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DTIC
SAPR
ELECTE
281994
Journal of Research
Internationally known as a leading scientific periodical, the Journal presents research papers by author-
ities in the specialized fields of physics, mathematics, chemistry, and engineering. Complete details of
the work are presented, including laboratory data, experimental procedures, and theoretical and mathe-
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Accesion For
NTIS CRAMi
OTIC TAB
Unannounced
Justification
By -...............
Distr ibution I
Availability Codes
Dist Avail and/ or
-Special
94-12769
V~~ 062
Contents
Page
1. Introduction ------------- --------------------------------
2. Description of table ---.--------------------------------------
2.1 List of svmhol -.. . ........-------------------
2.2 Standard liquids ---------------------- -----------
2.3 Chemical formulas and the order of listing of substances _II
2.4 Estimated accuracy of the values of fiielectric constant_- Iv
2.5 Variation of dielectric constant with temperature ---------- Iv
2.6 Literature references in table -------------------------- Iv
3. Table of dielectric constants ----------------------------
A. Standard liquids- --.---------------------------------- 7
B. Inorganic liquids- ------------------- 8
C. Organic liquids ---------------- ----------------------- 15
4. Bibliography --------------------------------------------- 40
I!
Table of Dielectric Constants of Pure Liquids
Arthur A. Maryott and Edgar R. Smith
The "static" dielectric constants of more than 800 substances in the liquid state were
critically examined and tabulated ini concise form. Tihe table consists of three sections: A,
Standard Liquids; 13, Inorganic liquids; and (', Organic Liquids. An indication of the prob-
able accuracy of the data is given. Wherever feasible, a simple analytical fuinction is em-
ployed to express the variation of dielectric constant with temperature.
Formulas for the organic compounds are written 2.5. Variation of Dielectric Constant With
with carbon first and hydrogen, if present, second. Temperature
Symbols for all remaining elements then follow ill
alphabetical sequence The arrangement of these Where feasible, the variation of dielectric
compounds in section C is determined first by the constant with temperature is represented by one
number of carbon atoms, secondliv b% tile nulnber of the following equations:
of hydrogen atoms, and finally by thle symbols for
the remaining helements in alphal)etical order.'
g1
0 et-Log, 0 f,-a(t'-t (2)
2.4. Estimated Accuracy of the Values
of Dielectric Constant where ,, 1, and a (or a if the value is followed
immediately by a in parentheses) are specified in
Values of dielectric constant recorded in sections the table. Occasionally other equations are in-
B and C have an estimated accuracy indicated by dicated in footnotes.
tie number of figures retained. The range of temperature over which the equa-
(a) Values listed to four figures are considered tion is considered satisfactory appears under the
probably accurate to 0.5 percent or better, heading t,, t 2. This range was chosen such that
(b) Values listed to three figures are con- the deviations between the calculated and reported
sidered probably accurate to 2 percent or better. values of e are not greater than one-fourth of the
(c) Values listed to two figures are considered accuracy assigned to E. Thus if E is listed to four
probal)ly less accurate than 2 percent. figures (discounting figures in smaller type), the
However, where lack of detailed information equation fits the reported data to 0.13 percent or
makes any assignment of accuracy difficult or better over the specified range of temperature;
where excessive rounding off is undesirable, an and, if e is listed to three figures (discounting
additional figure is often retained which is not to figures in smaller type), the equation fits the data
be counted in determining the probable range of to 0.5 percent or better. Values of e falling out-
accuracy. Such figures are printed in smaller side of this range of temperature are listed at
type as subscripts. They are also retained when selected temperatures.
significant with respect to variations of dielectric
constant with temperature or to differences 2.6. Literature Reference in Table
between isomeric or other closely related com-
pounds in a series of measurements. All tabulated data are based on the references
These estimates of accuracv were assigned indicated by numbers not enclosed in brackets.
arbitrarily after considerations of the investi- The numbers refer to the bibliography following
gators' apparatus and methods, precision, prob- the table. Some additional references not em-
able purity of materials, and comparisons, where ployed for one reason or another are enclosed in
possible, with the results of others, brackets. These latter references are not in-
tended to be complete with regard to data pub-
Exception is made for certain series of polymers (e. g., polysiloxanes) lished for each substance but have been selected
which may he represented by the general formula (X). or .4(X).H. where on the basis that they probably merit considera-
n = 1, 2. 3. etc. The location of all compounds of such a series is determined
hy the formuia corresponding to n-l. tion in any revision of the tabulated data.
Table of Dielectric Constants
of Pure Liquids
A. STANDARD LIQUIDS
E DO c E 2o 0 a (or a)
*The values of a or a given in this table are derived from data in the vicinity of room temperature and
are not necessarily identical with the values listed in Parts 8 and C. They may be used to calculate values
of dielectric constant between 150 and 300 C without introducing significant error.
