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TECHNICAL BRIEF
SISTEMA PACT
RESUMO TCNICO
AND
E
FAQ
PERGUNTAS MAIS FREQUENTES
PREPARED BY:
PREPARADO POR:
The PACT system can accept a wide variety of heterogeneous wastes while
producing a volume-reduced durable slag that needs no further treatment.
A TECNOLOGIA
O sistema PACT pode aceitar uma grande variedade de resduos heterogneos ao produzir
um volume reduzido de uma escria durvel que no precisa de nenhum tratamento
adicional.
PACT PRINCIPLES
The plasma gas transfers energy from the arc to the molten slag, which acts as one
arc termination. The rotating crucible (centrifuge) moves the molten waste material
beneath the torch at about 20 to 40 times per minute. Centrifugal force keeps the
molten slag away from the pour nozzle in the center during processing. The
centrifuge is housed within a sealed, water-cooled Primary Processing Chamber
(PPC, Fig. 1). Pouring is achieved by slowing the centrifuge so slag moves toward
the center, then flows through the pour nozzle into a mold positioned inside the Slag
Collection Chamber. The bottom part of the centrifuge shell is spray-cooled with
water. All chambers are kept under negative pressure (-25 to 50 mbar) to prevent
outward leakage of potentially hazardous gases.
PRINCPIOS DO SISTEMA PACT
O gs de plasma transfere energia do arco para a escria fundida, que actua como
terminao de um arco. O cadinho rotativo (centrfuga) move o resduo de material fundido
sob a tocha cerca de 20 a 40 vezes por minuto. A fora centrfuga mantm a escria fundida
longe do bocal de despejo no centro durante o processamento. A centrfuga est alojada
dentro de um selado, water-cooled primrio processamento cmara (PPC, Fig. 1). O despejo
conseguido retardando o centrifugador para que escria se mova em direo ao centro e,
em seguida, flui atravs do bocal de despejo em um molde posicionado dentro da cmara de
coleta de escria. A parte inferior do reservatrio da centrfuga refrigerada com spray de
gua. Todas as cmaras so mantidas sob presso negativa (-25 a -50 mbar) para evitar
fugas para o exterior dos gases potencialmente perigosos.
Tubulao de gs
de escape
Cmara de
Processamento
Primrio
Fuso Alimentador
Tocha de
Plasma
Centrifugador
Arco de Plasma
Escria
Bocal de Despejo Fundida
Generally, the primary chamber volume limits the organic material feed rate while
PPC bath area in combination with plasma power determines inorganic feed rates.
System simplification possible with PACT melters (due to minimal pre- and post-
treatment) reduces overall capital cost and requires fewer operating personnel.
Reducing exposure to hazardous waste remains important for worker safety, so
reduction of material handling made possible by the PACT process is an important
advantage.
Mixed oxides are generally conductive when hot so that torch current can transfer
directly into the slag. However, such materials have much lower conductivity near
room temperature, and some materials such as spinels have poor conductivity even
when heated to melting temperature.
The patented torch has been designed and tested to operate in both transferred
and non-transferred modes at the same time. The torch, not the operator,
automatically seeks the mode combination that suits the conditions. With prior
transferred arc torch designs, cold heterogeneous feed material would cause a
high voltage spike with visible instability as the arc sought a better ground path.
Repeated instability, such as with a large amount of bulky feed material, would
cause arc-outs and lost visibility inside the PPC. With the dual mode torch, the
plasma gas envelope maintained by the non-transferred arc stabilizes transferred
arc voltage so that arc-outs and arc instability are eliminated. In some 650 kg
batch tests, feed times were decreased from 200 minutes with only transferred
mode operation, to 60 minutes with dual mode.
The torch can now "pull" a one meter arc length, making it possible to batch melt
multiple 200 liter drums weighing >500 kg in the centrifuge. Before dual mode torch
development, a stable arc of this length was not practical. Longer arc length or
processing in non-transferred mode also means the system can be operated at
reduced heat when processing more volatile materials.
FEED SYSTEMS
The choice of feed system has a direct effect on processing rate. Table 1 shows the
feeds and systems that have undergone full scale testing. The Toyo Engineering
vertical drum feeds are the only ones batch loaded owing to their excessive weight
(>500 kg)
Shredders allow a 200 liters storage drum to be fed into a system that would
otherwise be too small to accept directly. Another advantage of shredders is
acceptability of varied forms and chemistries and metering of organic material such
as dry active waste so downstream flue gas treatment can be economically sized.
