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BUFFERAMPSAMPSMONOMER2Acrylamido2methyl1
propane
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BiopharmCo.,Ltd.
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China(Mainland)

CASNo.:15214898 OtherNames:TBAS MF:C7H13NO4S

TransactionLevel:
EINECSNo.:2392680 PlaceofOrigin:Shaanxi,China(Mainland) Type:Industrial/FineChemicals
SupplierAssessments:
GradeStandard:MedicineGrade,Tech BrandName:ForesightCare ModelNumber:AFC2105
Grade,Industry
Purity:99.75% Appearance:whitecrystallinepowder
ResponseTime >72h
MeltingPoint:195200C(dec.)(lit.) Density:1.45 FlashPoint:160C
ResponseRate 71%
Stability:Hygroscopic Function:chemicalindustryrawmaterial Classification:Industrial/FineChemicals
ContactDetail Storage:28C Solubility:1500g/L20degree AssayTestMethod:HPLC

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PackagingDetails: 1kginaAlfoilbag&25kg/barrel.
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ProductCategories
Pharmaceuticalrawmateria...

medicalintermediate Specifications
1.ISOVerification.
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CustomizeContent 4.USP,BP,EP,JP,CP
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Xi'An Wango
Biochem Co.,Ltd

AMPS(2Acrylamido2methylpropanesulfonicacid)

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service 2Acrylamido2methylpropanesulfonicacid(AMPS)isareactive,hydrophilic,sulfonicacidacrylicmonomerusedtoalterthe

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chemicalpropertiesofwidevarietyofanionicpolymers.Inthe1970s,theearliestpatentsusingthismonomerwerefiledforacrylicfiber
X
manufacturing.Today,thereareoverseveralthousandspatentsandpublicationsinvolvinguseofAMPSinmanyareasincludingwater
treatment,oilfield,constructionchemicals,hydrogelsformedicalapplications,personalcareproducts,emulsioncoatings,adhesives,and
rheologymodifiers.

Production
AMPSismadebytheRitterreactionofacrylonitrileandisobutyleneinthepresenceofverystrongsulfonicacidsandwater.

Properties

Hydrolyticandthermalstability:Thegeminaldimethylgroupandthesulfomethylgroupcombinetostericallyhindertheamide
functionalityandprovidebothhydrolyticandthermalstabilitiestoAMPScontainingpolymers.
Polarityandhydrophilicity:Thesulfonategroupgivesthemonomerahighdegreeofhydrophilicityandanioniccharacteratwide
rangeofpH.Inaddition,AMPSisabsorbingwaterreadilyandalsoimpartsenhancedwaterabsorptionandtransportcharacteristics
topolymers.
Solubility:AMPSisverysolubleinwateranddimethylformamide(DMF)andalsoshowslimitedsolubilityinmostpolarorganic
solvents.

Solvent Solubility(gAMPS/100gsolvent)
Water 150
Dimethylformamide >100
NMethyl2pyrrolidone 80
Methanol 8.7

Inhibitionofdivalentcationprecipitation:SulfonicacidinAMPSisaverystrongionicgroupandionizescompletelyinaqueous
solutions.Inapplicationswheretheprecipitationofmineralsaltsisundesirable,theincorporationofapolymercontainingevena
smallquantityofAMPScansignificantlyinhibittheprecipitationofdivalentcations.Theresultisasignificantreductioninthe
precipitationofawidevarietyofmineralsalts,includingcalcium,magnesium,iron,aluminum,zinc,bariumandchromium.