(1)
B. INORGANIC LIQUIDS
a (or a) Range References
2
Substance E toc x10 t2.tr
HBr Hydrogen bromide ............. 7.00 -85 0.26(a) -85,-70 137 [296]
3.8b 25 .................... 25
3
a f= 4x 10 cycles/sec. E =78.54 [I - 4.579(l0- )(t- 25) +1.19(10-5)
b 1=3.6 X10" cycles/sec. (t-25f- 2.8 (10-)(t - 25)3]; av. dev. +0.03%.
SAt presure of 50 atmospheres. YE =5321/T+233.76- 0.9297T+0. 001417T
4 3
E =78.25 [1 - 4.617(10-3)(t- 25) +1.22(10-5)(t- 25)2 -0-0000008292T .
2
-2.7(10-8)(t-25)3]; av. dev. 0.0O4%. "E84.2- 0.62t+O.0032t .
(2)
B. INORGANIC LIQUIDS-Continued
955049 0 - 51 - 2
B. INORGANIC LIQUIDS-Continued
CI
CCIO Phosgene ..................... . 4 .7 2 b 0 ......... ......... 52
4.3 4 b 22
CC14 Carbon tetrachloride ......... 2.238 20 0.200 -10,60 146,169,233,240a,
245,292
C2
C2 C12 02 Oxalyl chloride .............. 3.47 21 .................... 107
C
2 8r0 Acetyl bromide ............... 16.s' 20.. ................... 17
* f = 4 x 108 cycles/sec.
" f =5 x 10 cycles/sec.
7
C. ORGANIC LIQUIDS-Continued
la -(or a) Range
Substance E toC a (
xlO0 t)
tt~t References
C. ORGANIC LIQUIDS-Continued
C2 N110
2 Nitroethane .................. 28.0, 30 II.4 30,35 295 Lilt]
CY N110
5 Ethyl nitrate ................ 19.4 20 9. 0,50 7,17,26 [4,141
(C 2H6 OS')n
n =4 OctamethylcycIotetrasiloxane.. 2.39 20 .................... 266
n= Doecanethylcyclopentasiloxane 2.50 20 ................... 266
CA
2 N5 02 l.(, ...... 37.7 25 0.224(a) 20,100 112 [26,131, 142,2361
a f=1,xlO cycles/sec.
o E -6. 94-0.O036( t- 10) +O.O0004(t- 1O)2
'Critical temperature = 126.9 0 C.
'Value chosen to conform with the remainder of the tabulated data for this substance.
C. ORGANIC LIQUIDS-Continued
C3
N2
C3 2N Malononitrile ................ 46.b 36 .................... is
CNH
7 I-lodopropane ................ 7.00 20 ................... 242
a f= 4x 1Oe cycles/sec.
b f 3.6 x l10 cycles/sec.
n f= 5 X S0s cycles/sec.
II
C. ORGANIC LIQUIDS-Continued
a (or a) Range References
Substance E taC slOt
C01
9 803 Trimethylborate .............. 8.0a 20 .................... 17
CH1
0 Isopropylamine ............... 5. 5 b 20 .......... ......... 14
Trimethylamine ............... 2.414 25 0.52 0,25 268 [4l1
C4
C4 C16 Nexachloro-1,3-butadiene ..... 2.55 25 .................... 279
C4 H1
5 10 Methyl cyanoacetate .......... 28.,- 20 ................... 17
Sf =-4 x o0 cycles/sec.
bf-3.6 XION cycles/sec. "I>
IN
I
" f-5x108 cycles/sec.
4 cis- trans Isomers. 40
955049 0- 51 - 3\ CI
t
12
C. ORGANIC LIQUIDS-Continued
* (or a=) Range.eerne
2
Subs tance E toc a References
C. ORGANIC LIQUIDS-Continued
C. ORGANIC LIQUIDS-Continued
0 0-Con.
C4Ho,
2-Nethyl-2-propanol .......... 10.9 30 .................... 109 ['3,112,142,
8.49 50 157,261]
6.89 70
C5
C5FeO5 Iron pentacarbonyl ........... 2.60 20 ................... 114
a f= x tOo cycles/sec.
b f= 3.6 x l10 cyclesfsec.
hCritical temperature.
' Value chosen to conform with the remainder of the tabulated data for this substance.
15
C. ORGANIC LIQUIDS-Continued
C5 He 1,3-P'+adiene t . . . . . . . . . . . . .
2.32 25 ..................... 1011,130
2-Methyl-I,3-butadione ...... 2.10 25 0.24 -75,25 129
(Isoprene)
C5 1110 0,-Con.
