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Survey of volume IV/8

Thermodynamic Properties of Organic Compounds


and their Mixtures

1. Enthalpies of Fusion and Transition of Organic Compounds Subvolume A

2. Densities of Aliphatic Hydrocarbons: Alkanes Subvolume B

3. Densities of Aliphatic Hydrocarbons: Alkenes, Alkadienes,


Alkynes, and Miscellaneous Compounds Subvolume C

4. Densities of Monocyclic Hydrocarbons Subvolume D

5. Vapor Pressure of Aliphatic Halohydrocarbons

6. Densities of Aliphatic Halohydrocarbons

7. Densities of Aromatic Hydrocarbons


Thermodynamic Properties
of Organic Compounds
and their Mixtures
Subvolume D
Densities of Monocyclic Hydrocarbons

R. C. Wilhoit, X. Hong, M. Frenkel, K. R. Hall

Edited by K. R. Hall and K. N. Marsh

Thermodynamics Research Center


The Texas A&M University System
College Station, Texas 77843-3111, USA
Editors
K.R. Hall
Thermodynamics Research Center
TheTexas A&M University System
College Station, Texas 77843-3111, USA

K.N. Marsh
former
Thermodynamics Research Center
TheTexas A&M University System
College Station, Texas 77843-3111, USA
now
University of Christchurch
New Zealand

Authors
R.C. Wilhoit
X. Hong
M. Frenkel
K.R. Hall
Thermodynamics Research Center
TheTexas A&M University System
College Station, Texas 77843-3111, USA
Preface

Critically evaluated experimental data covering the densities of organic compounds is essential for both
scientific and industrial applications. Knowledge of densities is important in many areas, including custody
transfer of materials, product specification, development of various predictive methods, and for
characterizing compounds and estimating their purity.
Various compilations of densities for organic compounds have been published. The early Landolt-
Brnstein compilation [23-ano] contained recommended values at specific temperatures. International
Critical Tables [28-ano-1] provided recommended densities at 0 C and values of constants for either a
second or third order polynomial equation to represent densities as a function of temperature. This
compilation also gave the range of validity of the equation and the limits of uncertainty, references used in
the evaluation and those not considered. This compilation is one of the most comprehensive ever published.
Timmermans [50-tim, 65-tim], Dreisbach [55-dre, 59-dre, 61-dre] and Landolt-Brnstein [71-ano] published
additional compilations, primarily of experimental data. These compilations contained experimental data
along with reference sources but no estimates of uncertainty for the data nor recommended values.
The Thermodynamics Research Center has published recommended values for the densities of organic
compounds since 1942 in its two loose leaf publications: TRC Thermodynamic Tables - Hydrocarbons and
Non-Hydrocarbons. These compilations are updated with four supplements per year. References to the
literature values used in the selection and those not used in the selection appear in the references for each
table. The accuracy of the values ia apparent from the number of significant figures provided. More
recently, the Design Institute of Physical Property Data, Project 801 has assembled a set of recommended
equations for the densities of over 1500 compounds [89-dau/dan, 91-dau/dan, 92-dau/dan, 93-dau/dan, 94-
dau/dan, 95-dau/dan]. Densities are represented by an equation fit to selected values from the freezing
temperature to the critical temperature. References to sources of data used in the evaluation and those not
used are given along with a quality assessment. In many cases, the equation does not fit density values at
intermediate temperatures, especially at 293.15 K and 298.15 K, within the experimental uncertainty. Thus,
the equation is not useful for purity comparisons, custody transfer, or product specification when the highest
accuracy is required. Smith and Srivastava [86-smi/sri, 86-smi/sri-1] recently have published a compilation
(in two volumes) which contains recommended values in tabular form as well as equations with statistical
information regarding the fit. However, this compilation contains no indication of data quality or
uncertainties.
The present volume contains densities for monocyclic, non-aromatic hydrocarbons including
alkylcycloalkanes, alkylcycloalkenes, alkenylcycloalkanes, alkylcyclodienes, alkenylcycloalkenes,
alkadienylcycloalkanes, alkynylcycloalkanes, alkylcyclotrienes, alkenylcyclodienes, alkylcyclotetraenes,
dialkenylcycloalkenes, trialkenylcycloalkanes and other related compounds which have been collected from
the literature published from 1870 to early 1996. The various compilations listed above also have been
consulted for sources of original data. This volume continues our effort in evaluation of the densities of
organic compounds (see volume IV/8B [96-wil/mar] for the densities of alkanes and volume IV/8C [96-
wil/mar-1] for the densities of alkenes, alkynes and alkadienes). All experimental density values have been
evaluated critically and assigned numerical uncertainties individually. These assessments have been used to
derive an equation to fit the data and to obtain recommended values with uncertainties. Detailed evaluation
procedures appear in Chapter 1. Algorithms for the automatic selection of data used in the fit and for the
selection of the type of equation and order of polynomial have been developed. The algorithms depend upon
the assigned uncertainties, the distribution of density values over the experimental temperature range, and
the magnitude and distribution of differences between observed and smoothed values. These algorithms can
fit any kind of data to a function of independent variables. We have collected data for 820 compounds,
consisting of 2672 data sets (total of 3903 data points) drawn from 1250 sources of which 1216 sets have
been used in the evaluation. The other data sets have been rejected, but references to them are given.
The volume contains six chapters; a list of references, and two indexes (Chemical Abstracts Service
Registry Number Index and Chemical Name Index). Chapter 1 contains: a short introduction; a description
of the tables; a detailed description of the methods used in the evaluation, selection and smoothing process;
a glossary of symbols and a description of the nomenclature used. Chapter 2 covers the alkylcycloalkanes,
Chapter 3 contains the alkylcycloalkenes and alkenylcycloalkanes, Chapter 4 has the monocyclic
hydrocarbons of general formula CnH2n-4, Chapter 5 provides the monocyclic hydrocarbons of general
formula CnH2n-6, and Chapter 6 presents the monocyclic hydrocarbons of general formula CnH2n-8. Section
1.7.2 describes the method used to determine the sequence of the compounds. The tables contain the
original literature data along with their estimated uncertainties and the evaluated data in both numerical form
and as coefficients to equations with selected statistical information. When data cover a sufficient
temperature range, graphical plots of the deviations of the experimental data from the recommended
equation are given. The chemical name index contains the IUPAC names for the compounds, as well as
alternate names that often appear in practice.
This volume should be useful to a wide community of researchers, data specialists, and engineers
working in the field of physical and organic chemistry, chemical engineering, material science,
environmental chemistry, chemical aspects of energy technology, and those engaged in the development of
new predictive procedures. The book should also be of use to students and faculty in Chemistry and
Chemical Engineering departments at universities as a reference book of evaluated thermophysical
properties.

Acknowledgments
The authors wish to express their sincere appreciation to staff members of the Thermodynamics Research
Center (TRC), part of the Chemical Engineering Division of the Texas Engineering Experiment Station in
The Texas A&M University System. Our special thanks to Steve Conroy who supervised the preparation of
the camera-ready copy of the manuscript. Also we thank Mark Sutton, Stephanie Hale and Yong Lee for
their assistance in formatting the text and preparing the graphs.

College Station, August 1997 R. C. Wilhoit, X. Hong, M. Frenkel, K. R. Hall


References
23-ano Landolt-Brnstein Physikalisch-Chemische Tabellen, Hauptwerk, Vol. 1, Roth, W.A., Scheel,
K. (eds.), Springer-Verlag: Berlin (1923).

28-ano-1 International Critical Tables of Numerical Data, Physics, Chemistry and Technology
Vol. III, Washburn, E. W. (ed.), McGraw-Hill: New York (1928).

50-tim Timmermans, J.; Physico-Chemical Constants of Pure Organic Compounds, Vol. 1, Elsevier:
New York (1950).

55-dre Dreisbach, R. R.; Physical Properties of Chemical Compounds, Advances in Chemistry Series
No. 15, Am. Chem. Soc.: Washington, D. C. (1955).

59-dre Dreisbach, R. R.; Physical Properties of Chemical Compounds - II, Advances in Chemistry
Series No. 22, Am. Chem. Soc., Washington, D. C. (1959).

61-dre Dreisbach, R. R.; Physical Properties of Chemical Compounds, Advances in Chemistry Series
No. 29, Am. Chem. Soc.: Washington, D.C. (1961).

65-tim Timmermans, J.; Physico-Chemical Constants of Pure Organic Compounds, Vol. II, Elsevier:
New York (1965).

71-ano Landolt-Brnstein Sechste Auflage, II Band, Eigenschaften der Materie in ihren


Aggregatzustanden, 1 Teil, Mechanisch-thermische Zustandsgrssen. Springer-Verlag:
Berlin (1971).

86-smi/sri Smith, B. D.; Srivastava, R.; Thermodynamic Data for Pure Compounds, Part B. Halogenated
Hydrocarbons and Alcohols, Elsevier: New York (1986).

86-smi/sri-1 Smith, B. D.; Srivastava, R.; Thermodynamic Data for Pure Compounds, Part A.
Hydrocarbons and Ketones, Elsevier: New York (1986).

89-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation. Taylor & Francis: London (1989).

91-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation, Supplement 1. Taylor & Francis: London (1991).

92-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation, Supplement 2. Taylor & Francis: London (1992).

93-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation, Supplement 3. Taylor & Francis: London (1993).

94-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation, Supplement 4. Taylor & Francis: London (1994).

95-dau/dan Daubert, T. E.; Danner, R. P.; Physical and Thermodynamic Properties of Pure Chemicals:
Data Compilation, Supplement 5. Taylor & Francis: London (1995).
96-wil/mar Wilhoit, R. C.; Marsh, K. N.; Hong, X.; Gadalla, N.; Frenkel, M.; Densities of Aliphatic
Hydrocarbons: Alkanes.
Landolt-Brnstein, New Series, Vol. IV/8B, Springer: Berlin (1996)

96-wil/mar-1 Wilhoit, R. C.; Marsh, K. N.; Hong, X.; Gadalla, N.; Frenkel, M.; Densities of Aliphatic
Hydrocarbons: Alkenes, Alkadienes, Alkynes and Miscellaneous Compounds.
Landolt-Brnstein, New Series, Vol. IV/8C, Springer: Berlin (1996)
1.1 Basic Concepts 1

1 Introduction

1.1 Basic Concepts


The mass density of a substance is an intensive quantity defined by:
= m/v (1.1)

where m is the mass and v is the volume of the sample. Both these quantities are extensive quantities.
Other densities often referred to in the literature are the relative density and the molar density. Relative
density, also called specific gravity, is:
r = / 0 (1.2)

where 0 is the density of a standard substance. It is necessary to specify the conditions of temperature and
pressure for the standard substance. The most common reference material is water often at the temperature
of its maximum density, 4 C, at atmospheric pressure. The molar density is defined as
m = 1/V (1.3)

where V is the volume occupied by one mole of the substance. The only densities reported in this volume
are the mass densities; relative and molar densities have been converted to mass densities, and all densities
have been reported in SI units. The API specific gravity is: (API) = 141.5/r 131.5, in which r is
(288.68 K)/(288.68 K), and the standard substance is water at 288.68 K (60 F).
The density of a material is a function of temperature and pressure but its value at some standard
condition (for example, 293.15 K or 298.15 K at either atmospheric pressure or at the vapor pressure of
the compound) often is used to characterize a compound and to ascertain its purity. Accurate density
measurements as a function of temperature are important for custody transfer of materials when the
volume of the material transferred at a specific temperature is known but contracts specify the mass of
material transferred. Engineering applications utilize the density of a substance widely, frequently for the
efficient design and safe operation of chemical plants and equipment. The density and the vapor pressure
are the most often-quoted properties of a substance, and the properties most often required for prediction
of other properties of the substance. In this volume, we do not report the density of gases, but rather the
densities of solids as a function of temperature at atmospheric pressure and the densities of liquids either
at atmospheric pressure or along the saturation line up to the critical temperature.
The purpose of this compilation is to tabulate the densities of compounds, hence only minimal
description of experimental methods used to measure the density of liquids or solids appears. Detailed
descriptions of methods for density determination of solids, liquids and gases, along with appropriate
density reference standards, appear in a chapter by Davis and Koch in Physical Methods of Chemistry,
Volume VI, Determination of Thermodynamic Properties [86-ros/bae].
The two principal experimental apparatus used to determine the density of a liquid are: the pycnometer
and the vibrating tube densimeter. The pycnometer method involves measuring the mass of a liquid in a
vessel of known volume. The volume of the pycnometer, either at the temperature of measurement or at
some reference temperature, is determined using a density standard, usually water or mercury. Using
considerable care and a precision analytical balance accurate to 10-5 g, it is possible to achieve densities
accurate to a few parts in 106 with a pycnometer having a volume of 25 cm3 to 50 cm3.

Landolt-Brnstein
New Series IV/8D
2 1.2 Scope of the Compilation

It is common to achieve accuracies of 1 part in 105 and routine measurements can achieve 1 part in 104
with pycnometers having volumes as small as 5 cm3
The vibrating tube densimeter relies upon the fact that the frequency f of vibration for a U or V shaped
tube depends upon the mass of material in the tube:

= A/ f 2 + B (1.4)

Calibration of the apparatus is necessary; usually water and air or nitrogen are the reference materials.
Vibrating tube densimeters designed to operate close to atmospheric pressure can achieve repeatability of
parts in 106. If the reciprocal of the frequency is linear in density, accuracies of 1 part in 105 are readily
achievable.
The principal experimental method used to measure the density of a solid is determination of the mass
of liquid displaced by a known mass of solid. It is essential that the solid have no appreciable solubility in
the liquid, that all occluded air be removed from the solid and that the density of the displacement fluid be
less than that of the solid lest the solid float. Densities of crystalline solids also can be determined from
the dimensions of the unit cell. Davis and Koch discuss other methods for measuring the density of liquids
and solids such as: hydrostatic weighing of a buoy and flotation methods.

1.2 Scope of the Compilation


Volume IV/8D presents observed values for the densities of monocyclic hydrocarbons, the majority of
which are important industrial compounds. These values represent a compilation and evaluation of data
from the scientific literature covering approximately the past 100 years. The values presented come from
the TRC Source Database. The Thermodynamics Research Center has assembled these data over a period
of years and has used them to provide the evaluated density values listed in the TRC Thermodynamic
Tables - Hydrocarbons. An additional literature search has been performed immediately before producing
this compilation to locate new or missing data and to bring the collection up-to-date. This compilation
should include at least 90% of the pertinent data reported in the literature. The usual experimental
conditions are in contact with air at one atmosphere below the normal boiling point of the hydrocarbon,
and in equilibrium with the vapor phase above the normal boiling point. In the summary tables,
temperatures reported on the Kelvin scale have been obtained by adding 273.15 to temperatures originally
given on the Celsius scale.
Densities have units of kilograms per cubic meter (kgm-3). Values reported in units of grams per
milliliter, where the liter is the volume of one kilogram of water at its temperature of maximum density
convert to kgm-3 when multiplied by 0.999972 (as defined by the 12th General Conference of the
International Committee on Weights and Measure, 1964). Values of specific gravity relative to water at a
stated reference temperature become density upon multiplication by the accepted density of water at the
reference temperature. Most reported densities for liquids below the boiling point apply to the air-
saturated liquid.
Compounds are identified by an IUPAC approved name, the empirical molecular formula, and the
Chemical Abstracts Service Registry Number. A summary table is available for each compound which
includes the reported temperature and density values, an assigned uncertainty for the density, the
difference between the observed and smoothed density values and an index key to the source of the data.
A complete list of references, identified by the index keys, appears at the end of the volume.
Where appropriate, tables of smoothed, recommended values are given at integral multiples of 10 K
over the experimental range of temperatures. Values at 293.15 K and 298.15 K are included when they are
in the range of the original data set. The recommended values also have assigned uncertainties.

Landolt-Brnstein
New Series IV/8D
3 1.4 Evaluation, Selection, and Smoothing of Data

1.3 Description of Data Tables


Data for a particular compound are selected, evaluated and smoothed in one of four ways, depending
upon the number and accuracy of the reported values and upon their distribution over the temperature
range.

Case 1. When the data set consists of at least four acceptable, effectively distinct values (see
section 1.5.3), the densities in selected subsets are fit to a function of temperature using the least
squares criterion. A summary table for the selected set gives the densities, their estimated
uncertainties, the deviations between observed and calculated values, an index key to the list of
references and a plotting symbol. If sufficient space remains, some data outside the selected set
also are included in the summary table along with reference keys to any remaining data. A plot of
the deviations between observed and calculated values is shown for the selected subset. Error bars
indicate the size of the estimated uncertainties for the data. Distinct plotting symbols identify the
five data sources that have the smallest average estimated uncertainties. A single symbol represents
all remaining data in the selected set. A table consisting of smoothed, recommended values
(calculated from the fitted functions) also is given. Estimated uncertainties are given for the
recommended values which also appear as a continuous line on the deviation plot. Densities of
crystal phases are in a separate section of the table. In most cases, these densities have not been fit
as a function of temperature. Values of parameters, statistical measures of the fit, and references to
sources of critical constants appear at the beginning of these sections.

Case 2. For data sets that do not meet the criteria of Case 1, but contain acceptable values over a
temperature range of at least two degrees, the results are smoothed using a linear function of
temperature with an estimated coefficient of thermal expansion. A table of smoothed recommended
values is presented.

Case 3. For data sets that do not meet the criteria of either Case 1 or 2 but contain two or more
values at a single temperature, a recommended value is given for this temperature by taking a
weighted average of the observed values.

Case 4. For data sets that contain only single values at one or two temperatures, the reported values are
given rather than recommended values.

1.4 Evaluation, Selection and Smoothing of Data


1.4.1 Assignment of Uncertainties
The Thermodynamics Research Center staff have assigned an uncertainty value to each observed and
recommended density value listed in the tables. The true value of the property has a 95% probability of
being in the range covered by + or - the uncertainty about the reported value. Assignment of uncertainty is
a subjective evaluation based upon what is known about the measurement when the value is entered into
the database, and includes the effects of all sources of experimental error. The errors have been
propagated to the listed density at the reported temperature. Uncertainties reported by the investigators are
considered but not necessarily adopted. Often, investigators report repeatability, but they usually do not
provide uncertainty.
Errors in density result from errors in temperature measurement or control; calibration of instruments;
transfer, handling and weighing of samples; and impurities in the samples. At temperatures well below the
critical temperature and near room temperature, standard techniques easily achieve accuracies of 0.05%.
For the compounds in this compilation, that level corresponds to about 0.4 kgm-3. Under these
conditions, errors in temperature are not very significant. This level of accuracy only requires
temperatures to be known within 0.5 K. At temperatures approaching the critical temperature,

Landolt-Brnstein
New Series IV/8D
4 1.4 Evaluation, Selection, and Smoothing of Data

measurements become more demanding because of the rapid increase in the coefficient of thermal
expansion. Greater accuracy, in general, requires careful attention to calibration, mass determination and
sample handling techniques. It is assumed that values obtained by pycnometers have been corrected for
buoyancy of air, unless the author specifically says otherwise. This correction increases the apparent
density by 0.05 - 0.1%. When this correction has not been made, the estimated uncertainty is greater.
Most measurements of densities of liquids below their normal boiling points are made in the presence
of air. Densities reported here refer to liquids in equilibrium with a gas phase consisting of a mixture or air
and vapor at a total pressure of one atmosphere below the normal boiling point and of vapor at the
equilibrium vapor pressure above the boiling point. Thus air is not regarded as an impurity. The effect of
dissolved air and other gases on the densities of liquid hydrocarbons has been reported by Ashcroft and
Ben Isa (97-ash/ben). The differences they observed between the density of a liquid saturated with air at 1
atm and 298.15 K and the air-free liquid are shown in Table 1.

Table 1. Difference between densities of liquids saturated with air at 1 atm and 298.15 K and air free
liquids at the same temperature
Compound (air sat.) - (air free) Compound (air sat.) - (air free)
kgm-3 kgm-3
Heptane -0.089 Tetradecane -0.054
Octane -0.081 Hexadecane -0.047
Nonane -0.072 Cyclohexane -0.068
Decane -0.067 Methylcyclohexane -0.077
Dodecane -0.059 Toluene -0.062

A major source of error in most measurements is the presence of impurities in the sample. The effect
of an impurity depends upon its amount in the sample and upon the difference between its density and the
density of the principal constituent. Even when the sample purity is provided quantitatively, the impurities
often are not identified individually. Nevertheless, a report of sample purity reduces the estimated
uncertainty because it can be taken as evidence that the investigator has considered sample purity. The
most ubiquitous impurity in liquids is water, and, because its density differs significantly from those of
hydrocarbons, it is a common source of error. Exclusion of water requires that the sample be protected
from the atmosphere during transfer, and that special precautions be taken to remove the sample from
containers.
The principal source of high purity samples from 1952 to 1960 was the American Petroleum Institute
Research Project 6 at Carnegie-Mellon University. These samples were distributed to researchers through
the API Project 44 from Carnegie-Mellon University and Texas A&M University. Phillips Petroleum Co.
also supplied high purity samples, but they ceased doing so. Samples for 300 compounds from API
Project 42 are available from the Thermodynamics Research Center, along with limited supplies of
samples for compounds from API Project 6.

1.4.2 Quantitative Effect of Impurity on Density of Liquids


The molar volume of a mixture of components, V, in terms of the mole fractions xi and partial molar
volumes of the components Vi is:
c
V = xiVi (1.5)
i =1

Landolt-Brnstein
New Series IV/8D
1.4 Evaluation, Selection, and Smoothing of Data 5

For an ideal solution, the partial molal volumes equal the molar volumes of the pure liquid components.
Denoting component the main components as 1 and the impurities as > 1, the volume becomes:
c
V = x1V1 + xiVi . (1.6)
i=2

Then using,
= M /V (1.7)

and the molar mass of the mixture:


c
M = xi M i (1.8)
i =1

and assuming that the xi are small for i > 1, then

1 c

= 1 1 wi vi (1.9)
w1 i=2

where vi = Vi /Mi are partial specific volumes of the impurities and wi is the mass fraction of component i.
Finally, the density of the mixture is related to the density of the main component and the impurities i by:

1 c
w
= 1 1 i (1.10)
w1 i =2 i

The observed value of the density of a sample is sometimes presented as evidence of its purity.
Assuming the sample contains a single impurity, equation (1.10) can be solved for - 1:
1 = 1 (1 w1 1 w2 / 2 ) / w1 (1.11)

If water is the single impurity, with 2 = 1000 kgm-3 and 1 = 800 kgm-3, equation (1.10) gives the values
summarized in Table 2.

Table 2. Effect of water as an impurity on density


of a sample.
100 w2 ( 1)/ kgm-3
0.02 0.032
0.05 0.080
0.10 0.16
0.2 0.32

If we replace - 1 by its uncertainty u in equation (1.11) then w2 is the minimum value of the mass
fraction of the impurity that could be reliably detected. The uncertainty in - 1 includes the uncertainty
in the measurement of but also the uncertainty in 1 , the density of the pure sample. The value of 1
must be determined for a sample whose purity is known, by some independent means, with an accuracy
considerably greater than the one being tested. An example using equation (1.11) and Table 3 is the
determination of a small impurity of cis-1,2-dimethylcyclopentane in trans-1,2-dimethylcyclopentane.
Table 3 contains numerical solutions of equation (1.11) at various densities and uncertainties.
The selected densities of trans- and cis-1,2-dimethylcylopentane are (746.83 0.15)kgm-3 and
(768.09 0.18)kgm-3 respectively at 298.15 K. Assuming the density of the sample with the impurity is
accurate to within 0.4 kgm-3, the total uncertainty is {(0.4)2 + (0.15)2}1/2 = 0.43 kgm-3.
Because 1/2 = 0.972, |1 -2| / u = 49.4.

Landolt-Brnstein
New Series IV/8D
6 1.4 Evaluation, Selection, and Smoothing of Data

Interpolation with these values from Table 3 indicates that the minimum mass fraction of cis-1,2-
dimethylcyclopentane that can be detected by density measurement is 0.020. This corresponds to a purity
of 98.0 mass %. The minimum detectable mass fraction of 1,1-dimethylcyclopentane is 0.130 for the same
assumptions. Hence density measurement is not a sensitive method to determine purity when the density
of the impurity is close to that of the compound under consideration.

Table 3. Minimum mass fraction of impurity detectable by density measurement for a mixture.
1 /2
2 1 / u
0.8 0.9 0.95 1.0 1.05 1.1 1.2
500 0.0025 0.0022 0.0021 0.0020 0.0019 0.0018 0.0017
200 0.0062 0.0055 0.0052 0.0050 0.0047 0.0045 0.0041
100 0.0123 0.0110 0.0104 0.0099 0.0094 0.0090 0.0083
50 0.024 0.022 0.021 0.020 0.019 0.018 0.016
20 0.059 0.053 0.050 0.048 0.046 0.044 0.040
10 0.111 0.100 0.095 0.091 0.087 0.083 0.077
5 0.200 0.182 0.174 0.167 0.160 0.154 0.143
2 0.385 0.357 0.345 0.333 0.323 0.312 0.294
1 0.556 0.526 0.513 0.500 0.488 0.476 0.454

1.4.3 Procedure for Selection and Smoothing of Density Values - Case 1


A selected subset of the reported densities is fit to functions of temperature using the least squares
criterion. Up to a boundary temperature Tb (approximately 0.8Tc), the calculated density is represented x

by a polynomial in temperature with coefficients a of order p,


k

p
x = ak T k . (1.12)
k =0

Above Tb the smoothed values are given by a modification of the Guggenheim equation [67-gug]

( )[
x = 1 + 1.75 + 0.75 3 c + b1 ( Tc T ) + b2 ( Tc T ) + b3 (Tc T ) + b4 ( Tc T )
2 3 4
] (1.13)

where Tc is the critical temperature and = (1-T/Tc)1/3. Selected values of critical constants are constant.
Continuity with equation (1.12) results from forcing the two functions and their first derivatives with
respect to temperature to be equal at the boundary. When no values are available above this temperature,
only the polynomial is used.
The following steps, implemented by a computer program written in C, generate the smoothed,
recommended values. Input to the program consists of the set of observed density values, temperatures,
estimated uncertainties, critical constants and values of certain parameters used by the program.

Step 1. Separate the initial data into two sets, corresponding to temperatures above and below Tb .

Step 2. Make an initial selection from the low temperature set by rejecting all points with zero
uncertainty and all points with uncertainties above a limit determined by the data selection
algorithm described in section 1.5.2. Zero uncertainties are assigned to values that are not
experimental and are included for comparison only (these are most often values recommended in
other compilations).
Step 3. Determine the effective number of data values, ne, as described in 1.5.3. If the effective
number of values is less than four, terminate the calculation. If the total number of values is more
than eight and the effective number is greater than or equal to four but less than eight, make
another initial data selection with relaxed selection criteria.

Landolt-Brnstein
New Series IV/8D
1.4 Evaluation, Selection, and Smoothing of Data 7

Step 4. For the j-th value in the set calculate normalized values, and T and weighting factors,
n,j n,j,

w j = 1 / u 2j where uj is the uncertainty assigned to the j-th observed density and n , j = j


where is the mean value of the observed density in the set. and Tn , j = T k T k where T k is the
mean value of the T jk value in the set..
Step 5. Using = a1T , fit the data subject to least squares with points weighted by w .
n n j

Step 6. Calculate the standard deviation for this fit. Eliminate any points from this set for which
| | > 3.5, where j = j x , j .
j

Step 7. Fit the remaining normalized values to a series of polynomials, n = a k T k , starting


with order 1 and increasing in order. Use wj as weighting factors and stop increasing the order
when satisfying one of the following conditions:
1. A value of p given as an input parameter to the program is reached, or
2. 2k < 11
. [1 + 1 / (n k )]2 2k 1 (see glossary of symbols) and the deviations pass the random
deviation test (see 1.5.4).
Step 8. If any points have | | > 2.2 for the final polynomial, eliminate these points and repeat
j

step 7.
Step 9. Calculate parameter a0 .
Step 10. Apply the initial data selection described in step 2 to the high temperature data set.
Step 11. Fit the selected high temperature data with the modified Guggenheim equation using least
squares with weighting factors w . j

Step 12. The following procedure provides continuity at the boundary. Set equation (1.13) and its
first derivative at Tb equal to the corresponding values from equation (1.12) at Tb. Eliminate
parameters b3 and b4 from these two simultaneous equations to obtain a function containing
parameters b1 and b2 which can be evaluated for the high temperature range using least squares. Do
not use densities at temperatures within 2 K of the critical temperature.
Step 13. Generate the output table of temperature, observed densities, estimated uncertainties, and
difference between observed and calculated densities and arrange it in order of year of publication
with authors. For data from a particular source, arrange in order of temperature.
Step 14. Calculate the table of smoothed and recommended values with their corresponding
estimated uncertainties.
Coefficients A, B, C, D and E listed in the heading of Table 1 for each compound correspond to a0, a1,
a2, a3 and a4 in equation (1.12) for temperatures below Tb. is the weighted standard deviation for
O

individual points in this region (see the glossary). If the data set includes values above Tb, the coefficients
A, B, C and D correspond to b1, b2, b3 and b4 in equation (1.13) for this range. The weighted standard
deviation, c,w, and the unweighted standard deviation for the fit, c,uw, include both ranges. If the data set
covers only values below Tb then c,w and c,uw represent that range only.
The uncertainty in the smoothed values depends upon the uncertainties in the original observed values
and upon the magnitude of deviations between observed and calculated values. To approximate the
contribution of these two effects at the temperature T, the uncertainties u (T) for the low temperature range
x

are calculated from:


1/ 2

u x (T ) = u(T ) 2 + Ckl (T k T k )(T l T l ) (1.14)
k l
In this equation, u(T) represents the uncertainty of the observed data in the vicinity of T and is

Landolt-Brnstein
New Series IV/8D
8 1.5 Calculation Procedures

approximated by fitting a polynomial of order 1-3 to the estimated uncertainties as a function of


temperature (other symbols appear in the glossary). Uncertainties in the smoothed data for the high
temperature range are calculated using:

[
u x ( T ) = u x (Tb ) + h( T ) ]
1/ 2
2 2
(1.15)

where u (Tb) is the uncertainty calculated using equation (1.14) for the low temperature range at the
x

boundary temperature Tb and h(T) is a polynomial in temperature fit to the reciprocals of the estimated
uncertainties in the high temperature region.

1.4.4 Procedure for Selection and Smoothing of Density Values - Case 2


When the data set for a particular compound satisfies the criteria for Case 2, it is smoothed by a linear
function of temperature,
x = a 0 + a1T (1.16)

The coefficient a1 is either calculated from two densities of sufficient accuracy reported at different
temperatures, preferably by the same investigator, or estimated by examination of the coefficient of
expansion of similar compounds obtained from a least squares calculation. The constant term then results
from equation (1.17) after eliminating values with large uncertainties

( )
a 0 = w j j a1Tj / w j (1.17)

The uncertainties for the smoothed values are:

ux (T ) = [ 20 + 12 (T T ) 2 ]2 (1.18)

where T is the weighted mean temperature for the accepted set, 20 = ( w j 2j ) / w j and 1 is the
estimated standard deviation of a1 .

1.4.5 Procedure for Selection and Smoothing of Density Values - Case 3


The recommended density at a particular temperature is the weighted mean observed density for that
temperature. The corresponding uncertainty is the standard deviation from the mean for each value.

1.5 Calculation Procedures


1.5.1 Least Squares Calculation
Parameters of all the smoothing functions are adjusted to minimize the function
2 = w j 2j (1.19)

by the singular value decomposition of the matrix of independent variables of the function. The
parameters are calculated by functions svdcmp and svbksb described in [88-pre/fla] modified to accept
weighting factors. The covariance matrix used in equation (1.14) is calculated by the function covar from
the same book.

Landolt-Brnstein
New Series IV/8D
1.5 Calculation Procedures 9

1.5.2 Selection of Data Based upon Estimated Uncertainties


The selection procedure is:
Step 1. Obtain T, the range of temperatures covered by the data set.
Step 2. For each density value, , in the set, calculate,
j

(
x jl = exp q Tj Tl ) (1.20)

z1 = x jl (1.21)
l j

z2 = ul x jl (1.22)
l j

y = u j z11.5 z21 (1.23)

Accept point j if y d; reject it otherwise


Step 3. Repeat steps 1 and 2 with points accepted in the first pass.

The accepted points are those that remain from Step 3. The constants q and d are:

[
q = 2.628 g1 1 + ( T / 30)
2
] / T
d = g 2 / log 10 (1 + n)

The number z2 / z1 is a weighted mean of all points in the set other than the j-th point. The weighting factor
decreases exponentially with the difference in temperature of the l-th point from the j-th point. The
parameter g1 determines the rate of decrease. This procedure compares the uncertainty of the j-th point to
the weighted mean of other points. The parameter g2 determines the rejection level from this comparison
for the j-th point. Larger values of g2 are less selective. Values for g1 and g2 are supplied to the algorithm.
For all cases g1 is in the range of 1 to 2 (usually 1.8). The value of g2 is in the range of 2 to 3 (kgm-3)
(usually 2.5).

1.5.3 Count of the Effective Number of Density Values in a Set


The number of degrees of freedom in a least squares fit is the number of distinct data values minus the
number of adjustable parameters. To obtain a meaningful smoothing of data, the order of the polynomial
function is limited to values which gives three or more degrees of freedom. However, if two or more
density values in the set are at the same (or nearly the same) temperature, they should count as only one
point in calculating the degrees of freedom. In general, the effective number of density values minus the
number of fitting parameters is used as the degrees of freedom. Effective data values are those that are
separated by at least 1.2 K.

1.5.4 Testing a Set of Deviations between Observed and Calculated Density Values
for a Random Distribution
One of the criteria for acceptance of the order of a polynomial least squares fit is that the deviations
between calculated and random values be distributed randomly over the range of conditions covered by
the data. The concept of randomness for this purpose probably cannot be defined rigorously. However, the
following test for randomness is used whenever the original data set contains seven or more values.

Landolt-Brnstein
New Series IV/8D
10 1.6 Glossary of Symbols

Step 1. Sort the values in order of increasing temperature


Step 2. Separate the total range of temperature, T, into s subranges each of size T/s. Form s
subsets of data corresponding to these temperature subranges.
Step 3. Make the following comparison for each subset j which has at least four members.

j j
0.01 < and 0.2 <
ns j

If both comparisons are true for any subset, the test for randomness fails.
Step 4. Apply steps 2 and 3 to the data for s from 2 to an upper limit. The upper limit is
determined by the number of values in the original set according to the following table.

n, number of values in original maximum number of


set subsets
7 to 10 2
11 to 20 3
21 to 33 4
> 33 5

1.6 Glossary of Symbols


ak parameters in the polynomial function for densities at temperatures Tb
bk k-th parameter in modified Guggenheim equation for density at temperatures >Tb
g 1, g 2 parameters used in the data selection algorithm
n number of accepted values of density in a set
ne effective number of accepted values of density in a set
ns number of density values in subset s
p order of the polynomial for density values at temperatures Tb
s number of subsets in the random deviation algorithm
uj uncertainty assigned to the j-th observed density value in a set
w j weighting factor for the j-th density value in a set
C k,l Element k,l of the variance-covariance matrix for the polynomial parameters
T absolute temperature
Tb boundary temperature
Tc critical temperature
T j temperature for the j-th observed density
Tk mean value of the T jk values in a set
T n,j T jk - T k , normalized value of the j-th temperature raised to the k power
j -
j x,j

j (1 - T /Tc)1/3
j

density
(API) API specific gravity
mean value of observed densities in a set
o density of a standard substance
c critical density

Landolt-Brnstein
New Series IV/8D
11 1.7 Compound Nomenclature

j observed value of j-th density in a data set


m molar density
n,j - , normalized density for the j-th value
j

r relative density
x,j calculated value of the j-th density in a data set
(2/n)1/2, standard deviation for density values in a set
2k 2j for all values in a set fit to a polynomial of order k
T T - T1, range of temperatures for data in a set
n

The following symbols refer to components in a mixture at a fixed temperature

c number of components in the mixture


i component number
vi partial specific volume of component i in the mixture
wi mass fraction of component i in the mixture
xi mole fraction of component i in the mixture
Mi molar mass (molecular weight) of component i
V molar volume of a mixture
Vi partial molal volume of component i in the mixture
density of a mixture of components
i density of pure component i

Symbols used in the tables:

A, B, C, D, E coefficients in function for density (see section 1.4.3)


calc calculated density, x

exp observed value of j-th density in a data set, j

O
( w j 2j / w j )1/ 2 , for low temperature range only
c,w ( w j 2j / w j )1/ 2 , for low and high temperature range combined
c,uw [ 2j / n(n p 2)]1 / 2 , for low and high temperature range combined
2est estimated uncertainty, u j

1.7 Compound Nomenclature


1.7.1 Names of Compounds Used in the Tables

Compound names follow the style: <side chains> <ring name>, where <ring name> is the name of the
cyclic group. Saturated rings are cycloalkanes, such as: cyclobutane, cyclohexane. Unsaturated rings are
cycloalkenes, cycloalkynes, cycloalkadienes, etc.
Side chains, which are attached to the ring, are called radicals in the accepted style for alkanes, alkenes,
alkynes, alkadienes, etc. Thus, names such as butyl, pentyl, hexyl refer to saturated, straight chain, alkyl
radicals. Names such as ethenyl, 1-propenyl, 2-butenyl indicate normal radicals with a double bond at the
position indicated by the number. Prefixes such as di, tri, tetra specify 2, 3, 4 radical groups.

