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OBJECTIVES:
A Solution is a homogeneous mixture with the presence of only a. Define solution and
one phase and with a uniform appearance throughout the system. give examples of
Examples of solutions are juice drinks, air and water. different kinds of
solution
Components: b. Differentiate
1. Solute: Substance being dissolved; Usually in smaller amounts solubility from rate
of dissolution.
(Minor Component in a Solution)
c. Give the factors
2. Solvent: dissolving medium; Substances present in greater
affecting solubility
amount (Major Component in a Solution) and rate of
dissolution;
Types of Solutions: d. Tell whether a
1. Solid in Solid Metal Alloys compound is
2. Solid in Liquid Sea Water soluble or insoluble
3. Liquid in Solid Dental Amalgam (Mercury in Silver) in water;
4. Liquid in Liquid Alcoholic Drinks, Gasoline e. Perform dilution; &
5. Gas in Gas Air (Mixture of O2, N2 and other gases) f. Express a given
6. Gas in Liquid Carbonated Drinks solution to different
7. Gas in Solid Hydrogen Gas in Palladium Metal ways of
concentration.
Parameters stated above are applicable only for a solid – liquid
solution (e.g. Salt in water). When the substances are both states, that is in solid, liquid and gas, there is
no clear distinction in identifying which is the solute or solvent. For this type, the solute is usually the
minor component while the solvent is the major component.
Example 5.1
a. Which of the following is a solution? Freshly squeezed pineapple juice or alkaline water
b. What is the solute and solvent in a sugar solution?
c. Identify the solute and solvent in a 75% Concentrated Hydrochloric Acid.
d. Identify the type of solution:
(1) Brass doorknob (2) Syrup (3) Steel (4) Rubbing Alcohol
Answer:
a. Alkaline Water (A Freshly Squeezed Pineapple juice usually have the pineapple pulps)
b. Solute: Sugar ; Solvent: Water
c. The given solution is made up of 75% Concentrated Hydrochloric Acid and 25% Water.
The solute is water and the solvent is the HCl solution.
d. (1) A metal alloy; Solid in Solid, (2) Solid in Liquid, (3) Solid in Solid, (4) Liquid in Liquid)
Chapter 5: Solutions | 42
5.2 PROPERTIES OF SOLUTIONS
5.2.1 SOLUBILITY
Solubility is the maximum amount of solute that can be dissolved in a given solvent at a
particular temperature to yield a solution at equilibrium. While Rate of Dissolution is how fast or slow a
given solute dissolves in a given amount of liquid at a certain temperature.
A solute can either be soluble or insoluble depending upon a given solvent. When a solution is
soluble, the solute can be dissolved by a given solute. A solute is insoluble if it remains undissolved in a
given solvent.
A rule of thumb can be expressed as “Like dissolves like”. Polar solvents dissolved polar solutes,
including ionic solutes and non polar solvents dissolved non polar solutes. Non Polar Solvents cannot
dissolve polar solute. This is the reason why when sugar is mixed to water, sugar is soluble to water
forming a sugar solution. Sugar and Water are both polar molecules.
When there is an increased in pressure, there is an increase in the solubility of gases in liquid.
This can be expressed by Henry’s Law defined as:
Where is the partial pressure of a gaseous solute is the mole fraction of the dissolved gas and
as the Henry’s law constant. As Pressure is raised, the concentration of molecules in the gas phase
and solubility is raised.
One possible application is when you open a bottle of carbonated drinks. Bubbling can be noted
due to escape of carbon dioxide as the bottle is opened or pressure is released.
3. Temperature
Chapter 5: Solutions | 43
Investigate!!
Materials: Carbonated Drink, 10 mL Pipet, Three Small Test Tubes, Hot Water and Cold Water Bath (250
mL beaker, burner, ice)
Procedure: Prepare three test tubes and label it as Control, HW (Hot Water) and CW (Cold Water). Place
5mL carbonated drink on each test tube. Place test tube HW and CW in hot water and cold water bath
respectively. Place the Control test tube on the rack. Observe for any changes in color for 5 minutes.
Interpret your results. You can also consult your experimental data to any General Chemistry Book.