Isobutyl formats ............ 6.14, 19 .................... 7 L1]
Propyl acetate .............. 5.69 19 0.8 atl9 7,8 L27]
Ethyl propionate ............ 5.65 19 1.8 atil9 7,8
CH 11 I-odopentane
- ............... 6.81 20 .......... ......... 242
f , I X 10 cycles/sec.
bf=3.6x10s cycles/sec.
ff 5 x 108 cyles/sec.
17
C. ORGANIC LIQUIDS-Continued
CH1
120 Xylitol ..................... 40. 20 . ........ .......... 131,142
CsN1 3S I-Pentanethiol ............... 4.55 25 .................. 1S40 [I'4,163
4.23 so
CsN 1 2S 4 Tetramethylthionothane ...... 2.82 70 .................. 250
C6
CI4,BrCI I-Broeo-2-chlorobenzene ..... 6.80 20 .................... 83
14.1 140
13.0 160
I-Chloro-4-nitrobenzene ..... 8.0, 120 0.16(a) 85,160 176 [32]
bf:3.6 X 10 cycles/see.
C. ORGANIC LIQUIDS-Continued
a f=Sx i0 cycles/sec.
19
C. ORGANIC LIQUIDS-Continued
a (or a) Range
Substance tQC X1O2 tlt References
15.1& 20 .................... 17
CNIoO
0 4 Diethyl oxalate .............. 8.11 21 .................... 7
'f=4XI10 cycles/sec.
955049 0 - 51 - 4
I,
20
C. ORGANIC LIQUIOS-Continued
a (or 2i) Range References
ubstanc C 10 tilts
bf=3.6X108 cycles/sec.
"f = 5 X 10 cycles/sec.
"Extrapolated from mixtures containing both isomers.
LI
21
C. ORGANIC LIQUIDS-Continued
COH 1 2 0 2 -Con.
Methyl valerate .............. 4.3f 19 .................... 27
C6 1H
12 0, 6-Ethoxyethyl acetate ........ 7.57 30 3.1 30,50 260
("Cellosolvel acetate)
1 N
CH, Cyclohexylamine .............. 5.37 -21 ......... ......... 237
C. ORGANIC LIQUIDS-Continued
C7
CH C5O Benzoyl chloride ............. 29. 0 ......... ......... 43 [22]
23. 20
C7NSCl a,a,a-Trichlorotoluene ....... 6.9" 21 .................... 22,27
C.115 F3 a., a-Trifluorotoluene ....... 9.18 30 ......... ......... 255a
8.09 60
C7 H1N Benzonitrile ................. 25.20 25 0.157(a) 0,25 85,138 [194]
24.02 40
22.10 70
CH 9NO Phenyl isocyanate ............ 8. 8 b 20 .................... 22 E[8]
C7 H5 NS Phenyl isothiocyanate ........ 10.,- 20 .................... 17,22 [i8]
C7H 602 a,a-Oichlorotoluene .......... 6.9n 20 ......... ......... 27
f , 4 XI08 cycles/sec.
b f3.6 xlog cycles/sec.
"f=5x108 cycles/sec.
23
C. ORGANIC LIQUIDS-Continued
CAH
7N03 m -Nitrobenzyl alcohol ....... 22.n 20 ................... 27
n f = 5 X 106 cycles/sec.
211
C. ORGANIC LIQUIDS-Continued
C0H
1 2 03 Ethyl levulinate ............. II.. 6 21 .................... 7
C. ORGANIC LIQUIDS-Continued
C. ORGANIC LIQUIDS-Continued
7 H1 00
C? Glucoheptitol ................ 27.4 120 .......... ......... 131,142
Ca
CsH2 C12 F6 4,5-Dichloro-i,3-bis ......... 3.1, 30 ................... 255a
(trifluoromethyl)-benzene 2.9, 60
6 e0
CsH Phthalide ..................... 36. 75 ......... ......... 7
"f=4X10 8 cycles/sec.
bf= 3.6 x 1O0 cycles/sec.
27
C. ORGANIC LIQUIDS-Continued
a (or 2i) Range References
Substance~ E tC x10 2 t~t
"f=5XlO cycles/sec.
28
C. ORGANIC LIQUIDS-Continued
a (or 2 ) Range References
Substance 0.t
Clla
1 cis-3-Octene ................. 2.062 25 .................... 239
C. ORGANIC LIQUIDS-Continued
CeH1 6 O-Con.
3-Nethyl-2-hePtanol .......... 7.33 20 0.23(a) -8,30 32
10.8 - 44
9.13 -20
6.22 55
I,-Methyl-2-heptanol .......... 4.6 - Is .......... ......... 82
3.90 0
3.63 20
3.52 40
3.36 60
C,11 1 O0-Con.