Landolt-Brnstein
New Series IV/8D
12 1.7 Compound Nomenclature

The names of branched side chains are enclosed in parenthesis with the position of the side chain shown
by the preceding number. Examples are: (1-methylethyl), (same as isopropyl), (2-ethyl-3-methyl-butyl).
Branched unsaturated side chains are named similarly with a number preceding the base chain to specify
the position of the double or triple bond. Thus (1,3-dimethyl-2-butenyl) indicates:

Names such as ethylidene, propylidene indicate that the double bond is attached directly to the ring, for
example: (1-methylethylidene)cyclohexane

Side chain names are ordered alphabetically within a compound name: butyl, diethyl, dimethyl, ethyl,
methyl, methylene, (1-methylethyl), propyl, tetramethyl. Each side chain name is preceded by its position
number on the ring. The starting point for numbering positions on saturated rings is arbitrary. The first
side chain in the name is number 1. Thus, 1-ethyl-4-methyl-2-propylcyclohexane is:

For unsaturated rings the multiple bond (or one of the multiple bonds if more than one exists) is position
1. Thus, 3-butyl-1-methylcyclopentene is:

The prefixes cis- and trans- identify geometrical isomers of compounds that contain two side chains on
a ring where cis means that the two groups are on the same side of the ring and trans means they are on
opposite sides. Thus cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane are:

cis trans
Geometrical isomers of compounds that contain more than two side chains on a ring are identified by
prefixes r-, c-, and t- preceding the positional number for each group. The r- prefix precedes the number
of the first side chain. This is the reference group that determines the relative orientation of the other
groups. The c- designation means the group is on the same side as the reference group while the t-
means the group is on the side opposite the reference group. For example, r-1-ethyl, c-2-methyl, t-3-
propylcyclopentane means that the methyl group is on the same side as the ethyl group, and the propyl
group is on the opposite side. Prefixes (Z)- and (E)- identify geometrical isomers that differ in the relative
orientation of groups on either side of a double bond in a side chain. The IUPAC rules (93-ano-1) apply,
thus (Z)-(1-methyl-2-propenyl)cyclohexane is:

Landolt-Brnstein
New Series IV/8D
1.7 Compound Nomenclature 13

Rings with double bonds that contain eight or more carbon atoms can also exist in two or more
geometrical forms. These are identified by the (Z)- and (E)- prefixes.
In some cases, the orientation of the side chains is not reported or known at the time the original source
is published. In most of these cases, the samples used for the density measurements are mixtures of
geometrical isomers. When only data on such mixtures are available, they are used as the basis for the
selected and recommended values. The estimated uncertainties reflect the possible differences between the
densities of such mixtures and the pure isomers. In some cases, values of such undefined mixtures and of
specific geometrical isomers are available then both sets of data are shown, but the recommended values
are derived from data on the specific isomers. In cases for which the values for the undefined mixtures
cover a wider temperature range than those of the pure isomers, recommended values are given for both
sets of data.
Compounds that contain an asymmetric substitutions on a carbon atoms exist in enantiomorphic forms.
These differ only in the direction of rotation of polarized light. When the absolute configuration has been
identified in the original report, these compounds are identified by (R)- and (S)- prefixes. Sometimes
prefixes such as d-, l-, (+)-, and (-)-, which are given in the original report have been used. Very often no
identification of the optical isomer is given even when the compound contains an asymmetric carbon
atom. Then it is assumed that the samples are racemic mixtures. However, none of these distinctions affect
the densities of liquids, therefore all the isomers of this type are combined to determined the
recommended values. If a compound contains more than one asymmetric compound diastereomers can
exist. In principle, these might have different densities, but no examples have been found.
Names of compounds in the name index include all those shown in the tables. In addition, other
IUPAC systematic names, Chemical Abstracts indexing names and certain trivial or obsolete names are
also included.

1.7.2 Order of Compounds in the Tables

Compounds in the tables are sorted in the following order:


1. By formula type CnH2n-x , where x = 0, 2, 4, 6, 8
2. Within each formula type by carbon number, n
3. Within each carbon number by ring size from 3 to the maximum
4. Within each ring size alphabetically by the names of the
side chains (omitting positional numbers), as described above
5. Finally by positional numbers of the side chains.

References
67-gug Guggenheim, E. A.; Thermodynamics, 5th edition, North-Holland Publishing
Company: Amsterdam (1957).

86-ros/bae Rossiter, B. W.; Baetzold, R. C.; Physical Methods of Chemistry, 2nd edition, Vol.
VI, Determination of Thermodynamic Properties, John Wiley & Sons: New York
(1986).

Landolt-Brnstein
New Series IV/8D
14 1.7 Compound Nomenclature

88-pre/fla Press, W. H.; Flannery, B. P.; Teukolsky, S. A.; Vetterling, W. T.; Numerical
Recipes in C, Cambridge Univ. Press: New York (1988).

93-ano-1 Panico, R.; Powell, W. H.; Richer, J. C.; A Guide to IUPAC Nomenclature of
Organic Compounds: Recommendation 1993, Blackwell Scientific Publications:
Oxford (1993).

97-ash/ben Ashcroft, S. J.; Ben Isa, M.; J. Chem. Eng. Data, (in press), (1997)

Landolt-Brnstein
New Series IV/8D
2. Tabulated Data on Density - Alkylcycloalkanes (CnH2n)
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 17

2.1 Alkylcycloalkanes (CnH2n), C3 to C5

Cyclopropane [75-19-4] C3H6 MW = 42.0806 1

Tc = 398.00 K [96-dau]
c = 259.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.3761 (low temperature range), c,w = (1.2305 combined temperature ranges, weighted),
O

c,uw = 2.7685 10-1 (combined temperature ranges, unweighted).


T = 193.15 to 335.00 K T = 335.00 to 398.00 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 1.65474 103 4.82099 10-1
B -9.97937 -5.47531 10-3
-2
C 3.66243 10 -8.09668 10-5
-5
D -4.96798 10 1.32545 10-6

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

crystal 318.15 586.40 0.39 -0.66 70-lin/sil()


94.00 913.0 30.00 88-nij/vos 323.15 577.60 0.40 -0.38 70-lin/sil()
liquid 328.15 568.70 0.41 0.38 70-lin/sil()
193.15 735.20 1.50 -0.38 38-gro/wak() 333.15 559.20 0.42 1.15 70-lin/sil()
233.15 688.60 1.00 -0.68 38-gro/wak() 338.15 549.50 0.43 2.10 70-lin/sil()
240.40 680.70 1.00 -1.39 38-gro/wak() 343.15 539.50 0.44 2.34 70-lin/sil()
193.15 735.20 0.70 -0.38 39-gro/lin( ){ 348.15 528.70 0.45 1.69 70-lin/sil()
203.15 723.50 0.60 1.10 39-gro/lin( ){ 353.15 517.50 0.46 0.96 70-lin/sil()
213.15 711.90 0.60 1.41 39-gro/lin( ){ 358.15 505.50 0.47 0.09 70-lin/sil()
223.15 700.20 0.60 0.65 39-gro/lin( ){ 363.15 492.70 0.48 -0.57 70-lin/sil()
233.15 688.60 0.50 -0.68 39-gro/lin( ){ 368.15 478.70 0.49 -1.10 70-lin/sil()
240.45 680.70 0.50 -1.34 39-gro/lin( ){ 373.15 463.60 0.50 -1.03 70-lin/sil()
243.15 676.90 0.50 -2.49 39-gro/lin( ){ 378.15 446.90 0.55 -0.37 70-lin/sil()
235.10 688.90 0.40 1.57 62-has/sno( ) 383.15 428.30 0.62 1.32 70-lin/sil()
238.00 685.60 0.40 1.15 62-has/sno( ) 388.15 403.30 0.80 1.06 70-lin/sil()
293.15 626.80 0.34 1.68 70-lin/sil() 393.15 370.70 1.00 1.92 70-lin/sil()
298.15 619.10 0.35 0.74 70-lin/sil() 397.15 322.50 1.50 4.22 70-lin/sil()
303.15 611.20 0.36 -0.02 70-lin/sil() 397.35 318.10 2.50 5.03 70-lin/sil()
308.15 603.00 0.37 -0.64 70-lin/sil() 397.55 313.40 3.00 6.71 70-lin/sil1)
313.15 594.80 0.38 -0.80 70-lin/sil()
1) Not included in Fig. 1.

Further references: [1889-hof, 00-gus, 17-jae, 20-mou/bou, 22-tra/win-1].

cont.

Landolt-Brnstein
New Series IV/8D
18 2.1 Alkylcycloalkanes (CnH2n), C3 to C5

Cyclopropane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
190.00 740.04 1.12 260.00 662.74 0.70 330.00 564.60 0.90
200.00 726.40 0.94 270.00 652.38 0.72 340.00 543.58 1.00
210.00 714.12 0.81 280.00 641.29 0.72 350.00 523.19 1.08
220.00 702.91 0.71 290.00 629.19 0.72 360.00 501.05 1.15
230.00 692.46 0.64 300.00 615.77 0.72 370.00 474.41 1.22
240.00 682.48 0.65 310.00 600.72 0.76 380.00 440.16 1.30
250.00 672.67 0.68 320.00 583.77 0.78 390.00 391.32 1.36

Landolt-Brnstein
New Series IV/8D
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 19

Methylcyclopropane [594-11-6] C4H8 MW = 56.11 2

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.9179 10-1 (combined temperature ranges,
weighted), c,uw = 7.3304 10-2 (combined
temperature ranges, unweighted).
T = 253.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01482 103
B -1.27805

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

253.15 691.30 3.00 0.02 1895-dem() 293.15 640.00 1.00 -0.16 56-ano( ){
265.15 676.00 3.00 0.06 1895-dem() 298.15 634.00 1.00 0.23 71-goo-1()
293.15 640.00 1.00 -0.16
52-ano-4( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
20 2.1 Alkylcycloalkanes (CnH2n), C3 to C5

Methylcyclopropane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
250.00 695.30 2.96 280.00 656.96 1.83 298.15 633.77 1.19
260.00 682.52 3.25 290.00 644.18 1.16 300.00 631.40 1.28
270.00 669.74 2.72 293.15 640.16 1.10 310.00 618.62 2.47

Cyclobutane [287-23-0] C4H8 MW = 56.1075 3

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0556 101 (combined temperature ranges,
weighted), c,uw = 4.8517 (combined
temperature ranges, unweighted).
T = 194.65 to 293.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.61715 102
B -9.14896 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

crystal II 194.65 802.00 5.00 18.37 42-ben()


117.00 948.00 30.00 92-ste/leh 206.15 788.00 5.00 14.89 42-ben()
crystal I 227.15 761.00 5.00 7.10 42-ben()
173.00 840.00 50.00 53-car/tem 236.15 731.00 5.00 -14.66 42-ben()
liquid 247.15 715.00 5.00 -20.60 42-ben()
268.15 718.50 1.00 2.11 07-wil/bru( ){ 273.15 698.00 5.00 -13.81 42-ben1)
273.15 703.80 1.00 -8.01 07-wil/bru( ){ 293.15 694.31 0.40 0.80 52-kaa/coo( )
1) Not included in Fig. 1.

cont.

Landolt-Brnstein
New Series IV/8D
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 21

Cyclobutane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
190.00 787.89 15.00 240.00 742.14 13.00 290.00 696.40 1.50
200.00 778.74 13.00 250.00 732.99 15.00 293.15 693.51 0.80
210.00 769.59 11.00 260.00 723.84 13.00 298.15 688.94 2.00
220.00 760.44 10.00 270.00 714.69 10.00 300.00 687.25 2.50
230.00 751.29 11.00 280.00 705.54 8.00

Landolt-Brnstein
New Series IV/8D
22 2.1 Alkylcycloalkanes (CnH2n), C3 to C5

Ethylcyclopropane [1191-96-4] C5H10 MW = 70.13 4

Table 1. Fit with estimated B coefficient for 13


accepted points. Deviation w = 1.162.
Coefficient = A + BT
A 976.90
B -1.000

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3 kg m3 K kg m3 kg m3

293.15 678.4 4.00 -5.35 13-zel/sch1) 293.15 677.0 2.00 -6.75 37-gro
273.15 697.5 4.00 -6.25 13-zel/sch 1) 293.15 684.0 0.60 0.25 42-van/mee
273.15 705.5 3.00 1.75 16-phi 293.15 683.9 0.40 0.15 47-ano-1
291.40 686.6 3.00 1.10 16-phi 293.15 683.9 0.50 0.15 49-van/gre
293.15 683.2 3.00 -0.55 16-ros-1 293.15 684.0 0.40 0.25 54-pom/foo-1
293.15 678.2 3.00 -5.55 22-cha 293.15 684.3 0.60 0.55 55-gra/gre
273.15 697.5 3.00 -6.25 22-cha 293.15 683.5 0.60 -0.25 69-par/kho
293.15 676.4 2.00 -7.35 30-les-1
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
K kg m 3
K kg m 3
K kg m3
270.00 706.9 4.7 290.00 686.9 1.3 298.15 678.8 1.6
280.00 696.9 2.8 293.15 683.8 1.2 300.00 676.9 1.8

1,1-Dimethylcyclopropane [1630-94-0] C5H10 MW = 70.13 5

Table 1. Fit with estimated B coefficient for 9


accepted points. Deviation w = 0.894.
Coefficient = A + BT
A 953.17
B -1.000

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

293.15 660.4 0.50 0.38 1898-gus/pop 283.15 669.75 0.30 -0.27 44-boo/per
290.15 661.9 1.00 -1.12 00-gus 283.15 669.7 1.00 -0.32 44-gre-1
287.55 668.1 1.00 2.48 39-whi/pop 293.15 658.9 0.50 -1.12 48-sho/cra
293.15 660.4 0.50 0.38 41-whi/pop 293.15 661.8 1.50 1.78 53-slo/gri
287.55 668.1 1.00 2.48 41-whi/pop 293.15 667.1 4.00 7.08 57-lev/kos 1)
1)
Not included in calculation of linear coefficients.
cont.

Landolt-Brnstein
New Series IV/8D
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 23

1,1-Dimethylcyclopropane (cont.)

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
280.00 673.2 1.9 293.15 660.0 1.3 300.00 653.2 2.5
290.00 663.2 1.0 298.15 655.0 2.2

cis-1,2-Dimethylcyclopropane [930-18-7] C5H10 MW = 70.13 6

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 0.164.
Coefficient = A + BT
A 975.31
B -0.960

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3
kg m3 K kg m 3
kg m3

293.15 692.8 1.00 -1.09 29-bau-1 293.15 693.9 0.20 0.01 53-ano-1
273.15 713.2 2.00 0.14 29-bau-1 293.15 693.9 0.20 0.01 53-ano-11
293.15 694.1 0.40 0.21 49-ano-2 293.15 694.1 1.00 0.21 55-kel/gre
293.15 693.7 0.40 -0.19 51-ano-5

Table 3. Recommended values.


T exp 2 est T exp 2est T exp 2 est
K kg m 3
K kg m3 K kg m3
270.00 716.1 0.9 290.00 696.9 0.2 298.15 689.1 0.3
280.00 706.5 0.5 293.15 693.9 0.2 300.00 687.3 0.4

trans-1,2-Dimethylcyclopropane [2402-06-4] C5H10 MW = 70.13 7

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.344.
Coefficient = A + BT
A 948.29
B -0.950

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3
kg m3 K kg m 3
kg m3

295.15 675.4 4.00 7.51 12-ost 1) 293.15 669.8 0.20 0.01 49-ano-2
293.15 676.9 5.00 7.11 29-bau-11) 293.15 669.7 0.40 -0.09 53-ano-1
273.15 698.5 5.00 9.71 29-bau-1 293.15 669.8 1.00 0.01 55-kel/gre
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
24 2.1 Alkylcycloalkanes (CnH2n), C3 to C5

trans-1,2-Dimethylcyclopropane (cont.)

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
270.00 691.8 1.0 290.00 672.8 0.4 298.15 665.0 0.4
280.00 682.3 0.6 293.15 669.8 0.3 300.00 663.6 0.5

Methylcyclobutane [598-61-8] C5H10 MW = 70.134 8

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.4272 10-1 (combined temperature ranges,
weighted), c,uw = 3.9228 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 293.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.20341 103
B -2.60011
C 2.93226 10-3

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 713.50 1.50 1.53 13-dem/doj1) 273.15 711.80 1.50 -0.17 16-phi-1( )
288.15 697.60 0.60 -0.06
13-dem/doj( ) 291.15 695.00 1.50 0.05 16-phi-1( )
291.15 695.00 0.60 0.05
13-dem/doj( ) 273.15 711.80 1.00 -0.17 16-phi()
293.15 693.10 0.60 -0.08
13-dem/doj( ) 291.15 695.00 1.00 0.05 16-phi()
273.15 711.80 1.50 -0.17 14-phi-3( ) 293.15 693.30 0.80 0.12 29-ros( ) {
273.15 712.20 1.50 0.23 14-phi-3( ) 273.15 712.00 1.00 0.03 37-gro/ipa()
291.15 695.00 1.50 0.05 14-phi-3( ) 293.15 693.00 1.00 -0.18 38-ipa/pin-2()
273.15 712.20 1.50 0.23 16-phi-1( )
1) Not included in Fig. 1.

Further references: [12-zel/sch, 54-luk/ovo].

cont.

Landolt-Brnstein
New Series IV/8D
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 25

Methylcyclobutane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 715.14 1.59 290.00 695.98 1.08 298.15 688.85 0.85
280.00 705.27 1.38 293.15 693.18 0.99 300.00 687.28 0.80

Landolt-Brnstein
New Series IV/8D
26 2.1 Alkylcycloalkanes (CnH2n), C3 to C5

Cyclopentane [287-92-3] C5H10 MW = 70.134 9

Tc = 511.70 K [96-dau]
c = 270.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.8036 (low temperature range), c,w = (8.7880 10-1 combined temperature ranges, weighted),
O

c,uw = 9.0963 10-1 (combined temperature ranges, unweighted).


T = 188.63 to 420.00 K T = 420.00 to 511.70 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
2
A 9.13652 10 4.38621
B -1.01827 10-5 -1.94738 10-1
C -1.81801 10-3 2.87479 10-3
-6
D -2.88017 10 -1.34859 10-5
-9
E 8.10380 10

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 764.96 0.10 0.54 37-tim/hen( ) 483.15 503.00 3.00 -0.65 62-kha-1( )
288.15 750.31 0.10 0.65 37-tim/hen( ) 493.15 478.00 5.00 -5.69 62-kha-1( )
303.15 735.69 0.10 0.91 37-tim/hen( ) 503.15 449.00 6.00 18.34 62-kha-1( )
275.43 762.76 0.20 0.57 44-gar( ) 508.15 429.00 8.00 49.75 62-kha-11)
282.62 755.70 0.20 0.58 44-gar( ) 298.15 740.35 0.10 0.61 70-ewi/lev()
283.24 755.11 0.20 0.60 44-gar( ) 298.15 740.36 0.10 0.62 70-mar-1( )
289.39 749.11 0.20 0.68 44-gar1) 313.15 725.13 0.30 0.28 80-sid/goe( )
289.84 748.66 0.20 0.67 44-gar1) 293.15 743.94 0.04 -0.76 86-hol/got6( )
293.15 745.34 0.20 0.64 44-gar1) 293.15 743.94 0.05 -0.76 86-hol/got7( ) {
293.15 745.30 0.20 0.60 44-gar1) 298.15 737.36 0.10 -2.38 86-tar/dia( )
298.02 740.62 0.20 0.75 44-gar1) 298.15 740.22 0.08 0.48 87-luo/ham()
293.15 745.36 0.05 0.66 46-for/gla() 298.15 739.92 0.10 0.18 87-luo/ham()
298.15 740.43 0.05 0.69 46-for/gla() 188.63 840.21 0.42 0.32 92-gar/cac1( )
353.15 683.32 0.60 -2.79 47-kay( ) 2) 192.79 836.70 0.42 0.06 92-gar/cac1( )
393.15 635.99 0.80 -15.24 47-kay1) 2) 198.85 831.58 0.42 -0.21 92-gar/cac1( )
433.15 579.35 1.50 -21.67 47-kay( ) 2) 208.10 823.73 0.41 -0.43 92-gar/cac1( )
473.15 503.49 2.00 -7.54 47-kay( ) 2) 216.70 816.08 0.41 -0.76 92-gar/cac1( )
508.15 365.03 3.00 -14.22 47-kay( ) 2) 219.65 813.84 0.41 -0.44 92-gar/cac1( )
373.15 668.00 2.00 0.02 62-kha-1( ) 222.41 811.46 0.41 -0.40 92-gar/cac1( )
393.15 644.00 2.00 -7.23 62-kha-11) 225.90 808.02 0.40 -0.76 92-gar/cac1( )
413.15 617.00 2.00 -19.32 62-kha-11) 229.82 804.93 0.40 -0.34 92-gar/cac1( )
433.15 589.00 2.20 -12.02 62-kha-1( ) 234.38 800.79 0.40 -0.36 92-gar/cac1( )
453.15 558.00 2.40 20.42 62-kha-1( ) 240.35 795.82 0.40 0.14 92-gar/cac1( )
473.15 523.00 2.60 11.97 62-kha-1( ) 244.61 791.96 0.40 0.23 92-gar/cac1( )
1) Not included in Fig. 1.
2) Calculated from equation given by author.
cont.

Landolt-Brnstein
New Series IV/8D
2.1 Alkylcycloalkanes (CnH2n), C3 to C5 27

Cyclopentane (cont.)

Table 2. (cont.)
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

246.59 790.06 0.39 0.18 92-gar/cac1( ) 278.79 759.56 0.38 0.67 92-gar/cac-11)
248.74 787.96 0.39 0.10 92-gar/cac1( ) 280.57 757.73 0.38 0.59 92-gar/cac-11)
251.48 785.36 0.39 0.08 92-gar/cac1( ) 282.57 755.84 0.38 0.67 92-gar/cac-11)
254.25 782.84 0.39 0.19 92-gar/cac1( ) 284.83 753.59 0.38 0.65 92-gar/cac-11)
257.45 779.82 0.39 0.22 92-gar/cac1( ) 286.36 752.05 0.38 0.62 92-gar/cac-11)
260.47 777.02 0.39 0.31 92-gar/cac1( ) 290.18 748.47 0.37 0.82 92-gar/cac-11)
263.77 773.93 0.39 0.40 92-gar/cac1( ) 292.49 746.16 0.37 0.80 92-gar/cac-11)
266.47 771.34 0.39 0.42 92-gar/cac1( ) 294.35 744.27 0.37 0.76 92-gar/cac-11)
268.02 769.80 0.39 0.38 92-gar/cac1( ) 295.90 742.65 0.37 0.67 92-gar/cac-11)
272.85 765.31 0.38 0.60 92-gar/cac-11) 297.45 741.04 0.37 0.60 92-gar/cac-11)
274.52 763.69 0.38 0.61 92-gar/cac-11) 299.02 739.36 0.37 0.48 92-gar/cac-11)
276.78 761.52 0.38 0.65 92-gar/cac-11) 293.15 744.60 0.60 -0.10 93-jan/xie1)
278.21 760.12 0.38 0.66 92-gar/cac-11)
1) Not included in Fig. 1.
2) Calculated from equation given by author.

Further references: [1893-wis/hen, 03-eyk, 15-ros, 19-cha/sim-1, 19-cha/sim-2, 19-eyk, 19-eyk-1, 22-
cha, 22-cha/van, 30-god/cau, 30-ruz/sto, 32-gar/eva, 33-hof/lan, 33-zel/kaz, 34-god, 38-eva, 38-vog, 39-
wib/hoo, 41-ano-1, 41-ben-1, 43-ano, 43-ano-2, 43-too, 44-can, 46-ano, 46-baz/ste, 46-gei/can, 46-kay-1,
46-ser/spu, 47-huc/har, 47-kay, 47-spi/huf, 49-den/fid, 49-foe/fen, 49-wei, 56-ano, 61-shi/hil, 62-kha-1,
65-wat/mcl, 69-bou/lam, 69-bra/fre, 69-rod/hsu, 70-pol/mur-2, 72-jon/wee, 73-lev, 79-for/dar, 80-sid/goe,
81-kiy/ben, 82-gri/phi, 84-tan/tak, 86-hne/cib].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
180.00 846.46 0.34 293.15 744.70 0.11 400.00 645.89 3.92
190.00 838.83 0.38 298.15 739.74 0.11 410.00 638.53 4.93
200.00 830.85 0.45 300.00 737.90 0.11 420.00 631.73 6.09
210.00 822.56 0.50 310.00 727.98 0.14 430.00 611.18 6.35
220.00 813.97 0.51 320.00 718.08 0.23 440.00 577.23 6.37
230.00 805.11 0.48 330.00 708.27 0.37 450.00 545.61 6.41
240.00 796.00 0.44 340.00 698.58 0.58 460.00 524.08 6.47
250.00 786.68 0.37 350.00 689.06 0.87 470.00 513.11 6.55
260.00 777.16 0.30 360.00 679.77 1.26 480.00 506.56 6.69
270.00 767.49 0.23 370.00 670.75 1.74 490.00 492.40 6.93
280.00 757.70 0.16 380.00 662.06 2.34 500.00 452.66 7.42
290.00 747.83 0.12 390.00 653.76 3.06 510.00 349.91 8.62

cont.

Landolt-Brnstein
New Series IV/8D
28 2.1 Alkylcycloalkanes (CnH2n), C3 to C5 - 2.2 Alkylcycloalkanes (CnH2n), C6

Cyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

2.2 Alkylcycloalkanes (CnH2n), C6


2.2.1 Cyclopropanes

1-Ethyl-1-methylcyclopropane [53778-43-1] C6H12 MW = 84.16 10

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m3 K kg m3
293.15 701.8 0.20 48-ano-3 293.15 701.3 0.60 53-slo/gri-1
293.15 701.5 0.40 49-der/gre 293.15 701.7 0.20 Recommended

Landolt-Brnstein
New Series IV/8D
2.2 Alkylcycloalkanes (CnH2n), C6 29

1-Ethyl-2-methylcyclopropane [19217-47-1] C6H12 MW = 84.16 11

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 695.0 1.50 32-les/wak -0
294.15 696.1 1.50 32-les/wak -0

cis-1-Ethyl-2-methylcyclopropane [19781-68-1] C6H12 MW = 84.16 12

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 714.6 0.40 55-kel/gre

trans-1-Ethyl-2-methylcyclopropane [19781-69-2] C6H12 MW = 84.16 13

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 693.5 0.40 55-kel/gre
293.15 693.3 1.00 69-par/kho
293.15 693.5 0.40 Recommended

(1-Methylethyl)cyclopropane [3638-35-5] C6H12 MW = 84.16 14

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m3 K kg m3
293.15 688.9 4.00 48-ano-61) 293.15 698.6 0.40 54-ano-10
293.15 698.3 0.20 49-sla/wis 293.15 698.1 1.00 61-luk/zot1)
293.15 688.9 2.00 49-van/gre1) 293.15 698.1 0.80 69-par/kho
293.15 698.6 0.20 52-sla/wis-1 293.15 698.4 0.20 Recommended
1)
Not included in calculation of recommended value.

Propylcyclopropane [2415-72-7] C6H12 MW = 84.16 15

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
289.85 712.1 2.00 37-boe/tak
293.15 711.2 0.60 55-gra/gre

Landolt-Brnstein
New Series IV/8D
30 2.2 Alkylcycloalkanes (CnH2n), C6

1,1,2-Trimethylcyclopropane [4127-45-1] C6H12 MW = 84.16 16

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
3 3
K kg m K kg m
680.3 8.00 694.7 0.30
1)
293.65 01-zel/zel 293.15 48-boo/gre
293.15 694.8 0.60 12-kis 293.15 686.1 2.00 48-lev
288.45 688.8 6.00 12-ost1) 293.15 692.7 2.00 50-pet
293.15 681.0 6.00 22-cha1) 293.15 694.7 0.50 52-kel/gre
288.45 688.8 6.00 22-cha1) 293.15 686.1 0.70 52-lev/gla
293.15 696.7 2.00 41-whi/car 293.15 694.8 0.60 54-kaz/luk-1
293.15 694.1 0.60 41-whi/car 293.15 694.8 0.70 56-gra/kos
293.15 685.3 4.00 46-bar/bur1) 293.15 694.8 0.80 69-par/kho
293.15 694.7 0.30 47-boo/gre 293.15 694.2 0.30 Recommended
1)
Not included in calculation of recommended value.

1,2,3-Trimethylcyclopropane [42984-19-0] C6H12 MW = 84.16 17

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
291.15 694.6 10.00 01-zel/zel

r-1, c-2, t-3-Trimethylcyclopropane [4806-59-1] C6H12 MW = 84.16 18

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 697.9 0.60 55-kel/gre

2.2.2 Cyclobutanes

Ethylcyclobutane [4806-61-5] C 6H12 MW = 84.16 19

Table 1. Fit with estimated B coefficient for 11


accepted points. Deviation w = 0.319.
Coefficient = A + BT
A 1021.05
B -1.000

cont.

Landolt-Brnstein
New Series IV/8D
2.2 Alkylcycloalkanes (CnH2n), C6 31

Ethylcyclobutane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3
kg m3 K kg m 3
kg m3

293.15 745.0 8.00 17.10 08-zel/gut1) 293.15 727.9 0.30 -0.00 46-boo/gre
283.15 754.0 8.00 16.10 08-zel/gut1) 293.15 727.9 0.30 -0.00 46-gre-1
293.15 728.3 0.60 0.40 13-kis-3 293.15 727.9 0.20 -0.00 48-boo/gre
273.15 746.1 0.60 -1.80 13-kis-3 293.15 728.0 0.20 0.10 48-boo/gre
293.15 727.9 0.30 -0.05 39-wib/hoo 293.15 726.9 1.00 -1.00 48-tur/luk
298.15 723.2 0.30 0.30 39-wib/hoo 293.15 728.0 0.50 0.10 49-der/gre
293.15 727.9 0.30 -0.05 42-van/mee
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
270.00 751.1 4.6 290.00 731.1 0.7 298.15 722.9 1.0
280.00 741.1 2.6 293.15 727.9 0.3 300.0 721.0 1.2

trans-1,2-Dimethylcyclobutane [15679-02-4] C6H12 MW = 84.16 20

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 712.2 2.00 32-zel/tur-1
293.15 702.9 0.50 54-kaz/luk-3
293.15 703.4 0.7 Recommended

cis-1,3-Dimethylcyclobutane [2398-09-6] C6H12 MW = 84.16 21

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 710.6 0.60 49-kaz/luk

trans-1,3-Dimethylcyclobutane [2398-10-9] C6H12 MW = 84.16 22

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 701.6 0.60 49-kaz/luk

Landolt-Brnstein
New Series IV/8D
32 2.2 Alkylcycloalkanes (CnH2n), C6

2.2.3 Cyclopentanes - Cyclohexane

Methylcyclopentane [96-37-7] C6H12 MW = 84.16 23

Tc = 532.70 K [96-dau]
c = 264.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.0472 10-1 (low temperature range), c,w = (9.6285 10-2 combined temperature ranges, weighted),
O

c,uw = 4.3803 10-2 (combined temperature ranges, unweighted).


T = 273.15 to 430.00 K T = 430.00 to 532.70 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 1.20619 103 6.60080 10-1
B -2.81171 -1.26408 10-2
-3
C 6.40249 10 1.12855 10-4
-6
D -7.28464 10 -3.73278 10-7

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 767.35 0.10 -0.06 37-tim/hen( {) 313.15 729.90 0.50 0.05 47-kay1) 2)
288.15 753.41 0.10 0.10 37-tim/hen( {) 333.15 710.70 0.60 -0.02 47-kay() 2)
303.15 739.46 0.10 0.20 37-tim/hen( {) 353.15 690.76 0.70 -0.12 47-kay() 2)
276.43 764.42 0.20 0.11 44-gar() 373.15 669.85 0.80 -0.15 47-kay() 2)
276.57 764.29 0.20 0.11 44-gar() 393.15 647.61 0.90 -0.10 47-kay() 2)
284.43 756.92 0.20 0.12 44-gar() 413.15 623.66 1.10 -0.01 47-kay() 2)
285.15 756.26 0.20 0.14 44-gar() 433.15 597.47 1.30 -0.03 47-kay() 2)
291.42 750.44 0.20 0.19 44-gar1) 453.15 568.29 1.50 0.27 47-kay() 2)
291.93 749.97 0.20 0.20 44-gar1) 473.15 534.85 1.70 -0.08 47-kay() 2)
300.51 741.97 0.20 0.23 44-gar1) 493.15 494.85 2.00 -0.24 47-kay() 2)
300.76 741.73 0.20 0.23 44-gar1) 508.15 456.03 3.00 0.44 47-kay() 2)
307.43 735.45 0.20 0.21 44-gar() 293.15 748.45 0.30 -0.18 80-sid/goe1)
293.15 748.58 0.05 -0.05 46-for/gla( ) 313.15 729.42 0.30 -0.43 80-sid/goe()
298.15 743.91 0.05 -0.04 46-for/gla( )
1) Not included in Fig. 1.
2) Calculated from equation given by author.
Further references: [1897-mar-2, 1897-zel-1, 1899-mar-3, 02-zel/mos, 10-eng/hal, 11-zel, 19-cha/sim-1,
19-cha/sim-2, 22-cha, 22-cha/bec, 22-cha/van, 27-bra/hun, 27-cha/bec, 30-cha/mil, 30-god/cau, 31-hic,
32-gar/eva, 33-hof/lan, 34-god, 34-zel/kaz, 35-zel/kaz, 38-eva, 38-vog, 39-gro/wac, 39-wib/hoo, 40-
moo/ren, 41-ano-1, 42-van/mee, 43-ano, 43-gri/lud, 44-can, 45-cra/boo, 45-gre/vog, 45-zel/arb, 46-ano,
46-baz/ste, 46-gei/can, 46-kay-1, 49-den/fid, 49-foe/fen, 51-ano, 52-cla/har, 54-seu, 54-smi/otv, 59-
ehr/web, 61-bel/web, 62-kae/web, 62-sus/lyz, 68-kem/buc, 69-rod/hsu, 80-fen/khu, 87-hol/goe, 90-
com/fra].

cont.

Landolt-Brnstein
New Series IV/8D
2.2 Alkylcycloalkanes (CnH2n), C6 33

Methylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 770.39 0.20 350.00 694.07 0.67 450.00 572.88 2.27
280.00 760.96 0.15 360.00 683.87 0.77 460.00 557.16 2.33
290.00 751.58 0.14 370.00 673.37 0.86 470.00 540.46 2.41
293.15 748.63 0.15 380.00 662.54 0.92 480.00 522.35 2.51
298.15 743.95 0.17 390.00 651.33 0.98 490.00 502.09 2.66
300.00 742.22 0.18 400.00 639.69 1.06 500.00 478.52 2.91
310.00 732.82 0.24 410.00 627.58 1.19 510.00 449.73 3.37
320.00 723.36 0.34 420.00 614.97 1.41 520.00 411.68 4.45
330.00 713.77 0.45 430.00 601.80 1.77 530.00 346.57 8.47
340.00 704.02 0.56 440.00 587.79 2.22

Landolt-Brnstein
New Series IV/8D
34 2.2 Alkylcycloalkanes (CnH2n), C6

Cyclohexane [110-82-7] C6H12 MW = 84.16 24

Tc = 553.80 K [96-dau]
c = 273.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 6.4681 10-2 (low temperature range), c,w = (8.9291 10-2 combined temperature ranges, weighted),
O

c,uw = 8.9196 10-2 (combined temperature ranges, unweighted).


T = 280.15 to 445.00 K T = 445.00 to 553.80 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 9.70258 102 6.11512 10-1
-5
B -1.88689 10 -1.34197 10-2
-3
C -4.23488 10 1.32162 10-4
-6
D 9.37240 10 -4.65394 10-7
-9
E -8.64854 10

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

303.10 768.17 0.39 -1.01 1899-you/for1) 547.10 390.52 0.60 0.38 1899-you/for( )
313.10 759.07 0.38 -0.59 1899-you/for1) 550.10 364.03 0.85 -3.10 1899-you/for1)
323.10 749.57 0.38 -0.46 1899-you/for1) 552.10 339.33 0.00 -4.99 1899-you/for1)
333.10 740.03 0.38 -0.26 1899-you/for1) 273.15 796.73 0.30 -0.42 10-you-11)
343.10 730.57 0.38 0.14 1899-you/for1) 283.15 787.40 0.30 -0.50 10-you-11)
353.10 720.56 0.38 0.14 1899-you/for1) 293.15 777.90 0.30 -0.66 10-you-11)
363.10 710.58 0.39 0.32 1899-you/for( ) 303.15 768.50 0.30 -0.63 10-you-11)
373.10 700.33 0.39 0.41 1899-you/for( ) 310.15 759.10 0.30 -3.38 10-you-11)
383.10 689.51 0.39 0.11 1899-you/for( ) 323.15 749.60 0.30 -0.38 10-you-11)
393.10 678.70 0.40 0.05 1899-you/for( ) 333.15 740.00 0.30 -0.24 10-you-11)
403.10 668.00 0.40 0.33 1899-you/for( ) 343.15 730.60 0.30 0.22 10-you-11)
413.10 656.51 0.40 0.09 1899-you/for( ) 353.15 720.60 0.32 0.23 10-you-11)
423.10 644.87 0.40 -0.00 1899-you/for( ) 363.15 710.60 0.32 0.39 10-you-1( )
433.10 632.47 0.42 -0.53 1899-you/for( ) 288.15 783.13 0.20 -0.11 36-mas1)
443.10 619.92 0.42 -0.85 1899-you/for1) 306.30 766.14 0.20 -0.01 36-mas1)
453.10 606.76 0.42 -0.94 1899-you/for( ) 318.50 754.52 0.20 0.05 36-mas1)
463.10 591.37 0.44 -1.90 1899-you/for( ) 337.20 736.59 0.20 0.33 36-mas1)
473.10 578.03 0.44 0.09 1899-you/for( ) 352.35 721.58 0.20 0.40 36-mas( )
483.10 561.64 0.44 -0.27 1899-you/for( ) 372.35 700.78 0.20 0.07 36-mas( )
493.10 546.45 0.45 1.42 1899-you/for( ) 298.15 773.84 0.03 -0.02 67-cru/cut( )
503.10 527.15 0.45 0.29 1899-you/for( ) 301.15 771.10 0.20 0.07 67-pre/fel1)
513.10 506.33 0.46 -0.24 1899-you/for( ) 313.15 759.44 0.20 -0.17 67-pre/fel1)
523.10 482.04 0.47 -0.77 1899-you/for( ) 323.15 749.70 0.20 -0.28 67-pre/fel1)
533.10 452.84 0.48 -0.45 1899-you/for( ) 333.15 740.23 0.20 -0.01 67-pre/fel1)
538.10 435.92 0.49 0.91 1899-you/for( ) 333.15 740.23 0.20 -0.01 67-pre/fel1)
543.10 412.54 0.50 -0.27 1899-you/for( ) 343.15 730.18 0.20 -0.20 67-pre/fel()
1) Not included in Fig. 1.
cont.
Landolt-Brnstein
New Series IV/8D
2.2 Alkylcycloalkanes (CnH2n), C6 35

Cyclohexane (cont.)

