of surface tension are a liquid records a rise of 3 cm. If the tube is held
(A) [M0 L1 T-2] (B) [M0 L0 T-1] immersed in the liquid at an angle of 60O with
(C) [M1 L0 T-2] (D) [M1 L1 T-2] the vertical, the liquid column along the tube
37.A needle can float on clear water but sinks will be
when some detergent is added to it. This (A) 3 cm (B) 4.5 cm
happens because (C) 6 cm (D) 7.5 cm
(A) addition of detergent increases the density 45.A ring of radius 0.75 cm is floating on the
of water surface of water. If surface tension of water is
(B) addition of detergents reduces the surface 0.07 N/m, the force required to lift the ring
tension of water from the surface of water will be
(C) solution of detergent decreases the density (A) 66 x 10-1 N (B) 66 x 10-2 N
of water (C) 1.05 x 10-3 N (D) 66 x 10-4 N
(D) addition of detergent increases the surface 46. When a clean glass tube of small boar is
tension of water immerged in pure water the water will
38.The SI unit of surface tension is (A) rise as angle of contact is zero
(A) N/m (B) dyne/cm (B) rise as angle of contact is obtuse
(C) J/m2 (D) A and C (C) fall as angle of contact is acute
39.The surface tension of a liquid with the rise (D) neither rise nor fall as angle of contact is
in temperature zero
(A) decreases (B) increases 47. If liquid rise in capillary is by volume V. Now
(C) constant the radius of capillary is made half then the
(D) independent of temperature volume rise will be
(A)2V (B)4V (C)V/4 (D)V/2
 (D) The reaction takes place with active metals
48. In an experiment to obtain relation between like Na.
surface energy and surface Among above correct statements are
tension the wire CD moves (A) (A) and (B) (B) (A), (B) and (C)
due to external force with (C) (B), (C) and (D) (D) All of these.
isothermal condition with 57. For the reaction____
(A)constant acceleration C2H5OH + HX ZnCl2 C2H5X.
(B)constant velocity The order of reactivity is ----
(C)no condition of motion (A) HCl > HBr > Hl (B) HBr > Hl > HCl
(D) acceleration so that film remain intact (C) HI > HCl > HBr (D) HI > HBr > HCl
49. If the radius of sphere of influence is 0.1mm 58. Grignards reagent contains ------
then molecules of liquid which are at distance d (A) Covalent bond between Mg and X
from upper surface will posses potential energy (B) Ionic bond between R and Mg
(C) Both (A) and (B)
if
(D) Neither (A) nor (B)
(A) 0 d 0.1mm (B) 0 d 0.05mm 59. An SN2 reaction takes place with
(C) 0 d 0.2mm (D) d has any value (if chiral centre is given)-
50. When captain Jack Sparrow was sailing in sea (A) Retention of configuration
he came across heavy sea storm and has to face (B) Inversion of configuration
high waves even if winds were with low speed he (C) Racemisation
will prefer to (D) Partial racemisation
(A)throw oil cans to reduce weight of black pearl 60.
(B)throw oil from cans to reduce surface tension Me
SOCl
of sea Ph COH 2