2. Describe the changes in each test tube. Note the physical changes for both test tubes.
Control:
Test Tube 1:
Test Tube 2:
3. What can you conclude about the relationship of temperature to the solubility of gases?
4. If the test tubes are interchanged from their respective set-ups, what will happen?
TYPES OF SOLUBILITY
A. Saturated: Contains the maximum amount of solute that can be dissolved in a given solvent.
B. Unsaturated: Contains less number of solute that a solvent can hold
C. Supersaturated: Contains more solute than the solvent can hold
Example 5.2
If the solubility of an unknown salt named as “Chocosan” is 4 grams per 20 mL distilled water at room
temperature, determine whether the solution at each event is saturated, unsaturated or supersaturated.
If applicable, determine the amount of solute dissolved in the solution.
SOLUBILITY RULES
A. Mainly Water Soluble Compounds
1. All nitrates (NO3-), chlorates (ClO3-), perchlorate (ClO4-) and acetates (CH3COO-) are soluble.
2. All chlorides (Cl-) are soluble except compounds with Ag+, Hg22+ and Pb2+.
3. All iodides (I-) and bromides (Br-) are soluble except compounds with Ag+, Hg22+, Hg2+, and Pb2+.
4. All sulfates (SO42-) are soluble except compounds with Cu2+, Ba2+, Pb2+, Ag+, Hg22+,and Sr2+.
B. Insoluble Compounds
1. All sulfides (S2-), carbonates (CO32-), phosphates (PO43-), chromates (CrO42-) and sulfites (SO32-)
are insoluble except compounds with Group 1 Elements and Ammonium ion (NH4+).
2. All hydroxides (OH-) are insoluble except compounds with Group 1 Elements, Ba2+, Ca2+, Sr2+
and Ammonium ion (NH4+).
Chapter 5: Solutions | 44
Example 5.3
1. Are the following salts soluble or insoluble in water at room temperature? State your reason/s.
a. KCl b. AgCl c. AgI
d. BaO e. BaS f. PbCl2
2. Write the complete chemical equation for the reaction of sodium bromide and silver nitrate. Is there a
possibility in forming an insoluble salt or precipitate?
Solution:
1. (a) Soluble, (b) Insoluble, (c) Insoluble, (d) Soluble, (e) Insoluble, (f) Slightly Soluble to Insoluble
2. NaBr(aq) + AgNO3(aq) → AgBr(s) + NaNO3(aq). Yes. There is a possibility in forming an insoluble salt.
5.2.2 MISCIBILITY
Miscibility is the ability of a substance to be completely mixed with another substance. It is only
applicable to liquid – liquid and gas solution. Two substances can be miscible, when two substances are
uniformly distributed or immiscible if the two substances cannot be mixed.
To determine whether two substances are miscible or not, the rule “ Like dissolves like” applies.
Water, a polar molecule is immiscible with gasoline, a non polar molecule.
5.2.3 DILUTION
Dilution is the process of adding more solvent to make the solution less concentrated. The
number of moles before dilution is the same as after dilution. It is usually done when preparing certain
amount of moles per liters from a stock solution.
Chapter 5: Solutions | 45
Example 5.4
In a clock reaction experiment, 0.3 M and 0.5 M KOH solutions were needed. At the General Chemistry
preparation room, only 1 M KOH was available. How many liters of the 1M solution and water will be
needed to prepare 0.3L of the 0.3 and 0.5 M solution?
Solution:
A. For the preparation of a 0.3 M Solution
Formula:
To prepare the 0.3 L solution, the 0.09 L of concentrated solution will be added with 0.27 L water.
To prepare the 0.5 L solution, the 0.15 L of concentrated solution will be added with 0.15 L water.
Example 5.4
A chemistry student dissolved 15 grams of calcium chloride in water to make 0.3 L of solution. If the
density of the solution is 4 g/mL, Find the Percentage by Mass of the solution.
Solution:
To find the mass of solution:
Since: Density = Mass/Volume. By rearranging the equation, Mass = Density x Volume
Applying % mass:
Chapter 5: Solutions | 46
B. Percentage by Volume
Example 5.5
D. Molarity is the number of moles of solute per liter of solution. It is expressed as M and also known as
molar concentration.