Table 2. (Cont.)
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

298.15 773.92 0.10 0.06 81-aic/tar1) 280.15 790.65 0.05 -0.03 92-ano-3()
308.15 764.43 0.10 0.04 81-aic/tar1) 280.16 790.65 0.05 -0.02 92-ano-3()
318.15 754.71 0.10 -0.10 81-aic/tar1) 283.15 787.88 0.05 -0.02 92-ano-3()
333.15 740.11 0.10 -0.13 81-aic/tar() 283.15 787.87 0.05 -0.03 92-ano-3()
283.15 787.90 0.30 0.00 81-dym/you1) 288.15 783.22 0.05 -0.02 92-ano-31)
288.15 783.20 0.30 -0.04 81-dym/you1) 288.16 783.22 0.05 -0.01 92-ano-31)
298.19 773.80 0.30 -0.02 81-dym/you1) 293.15 778.55 0.05 -0.01 92-ano-31)
313.23 759.50 0.40 -0.03 81-dym/you1) 298.11 773.89 0.05 -0.01 92-ano-31)
333.36 739.90 0.50 -0.14 81-dym/you1) 303.14 769.13 0.05 -0.01 92-ano-31)
353.29 719.70 0.50 -0.53 81-dym/you1) 308.15 764.36 0.05 -0.03 92-ano-31)
373.28 699.30 0.50 -0.44 81-dym/you1) 313.13 759.60 0.05 -0.03 92-ano-31)
393.20 678.30 0.60 -0.24 81-dym/you( ) 318.07 754.84 0.05 -0.05 92-ano-3()
308.15 763.51 0.21 -0.88 81-mal/rae1) 323.15 749.91 0.05 -0.07 92-ano-3()
308.22 763.51 0.21 -0.81 81-mal/rae1) 323.15 749.92 0.05 -0.06 92-ano-3()
318.15 753.80 0.20 -1.01 81-mal/rae1) 298.15 773.90 0.30 0.04 93-beg/tuk1)
328.27 744.20 0.21 -0.81 81-mal/rae1) 303.15 769.10 0.30 -0.03 93-beg/tuk1)
348.31 725.84 0.21 0.61 81-mal/rae( ) 313.15 759.50 0.30 -0.11 93-beg/tuk1)
293.15 778.58 0.03 0.02 87-mar-1( ){ 333.15 740.40 0.30 0.16 93-beg/tuk1)
298.15 773.90 0.03 0.04 87-mar-1( ){ 353.15 720.10 0.30 -0.27 93-beg/tuk1)
303.15 769.17 0.03 0.04 87-mar-1( ){ 373.15 699.20 0.40 -0.67 93-beg/tuk( )
308.15 764.41 0.03 0.02 87-mar-1( ){ 393.15 677.80 0.50 -0.80 93-beg/tuk( )
313.15 759.62 0.03 0.01 87-mar-1( ){ 433.15 631.40 0.65 -1.54 93-beg/tuk1)
318.15 754.80 0.04 -0.01 87-mar-1( ){ 453.15 605.50 0.80 -2.13 93-beg/tuk( )
323.15 749.96 0.04 -0.02 87-mar-1( ){ 473.15 576.80 1.00 -1.06 93-beg/tuk( )
1) Not included in Fig. 1.
Further references: [1825-far, 1894-bru-2, 1897-zel-1, 1898-for, 1898-mar, 00-you/for-1, 01-sab/sen,
01-zel-1, 03-sab/mai, 11-dra, 11-ski/rit, 15-von/hin, 16-ric/shi, 19-cha/sim-2, 19-ric/shi, 22-cha/van, 25-
eis/gor, 26-des, 26-mat, 26-pav, 26-tim/mar-1, 27-bou, 27-bra/hun, 28-ada/mar, 29-smy/sto, 29-str-1, 30-
god/cau, 30-tau/sta, 31-bru/hic-1, 31-kag, 32-gar/eva, 32-vor/fis, 32-zel/tur-1, 33-azi/bha, 34-car/jon, 34-
god, 34-rot/nag, 34-was/spe, 35-ear/gla, 35-wel, 36-bro/dur, 36-roz, 37-loz/dya, 38-eva, 38-pau/nik, 38-
vog, 39-phi-1, 39-wat/lee-2, 39-wib/hoo, 40-ano, 40-moo/ren, 42-gei, 43-ano, 44-can, 44-fri/har-1, 44-gar,
44-huc, 45-gre/vog, 46-boo/gre, 46-for/gla, 46-gei/can, 46-vog, 47-huc/har, 47-spi/huf, 49-ano-4, 49-
den/fid, 49-foe/fen, 49-wei, 50-bro/ewa, 51-ano, 51-shu/min, 53-par/cha, 54-dix/sch, 54-smi/otv, 54-
wec/hun, 55-cut/jon, 55-ham/sto, 55-kus, 56-moo/sty, 57-hol, 58-rea/sag, 59-wu /how, 61-del, 61-gom/liu,
61-shi/hil, 62-nag-2, 62-rat/rao, 62-sus/lyz, 63-jef, 63-plu/dow, 63-pod, 64-moe/tho, 64-sca/sat, 65-
for/moo, 65-wat/mcl, 66-bat, 66-bat/all, 66-ber/rea, 66-kat/cha, 66-lut/kov, 66-sab/bel, 67-fin/ken, 67-
loi/mer, 67-mur/sri, 67-nat/rao, 67-rid/but, 68-bar/sat, 68-kem/buc, 68-pow/swi, 68-ver, 69-bru/gub, 69-
cho/nai, 69-rod/hsu, 69-smi/kur, 70-fin, 70-kon/lya, 70-sto/lev, 70-str/svo, 71-len/hay, 71-nag/oht, 71-
san/fel, 72-jon/wee, 72-kon, 72-let, 72-let-1, 72-mar/mur, 73-che/cha, 73-lev, 73-li /lu , 73-nag/oht, 73-
min/rue, 73-paz, 73-paz-1, 73-paz-2, 73-paz-3, 73-san/hut, 73-svo/ves, 74-jai/nor, 74-kon/ani, 74-mye/cle,
74-pur/pol, 75-hsu/cle, 76-for/ben, 76-ha /mor, 76-tri/kri, 77-bou/lu, 77-hwa/rob, 77-rad/tas, 78-kiy/hal,
78-nat/yad, 79-for/dar, 79-goa/ott, 79-hoe/hoe, 79-mah/sur, 79-maj/svo, 79-mal/pat, 79-mur, 80-aic/tar,
80-aic/tar-1, 80-fen/khu, 80-jon/has, 80-mar/sym, 80-mar/you, 80-oht/nag]

cont.

Landolt-Brnstein
New Series IV/8D
36 2.2 Alkylcycloalkanes (CnH2n), C6

Cyclohexane (cont.)

Further references: (cont.)


[80-sid/goe, 80-sur, 81-aic/tar-2, 81-kiy/ben, 81-nai/nai, 81-mal/rae, 81-tas/djo, 82-ami/pat, 82-bha/tre,
82-bha/tre-1, 82-bha/tre-2, 82-bha/tre-3, 82-bha/tre-4, 82-chy/str, 82-dig/jad, 82-gri/goa, 82-gri/phi, 82-
gro/ing, 83-nat/tri, 83-wec, 83-wec/byl, 84-bau/mee, 84-cre/com, 84-gar/rey, 84-sin/nig, 85-hra/gik, 85-
mar/bha, 85-osw/rao, 85-sae/com, 85-sin/mah, 85-sin/sha, 85-tam/mur, 85-tan/nak, 86-aww/sal, 86-
hol/got-8, 86-sae/com, 86-san/sha, 86-tar/dia, 86-tar/dia-1, 87-ami, 87-lin, 87-luo/ham, 87-man/ami, 87-
nag/rob, 87-yad/yad, 88-cha/sur, 88-gar/cob-1, 88-jun/tar, 88-nag-1, 88-nag-2, 88-man/ami, 88-sai/tan,
88-sun/sch-1, 89-bec/ric, 89-der/poi, 89-lai/rod, 89-mat/gon, 89-rai/shu, 89-ram/sur, 90-all/bee, 90-
che/pet, 90-jos/ami, 90-jos/ami-2, 90-sin/mal, 91-kna/skj, 91-kri/vis, 91-pap/eva, 91-pap/zio, 91-ric/lau,
91-she/wan, 91-tre-9, 91-tre, 91-tre-1, 92-acr/ten-4, 92-acr/ten-8, 92-pit/mar, 92-qin/hof, 92-qin/hof-2, 92-
wei/wil, 92-yos/kat, 94-del/fer, 94-kri/vis, 94-toj/ram, 95-art/mun-3, 95-gaw/dor, 95-org/igl, 95-osw/pat,
95-pet/gas].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.2 Alkylcycloalkanes (CnH2n), C6 - 2.3 Alkylcycloalkanes (CnH2n), C7 37

Cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 790.82 0.06 360.00 713.43 0.27 460.00 597.85 0.88
290.00 781.51 0.05 370.00 703.15 0.30 470.00 582.77 0.88
293.15 778.56 0.05 380.00 692.68 0.34 480.00 566.95 0.86
298.15 773.86 0.05 390.00 682.01 0.37 490.00 550.37 0.84
300.00 772.11 0.05 400.00 671.10 0.41 500.00 532.67 0.82
310.00 762.62 0.08 410.00 659.93 0.45 510.00 513.15 0.80
320.00 753.03 0.12 420.00 648.48 0.49 520.00 490.66 0.80
330.00 743.32 0.16 430.00 636.72 0.55 530.00 463.27 0.82
340.00 733.50 0.19 440.00 624.60 0.64 540.00 427.15 0.88
350.00 723.54 0.23 450.00 611.92 0.85 550.00 368.05 1.15

2.3 Alkylcycloalkanes (CnH2n), C7


2.3.1 Cyclopropanes

Butylcyclopropane [930-57-4] C7H14 MW = 98.19 25

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 728.5 0.40 55-gra/gre
293.15 728.3 0.40 55-gra/gre
293.15 728.4 0.4 Recommended

1,1-Diethylcyclopropane [1003-19-6] C7H14 MW = 98.19 26

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m 3
K kg m3
293.15 713.8 0.50 44-boo 293.15 713.7 0.40 45-gre/waa
293.15 713.5+ 0.40 44-boo/per 293.15 713.8 0.50 48-sho/cra
293.15 713.7+ 0.50 45-boo/gre 293.15 713.7 0.4 Recommended

Landolt-Brnstein
New Series IV/8D
38 2.3 Alkylcycloalkanes (CnH2n), C7

1-Ethyl-2,2-dimethylcyclopropane [41845-47-0] C7H14 MW = 98.19 27

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 710.5 0.40 60-kac/tog

cis-1-Ethyl-2,3-dimethylcyclopropane [500004-95-5] C7H14 MW = 98.19 28

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 746.0 2.00 55-kel/gre

trans-1-Ethyl-2,3-dimethylcyclopropane [500004-94-4] C7H14 MW = 98.19 29

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 722.2 2.00 55-kel/gre

1-Methyl-1-(1-methylethyl)cyclopropane [13150-79-3] C7H14 MW = 98.19 30

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 722.7 0.50 46-ano-2
293.15 721.5 1.00 53-slo/gri-1
293.15 722.5 0.7 Recommended

1-Methyl-2-(1-methylethyl)cyclopropane [78757-65-0] C7H14 MW = 98.19 31

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 710.2 2.00 13-kis-3
293.15 710.2 2.00 13-kis-4
293.15 710.1 2.00 13-kis/amo

(1-Methylpropyl)cyclopropane [5750-02-7] C7H14 MW = 98.19 32

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 728.3 0.30 52-sla/wis-1

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 39

1-Methyl-2-propylcyclopropane [19217-48-2] C7H14 MW = 98.19 33

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
291.15 720.6 2.00 32-les/wak

cis-1-Methyl-2-propylcyclopropane [500004-93-3] C7H14 MW = 98.19 34

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 729.5 2.00 55-kel/gre

trans-1-Methyl-2-propylcyclopropane [500004-92-2] C7H14 MW = 98.19 35

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 715.3 0.40 55-kel/gre

1,1,2,2-Tetramethylcyclopropane [4127-47-3] C7H14 MW = 98.19 36

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m3 K kg m3
293.15 717.0 0.40 48-ano-4 293.15 718.6 0.40 51-ano-3
293.15 718.8 0.70 49-lev/gla 293.15 718.6 2.00 55-kel/gre
293.15 718.4 0.30 50-boo/gre 293.15 718.3 0.3 Recommended
293.15 718.4 0.40 50-boo/gre

2.3.2 Cyclobutanes

cis-1-Ethyl-3-methylcyclobutane [500025-74-1] C7H14 MW = 98.19 37

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 731.6 0.70 52-kaz/luk

trans-1-Ethyl-3-methylcyclobutane [500025-75-2] C7H14 MW = 98.19 38

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 722.4 0.70 52-kaz/luk

Landolt-Brnstein
New Series IV/8D
40 2.3 Alkylcycloalkanes (CnH2n), C7

(1-Methylethyl)cyclobutane [872-56-0] C7H14 MW = 98.19 39

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w= 0.969.
Coefficient = A + BT
A 1016.46
B -0.950

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

287.65 746.4 1.50 3.21 36-kaz


293.15 737.6 0.50 -0.37 49-der/gre
293.15 738.0 1.00 0.03 55-kaz/luk

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 750.5 1.5
290.00 741.0 1.0
293.15 738.0 1.0
298.15 733.2 1.2

Propylcyclobutane [4806-62-6] C7H14 MW = 98.19 40

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 744.0 1.50 27-zel/kaz

2.3.3 Cyclopentanes

Ethylcyclopentane [1640-89-7] C 7H14 MW = 98.19 41


Tc = 569.50 K [96-dau]
c = 262.00 kgm-3 [96-dau]
Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.5305 10-1 (low temperature range), c,w = (1.3858 10-1 combined temperature ranges, weighted),
O

c,uw = 5.8338 10-2 (combined temperature ranges, unweighted).


T = 275.28 to 440.00 K T = 440.00 to 569.50 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 9.40285 102 3.14583 10-1
-1
B -3.16123 10 -3.84557 10-3
-4
C -9.43225 10 2.88798 10-5
D -8.76556 10-8
cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 41

Ethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 766.60 0.20 0.04 43-ano() 333.15 729.65 0.60 -0.63 47-kay( ) 2)
273.15 782.70 0.40 -0.86 44-can1) 353.15 710.59 0.70 -0.42 47-kay( ) 2)
293.15 766.30 0.40 -0.26 44-can1) 373.15 690.97 0.80 -0.02 47-kay( ) 2)
313.15 748.60 0.40 -0.20 44-can() 393.15 670.58 0.90 0.37 47-kay( ) 2)
275.28 781.90 0.20 0.11 44-gar( ){ 413.15 649.19 1.00 0.51 47-kay( ) 2)
275.62 781.61 0.20 0.11 44-gar( ){ 433.15 626.51 1.40 0.12 47-kay( ) 2)
284.95 773.55 0.20 -0.07 44-gar( ){ 453.15 602.16 2.00 -0.53 47-kay( ) 2)
285.15 773.39 0.20 -0.06 44-gar( ){ 473.15 575.62 2.40 -0.21 47-kay( ) 2)
292.68 766.99 0.20 0.03 44-gar( ){ 493.15 546.10 3.00 0.18 47-kay( ) 2)
293.03 766.59 0.20 -0.07 44-gar( ){ 513.15 512.26 4.00 0.29 47-kay( ) 2)
302.73 758.33 0.20 0.19 44-gar( ){ 533.15 471.16 5.00 0.12 47-kay( ) 2)
303.15 757.97 0.20 0.20 44-gar( ){ 553.15 413.83 6.00 -0.80 47-kay( ) 2)
310.05 752.00 0.20 0.40 44-gar( ){ 568.15 316.05 0.00 -8.07 47-kay1) 2)
293.15 766.56 0.20 0.00 46-ano() 293.15 766.45 0.10 -0.11
49-for/ros( )
293.15 766.66 0.30 0.10 47-kay1) 2) 298.15 762.15 0.10 -0.04
49-for/ros( )
313.15 748.30 0.50 -0.50 47-kay( ) 2) 303.15 757.78 0.10 0.01
49-for/ros( )
1) Not included in Fig. 1.
2)
Calculated from equation given by author.
Further references: [05-zel-1, 25-eis/gor, 27-cha/bec, 32-gar/eva, 34-zel/kaz, 35-zel/kaz, 38-eva, 39-
gro/wac, 39-pin/ipa, 39-pin/ipa-1, 39-tur/mak, 40-moo/ren, 45-boo/gre, 45-cra/boo, 45-gre, 46-baz/ste,
46-boo/gre, 46-gei/can, 46-kay-1, 47-gla/wil, 49-boo/hen, 49-den/fid, 49-foe/fen, 50-pla/sha, 51-zel, 62-
ano-3].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 786.17 0.16 360.00 704.24 0.67 470.00 580.25 2.76
280.00 777.82 0.16 370.00 694.19 0.75 480.00 565.95 2.99
290.00 769.28 0.19 380.00 683.96 0.83 490.00 550.85 3.23
293.15 766.56 0.21 390.00 673.53 0.92 500.00 534.84 3.51
298.15 762.19 0.24 400.00 662.92 1.01 510.00 517.67 3.81
300.00 760.56 0.25 410.00 652.12 1.11 520.00 498.97 4.19
310.00 751.64 0.31 420.00 641.13 1.22 530.00 478.17 4.67
320.00 742.54 0.38 430.00 629.95 1.33 540.00 454.27 5.34
330.00 733.25 0.45 440.00 618.58 1.45 550.00 425.38 6.41
340.00 723.77 0.52 450.00 606.64 2.37 560.00 386.32 8.40
350.00 714.10 0.59 460.00 593.83 2.56

cont.

Landolt-Brnstein
New Series IV/8D
42 2.3 Alkylcycloalkanes (CnH2n), C7

Ethylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,1-Dimethylcyclopentane [1638-26-2] C7H14 MW = 98.19 42

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.3502 (combined temperature ranges,
weighted), c,uw = 3.7710 10-1 (combined
temperature ranges, unweighted).
T = 288.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01086 103
B -8.75856 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 43

1,1-Dimethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 754.60 0.60 0.50 08-kis-3( ) 293.15 754.80 0.60 0.70 49-baz/ukh( )
288.15 759.00 1.00 0.52 31-cha/mil( ) 293.15 754.40 0.30 0.30 49-den/fid( ){
293.15 755.10 1.00 1.00 31-cha/mil1) 293.15 754.46 0.10 0.36 49-for/ros( )
293.15 750.00 0.50 -4.10 33-bru/hic( ) 298.15 749.89 0.10 0.17 49-for/ros( )
293.15 754.50 0.40 0.40 43-ano() 303.15 745.30 0.10 -0.04 49-for/ros( )
293.15 754.60 0.60 0.50 46-ano( ) 293.15 754.30 0.30 0.20 50-boo/gre()
293.15 752.30 2.00 -1.80 49-baz/ukh1) 293.15 754.60 0.50 0.50 51-tur/ada()
1) Not included in Fig. 1.
Further references: [05-kis-2, 13-kis, 13-kis-3].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
44 2.3 Alkylcycloalkanes (CnH2n), C7

1,1-Dimethylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 765.62 2.54 293.15 754.10 0.15 300.00 748.10 0.15
290.00 756.86 0.35 298.15 749.72 0.13 310.00 739.34 0.51

1,2-Dimethylcyclopentane [2452-99-5] C7H14 MW = 98.19 43

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 762.8 8.00 08-kis-3
291.65 758.1 8.00 08-kis-3
293.15 764.0 6.00 28-cha/dev

cis-1,2-Dimethylcyclopentane [1192-18-3] C7H14 MW = 98.19 44

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.1498 10-1 (combined temperature ranges,
weighted), c,uw = 5.0190 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03467 103
B -8.94116 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

288.15 776.40 1.00 -0.63 30-cha( ) 303.15 763.72 0.40 0.10 44-chi()
293.15 771.80 1.00 -0.76 30-cha1) 293.15 772.70 0.40 0.14 45-ano-8()
293.15 772.64 0.40 0.08 35-chi( ) 293.15 772.60 0.70 0.04 49-den/fid( )
288.15 777.10 0.40 0.07 38-chi-1( ) 293.15 772.60 0.10 0.04 49-for/ros( )
293.15 772.70 0.40 0.14 38-chi-1( ) 298.15 768.05 0.10 -0.04 49-for/ros( )
293.15 772.30 0.40 -0.26 43-ano() 303.15 763.62 0.10 0.00 49-for/ros( )
273.15 790.36 0.40 -0.08 44-chi() 293.15 772.80 0.40 0.24 57-ano-4( )
288.15 777.07 0.40 0.04 44-chi() 293.15 772.60 0.40 0.04 63-lib/bra( ){
293.15 772.64 0.40 0.08 44-chi()
1) Not included in Fig. 1.
Further references: [41-tur/vse].

cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 45

cis-1,2-Dimethylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 793.26 0.18 293.15 772.56 0.45 300.00 766.44 0.20
280.00 784.32 0.81 298.15 768.09 0.18 310.00 757.49 0.83
290.00 775.38 0.53

trans-1,2-Dimethylcyclopentane [822-50-4] C7H14 MW = 98.19 45

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.7752 10-1 (combined temperature ranges,
weighted), c,uw = 6.7360 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01239 103
B -8.90688 10-1

cont.

Landolt-Brnstein
New Series IV/8D
46 2.3 Alkylcycloalkanes (CnH2n), C7

trans-1,2-Dimethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 751.35 0.40 0.07 35-chi( ) 303.15 742.40 0.40 0.02 44-chi()
288.15 755.81 0.40 0.07 38-chi-1( ){ 293.15 751.30 0.40 0.02 45-ano-8( )
293.15 751.35 0.40 0.07 38-chi-1( ){ 293.15 751.42 0.10 0.14 49-for/ros( )
293.15 750.60 0.80 -0.68 40-gla1) 298.15 746.84 0.10 0.01 49-for/ros( )
298.15 746.00 0.80 -0.83 40-gla( ) 303.15 742.39 0.10 0.01 49-for/ros( )
293.15 750.70 0.60 -0.58 43-ano( ) 293.15 751.50 0.60 0.22 54-pin/hof( )
273.15 769.18 0.40 0.08 44-chi() 293.15 751.50 0.50 0.22 54-pin/hof1( )
288.15 755.81 0.40 0.07 44-chi() 293.15 751.50 0.40 0.22 57-ano-4()
293.15 751.35 0.40 0.07 44-chi() 293.15 751.40 0.40 0.12 63-lib/bra()
1) Not included in Fig. 1.
Further references: [30-cha].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 47

trans-1,2-Dimethylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 771.90 0.58 293.15 751.28 0.15 300.00 745.18 0.15
280.00 762.99 0.32 298.15 746.83 0.15 310.00 736.27 0.25
290.00 754.09 0.28

1,3-Dimethylcyclopentane [2453-00-1] C7H14 MW = 98.19 46

Table 1. Experimental values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m
3
K kg m3
293.15 754.1 4.00 1897-zel-1 293.15 746.0 2.00 49-boo/hen
291.15 749.7 4.00 02-zel-1 293.15 746.4 2.00 50-boo/gre
297.15 741.0 4.00 02-zel-1 293.15 745.4 4.00 50-kop/noz
293.15 756.1 8.00 05-kis-1 293.15 747.0 4.00 55-ano-8
293.15 746.0 2.00 46-baz/ste

cis-1,3-Dimethylcyclopentane [2532-58-3] C7H14 MW = 98.19 47

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.5170 10-1 (combined temperature ranges,
weighted), c,uw = 1.0596 10-1 (combined
temperature ranges, unweighted).
T = 288.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02400 103
B -9.51237 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

288.15 749.80 1.00 -0.10 26-cha( ) 298.15 740.23 0.10 -0.16


49-for/ros( )
292.85 745.60 1.00 0.17 26-cha( ) 303.15 735.71 0.10 0.08
49-for/ros( )
288.15 749.80 0.50 -0.10 30-cha/mil() 293.15 744.50 0.40 -0.64 {
51-ano( )
288.15 750.40 1.50 0.50 38-eva( ) 293.15 744.90 0.40 -0.24 51-ano-3()
293.15 746.30 1.50 1.16 38-eva1) 293.15 745.00 0.60 -0.14 53-bir/dea( )
293.15 745.70 0.70 0.56 48-boo/gre( ) 293.15 745.60 0.60 0.46 54-bir/dea()
293.15 744.77 0.10 -0.37
49-for/ros( )
1) Not included in Fig. 1.
Further references: [40-gla].

cont.

Landolt-Brnstein
New Series IV/8D
48 2.3 Alkylcycloalkanes (CnH2n), C7

cis-1,3-Dimethylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 757.65 0.50 293.15 745.14 0.35 300.00 738.62 0.20
290.00 748.14 0.65 298.15 740.39 0.20 310.00 729.12 0.35

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 49

trans-1,3-Dimethylcyclopentane [1759-58-6] C7H14 MW = 98.19 48

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.3319 10-1 (combined temperature ranges,
weighted), c,uw = 9.7052 10-2 (combined
temperature ranges, unweighted).
T = 293.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.00288 103
B -8.67855 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 748.80 0.40 0.34 48-ano-3( ) { 303.15 739.83 0.10 0.04 49-for/ros( )
293.15 748.70 0.70 0.24 48-boo/gre() 293.15 748.10 1.00 -0.36 53-bir/dea()
293.15 748.00 1.50 -0.46 48-boo/gre() 293.15 748.50 1.00 0.04 53-bir/dea()
293.15 748.78 0.10 0.32 49-for/ros( ) 298.15 743.70 1.00 -0.42 53-bir/dea()
298.15 744.33 0.10 0.21 49-for/ros( ) 298.15 744.20 1.00 0.08 53-bir/dea()
Further references: [32-gar/eva, 49-den/fid].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
50 2.3 Alkylcycloalkanes (CnH2n), C7

trans-1,3-Dimethylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 751.20 0.57 298.15 744.13 0.20 310.00 733.84 0.35
293.15 748.46 0.30 300.00 742.52 0.20

2.3.4 Cyclohexanes and Cycloheptane

Methylcyclohexane [108-87-2] C7H14 MW = 98.19 49

Tc = 572.10 K [96-dau]
c = 266.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 2.3973 10-1 (low temperature range), c,w = (1.8409 10-1 combined temperature ranges, weighted),
O

c,uw = 1.3197 10-1 (combined temperature ranges, unweighted).


T = 178.05 to 460.00 K T = 460.00 to 572.10 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 9.66739 102 7.40338 10-1
-5
B -2.48282 10 -1.51277 10-2
-3
C -4.97048 10 1.34708 10-4
-5
D 1.26438 10 -4.29882 10-7
-8
E -1.20215 10

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 786.38 0.20 -0.26 22-tim/van( ) 372.65 698.23 0.30 -0.74 36-mas( )
273.15 786.40 0.20 -0.24 23-tim/van() 293.15 770.00 0.50 0.67 39-gro/wac1)
178.05 868.91 0.30 0.46 36-mas( ) 353.15 717.00 0.40 0.27 39-gro/wac( )
209.65 841.42 0.30 -0.13 36-mas( ) 285.60 775.30 0.30 -0.57 44-fri/har-11)
227.95 825.59 0.30 -0.17 36-mas( ) 323.45 742.50 0.30 -0.50 44-fri/har-1( )
250.25 806.36 0.30 -0.10 36-mas( ) 339.95 728.30 0.30 -0.19 44-fri/har-1( )
273.15 786.48 0.20 -0.16 36-mas( ) 357.15 713.10 0.30 -0.03 44-fri/har-1( )
288.15 773.38 0.20 -0.28 36-mas1) 370.65 701.30 0.30 0.48 44-fri/har-1( )
303.10 760.44 0.20 -0.27 36-mas1) 274.71 785.31 0.20 0.02 44-gar()
318.35 747.00 0.20 -0.45 36-mas( ) 275.28 784.80 0.20 0.00 44-gar()
333.85 733.58 0.30 -0.30 36-mas( ) 284.60 776.77 0.20 0.04 44-gar()
353.10 716.58 0.30 -0.19 36-mas( ) 291.66 770.66 0.20 0.04 44-gar1)
1) Not included in Fig. 1.
2) Calculated from equation given by author.
cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 51

Methylcyclohexane (cont.)

Table 2. (cont.)
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

770.12 0.20 576.80 1.00


1)
292.31 0.06 44-gar 483.15 0.55 57-fra( )
293.15 769.32 0.20 -0.01 44-gar1) 493.15 561.80 1.00 0.12 57-fra( )
293.15 769.33 0.20 -0.00 44-gar1) 503.15 546.80 1.00 0.30 57-fra( )
302.09 761.69 0.20 0.10 44-gar1) 513.15 530.00 1.00 -0.37 57-fra( )
309.59 755.19 0.20 0.11 44-gar() 523.15 511.30 1.00 -1.35 57-fra( )
293.15 769.34 0.05 0.01
46-for/gla( ) 533.15 490.60 1.00 -1.76 57-fra( )
298.15 764.99 0.05 -0.01
46-for/gla( ) 543.15 469.00 1.00 0.97 57-fra( )
293.15 769.40 0.30 0.07 47-kay1) 2) 553.15 437.50 1.00 0.39 57-fra( )
313.15 752.31 0.40 0.33 47-kay1) 2) 558.15 422.50 1.00 4.85 57-fra1)
333.15 735.01 0.40 0.52 47-kay( ) 2) 563.15 406.20 1.00 12.67 57-fra1)
353.15 717.33 0.45 0.60 47-kay( ) 2) 298.15 764.59 0.38 -0.41 76-chr/lau1)
373.15 699.09 0.50 0.58 47-kay( ) 2) 298.15 764.50 0.25 -0.50 76-chr/lau1)
393.15 680.12 0.55 0.53 47-kay( ) 2) 303.15 760.29 0.40 -0.38 76-chr/lau1)
413.15 660.17 0.60 0.46 47-kay( ) 2) 308.15 756.02 0.41 -0.31 76-chr/lau1)
433.15 638.96 0.65 0.43 47-kay( ) 2) 313.15 751.67 0.42 -0.31 76-chr/lau1)
453.15 616.10 0.70 0.41 47-kay( ) 2) 318.15 747.39 0.43 -0.24 76-chr/lau1)
473.15 591.11 0.80 0.86 47-kay( ) 2) 323.15 742.97 0.44 -0.29 76-chr/lau1)
493.15 563.20 0.90 1.52 47-kay( ) 2) 328.15 738.60 0.45 -0.28 76-chr/lau( )
513.15 531.10 1.10 0.73 47-kay( ) 2) 333.15 734.27 0.46 -0.22 76-chr/lau( )
533.15 492.11 2.60 -0.25 47-kay( ) 2) 338.15 730.07 0.47 -0.01 76-chr/lau( )
553.15 436.56 0.40 -0.55 47-kay( ) 2) 343.15 725.62 0.48 -0.04 76-chr/lau( )
553.15 438.56 2.50 1.45 47-kay1) 2) 348.15 721.21 0.50 0.00 76-chr/lau( )
568.15 353.30 3.00 -6.33 47-kay1) 2) 353.15 716.76 0.51 0.03 76-chr/lau1)
353.15 716.20 0.50 -0.53 57-fra1) 203.00 846.80 0.34 -0.46 79-jon/has( )
363.15 707.60 0.50 -0.09 57-fra( ) 223.00 830.00 0.35 -0.04 79-jon/has( )
373.15 698.40 0.60 -0.11 57-fra( ) 253.00 804.10 0.35 0.02 79-jon/has( )
383.15 689.50 1.00 0.35 57-fra( ) 203.00 846.80 0.34 -0.46 79-jon/has( )
393.15 679.80 1.00 0.21 57-fra( ) 223.00 830.00 0.35 -0.04 79-jon/has( )
403.15 670.30 1.00 0.51 57-fra( ) 253.00 804.10 0.35 0.02 79-jon/has( )
413.15 659.80 1.00 0.09 57-fra( ) 298.00 765.00 0.36 -0.13 79-jon/has1)
423.15 649.30 1.00 -0.00 57-fra( ) 298.15 765.14 0.10 0.14 79-mur-1()
433.15 638.60 1.00 0.07 57-fra( ) 293.15 769.44 0.05 0.11 85-tam/mur( ){
443.15 626.30 1.00 -1.04 57-fra( ) 298.15 765.14 0.10 0.14 79-mur-1()
453.15 615.10 1.00 -0.59 57-fra( ) 293.15 769.44 0.05 0.11 85-tam/mur( ){
463.15 603.40 1.00 -0.08 57-fra( ) 298.15 764.97 0.05 -0.03 85-tam/mur( ){
473.15 590.90 1.00 0.65 57-fra( ) 303.15 760.65 0.05 -0.02 85-tam/mur( ){
1) Not included in Fig. 1.
2) Calculated from equation given by author.

cont.

Landolt-Brnstein
New Series IV/8D
52 2.3 Alkylcycloalkanes (CnH2n), C7

Methylcyclohexane (cont.)

Further references: [1892-ber, 1897-kno-1, 1897-zel, 1899-kur-1, 01-sab/sen, 03-mar-2, 05-sab/sen-1,


06-eyk-1, 08-kis-3, 11-kis-4, 13-von/eis, 19-cha/sim-1, 19-cha/sim-2, 19-eyk, 22-cha/van, 26-des, 26-mat,
26-tim/mar, 26-tim/mar-1, 26-wei/hen, 27-bra/hun, 28-ada/mar, 30-god/cau, 30-tau/sta, 32-gar/eva, 32-
hic/bru, 32-ton/fen, 33-bro/qui, 33-sig/cra, 34-god, 35-mam, 36-bro/dur, 37-loz/dya, 38-eva, 38-vog, 38-
wil/lan, 39-cow/jef, 39-tur/mak, 39-wib/hoo, 40-ano, 40-moo/ren, 42-gei, 43-ano, 44-huc, 45-fid, 45-
gre/vog, 46-baz/ste, 46-gei/can, 49-den/fid, 49-gel/mar, 54-chi/maq, 55-bal/tur, 55-gar/hal, 55-roc/sie, 55-
roe/sie, 55-web, 56-ano-5, 59-yen/ree, 61-shi/hil, 61-shu/tul, 63-raj/ran, 66-rob/edm, 69-bra/fre, 69-
rod/hsu, 72-let-1, 73-chi/hou, 73-nag/oht, 74-mye/cle, 74-rao/nai, 74-rao/nai-1, 75-hol/zie, 75-hsu/cle, 75-
mus/ver, 79-maj/svo, 80-dia/cre, 80-fen/khu, 80-sid/goe, 80-sur, 82-gri/phi, 83-gri/phi, 84-tan/tak, 86-
hol/got, 86-tar/dia-1, 88-cha/sur, 88-gar/cob-1, 89-ram/sur, 90-che/pet, 91-aiz/kat, 91-ric/lau, 92-yos/kat,
94-del/fer, 95-pet/gas].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 53

Methylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
170.00 875.17 0.64 300.00 763.40 0.22 440.00 630.92 0.94
180.00 866.81 0.53 310.00 754.72 0.25 450.00 619.42 1.00
190.00 858.36 0.44 320.00 746.01 0.29 460.00 607.41 1.07
200.00 849.83 0.36 330.00 737.26 0.33 470.00 594.52 1.41
210.00 841.25 0.30 340.00 728.45 0.38 480.00 580.72 1.52
220.00 832.63 0.25 350.00 719.55 0.43 490.00 566.33 1.56
230.00 823.99 0.21 360.00 710.55 0.49 500.00 551.37 1.53
240.00 815.34 0.18 370.00 701.42 0.54 510.00 535.58 1.46
250.00 806.68 0.16 380.00 692.12 0.60 520.00 518.45 1.41
260.00 798.02 0.16 390.00 682.63 0.65 530.00 499.10 1.37
270.00 789.37 0.16 400.00 672.91 0.71 540.00 476.25 1.37
280.00 780.71 0.17 410.00 662.92 0.76 550.00 447.80 1.41
290.00 772.06 0.19 420.00 652.62 0.82 560.00 409.41 1.56
293.15 769.33 0.20 430.00 641.97 0.88 570.00 340.43 2.22
298.15 765.00 0.21

Cycloheptane [291-64-5] C7H14 MW = 98.19 50

Tc = 604.20 K [96-dau]
c = 278.00 kgm-3 [96-dau]

Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.0829 (low temperature range), c,w = (3.4892 10-1 combined temperature ranges, weighted),
O

c,uw = 4.9750 10-1 (combined temperature ranges, unweighted).