in C5H5N
(C)take down the wind shields H
(D) will send SOS to captain Jone Which statement is true for the above reaction?
(A) Retention of configuration
51. Position isomer of 2-chloropropane when react (B) Inversion of configuration
with aq. KOH it gives functional isomer of (C) Inversion and Retention both
(A) 2-methylpropanol (B) 2-chloropropanol (D) None
(C) methoxy ethane (D) methoxy methane 61.Chlorobenzene is_____
52. When propene reacts with HCl in the presence (A) Less reactive than benzyl chloride
of peroxide what product will be formed? (B)More reactive than ethyl bromide
(A) iso-propyl chloride (B) n-propyl chloride (C) Nearly as reactive as methyl chloride
(C) A or B (D) propane (D) More reactive than isopropyl chloride
53. Which of the following shows negative
inductive effect? 62. Toluene reacts with a halogen in the presence
(A) NO2(B) CH3 (C)OCH3 (D) Both A & C of iron(III) chloride giving ortho and para halo
54. The backside attack on substrate occurs in --- compounds. The reaction is__
(A) SN1 (B) SN2 (A) Electrophilic elimination reaction
(C) reaction of phenol with Br2 (D) Both A & B (B) Electrophilic substitution reaction
55. Which of the following vibrates in different (C) Free radical addition reaction
planes perpendicular to its direction of (D) Nucleophilic substitution reaction
propagation? 63. Bromobenzene when react with sodium metal
(A) Monochromatic light (B) ordinary light under dry condition gives__
(C) Both A & B (D)Plane polarized light (A)Toluene (B)naphthalene
56. Some statements about Wurtzs reaction are (C)diphenyl (D)no reaction takes place
given below 64. By Wurtz reaction a mixture of methyl iodide
(A) It is used to prepare saturated hydrocarbons and ethyl iodide gives__
other than methane (A)butane (B)ethane
(B) Higher alkanes containing odd no. of carbon (C)propane (D)mixture of all three (A), (B) & (C)
atoms can be prepared
(C) The reaction takes place in presence of dry
ether.
65. During alkaline hydrolysis of t-butyl bromide if 75. Methyl chloride reacts with AgCN and KCN
concentration of alkali is tripled then reaction gives ____respectively.
rate__ (A) methyl isocyanide & methyl cyanide
(A)will be doubled (B)will be halved (B) methyl cyanide & methyl isocyanide
(C)remains unaffected (D)cant be predicted (C) both methyl isocyanide
66. ____ is having highest nucleophilicity? (D) both methyl cyanide
(A)F- (B)OH- (C)CH3- (D)NH2- 76. Hydrogen atom in CHCl3 is
67. Which of the following compound undergoes (A) neutral (B) acidic
SN1 reaction faster? (C) basic (D) amphoteric
Cl
Cl CH2Cl
77. A racemic mixture is optically inactive because
of___
(A)internal compensation (B) external
compensation
(C) absence of chiral C-atom(D) unpredictable
Cl

(A) (B) (C) (D)

78. Kharash effect is applicable only for
68. Which type of isomerism do alkyl halides show
(A) HCl only (B) HI only
will not show?
(C) HF only (D) HBr only
(A) Chain isomerism (B)Position isomerism
79. When alkyl halide when boiled with moist
(C) Metamerism (D) Both (A) and (B)
silver oxide form___
69.For the conversion of alkanes to alkyl halide,
(A) ether (B) alcohol
the order of reactivity of halogen is :
(C) chloride (D) isocyanide
(A) F2 > Cl2 > Br2 > I2 (B) Cl2 > Br2 > F2 > I2
80. Many halogen derivatives are commercially
(C) Cl2 > F2 > Br2 > I2 (D) I2 > Br2 > Cl2 > F2
important as__
70. Dehydrohalogenation of an alkyl halide is a/an
(A) cleaning agent (B) refrigerant
(A) nucleophilic substitution reaction
(C) proellants (D) all of the above
(B) elimination reaction
81. In this reaction
(C)both nucleophilic substitution and elimination
reaction
(D) rearrangement reaction
71. Which of the following compound can exhibit
optical isomerism?
(A) HOOCCH (OH) COOC2H5 (a)2-ethoxy-2-methylbutane is the major product
(B) CH3 CH (OH) COOH in the presence of ethoxide ion
(C) CH3 (COOH) CH (CH3) (b)mixture of 2-methyl-2-butene and 2-methyl 1-
(D) Both (A) & (B) butene is formed in the presence of ethoxide ion
72. Select true statement. (c)both are correct
(A) Under extreme conditions aryl halides undergo (d)none of these
nucleophilic substitution. 82. ethyl propionate can be prepared by treating
(B) The C-X bond length in aryl halides is shorter ethyl bromide with :
by value of 8 pm, as compared with that of alkyl (A) Silver propionate (B) silver butanoate
halides. (C) methyl acetate (D) none of these
(C) Due to resonance, C-X bond in aryl halides 83. Which of the following gives symmetric dialkyl
possesses double bond character. ether?
(D) All of these. (A) R X + Na-OR (B) R-X + NaOR

