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Journal of Engineering Research and Studies E-ISSN 0976-7916

Research Article
PERFORMANCE ANALYSIS OF BIODIESEL FOR
DOMESTIC USE
Ademola A. Dare1* , Adetokunbo Simon Callender2, Adebambo Joseph Badejo2

Address for Correspondence


*1
Department of Mechanical Engineering, University of Ibadan, Ibadan, Nigeria
2
Department of Mechanical Engineering Lagos State University , Lagos, Nigeria
Email: *ademola_dare@yahoo.com, *ademola.dare@mail.ui.edu.ng
ABSTRACT
There is continued growing demand for alternative energy resources worldwide. One of the emerging
energy alternatives being explored is Biodiesel. Biodiesel has been produced from varieties of plant and
animal resources. However most of its targets have been for use as fuel for engines with little
consideration for domestic purposes This work has examined the use of biodiesel for domestic use such as
cooking. Three grades of biodiesel were produced by mixing ethanol with either vegetable oil, diesel or
kerosine. The fuel was then tested with a constructed cooking stove. Biodiesel with diesel blend was found
not suitable for use in domestic cooking while the blends with either vegetable oil or kerosene were
suitable. However only the kerosene blend gave satisfactory performance for both pressure stove and wool
stove. Pressure stove had better performance than wool stove for the kerosene blend. The work thus
established that a blend of kerosene with ethanol can be used for domestic cooking without incurring any
hazards. Equally it is established that biodiesel will perform creditably better with a pressure stove.
KEYWORDS Energy resources, Renewable, Biodiesel, domestic use
INTRODUCTION from plant oils combined with alcohol to
The continual search for alternative energy form esters. The esters can be burned as a
resource has been on the increase. One of fuel. In addition to vegetable oils from
the now considered viable alternatives is soybeans, rapeseed, or palm oil, biodiesel
Biodiesel. At present Biodiesel is an can also be made from used cooking oil,
alternative fuel for diesel engines that is animal fats, or oils produced by certain types
gaining attention in the United States after of microalgae.(Encarta Premium 2009).
reaching a considerable level of success in Considerable efforts have been made to
Europe (see Figs. 1 and 2). Its primary produce biodiesel from many plant sources
advantages are that it is one of the most (see Fig. 3). The use of Jatropha curcas
renewable fuels currently available and it is was considered by Tomomatsu and
also non-toxic and biodegradable (Gerpen et Swallow(2007). The study largely rules out
al, 2004). Research on biodiesel has focused jatropha as a plantation type of crop under
on three main areas namely: production current economic conditions, the
source, production techniques and opportunity for smallholder farmers in
productions costs. These three are being valuechain development were discussed.
pursued in making biodiesel a viable The use of High Iodine Number Candlenut
alternative to existing/ upcoming energy Oil in Biodiesel production was reported by
sources. It is envisaged that by 2030 the Sulistyo et. al.(2008). The biodiesel obtained
production cost would have been reasonably had properties similar to those of diesel oil,
low (see Fig 3). Biodiesel is typically made except for the viscosity that was higher.

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Journal of Engineering Research and Studies E-ISSN 0976-7916

Fig.1 EU and Member State Biodiesel Production ( in metric tones)


Source : European Biodiesel Board , 2009 * Total EU27 biodiesel production for 2008 was over 7.7 million metric
tonnes, an increase of 35.7% from the 2007 figures.

Fig. 2: Biodiesel Production: Europe and other Nations.


Source: IEA Energy Technology Essential- Biofuel Production, ETR 02 2007

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Journal of Engineering Research and Studies E-ISSN 0976-7916