T = 273.15 to 485.00 K T = 485.00 to 604.20 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 7.98067 102 1.45435
B 1.38830 -4.54351 10-2
C -6.26106 10-3 5.25283 10-4
-6
D 5.70644 10 -1.95959 10-6

cont.

Landolt-Brnstein
New Series IV/8D
54 2.3 Alkylcycloalkanes (CnH2n), C7

Cycloheptane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 825.20 2.00 -1.23 02-mar( ) 574.00 491.00 2.00 -2.40 72-you( )
288.15 815.30 2.00 0.53 02-mar1) 580.30 479.00 2.00 2.05 72-you( )
293.15 809.20 2.00 -1.55 02-mar1) 300.45 804.80 0.30 0.04 73-nay/kud()
273.15 825.20 1.00 -1.23 03-mar-1( ) 310.27 796.62 0.30 0.10 73-nay/kud()
293.15 809.20 1.00 -1.55 03-mar-11) 320.89 787.63 0.30 0.22 73-nay/kud()
273.15 827.50 1.50 1.07 08-wil/kam( ) 330.83 779.10 0.30 0.38 73-nay/kud()
273.65 823.90 2.00 -2.16 26-ruz/bru1( ) 340.81 770.41 0.30 0.54 73-nay/kud()
289.25 813.30 0.60 -0.59 38-vog( ) 350.02 762.28 0.30 0.64 73-nay/kud()
293.15 809.80 0.60 -0.95 38-vog1) 359.78 753.54 0.30 0.68 73-nay/kud()
314.15 790.50 0.60 -2.72 38-vog1) 369.70 744.55 0.30 0.63 73-nay/kud()
334.15 773.30 0.60 -2.49 38-vog1) 298.15 806.56 0.30 -0.10 75-ana/gro()
293.15 809.80 0.40 -0.95 52-ano-5( ) 289.23 814.59 0.09 0.68 76-mey/hot( )
293.15 811.00 0.40 0.25 54-ano-8( ) 301.55 804.00 0.09 0.15 76-mey/hot( )
298.15 807.32 0.40 0.66 65-wat/mcl( ) 318.29 789.54 0.10 -0.12 76-mey/hot( )
477.10 639.00 5.00 -15.97 72-you1) 333.52 776.27 0.10 -0.07 76-mey/hot( )
492.20 620.00 5.00 -22.31 72-you1) 349.14 762.52 0.10 0.09 76-mey/hot( )
504.50 606.00 5.00 -15.59 72-you( ) 363.46 749.75 0.10 0.21 76-mey/hot( )
535.90 563.00 2.00 2.83 72-you( ) 376.96 737.52 0.11 0.14 76-mey/hot( )
542.60 547.00 2.00 -1.78 72-you( ) 387.44 727.88 0.13 -0.10 76-mey/hot( )
545.70 544.00 2.00 0.28 72-you( ) 298.15 806.67 0.20 0.01 79-for/dar( ) {
565.00 512.00 2.00 0.10 72-you( ) 298.15 806.75 0.20 0.09 81-mar/sym()
1) Not included in Fig. 1.
Further references: [16-ros, 26-ruz/bru-1, 29-ros, 30-god/cau, 30-ruz/sto, 46-baz/ste, 47-spi/huf, 52-
kaa/coo, 83-wil/ing].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 828.80 1.83 370.00 743.65 0.30 490.00 645.05 13.33
280.00 821.19 1.08 380.00 734.65 0.17 500.00 629.98 6.96
290.00 813.29 0.57 390.00 725.70 0.14 510.00 610.66 5.29
293.15 810.75 0.45 400.00 716.83 0.24 520.00 590.28 4.64
298.15 806.66 0.30 410.00 708.08 0.39 530.00 570.83 4.33
300.00 805.14 0.25 420.00 699.48 0.60 540.00 553.12 4.18
310.00 796.75 0.11 430.00 691.07 0.86 550.00 536.84 4.11
320.00 788.18 0.08 440.00 682.87 1.19 560.00 520.66 4.09
330.00 779.45 0.12 450.00 674.94 1.60 570.00 502.19 4.12
340.00 770.60 0.19 460.00 667.29 2.08 580.00 477.82 4.25
350.00 761.66 0.28 470.00 659.96 2.64 590.00 441.87 4.61
360.00 752.66 0.33 480.00 652.99 3.30 600.00 379.46 6.32
cont.
Landolt-Brnstein
New Series IV/8D
2.3 Alkylcycloalkanes (CnH2n), C7 - 2.4 Alkylcycloalkanes (CnH2n), C8 55

Cycloheptane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

2.4 Alkylcycloalkanes, (CnH2n), C8


2.4.1 Cyclopropanes

1-Butyl-2-methylcyclopropane [2511-92-4] C8H16 MW = 112.22 51

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 744.5 2.00 63-nef/nov

1-Ethyl-2-propylcyclopropane [500011-08-5] C8H16 MW = 112.22 52

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 735.4 0.80 56-gra/kos

Landolt-Brnstein
New Series IV/8D
56 2.4 Alkylcycloalkanes (CnH2n), C8

1,2-Diethyl-1-methylcyclopropane [98997-51-4] C8H16 MW = 112.22 53

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 738.1 2.00 13-zel/upe
293.15 741.2 0.80 56-gra/kos
293.15 740.8 0.9 Recommended

1,1-Dimethyl-2-propylcyclopropane [41845-48-1] C8H16 MW = 112.22 54

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 729.7 0.40 60-kac/tog

(1,2-Dimethylpropyl)cyclopropane [6976-27-8] C8H16 MW = 112.22 55

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 750.2 1.00 52-sla-1

(1-Methylbutyl)cyclopropane [5458-16-2] C8H16 MW = 112.22 56

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 742.7 0.20 52-sla/wis-1

1-Methyl-2-(2-methylpropyl)cyclopropane [500030-54-6] C8H16 MW = 112.22 57

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 740.3 2.00 13-zel/upe

Pentylcyclopropane [2511-91-3] C8H16 MW = 112.22 58

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 742.7 1.00 63-nef/nov

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 57

2.4.2 Cyclobutanes

Butylcyclobutane [13152-44-8] C 8H16 MW = 112.22 59

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 995.73
B -0.725

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 783.2 2.00 0.00 39-pin/ipa


313.15 768.7 2.00 0.00 39-pin/ipa

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 785.5 2.5
293.15 783.2 2.0
298.15 779.6 2.0
310.00 771.0 2.0
320.00 763.7 2.5

1-(1-Methylethyl)-1-methylcyclobutane [500004-72-8] C8H16 MW = 112.22 60

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 722.7 1.00 49-der/gre

trans-1-Methyl-3-propylcyclobutane [500025-80-9] C8H16 MW = 112.22 61

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 737.0 0.80 54-kaz/luk

Landolt-Brnstein
New Series IV/8D
58 2.4 Alkylcycloalkanes (CnH2n), C8

2.4.3 Cyclopentanes

1-Ethyl-1-methylcyclopentane [16747-50-5] C8H16 MW = 112.22 62

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.051.
Coefficient = A + BT
A 1025.08
B -0.833

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 780.6 0.60 -0.28 46-pla/zab


293.15 780.9 0.15 0.03 49-for/ros
298.15 776.7 0.15 -0.04 49-for/ros
303.15 772.6 0.15 0.03 49-for/ros
293.15 782.4 1.00 1.52 57-nov/khr 1)
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 783.5 0.2
293.15 780.9 0.2
298.15 776.7 0.2
300.00 775.2 0.2
310.00 766.8 0.3

1-Ethyl-2-methylcyclopentane [500030-22-8] C8H16 MW = 112.22 63

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 772.8 4.00 35-nen/van

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 59

cis-1-Ethyl-2-methylcyclopentane [930-89-2] C8H16 MW = 112.22 64

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.6727 10-1 (combined temperature ranges,
weighted), c,uw = 1.1124 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.54368 102
B -3.48442 10-1
C -7.80948 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 801.10 0.60 0.18 31-chi() 273.15 801.55 0.40 0.63 {


44-chi( )
293.15 784.60 0.60 -0.51 31-chi() 293.15 785.06 0.40 -0.05 {
44-chi( )
273.15 801.10 0.60 0.18 34-chi-1() 293.15 785.20 0.10 0.09
49-for/ros( )
293.15 784.60 0.60 -0.51 34-chi-1() 298.15 781.11 0.10 0.05
49-for/ros( )
293.15 785.06 0.60 -0.05 35-chi() 303.15 776.97 0.10 0.00
49-for/ros( )

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 803.36 0.60 293.15 785.11 0.20 300.00 779.55 0.12
280.00 795.58 1.00 298.15 781.06 0.11 310.00 771.30 1.16
290.00 787.64 0.40

cont.

Landolt-Brnstein
New Series IV/8D
60 2.4 Alkylcycloalkanes (CnH2n), C8

cis-1-Ethyl-2-methylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

trans-1-Ethyl-2-methylcyclopentane [930-90-5] C8H16 MW = 112.22 65

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.6736 10-1 (combined temperature ranges,
weighted), c,uw = 8.9482 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01326 103
B -8.32453 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 61

trans-1-Ethyl-2-methylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 786.00 0.60 0.13 31-chi() 273.15 785.48 0.50 -0.39 {


44-chi( )
293.15 769.60 0.60 0.38 31-chi() 293.15 769.10 0.50 -0.12 {
44-chi( )
273.15 786.00 0.60 0.13 34-chi-1() 293.15 769.00 0.40 -0.22
46-for/ros-1( )
293.15 769.60 0.60 0.38 34-chi-1() 298.15 764.90 0.40 -0.16
46-for/ros-1( )
293.15 769.10 0.60 -0.12 35-chi()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 788.49 0.60 293.15 769.22 0.5 300.00 763.52 0.50
280.00 780.17 0.66 298.15 765.06 0.5 310.00 755.19 0.60
290.00 771.84 0.60

Landolt-Brnstein
New Series IV/8D
62 2.4 Alkylcycloalkanes (CnH2n), C8

1-Ethyl-3-methylcyclopentane [3726-47-4] C8H16 MW = 112.22 66

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
289.15 766.9 6.00 02-zel-1
293.15 763.3 4.00 50-boo/gre
293.15 763.1 4.00 56-ano

cis-1-Ethyl-3-methylcyclopentane [2613-66-3] C8H16 MW = 112.22 67

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1024.51
B -0.860

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 772.4 0.40 -0.00 46-for/ros-1


298.15 768.1 0.40 0.00 46-for/ros-1

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 775.1 0.5
293.15 772.4 0.4
298.15 768.1 0.4
300.00 766.5 0.5

trans-1-Ethyl-3-methylcyclopentane [2613-65-2] C8H16 MW = 112.22 68

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.330.
Coefficient = A + BT
A 1008.38
B -0.840

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 63

trans-1-Ethyl-3-methylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 761.9 0.40 -0.23 46-for/ros-1


298.15 757.7 0.40 -0.23 46-for/ros-1
293.15 762.6 0.40 0.47 54-baz/kop

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 764.8 0.5
293.15 762.1 0.4
298.15 757.9 0.4
300.00 756.4 0.5

(1-Methylethyl)cyclopentane [3875-51-2] C8H16 MW = 112.22 69

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.2868 10-2 (combined temperature ranges,
weighted), c,uw = 1.3107 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.31678 102
B -2.64716 10-1
C -9.02208 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 776.50 0.40 -0.04 41-ano-1( ) 273.15 792.00 1.50 -0.06 46-gei/can( )
273.15 792.00 0.40 -0.06 44-can() 293.15 776.00 1.50 -0.54 46-gei/can1)
293.15 776.30 0.40 -0.24 44-can1) 313.15 761.00 1.50 0.69 46-gei/can1)
313.15 760.70 0.40 0.39 44-can1) 293.15 776.60 0.40 0.06 49-boo/hen( )
293.15 776.59 0.40 0.05 44-gar() 293.15 776.50 0.40 -0.04 49-foe/fen( )
293.15 776.61 0.40 0.07 44-gar() 293.15 776.51 0.15 -0.03 {
49-for/ros( )
293.15 776.60 0.30 0.06 46-boo/gre() 298.15 772.57 0.15 0.02 {
49-for/ros( )
293.15 776.54 0.05 -0.00
46-for/gla( ) 303.15 768.51 0.15 -0.01 {
49-for/ros( )
298.15 772.55 0.05 -0.00
46-for/gla( )
1) Not included in Fig. 1.

cont.

Landolt-Brnstein
New Series IV/8D
64 2.4 Alkylcycloalkanes (CnH2n), C8

(1-Methylethyl)cyclopentane (cont.)

Further references: [25-eis/gor, 36-kaz/pla-1, 39-kaz/tat, 39-pin/ipa, 43-ano, 45-cra/boo, 46-baz/ste, 50-
kaz/ter-1].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 794.43 1.05 293.15 776.54 0.22 300.00 771.06 0.12
280.00 786.82 0.72 298.15 772.55 0.17 310.00 762.91 0.25
290.00 779.03 0.42

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 65

Propylcyclopentane [2040-96-2] C8H16 MW = 112.22 70

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.9868 10-1 (combined temperature ranges,
weighted), c,uw = 5.1371 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01354 103
B -8.09393 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 775.60 0.60 -0.67 39-pin/ipa1) 293.15 776.35 0.20 0.08 44-gar()
313.15 760.10 0.60 0.02 39-pin/ipa() 299.85 770.98 0.20 0.14 44-gar()
273.15 791.80 0.40 -0.65 44-can() 300.42 770.46 0.20 0.08 44-gar()
293.15 776.00 0.40 -0.27 44-can1) 308.54 763.84 0.20 0.03 44-gar()
313.15 759.70 0.40 -0.38 44-can() 309.15 763.35 0.20 0.03 44-gar()
281.19 786.14 0.20 0.19 44-gar() 293.15 776.23 0.05 -0.04 46-for/gla()
281.53 785.84 0.20 0.17 44-gar() 298.15 772.31 0.05 0.09 46-for/gla()
289.43 779.39 0.20 0.11 44-gar() 293.15 776.31 0.15 0.04 49-for/ros({)
289.88 779.05 0.20 0.14 44-gar() 298.15 772.27 0.15 0.05 49-for/ros({)
293.15 776.35 0.20 0.08 44-gar() 303.15 768.09 0.15 -0.08 49-for/ros({)
1) Not included in Fig. 1.

Further references: [06-zel, 27-cha/bec, 32-gar/eva, 34-zel/kaz, 35-zel/kaz, 38-eva, 39-tur/pol, 40-ano,
43-ano, 45-boo/gre, 45-cra/boo, 46-baz/ste, 46-boo/gre, 46-gei/can, 49-foe/fen, 51-ano, 54-khr/bal-1].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 795.00 0.41 293.15 776.27 0.14 310.00 762.63 0.33
280.00 786.91 0.29 298.15 772.22 0.13 320.00 754.53 0.84
290.00 778.82 0.16 300.00 770.72 0.14

cont.

Landolt-Brnstein
New Series IV/8D
66 2.4 Alkylcycloalkanes (CnH2n), C8

Propylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,1,2-Trimethylcyclopentane [4259-00-1] C8H16 MW = 112.22 71

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.4703 (combined temperature ranges,
weighted), c,uw = 3.3354 10-1 (combined
temperature ranges, unweighted).
T = 277.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01539 103
B -8.29191 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 67

1,1,2-Trimethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

277.15 784.70 2.00 -0.88 06-cro/ren( ) 293.15 772.20 0.40 -0.11 45-ano()
283.15 779.80 2.00 -0.81 06-cro/ren( ) 293.15 772.50 0.15 0.19 49-for/ros( )
288.18 775.50 2.00 -0.94 06-cro/ren1) 298.15 768.15 0.15 -0.02 49-for/ros( )
289.35 774.61 2.00 -0.86 06-cro/ren1) 303.15 763.97 0.15 -0.05 49-for/ros( )
293.15 771.40 2.00 -0.91 06-cro/ren1) 293.15 772.20 0.40 -0.11 51-ano()
298.15 767.10 2.00 -1.07 06-cro/ren1) 293.15 772.20 0.40 -0.11 51-des/fid( ){
289.35 774.60 1.00 -0.87 06-eyk-1( ) 293.15 775.10 0.50 2.79 56-lev/gir-1()
1) Not included in Fig. 1.

Further references: [01-zel/lep-1, 22-cha].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
68 2.4 Alkylcycloalkanes (CnH2n), C8

1,1,2-Trimethylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 791.51 3.00 293.15 772.31 0.41 300.00 766.63 0.11
280.00 783.22 2.11 298.15 768.17 0.09 310.00 758.34 2.57
290.00 774.93 0.90

1,1,3-Trimethylcyclopentane [4516-69-2] C8H16 MW = 112.22 72

Table 1. Fit with estimated B coefficient for 12


accepted points. Deviation w = 0.056.
Coefficient = A + BT
A 1002.42
B -0.867

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

293.15 770.3 2.00 22.04 13-zel/usp 1) 293.15 748.3 0.30 0.04 49-boo/gre
293.15 748.2 0.40 -0.06 45-ano-8 293.15 748.23 0.15 -0.03 49-for/ros
293.15 748.3 0.30 0.04 45-boo/gre 298.15 743.90 0.15 -0.02 49-for/ros
293.15 748.1 0.50 -0.16 45-mck/ste 1) 303.15 739.56 0.15 -0.03 49-for/ros
293.15 748.3 0.40 0.04 45-per 293.15 748.2 0.40 -0.03 51-slo
293.15 748.3 0.40 0.04 46-ano-2 293.15 748.2 0.40 -0.06 54-ano-8
298.15 744.2 0.60 0.28 47-gla/wil 1) 293.15 748.4 0.30 0.14 54-baz/kop
293.15 748.4 0.30 0.14 49-boo/gre
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 751.0 0.2
293.15 748.3 0.2
298.15 743.9 0.2
300.00 742.3 0.2
310.00 733.7 0.3

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 69

1,2,3-Trimethylcyclopentane [2815-57-8] C8H16 MW = 112.22 73

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 0.129.
Coefficient = A + BT
A 1001.83
B -0.830

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

277.15 771.8 5.00 0.01 06-cro/ren


288.15 762.6 5.00 -0.06 06-cro/ren
292.95 758.8 5.00 0.12 06-cro/ren
293.15 758.3 5.00 -0.21 06-cro/ren
298.15 754.5 5.00 0.14 06-cro/ren

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 777.7 6.0
280.00 769.4 5.0
290.00 761.1 5.0
293.15 758.5 5.0
298.15 754.4 5.0
300.00 752.8 5.0

r-1, c-2, c-3-Trimethylcyclopentane [2613-69-6] C8H16 MW = 112.22 74

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1019.58
B -0.820

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 779.2 0.40 0.00 46-for/ros-1


298.15 775.1 0.40 0.00 46-for/ros-1
293.15 776.6 2.00 -2.60 47-kaz/kop 1)
293.15 776.6 2.00 -2.60 48-kop/kaz 1)
1)
Not included in calculation of linear coefficients.
cont.

Landolt-Brnstein
New Series IV/8D
70 2.4 Alkylcycloalkanes (CnH2n), C8

r-1, c-2, c-3-Trimethylcyclopentane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 781.8 0.5
293.15 779.2 0.4
298.15 775.1 0.4

r-1, c-2, t-3-Trimethylcyclopentane [15890-40-1] C8H16 MW = 112.22 75

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.380.
Coefficient = A + BT
A 1022.30
B -0.860

Table 2. Experimental values with uncertainties


and deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 770.4 0.40 0.21 46-for/ros-1


298.15 766.1 0.40 0.21 46-for/ros-1
293.15 769.5 0.60 -0.69 47-kaz/kop
293.15 769.5 1.00 -0.69 48-kop/kaz

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 772.9 0.4
293.15 770.2 0.4
298.15 765.9 0.4
300.00 764.3 0.4

r-1, t-2, c-3-Trimethylcyclopentane [19374-46-0] C8H16 MW = 112.22 76

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 0.168.
Coefficient = A + BT
A 1005.76
B -0.860

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 71

r-1, t-2, c-3-Trimethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 753.5 0.40 -0.15 46-ano


298.15 749.2 0.40 -0.15 46-ano
293.15 754.0 0.60 0.35 47-kaz/kop
293.15 754.0 1.00 0.35 48-kop/kaz
293.15 753.7 0.30 0.05 61-ano-9

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 756.4 0.5
293.15 753.7 0.5
298.15 749.4 0.5
300.00 747.8 0.5

r-1, c-2, c-4-Trimethylcyclopentane [2613-72-1] C8H16 MW = 112.22 77

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 776.6 1.00 48-kop/kaz
293.15 762.0 1.50 63-ano-3

r-1, c-2, t-4-Trimethylcyclopentane [4850-28-6] C8H16 MW = 112.22 78

Table 1. Fit with estimated B coefficient for 8


accepted points. Deviation w = 0.078.
Coefficient = A + BT
A 1009.96
B -0.841

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3 kg m3 K kg m3 kg m3

293.15 763.6 0.40 0.18 43-ano 293.15 763.6 0.50 0.18 51-ano
293.15 763.43 0.15 0.01 49-for/ros 293.15 763.4 0.60 -0.02 51-bir/joh1)
298.15 759.18 0.15 -0.03 49-for/ros 293.15 763.5 0.40 0.08 51-slo
303.15 755.02 0.15 0.01 49-for/ros 293.15 763.2 0.30 -0.22 54-baz/kop
293.15 763.5 0.50 0.08 50-boo/gre
1)
Not included in calculation of linear coefficients.

cont.
Landolt-Brnstein
New Series IV/8D
72 2.4 Alkylcycloalkanes (CnH2n), C8

r-1, c-2, t-4-Trimethylcyclopentane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 766.1 0.2
293.15 763.4 0.2
298.15 759.2 0.2
310.00 749.2 0.3

r-1, t-2, t-4-Trimethylcyclopentane [16883-48-0] C8H16 MW = 112.22 79

Table 1. Fit with estimated B coefficient for 8


accepted points. Deviation w = 0.179.
Coefficient = A + BT
A 997.58
B -0.854

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

293.15 747.5 0.40 0.27 43-ano 303.15 738.71 0.10 0.02 49-for/ros
293.15 747.2 0.30 -0.03 49-boo/gre 293.15 747.1 0.60 -0.13 51-bir/joh
293.15 747.25 0.10 0.02 49-for/ros 293.15 747.5 0.40 0.27 51-slo
298.15 743.00 0.10 0.04 49-for/ros 293.15 746.3 0.30 -0.93 54-baz/kop

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 749.9 0.2
293.15 747.2 0.2
298.15 743.0 0.2
310.00 732.8 0.3

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 73

2.4.4 Cyclohexanes

Ethylcyclohexane [1678-91-7] C8H16 MW = 112.22 80

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.9087 10-1 (combined temperature ranges,
weighted), c,uw = 7.0424 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02440 103
B -8.06381 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

288.15 791.40 0.40 -0.65 32-gar/eva( ) 291.54 789.62 0.20 0.31 44-gar()
293.15 787.50 0.40 -0.51 32-gar/eva1) 292.19 788.97 0.20 0.18 44-gar()
288.15 791.40 0.40 -0.65 38-eva( ) 293.15 788.21 0.30 0.20 44-gar()
293.15 787.50 0.40 -0.51 38-eva1) 293.15 788.20 0.30 0.19 44-gar()
273.15 803.90 0.50 -0.24 42-gei( ) 302.48 780.74 0.20 0.25 44-gar()
293.15 788.10 0.50 0.09 42-gei1) 302.98 780.31 0.20 0.22 44-gar()
313.15 772.30 0.50 0.41 42-gei( ) 311.00 773.83 0.20 0.21 44-gar()
273.15 803.90 0.30 -0.24 44-can() 293.15 787.90 0.05 -0.11
46-for/gla( )
293.15 788.10 0.30 0.09 44-can() 298.15 783.88 0.05 -0.10
46-for/gla( )
313.15 772.30 0.30 0.41 44-can() 303.15 779.40 0.50 -0.55 64-pra/van( )
273.78 803.80 0.20 0.17 44-gar() 298.15 783.59 0.30 -0.39 90-fer/lap()
283.07 796.33 0.20 0.19 44-gar() 298.15 783.82 0.20 -0.16 {
94-del/fer( )
283.86 795.76 0.20 0.26 44-gar()
1) Not included in Fig. 1.

Further references: [1899-kur-1, 01-sab/sen, 01-sab/sen-1, 11-leb/ska, 14-vav, 25-eis/gor, 28-ada/mar,


29-str-1, 33-sig/cra, 34-lev/tzu, 35-ros/whi, 37-loz/dya, 39-ano, 40-ano, 46-baz/ste, 46-gei/can, 51-des/fid,
54-chi/maq, 55-bal/tur, 60-qoz/van, 60-yak/vol, 61-pau/yuz, 61-tar/tul, 63-ano-3, 63-pra/van].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 806.68 0.39 293.15 788.01 0.15 310.00 774.43 0.27
280.00 798.62 0.29 298.15 783.98 0.13 320.00 766.36 0.45
290.00 790.55 0.20 300.00 782.49 0.13

cont.

Landolt-Brnstein
New Series IV/8D
74 2.4 Alkylcycloalkanes (CnH2n), C8

Ethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,1-Dimethylcyclohexane [590-66-9] C8H16 MW = 112.22 81

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.1142 10-1 (combined temperature ranges,
weighted), c,uw = 9.8668 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01699 103
B -8.05772 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 75

1,1-Dimethylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

277.15 794.70 1.00 1.03 05-cro/ren( ) 293.15 780.99 0.40 0.21 46-lib/kaz( )
288.15 785.69 1.00 0.88 05-cro/ren1) 293.15 780.60 0.30 -0.18 49-eva()
293.15 781.88 1.00 1.10 05-cro/ren1) 293.15 780.92 0.10 0.14 49-for/ros( )
298.15 777.50 1.00 0.75 05-cro/ren1) 298.15 776.75 0.10 0.00 49-for/ros( )
290.35 782.24 0.50 -0.79 19-eyk( ) 303.15 772.74 0.10 0.02 49-for/ros( )
288.15 784.00 0.60 -0.81 31-cha/mil( ) 293.15 780.75 0.50 -0.03 50-chi/fie1)
273.15 797.07 0.30 0.18 35-mam( ) { 303.15 772.55 0.50 -0.17 50-chi/fie( )
293.15 780.73 0.30 -0.05 35-mam( ) { 293.15 781.00 0.40 0.22 51-ano( )
273.15 797.07 0.60 0.18 35-mil( ) 293.15 780.90 0.40 0.12 56-ano( )
293.15 780.71 0.40 -0.07 35-mil( ) 293.15 780.90 0.40 0.12 56-ano-6()
293.15 780.60 0.30 -0.18 45-boo/gre()
1) Not included in Fig. 1.
Further references: [13-von/eis, 13-zel/lep, 15-von/lan, 23-zel, 23-zel-2, 35-zel/pac, 36-hib/lin, 48-
sho/cra, 49-baz/ukh, 50-zel/ela, 55-bal/tur, 56-goe/mcc, 66-khr/koc, 68-puz/eid].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
76 2.4 Alkylcycloalkanes (CnH2n), C8

1,1-Dimethylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 799.43 0.69 293.15 780.78 0.20 300.00 775.26 0.15
280.00 791.37 0.55 298.15 776.75 0.15 310.00 767.20 0.25
290.00 783.32 0.35

1,2-Dimethylcyclohexane [583-57-3] C8H16 MW = 112.22 82

Table 1. Experimental values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
3 3
K kg m K kg m
273.15 800.8 4.00 01-sab/sen 293.15 781.4 4,00 37-loz/dya
273.15 800.3 4.00 05-sab/mai-1 288.15 791.2 4.00 38-eva
287.45 788.0 6.00 11-eyk 293.15 787.4 4.00 38-eva
286.15 798.0 6.00 19-cha/sim-1 293.15 783.0 4.00 66-mek/mag
291.00 780.9 4.00 20-von-2 293.15 772.6 4.00 67-mek/mag
566.30 779.0 6.00 20-von-2 298.15 786.1 4.00 90-che/pet
293.15 789.3 4.00 24-zel-2 298.15 786.1 4.00 95-pet/gas
286.65 792.0 5.00 30-god/cau

cis-1,2-Dimethylcyclohexane [2207-01-4] C8H16 MW = 112.22 83

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8377 10-1 (combined temperature ranges,
weighted), c,uw = 9.8146 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03175 103
B -8.02866 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 77

cis-1,2-Dimethylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 811.23 0.25 -1.22 32-mil() 290.54 798.73 0.20 0.24 44-gar( ){
293.15 796.18 0.25 -0.21 32-mil() 291.19 798.21 0.20 0.25 44-gar( ){
273.15 813.09 0.25 0.64 35-mil() 293.15 796.56 0.20 0.17 44-gar( ){
293.15 796.23 0.25 -0.16 35-mil() 301.43 789.95 0.20 0.21 44-gar( ){
273.15 812.10 0.50 -0.35 42-gei( ) 301.93 789.94 0.20 0.60 44-gar( ){
293.15 795.70 0.50 -0.69 42-gei1) 310.24 782.73 0.20 0.06 44-gar( ){
313.15 780.10 0.50 -0.23 42-gei( ) 310.89 782.20 0.20 0.05 44-gar( ){
273.15 812.10 0.50 -0.35 44-can( ) 293.15 796.25 0.05 -0.14 46-for/gla( )
293.15 795.70 0.50 -0.69 44-can1) 298.15 792.20 0.05 -0.18 46-for/gla( )
313.15 780.10 0.50 -0.23 44-can( ) 298.15 792.86 0.30 0.48 90-che/pet()
282.09 805.64 0.20 0.37 44-gar( ){
1) Not included in Fig. 1.
Further references: [22-cha/bec, 22-cha/van, 22-ski/sch, 32-gar/eva, 32-zel/mar, 33-mil/pia, 33-sig/cra,
35-mam, 41-ano-1, 45-gre-1, 46-ano, 46-boo/gre, 46-gei/can, 49-baz/ukh, 49-boo/hen, 54-cla/cor, 68-
man/mue, 68-wip/cle, 74-anf/bal, 75-pav/kla, 95-pet/gas].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
78 2.4 Alkylcycloalkanes (CnH2n), C8

cis-1,2-Dimethylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 814.98 0.40 293.15 796.39 0.18 310.00 782.86 0.32
280.00 806.95 0.31 298.15 792.38 0.16 320.00 774.83 0.75
290.00 798.92 0.20 300.00 790.89 0.17

trans-1,2-Dimethylcyclohexane [6876-23-9] C8H16 MW = 112.22 84

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.8273 10-2 (combined temperature ranges,
weighted), c,uw = 2.9783 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.91644 102
B -6.76113 10-1
C -2.03176 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 791.83 0.25 0.02 32-mil() 283.12 784.05 0.20 0.11 {


44-gar( )
293.15 775.99 0.25 0.01 32-mil() 290.88 777.85 0.20 0.06 {
44-gar( )
293.15 775.84 0.30 -0.14 33-mil/pia( ) 293.15 776.03 0.20 0.05 {
44-gar( )
273.15 791.86 0.20 0.05 35-mil() 301.49 769.43 0.20 0.09 {
44-gar( )
293.15 775.99 0.20 0.01 35-mil() 302.21 768.85 0.20 0.09 {
44-gar( )
298.15 792.02 0.20 20.02 35-mil1) 310.31 762.34 0.20 0.06 {
44-gar( )
293.15 775.65 0.30 -0.33 41-ano-1( ) 293.15 776.04 0.20 0.06 46-ano()
273.15 791.00 0.40 -0.81 44-can1) 293.15 776.04 0.30 0.06 46-boo/gre( )
293.15 775.50 0.40 -0.48 44-can1) 293.15 775.99 0.05 0.01 46-for/gla( )
313.15 759.90 0.40 -0.10 44-can( ) 298.15 772.02 0.05 0.02 46-for/gla( )
282.66 784.42 0.20 0.12 44-gar( ){ 293.15 775.65 0.30 -0.33 49-boo/hen( )
1) Not included in Fig. 1.

Further references: [21-ski, 22-ski/sch, 25-eis/gor, 29-str-1, 32-zel/mar, 36-mar-1, 46-baz/ste, 46-
gei/can, 49-baz/ukh, 54-cla/cor].

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 79

trans-1,2-Dimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 794.28 0.30 293.15 775.98 0.15 310.00 762.52 0.28
280.00 786.40 0.25 298.15 772.00 0.13 320.00 754.48 0.65
290.00 778.48 0.19 300.00 770.52 0.15

Landolt-Brnstein
New Series IV/8D
80 2.4 Alkylcycloalkanes (CnH2n), C8

1,3-Dimethylcyclohexane [591-21-9] C8H16 MW = 112.22 85

Table 1. Experimental values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
3 3
K kg m K kg m
273.15 777.0 4.00 1877-wre 293.15 782.2 4.00 08-ski
293.15 766.0 4.00 1877-wre 294.95 770.1 4.00 10-lei
292.45 766.5 3.00 1884-los/zan 286.15 775.0 4.00 19-cha/sim-1
292.15 764.0 4.00 1884-ren 288.15 775.0 6.00 19-cha/sim-2
290.15 757.3 4.00 1891-asc 293.15 777.0 4.00 26-wei/hen
295.15 764.0 4.00 1892-wal-1 286.65 777.2 5.00 30-god/cau
292.15 768.8 5.00 1895-zel 293.15 770.1 4.00 32-zel/mar
295.15 795.7 4.00 1895-zel/rud 293.15 769.3 4.00 32-zel/mar
291.15 773.6 4.00 1897-kno-1 293.15 772.0 4.00 33-sig/cra
293.15 768.7 4.00 1897-zel 293.15 767.7 4.00 37-loz/dya
273.15 787.4 4.00 01-sab/sen 288.15 776.1 4.00 38-eva
273.15 787.4 4.00 01-sab/sen-1 293.15 772.3 4.00 38-eva
299.15 766.1 4.00 02-zel-1 293.15 770.7 4.00 49-vve/tak
288.15 774.1 6.00 04-bal/ang 293.15 767.6 4.00 66-mek/mag
273.15 786.9 4.00 05-sab/mai-1

cis-1,3-Dimethylcyclohexane [638-04-0] C8H16 MW = 112.22 86

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.2120 10-1 (combined temperature ranges,
weighted), c,uw = 7.9671 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03766 103
B -1.04011
C 3.87507 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 782.49 0.60 0.03 35-mil( ) 293.15 766.01 0.05 -0.04 46-for/gla( )
293.15 766.26 0.40 0.21 35-mil( ) 298.15 761.94 0.05 -0.05 46-for/gla( )
273.15 781.90 0.50 -0.56 42-gei( ) 298.15 762.00 0.30 0.01 47-osb/gin()
293.15 765.90 0.50 -0.15 42-gei( ) 293.15 766.28 0.30 0.23 60-nat()
313.15 749.80 0.50 -0.15 42-gei( ) 293.15 766.00 0.20 -0.05 63-gon/sha( ) {
293.15 766.70 0.30 0.65 43-ano( ) 303.15 757.90 0.20 -0.06 63-gon/sha( ) {
273.15 781.90 0.30 -0.56 44-can() 293.15 766.30 0.50 0.25 68-man/mue( )
293.15 765.90 0.30 -0.15 44-can() 293.15 766.60 0.50 0.55 75-pav/kla( )
313.15 749.80 0.30 -0.15 44-can()
cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 81

cis-1,3-Dimethylcyclohexane (cont.)

Further references: [15-von/hin, 19-cha/sim-1, 21-ski, 22-cha/bec, 22-cha/van, 22-ski/sch, 25-eis/gor,


26-wei/hen, 32-gar/eva, 32-zel/mar, 35-mam, 36-mar-1, 38-mou/gra, 38-mou/gra-1, 39-mou/pau, 41-ano-
1, 46-ano-4, 46-baz/ste, 46-gei/can, 49-baz/ukh, 51-des/fid, 53-noy/nag].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 785.08 0.34 293.15 766.05 0.34 310.00 752.46 0.29
280.00 776.81 0.60 298.15 761.99 0.22 320.00 744.50 1.06
290.00 768.61 0.42 300.00 760.50 0.19

Landolt-Brnstein
New Series IV/8D
82 2.4 Alkylcycloalkanes (CnH2n), C8

(1R-trans)-1,3-Dimethyl-cyclohexane [69685-68-3] C8H16 MW = 112.22 87

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
783.48 0.30 35-mil
1)
293.15
298.15 777.00 0.70 38-mou/gra
298.15 777.00 2.00 38-mou/gra-1
298.15 777.00 0.70 46-mou
293.15 784.90 0.70 68-man/mue
293.15 784.80 0.70 75-pav/kla
1)
This point included in the fit of trans-1,3-Dimethylhexane.

trans-1,3-Dimethylcyclohexane [2207-03-6] C8H16 MW = 112.22 88

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.9790 10-1 (combined temperature ranges,
weighted), c,uw = 1.2820 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.11135 103
B -1.40304
C 9.84496 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 783.48 0.30 -1.18 35-mil() 313.15 768.70 0.40 0.17 44-can()
298.15 779.28 0.50 -1.27 35-mil1) 293.15 784.70 0.05 0.04 46-for/gla( )
293.15 784.00 0.50 -0.66 41-ano-1( ) 298.15 780.53 0.05 -0.02 46-for/gla( )
273.15 801.60 0.50 0.03 42-gei( ) 298.15 780.60 0.30 0.05 47-osb/gin()
293.15 785.30 0.50 0.64 42-gei( ) 293.15 784.50 0.50 -0.16 49-baz/ukh( )
313.15 768.70 0.50 0.17 42-gei( ) 293.15 784.80 0.20 0.14 63-gon/sha( ) {
273.15 801.60 0.40 0.03 44-can() 303.15 776.60 0.20 0.10 63-gon/sha( ) {
293.15 785.30 0.40 0.64 44-can()
1) Not included in Fig. 1.