73. Which one of the following is most reactive (C) R X + Na-OR (D) All of the above
towards SN1 reaction? 84. The total number of electron present in the
(A) C6H5CH2Br (B)C6H5CH (C6H5 )Br central carbon atom of methyl free radical__
(C) C6H5CH (CH3)Br (D)C6H5C(C6H5 )(CH3)Br (A)7 (B)8 (C)9 (D)6
74. Identify the correct order of priority. 85. The phosphorous tribromide required for the
(A) I > SO3H > OH >NO2(B)I > SO3H > NO2 >OH preparation of alkyl bromides by using alcohol, is
(C) SO3H > I > OH >NO2(D)I > NO2 > OH > SO3H obtained as follows.
(A) AlCl3+Br2 (B) NaBr+H2SO4
(C) Red P+Br2 (D) Yellow P+Br2
86. In aryl halides, the reactivity is controlled by 92. Which of the following option is having
_______& the o,p orientation is controlled by___. required reactants to convert methyl iodide into
(A) weaker inductive effect & stronger resonating methyl benzene?
effect resp. (A) bromobenzene (B) sodium & benzene
(B) stronger inductive effect & weaker resonating (C) bromobenzene & sodium
effect resp. (D) bromobenzene & sodium progesterone
(C) inductive effect & resonating effect resp. 93. Alcoholic solution of KOH is a specific reagent
(D) weaker inductive effect & weaker resonating for__
effect resp. (a)dehydration (b) dehalogenation
87. Which of the following is not a characteristic of (c) dehydrohalogenation (d) dehydrogenation
arenes? 94. _____has only one asymmetric carbon atom.
(A) more stability (A) 2-Chloro-2-methyl propane(B) 2-Chlorobutane
(B) resonance (C) Glucose (D) all of the above
(C)delocalization of pi electrons 95. Reaction of t-butyl bromide with sodium
(D) electrophilic addition reaction. methoxide produces
88. In which of the following reactions, hexane will (a)isobutane (b)isobutylene
be formed as a minor product? (c)sodium-t-butoxide (d)t-butylmethylether.
(A) reaction between propyl chloride & sodium in 96. Generally alkyl halides are insoluble in water
presence of dry ether. because
(B) reaction between pentyl chloride & methyl (A) they are very viscous
chloride & sodium in presence of dry ether. (B) they do not form H bonds with water
(C) reaction between ethyl bromide & butyl (C) they do not ionize
bromide & sodium in presence of dry ether. (D) they have strong C-X bond
(D) Both (A) & (B) 97. SN1 mechanism of R-X is favoured by:
89. Which of the following is formed when water is (A) higher concentration of nucleophile
reacted with methyl magnesium iodide? (B) polar solvents
(A) dimethyl ketone (B) methane (C) presence of less bulky alkyl groups
(C) ethane (D) ethanol (D) all of the above
90. How many (O-O) bond are present in benzoyl 98. In the following reaction, the final product is_
peroxide? CH3CH 2 I alc
.KOH

X
Y Z
HBr
KCN

(A) 3 (B) 2 (C) 1 (D) 0

(A) CH3CH2CN (B) CH3CH2CH2NH2
91. When HBr reacts with propene the major
(C) C2H5 NH2 (D) CH3CH2CH2CN
product forms from antimorkownikoffs rule in 1
99. In SN mechanism, the attack on tertiary butyl
presence of benzoyl peroxide has an intermediate
carbocation by OH nucleophile occurs from --
product as
(A) Front side (B) Back side
(A) carbocation (B) carbanion
(C) Both (A) & (B) (D) Data incorrect
(C) carbene (D) free radical
100. The most easily hydrolysed molecule is____
(A)allyl chloride (B)ethyl chloride
(C)iso-propyl chloride (D)benzyl chloride.