Table 1. Feeder Summary
Feeding whole drums of organic materials such as dry active waste is possible as
proven in the ZWILAG pre-commissioning tests, but correctly sizing the flue gas
system and controlling oxidizing gas flows to the primary and secondary chambers
are critical to success.
Slurries and liquids should be fed at a metered rate through a lance into the furnace.
When feeding liquids, no effort is made to get small droplets in the head-space above
the bath, since volatilization at the bath surface results in best overall mixing and
destruction of toxics.
PRETREATMENT OF WASTE
Essentially the only pre-treatment of wastes needed for the PACT process is to
enable feeding. Container contents can either be dumped into a hopper, then screw-
fed, or the containers can be fed and destroyed along with the contents.
Molten slag is poured at intervals (typically ranging between 0.5 and 8 hours) into
molds, then cooled to room temperature. When the material treated is radioactive,
the molds are usually put into other containers for permanent storage. When wastes
do not contain radioactivity, the slag can usually be removed from the casting molds
and discarded.
When hazardous wastes are destroyed, the permitting agency will want verification
that no toxic substances are being released into the environment. This means that
monitoring equipment must keep track of the concentration of potential contaminants
and that the gas clean-up system must be designed to meet the standards set by the
regulatory agency. Because plasma-treatment systems have lower off-gas flow rates
than combustion-heated systems, there is usually a somewhat higher percentage
flow variation (but lower absolute flow rate variation) than with combustion systems.
This requires attention in the design of the off-gas system.
The plasma system is usually designed to sequentially remove particulates and acid
gases from the off-gas leaving the SCC. The particulates can be re-introduced to the
furnace, thus achieving essentially 100% removal of metal, oxide and phosphate
products, while acid gases wind up as neutralized compounds in the water used in
gas cleanup.
Wastes containing arsenic and lead have been successfully treated and
stabilized into leach-resistant slags.
The temperatures and residence times for the slag and the off-gas are such
that by properly controlling the oxygen potential in primary and secondary
chambers Destruction and Removal Efficiency (DRE) values exceeding
99.9999% (six 9s) are achievable. Of special relevance is the excellent
homogeneity of the slag, which assures low carbon levels in the solid
treatment product.
During the waste feed part of processing, a safety mold is positioned below
the primary chamber to catch and hold for later treatment any material that
falls through the pour nozzle opening. After feeding stops in preparation for
pouring, the safety mold is removed and a casting mold positioned.
1.3 Is it possible to pour metal and slag as separate layers in the same mold?
Double layer pouring of metal and slag or two phase pouring and separation
in the mold has been accomplished in the PACT system (PACT-1, PACT-2, and
PACT-8). The operational parameters are well established that include, but are
not limited to: torch power, PPC refractory design, feed sequence, and process
temperatures.
1.4 Is it possible for the system to switch from double layer pouring (metal and
slag) to single layer pouring (oxidized metal) without modifying the hardware?
Soot formation is prevented by by supplying both sufficient oxidant gas and good
mixing conditions in the primary chamber to oxidize carbon-containing
compounds at least to carbon monoxide. Baking organic feeds in oxygen-starved
conditions must be avoided, since soot, once formed, is difficult to burn.
The PACT process is semi-continuous. When starting up for the first time, or
after refractory repair or renovation, a preheat period of a few days is needed to
obtain maximum refractory life. Then tests are conducted, usually around the
clock, with process feed for a time of order one or a few hours during which the
predominately oxide content of the wastes accumulates in the centrifuge. When
an appropriate avoid of molten slag has accumulated, feeding is stopped for a
few minutes while the last material added is heated and homogenized in the slag.
Then some of the slag is poured into a mold, and feeding resumes. The duration
of uninterrupted feeding and pouring cycles is limited to about 300 hours by
electrode life. However, campaigns are frequently run for 120 hours (five days)
depending on customer preference, followed by a week-end period at reduced
primary chamber temperature. Electrodes are usually replaced during the week-
end period.
The first PACT system started operating in Ukiah in 1987. The second system
was built in 1989 and the third delivered in 1990.