Further references: [21-ski, 32-gar/eva, 32-zel/mar, 35-mam, 36-mar-1, 38-mou/gra, 38-mou/gra-1, 39-
mou/pau, 46-gei/can, 46-mou, 68-man/mue, 75-pav/kla].

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 83

trans-1,3-Dimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 804.30 0.70 293.15 784.66 0.20 310.00 771.02 0.31
280.00 795.69 0.60 298.15 780.55 0.18 320.00 763.19 1.21
290.00 787.27 0.35 300.00 779.05 0.20
*
Data sets 87 and 88 are combined for recommended values.

Landolt-Brnstein
New Series IV/8D
84 2.4 Alkylcycloalkanes (CnH2n), C8

1,4-Dimethylcyclohexane [589-90-2] C8H16 MW = 112.22 89

Table 1. Experimental values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
3 3
K kg m K kg m
293.15 769.0 4.00 1898-zel/nou 286.65 775.6 5.00 30-god/cau
293.15 768.8 4.00 1898-zel/nou 293.15 775.0 4.00 33-sig/cra
273.15 786.6 4.00 01-sab/sen 293.15 782.7 4.00 35-mil
293.15 762.6 4.00 01-sub 293.15 766.9 4.00 37-loz/dya
273.15 786.1 4.00 05-sab/mai-1 288.15 776.7 4.00 38-eva
295.35 762.0 4.00 11-eyk 293.15 772.7 4.00 38-eva
286.15 783.0 4.00 19-cha/sim-1 293.15 770.5 4.00 55-bal/tur
288.85 772.2 4.00 20-von-2 293.15 766.6 4.00 66-mek/mag
293.15 769.0 4.00 20-von-2

cis-1,4-Dimethylcyclohexane [624-29-3] C8H16 MW = 112.22 90

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.4917 10-1 (combined temperature ranges,
weighted), c,uw = 6.4911 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02460 103
B -8.24605 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 799.25 0.30 -0.11 35-mil( ) 289.75 785.84 0.20 0.17 {


44-gar( )
293.15 782.71 0.30 -0.16 35-mil( ) 293.15 782.97 0.15 0.10 {
44-gar( )
273.15 799.00 0.50 -0.36 42-gei( ) 300.16 777.22 0.20 0.13 {
44-gar( )
293.15 782.60 0.50 -0.27 42-gei1) 300.39 777.02 0.20 0.12 {
44-gar( )
313.15 766.00 0.50 -0.38 42-gei( ) 308.18 770.54 0.20 0.06 {
44-gar( )
293.15 782.80 0.20 -0.07 43-for-1() 293.15 782.97 0.20 0.10 46-ano()
298.15 778.61 0.20 -0.14 43-for-1() 293.15 782.97 0.30 0.10 46-boo/gre( )
273.15 799.00 0.30 -0.36 44-can( ) 293.15 782.83 0.05 -0.04 46-for/gla( )
293.15 782.60 0.30 -0.27 44-can( ) 298.15 778.68 0.05 -0.07 46-for/gla( )
313.15 766.00 0.30 -0.38 44-can( ) 293.15 782.71 0.30 -0.16 60-nat( )
281.94 792.41 0.20 0.30 {
44-gar( ) 293.15 783.70 0.30 0.83 81-sid/koh()
281.29 792.92 0.20 0.28 {
44-gar( ) 313.15 766.98 0.30 0.60 81-sid/koh()
1) Not included in Fig. 1.

Further references: [22-ski/sch, 32-zel/mar, 36-mar-1, 41-ano-1, 46-gei/can, 49-boo/hen, 54-baz/kop,


64-doe/hau, 65-zhi/ste, 68-akh/yas, 68-man/mue, 68-wip/cle, 75-pav/kla].
cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 85

cis-1,4-Dimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 801.96 0.38 293.15 782.87 0.17 310.00 768.98 0.30
280.00 793.71 0.32 298.15 778.75 0.15 320.00 760.73 0.61
290.00 785.47 0.20 300.00 777.22 0.15

Landolt-Brnstein
New Series IV/8D
86 2.4 Alkylcycloalkanes (CnH2n), C8

trans-1,4-Dimethylcyclohexane [2207-04-7] C8H16 MW = 112.22 91

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.5969 10-1 (combined temperature ranges,
weighted), c,uw = 1.0481 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.06462 103
B -1.22900
C 6.78048 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 779.11 0.30 -0.39 35-mil() 293.15 762.55 0.15 -0.05 {


44-gar( )
293.15 762.62 0.30 0.02 35-mil1) 293.28 763.39 0.20 0.89 {
44-gar( )
298.15 758.50 0.30 0.04 35-mil1) 293.84 762.98 0.20 0.95 {
44-gar( )
273.15 778.50 0.50 -1.00 42-gei( ) 298.65 758.77 0.20 0.72 {
44-gar( )
293.15 762.30 0.50 -0.30 42-gei1) 298.93 758.99 0.20 1.17 44-gar1)
313.15 746.00 0.50 -0.25 42-gei( ) 302.27 755.08 0.20 0.00 {
44-gar( )
293.15 762.49 0.20 -0.11 43-for-1() 302.68 754.72 0.20 -0.02 {
44-gar( )
298.15 758.28 0.20 -0.18 43-for-1() 310.36 748.34 0.20 -0.16 {
44-gar( )
283.71 770.45 0.20 -0.06 44-gar( ){ 293.15 762.52 0.05 -0.08 46-for/gla( )
284.47 769.86 0.20 -0.01 44-gar( ){ 298.15 758.33 0.05 -0.13 46-for/gla( )
291.94 763.59 0.20 -0.02 44-gar( ){ 293.15 762.87 0.30 0.27 81-sid/koh1)
292.25 763.32 0.20 -0.03 44-gar( ){ 313.15 746.21 0.30 -0.04 81-sid/koh()
1) Not included in Fig. 1.

Further references: [13-gad/sso, 22-ski/sch, 25-eis/gor, 32-zel/mar, 36-mar-1, 41-ano-1, 46-baz/ste, 46-
boo/gre, 46-gei/can, 49-boo/hen, 54-cla/cor, 60-nat, 68-akh/yas, 68-man/mue, 68-wip/cle, 75-pav/kla].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 782.22 0.51 293.15 762.60 0.16 310.00 748.79 0.31
280.00 773.66 0.28 298.15 758.46 0.17 320.00 740.77 0.56
290.00 765.23 0.17 300.00 756.94 0.18

cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 87

trans-1,4-Dimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

2.4.5 Cycloheptanes and Cyclooctane

Methylcycloheptane [4126-78-7] C8H16 MW = 112.22 92

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.925.
Coefficient = A + BT
A 1052.29
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m
3
kg m3 K kg m 3
kg m3

293.15 798.1 2.00 -5.01 05-zel 293.15 805.2 1.00 2.09 36-ruz/sei
286.65 808.7 0.80 0.07 30-god/cau 293.15 800.1 2.00 -3.01 46-baz/ste
286.65 808.2 1.50 -0.43 34-god

cont.

Landolt-Brnstein
New Series IV/8D
88 2.4 Alkylcycloalkanes (CnH2n), C8

Methylcycloheptane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 814.3 3.0
290.00 805.8 2.5
293.15 803.1 2.5
298.15 798.9 3.0

Cyclooctane [292-64-8] C8H16 MW = 112.22 93


Tc = 647.20 K [96-dau]
c = 274.00 kgm-3 [96-dau]
Table 1. Coefficients for the polynomial expansion equations. Standard deviations (see introduction):
= 1.0093 10-1 (low temperature range), c,w = (3.3891 10-1 combined temperature ranges, weighted),
O

c,uw = 7.8804 10-1 (combined temperature ranges, unweighted).


T = 288.15 to 520.00 K T = 520.00 to 647.20 K
Coefficient = A + BT + CT 2 + DT 3 + = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)]
[c + A(Tc -T ) + B(Tc - T )2 + C(Tc - T )3
+ D(Tc - T )4]
A 9.98119 102 1.44739
B -1.48110 10-5 -3.59047 10-2
C -3.36957 10-3 3.35402 10-4
-6
D 6.56657 10 -1.04712 10-6
-9
E -5.13236 10

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 836.20 0.20 0.13 52-kaa/coo() 638.30 422.00 2.00 15.62 72-you( )
293.15 836.10 0.20 0.03 53-ano-1( ){ 288.15 840.05 0.20 -0.01 73-lev( )
293.10 836.70 0.34 0.59 55-kus1) 298.15 832.01 0.20 -0.05 73-lev( )
298.10 832.60 0.35 0.50 55-kus1) 318.15 815.63 0.20 -0.30 73-lev1)
303.10 828.40 0.36 0.31 55-kus1) 302.24 828.95 0.09 0.17 76-mey/hot( )
313.10 820.20 0.38 0.18 55-kus( ) 318.92 815.33 0.10 0.03 76-mey/hot( )
323.10 812.00 0.40 0.09 55-kus( ) 337.71 799.95 0.10 -0.03 76-mey/hot( )
333.10 804.00 0.42 0.25 55-kus1) 349.62 790.20 0.10 0.02 76-mey/hot( )
343.10 795.60 0.44 0.05 55-kus( ) 363.74 778.49 0.10 0.02 76-mey/hot( )
353.10 787.20 0.46 -0.10 55-kus( ) 383.49 761.94 0.12 0.03 76-mey/hot( )
288.15 840.05 0.20 -0.01 70-ewi/lev( ) 401.89 746.23 0.14 -0.00 76-mey/hot( )
298.15 832.01 0.20 -0.05 70-ewi/lev( ) 298.15 832.10 0.20 0.04 79-for/dar()
308.15 823.80 0.20 -0.22 70-ewi/lev( ) 298.15 831.99 0.20 -0.07 81-mar/sym()
568.60 573.00 2.00 7.52 72-you( ) 293.15 836.07 0.20 0.00 84-tan/tak( )
580.10 553.00 2.00 2.86 72-you( ) 298.15 831.98 0.20 -0.08 84-tan/tak( )
601.40 515.00 2.00 -4.91 72-you( ) 303.15 827.90 0.20 -0.15 84-tan/tak( )
613.30 488.00 2.00 -9.19 72-you( )
1) Not included in Fig. 1. cont.

Landolt-Brnstein
New Series IV/8D
2.4 Alkylcycloalkanes (CnH2n), C8 89

Cyclooctane (cont.)
Further references: [07-wil/bru, 07-wil/ver, 10-wil/was, 11-wil/was, 30-god/cau, 30-ruz/sto, 30-zel/fre,
31-ruz/boe, 33-ruz/boe, 47-spi/huf, 50-zie/wil, 65-tre/mit, 65-wat/mcl, 74-jai/nor, 75-ana/gro, 79-wil/far,
81-kiy/ben, 82-gri/phi, 83-wil/ing].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 846.54 0.21 390.00 756.39 0.17 520.00 635.03 6.40
290.00 838.59 0.19 400.00 747.85 0.16 530.00 622.53 6.90
293.15 836.07 0.20 410.00 739.23 0.22 540.00 607.77 7.20
298.15 832.06 0.21 420.00 730.52 0.37 550.00 592.44 7.30
300.00 830.58 0.21 430.00 721.70 0.60 560.00 577.57 7.40
310.00 822.53 0.23 440.00 712.77 0.90 570.00 563.57 7.50
320.00 814.43 0.25 450.00 703.69 1.29 580.00 550.27 7.60
330.00 806.29 0.26 460.00 694.48 1.78 590.00 536.90 7.70
340.00 798.10 0.26 470.00 685.09 2.38 600.00 522.18 7.78
350.00 789.87 0.25 480.00 675.53 3.11 610.00 504.23 7.86
360.00 781.58 0.24 490.00 665.76 3.97 620.00 480.48 7.90
370.00 773.25 0.22 500.00 655.77 5.00 630.00 447.06 8.10
380.00 764.85 0.20 510.00 645.53 5.80 640.00 395.47 8.60

Landolt-Brnstein
New Series IV/8D
90 2.5 Alkylcycloalkanes (CnH2n), C9

2.5 Alkylcycloalkanes (CnH2n), C9


2.5.1 Cyclopropanes - Cyclobutanes

1-Butyl-1-ethylcyclopropane [66688-70-8] C9H18 MW = 126.24 94

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 755.9 0.60 48-sho/cra

1,2-Diethyl-1,2-dimethylcyclopropane [500011-35-8] C9H18 MW = 126.24 95

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 759.5 0.70 52-lev/gla

1,1-Dimethyl-2-(2-methylpropyl) [500030-55-7] C9H18 MW = 126.24 96


cyclopropane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 954.59
B -0.805

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 718.6 1.50 0.00 13-kis-5


273.15 734.7 1.50 0.00 13-kis-5

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 737.2 3.0
280.00 729.2 2.0
290.00 721.1 2.0
293.15 718.6 2.0
298.15 714.6 3.0

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 91

Hexamethylcyclopropane [2570-81-2] C9H18 MW = 126.24 97

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 768.3 0.40 55-kel/gre

(1-Methylpentyl)cyclopropane [6976-28-9] C9H18 MW = 126.24 98

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 754.2 0.20 52-sla/wis-1

(1-Ethylpropyl)cyclobutane [500025-81-0] C9H18 MW = 126.24 99

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
292.15 794.5 6.00 05-kis/amo
293.15 781.5 0.80 57-kaz/luk

2.5.2 Cyclopentanes

Butylcyclopentane [2040-95-1] C 9H18 MW = 126.24 100

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.9604 10-1 (combined temperature ranges,
weighted), c,uw = 1.4276 10-1 (combined
temperature ranges, unweighted).
T = 288.10 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01768 103
B -7.95859 10-1

cont.

Landolt-Brnstein
New Series IV/8D
92 2.5 Alkylcycloalkanes (CnH2n), C9

Butylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

288.15 788.70 0.60 0.34 27-cha( ) 293.15 783.20 0.70 -1.18 39-gro/wac( )
293.35 784.80 0.60 0.58 27-cha( ) 293.15 783.20 0.60 -1.18 39-pin/ipa( )
288.10 788.70 0.60 0.30 27-cha/bec( ) 313.15 768.70 0.60 0.24 39-pin/ipa( )
293.35 784.80 0.60 0.58 27-cha/bec( ) 293.15 784.00 0.50 -0.38 45-cra/boo()
288.15 788.60 0.50 0.24 32-gar/eva( ) 293.15 784.60 0.30 0.22 47-boo/gre( )
293.15 784.70 0.50 0.32 32-gar/eva( ) 293.15 784.60 0.30 0.22 47-boo/gre( )
289.15 786.20 1.00 -1.36 36-kaz/pla( ) 293.15 784.60 0.40 0.22 49-boo/hen( ) {
288.15 788.60 0.40 0.24 38-eva() 293.15 784.40 0.50 0.02 49-foe/fen()
293.15 784.70 0.40 0.32 38-eva() 293.15 784.60 0.50 0.22 50-chi/fie-1( )

Further references: [27-bau, 39-tur/kos, 46-baz/ste, 57-pla/sta, 57-shu/che].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 93

Butylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 794.84 1.00 298.15 780.40 0.44 310.00 770.97 0.44
290.00 786.88 1.07 300.00 778.93 0.44 320.00 763.01 4.20
293.15 784.38 0.51

1,1-Diethylcyclopentane [2721-38-2] C9H18 MW = 126.24 101

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 802.7 0.60 11-kis

cis-1,2-Diethylcyclopentane [932-39-8] C9H18 MW = 126.24 102

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 0.275.
Coefficient = A + BT
A 1030.24
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 795.1 1.00 -0.62 11-kis


293.15 796.0 1.00 0.25 33-chi
273.15 811.6 1.00 -0.07 33-chi
293.15 796.0 0.60 0.25 44-chi
273.15 811.6 0.60 -0.09 44-chi

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 814.2 0.7
280.00 806.2 0.5
290.00 798.2 0.5
293.15 795.7 0.5
298.15 791.7 0.7

Landolt-Brnstein
New Series IV/8D
94 2.5 Alkylcycloalkanes (CnH2n), C9

trans-1,2-Diethylcyclopentane [932-40-1] C9H18 MW = 126.24 103

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 0.583.
Coefficient = A + BT
A 1011.41
B -0.780

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 783.2 1.00 0.41 33-chi


273.15 798.6 1.00 0.21 33-chi
293.15 783.1 1.00 0.39 35-chi
293.15 781.7 1.00 -1.05 44-boo/per
293.15 783.2 0.60 0.41 44-chi
273.15 798.6 0.60 0.21 44-chi
293.15 781.7 0.80 -1.05 44-gre/per

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 800.8 0.8
280.00 793.0 0.9
290.00 785.2 0.6
293.15 782.8 0.6
298.15 778.9 0.8

1,3-Diethylcyclopentane [19398-75-5] C9H18 MW = 126.24 104

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 785.0 6.00 05-kis-1

(1,1-Dimethylethyl)cyclopentane [3875-52-3] C9H18 MW = 126.24 105

Table 1. Fit with estimated B coefficient for 10


accepted points. Deviation w = 0.415.
Coefficient = A + BT
A 1022.41
B -0.790

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 95

(1,1-Dimethylethyl)cyclopentane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3
kg m3 K kg m 3
kg m3

293.15 791.1 0.60 0.28 39-gro/wac 293.15 790.9 0.30 0.08 44-boo/per
293.15 791.1 0.60 0.28 39-pin/ipa 293.15 789.4 0.50 -1.42 45-cra/boo
313.15 775.3 0.60 0.28 39-pin/ipa 293.15 790.9 0.40 0.08 45-per
293.15 791.1 0.50 0.28 39-pin/ipa-1 293.15 790.8 0.30 -0.02 46-boo/gre
313.15 775.3 0.50 0.28 39-pin/ipa-1 293.15 790.8 0.40 -0.02 47-ano-4

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 793.3 0.5
293.15 790.8 0.4
298.15 786.9 0.4
300.00 785.4 0.5
310.00 777.5 0.6
320.00 769.6 1.0

r-1-Ethyl-c-2, t-4-dimethylcyclopentane [2532-62-9] C9H18 MW = 126.24 106

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 779.5 0.60 54-baz/kop

r-1-Ethyl-t-2, c-4-dimethylcyclopentane [2532-61-8] C9H18 MW = 126.24 107

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 763.7 0.30 54-baz/kop

r-1-Ethyl-t-2, t-3-dimethylcyclopentane [18469-76-6] C9H18 MW = 126.24 108

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 763.7 1.00 54-baz/kop

Landolt-Brnstein
New Series IV/8D
96 2.5 Alkylcycloalkanes (CnH2n), C9

1-Methyl-2-(1-methylethyl)cyclopentane [89223-57-4] C9H18 MW = 126.24 109

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1019.48
B -0.820

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 779.1 4.00 0.00 12-kis-1


288.15 783.2 4.00 0.00 12-kis-1

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 789.9 5.0
290.00 781.7 4.0
293.15 779.1 4.0
298.15 775.0 5.0
300.00 773.5 5.0

1-Methyl-3-(1-methylethyl)cyclopentane [53771-88-3] C9H18 MW = 126.24 110

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 2.110.
Coefficient = A + BT
A 1009.31
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

288.35 779.9 5.00 1.27 11-eyk-1


293.15 779.2 6.00 4.41 12-kis-1
295.15 773.0 5.00 -0.19 12-wal/mey
292.15 773.0 5.00 -2.59 13-god/tab-1
291.65 775.0 4.00 -0.99 29-kaz

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 97

1-Methyl-3-(1-methylethyl)cyclopentane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 785.3 6.0
290.00 777.3 5.0
293.15 774.8 4.0
298.15 770.8 5.0
300.00 769.3 5.0

(1-Methylpropyl)cyclopentane [4850-32-2] C9H18 MW = 126.24 111

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.1356 (combined temperature ranges,
weighted), c,uw = 2.1197 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02780 103
B -7.95659 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 810.00 2.00 -0.47 13-wil/hei( ) 293.15 794.10 0.60 -0.46 39-pin/ipa()
273.15 810.00 1.00 -0.47 13-wil/kin( ) 313.15 778.70 0.60 0.06 39-pin/ipa()
291.15 797.10 1.00 0.95 36-kaz( ) 293.15 793.40 0.50 -1.16 {
45-cra/boo( )
291.15 797.10 1.00 0.95 36-kaz/pla( ) 293.15 794.70 0.40 0.14
48-ano-6( )
291.15 797.10 0.70 0.95 36-kaz/pla-1( ) 293.15 794.50 0.50 -0.06 49-foe/fen()
293.15 794.10 0.60 -0.46 39-gro/wac()

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit
K kg m3 K kg m3
270.00 812.98 0.65 293.15 794.56 0.52 310.00 781.15 0.80
280.00 805.02 2.30 298.15 790.58 0.50 320.00 773.19 3.50
290.00 797.06 1.12 300.00 789.11 0.60

cont.

Landolt-Brnstein
New Series IV/8D
98 2.5 Alkylcycloalkanes (CnH2n), C9

(1-Methylpropyl)cyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(2-Methylpropyl)cyclopentane [3788-32-7] C9H18 MW = 126.24 112

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 779.5 1.00 25-eis-1
293.15 779.5 2.00 25-eis/gor
293.15 780.6 0.60 39-gro/wac
293.15 780.9 0.20 44-boo/per
293.15 780.9 0.40 44-gre
293.15 780.7 0.50 45-cra/boo
293.15 780.8 0.30 Recommended

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 99

1-Methyl-1-propylcyclopentane [16631-63-3] C9H18 MW = 126.24 113

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 785.1 4.00 57-nov/khr

cis-1-Methyl-2-propylcyclopentane [932-43-4] C9H18 MW = 126.24 114

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.045.
Coefficient = A + BT
A 1023.64
B -0.790

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 792.1 2.00 0.04 34-chi


273.15 807.8 2.00 -0.05 34-chi
293.15 792.1 0.50 0.04 44-chi
273.15 807.8 0.50 -0.05 44-chi

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 810.3 0.5
280.00 802.4 0.6
290.00 794.5 0.5
293.15 792.1 0.5
298.15 788.1 0.6

trans-1-Methyl-2-propylcyclopentane [932-44-5] C9H18 MW = 126.24 115

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 0.024.
Coefficient = A + BT
A 1009.04
B -0.790

cont.

Landolt-Brnstein
New Series IV/8D
100 2.5 Alkylcycloalkanes (CnH2n), C9

trans-1-Methyl-2-propylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 777.4 1.00 -0.05 26-cha-3


293.15 777.4 2.00 -0.04 34-chi
273.15 793.3 2.00 0.01 34-chi
293.15 777.4 2.00 -0.05 35-chi
293.15 777.5 0.60 0.01 44-chi
273.15 793.3 0.60 0.01 44-chi

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 795.7 0.6
280.00 787.8 0.7
290.00 779.9 0.6
293.15 777.4 0.6
298.15 773.5 0.7

cis-1-Methyl-3-propylcyclopentane [2443-04-1] C9H18 MW = 126.24 116

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 771.7 2.00 33-lov/cam
293.15 771.5 2.00 49-baz/ukh
293.15 771.5 1.00 50-kaz/kop
293.15 771.5 1.00 Recommended

1,1,2,3-Tetramethylcyclopentane [102653-33-8] C9H18 MW = 126.24 117

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
287.25 782.0 5.00 06-eyk-1

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 101

cis-1,1,2,3-Tetramethylcyclopentane [62016-69-7] C9H18 MW = 126.24 118

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 4.752.
Coefficient = A + BT
A 999.92
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

287.25 782.0 2.00 11.88 06-eyk-1


273.15 779.5 0.80 -1.90 19-eyk

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 783.9 1.0
280.00 775.9 3.0
290.00 767.9 6.0
293.15 765.4 8.0

1,1,2,4-Tetramethylcyclopentane [90674-66-1] C9H18 MW = 126.24 119

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 764.8 3.00 63-lev/sha

cis-1,1,2,4-Tetramethylcyclopentane [62016-71-1] C9H18 MW = 126.24 120

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

293.15 764.6 0.80 56-ano

trans-1,1,2,4-Tetramethylcyclopentane [62016-72-2] C9H18 MW = 126.24 121

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 764.8 0.80 51-ano-3

Landolt-Brnstein
New Series IV/8D
102 2.5 Alkylcycloalkanes (CnH2n), C9

1,1,3,3-Tetramethylcyclopentane [50876-33-0] C9H18 MW = 126.24 122

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 750.9 0.40 48-ano-3
293.15 750.9 0.40 49-ano-1
293.15 750.9 0.40 51-slo
293.15 750.9 0.40 Recommended

cis-1,1,3,4-Tetramethylcyclopentane [53907-60-1] C9H18 MW = 126.24 123

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 767.0 0.40 51-ano-3

trans-1,1,3,4-Tetramethylcyclopentane [20309-77-7] C9H18 MW = 126.24 124

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 748.9 0.40 51-ano-3

r-1, c-2, c-3, c-4- [2532-65-2] C9H18 MW = 126.24 125


Tetramethylcyclopentane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 792.4 0.30 61-mil/gre
293.15 792.4 0.30 63-ano-3

r-1, c-2, c-3, t-4- [2532-69-6] C9H18 MW = 126.24 126


Tetramethylcyclopentane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 776.3 0.40 61-mil/gre
293.15 776.3 0.40 63-ano-3

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 103

r-1, c-2, t-3, c-4- [2532-68-5] C9H18 MW = 126.24 127


Tetramethylcyclopentane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 766.9 0.30 61-mil/gre
293.15 766.9 0.30 63-ano-3

r-1, t-2, t-3, c-4- [19907-40-5] C9H18 MW = 126.24 128


Tetramethylcyclopentane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 756.2 0.30 61-mil/gre
293.15 756.2 0.30 63-ano-3

2.5.3 Cyclohexanes

1-Ethyl-1-methylcyclohexane [4926-90-3] C9H18 MW = 126.24 129

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 806.2 0.20 53-ano-1
293.15 806.2 0.20 55-ano-8
293.15 806.5 0.40 55-pin/mar
293.15 806.1 1.00 55-pin/mar
293.15 805.3 1.00 66-khr/koc
298.15 805.0 2.00 70-goo-31)
293.15 806.2 0.20 Recommended
1)
Not included in calculation of recommended value.

1-Ethyl-2-methylcyclohexane [3728-54-9] C9H18 MW = 126.24 130

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 803.6 4.00 33-sig/cra

Landolt-Brnstein
New Series IV/8D
104 2.5 Alkylcycloalkanes (CnH2n), C9

cis-1-Ethyl-2-methylcyclohexane [4923-77-7] C9H18 MW = 126.24 131

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.105.
Coefficient = A + BT
A 1044.16
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 809.4 0.40 -0.24 54-bir/dea-1


298.15 805.6 0.40 -0.04 54-bir/dea-1
293.15 809.7 0.20 0.06 58-ano-6
293.15 809.7 0.40 0.06 63-ano-3
298.15 809.0 2.00 3.36 70-goo-31)
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 812.2 0.5
293.15 809.6 0.4
298.15 805.6 0.5
300.00 804.2 0.6

trans-1-Ethyl-2-methylcyclohexane [4923-78-8] C9H18 MW = 126.24 132

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.687.
Coefficient = A + BT
A 1033.03
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 797.2 1.00 -1.31 54-bir/dea-1


298.15 793.4 1.00 -1.11 54-bir/dea-1
293.15 798.9 0.40 0.39 58-ano-6
298.15 796.0 2.00 1.49 70-goo-31)
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 105

trans-1-Ethyl-2-methylcyclohexane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 801.0 1.0
293.15 798.5 0.7
298.15 794.5 0.7
300.00 793.0 0.8

1-Ethyl-3-methylcyclohexane [3728-55-0] C9H18 MW = 126.24 133

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
290.15 789.6 4.00 02-zel-1

cis-1-Ethyl-3-methylcyclohexane [19489-10-2] C9H18 MW = 126.24 134

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation = 0.387.
Coefficient = A + BT
A 1051.49
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 788.7 2.00 1.04 33-sig/cra


298.15 783.0 1.00 -0.16 38-mou/gra-1
298.15 783.0 1.00 -0.16 39-mou/pau
298.15 783.0 1.00 -0.16 46-mou
293.15 783.7 3.00 -3.96 63-ano-31)
298.15 784.0 2.00 0.84 70-goo-3
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 790.5 1.5
293.15 787.7 1.0
298.15 783.2 1.5
300.00 781.5 2.0

Landolt-Brnstein
New Series IV/8D
106 2.5 Alkylcycloalkanes (CnH2n), C9

trans-1-Ethyl-3-methylcyclohexane [4926-76-5] C9H18 MW = 126.24 135

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation = 4.831.
Coefficient = A + BT
A 1047.48
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

298.15 786.0 2.00 -8.05 38-mou/gra-1


298.15 786.0 1.00 -8.05 39-mou/pau
298.15 786.0 1.00 -8.05 46-mou
293.15 801.2 0.40 2.90 63-ano-3

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 801.0 4.8
293.15 798.3 4.8
298.15 794.1 4.8
300.00 792.5 5.0

1-Ethyl-4-methylcyclohexane [3728-56-1] C9H18 MW = 126.24 136

Table 1. Fit with estimated B coefficient for 1


accepted point. Deviation = 0.000.
Coefficient = A + BT
A 1047.73
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

273.15 804.1 2.00 2.20 01-sab/sen1)


288.15 788.4 1.00 0.00 06-sab/mai
293.15 789.7 2.00 5.80 33-sig/cra1)
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 107

1-Ethyl-4-methylcyclohexane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 795.7 4.0
290.00 786.7 4.0
293.15 783.9 5.0

cis-1-Ethyl-4-methylcyclohexane [4926-78-7] C9H18 MW = 126.24 137

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 789.7 2.00 33-sig/cra1)
293.15 796.9 0.80 55-kaz/lib
293.15 795.6 0.40 63-ano-3
298.15 795.0 2.00 70-goo-31)
293.15 795.9 0.40 Recommended
1)
Not included in calculation of recommended value.

trans-1-Ethyl-4-methylcyclohexane [6236-88-0] C9H18 MW = 126.24 138

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 779.4 0.40 63-ano-3
298.15 778.0 2.00 70-goo-3

(1-Methylethyl)cyclohexane [696-29-7] C9H18 MW = 126.24 139

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.7990 10-1 (combined temperature ranges,
weighted), c,uw = 8.4061 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 323.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02537 103
B -7.61832 10-1

cont.

Landolt-Brnstein
New Series IV/8D
108 2.5 Alkylcycloalkanes (CnH2n), C9

(1-Methylethyl)cyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

284.15 809.00 1.00 0.10 29-str-1( ) 293.15 802.06 0.20 0.02 44-gar( ){
293.15 802.30 0.30 0.26 39-wib/hoo() 293.15 802.06 0.20 0.02 46-ano()
298.15 798.38 0.30 0.15 39-wib/hoo() 273.15 817.00 1.50 -0.28 46-gei/can( )
293.15 801.60 0.30 -0.44 41-ano-1() 293.15 803.00 1.50 0.96 46-gei/can1)
273.15 816.60 0.40 -0.68 44-can( ) 313.15 786.00 1.50 -0.81 46-gei/can1)
293.15 802.60 0.40 0.56 44-can( ) 293.15 802.19 0.10 0.15 49-for/ros( )
313.15 786.20 0.40 -0.61 44-can( ) 298.15 798.31 0.10 0.08 49-for/ros( )
303.15 794.76 0.40 0.33 44-gar/( )2) 303.15 794.42 0.10 -0.01 49-for/ros( )
313.15 786.88 0.40 0.07 44-gar/( )2) 293.15 801.80 0.50 -0.24 50-chi/fie-1( )
323.15 779.07 0.40 -0.12 44-gar/( )2) 293.15 802.70 0.50 0.66 54-khr/nov( )
1) Not included in Fig. 1.
2)
Calculated from equation given by author

Further references: [25-eis/gor, 33-sig/cra, 45-gre/vog, 47-nam/vol, 49-vve/tak, 54-chi/maq, 54-eve/bor,


55-bal/tur, 56-tur/kra].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.
Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 109

(1-Methylethyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 819.68 1.18 293.15 802.04 0.35 310.00 789.21 0.28
280.00 812.06 0.73 298.15 798.23 0.28 320.00 781.59 0.44
290.00 804.44 0.42 300.00 796.82 0.26 330.00 773.97 0.74

Propylcyclohexane [1678-92-8] C9H18 MW = 126.24 140

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.3425 10-1 (combined temperature ranges,
weighted), c,uw = 3.2790 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.07063 103
B -1.10742
C 5.52915 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 809.10 1.00 -0.29 01-sab/sen( ) 300.82 787.68 0.20 0.15 44-gar()
293.15 793.48 0.20 -0.03 43-for-1() 301.19 787.38 0.20 0.14 44-gar()
298.15 789.56 0.20 -0.04 43-for-1() 309.65 780.76 0.20 0.03 44-gar()
273.15 808.50 0.30 -0.89 44-can1) 310.35 780.21 0.20 0.01 44-gar()
293.15 793.00 0.30 -0.51 44-can1) 293.15 793.47 0.05 -0.04
46-for/gla( )
313.15 777.70 0.30 -0.36 44-can( ) 298.15 789.58 0.05 -0.02
46-for/gla( )
280.88 803.23 0.20 0.03 44-gar() 293.15 793.58 0.15 0.07 {
49-for/ros( )
281.32 802.88 0.20 0.03 44-gar() 298.15 789.75 0.15 0.15 {
49-for/ros( )
289.61 796.37 0.20 0.08 44-gar() 303.15 785.79 0.15 0.06 {
49-for/ros( )
289.97 796.10 0.20 0.10 44-gar() 293.15 793.27 0.20 -0.24 50-chi/fie-1( )
293.15 793.54 0.20 0.03 44-gar() 298.15 789.74 0.20 0.14 94-del/fer()
1) Not included in Fig. 1.

Further references: [1899-kur, 01-kur-2, 01-sab/sen-1, 25-eis/gor, 27-bou, 29-str-1, 32-gar/eva, 33-
sig/cra, 34-lev/tzu, 37-loz/dya, 38-eva, 41-ano-1, 46-ano, 46-boo/gre, 46-gei/can, 46-gre-1, 48-fie/ber-2,
54-chi/maq, 54-khr/nov, 56-tur/kra, 60-ale/ste, 91-ric/lau].

cont.

Landolt-Brnstein
New Series IV/8D
110 2.5 Alkylcycloalkanes (CnH2n), C9

Propylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 811.93 1.32 293.15 793.51 0.13 310.00 780.47 0.26
280.00 803.90 0.39 298.15 789.60 0.17 320.00 772.87 0.20
290.00 795.98 0.13 300.00 788.17 0.19

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 111

1,1,2-Trimethylcyclohexane [7094-26-0] C9H18 MW = 126.24 141

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 798.7 0.50 47-ano-2
293.15 798.6 0.80 48-sho/cra
293.15 798.7 0.50 49-eva
293.15 798.6 0.20 56-ano
293.15 798.6 0.20 Recommended

1,1,3-Trimethylcyclohexane [3073-66-3] C9H18 MW = 126.24 142

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.7802 10-1 (combined temperature ranges,
weighted), c,uw = 7.4897 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 313.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.04924 102
B -9.18282 10-2
C -1.15476 10-3

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 779.20 0.30 0.43 41-ano-1() 293.15 778.00 1.50 -0.77 46-gei/can1)
273.15 793.90 0.60 0.22 44-can( ) 313.15 763.00 1.50 0.07 46-gei/can( )
293.15 778.30 0.60 -0.47 44-can( ) 293.15 778.30 0.60 -0.47 46-ipa/pin( )
313.15 762.90 0.60 -0.03 44-can( ) 293.15 778.81 0.15 0.04
49-for/ros( )
293.15 778.67 0.20 -0.10 {
44-gar( ) 298.15 774.95 0.15 0.06
49-for/ros( )
293.15 778.67 0.20 -0.10 46-ano() 303.15 770.98 0.15 0.02
49-for/ros( )
273.15 794.00 1.50 0.32 46-gei/can( ) 293.15 778.78 0.40 0.01 50-chi/fie-1()
1) Not included in Fig. 1.

Further references: [1897-kno/fis, 20-von-2, 54-lev/shu].

cont.

