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Magma
Degassing/volatiles release
Magma mixing
Photo J. k
Trace elements
Concentration < 0.1 %, usually expressed in parts per million, ppm
Substitute in major phases and/or occur as accessory minerals where
they often form essential structural components (zircon ZrSiO4)
Volatiles
H2O+, H2O, F, Cl, CO2 vs. Loss on ignition, LOI
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Classification of igneous rocks Classification of igneous rocks
Gill (2010)
Gill (2010)
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M < 90 %
Modal (QAPF) classification
Ternary plots of plutonic rocks
(Streckeisen 1976)
Q = quartz
A = alkali feldspar
P = plagioclase (An >5)
F = foids
(nepheline, leucite,
kalsilite, sodalite, nosean,
hayne, cancrinite,
70 % X, 20 % Y, 10 % Z analcime)
M = mafic minerals
(micas, amphibole, olivine,
pyroxene, accessories)
Q + A + P + F = 100
Remarks
3 granite = syeno- (a) + monzo- (b)
5 tonalite (M > 10)
trondhjemite, plagiogranite (M < 10)
9 monzodiorite (An < 50)
Gabbroic
monzogabbro (An > 50)
rocks
10 anorthosite (M < 10)
diorite (An < 50)
gabbro (An > 50): separate scheme
gabbro, troctolite, norite,
9* quartz monzodiorite (An < 50)
quartz monzogabbro (An > 50)
10* quartz anorthosite (M < 10)
quartz diorite (An < 50)
quartz gabbro (An > 50)
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M > 90 % QAPF classification Field classification
(Streckeisen 1976) (Streckeisen 1976)
Ultramafic
rocks
Le Maitre ed. (2002)
Nature of phenocrysts:
plagioclase-phyric andesite
olivine-augite-phyric basalt
Chemical features:
low-K basalt, peraluminous granite
Le Maitre ed. (2002)
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TAS classification of volcanic rocks TAS classification of volcanic rocks
(Le Bas et al. 1986) (Le Bas et al. 1986)
Qtz-normative
MacDonald (1974) = saturated
Subdivision to
alkaline/alkali and
subalkaline/subalkali
series
y = K2O
A = Na2O + K2O x = SiO2
F = FeOt
M = MgO Both in wt. %
All in wt. %
Definition of tholeiitic
and calc-alkaline series
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Subdivision of the calc-alkaline magmas Alternatives for weathered samples
Alternative to TAS
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Al vs. (Ca) + Na + K balance Simple recalculations
MgO
mg # 100 [mol.%]
FeO MgO
MgO
Mg # 100 [mol.%]
FeOt MgO
Mg# or mg# represent useful index of fractionation for binary plots showing
differentiation trends.
Example of calculation
Millications Cationic
Millications
Wt. % MW n (per 100 g
C proportions
milli n 1000 of rock)
MW SiO2 73.60 60.09 x1 1.225 1225
TiO2 0.10 79.90 x1 0.001 1
Al2O3 13.17 101.96 x2 0.258 258
MW molecular weight
Fe2O3 0.99 159.69 x2 0.012 12
number of atoms
FeO 1.61 71.85 x1 0.022 22
in the oxide
formula MgO 0.06 40.30 x1 0.001 1
n
(e.g., 2 for Na2O, CaO 0.70 56.08 x1 0.012 12
and again 2 for
Al2O3) Na2O 3.69 61.98 x2 0.119 119
K2O 5.38 94.20 x2 0.114 114
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Multicationic classifications Multicationic classifications
P = K(Na + Ca)
proportion of K-feldspar among feldspars
Example of calculation
Debon and Le Fort (1984)
Millications
I muscovite > biotite
Wt. % MW n (per 100 g
II Peraluminous biotite > muscovite
domain of rock)
biotite ( minor SiO2 66.95 60 x1 1116
III
amphibole)
TiO2 0.35 80 x1 4
biotite, amphibole,
IV Al2O3 16.16 102 x2 317
pyroxene
clinopyroxene, Fe2O3t 2.95 160 x2 37
V Metaluminous
amphibole, biotite MnO 0.10 71 x1 1
domain
unusual mineral MgO 0.68 40 x1 17
VI associations
(carbonatites...) CaO 3.96 56 x1 71
Na2O 4.27 62 x2 138
K2O 2.97 94 x2 63
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Processes determining/modifying the
Partial melting
composition of magmatic rocks
Kriegsman (2001)
https://www.geol.umd.edu/facilities/LCP/lcp.htm https://www.geol.umd.edu/~jmerck/nature/specimens
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Differentiation Differentiation
Fractional crystallization
continuous separation of newly formed crystals from the residual magma
Gravity settling
density contrast between the
crystals and the melt
Convection
thermally-induced
movement of magma in the
magma chamber
http://www.whitman.edu/geology/winter/JDW_PetClass.htm
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Xenoliths Assimilation/magma contamination
Hudie, Central
Bohemian Plutonic
Complex
(CBPC; Czech
Republic)
The AFC model assumes that the extra heat needed for assimilation (which is
Late syn-plutonic dykes Pitcher (1993)
an endothermic process) is provided by the latent heat of crystallization
(DePaolo 1981).