Example 5.6
If 14.12 grams of sulfuric acid is dissolved in water to make 420 mL solution, find the molarity.
Solution:
Chapter 5: Solutions | 47
E. Molality is the number of moles per kilogram of solvent. It is expressed as m and also known as
molal concentration.
Example 5.7
How many grams of an unknown solute with a molar mass of 166.0 g/mol is needed to produce a 0.25
molal solution with 600 grams of unknown solvent.
Solution:
F. Normality (N) is defined as the number of equivalents of solute per liter of solution.
Chapter 5: Solutions | 48
Note: Get first the value of the equivalent weight before getting the no. of equivalent. The process is
NOT a continuous division.
Example 5.8
Find the normality of 13 grams triprotic acid dissolved in water to make a 4 L solution. The molar mass of
the acid is 97.98 g/mol.
Solution:
G. Mole Fraction:
To check if your answer is correct, Mole Fraction of Solute + Mole Fraction of Solvent = 1
Example 5.9
Find the mass of potassium acid phthalate (KHC8H4O4) if the mole fraction of NaOH is 0.14.
Solution:
Since Mole Fraction of Solute + Mole Fraction of Solvent = 1
Rearranging the equation, Mole Fraction of Potassium Acid Phthalate = 1 - Mole Fraction of NaOH
Mole Fraction of Potassium Acid Phthalate = 1 – 0.14
Mole Fraction of Potassium Acid Phthalate = 0.86
Chapter 5: Solutions | 49
H. Parts per Million
Example 5.10
a. If 0.25 mg Barium Chloride was found in 540 mL of solution sample obtained from a deep water
excavation, Find ppm of BaCl.
Given: 0.25 mg BaCl
540 mL solution (Converting it to liters, 0.540 L)
Solution:
b. A laboratory analyst tested the amount of a toxic compound of lead on children toys. In a sample
obtained from a famous children’s toy store, 9 μg of Pb was found out on a toy car weighing 581 grams.
(a) Calculate the parts per billion of the amount of Pb. (b) If the inhibitory amount of Pb is 14.2 ppb, is
the sample tested harmful or not?
(a) Given: 9 μg Pb
581 g of solution or 0.581 kg
Solution:
Challenge
Two students of General Chemistry were preparing a 0.55 L of an unknown
solution of Cj2M3 (with a density of 0.3g/mL). If 4 grams of the solute (Molar
Mass of 125.25 g/mol) is used and the solvent is MVe8 with twice the molar
mass of solute, Find:
1. Moles of Solute 7. Molality
2. Mass of Solution 8. Normality
3. Mass of Solvent 9. Mole Fraction of Solute
4. Percentage by Mass 10. Mole Fraction of Solvent
5. Percentage by Mass/Volume 11. Parts per Million
6. Molarity 12. Parts per Billion
Chapter 5: Solutions | 50
Chapter Review
A. Choose the best answer. If none of the answers are correct, write the atomic symbol of the
most electronegative atom in the periodic table.
1. When preparing diluted solutions from a stock solution, the process of ______ is most important.
a. Miscibility c. Solubility
b. Dilution d. Concentration
For nos. 4- 5, Consider the reaction: Cj5M6(aq) + M2V(aq) → Cj2V6(s) + M5M(aq) ∆H = -58.5 kJ
For nos. 8 to 10, Consider the following: If the maximum capacity of compound XYZ on water is 2.5 g/L at
21OC, is the mixture saturated, unsaturated or supersaturated.
Chapter 5: Solutions | 51
C. Classify the following as a solution or not. If applicable, determine the solute and solvent in the
solution.
D. Write the following chemical equation with the respective states of the following compounds.
Predict whether a precipitate will form.
1. Calcium Chloride and Sodium Phosphate
2. Potassium Hydroxide and Ferric Chloride
3. Potassium Chloride and Sodium Acetate
F. Solve the following. Report your answers with complete solution and proper significant figures.
Try it!
When Element A-1245 was combined with Element B-9456, compound A5VcH2 was synthesized. If 4 10-3
grams of compound A5(VcH)2 was prepared to make 1.2 10-10 L, Find the Molarity of the solution.
Chapter 5: Solutions | 52