4-Methyl-4-heptanol .......... 2.87 20 - 1.04 10,55 82
2.53 -44
2.59 20
2.70 0
3.27 60
C9
CHtN Quinoline .................... 9.00 25 . .................. 41,156,159
5.05 238
4f=
X08 cycles/sec.
b f=3.6 X108 cycles/sec.
" f= 5 X108 cycles/sec.
32
C. ORGANIC LIQUIDS-Continued
CsN, 1 --Con.
.12,4-Trisethylbenzene 2.42 17 .................... 1,3
(Pseudocumene)
CH-
1 N Benzylethylamine ............. .1.3" 20 .................... 27
f = 5 x106 cycles/sec.
tMixture of cic-trans isomers.
33
C. ORGANIC LIQUIDS-Continued
Substance
0
t C a (or a) Range References
CeNSo-Con.
2,4-Dimethylheptane .......... 1.89 20 .......... ......... 35
ClO
C1 0 H7 Br I-Bromonaphthalene ........... 4.83 25 0.87 25,55 272 [7,12]
a f = X 108 cycles/sec.
bf=3.6XlOs cycles/sec.
Sf=5 x lOb cycles/sec.
34
C. ORGANIC LIQUIDS-Continued
0
Substanc'ot a (or 2a) Range References
6T X10 t~t 2
C1
H, d-Camphene..................... 2.33 ca 0............. ......... 237 [24]
d-Pinene...................... 2.64 25............. ......... 164 [204]
I-Pinene...................... 2.76 20............. ......... 196 [24]
180
C1011 Menthone...................... 8.8b 18............. ......... 22 [27]
11.8 -35.......................232
C1 2
C,,HO Dibenzofuran ................. 3.00 100 .................... 232
(Diphenylene oxide)
CIAH
1O Diphenyl ..................... 2.53 75 0.18 75,155 67
C lsloO
5 Phenyl ether ................. 3.65 30 0.7 30,50 66,260 [289]
ff,4 X 10 cycles/sec.
b f 3.6 XIO1 cycles/sec.
Sf =5 XlO1 cycles/sec.
36
C. ORGANIC LIQUIDS-Continued
C12 1H
2 n-Dodecane ................... 2.014 20 0.120 10,150 88
2.047 -10
1.776 210
C13
C1 3Ho 0 0 Benzophenone .................. . 50.. . .................... 180 [26,260]
C14
C1 0
4 10 Phenanthrene ................. 2.72 I10 . .................. 246
C16
3
C1 6 H2 2 O4 Dibutyl phthalate ............ 6.4 e 30 1.98 30,35 295 [267]
C1 8 H 30s
2 Palmitic acid ................ 2.30 71 .................... 181,192
C17
C1 7 " 3 4 0 9-Neptadecanone .............. 5.3 60 .................... 195
Cis
C1 8 H30 0 4 Dicyclohexyl adipate ......... 't.8a 35 .................... 237
C1 0 33 "NaO
2 Sodium oleate ................ 2.8a ep .................... 21
C1 8 H3 4 02 Oleic acid .................... 2.46 20 ......... ......... 136,181,208,
2.45 60 235,262
2.41 100
C1,H 3 4 04 Dibutyl sebacate ............. 4.540 30 1.07 30,35 295 [267,279]
ff= x 10 cycles/sec.
38
C. ORGANIC LIOUIDS-Continued
C19
C19 H16 Triphenylmethane ............. 2.45 100 0.114 94,175 67
C20
C20oH3 0, Ethyl oleate ................. 3.17 28 0.48 28,122 67
2.63 150
C2 1
C2 ,13 1 0 4P Tricresyl phosphate ........... 6.9 40 .................... 219
C2 2 1H
4 2 03 Isobutyl ricinoleate 4.7 21 ................... 26
(Isobutyl 12-hydroxy-9-
octadecenoate)
C23
CzsH4eO 12-Tricosanone ............... .. 4.0 80 I. 72,90 195
39
C. ORGANIC LIQUIDS-Continued
C 214
C2 4 113 0 0 4 DibenzyT sebacate ............ 4.6 25 .................... 267
C2 6
C2 0 H5 o04 Dioctyl sebacate ............. 4.01 26 .................... 279
C3 4
C3 4 "6 6 Tetratriacontadiene .......... 2.82 25 .................... 155
C35
C356l8 05 1,3-Dipalmitin ............... 3.52 72 .................... 288
3.119 76
C 36
C3 6 H,,Cu0 4 Copper oleate ................ 2.8,- mp .................... 21
C3 9
C3 917 6 0 5 1,3-Distearin ................ 3.32 78 .................... 288
3.29 82
C5 1
C5 1 HOSOO Tripalmitin .................. 2.927 60 0.32 60,70 288
C 57
C5 7 ",, 4 06 Triolein ..................... 3.20 25 . .................. 235 [2081
a f 14 x O08 cycles/sec.
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