Fig. 3: Current and Projected Cost of Biofuel compared with Conventional Wholesale
Gasoline
Source IEA Energy Technology Essential- Biofuel Production ETR 02, 2007
With increased attention being paid to its to mineral acids catalysts, such as less
production, improved production processes corrosion of the reactors and as well as
were being investigated. Gerpen(2010) avoiding the unnecessary neutralization of
emphasis on the need for proper production products. Kapilakarn and Peugtong (2007)
process as this affects the quality and in their study found that the optimal
suitablility for use as fuel for engine. Dhar condition that minimizes the operating cost
and Khitania(2009) suggested techniques for for biodiesel is the ratio of methanol to oil at
recovering excess methanol in biodiesel 6:1 (or 0.238:1 by wt.), the reaction
production. The production of biodiesel temperature at 70C, and the reaction time
from low cost raw materials received lot of of 20 minutes. In addition, for the same
attention. Abiney et. al. (2008) investigated production rate, the process with double size
the use of tin(II) chloride dehydrate as a of the reactor improves the product purity
catalyst on the ethanolysis of oleic acid, (from 96.62 % to 98.21 %). For the number
which is the major component of several fat of reactors, it is found that two half-size
and vegetable oils feedstocks. Tin chloride reactors give better product purity and
efficiently promoted the conversion of oleic operating cost than the single reactor with
acid into ethyl oleate in ethanol solution and the equivalent size. It should however be
in soybean oil samples, under mild reaction noted that efforts so far has largely been
conditions. The SnCl2 catalyst was shown to geared towards production of biodiesel for
be as active as the mineral acid H2SO4. Its engine use. This has therefore necessitated
use has relevant advantages in comparison this present work which is aimed at

JERS/Vol.II/ Issue I/January-March 2011/167-172


Journal of Engineering Research and Studies E-ISSN 0976-7916

assessing the performance of different ethanol and diesel while Biodiesel grade C
grades of biodiesel for domestic use. The consists of a mixture of ethanol and
performance of biodiesel when in use for kerosine. The methods of preparation of
stove was carried out as this may further each grade are presented below
assist in reducing energy burdens in the rural METHOD OF PREPARATION OF
communities. BIODIESEL GRADE A
MATERIALS AND METHODS All apparatus was clean, washed and dried
A cooking stove was first constructed. 200ml of pure vegetable oil was
Thereafter different grades of biodiesel were measured into a beaker and placed in a
prepared. Various tests such as Flamability pot containing water . The oil in the
Test, Combustibility Test, Wool Stove Test, beaker was heated to a temperature of
Pressure Stove Test, Environmental Test about 55C, using a burner or a gas
Miscibility Test, Mechanical Test, and stove.
Lubricity Test were then carried out The 1000ml of pure ethanol was measured
cooking stove was tested with biodiesel and poured into a stirring bowl.
when operating normally and when 3.5g of NaOH (Caustic soda) was added
pressurised. to ethanol and stir continuously until
APPARATUS USED IN PRODUCTION the CAUSTIC SODA crystals dissolve
A cooking stove or a gas burner. completely inside the ethanol.
1 funnel. After reaching the desired temperature
3 plastic bottles. the hot vegetable oil was poured into a
A thermometer. stirring bowl and stir continuously. The
NaoH (caustic soda). stirring was continued for about 30 min,
Ethanol. until the mixture becomes lighter than
Pure vegetable oil. the original oil.
Mixing bowl. The mixture was subsequently left to
Stirrer. settle for 24hrs in a tall vessel. By then
Chemical balance scale. the biodiesel floated to the top and a
Kerosene. whitish precipitate of glycerine is
Diesel. formed at the bottom was filtered out as
by product which can be used for
Spatula.
production of quality soap
4x (250ml) beakers.
METHOD OF PREPARING BIODIESEL
2 conical flasks.
GRADE B AND GRADE C
DESCRIPTION OF EXPERIMENT
The same procedure for production of grade
Three different grades of biodiesel mixtures
A was adopted. However the ratio of ethanol
were made. Biodiesel grade A consists of a
to diesel was 2:1(grade B) and ethanol to
mixture of ethanol and vegetable oil.
kerosine was also 2:1(grade C).
Biodiesel grade B consists of a mixture of

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Journal of Engineering Research and Studies E-ISSN 0976-7916

RESULTS AND DISCUSSION cooking stove. However this grade made can
(a) Effect and Observation of Biodiesel be used on diesel engines and generators.
Grades on Pressurised Cooking Biodiesel grade C
Stove. When biodiesel grade C is poured inside the
Biodiesel grade A tank of the pressurised stove and pumped at
When Biodiesel grade A was poured inside a pressure of 2.5kg/cm(35 pounds /Sq
the tank of the pressurised stove and in),the air inside the tank diffuses partially
pumped at a pressure of inside the biodiesel and due to the effect of
2.5kg/cm(35pounds /sq in), the air inside pressure it flows through the stem and up to
the tank diffuses partially inside the the hole in the burner nipple. When the
biodiesel and due to the effect of pressure it biodiesel is ignited in the spirit cup, the
flows through its stem and up to the hole in flame rises and heats up the remaining
the burner nipple. When the biodiesel is biodiesel coming from the burner nipple.
ignited on the spirit cup, the flame rises and The heating effect then produces a flame.
heats up the remaining biodiesel coming After some minutes the flame rises from the
from the burner nipple. The heating effect hole of the burner nipple and it is sustained
then produces a flame. After some minutes due to the exerted pressure already in the
of burning; the flame extinguishes itself due tank. A summary of the observation is
to the formation of saturated oil which is presented in Table 1.
produced at the hole of the burner nipple. (b) Results of Test on Biodiesel
Biodiesel grade B The results of tests carried out on the three
For this grade, the combustion was very grades of biodiesel produced are
excessive and could not be used for the summarised in Table 2