Landolt-Brnstein
New Series IV/8D
112 2.5 Alkylcycloalkanes (CnH2n), C9

1,1,3-Trimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 795.95 0.96 293.15 778.77 0.26 310.00 765.48 0.64
280.00 788.68 1.04 298.15 774.89 0.15 320.00 757.29 2.74
290.00 781.18 0.40 300.00 773.45 0.15

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 113

1,1,4-Trimethylcyclohexane [7094-27-1] C9H18 MW = 126.24 143

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.500.
Coefficient = A + BT
A 991.56
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 772.2 1.00 0.50 51-chi/maq


273.15 786.2 1.00 -0.50 51-chi/maq

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 789.1 1.2
280.00 781.6 1.2
290.00 774.1 0.8
293.15 771.7 0.7
298.15 768.0 0.9

1,2,3-Trimethylcyclohexane [1678-97-3] C9H18 MW = 126.24 144

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 793.0 8.00 25-eis/gor
293.15 792.0 6.00 50-chi/fie-1

r-1, c-2, c-3-Trimethylcyclohexane [1839-88-9] C9H18 MW = 126.24 145

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 802.1 0.50 56-bus/gre
293.15 802.7 0.40 61-ano-9
293.15 802.7 0.60 62-mah/gre

Landolt-Brnstein
New Series IV/8D
114 2.5 Alkylcycloalkanes (CnH2n), C9

r-1, c-2, t-3-Trimethylcyclohexane [7667-55-2] C9H18 MW = 126.24 146

Table 1. Experimental and recommended values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
3 3
K kg m K kg m
293.15 802.9 0.40 56-ano 293.15 803.0 0.25 62-ano-3
293.15 802.9 0.40 56-bus/gre 293.15 803.1 0.60 62-mah/gre
293.15 803.1 0.40 61-ano-9 293.15 803.0 0.30 Recommended
293.15 803.1 0.50 61-ano-9

r-1, t-2, c-3-Trimethylcyclohexane [1678-81-5] C9H18 MW = 126.24 147

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 787.0 0.40 56-bus/gre
293.15 787.0 0.60 62-mah/gre

1,2,4-Trimethylcyclohexane [2234-75-5] C9H18 MW = 126.24 148

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.9951 (combined temperature ranges,
weighted), c,uw = 1.6500 (combined temperature
ranges, unweighted).
T = 273.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04297 103
B -8.95135 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 780.80 6.00 0.23 1883-mar/ogl( ) 293.15 778.00 4.00 -2.57 20-von-2( )
273.15 783.30 6.00 -15.17 1894-gue( ) 293.15 781.30 4.00 0.73 25-eis-1( )
291.15 780.70 6.00 -1.66 1896-zel/ref( ) 293.15 785.00 5.00 4.43 25-eis/gor( )
273.15 805.20 4.00 6.73 01-sab/sen( ) 286.65 798.10 4.00 11.72 30-god/cau()
289.75 785.00 5.00 1.39 11-eyk-1( ) 293.15 772.00 3.00 -8.57 39-whi/gla()
289.85 784.80 5.00 1.28 11-eyk-1( ) 293.15 782.50 3.00 1.93 50-chi/fie-1( )
293.15 778.00 4.00 -2.57 13-gad/sso() 298.15 781.60 3.00 5.51 95-pet/gas( ) {
290.05 779.90 4.00 -3.44 20-von-2( )

cont.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 115

1,2,4-Trimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 801.29 7.10 293.15 780.57 4.58 300.00 774.43 4.00
280.00 792.34 5.58 298.15 776.09 4.00 310.00 765.48 5.56
290.00 783.39 4.88

Landolt-Brnstein
New Series IV/8D
116 2.5 Alkylcycloalkanes (CnH2n), C9

r-1, c-2, c-4-Trimethylcyclohexane [1678-80-4] C9H18 MW = 126.24 149

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 790.0 2.00 22-ski/sch
293.15 785.0 2.00 25-eis-1
293.15 791.4 0.50 56-ano-19
293.15 791.0 0.60 Recommended

r-1, c-2, t-4-Trimethylcyclohexane [7667-58-5] C9H18 MW = 126.24 150

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 786.0 2.00 22-ski/sch
293.15 782.8 0.50 56-ano-19
293.15 790.8 0.40 61-ano-9
293.15 787.6 2.50 Recommended

r-1, t-2, c-4-Trimethylcyclohexane [7667-59-6] C9H18 MW = 126.24 151

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 773.8 0.60 54-ano-13
293.15 774.5 0.50 56-ano-19
293.15 774.2 0.50 Recommended

r-1, t-2, t-4-Trimethylcyclohexane [7667-60-9] C9H18 MW = 126.24 152

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 774.0 2.00 22-ski/sch1)
293.15 772.0 2.00 39-whi/gla1)
283.15 788.4 0.50 56-ano-19
293.15 790.8 0.40 61-ano-9
293.15 790.6 0.40 62-ano-3
293.15 790.1 1.00 Recommended
1)
Not included in calculation of recommended value.

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 117

1,2,5-Trimethylcyclohexane [500030-50-2] C9H18 MW = 126.24 153

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
291.15 780.7 2.00 1896-zel/ref
290.05 779.9 3.00 20-von-2

1,3,5-Trimethylcyclohexane [1839-63-0] C9H18 MW = 126.24 154

Table 1. Experimental values with uncertainties.


T exp 2 est Ref. T exp 2 est Ref.
K kg m3 K kg m3
273.15 788.4 4.00 01-sab/sen 293.15 775.7 6.00 33-sig/cra
288.85 774.4 6.00 11-eyk 293.15 771.1 4.00 37-loz/dya
293.15 759.0 4.00 15-pic/bou 293.15 773.8 4.00 55-bal/tur
293.15 772.0 5.00 20-von-2 293.15 772.2 4.00 56-tur/kra
286.25 777.7 4.00 20-von-2

r-1, c-3, t-5-Trimethylcyclohexane [1795-26-2] C9H18 MW = 126.24 155

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.4860 (combined temperature ranges,
weighted), c,uw = 5.0848 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.94516 102
B -7.31800 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 781.70 0.60 1.71 49-ano-2() 293.15 778.85 0.70 -1.14 51-chi()
293.15 778.85 1.00 -1.14 50-chi/fie-1() 303.15 771.08 0.70 -1.59 51-chi()
273.15 794.38 0.70 -0.25 51-chi() 293.15 781.60 0.60 1.61 {
54-ano-5( )
288.15 782.73 0.70 -0.92 51-chi() 293.15 781.70 0.50 1.71 56-ano( )
Further references: [25-eis/gor, 49-ano-2].

cont.

Landolt-Brnstein
New Series IV/8D
118 2.5 Alkylcycloalkanes (CnH2n), C9

r-1, c-3, t-5-Trimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 796.93 0.96 293.15 779.99 0.69 300.00 774.98 0.74
280.00 789.61 0.78 298.15 776.33 0.72 310.00 767.66 0.90
290.00 782.29 0.69

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 119

r-1, c-3, c-5-Trimethylcyclohexane [1795-27-3] C9H18 MW = 126.24 156

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.6409 10-1 (combined temperature ranges,
weighted), c,uw = 1.3873 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.00232 103
B -7.92266 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 770.00 0.60 -0.06 46-baz/ste() 293.15 770.48 0.70 0.42 51-chi( )
293.15 769.70 0.40 -0.36 49-ano-2( ) 303.15 762.73 0.70 0.59 51-chi( )
293.15 770.48 0.80 0.42 50-chi/fie-1( ) 293.15 769.90 0.50 -0.16 56-ano()
273.15 785.98 0.70 0.07 51-chi( ) 293.15 769.50 0.60 -0.56 56-ano-6()
288.15 774.36 0.70 0.33 51-chi( ) 293.15 769.40 0.50 -0.66 56-lib/pry-2( ){
Further references: [25-eis-1, 25-eis/gor].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
120 2.5 Alkylcycloalkanes (CnH2n), C9

r-1, c-3, c-5-Trimethylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 788.41 0.83 293.15 770.06 0.59 300.00 764.64 0.64
280.00 780.48 0.92 298.15 766.10 0.59 310.00 756.71 1.45
290.00 772.56 0.66

2.5.4 Cycloheptanes - Cyclononane

Ethylcycloheptane [13151-55-8] C 9H18 MW = 126.24 157

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 0.399.
Coefficient = A + BT
A 1035.14
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 829.8 1.00 -0.48 02-mar/jak


293.15 815.1 1.00 -0.18 02-mar/jak
273.15 829.8 1.00 -0.48 03-mar-1
293.15 815.2 1.00 -0.08 03-mar-1
293.15 814.8 1.00 -0.48 46-baz/ste
293.15 815.7 0.50 0.42 56-ano

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 832.6 1.0
280.00 825.1 0.6
290.00 817.6 0.4
293.15 815.3 0.5
298.15 811.5 0.6

Landolt-Brnstein
New Series IV/8D
2.5 Alkylcycloalkanes (CnH2n), C9 - 2.6 Alkylcycloalkanes (CnH2n), C10 121

Methylcyclooctane [1502-38-1] C9H18 MW = 126.24 158

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 3.612.
Coefficient = A + BT
A 1053.21
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

286.65 840.5 0.80 2.28 30-god/cau


293.15 834.9 1.00 1.55 34-god
286.65 839.9 1.00 1.68 34-god
298.15 822.8 1.00 -6.80 52-cop/cam

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 843.2 3.7
290.00 835.7 3.6
293.15 833.3 3.6
298.15 829.6 3.6

Cyclononane [293-55-0] C9H18 MW = 126.24 159

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3

289.15 773.3 30.00 07-zel


273.15 785.0 30.00 07-zel
293.15 850.2 0.20 52-kaa/coo

2.6 Alkylcycloalkanes (CnH2n), C10


2.6.1 Cyclopropanes - Cyclobutanes

1,1-Dimethyl-2-(1,1-dimethylpropyl) [500028-22-8] C10H20 MW = 140.27 160


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

293.15 761.9 2.00 65-lev/kos

Landolt-Brnstein
New Series IV/8D
122 2.6 Alkylcycloalkanes (CnH2n), C10

1,1-Dimethyl-2-(1,1,2-trimethylpropyl) [500023-51-8] C10H20 MW = 40.27 161


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 784.7 1.00 65-lev/kos

1-Methyl-1,2-dipropylcyclopropane [99976-16-6] C10H20 MW = 140.27 162

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 762.1 1.00 56-gra/kos

1-(1-Methylethyl)-2-(2-methylpropyl) [99976-15-5] C10H20 MW = 140.27 163


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 750.8 2.00 56-gra/kos

1-Methyl-1-(4-methylpentyl) [500025-70-7] C10H20 MW = 140.27 164


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 754.4 0.80 57-kaz/luk-1

1,2-bis(1-Methylethyl)cyclobutane [3642-15-7] C10H20 MW = 140.27 165

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.200.
Coefficient = A + BT
A 995.16
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 775.5 4.00 0.20 11-leb


273.15 790.1 4.00 -0.20 11-leb

cont.
Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 123

1,2-bis(1-Methylethyl)cyclobutane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 792.7 4.0
280.00 785.2 4.0
290.00 777.7 4.0
293.15 775.3 4.0
298.15 771.6 5.0

1,1,2-Trimethyl-3-(1-methylethyl) [500030-18-2] C10H20 MW = 140.27 166


cyclobutane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 973.80
B -0.730

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 759.8 4.00 0.00 11-leb


273.15 774.4 4.00 0.00 11-leb

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 776.7 4.0
280.00 769.4 4.0
290.00 762.1 4.0
293.15 759.8 4.0
298.15 756.1 5.0

2.6.2 Cyclopentanes

cis-1-Butyl-2-methylcyclopentane [20556-39-2] C10H20 MW = 140.27 167

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 798.0 0.80 56-baz/sok

Landolt-Brnstein
New Series IV/8D
124 2.6 Alkylcycloalkanes (CnH2n), C10

trans-1-Butyl-2-methylcyclopentane [53366-35-1] C10H20 MW = 140.27 168

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 784.7 0.80 56-baz/sok

(1-Ethylpropyl)cyclopentane [700001-38-3] C10H20 MW = 140.27 169

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 1.603.
Coefficient = A + BT
A 1043.13
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

292.15 811.6 1.00 2.19 36-kaz/pla-1


293.15 809.9 0.80 1.29 39-gro/wac
293.15 807.1 0.60 -1.51 39-pin/ipa

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 811.1 2.5
293.15 808.6 2.0
298.15 804.6 3.0

4-Ethyl-1,1,2-trimethylcyclopentane [91351-91-6] C10H20 MW = 140.27 170

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 778.2 2.00 63-lev/sha

1-Butyl-3-methylcyclopentane [500030-24-0] C10H20 MW = 140.27 171

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 784.0 4.00 30-cha/mil

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 125

1,1-Dimethyl-2-(1-methylethyl) [500025-87-6] C10H20 MW = 140.27 172


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 795.9 0.80 49-ste/spa

1,2-Dimethyl-3-(1-methylethyl) [489-20-3] C10H20 MW = 140.27 173


cyclopentane

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 2.046.
Coefficient = A + BT
A 1022.63
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

289.15 786.0 3.00 -5.31 13-god/tab-1


288.15 793.0 2.00 0.89 21-god
294.15 788.0 2.00 0.69 29-kaz
288.15 792.9 2.00 0.79 31-ric/wol

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 798.6 2.5
290.00 790.6 2.5
293.15 788.1 2.5
298.15 784.1 3.0

r-1, t-2-Dimethyl-c-3-(1-methylethyl) [36208-14-7] C10H20 MW = 140.27 174


cyclopentane

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 0.688.
Coefficient = A + BT
A 1022.69
B -0.800

cont.

Landolt-Brnstein
New Series IV/8D
126 2.6 Alkylcycloalkanes (CnH2n), C10

r-1, t-2-Dimethyl-c-3-(1-methylethyl)cyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

294.15 787.7 1.00 0.33 29-kaz


294.15 788.3 1.00 0.93 29-kaz
288.15 792.9 1.00 0.73 31-ric/wol
293.15 788.2 0.60 0.03 53-ipa/hun
293.15 787.2 0.60 -0.97 54-pin/hof
293.15 788.8 1.00 0.63 57-ish/kog

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 798.7 1.0
290.00 790.7 1.0
293.15 788.2 1.0
298.15 784.2 1.5

r-1, c-2-Dimethyl, c-3-(1-methylethyl) [36208-17-0] C10H20 MW = 140.27 175


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 804.0 0.60 54-pin/hof

(1,1-Dimethylpropyl)cyclopentane [66291-56-3] C10H20 MW = 140.27 176

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1024.03
B -0.740

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 807.1 0.80 0.00 39-gro/wac


293.15 807.1 1.00 0.00 39-pin/ipa-1
313.15 792.3 1.00 0.00 39-pin/ipa-1
cont.

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 127

(1,1-Dimethylpropyl)cyclopentane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 809.4 1.0
293.15 807.1 1.0
298.15 803.4 1.0
310.00 794.6 1.0
320.00 787.2 1.5

(1-Methylbutyl)cyclopentane [4737-43-3] C10H20 MW = 140.27 177

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 809.9 2.00 00-pin/ipa
313.15 795.5 2.00 00-pin/ipa
293.15 798.7 0.40 49-foe/fen

(3-Methylbutyl)cyclopentane [1005-68-1] C10H20 MW = 140.27 178

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.372.
Coefficient = A + BT
A 1022.10
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

298.15 783.7 0.60 0.12 29-har


293.65 786.8 0.60 -0.38 36-kaz/pla
293.15 787.5 0.80 -0.08 57-shu/che
293.15 788.4 1.00 0.82 57-shu/che

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 790.1 1.0
293.15 787.6 0.7
298.15 783.6 0.6
300.00 782.1 1.0

Landolt-Brnstein
New Series IV/8D
128 2.6 Alkylcycloalkanes (CnH2n), C10

1,1,3,3,4-Pentamethylcyclopentane [500031-17-4] C10H20 MW = 140.27 179

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 767.4 1.00 62-lev/sha-1

Pentylcyclopentane [3741-00-2] C10H20 MW = 140.27 180

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 4.947.
Coefficient = A + BT
A 1025.33
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 802.0 2.00 11.19 27-bau


284.15 816.0 4.00 17.99 29-str-1
293.15 789.8 1.00 -1.01 39-pla
293.15 789.3 1.00 -1.51 39-pla
293.15 785.2 2.00 -5.61 46-baz/ste

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 801.3 5.0
290.00 793.3 4.9
293.15 790.8 4.9
298.15 786.8 5.0

2.6.3 Cyclohexanes

Butylcyclohexane [1678-93-9] C 10H20 MW = 140.27 181

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.7731 10-1 (combined temperature ranges,
weighted), c,uw = 7.5910 10-2 (combined
temperature ranges, unweighted).
T = 288.15 to 333.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.12702 103
B -1.46341
C 1.17912 10-3
cont.

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 129

Butylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

288.15 803.70 1.00 0.46 32-gar/eva( ) 298.15 795.49 0.15 -0.03 49-for/ros( )
293.15 800.50 1.00 1.15 32-gar/eva1) 303.15 791.74 0.15 -0.01 49-for/ros( )
288.15 803.70 1.00 0.46 38-eva( ) 293.15 799.20 0.60 -0.15 59-dix-1( )
293.15 800.50 1.00 1.15 38-eva1) 313.15 784.50 0.60 0.12 59-dix-1( )
293.15 799.30 0.50 -0.05 43-ano-3( ) 333.15 769.80 0.60 -0.55 59-dix-1( )
293.15 799.40 0.30 0.05 45-boo/gre() 293.15 799.25 0.20 -0.10 87-hol/goe( ) {
293.15 799.40 0.50 0.05 46-boo/gre() 298.15 795.46 0.20 -0.06 94-del/fer()
293.15 799.16 0.15 -0.19 49-for/ros( )
1) Not included in Fig. 1.

Further references: [27-bou, 29-str-1, 33-sig/cra, 37-lev/pot, 39-loz/dya, 40-sch/gro, 42-sch, 49-boo/hen,
49-lut, 51-sch, 54-naz/kak-1].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
130 2.6 Alkylcycloalkanes (CnH2n), C10

Butylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 809.71 2.98 298.15 795.52 0.16 320.00 779.47 0.96
290.00 801.79 0.73 300.00 794.12 0.15 330.00 772.50 0.94
293.15 799.35 0.39 310.00 786.68 0.47 340.00 765.77 0.64

(R)-(+)-(1-Methylpropyl)cyclohexane [29916-19-6] C10H20 MW = 140.27 182

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 1.173.
Coefficient = A + BT
A 1076.20
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

300.15 805.0 3.00 -1.07 32-lev/mar-1


295.15 810.0 3.00 -0.57 32-lev/mar-1
293.15 814.0 3.00 1.63 35-lev/har

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 815.2 3.5
293.15 812.4 3.0
298.15 807.9 3.0
310.00 797.2 4.0

1,1-Diethylcyclohexane [78-01-3] C10H20 MW = 140.27 183

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 824.9 1.00 57-khr/bal

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 131

1,3-Diethylcyclohexane [1678-99-5] C10H20 MW = 140.27 184

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 2.812.
Coefficient = A + BT
A 1063.57
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

295.15 795.7 2.00 -2.23 1895-zel/rud


284.15 811.8 2.00 3.97 29-str-1
293.15 798.0 2.00 -1.73 33-sig/cra

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 811.6 3.0
290.00 802.6 2.8
293.15 799.7 2.8
298.15 795.2 2.9

1,4-Diethylcyclohexane [1679-00-1] C10H20 MW = 140.27 185

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 800.0 2.00 33-sig/cra

cis-1,4-Diethylcyclohexane [13990-92-6] C10H20 MW = 140.27 186

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

310.93 794.9 1.20 63-gud/cam

Landolt-Brnstein
New Series IV/8D
132 2.6 Alkylcycloalkanes (CnH2n), C10

(1,1-Dimethylethyl)cyclohexane [3178-22-1] C10H20 MW = 140.27 187

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8615 10-1 (combined temperature ranges,
weighted), c,uw = 1.4884 10-1 (combined
temperature ranges, unweighted).
T = 284.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04183 103
B -7.80906 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

284.15 820.50 2.00 0.57 29-str-1() 298.15 808.88 0.15 -0.12 49-for/ros( )
293.15 812.70 0.30 -0.21 {
44-boo/per( ) 303.15 805.11 0.15 0.01 49-for/ros( )
293.15 812.65 0.15 -0.26
49-for/ros( )
1) Not included in Fig. 1.
Further references: [63-gud/cam].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 133

(1,1-Dimethylethyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 823.17 4.14 293.15 812.91 0.23 300.00 807.56 0.19
290.00 815.36 0.52 298.15 809.00 0.16 310.00 799.75 0.25

1-Ethyl-1,3-dimethylcyclohexane [500032-69-9] C10H20 MW = 140.27 188

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m
3

293.15 800.5 1.00 54-lev/shu

1-Ethyl-3,5-dimethylcyclohexane [7045-68-3] C10H20 MW = 140.27 189

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.463.
Coefficient = A + BT
A 1012.12
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

293.15 792.8 2.00 0.54 1893-sub


273.15 807.2 2.00 -0.06 1893-sub
288.15 795.3 2.00 -0.71 1898-rud
273.15 807.5 2.00 0.24 1898-rud

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 809.6 2.0
280.00 802.1 2.0
290.00 794.6 2.0
293.15 792.3 2.0
298.15 788.5 2.5

Landolt-Brnstein
New Series IV/8D
134 2.6 Alkylcycloalkanes (CnH2n), C10

1-Methyl-1-(1-methylethyl)cyclohexane [16580-26-0] C10H20 MW = 140.27 190

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 826.1 0.80 55-pin/mar

d-1-Methyl-2-(1-methylethyl) [500030-52-4] C10H20 MW = 140.27 191


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 829.7 1.00 24-wei/sch

1-Methyl-2-(1-methylethyl)cyclohexane [16580-23-7] C10H20 MW = 140.27 192

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 3.335.
Coefficient = A + BT
A 1062.28
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 832.5 1.50 2.37 13-sab/mur-1


294.15 813.4 1.50 1.12 13-sab/mur-1
293.15 806.9 2.00 -6.20 66-sad/akh

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 832.8 3.4
280.00 824.3 3.3
290.00 815.8 3.3
293.15 813.1 3.4
298.15 808.9 3.4

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 135

d-1-Methyl-3-(1-methylethyl) [500030-75-1] C10H20 MW = 140.27 193


cyclohexane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
794.7 3.00 11-kis
1)
293.15
823.4 3.00 13-sab/mur
1)
273.15
1)
Not included in fit of 1-methyl-3-(1-methylethyl)cyclohexane.

l-1-Methyl-3-(1-methylethyl) [500030-76-2] C10H20 MW = 140.27 194


cyclohexane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
793.7 2.00 11-kis/sav
1)
293.15
807.7 2.00 11-kis/sav
1)
273.15
1)
Included in fit of 1-methyl-3-(1-methylethyl)cyclohexane.

1-Methyl-3-(1-methylethyl)cyclohexane [16580-24-8] C10H20 MW = 140.27 195

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 6.564.
Coefficient = A + BT
A 1062.51
B -0.900
Table 2. Experimental values with uncertainties and
deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

287.15 803.3 2.00 -0.77 01-sab/sen-1


297.15 796.4 3.00 1.30 13-sab/mur-11)
273.15 823.3 2.00 6.60 13-sab/mur-1
296.15 811.5 5.00 15.50 13-sab/mur-11)
293.15 806.8 2.00 8.13 66-sad/akh
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 819.5 6.7
280.00 810.5 6.6
290.00 801.5 6.6
293.15 798.7 6.6
298.15 794.2 6.7

Landolt-Brnstein
New Series IV/8D
136 2.6 Alkylcycloalkanes (CnH2n), C10

1-Methyl-4-(1-methylethyl)cyclohexane [99-82-1] C10H20 MW = 140.27 196

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 7.7722 (combined temperature ranges,
weighted), c,uw = 1.9446 (combined
temperature ranges, unweighted).
T = 273.15 to 352.35 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.00813 103
B -7.09194 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 805.60 4.00 -8.82 1887-kon( ) 298.15 806.10 2.50 9.41 28-ada/mar( ) {
293.15 793.00 4.00 -7.23 1887-kon1) 293.15 796.00 3.00 -4.23 37-dya/loz1)
273.15 806.60 6.00 -7.82 1894-wag( ) 293.15 796.00 2.50 -4.23 37-loz/dya()
273.15 813.20 3.00 -1.22 01-sab/sen() 293.15 799.30 2.50 -0.93 47-boo/gre( )
293.05 790.40 4.00 -9.90 06-eyk-11) 293.15 798.70 2.50 -1.53 47-boo/gre( )
293.25 790.40 4.00 -9.76 06-eyk-11) 301.15 808.30 3.00 13.74 47-son/bhu( )
352.35 744.80 4.00 -13.45 06-eyk-1( ) 298.15 808.30 3.00 11.61 47-son/bhu-1( )
288.15 802.23 3.00 -1.55 09-vav( ) 293.15 800.20 2.50 -0.03 49-boo/gre()
273.15 813.27 3.50 -1.15 13-sab/mur-1( ) 293.15 800.20 2.60 -0.03 49-boo/gre()
298.15 802.67 3.50 5.98 13-sab/mur-1( )
1) Not included in Fig. 1.
Further references: [09-smi, 12-kis-3, 31-ric/wol, 36-bro/dur, 41-ano-1, 46-ano-2, 49-ano-1, 50-her/ruz,
66-sad/akh].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 816.65 5.20 298.15 796.69 3.10 330.00 774.10 6.30
280.00 809.56 3.30 300.00 795.37 3.50 340.00 767.01 7.30
290.00 802.47 2.61 310.00 788.28 4.60 350.00 759.91 8.30
293.15 800.23 3.00 320.00 781.19 5.80 360.00 752.82 10.0

cont.

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 137

1-Methyl-4-(1-methylethyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cis-1-Methyl-4-(1-methylethyl) [6069-98-3] C10H20 MW = 140.27 197


cyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 816.0 2.00 22-ski/sch
293.15 807.6 0.80 53-ano-1
293.15 808.6 0.70 54-oco/gol
293.15 808.7 0.7 Recommended

Landolt-Brnstein
New Series IV/8D
138 2.6 Alkylcycloalkanes (CnH2n), C10

trans-1-Methyl-4-(1-methylethyl) [1678-82-6] C10H20 MW = 140.27 198


cyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 792.0 2.00 22-ski/sch
293.15 795.0 1.00 34-war/ful
293.15 792.4 0.70 53-ano-1
293.15 793.2 0.70 54-oco/gol
293.15 793.2 0.7 Recommended

(1-Methylpropyl)cyclohexane [7058-01-7] C10H20 MW = 140.27 199

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.8366 10-2 (combined temperature ranges,
weighted), c,uw = 3.7968 10-2 (combined
temperature ranges, unweighted).
T = 293.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03394 103
B -7.53139 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 813.10 0.60 -0.06 45-gre-2() 298.15 809.33 0.15 -0.06 49-for/ros( )
293.15 813.30 0.50 0.14 46-ano( ){ 303.15 805.63 0.15 0.01 49-for/ros( )
293.15 813.12 0.15 -0.04 49-for/ros( )
1) Not included in Fig. 1.
Further references: [29-str-1, 32-lev/mar-1, 33-sig/cra].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 815.53 0.73 298.15 809.39 0.15 310.00 800.47 0.64
293.15 813.16 0.42 300.00 808.00 0.14

cont.

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 139

(1-Methylpropyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(2-Methylpropyl)cyclohexane [1678-98-4] C10H20 MW = 140.27 200

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 0.042.
Coefficient = A + BT
A 1020.94
B -0.770

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3 kg m3 K kg m3 kg m3

293.15 795.0 2.00 -0.22 25-eis/gor 293.15 795.3 0.40 0.08 49-boo/hen
293.15 785.3 5.00 -9.92 33-sig/cra 1) 293.15 795.19 0.15 -0.03 49-for/ros
293.15 795.3 0.30 0.08 45-boo/gre 298.15 791.39 0.15 0.02 49-for/ros
293.15 795.3 0.50 0.08 46-boo/gre 303.15 787.48 0.15 -0.04 49-for/ros
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
140 2.6 Alkylcycloalkanes (CnH2n), C10

(2-Methylpropyl)cyclohexane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 797.6 0.2
293.15 795.2 0.1
298.15 791.4 0.1
310.00 782.2 0.3

1-Methyl-1-propylcyclohexane [4258-93-9] C10H20 MW = 140.27 201

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 807.7 1.00 54-khr/bal-3
293.15 810.1 0.80 55-pin/mar
824.3 5.00 57-khr/bal
1)
293.15
293.15 810.1 1.00 66-khr/koc
293.15 809.4 0.9 Recommended
1)
Not included in calculation of recommended value.

1-Methyl-2-propylcyclohexane [4291-79-6] C10H20 MW = 140.27 202

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 2.352.
Coefficient = A + BT
A 1058.58
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

292.15 813.0 2.00 2.74 32-kuh/deu


293.15 808.0 2.00 -1.41 33-sig/cra
293.15 806.4 3.00 -3.01 39-loz/dya

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 812.1 2.4
293.15 809.4 2.4
298.15 805.2 2.4

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 141

cis-1-Methyl-2-propylcyclohexane [4926-71-0] C10H20 MW = 140.27 203

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 812.6 0.40 56-ano

trans-1-Methyl-2-propylcyclohexane [42806-77-9] C10H20 MW = 140.27 204

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 799.9 0.40 56-ano

1-Methyl-3-propylcyclohexane [4291-80-9] C10H20 MW = 140.27 205

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 794.0 2.00 33-sig/cra
298.15 781.0 3.00 38-mou/gra

cis-1-Methyl-3-propylcyclohexane [42806-75-7] C10H20 MW = 140.27 206

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
298.15 791.0 3.00 38-mou/gra
298.15 791.0 3.00 39-mou/pau

trans-1-Methyl-3-propylcyclohexane [34522-19-5] C10H20 MW = 140.27 207

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 792.0 2.00 38-mou/gra

1-Methyl-4-propylcyclohexane [4291-81-0] C10H20 MW = 140.27 208

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 796.0 2.00 33-sig/cra

Landolt-Brnstein
New Series IV/8D
142 2.6 Alkylcycloalkanes (CnH2n), C10

1,1,3,4-Tetramethylcyclohexane [500032-70-2] C10H20 MW = 140.27 209

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 797.6 1.00 54-chi/maq

cis-1,1,3,5-Tetramethylcyclohexane [50876-32-9] C10H20 MW = 140.27 210

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 781.3 1.00 54-chi/maq

trans-1,1,3,5-Tetramethylcyclohexane [50876-31-8] C10H20 MW = 140.27 211

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 792.9 1.00 54-chi/maq

1,2,3,4-Tetramethylcyclohexane [3726-45-2] C10H20 MW = 140.27 212

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 821.9 2.00 33-mit/mar

1,2,3,5-Tetramethylcyclohexane [3726-36-1] C10H20 MW = 140.27 213

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 816.6 2.00 25-eis/gor
293.15 814.0 2.00 25-eis/gor
293.15 815.3 2.2 Recommended

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 143

1,2,4,5-Tetramethylcyclohexane [2090-38-2] C10H20 MW = 140.27 214

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.1019 101 (combined temperature ranges,
weighted), c,uw = 3.9070 (combined
temperature ranges, unweighted).
T = 273.15 to 343.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.05204 103
B -8.50015 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 825.00 4.00 5.14 12-wil/hat() 293.15 810.00 7.00 7.14 25-eis/gor()
293.15 811.00 4.00 8.14 12-wil/hat() 293.15 793.40 3.00 -9.46 37-loz/dya( ) {
286.25 791.00 3.00 -17.73 20-von-2( ) 343.15 757.80 3.00 -2.56 37-loz/dya( ) {
293.15 812.20 7.00 9.34 25-eis/gor()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
144 2.6 Alkylcycloalkanes (CnH2n), C10

1,2,4,5-Tetramethylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 822.54 5.93 298.15 798.61 7.51 330.00 771.54 14.95
280.00 814.04 2.59 300.00 797.04 8.42 340.00 763.04 7.57
290.00 805.54 4.08 310.00 788.54 13.21 350.00 754.54 3.14
293.15 802.86 5.25 320.00 780.04 16.14

2.6.4 Cycloheptanes - Cyclodecane

Propylcycloheptane [13705-36-7] C 10H20 MW = 140.27 215

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
291.15 817.5 2.00 06-zel

1,1,2-Trimethylcycloheptane [35099-89-9] C10H20 MW = 140.27 216

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 824.3 2.00 36-ruz/sei

1,1,4-Trimethylcycloheptane [2158-55-6] C10H20 MW = 140.27 217

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 801.1 1.00 36-ruz/sei

Ethylcyclooctane [13152-02-8] C10H20 MW = 140.27 218

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
298.15 832.8 1.00 51-cra/lar
293.15 837.6 1.00 52-hag

Landolt-Brnstein
New Series IV/8D
2.6 Alkylcycloalkanes (CnH2n), C10 145

Cyclodecane [293-96-9] C10H20 MW = 140.27 219

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.1920 10-1 (combined temperature ranges,
weighted), c,uw = 1.2011 10-1 (combined
temperature ranges, unweighted).
T = 293.15 to 439.40 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.29173 103
B -2.61827
C 5.41046 10-3
D -5.19182 10-6

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 857.70 0.40 -0.65 44-pla/hul() 319.10 838.22 0.40 -0.24 85-mcl/bar()
293.15 857.50 0.40 -0.85 44-pla/hul() 327.23 832.14 0.60 -0.24 85-mcl/bar()
293.15 857.50 0.40 -0.85 52-blo/bur() 335.73 825.80 0.60 -0.27 85-mcl/bar()
294.82 857.23 0.10 0.19 76-mey/hot( ) 344.39 819.35 0.80 -0.31 85-mcl/bar()
307.72 847.33 0.10 0.25 76-mey/hot( ) 353.37 812.66 0.80 -0.37 85-mcl/bar()
322.28 836.27 0.10 0.19 76-mey/hot( ) 362.39 806.00 1.00 -0.35 85-mcl/bar()
339.39 823.42 0.10 0.06 76-mey/hot( ) 372.18 798.71 1.00 -0.34 85-mcl/bar()
352.56 813.63 0.10 0.00 76-mey/hot( ) 381.95 791.43 1.50 -0.27 85-mcl/bar()
366.88 802.99 0.11 -0.02 76-mey/hot( ) 393.21 782.92 1.50 -0.17 85-mcl/bar()
385.16 789.38 0.13 0.12 76-mey/hot( ) 404.15 774.70 1.50 0.14 85-mcl/bar()
404.42 774.92 0.15 0.57 76-mey/hot( ) 415.44 766.13 2.00 0.60 85-mcl/bar()
298.15 854.69 0.20 0.24 81-mar/sym( ){ 427.12 757.15 2.00 1.24 85-mcl/bar()
298.84 853.62 0.40 -0.29 85-mcl/bar() 439.40 747.60 2.00 2.18 85-mcl/bar()
302.84 850.49 0.40 -0.33 85-mcl/bar() 464.95 727.16 2.00 5.01 85-mcl/bar1)
311.25 844.14 0.40 -0.25 85-mcl/bar()
1) Not included in Fig. 1.

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 860.83 0.36 340.00 822.91 0.43 400.00 777.82 1.20
293.15 858.35 0.34 350.00 815.52 0.51 410.00 769.91 1.40
298.15 854.45 0.33 360.00 808.12 0.60 420.00 761.81 1.63
300.00 853.01 0.32 370.00 800.68 0.72 430.00 753.48 1.88
310.00 845.34 0.32 380.00 793.17 0.86 440.00 744.90 2.16
320.00 837.79 0.33 390.00 785.56 1.02 450.00 736.02 2.48
330.00 830.32 0.37
cont.

Landolt-Brnstein
New Series IV/8D
146 2.6 Alkylcycloalkanes (CnH2n), C10 - 2.7 Alkylcycloalkanes (CnH2n), C11

Cyclodecane (cont.)

Further references: [33-huc/ger].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

2.7 Alkylcycloalkanes (CnH2n), C11


2.7.1 Cyclopropanes - Cyclobutanes

1,1-Dimethyl-2-(1,1-dimethylbutyl) [500023-52-6] C10H20 MW = 140.27 220


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 777.6 1.00 65-lev/kos

Landolt-Brnstein
New Series IV/8D
2.7 Alkylcycloalkanes (CnH2n), C11 147

1,1-Dimethyl-2-hexylcyclopropane [41845-49-2] C11H22 MW = 154.30 221

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 761.2 0.70 60-kac/tog

2.7.2 Cyclopentanes

Hexylcyclopentane [4457-00-5] C 11H22 MW = 154.30 222

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 790.3 2.00 33-zel/mic
293.15 795.7 0.70 39-pla
293.15 795.6 0.70 39-pla
293.15 795.7 0.7 Recommended

4-(1-Methylethyl)-1,1,2- [91242-58-9] C11H22 MW = 154.30 223


trimethylcyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 786.3 2.00 63-lev/sha

l-(1-Methylbutyl)cyclopentane [500030-78-4] C11H22 MW = 154.30 224

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
298.15 823.0 3.00 32-lev/mar-1
300.15 814.0 3.00 32-lev/mar-1

4-(1-Methylethyl)-1,2,3-trimethyl- [500030-25-1] C11H22 MW = 154.30 225


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
286.15 783.3 2.00 21-god

Landolt-Brnstein
New Series IV/8D
148 2.7 Alkylcycloalkanes (CnH2n), C11

4-Propyl-1,1,2-trimethylcyclopentane [91242-59-0] C11H22 MW = 154.30 226

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 788.6 2.00 63-lev/sha

2.7.3 Cyclohexanes

1-Butyl-1-methylcyclohexane [5009-92-7] C11H22 MW = 154.30 227

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 813.3 1.00 54-khr/bal

1-Butyl-2-methylcyclohexane [72993-33-0] C11H22 MW = 154.30 228

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 811.0 2.00 33-sig/cra

1-Butyl-3-methylcyclohexane [52829-83-1] C11H22 MW = 154.30 229

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 799.0 2.00 33-sig/cra

1-Butyl-4-methylcyclohexane [500018-96-4] C11H22 MW = 154.30 230

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 805.0 2.00 33-sig/cra

1-(1,1-Dimethylethyl)- [61828-22-6] C11H22 MW = 154.30 231


2-methylcyclohexane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 831.5 3.0 49-ser/wis

[73908-41-5] C11H22 MW = 154.30 232


Landolt-Brnstein
New Series IV/8D
2.7 Alkylcycloalkanes (CnH2n), C11 149

1-(1,1-Dimethylethyl)-
3-methylcyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 817.6 3.00 49-ser/wis
293 15 808.3 3.00 49-ser/wis
293.15 813.0 6.00 Recommended

1-(1,1-Dimethylethyl)- 75736-66-2 C11H22 MW = 154.30 233


4-methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.2 3.0 49-ser/wis

cis-1-(1,1-Dimethylethyl)- [3325-80-2] C11H22 MW = 154.30 234


4-methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.3 1.00 64-lib/ler

trans-1-(1,1-Dimethylethyl)- [4001-94-9] C11H22 MW = 154.30 235


4-methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 801.6 1.00 64-lib/ler

1,2-Dimethyl-4-(1-methylethyl) [99993-31-4] C11H22 MW = 154.30 236


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
290.15 820.0 2.00 54-cle

Landolt-Brnstein
New Series IV/8D
150 2.7 Alkylcycloalkanes (CnH2n), C11

1,3-Dimethyl-5-(1-methylethyl) [16580-28-2] C11H22 MW = 154.30 237


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 807.8 3.0 66-sad/akh

2,3-Dimethyl-1-(1-methylethyl) [16580-27-1] C11H22 MW = 154.30 238


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 816.3 3.0 66-sad/akh

(1,1-Dimethylpropyl)cyclohexane [31797-64-5] C11H22 MW = 154.30 239

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 2.551.
Coefficient = A + BT
A 1076.90
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

289.15 822.6 1.00 -8.52 15-hal


293.15 819.6 2.00 -8.12 33-sig/cra1)
293.15 828.5 0.70 0.78 50-ano-1
293.15 828.4 0.70 0.68 52-ano-14
293.15 828.7 0.80 0.98 52-ina/gre
293.15 828.8 0.80 1.08 52-ina/gre
293.15 828.3 0.50 0.58 50-boo/gre
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 838.9 5.0
290.00 830.4 2.6
293.15 827.7 2.6
298.15 823.5 4.0

Landolt-Brnstein
New Series IV/8D
2.7 Alkylcycloalkanes (CnH2n), C11 151

(2,2-Dimethylpropyl)cyclohexane [25446-34-8] C11H22 MW = 154.30 240

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.005.
Coefficient = A + BT
A 1024.65
B -0.770

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 798.9 1.00 0.00 00-pin/ipa


313.15 783.5 1.00 -0.00 00-pin/ipa

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 801.4 1.5
293.15 798.9 1.0
298.15 795.1 1.0
310.00 786.0 1.0
320.00 778.3 2.0

1,3-Dimethyl-1-propylcyclohexane [500027-65-6] C11H22 MW = 154.30 241

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 806.5 1.00 54-lev/shu

1-Ethyl-2-(1-methylethyl)cyclohexane [16580-30-6] C11H22 MW = 154.30 242

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 825.1 3.0 66-sad/akh

1-Ethyl-2-propylcyclohexane [62238-33-9] C11H22 MW = 154.30 243

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 818.1 3.0 57-els/str-2

Landolt-Brnstein
New Series IV/8D
152 2.7 Alkylcycloalkanes (CnH2n), C11

1-Ethyl-1,3,5-trimethylcyclohexane [500027-66-7] C11H22 MW = 154.30 244

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 803.5 3.0 56-lev/gir

(1-Methylbutyl)cyclohexane [61208-94-4] C11H22 MW = 154.30 245

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
300.15 814.0 2.00 32-lev/mar-1

(3-Methylbutyl)cyclohexane [54105-76-9] C11H22 MW = 154.30 246

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
813.6 4.00 29-str-1
1)
284.15
293.15 798.0 2.00 33-sig/cra
823.5 4.00 36-nen/cio-1
1)
293.15
293.15 802.3 2.00 39-loz/dya
293.15 792.2 1.00 42-lev
293.15 794.9 2.4 Recommended
1)
Not included in calculation of linear coefficients.