The table below gives estimated operating hours for almost all of the PACT
systems Retech has built. Retech has been operating a PACT-8 system in
Ukiah for production scale testing since 1997.
Table 2. PACT Annual Operation Hours
Slag Collection Mold transfer cart Bad transfer cart Remove and 1
out of position limit switch replace limit
switch; Insulate
limit switch from
heat
2.3 What wastes have been treated so far, in particular organic materials and
glass produced?
A wide variety of military wastes, surrogates for radioactive wastes and toxic
chemicals have been treated. Achieving adequate destruction efficiency for
substances in the off-gas is not a problem in systems with a secondary
combustion chamber operated at licensed conditions, but adequate destruction in
the solid phase can be a problem with fixed hearth melting systems. The PACT
system shows a factor of 10 improvement in carbon destruction compared to a
fixed hearth plasma system. Durability of slags is especially important in
stabilizing radioactive wastes, and the relatively high melting temperature
achievable with PACT (1300 to 1500 C) results in durability greater than that of
the glasses (melting at 1100 to 1200 C) used in the US DOE Savannah River
melting system. PACT slags also have very good leach resistance in US EPA
leach tests.
2.4 What can you say about the ability of the system to cope with unforeseen
and/or unknown variations in the physical and chemical characteristics of the
waste feeding system?
In general, the PACT system design can handle a wide variety of feed variations
and combinations. This is enhanced by several closed loop controls that are
automatically adjusted during operation. Furthermore, we have utilized predictive
algorithms in certain cases to control processing. The most noticeable changes to
operational variables are torch transferred voltage and system pressure. To
examine torch voltage issues see paper presented at Waste Management 2001,
Tucson, Arizona (Appendix B). System pressure variations are usually due to
organic feeding, particularly drum feeding, and can range from 1 mbar to 10
mbar. This range of pressure fluctuation does not pose a problem with the PACT
system.
The PACT system can process many types of feed and combinations of feed.
Example: simultaneous feeding of organic and inorganic materials. In order to be
able to process a wide range of materials a system has to be operationally
flexible. From an operator perspective, there are few process variables that need
to be adjusted to process different waste forms. For example, processing
inorganic materials of high melting point, torch current can be increased to rapidly
melt the materials and compensate for heat losses. Processing organic materials,
the torch current is lowered to minimize input energy. Combination feeding of
organic and inorganic materials can be done by monitoring torch current, and
adjusting it to maintain a desired temperature for processing. Additionally, optimal
processing rates can be achieved by combining organic and inorganic materials
in appropriate proportions. In general, process specifications can be derived for
various waste forms and PLC programming can help reduce operator activities.
Centrifuge speed Mixing Waste transfer, assist mixing Mold fill volume
Nitrogen results in longer electrode life and reduced NOx than does air.
Both are much cheaper than other choices of plasma gas, and monatomic
gases are not as effective in melting solid feeds as di- or poly-atomic
gases. It is, however, true that monatomic gases extend electrode life.
2.8 How does the transferred arc current get through the torch refractory?
See reference material for test methods and results (Appendix D).
Generally, slag leaching test methods are FED EPA Method 1311 TCLP
(RCRA protocols, 40 CFR, Appendix II, Part 26), and CAL EPA STLC and
TTLC (Title 22, CCR, Section 66261.24).
Slags tested thus far have successfully met disposal criteria according to
Federal and California State EPA toxicity requirements.
Other critical components that are inspected are listed in Table 7. Where Retech
has limited critical component analysis, vendors are used to inspect and give
recommendations for those components.
Record of yearly Nominal at 18,000 hours 12 operators (4 per shift, 24-hour cycle) x
man-hours for 1,500 hours = 18,000 total operational man
operation hours and nominal 24,000 paid hours
Number of 3 full time, 1 part time 3 full time people operate and maintain the
maintenance staff Retech PACT-8 during operational cycles. 1
part time electrical technician (OEM) who
usually is an operator.
Man-hours periodic Mean value for 1998- Periodic maintenance is based on campaign
maintenance 2000 = 425 hrs testing for the Retech PACT-8 including
quarterly and annual maintenance functions.
4.2 Can Retech assist in qualifying the process and the slag product?
Yes. The entire process has been qualified several times in the past as part of
the licensing process of our customers for their PACT systems.