Determiningviscosityaveragemolecularweight(MarkHouwinkconstants)

NaAMPS 0.01N 0.05N 0.1N 0.5N 1.0N 5.0N

Kx105 0.67 1.47 1.67 1.32 3.34 5.01
1.02 0.91 0.88 0.86 0.77 0.72

Reactivityratio:[12]AMPSreactswellwithavarietyofvinylmonomers.M2=AMPSorsodiumsaltofAMPS

M1 r1 r2 Remark
Acrylonitrile 1.2 0.7 DMF
Acrylicacid 0.74 0.19 Water,pH=7.0
Acrylicacid 1.58 0.11 Water,pH=2~4
Itaconicacid 0.46 0.04 DMF,70C,BenzoylPeroxide
Acrylamide 0.98 0.49 Water,K2S2O8

Styrene 1.13 0.31 DMF,60C,AIBN

VinylAcetate 0.05 11.60 Methanol,60C,
NVinylpyrrolidone 0.13 0.66 60C,AIBN
2Hydroxyethylmethacrylate 0.86 0.90 Water,60C,AIBN
2Hydroxypropylmethacrylate 6.30 0.04 Water,80C,(NH4)2S2O8
N,NDimethylacrylamide 1.26 0.68 Water,30C,K2S2O8

NVinylformamide 0.32 0.39 VA044

Applications

Acrylicfiber:Anumberofenhancedperformancecharacteristicsareimpartedtoacrylic,modifiedacrylic,polypropyleneand
polyvinylidinefluoridefibers:dyereceptivity,moistureabsorbency,andstaticresistance.

Coatingandadhesive:SulfonicacidgroupgivesthemonomersioniccharacteroverawiderangeofpH.AnionicchargesfromAMPS
fixedonpolymerparticlesenhancethechemicalandshearstabilitiesofpolymeremulsionandalsoreducetheamount
ofsurfactantsleachingoutofpaintfilm.

Personalcare:StrongpolarandhydrophilicpropertiesintroducedtoahighmolecularweightAMPShomopolymerareexploitedasa
veryefficientlubricantcharacteristicforskincare.

Medicalhydrogel:HighwaterabsorbingandswellingcapacitywhenAMPSisintroducedtoahydrogelarekeystomedical
applications.HydrogelwithAMPSshoweduniformconductivity,lowelectricalimpedance,cohesivestrength,appropriateskin
adhesion,andbiocompatibleandcapableofrepeateduseandhavebeenused
toelectrocardiograph(ECG)electrodes,defibrillationelectrode,electrosurgicalgroundingpads,andiontophoreticdrugdelivery
electrodes.inaddition,polymersderivedfromAMPSareusedastheabsorbinghydrogelandthetackifiercomponentofwound
dressings.

Oilfieldapplications:Polymersinoilfieldapplicationshavetostandhostileenvironmentsandrequirethermalandhydrolyticstability
andtheresistancetohardwatercontainingmetalions.Forexample,indrillingoperationswhereconditionsofhighsalinity,high
temperatureandhighpressurearepresent,AMPScopolymerscaninhibitfluidlossandbeusedinoilfieldenvironmentsasscale
inhibitors,frictionreducersandwatercontrolpolymers,andinpolymerfloodingapplications.

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Watertreatmentapplications:ThecationstabilityoftheAMPScontainingpolymersareveryusefulforwatertreatmentprocesses.
X
Suchpolymerswithlowmolecularweightscannotonlyinhibitcalcium,magnesium,andsilicascaleincoolingtowersandboilers,but
alsohelpcorrosioncontrolbydispersingironoxide.Whenhighmolecularweightpolymersareused,theycanbeusedtoprecipitate
solidsinthetreatmentofindustrialeffluentstream.

Constructionapplications:SuperplasticizerswithAMPSareusedtoreducewaterinconcreteformulations.Benefitsoftheseadditives
includeimprovedstrength,improvedworkability,improveddurabilityofcementmixtures.Redispersiblepolymerpowder,whenAMPS
isintroduced,incementmixturescontrolairporecontentandpreventagglomerationofpowdersduringthespraydryingprocess
fromthepowdermanufacturingandstorage.CoatingformulationswithAMPScontainingpolymerspreventcalciumionsfrombeing
formedaslimeonconcretesurfaceandimprovetheappearanceanddurabilityofcoating.

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