Table 1: Comparison of the Grades of Biodiesel on Stoves


Grades Effect On Pressure Stove Effect On Wool Stove
A Poor Not Suitable. Fair Performance.
B Not Usable. Not Usable.
C Can Be Used. Can Be Used.

Table 2: Tests on Various Grades of Biodiesel

Property Flammability Volatility Colour Viscosity Colour of


of Liquid ppt after
Burning.
Grades
A Partially flammable Not volatile Light Yellow Highly viscous Light brown
B Extremely Volatile Dark brown Partially Black
Flammable viscous
C Highly Volatile Off White Partially Dark White
Flammable Viscous

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Journal of Engineering Research and Studies E-ISSN 0976-7916

COMPARISON BURN TIME OF Bipro Ranjan Dhar, Kawnish Kirtania


(2009).Excess Methanol Recovery In
PRESSURE STOVE AND WOOL ON
Biodiesel Production Process Using A
STOVE Distillation Column: A Simulation
Since the kerosene blend biodiesel was Study. Chemical Engineering Research
Bulletin 13 , 55-60
found most suitable for use, the performance Hary Sulistyo, Suprihastuti S. Rahayu,
of the biodiesel for both pressure stove and Gatot Winoto, I M. Suardjaja(2008).
Biodiesel Production from High Iodine
wool on stove was compared. This was Number Candlenut Oil. World Academy
carried out by comparing the time taken for of Science, Engineering and Technology
each stove to evaporate completely 25cl of 48, 485-488.lIEA Energy Technology
Essentials-Biofuel Production, ETR 02
water using the biodiesel as against the time , 2007
taken using kerosene. The efficiency is thus J. Van Gerpen, B. Shanks, R. Pruszko,
D. Clements and G. Knothe(2004).
calculated as below. Biodiesel Production Technology.
Efficiency of Pressure Stove= NREL/SR-510-36244.
= Burn time of 25cl biodiesel used/Burn Jon Van Gerpen. Biodiesel Production
and Fuel Quality. Retrieved from
time of 25cl kerosene used www.uiweb.uidaho.edu/bioenergy/biod
= (45mins/75mins) = 0.60 = 60% ieselED/publication/01.pdf on 15th
June, 2010
Efficiency of Wool Stove = Kulchanat Kapilakarn and Ampol
=Burn time of 25cl biodiesel used/ Burn Peugtong(2007). A Comparison of
Costs of Biodiesel Production from
time of 25cl kerosene used Transesterication International Energy
= (48 mins/75mins) = 0.64 = 64% Journal 8, 1-6
The pressure stove thus gave better Microsoft Encarta 2009. 1993-
2008 Microsoft Corporation Statistics:
performance than the wool stove using the European Biodiesel Industry
kerosene blend biodiesel. European Biodiesel Board 2003-2009
Yuka Tomomatsu and Brent Swallow
CONCLUSION AND RECOMMENDATION
(2007). Jatropha curcas Biodiesel
This study has established the viability of Production in Kenya Economics and
biodiesel for domestic use. The analysis Potential Value Chain Development for
Smallholder Farmers, World
showed that a biodiesel formed from a blend Agroforestry Centre Working Paper #
of ethanol and kerosene performed 54.
excellently well for both pressure stove and
wool stove and is thus recommended for
use. Equally since wool stove gave better
performance, it is thus recommended that
the biodiesel be used with wool stove.
REFERENCES
Abiney L. Cardoso, Soraia Cristina
Gonzaga Neves and Marcio J. da
Silva(2008). Esterification of Oleic
Acid for Biodiesel Production
Catalyzed by SnCl2: A Kinetic
Investigation. Energies , 1, 79-92; DOI:
10.3390/en1020079

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