1,1,3,3,5-Pentamethylcyclohexane [70810-19-4] C11H22 MW = 154.30 247

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 793.2 1.00 54-chi/maq

1,2,3,4,5-Pentamethylcyclohexane [1839-64-1] C11H22 MW = 154.30 248

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
295.15 783.8 6.00 13-pic/bou
284.15 808.1 2.00 29-str-1
293.15 820.0 0.50 37-loz/dya

Landolt-Brnstein
New Series IV/8D
2.7 Alkylcycloalkanes (CnH2n), C11 153

Pentylcyclohexane [4292-92-6] C11H22 MW = 154.30 249

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.687.
Coefficient = A + BT
A 1052.00
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 802.0 2.00 -0.83 27-bou


284.15 816.0 4.00 5.52 29-str-1
293.15 802.6 2.00 -0.23 33-sig/cra
293.15 801.8 2.00 -1.03 39-lev/gol
293.15 804.4 3.00 1.57 39-loz/dya

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 814.0 5.0
290.00 805.5 2.0
293.15 802.8 2.0
298.15 798.6 3.0

2.7.4 Cycloheptanes - Cycloundecane

Butylcycloheptane [13152-41-5] C 11H22 MW = 154.30 250

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 819.5 0.80 54-khr/bal-2

Propylcyclooctane [500028-16-0] C11H22 MW = 154.30 251

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 887.0 2.00 52-cop/cam

Landolt-Brnstein
New Series IV/8D
154 2.7 Alkylcycloalkanes (CnH2n), C11 - 2.8 Alkylcycloalkanes (CnH2n), C12

Cycloundecane [294-41-7] C11H22 MW = 154.30 252

Table 1. Experimental values with uncertainties


T exp 2 est Ref.
3
K kg m
287.15 800.2 10.00 1883-mar/ogl-2
273.15 811.9 10.00 1883-mar/ogl-2
293.15 812.8 5.00 30-kom

2.8 Alkylcycloalkanes (CnH2n), C12


2.8.1 Cyclopropanes - Cyclopentanes

Heptylcyclopentane [5617-42-5] C 12H24 MW = 168.32 253

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 0.175.
Coefficient = A + BT
A 1021.19
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 800.2 0.70 -1.13 39-pla


293.15 801.3 0.60 -0.01 61-jes/sta
298.15 797.8 0.60 0.20 61-jes/sta
293.15 801.3 0.30 -0.03 63-mea/sta
298.15 797.8 0.30 0.18 63-mea/sta

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 803.7 0.4
293.15 801.3 0.3
298.15 797.6 0.3

1-Methyl-2,3-bis(1-methylethyl) [500030-26-2] C12H24 MW = 168.32 254


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
290.15 781.0 2.00 13-god/tab-1

Landolt-Brnstein
New Series IV/8D
2.8 Alkylcycloalkanes (CnH2n), C12 155

(1-Methylhexyl)cyclopentane [89216-54-6] C12H24 MW = 168.32 255

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 535.7 0.60 49-foe/fen

(1-Propylbutyl)cyclopentane [5617-43-6] C12H24 MW = 168.32 256

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 812.4 1.00 49-kaz/gak

2.8.2 Cyclohexanes

1,4-Diethyl-2,3-dimethylcyclohexane [91695-26-0] C12H24 MW = 168.32 257

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 853.6 2.00 33-mit/mar

(1,1-Dimethylbutyl)cyclohexane [500030-80-0] C12H24 MW = 168.32 258

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.15 837.2 2.00 15-hal

(1,2-Dimethylbutyl)cyclohexane [61142-37-8] C12H24 MW = 168.32 259

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.15 837.2 2.00 15-hal

cis-1-(1,1-Dimethylethyl)- [1129-24-4] C12H24 MW = 168.32 260


4-ethylcyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 820.3 1.00 64-lib/ler
293.15 825.3 2.00 65-lib/ler
293.15 821.3 2.0 Recommended

Landolt-Brnstein
New Series IV/8D
156 2.8 Alkylcycloalkanes (CnH2n), C12

trans-1-(1,1-Dimethylethyl)- [1129-23-3] C12H24 MW = 168.32 261


4-ethylcyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 814.2 1.00 64-lib/ler
293.15 812.8 2.00 65-lib/ler
293.15 813.9 2.0 Recommended

1,3-Dimethyl-5-(2-methylpropyl) [500030-82-2] C12H24 MW = 168.32 262


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
273.15 822.7 2.00 06-sab/sen

1,2-Dipropylcyclohexane [105946-02-9] C12H24 MW = 168.32 263

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 818.8 4.00 57-els/str-2

(1-Ethylbutyl)cyclohexane [4456-99-9] C12H24 MW = 168.32 264

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
296.15 823.0 2.00 32-lev/mar-1
292.15 838.0 2.00 45-pet/kru
293.15 823.3 0.30 53-lam/wis

(2-Ethylbutyl)cyclohexane [61828-23-7] C12H24 MW = 168.32 265

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 817.3 0.30 53-lam/wis

Landolt-Brnstein
New Series IV/8D
2.8 Alkylcycloalkanes (CnH2n), C12 157

(1-Ethyl-1-methylpropyl)cyclohexane [500027-67-8] C12H24 MW = 168.32 266

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.15 831.0 1.00 15-hal

1-Ethyl-2-(1-methylethyl)- [500030-83-1] C12H24 MW = 168.32 267


5-methylcyclohexane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 1.700.
Coefficient = A + BT
A 1034.06
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 815.9 4.00 1.70 01-kur


273.15 827.5 4.00 -1.70 01-kur

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 831.6 5.0
280.00 824.1 4.0
290.00 816.6 4.0
293.15 814.2 4.0
298.15 810.5 5.0

Hexamethylcyclohexane [51345-51-8] C12H24 MW = 168.32 268

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 819.4 4.0 54-chi/maq

1,2,3,4,5,6-Hexamethylcyclohexane [1795-13-7] C12H24 MW = 168.32 269

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 840.5 5.0 37-dya/loz
293.15 840.5 3.0 37-loz/dya

Landolt-Brnstein
New Series IV/8D
158 2.8 Alkylcycloalkanes (CnH2n), C12

Hexylcyclohexane [4292-75-5] C12H24 MW = 168.32 270

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.175.
Coefficient = A + BT
A 1042.85
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 806.0 2.00 -2.33 27-bou1)


293.15 806.0 2.00 -2.33 51-sch1)
293.15 808.2 0.60 -0.16 61-jes/sta
298.15 804.5 0.60 0.19 61-jes/sta
293.15 808.1 0.30 -0.18 63-mea/sta
298.15 804.5 0.30 0.17 63-mea/sta
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 810.8 1.0
293.15 808.3 0.8
298.15 804.3 0.4

1,4-bis(1-Methylethyl)cyclohexane [22907-72-8] C12H24 MW = 168.32 271

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m 3

293.15 814.5 3.00 52-mek/kam


293.15 823.6 2.00 56-lib/lap
293.15 814.3 2.00 56-lib/lap
293.15 818.1 3.2 Recommended

4-(1-Methylethyl)-1,2,4- [500027-69-0] C12H24 MW = 168.32 272


trimethylcyclohexane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m 3

293.15 837.5 5.00 38-far/pit


293.15 789.2 30.0 56-ano

Landolt-Brnstein
New Series IV/8D
2.8 Alkylcycloalkanes (CnH2n), C12 159

1-Methyl-2-(3-methylbutyl)cyclohexane [500030-81-1] C12H24 MW = 168.32 273

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
273.15 825.0 6.00 09-mur
290.15 825.0 6.00 09-mur

(1-Methylpentyl)cyclohexane [66553-51-3] C12H24 MW = 168.32 274

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 823.0 2.00 32-lev/mar-1

(3-Methylpentyl)cyclohexane [61142-38-9] C12H24 MW = 168.32 275

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
300.15 806.0 3.00 35-lev/mar-2

1-Methyl-2-pentylcyclohexane [54411-01-7] C12H24 MW = 168.32 276

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 814.0 4.00 33-sig/cra
293.15 814.4 3.00 52-col/ber
293.15 814.3 3.0 Recommended

1,3,5-Trimethyl-1-propylcyclohexane [500027-68-9] C12H24 MW = 168.32 277

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 808.7 4.00 56-lev/gir

r-1, c-3, c-5-Triethylcyclohexane [500032-66-6] C12H24 MW = 168.32 278

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 806.9 0.70 51-chi

Landolt-Brnstein
New Series IV/8D
160 2.8 Alkylcycloalkanes (CnH2n), C12

r-1, t-3, c-5-Triethylcyclohexane [500032-67-7] C12H24 MW = 168.32 279

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 808.1 0.60 51-chi

2.8.3 Cycloheptanes - Cycloundodecane

Butylcyclooctane [16538-93-5] C12H24 MW = 168.32 280

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 826.1 1.00 52-cop/van

Cyclododecane [294-62-2] C12H24 MW = 168.32 281

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.3087 10-1 (combined temperature ranges,
weighted), c,uw = 1.6725 10-1 (combined
temperature ranges, unweighted).
T = 339.30 to 406.50 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.05315 103
B -6.58616 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

339.30 829.40 0.17 -0.29 76-mey/hot( ) 375.81 805.80 0.17 0.16 76-mey/hot( )
346.52 824.60 0.17 -0.33 76-mey/hot( ) 385.64 800.00 0.17 0.83 76-mey/hot( )
356.81 818.50 0.17 0.35 76-mey/hot( ) 396.81 791.50 0.17 -0.31 76-mey/hot( )
366.02 812.30 0.17 0.21 76-mey/hot( ) 406.50 784.80 0.20 -0.63 76-mey/hot( )
Further references: [30-ruz/sto].

cont.

Landolt-Brnstein
New Series IV/8D
2.8 Alkylcycloalkanes (CnH2n), C12 161

Cyclododecane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
330.00 835.81 0.19 370.00 809.47 0.17 400.00 789.71 0.20
340.00 829.22 0.19 380.00 802.88 0.17 410.00 783.12 0.23
350.00 822.64 0.18 390.00 796.29 0.18 420.00 776.54 0.28
360.00 816.05 0.17

Landolt-Brnstein
New Series IV/8D
162 2.9 Alkylcycloalkanes (CnH2n), C13

2.9 Alkylcycloalkanes (CnH2n), C13


2.9.1 Cyclopropanes - Cyclopentanes

Decylcyclopropane [5794-39-8] C 13H26 MW = 182.35 282

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1002.46
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 782.6 0.50 0.00 69-rie/hoy


313.15 767.6 0.50 0.00 69-rie/hoy
333.15 752.6 0.50 0.00 69-rie/hoy
353.15 737.6 0.50 0.00 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 785.0 0.5 310.00 770.0 0.5 340.00 747.5 0.5
293.15 782.6 0.5 320.00 762.5 0.5 350.00 740.0 0.5
298.15 778.9 0.5 330.00 755.0 0.5 360.00 732.5 0.6

1-(Methylheptyl)cyclopentane [500025-88-7] C13H26 MW = 182.35 283

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 811.8 1.00 56-tar/tai

Octylcyclopentane [1795-20-6] C13H26 MW = 182.35 284

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.165.
Coefficient = A + BT
A 1046.54
B -0.800

cont.

Landolt-Brnstein
New Series IV/8D
2.9 Alkylcycloalkanes (CnH2n), C13 163

Octylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

291.15 815.6 4.00 1.98 33-zel/mic


293.15 812.0 2.00 -0.02 40-sch/gem
293.15 812.0 0.50 -0.02 42-sch
293.15 812.0 0.46 -0.00 49-lut

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 814.5 1.0
293.15 812.0 0.5
298.15 808.0 1.0

2.9.2 Cyclohexanes

1-Butyl-2,2,6-trimethylcyclohexane [500030-85-3] C 13H26 MW = 182.35 285

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 829.2 2.00 36-ruz/sei

2-Butyl-1,1,3-trimethylcyclohexane [54676-39-0] C13H26 MW = 182.35 286

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 829.2 2.00 36-ruz/sei

(1,1-Diethylpropyl)cyclohexane [500027-76-9] C13H26 MW = 182.35 287

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.15 838.8 1.00 15-hal

1,1-Diethyl-2-propylcyclohexane [500027-77-0] C13H26 MW = 182.35 288

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 818.1 1.00 57-els/str-1

Landolt-Brnstein
New Series IV/8D
164 2.9 Alkylcycloalkanes (CnH2n), C13

2,4-Dimethyl-1-(1-ethylpropyl) [500005-03-8] C13H26 MW = 182.35 289


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 828.3 3.00 53-lam/wis

cis-1-Ethyl-4-(1,1-dimethylpropyl) [1130-56-9] C13H26 MW = 182.35 290


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 838.0 1.00 65-lib/ler

trans-1-Ethyl-4-(1,1-dimethylpropyl) [1130-57-0] C13H26 MW = 182.35 291


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 828.2 1.00 65-lib/ler

(1-Ethyl-1-methylbutyl)cyclohexane [500030-84-4] C13H26 MW = 182.35 292

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.15 840.6 2.00 15-hal

(1-Ethylpentyl)cyclohexane [500027-74-7] C13H26 MW = 182.35 293

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 819.0 2.00 32-lev/mar-1

Landolt-Brnstein
New Series IV/8D
2.9 Alkylcycloalkanes (CnH2n), C13 165

Heptylcyclohexane [5617-41-4] C13H26 MW = 182.35 294

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 812.4 1.00 40-sch/gro
293.15 812.4 0.50 42-sch
293.15 812.4 6.60 49-lut
293.15 810.0 2.00 51-sch
293.15 812.3 1.0 Recommended

(1,1,3-Trimethylbutyl)cyclohexane [500027-75-8] C13H26 MW = 182.35 295

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.15 830.4 2.00 15-hal

2.9.3 Cycloheptanes - Cyclotridecane

Hexylcycloheptane [18208-62-3] C 13H26 MW = 182.35 296

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1036.47
B -0.720

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 825.4 0.50 0.00 69-rie/hoy


313.15 811.0 0.50 0.00 69-rie/hoy
333.15 796.6 0.50 0.00 69-rie/hoy
353.15 782.2 0.50 0.00 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 827.7 0.5 310.00 813.3 0.5 340.00 791.7 0.5
293.15 825.4 0.5 320.00 806.1 0.5 350.00 784.5 0.5
298.15 821.8 0.5 330.00 798.9 0.5 360.00 777.3 0.6

Landolt-Brnstein
New Series IV/8D
166 2.9 Alkylcycloalkanes (CnH2n), C13 - 2.10 Alkylcycloalkanes (CnH2n), C14

Cyclotridecane [295-02-3] C13H26 MW = 182.35 297

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.351.
Coefficient = A + BT
A 1080.80
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

306.65 851.3 1.00 0.48 30-ruz/sto


289.15 863.6 1.00 -0.34 30-ruz/sto
293.15 860.8 1.00 -0.14 30-ruz/sto

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 870.8 1.5
290.00 863.3 1.0
293.15 860.9 1.0
298.15 857.2 1.5
310.00 848.3 2.0

2.10 Alkylcycloalkanes (CnH2n), C14


2.10.1 Cyclobutanes

1,1,2,2-Tetramethyl-3,4-bis [500030-56-8] C14H28 MW = 196.38 298


(1-methylethyl)cyclobutane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.075.
Coefficient = A + BT
A 1050.20
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 818.1 3.00 0.08 13-mer-5


290.15 803.5 3.00 -0.07 13-mer-5

cont.

Landolt-Brnstein
New Series IV/8D
2.10 Alkylcycloalkanes (CnH2n), C14 167

1,1,2,2-Tetramethyl-3,4-bis(1-methylethyl)cyclobutane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 820.7 3.5
280.00 812.2 3.5
290.00 803.7 3.0
293.15 801.0 3.0
298.15 796.8 4.0

2.10.2 Cyclohexanes

1,3-bis(1,1-Dimethylethyl)- [107918-24-1] C14H28 MW = 196.38 299


butylcyclohexane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.050.
Coefficient = A + BT
A 1065.77
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 831.2 3.00 -0.05 49-pin/cza


298.15 827.3 3.00 0.05 49-pin/cza

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 833.8 3.0
293.15 831.2 3.0
298.15 827.2 3.0

1,4-bis(1,1-Dimethylethyl)cyclohexane [34386-82-8] C14H28 MW = 196.38 300

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 830.9 3.00 52-mek/kam

Landolt-Brnstein
New Series IV/8D
168 2.10 Alkylcycloalkanes (CnH2n), C14

1,4-bis(1-Methylpropyl)cyclohexane [500027-81-6 ] C14H28 MW = 196.38 301

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 830.5 3.00 52-mek/kam
293.15 831.3 3.00 52-mek/kam
293.15 830.9 3.0 Recommended

1,2-Dibutylcyclohexane [107918-23-0] C14H28 MW = 196.38 302

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 824.4 3.00 57-els/str-2

(1,1-Diethylbutyl)cyclohexane [500030-87-7] C14H28 MW = 196.38 303

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 854.7 2.00 15-hal

(1-Methylheptyl)cyclohexane [2883-05-8] C14H28 MW = 196.38 304

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.3633 10-2 (combined temperature ranges,
weighted), c,uw = 1.4779 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02429 103
B -6.75413 10-1
C -3.33100 10-5

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 837.30 0.50 -0.02


68-ano-1( ) 333.15 795.60 0.50 0.02 68-ano-1( )
293.15 823.50 0.50 0.07
68-ano-1( ) 372.05 768.40 0.50 0.00 68-ano-1( )
310.95 811.00 0.50 -0.05
68-ano-1( )
Further references: [52-ano]. cont.

Landolt-Brnstein
New Series IV/8D
2.10 Alkylcycloalkanes (CnH2n), C14 169

(1-Methylheptyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 839.50 0.66 300.00 818.67 0.57 350.00 783.82 0.58
280.00 832.57 0.59 310.00 811.72 0.58 360.00 776.83 0.59
290.00 825.62 0.57 320.00 804.75 0.58 370.00 769.83 0.63
293.15 823.43 0.56 330.00 797.78 0.59 380.00 762.83 0.71
298.15 819.96 0.57 340.00 790.80 0.58

(1-Methyl-1-propylbutyl)cyclohexane [500030-86-4] C14H28 MW = 196.38 305

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 848.3 2.00 15-hal

Landolt-Brnstein
New Series IV/8D
170 2.10 Alkylcycloalkanes (CnH2n), C14

1,1,2,2,4,4,5,5-Octamethylcyclohexane [500027-83-8] C14H28 MW = 196.38 306

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 790.2 1.00 55-pet

Octylcyclohexane [1795-15-9] C 14H28 MW = 196.38 307

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.5283 10-1 (combined temperature ranges,
weighted), c,uw = 2.4430 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01827 103
B -6.95723 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 816.50 2.00 2.19 39-wat/lee1) 313.15 792.80 0.50 -7.60 59-dix-11)
343.45 782.20 2.00 2.88 39-wat/lee() 333.15 786.40 0.50 -0.09 59-dix-1( {)
273.15 828.20 1.00 -0.03 47-sch() 273.15 828.20 0.50 -0.03 68-ano-1( )
293.15 813.90 1.00 -0.41 47-sch() 293.15 813.90 0.50 -0.41 68-ano-1( )
310.93 801.70 1.00 -0.24 47-sch() 310.95 801.70 0.50 -0.23 68-ano-1( )
333.15 786.40 1.00 -0.09 47-sch() 333.15 786.40 0.50 -0.09 68-ano-1( )
372.04 759.00 1.00 -0.43 47-sch() 372.05 759.00 0.50 -0.42 68-ano-1( )
293.15 813.90 0.50 -0.41 {
59-dix-1( )
1) Not included in Fig. 1.

Further references: [39-loz/dya, 51-sch].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 830.42 0.73 300.00 809.55 0.77 350.00 774.76 0.91
280.00 823.46 0.74 310.00 802.59 0.79 360.00 767.81 0.95
290.00 816.51 0.75 320.00 795.63 0.81 370.00 760.85 0.99
293.15 814.31 0.76 330.00 788.68 0.84 380.00 753.89 1.03
298.15 810.84 0.76 340.00 781.72 0.87
cont.

Landolt-Brnstein
New Series IV/8D
2.10 Alkylcycloalkanes (CnH2n), C14 171

Octylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(1-Propylpentyl)cyclohexane [500027-79-2] C14H28 MW = 196.38 308

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
300.15 823.0 1.00 32-lev/mar-1

(1,1,3,3-Tetramethylbutyl)cyclohexane [500027-80-5] C14H28 MW = 196.38 309

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 842.1 1.00 53-dre/har
293.15 842.1 1.00 53-pin/mye

Landolt-Brnstein
New Series IV/8D
172 2.10 Alkylcycloalkanes (CnH2n), C14

(1,1,4-Trimethylpentyl)cyclohexane [500030-88-6] C14H28 MW = 196.38 310

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 851.2 2.00 15-hal

2.10.3 Cycloheptanes - Cyclotetradecane

Heptylcycloheptane [18373-89-2] C14H28 MW = 196.38 311

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.030.
Coefficient = A + BT
A 1035.18
B -0.711

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 826.8 0.50 0.05 69-rie/hoy


313.15 812.5 0.50 -0.03 69-rie/hoy
333.15 798.3 0.50 -0.01 69-rie/hoy
353.15 784.1 0.50 0.01 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 829.0 0.5 310.00 814.8 0.5 340.00 793.4 0.5
293.15 826.8 0.5 320.00 807.7 0.5 350.00 786.3 0.5
298.15 823.2 0.5 330.00 800.6 0.5 360.00 779.2 0.5

Cyclotetradecane [295-17-0] C14H28 MW = 196.38 312

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.250
Coefficient = A + BT
A 1089.76
B -0.750

cont.

Landolt-Brnstein
New Series IV/8D
2.10 Alkylcycloalkanes (CnH2n), C14 - 2.11 Alkylcycloalkanes (CnH2n), C15 173

Cyclotetradecane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

352.15 825.9 1.00 0.25 30-ruz/sto


348.15 828.4 1.00 -0.25 30-ruz/sto

Table 3. Recommended values.


T exp 2 est
K kg m3
340.00 834.8 2.0
350.00 827.3 1.0
360.00 819.8 2.0

2.11 Alkylcycloalkanes (CnH2n), C15


Dodecylcyclopropane [500032-52-0] C15H30 MW = 210.40 313

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.045
Coefficient = A + BT
A 1005.22
B -0.729

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 791.4 0.50 -0.03 69-rie/hoy


313.15 776.9 0.50 0.06 69-rie/hoy
333.15 762.2 0.50 -0.06 69-rie/hoy
353.15 747.7 0.50 0.03 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 793.7 0.6 310.00 779.1 0.6 340.00 757.3 0.6
293.15 791.4 0.6 320.00 771.8 0.6 350.00 750.0 0.6
298.15 787.8 0.6 330.00 764.6 0.6 360.00 742.7 0.6

Landolt-Brnstein
New Series IV/8D
174 2.11 Alkylcycloalkanes (CnH2n), C15

Decylcyclopentane [1795-21-7] C15H30 MW = 210.40 314

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.7985 10-1 (combined temperature ranges,
weighted), c,uw = 9.3047 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04276 103
B -8.71253 10-1
C 2.74545 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 811.20 0.40 0.25 49-boo/gre() 273.15 824.60 0.50 -0.67 68-ano-1()
293.15 811.00 0.30 0.05 50-boo/gre( ) { 293.15 810.90 0.50 -0.05 68-ano-1()
293.15 811.10 0.30 0.15 51-ano-3() 310.95 798.60 0.50 0.21 68-ano-1()
293.15 810.97 0.06 0.02 54-cam/for( ) 333.15 783.40 0.50 0.42 68-ano-1()
298.15 807.39 0.06 -0.02 54-cam/for( ) 372.05 756.30 0.50 -0.32 68-ano-1()
303.15 803.83 0.06 -0.05 54-cam/for( )
Further references: [40-sch/gem, 42-sch, 49-lut].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
2.11 Alkylcycloalkanes (CnH2n), C15 175

Decylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 827.54 0.65 300.00 806.10 0.26 350.00 771.46 0.65
280.00 820.34 0.41 310.00 799.06 0.31 360.00 764.69 0.65
290.00 813.19 0.28 320.00 792.08 0.41 370.00 757.99 0.58
293.15 810.95 0.27 330.00 785.15 0.51 380.00 751.33 0.43
298.15 807.41 0.26 340.00 778.28 0.60

1-Butyl-2-pentylcyclohexane [101452-35-1] C15H30 MW = 210.40 315

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 825.1 4.00 57-els/str
293.15 825.1 3.00 57-els/str-2

1-(1,5-Dimethylhexyl)- [29799-19-7] C15H30 MW = 210.40 316


4-methylcyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 826.4 3.00 13-sem/bec
293.15 824.4 4.00 13-sem/ros
293.15 829.0 4.00 29-ruz/van
288.15 828.0 5.00 29-ruz/van
293.15 826.8 4.0 Recommended

(1-Ethyl-1,3-dimethylpentyl)cyclohexane [500027-86-1] C15H30 MW = 210.40 317

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 851.5 1.00 52-lev/shu-2

(1-Ethyl-1,4-dimethylpentyl)cyclohexane [500030-89-7] C15H30 MW = 210.40 318

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 871.7 3.00 15-hal

Landolt-Brnstein
New Series IV/8D
176 2.11 Alkylcycloalkanes (CnH2n), C15

(1-Ethyl-1,3-dimethylpentyl)cyclohexane [500011-34-7] C15H30 MW = 210.40 319

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 851.5 1.00 52-lev/shu-2

(1,1-Diethyl-3-methylbutyl)cyclohexane [500032-71-3] C15H30 MW = 210.40 320

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 835.9 0.50 60-sok/she

1-Ethyl-2,4-bis(1-methylethyl)- [500027-89-4] C15H30 MW = 210.40 321


1-methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 848.0 2.00 54-syk/cer

1-(3-Methylbutyl)-3-(1-methylethyl)- [500027-88-3] C15H30 MW = 210.40 322


6-methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 825.0 3.00 17-sem/jon

1-(1-Methylpropyl)-3-(1-methylethyl)- [500027-90-7] C15H30 MW = 210.40 323


6,6-dimethylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 841.2 3.00 53-syk/her

Nonylcyclohexane [2883-02-5] C15H30 MW = 210.40 324

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.0 2.00 51-sch

Landolt-Brnstein
New Series IV/8D
2.11 Alkylcycloalkanes (CnH2n), C15 177

Octylcycloheptane [18208-63-4] C15H30 MW = 210.40 325

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.028.
Coefficient = A + BT
A 1034.36
B -0.702

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 828.6 0.50 -0.03 69-rie/hoy


313.15 814.6 0.50 0.01 69-rie/hoy
333.15 800.6 0.50 0.04 69-rie/hoy
353.15 786.5 0.50 -0.02 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 830.8 0.5 310.00 816.8 0.5 340.00 795.7 0.5
293.15 828.6 0.5 320.00 809.8 0.5 350.00 788.7 0.5
298.15 825.1 0.5 330.00 802.8 0.5 360.00 781.7 0.6

Cyclopentadecane [295-48-7] C15H30 MW = 210.40 326

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 7.2537 10-1 (combined temperature ranges,
weighted), c,uw = 5.7492 10-1 (combined
temperature ranges, unweighted).
T = 334.65 to 382.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.06236 103
B -6.77165 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

334.65 836.40 1.00 0.66


26-ruz/bru-1( ) 351.15 824.00 1.00 -0.57
30-ruz/sto( )
344.15 828.00 1.00 -1.31 30-ruz/sto( ) 382.15 804.80 1.00 1.22
30-ruz/sto( )

cont.

Landolt-Brnstein
New Series IV/8D
178 2.11 Alkylcycloalkanes (CnH2n), C15

Cyclopentadecane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
330.00 838.89 1.39 360.00 818.58 1.04 380.00 805.03 1.51
340.00 832.12 1.14 370.00 811.81 1.23 390.00 798.26 1.84
350.00 825.35 1.01

Landolt-Brnstein
New Series IV/8D
2.12 Alkylcycloalkanes (CnH2n), C16 179

2.12 Alkylcycloalkanes (CnH2n), C16


1-Butyl-2-hexylcyclohexane [500027-94-1] C16H32 MW = 224.43 327

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 826.4 4.00 57-els/str-1
293.15 826.4 4.00 57-els/str-2

Decylcyclohexane [1795-16-0] C16H32 MW = 224.43 328

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.1250 10-1 (combined temperature ranges,
weighted), c,uw = 6.7313 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01417 103
B -6.67245 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 819.10 0.60 0.53 49-ano-1() 273.15 831.90 0.50 -0.01 68-ano-1()
293.15 819.10 0.50 0.53 49-boo/gre( ) { 293.15 818.60 0.50 0.03 68-ano-1()
293.15 818.58 0.06 0.01 54-cam/for( ) 310.95 806.70 0.50 0.01 68-ano-1()
298.15 815.17 0.06 -0.06 54-cam/for( ) 333.15 791.80 0.50 -0.08 68-ano-1()
303.15 811.83 0.06 -0.06 54-cam/for( ) 372.05 765.50 0.50 -0.42 68-ano-1()
Further references: [47-tuo/guy, 51-sch, 52-ano].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 834.01 0.63 300.00 814.00 0.10 350.00 780.63 0.65
280.00 827.34 0.47 310.00 807.32 0.15 360.00 773.96 0.67
290.00 820.67 0.26 320.00 800.65 0.40 370.00 767.29 0.69
293.15 818.57 0.15 330.00 793.98 0.54 380.00 760.62 0.71
298.15 815.23 0.10 340.00 787.31 0.61

cont.

Landolt-Brnstein
New Series IV/8D
180 2.12 Alkylcycloalkanes (CnH2n), C16

Decylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,4-Dipentylcyclohexane [65162-15-4] C16H32 MW = 224.43 329

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 818.0 6.00 54-cra/dae

(1,1-Dipropylbutyl)cyclohexane [500027-92-9] C 16H32 MW = 224.43 330

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 838.2 2.00 15-hal

Landolt-Brnstein
New Series IV/8D
2.12 Alkylcycloalkanes (CnH2n), C16 181

[1-(1-Methylethyl)heptyl]cyclohexane [500027-91-8] C16H32 MW = 224.43 331

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
290.15 856.0 1.00 45-pet/kru

[1-(2-Methylpropyl)- [500027-93-0] C16H32 MW = 224.43 332


1,3-dimethylbutyl]cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 839.6 2.00 15-hal

Nonylcycloheptane [18208-64-5] C16H32 MW = 224.43 333

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.028.
Coefficient = A + BT
A 1033.23
B -0.692

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 830.4 0.50 -0.03 69-rie/hoy


313.15 816.6 0.50 0.01 69-rie/hoy
333.15 802.8 0.50 0.04 69-rie/hoy
353.15 788.9 0.50 -0.02 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 832.6 0.6 310.00 818.8 0.5 340.00 798.0 0.6
293.15 830.4 0.5 320.00 811.9 0.6 350.00 791.1 0.5
298.15 827.0 0.5 330.00 804.9 0.5 360.00 784.2 0.7

Methylcyclopentadecane [58259-50-0] C16H32 MW = 224.43 334

Landolt-Brnstein
New Series IV/8D
182 2.12 Alkylcycloalkanes (CnH2n), C16

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.4846 10-1 (combined temperature ranges,
weighted), c,uw = 3.6935 10-1 (combined
temperature ranges, unweighted).
T = 291.15 to 382.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03251 103
B -5.95332 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

291.15 859.40 1.00 0.22 30-ruz/sto( ) 307.65 847.50 1.00 -1.85 33-ruz/boe( ) {
293.15 858.00 1.00 0.01 30-ruz/sto( ) 334.05 833.70 1.00 0.06 33-ruz/boe( ) {
382.15 805.10 1.00 0.10 30-ruz/sto( ) 352.35 822.70 1.00 -0.04 33-ruz/boe( ) {
293.45 859.30 1.00 1.49 33-ruz/boe( {)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
2.12 Alkylcycloalkanes (CnH2n), C16 - 2.13 Alkylcycloalkanes (CnH2n), C17 to C18 183

Methylcyclopentadecane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 859.86 1.15 320.00 842.00 1.30 360.00 818.19 1.15
293.15 857.99 1.10 330.00 836.05 1.11 370.00 812.23 1.23
298.15 855.01 1.06 340.00 830.09 1.15 380.00 806.28 1.32
300.00 853.91 1.05 350.00 824.14 1.08 390.00 800.33 1.50
310.00 847.95 1.12

Cyclohexadecane [295-65-8] C16H32 MW = 224.43 335

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
352.15 819.0 3.00 30-ruz/sto
345.15 824.0 3.00 30-ruz/sto

2.13 Alkylcycloalkanes (CnH2n), C17 to C18


Tetradecylcyclopropane [500032-53-1] C17H34 MW = 238.46 336

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1006.04
B -0.710

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 797.9 0.50 0.00 69-rie/hoy


313.15 783.7 0.50 0.00 69-rie/hoy
333.15 769.5 0.50 0.00 69-rie/hoy
353.15 755.3 0.50 0.00 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 800.1 0.6 310.00 785.9 0.5 340.00 764.6 0.6
293.15 797.9 0.5 320.00 778.8 0.6 350.00 757.5 0.5
298.15 794.3 0.5 330.00 771.7 0.5 360.00 750.4 0.7

Landolt-Brnstein
New Series IV/8D
184 2.13 Alkylcycloalkanes (CnH2n), C17 to C18

Dodecylcyclopentane [5634-30-0] C17H34 MW = 238.46 337

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
291.15 828.0 5.00 37-von/kam 1)
293.15 818.0 2.00 40-sch/gem
293.15 818.0 0.50 42-sch
293.15 818.1 0.67 49-lut
293.15 818.0 0.6 Recommended
1)
Not included in calculation of linear coefficients

(3-Butylheptyl)cyclohexane [500028-18-2] C17H34 MW = 238.46 338

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 835.1 0.80 37-nes/mar

[1-(3-Methylbutyl)-1,3,3-trimethylbutyl] [500032-73-5] C17H34 MW = 238.46 339


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 839.2 0.50 60-sok/she

(3-Methyl-1,1-dipropylbutyl) [500028-19-3] C17H34 MW = 238.46 340


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 844.1 1.00 15-hal

Undecylcyclohexane [54105-66-7] C17H34 MW = 238.46 341

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 823.0 2.00 51-sch

Landolt-Brnstein
New Series IV/8D
2.13 Alkylcycloalkanes (CnH2n), C17 to C18 185

Decylcycloheptane [18208-65-6] C17H34 MW = 238.46 342

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.023.
Coefficient = A + BT
A 1032.15
B -0.683

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 832.0 0.50 0.02 69-rie/hoy


313.15 818.3 0.50 -0.03 69-rie/hoy
333.15 804.7 0.50 0.03 69-rie/hoy
353.15 791.0 0.50 -0.02 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 834.1 0.6 310.00 820.5 0.5 340.00 800.0 0.6
293.15 832.0 0.5 320.00 813.7 0.6 350.00 793.2 0.5
298.15 828.6 0.5 330.00 806.8 0.5 360.00 786.3 0.6

Nonylcyclooctane [500032-59-7] C17H34 MW = 238.46 343

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.030.
Coefficient = A + BT
A 1040.53
B -0.674

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 842.9 0.50 -0.05 69-rie/hoy


313.15 829.5 0.50 0.03 69-rie/hoy
333.15 816.0 0.50 0.02 69-rie/hoy
353.15 802.5 0.50 -0.00 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
K kg m 3
K kg m 3
K kg m3
290.00 845.1 0.6 310.00 831.6 0.5 340.00 811.4 0.6
293.15 842.9 0.5 320.00 824.8 0.6 350.00 804.6 0.5
298.15 839.6 0.5 330.00 818.1 0.5 360.00 797.9 0.6

Landolt-Brnstein
New Series IV/8D
186 2.13 Alkylcycloalkanes (CnH2n), C17 to C18

Cycloheptadecane [295-97-6] C17H34 MW = 238.46 344

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 2.963.
Coefficient = A + BT
A 1104.22
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

381.15 802.1 3.00 2.80 30-ruz/sto


374.15 806.2 3.00 1.30 30-ruz/sto
350.15 820.0 3.00 -4.10 30-ruz/sto

Table 3. Recommended values.