M a
r
M c
The parameter r is
determined by the thermal
state of the assimilated
country rock (will be lower
for cold, upper crustal
lithologies)
In any case it is unlikely to De Paolo (1981)
exceed unity.
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Interaction of magmas with contrasting
Mafic microgranular enclaves (MME)
composition
Field evidence
presence of MME
chilled margins in a mafic magma at
its contact with a felsic one
round or lobate liquidliquid contacts
net veining with a relatively mobile
felsic magma invading a nearly
solidified mafic one, silicic pipes
late syn-plutonic dykes often
disrupted into enclave swarms
exchange of crystals (xenocrysts)
e.g., ocellar quartz, rapakivi Fsp
a b
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Interaction of magmas with contrasting Interaction of magmas with contrasting
composition composition
Cathodoluminescence Cathodoluminescence
80
60
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Petrogenetic classification of granitoid rocks Petrogenetic classification of granitoid rocks
I S M A
BATCHELOR, R. A. & BOWDEN, P., 1985. Petrogenetic interpretation of granitoid rock series using
Classification of Ishihara (1977): multicationic parameters. Chemical Geology, 48, 43-55.
ilmenite series reduced due to the presence of the CASTRO A., DE LA ROSA J.D. & STEPHENS W.E. 1990. Magma mixing in the subvolcanic
environment: petrology of the Gerena interaction zone near Seville, Spain. Contrib. Mineral. Petrol.
organic matter 105: 926.
magnetite series oxidized CASTRO, A., MORENO-VENTAS, I. & DE LA ROSA, J.D. 1991. H(Hybrid)- type granitoids:
a proposed revision of the granite-type classification and nomenclature. Earth-Science Reviews, 31,
237253.
CHAPPELL, B. W., 1999. Aluminium saturation in I- and S-type granites and the characterization of
a) Magnetic susceptibility measurement
fractionated haplogranites. Lithos, 46, 535-551.
(by hand-held kappameters)
CHAPPELL, B.W. & WHITE, A.J.R. 1974. Two contrasting granite types. Pacific Geology 8, 173174.
b) Magnetite presence established by the hand-held CHAPPELL, B.W. & WHITE, A.J.R. 1992. I- and S-type granites in the Lachlan Fold Belt. Transactions
magnet of the Royal Society of Edinburgh, Earth Sciences, 83, 126.
c) Biotite colour: CHAPPELL, B.W., WHITE, A.J.R. & WYBORN, D. 1987. The importance of residual source material
oxidized is chocolate or green-brown (restite) in granite petrogenesis. Journal of Petrology, 28, 571604.
CLARKE, D.B. 1992. Granitoid Rocks. Chapman & Hall, London.
reduced is bright red COX K.G., BELL J.D. & PANKHURST R.J. 1979. The Interpretation of Igneous Rocks.
d) K-feldspar colour: George Allen & Unwin, London.
oxidized granitoids: Kfs pink CLEMENS, J. D. & STEVENS, G., 2012. What controls chemical variation in granitic magmas? Lithos,
reduced: Kfs white 134-135, 317-329.
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References and further reading References and further reading
DEPAOLO, D.J. 1981. Trace element and isotopic effects of combined wallrock assimilation and HILDRETH, W., 1979. The Bishop Tuff: evidence for the origin of compositional zonation in silicic
fractional crystallization. Earth Planet. Sci. Lett., 53, 189202. magma chambers. Geological Society of America Special Papers, 180, 43-75.
DE LA ROCHE, H. et al. 1980. A classification of volcanic and plutonic rocks using R1R2-diagram and ISHIHARA, S. 1977. The magnetite-series and ilmenite-series granitic rocks. Mining Geology, 27,
major element analyses its relationships with current nomenclature. Chemical Geology, 29, 183- 293305.
210. IRVINE, T. N. & BARAGAR, W. R. A., 1971. A guide to the chemical classification of the common
DEBON, F. & LE FORT, P., 1983. A chemical-mineralogical classification of common plutonic rocks and volcanic rocks. Canadian Journal of Earth Sciences, 8, 523-548.
associations. Transactions of the Royal Society of Edinburgh, Earth Sciences, 73, 135-149. JANOUEK, V. et al. 2004. Magma-mixing in the genesis of Hercynian calc-alkaline granitoids: an
DEBON, F. & LE FORT, P., 1988. A cationic classification of common plutonic rocks and their magmatic integrated petrographic and geochemical study of the Szava intrusion, Central Bohemian Pluton,
associations: principles, method, applications. Bulletin de Minralogie, 111, 493-510. Czech Republic. Lithos, 78, 67-99.
