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by
Larry "Harris" Taylor, Ph.D.
This material is copyrighted and all rights retained by the author. This article is made
available as a service to the diving community by the author and the Occupational Safety
and Environmental Health Department of the University of Michigan. It may be distributed
for any non-commercial or Not-For-Profit use
All rights reserved.
This article assumes a basic understanding of the common gas law properties.
See A Gas Law Primer for review of these concepts.
Density is defined as mass / volume. Since one mole of dry gas at STP occupies 22.4 liters, the
density of a pure substance is easily determined:
Density = Mass
Volume
Oxygen enriched air (EANx or Nitrox) is a binary mixture of nitrogen and oxygen. Thus, the mass
for the mix can be determined by simply summing the masses of the individual components. For
example, by choosing a volume of 1 liter, the density at STP, of 32 % oxygen containing mix
(NOAA 1) can be calculated.
This method, as long as components are known, can be applied to any mixture of gases. For
example, the density of Tri-mix 21/50 calculates to be 0.75196 g/L. This can be compared to the
value of dry air at STP listed in the CRC HANDBOOK OF CHEMISTRY AND PHYSICS of 1.296
g/L.
2
Conclusion
Assuming ideal gas behavior allows basic chemical principles to be used to estimate gas density
of a dry gas at recreational depths. It should be noted that mixes with helium often do not display
ideal gas behavior. Also, as depth increases well beyond the recreational limit, gas behavior
departs from predictions of ideal relationships and more complex real gas equations must be
used. Although this simple method offers a reasonable estimate of gas densities, it should not be
considered "gospel" for all mixes at all depths.