DIDIER, J. & BARBARIN, B. 1991. Enclaves and Granite Petrology. Elsevier, Amsterdam. JANOUEK, V. et al. 2006. Low-pressure granulites of the Liov Massif, Southern Bohemia: Visan
EBY G.N. (1990) The A-type granitoids: a review of their occurrence and chemical characteristics and metamorphism of Late Devonian plutonic arc rocks. Journal of Petrology, 47, 705-744.
speculations on their petrogenesis. Lithos, 26, 115134. KRIEGSMAN, L. M., 2001. Partial melting, partial melt extraction and partial back reaction in anatectic
FERNANDEZ, A. N. & BARBARIN, B., 1991. Relative rheology of coeval mafic and felsic magmas: migmatites. Lithos, 56, 75-96.
nature of resulting interaction processes. Shape and mineral fabric of mafic microgranular enclaves. LE BAS, M. J. ET AL. 1986. A chemical classification of volcanic rocks based on the total alkali-silica
In: DIDIER, J. & BARBARIN, B. (eds): Enclaves and Granite Petrology. Elsevier, Amsterdam, diagram. Journal of Petrology, 27, 745-750.
263-276.
LE MAITRE, R. W. (ed.), 2002. Igneous Rocks: A Classification and Glossary of Terms:
GILL, R., 2010. Igneous Rocks and Processes: A Practical Guide. J. Wiley, Chichester. Recommendations of the International Union of Geological Sciences, Subcommission on the
HASTIE, A. R. et al. 2007. Classification of altered volcanic island arc rocks using immobile trace Systematics of Igneous Rocks. Cambridge University Press, Cambridge.
elements: development of the Th-Co discrimination diagram. Journal of Petrology, 48, 2341-2357. MACDONALD, R., 1974. Nomenclature and petrochemistry of the peralkaline oversaturated extrusive
HIBBARD, M. J. 1995. Petrography to Petrogenesis. Prentice Hall, New Jersey. rocks. Bulletin Volcanologique, 38, 498-516.
MILLER C.F. (1985) Are strongly peraluminous magmas derived from pelitic sources? WALKER, D. & DELONG, S. E., 1982. Soret separation of mid-ocean ridge basalt magma.
Contributions to Mineralogy and Petrology, 79, 231-240.
The Journal of Geology, 93, 673689.
WINCHESTER, J. & FLOYD, P., 1976. Geochemical magma type discrimination; application to
NIGGLI, P., 1948. Gesteine und Minerallagersttten. Birkhuser, Basel. altered and metamorphosed basic igneous rocks. Earth and Planetary Science Letters, 28, 459-
PEARCE, J. A., 1996. A user's guide to basalt discrimination diagrams. In: WYMAN, D. A. (ed.): 469.
Trace Element Geochemistry of Volcanic Rocks: Applications for Massive Sulphide WHALEN J.B., CURRIE K.L., CHAPPELL B.W. (1987) A-type granites: geochemical
Exploration. Geological Association of Canada, Short Course Notes 12, 79-113. characteristics, discrimination and petrogenesis. Contributions to Mineralogy and Petrology, 95,
PECCERILLO, A. & TAYLOR, S. R., 1976. Geochemistry of Eocene calc-alkaline volcanic rocks 407419.
from the Kastamonu area, Northern Turkey. Contributions to Mineralogy and Petrology, 58, WILSON M. 1989. Igneous Petrogenesis. Unwin Hyman, London.
63-81.
PITCHER, W.S. 1993. The Nature and Origin of Granite. Chapman & Hall, London.
ROLLINSON H.R. 1993. Using Geochemical Data: Evaluation, Presentation, Interpretation.
Longman, London.
SHAND, S. J., 1943. Eruptive Rocks. Their Genesis, Composition, Classification, and Their Relation
to Ore-Deposits with a Chapter on Meteorite. John Wiley & Sons, New York.
STRECKEISEN, A., 1976. To each plutonic rock its proper name. Earth-Science Reviews, 12, 1-33.
VERNON, R.H. 1984. Microgranitoid enclaves in granites globules of hybrid magma quenched in a
plutonic environment. Nature, 309, 438439
VERNON, R.H. 1990. Crystallization and hybridism in microgranitoid enclave magmas:
microstructural evidence. Journal of Geophysical Research, 95, 1784917859.
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Web links
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