T exp 2 est
K kg m3
350.00 824.2 3.0
360.00 816.2 3.5
370.00 808.2 3.0
380.00 800.2 3.0
390.00 792.2 3.6

1,3-Dimethyl-2-(3,7-dimethyloctyl) [500028-20-6] C18H36 MW = 252.48 345


cyclohexane

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 826.0 5.00 61-ano-9
293.15 822.00 4.00 63-ano-3

Dodecylcyclohexane [795-17-1] C18H36 MW = 252.48 346

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 825.0 1.00 40-sch/gro
293.15 825.0 1.00 42-sch
293.15 825.6 1.50 49-lut
293.15 825.0 2.00 51-sch
293.15 824.0 0.80 66-sha/bek
293.15 824.7 0.9 Recommended

Landolt-Brnstein
New Series IV/8D
2.13 Alkylcycloalkanes (CnH2n), C17 to C18 187

Hexaethylcyclohexane [98803-61-3] C18H36 MW = 252.48 347

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
310.93 862.7 4.00 63-gud/cam

[1-(3-Methylbutyl)-1,4- [500030-90-0] C18H36 MW = 252.48 348


dimethylpentyl]cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.65 844.0 2.00 15-hal

(4-Methyl-1,1-dipropylpentyl) [500032-74-6] C18H36 MW = 252.48 349


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 848.9 0.50 60-sok/she

Decylcyclooctane [500032-60-0] C18H36 MW = 252.48 350

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.030.
Coefficient = A + BT
A 1040.66
B -0.669

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

293.15 844.5 0.50 -0.05 69-rie/hoy


313.15 831.2 0.50 0.03 69-rie/hoy
333.15 817.8 0.50 0.01 69-rie/hoy
353.15 804.4 0.50 -0.01 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 846.7 0.6 310.00 833.3 0.5 340.00 813.2 0.6
293.15 844.5 0.5 320.00 826.6 0.6 350.00 806.5 0.5
298.15 841.2 0.5 330.00 819.9 0.5 360.00 799.8 0.6

Landolt-Brnstein
New Series IV/8D
188 2.13 Alkylcycloalkanes (CnH2n), C17 to C18 - 2.14 Alkylcycloalkanes (CnH2n), C19 to C20

Cyclooctadecane [296-18-4] C18H36 MW = 252.48 351

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 2.975.
Coefficient = A + BT
A 1084.94
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

349.15 820.1 2.00 -2.98 30-ruz/sto


384.15 799.8 2.00 2.97 30-ruz/sto

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
K kg m 3
K kg m 3
K kg m3
340.00 829.9 3.5 360.00 814.9 3.5 380.00 799.9 3.0
350.00 822.4 2.5 370.00 807.4 3.5 390.00 792.4 3.6

2.14 Alkylcycloalkanes (CnH2n), C19 to C20


Hexadecylcyclopropane [18208-79-2] C19H38 MW = 266.51 352

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1006.84
B -0.695

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 803.1 0.50 0.00 69-rie/hoy


313.15 789.2 0.50 0.00 69-rie/hoy
333.15 775.3 0.50 -0.00 69-rie/hoy
353.15 761.4 0.50 -0.00 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
K kg m 3
K kg m 3
K kg m3
290.00 805.3 0.6 310.00 791.4 0.5 340.00 770.5 0.6
293.15 803.1 0.5 320.00 784.4 0.6 350.00 763.6 0.5
298.15 799.6 0.5 330.00 777.5 0.5 360.00 756.6 0.6

Landolt-Brnstein
New Series IV/8D
2.14 Alkylcycloalkanes (CnH2n), C19 to C20 189

1,2-Diheptylcyclopentane [500023-46-1] C19H38 MW = 266.51 353

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 831.0 4.00 55-del/rud

(2-Hexyloctyl)cyclopentane [55044-77-4] C19H38 MW = 266.51 354

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 7.1937 10-2 (combined temperature ranges,
weighted), c,uw = 2.8905 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.04 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01315 103
B -6.27672 10-1
C -7.46736 10-5

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 836.10 1.00 -0.03


52-ano( ) 333.15 795.80 1.00 0.04
52-ano( )
293.15 822.80 1.00 0.06
52-ano( ) 372.04 769.30 1.00 0.00
52-ano( )
310.93 810.70 1.00 -0.07
52-ano( )

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 838.24 1.22 300.00 818.13 1.02 350.00 784.32 1.30
280.00 831.55 1.15 310.00 811.40 1.05 360.00 777.51 1.30
290.00 824.85 1.05 320.00 804.65 1.10 370.00 770.69 1.10
293.15 822.74 1.02 330.00 797.89 1.10 380.00 763.86 1.30
298.15 819.38 1.01 340.00 791.11 1.20

cont.

Landolt-Brnstein
New Series IV/8D
190 2.14 Alkylcycloalkanes (CnH2n), C19 to C20

(2-Hexyloctyl)cyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Tetradecylcyclopentane [1795-22-8] C19H38 MW = 266.51 355

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 822.0 2.00 40-sch/gem
293.15 822.0 0.70 42-sch
293.15 822.0 0.68 49-lut
293.15 822.0 0.7 Recommended

(1,1-Dibutylpentyl)cyclohexane [00028-21-7] C19H38 MW = 266.51 356

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 829.5 0.50 60-sok/she

Landolt-Brnstein
New Series IV/8D
2.14 Alkylcycloalkanes (CnH2n), C19 to C20 191

1-Dodecyl-2-methylcyclohexane [39762-41-9] C19H38 MW = 266.51 357

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 823.6 4.00 42-pet/che

1-Dodecyl-3-methylcyclohexane [5452-29-9] C19H38 MW = 266.51 358

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 824.7 4.00 42-pet/che

[1-Ethyl-4-methyl-1- [500028-23-9] C19H38 MW = 266.51 359


(3-methylbutyl)pentyl]cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.65 868.1 1.00 15-hal

(1-Hexylheptyl)cyclohexane [13151-92-3] C19H38 MW = 266.51 360

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.8510 10-2 (combined temperature ranges,
weighted), c,uw = 1.0611 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02356 103
B -6.40176 10-1
C -4.91724 10-5

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 831.70 0.50 0.03 {)


59-dix-1( 293.15 831.70 0.50 0.03 68-ano-1( )
313.15 818.30 0.50 0.03 {)
59-dix-1( 310.95 819.60 0.50 -0.15 68-ano-1( )
333.15 804.80 0.50 -0.03 {)
59-dix-1( 333.15 804.80 0.50 -0.03 68-ano-1( )
273.15 845.00 0.50 -0.03 )
68-ano-1( 372.05 778.60 0.50 0.02 68-ano-1( )
Further references: [48-ano].

cont.

Landolt-Brnstein
New Series IV/8D
192 2.14 Alkylcycloalkanes (CnH2n), C19 to C20

(1-Hexylheptyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 847.13 1.50 300.00 827.09 0.48 350.00 793.48 0.90
280.00 840.46 0.90 310.00 820.38 0.45 360.00 786.73 0.85
290.00 833.78 0.60 320.00 813.67 0.45 370.00 779.97 0.60
293.15 831.67 0.50 330.00 806.95 0.55 380.00 773.20 0.70
298.15 828.32 0.48 340.00 800.22 0.70

Tridecylcyclohexane [6006-33-3] C19H38 MW = 266.51 361

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 830.0 2.00 51-sch

Landolt-Brnstein
New Series IV/8D
2.14 Alkylcycloalkanes (CnH2n), C19 to C20 193

[1,1,1-tris(2-Methylpropyl) methyl] [500032-76-8] C19H34 MW = 262.48 362


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 847.3 0.50 60-sok/she

Dodecylcycloheptane [500032-57-5] C19H38 MW = 266.51 363

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.028.
Coefficient = A + BT
A 1031.52
B -0.673

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 834.2 0.50 0.03 69-rie/hoy


313.15 820.7 0.50 -0.01 69-rie/hoy
333.15 807.2 0.50 -0.04 69-rie/hoy
353.15 793.8 0.50 0.02 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 836.3 0.6 310.00 822.8 0.5 340.00 802.6 0.6
293.15 834.2 0.5 320.00 816.1 0.6 350.00 795.9 0.5
298.15 830.8 0.5 330.00 809.4 0.5 360.00 789.2 0.6

Undecylcyclooctane [500032-61-1] C19H38 MW = 266.51 364

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.023.
Coefficient = A + BT
A 1040.14
B -0.662

cont.

Landolt-Brnstein
New Series IV/8D
194 2.14 Alkylcycloalkanes (CnH2n), C19 to C20

Undecylcyclooctane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

293.15 846.0 0.50 -0.02 69-rie/hoy 333.15 819.5 0.50 -0.03 69-rie/hoy
313.15 832.8 0.50 0.03 69-rie/hoy 353.15 806.3 0.50 0.02 69-rie/hoy

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
290.00 848.1 0.6 310.00 834.9 0.5 340.00 815.0 0.6
293.15 846.0 0.5 320.00 828.2 0.6 350.00 808.4 0.5
298.15 842.7 0.5 330.00 821.6 0.5 360.00 801.7 0.6

1-(1,5-Dimethylhexyl)-4- [56009-20-2] C20H40 MW = 280.54 365


(4-methylpentyl)cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 833.1 6.00 14-sem/jon

[4-Methyl-1-(3-methylbutyl)-1- [500028-25-1] C20H40 MW = 280.54 366


propylpentyl]cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.65 842.1 1.00 15-hal

(1-Methyltridecyl)cyclohexane [500028-24-0] C20H40 MW = 280.54 367

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 849.2 1.00 42-pet/che

Tetradecylcyclohexane [1795-18-2] C20H40 MW = 280.54 368

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 825.8 1.00 42-sch
293.15 833.0 2.00 51-sch
293.15 827.2 2.8 Recommended

Landolt-Brnstein
New Series IV/8D
2.15 Alkylcycloalkanes (CnH2n), C21 to C23 195

2.15 Alkylcycloalkanes (CnH2n), C21 to C23


1-Butyl-2-dodecylcyclopentane [500023-47-2] C21H42 MW = 294.56 369

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 823.8 4.00 55-del/rud

1-Decyl-2-hexylcyclopentane [500023-48-3] C21H42 MW = 294.56 370

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 827.5 4.00 55-del/rud

1,2-Dioctylcyclopentane [500034-49-1] C21H42 MW = 294.56 371

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 829.5 4.00 55-del/rud

Hexadecylcyclopentane [6812-39-1] C21H42 MW = 294.56 372

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 823.2 2.00 40-sch/gem
293.15 823.2 0.70 42-sch
293.15 823.0 2.50 49-lut
293.15 822.9 1.00 55-del/rud
293.15 823.1 0.9 Recommended

1-Heptyl-2-nonylcyclopentane [500023-49-4] C21H42 MW = 294.56 373

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 826.50 4.00 55-del/rud

Landolt-Brnstein
New Series IV/8D
196 2.15 Alkylcycloalkanes (CnH2n), C21 to C23

4-Methyl-1-(2-methylpropyl)-1- [500028-26-2] C21H42 MW = 294.56 374


(3-methylbutyl) pentyl]cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.65 779.7 4.00 15-hal

Pentadecylcyclohexane [6006-95-7] C21H42 MW = 294.56 375

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 832.3 2.00 31-haa
293.15 833.0 0.80 49-lut
293.15 832.9 0.9 Recommended

(1,1-Dimethyltetradecyl)cyclohexane [500028-28-4] C22H44 MW = 308.59 376

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 841.3 1.00 42-pet/che

1-Dodecyl-3-(1-methylethyl)- [500028-29-5] C22H44 MW = 308.59 377


6-methylcyclohexane

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.462.
Coefficient = A + BT
A 1028.69
B -0.670

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 831.8 4.00 -0.48 40 -tur


293.15 831.8 3.00 -0.48 41 -ney/pil
313.15 819.0 3.00 0.12 41 -ney/pil
333.15 806.1 3.00 0.62 41 -ney/pil

cont.

Landolt-Brnstein
New Series IV/8D
2.15 Alkylcycloalkanes (CnH2n), C21 to C23 197

1-Dodecyl-3-(1-methylethyl)-6-methylcyclohexane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 834.4 3.5
293.15 832.3 3.5
298.15 828.9 4.0
310.00 821.0 3.5
320.00 814.3 4.0
330.00 807.6 3.5
340.00 800.9 4.0

Hexadecylcyclohexane [6812-38-0] C22H44 MW = 308.59 378

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.3896 (combined temperature ranges,
weighted), c,uw = 8.2502 10-1 (combined
temperature ranges, unweighted).
T = 293.15 to 323.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03445 103
B -7.06590 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 828.70 0.50 1.39 {


41-ney/pil( ) 293.15 826.00 2.00 -1.31 42-pet/che()
318.15 812.20 0.50 2.55
42-lar/tho( ) 293.15 826.00 1.00 -1.31 42-sch()
323.15 804.80 0.50 -1.31
42-lar/tho( )

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 829.54 1.80 300.00 822.47 1.70 320.00 808.34 2.00
293.15 827.31 1.50 310.00 815.41 1.80 330.00 801.27 2.40
298.15 823.78 1.60

cont.

Landolt-Brnstein
New Series IV/8D
198 2.15 Alkylcycloalkanes (CnH2n), C21 to C23

Hexadecylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(4-Hexyldecyl)cyclohexane [500028-27-3] C22H44 MW = 308.59 379

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 853.2 1.00 49-pet/kap

Landolt-Brnstein
New Series IV/8D
2.15 Alkylcycloalkanes (CnH2n), C21 to C23 199

1-(1-methylethyl)-3-[5-methyl-2- [500028-30-8] C22H44 MW = 308.59 380


(3-methylbutyl)hexyl]-
4-methylcyclohexane

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.226.
Coefficient = A + BT
A 1031.19
B -0.680

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 831.6 4.00 -0.25 40-tur


293.15 831.6 3.00 -0.25 41-ney/pil
313.15 818.4 3.00 0.15 41-ney/pil
333.15 804.9 3.00 0.25 41-ney/pil

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 834.0 4.0
293.15 831.9 3.5
298.15 828.5 4.0
310.00 820.4 3.5
320.00 813.6 4.0
330.00 806.8 3.5
340.00 800.0 4.0

Cyclodocosane [296-86-6] C22H44 MW = 308.59 381

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
348.15 817.40 1.00 30-ruz/sto

Octadecylcyclopentane [62016-53-9] C23H46 MW = 322.62 382

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 824.0 2.00 40-sch/gem
293.15 824.0 0.80 42-sch
293.15 824.0 1.30 49-lut
293.15 824.0 0.9 Recommended

Landolt-Brnstein
New Series IV/8D
200 2.15 Alkylcycloalkanes (CnH2n), C21 to C23

(1-Octylnonyl)cyclohexane [55124-77-1] C23H46 MW = 322.62 383

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.7600 10-2 (combined temperature ranges,
weighted), c,uw = 9.0608 10-3 (combined
temperature ranges, unweighted).
T = 273.15 to 372.04 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04165 103
B -7.60253 10-1
C 1.73341 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 833.70 0.60 0.02 49-foe/fen( ) 310.93 822.00 0.50 -0.02 52-ano( )
273.15 846.90 0.50 -0.02 52-ano( ) 333.15 807.60 0.50 -0.01 52-ano( )
293.15 833.70 0.50 0.02 52-ano( ) 372.04 782.80 0.50 0.00 52-ano( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.15 Alkylcycloalkanes (CnH2n), C21 to C23 201

(1-Octylnonyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 849.02 0.70 300.00 829.17 0.54 350.00 796.79 0.57
280.00 842.37 0.59 310.00 822.63 0.56 360.00 790.42 0.59
290.00 835.75 0.54 320.00 816.12 0.57 370.00 784.09 0.65
293.15 833.68 0.54 330.00 809.64 0.58 380.00 777.78 0.78
298.15 830.39 0.54 340.00 803.20 0.57

Cyclotricosane [296-96-8] C23H46 MW = 322.62 384

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.0760 10-1 (combined temperature ranges,
weighted), c,uw = 2.6152 10-1 (combined
temperature ranges, unweighted).
T = 328.15 to 384.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02936 103
B -6.03926 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1)

342.15 823.30 1.00 0.58 30-ruz/sto( )


384.15 797.30 1.00 -0.06 30-ruz/sto( )
337.15 825.90 1.00 0.16 33-ruz/sto( )
328.15 830.50 1.00 -0.68 33-ruz/sto( )
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
320.00 836.10 1.50 350.00 817.98 1.00 380.00 799.86 1.30
330.00 830.06 1.20 360.00 811.94 1.10 390.00 793.82 1.50
340.00 824.02 1.10 370.00 805.90 1.20

cont.

Landolt-Brnstein
New Series IV/8D
202 2.15 Alkylcycloalkanes (CnH2n), C21 to C23 - 2.16 Alkylcycloalkanes (CnH2n), C24 to C25

Cyclotricosane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

2.16 Alkylcycloalkanes (CnH2n), C24 to C25


Octadecylcyclohexane [4445-06-1] C24H48 MW = 336.65 385

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.3555 (combined temperature ranges,
weighted), c,uw = 6.8217 10-1 (combined
temperature ranges, unweighted).
T = 293.15 to 363.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02663 103
B -6.61754 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.16 Alkylcycloalkanes (CnH2n), C24 to C25 203

Octadecylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

298.15 834.00 2.00 4.67 36-mik( ) 328.15 808.40 1.00 -1.08 42-lar/tho()
293.15 833.50 1.00 0.86 39-sui/gem( ) 314.15 817.80 1.00 -0.94 43-het/shc()
321.15 812.40 2.00 -1.71 39-wat/lee-1() 343.15 799.70 1.00 0.15 48-maz( ) {
343.15 798.30 2.00 -1.25 39-wat/lee-1() 363.15 787.40 1.00 1.09 48-maz( ) {
318.15 814.30 1.00 -1.79 42-lar/tho()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
204 2.16 Alkylcycloalkanes (CnH2n), C24 to C25

Octadecylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 834.72 1.56 310.00 821.49 1.40 350.00 795.02 1.34
293.15 832.64 1.53 320.00 814.87 1.35 360.00 788.40 1.38
298.15 829.33 1.49 330.00 808.25 1.32 370.00 781.78 1.44
300.00 828.10 1.47 340.00 801.63 1.32

1-Methyl-3-octadecylcyclopentane [500023-50-7] C24H48 MW = 336.65 386

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 833.8 1.00 39-sui/gem

(4-Octyldodecyl)cyclopentane [5638-09-5] C25H50 MW = 350.67 387

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0518 10-1 (combined temperature ranges,
weighted), c,uw = 3.6048 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 408.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02118 103
B -6.54834 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

310.95 817.80 1.75 0.24 58-cut/mcm( {) 293.15 829.20 0.50 -0.01 68-ano-1( )
333.15 802.89 1.72 -0.13 58-cut/mcm( {) 310.95 817.80 0.50 0.24 68-ano-1( )
352.55 790.20 1.69 -0.12 58-cut/mcm( {) 333.15 802.90 0.50 -0.12 68-ano-1( )
372.05 777.48 1.66 -0.07 58-cut/mcm( {) 352.59 790.20 0.50 -0.09 68-ano-1( )
388.15 767.22 1.64 0.22 58-cut/mcm( {) 372.05 777.50 0.50 -0.05 68-ano-1( )
408.15 753.92 1.60 0.01 58-cut/mcm( {) 388.15 767.00 0.50 -0.00 68-ano-1( )
273.15 842.20 0.50 -0.11 68-ano-1( ) 408.15 753.90 0.50 -0.01 68-ano-1( )
Further references: [47-sch, 52-ano, 53-ano-7].

cont.

Landolt-Brnstein
New Series IV/8D
2.16 Alkylcycloalkanes (CnH2n), C24 to C25 205

(4-Octyldodecyl)cyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 844.37 0.55 310.00 818.18 0.70 370.00 778.89 0.86
280.00 837.83 0.65 320.00 811.63 0.80 380.00 772.34 0.84
290.00 831.28 0.76 330.00 805.08 0.85 390.00 765.79 0.82
293.15 829.21 0.70 340.00 798.54 0.85 400.00 759.24 0.84
298.15 825.94 0.73 350.00 791.99 0.80 410.00 752.70 0.84
300.00 824.73 0.73 360.00 785.44 0.84 420.00 746.15 0.93

Landolt-Brnstein
New Series IV/8D
206 2.16 Alkylcycloalkanes (CnH2n), C24 to C25

1-Hexadecyl-2,4,5-trimethylcyclohexane [500028-32-0] C25H50 MW = 350.67 388

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 839.5 4.00 42-pet/che

(3-Octylundecyl)cyclohexane [25446-35-9] C25H50 MW = 350.67 389

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.6383 10-1 (combined temperature ranges,
weighted), c,uw = 1.0047 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 408.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02365 103
B -6.50763 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 832.50 0.30 -0.38


49-foe/fen( ) 293.15 832.70 0.50 -0.18 68-ano-1( {)
310.95 821.63 1.76 0.33 58-cut/mcm() 310.95 821.60 0.50 0.30 68-ano-1( {)
333.15 806.78 1.73 -0.07 58-cut/mcm() 333.15 806.80 0.50 -0.05 68-ano-1( {)
352.55 794.60 1.70 0.37 58-cut/mcm() 352.59 794.60 0.50 0.40 68-ano-1( {)
372.05 781.98 1.67 0.44 58-cut/mcm() 372.05 782.00 0.50 0.46 68-ano-1( {)
388.15 770.77 1.65 -0.29 58-cut/mcm() 388.15 770.80 0.50 -0.26 68-ano-1( {)
408.15 757.40 1.61 -0.64 58-cut/mcm() 408.15 757.40 0.50 -0.64 68-ano-1( {)
273.15 846.10 0.50 0.20 {
68-ano-1( )

Further references: [47-sch, 52-ano, 55-cut].

cont.

Landolt-Brnstein
New Series IV/8D
2.16 Alkylcycloalkanes (CnH2n), C24 to C25 207

(3-Octylundecyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 847.95 0.50 310.00 821.92 0.55 370.00 782.87 0.65
280.00 841.44 0.53 320.00 815.41 0.58 380.00 776.36 0.70
290.00 834.93 0.55 330.00 808.90 0.55 390.00 769.85 0.70
293.15 832.88 0.50 340.00 802.39 0.60 400.00 763.35 0.75
298.15 829.63 0.65 350.00 795.89 0.70 410.00 756.84 0.75
300.00 828.42 0.68 360.00 789.38 0.75 420.00 750.33 0.85

Landolt-Brnstein
New Series IV/8D
208 2.17 Alkylcycloalkanes (CnH2n), C26

2.17 Alkylcycloalkanes (CnH2n), C26


(1-Decylundecyl)cyclopentane [6703-81-7] C26H52 MW = 364.70 390

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.0451 10-1 (combined temperature ranges,
weighted), c,uw = 1.1275 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04810 103
B -8.04299 10-1
C 2.43365 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 832.90 0.80 -0.34 49-foe/fen( ){ 310.95 821.50 0.50 -0.04 68-ano-1( )
273.15 846.80 0.50 0.23 68-ano-1( ) 333.15 807.50 0.50 0.34 68-ano-1( )
293.15 833.10 0.50 -0.14 68-ano-1( ) 372.05 782.50 0.50 -0.05 68-ano-1( )
Further references: [47-sch].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 209

(1-Decylundecyl)cyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 848.69 0.75 300.00 828.72 0.58 350.00 796.41 0.58
280.00 841.98 0.64 310.00 822.16 0.59 360.00 790.10 0.59
290.00 835.33 0.59 320.00 815.65 0.60 370.00 783.83 0.65
293.15 833.24 0.58 330.00 809.19 0.60 380.00 777.61 0.78
298.15 829.94 0.58 340.00 802.78 0.59

Heneicosylcyclopentane [6703-82-8] C26H52 MW = 364.70 391

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0861 10-1 (combined temperature ranges,
weighted), c,uw = 6.1623 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01798 103
B -6.43850 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 829.00 1.50 -0.24 {


45-whi/her( ) 310.95 817.80 0.50 0.02
68-ano-1( )
273.15 842.20 0.50 0.08 68-ano-1( ) 333.15 803.70 0.50 0.21
68-ano-1( )
293.15 829.20 0.50 -0.04 68-ano-1( ) 372.05 778.40 0.50 -0.04
68-ano-1( )
Further references: [47-sch].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 844.14 0.85 300.00 824.83 0.71 350.00 792.64 0.60
280.00 837.71 0.80 310.00 818.39 0.67 360.00 786.20 0.60
290.00 831.27 0.75 320.00 811.95 0.65 370.00 779.76 0.61
293.15 829.24 0.74 330.00 805.51 0.62 380.00 773.32 0.63
298.15 826.02 0.72 340.00 799.08 0.61

cont.

Landolt-Brnstein
New Series IV/8D
210 2.17 Alkylcycloalkanes (CnH2n), C26

Heneicosylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(1-Butylhexadecyl)cyclohexane [4443-59-8] C26H52 MW = 364.70 392

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8279 10-1 (combined temperature ranges,
weighted), c,uw = 3.2495 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02687 103
B -6.45230 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 211

(1-Butylhexadecyl)cyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

293.15 836.40 1.00 -1.32 {


42-pet/che( ) 310.95 826.80 0.50 0.57
68-ano-1( )
273.15 851.50 0.50 0.88 68-ano-1( ) 333.15 811.80 0.50 -0.11
68-ano-1( )
293.15 837.30 0.50 -0.42 68-ano-1( ) 372.05 787.20 0.50 0.39 68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 852.65 0.71 300.00 833.30 0.61 350.00 801.04 0.58
280.00 846.20 0.67 310.00 826.84 0.59 360.00 794.58 0.59
290.00 839.75 0.64 320.00 820.39 0.57 370.00 788.13 0.62
293.15 837.72 0.63 330.00 813.94 0.57 380.00 781.68 0.65
298.15 834.49 0.61 340.00 807.49 0.57

Landolt-Brnstein
New Series IV/8D
212 2.17 Alkylcycloalkanes (CnH2n), C26

1,3-Didecylcyclohexane [55334-19-5] C26H52 MW = 364.70 393

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.0702 10-2 (combined temperature ranges,
weighted), c,uw = 1.1356 10-2 (combined
temperature ranges, unweighted).
T = 293.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03311 103
B -7.28326 10-1
C 1.40664 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

372.05 781.60 1.00 -0.00 58-cla/dix( ) 333.15 806.10 1.00 0.02 68-ano-1( )
293.15 831.70 1.00 0.01 68-ano-1( ) 372.05 781.60 1.00 -0.00 68-ano-1( )
310.95 820.20 1.00 -0.03 68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 213

1,3-Didecylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 833.72 1.20 310.00 820.84 1.03 350.00 795.42 1.16
293.15 831.69 1.10 320.00 814.45 1.05 360.00 789.14 1.14
298.15 828.46 1.05 330.00 808.08 1.06 370.00 782.88 1.04
300.00 827.27 1.04 340.00 801.74 1.12 380.00 776.65 1.18

1,4-Didecylcyclohexane [55334-20-8] C26H52 MW = 364.70 394

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.8374 10-1 (combined temperature ranges,
weighted), c,uw = 3.1775 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02007 103
B -6.38915 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

310.95 821.70 0.50 0.30 {


59-dix/cla( ) 310.95 821.70 0.50 0.30
68-ano-1( )
323.15 811.70 1.00 -1.90 66-stu() 333.15 807.60 0.50 0.38
68-ano-1( )
273.15 845.80 0.50 0.25 68-ano-1( ) 372.05 782.70 0.50 0.34
68-ano-1( )
293.15 833.10 0.50 0.33 68-ano-1( )
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 847.56 0.59 300.00 828.40 0.54 350.00 796.45 0.73
280.00 841.17 0.53 310.00 822.01 0.58 360.00 790.06 0.70
290.00 834.78 0.52 320.00 815.62 0.64 370.00 783.67 0.63
293.15 832.77 0.52 330.00 809.23 0.69 380.00 777.28 0.53
298.15 829.58 0.53 340.00 802.84 0.73

cont.

Landolt-Brnstein
New Series IV/8D
214 2.17 Alkylcycloalkanes (CnH2n), C26

1,4-Didecylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,4-Dimethyl-2-octadecylcyclohexane [55282-02-5] C26H52 MW = 364.70 395

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.8504 10-2 (combined temperature ranges,
weighted), c,uw = 4.6516 10-2 (combined
temperature ranges, unweighted).
T = 293.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01544 103
B -6.25066 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 215

1,4-Dimethyl-2-octadecylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

372.05 782.90 4.00 0.02 58-cla/dix() 310.95 821.00 4.00 -0.07


68-ano-1( )
310.95 821.20 4.00 0.13 {
59-dix/cla( ) 333.15 807.20 4.00 0.00
68-ano-1( )
293.15 832.30 4.00 0.10 68-ano-1( ) 372.05 782.70 4.00 -0.18
68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 834.17 4.40 310.00 821.67 4.12 350.00 796.66 4.08
293.15 832.20 4.35 320.00 815.42 4.04 360.00 790.41 4.19
298.15 829.07 4.27 330.00 809.16 4.00 370.00 784.16 4.33
300.00 827.92 4.25 340.00 802.91 4.02 380.00 777.91 4.50

Landolt-Brnstein
New Series IV/8D
216 2.17 Alkylcycloalkanes (CnH2n), C26

1-Dodecyl-4-octylcyclohexane [500033-05-6] C26H52 MW = 350.67 396

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
323.15 811.9 4.00 66-stu

Eicosylcyclohexane [4443-55-4] C26H52 MW = 364.70 397

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.7495 10-2 (combined temperature ranges,
weighted), c,uw = 2.1496 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01345 103
B -6.04594 10-1
C -4.79159 10-5

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 832.00 1.50 -0.09 45-whi/her() 293.15 832.20 0.50 0.11 68-ano-1( )
333.15 806.70 1.00 -0.01 47-sch( ) { 310.95 820.80 0.50 -0.02 68-ano-1( )
372.04 781.90 1.00 0.02 47-sch( ) { 333.15 806.70 0.50 -0.01 68-ano-1( )
273.15 844.70 0.50 -0.03 68-ano-1( ) 372.05 781.90 0.50 0.02 68-ano-1( )
Further references: [57-ano-1, 59-dix/cla].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 846.71 0.89 300.00 827.76 0.77 350.00 795.97 0.78
280.00 840.40 0.81 310.00 821.42 0.78 360.00 789.58 0.79
290.00 834.08 0.77 320.00 815.07 0.79 370.00 783.19 0.83
293.15 832.09 0.77 330.00 808.71 0.79 380.00 776.78 0.92
298.15 828.93 0.77 340.00 802.35 0.78

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 217

Eicosylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(1-Ethyloctadecyl)cyclohexane [4443-57-6] C26H52 MW = 364.70 398

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.5499 10-2 (combined temperature ranges,
weighted), c,uw = 4.7749 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02448 103
B -6.34512 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 851.20 0.50 0.04 68-ano-1( ) 333.15 813.20 0.50 0.11 68-ano-1( )
293.15 838.50 0.50 0.03 68-ano-1( ) 372.05 788.40 0.50 -0.01 68-ano-1( )
310.95 827.00 0.50 -0.18 68-ano-1( )
Further references: [47-sch].

cont.

Landolt-Brnstein
New Series IV/8D
218 2.17 Alkylcycloalkanes (CnH2n), C26

(1-Ethyloctadecyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 853.16 0.59 300.00 834.12 0.51 350.00 802.40 0.55
280.00 846.81 0.55 310.00 827.78 0.50 360.00 796.05 0.58
290.00 840.47 0.53 320.00 821.43 0.50 370.00 789.71 0.61
293.15 838.47 0.52 330.00 815.09 0.51 380.00 783.36 0.65
298.15 835.30 0.51 340.00 808.74 0.52

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 219

(1-Hexyltetradecyl)cyclohexane [4443-60-1] C26H52 MW = 364.70 399

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.4205 10-1 (combined temperature ranges,
weighted), c,uw = 8.7943 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03804 103
B -7.23702 10-1
C 1.29455 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 836.70 0.50 -0.32


49-foe/fen( ) 310.95 825.60 0.50 0.07 68-ano-1( )
273.15 850.20 0.50 0.18 68-ano-1( ) 333.15 811.50 0.50 0.19 68-ano-1( )
293.15 836.90 0.50 -0.12 68-ano-1( ) 372.05 786.70 0.50 -0.01 68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
220 2.17 Alkylcycloalkanes (CnH2n), C26

(1-Hexyltetradecyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 852.08 0.60 300.00 832.58 0.55 350.00 800.61 0.60
280.00 845.56 0.53 310.00 826.14 0.52 360.00 794.29 0.58
290.00 839.06 0.52 320.00 819.72 0.56 370.00 788.00 0.55
293.15 837.02 0.51 330.00 813.32 0.53 380.00 781.73 0.65
298.15 833.78 0.55 340.00 806.95 0.56

1-Hexyl-4-tetradecylcyclohexane [500028-12-6] C26H52 MW = 364.70 400

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
323.15 811.8 4.00 16 -tu -0

8-(4-Methylcyclohexyl)nonadecane [103048-68-6] C26H52 MW = 364.70 401

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0124 10-2 (combined temperature ranges,
weighted), c,uw = 5.8452 10-3 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02133 103
B -6.28034 10-1
C -2.00171 10-5

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 848.30 0.50 0.01


68-ano-1( ) 333.15 809.90 0.50 0.02 68-ano-1( )
293.15 835.50 0.50 -0.01
68-ano-1( ) 372.05 784.90 0.50 -0.00 68-ano-1( )
310.95 824.10 0.50 -0.01
68-ano-1( )
Further references: [59-dix/cla].

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 221

8-(4-Methylcyclohexyl)nonadecane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 850.31 0.68 300.00 831.12 0.53 350.00 799.07 0.56
280.00 843.92 0.57 310.00 824.72 0.55 360.00 792.65 0.58
290.00 837.52 0.53 320.00 818.31 0.56 370.00 786.22 0.64
293.15 835.51 0.53 330.00 811.90 0.57 380.00 779.79 0.77
298.15 832.31 0.53 340.00 805.49 0.56

Landolt-Brnstein
New Series IV/8D
222 2.17 Alkylcycloalkanes (CnH2n), C26

(1-Methylnonadecyl)cyclohexane [4443-56-5] C26H52 MW = 364.70 402

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.4172 10-1 (combined temperature ranges,
weighted), c,uw = 7.0861 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02441 103
B -6.38656 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 850.10 0.50 0.14 68-ano-1( ) 333.15 811.80 0.50 0.16 68-ano-1( )
293.15 837.10 0.50 -0.09 68-ano-1( ) 372.05 786.80 0.50 0.00 68-ano-1( )
310.95 825.60 0.50 -0.22 68-ano-1( )
Further references: [47-sch].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 223

(1-Methylnonadecyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 851.97 0.59 300.00 832.81 0.51 350.00 800.88 0.55
280.00 845.58 0.55 310.00 826.42 0.50 360.00 794.49 0.58
290.00 839.20 0.53 320.00 820.04 0.50 370.00 788.11 0.61
293.15 837.19 0.52 330.00 813.65 0.51 380.00 781.72 0.65
298.15 833.99 0.51 340.00 807.27 0.52

(1-Propylheptadecyl)cyclohexane [4443-58-7] C26H52 MW = 364.70 403

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8888 10-2 (combined temperature ranges,
weighted), c,uw = 2.3237 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02692 103
B -6.43821 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 851.00 0.50 -0.06 68-ano-1( ) 333.15 812.40 0.50 -0.03


68-ano-1( )
293.15 838.20 0.50 0.01 68-ano-1( ) 372.05 787.40 0.50 0.01
68-ano-1( )
310.95 826.80 0.50 0.07 68-ano-1( )
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 853.09 0.56 300.00 833.78 0.53 350.00 801.59 0.53
280.00 846.65 0.54 310.00 827.34 0.52 360.00 795.15 0.55
290.00 840.21 0.53 320.00 820.90 0.52 370.00 788.71 0.58
293.15 838.19 0.53 330.00 814.46 0.51 380.00 782.27 0.65
298.15 834.97 0.53 340.00 808.02 0.52

cont.

Landolt-Brnstein
New Series IV/8D
224 2.17 Alkylcycloalkanes (CnH2n), C26

(1-Propylheptadecyl)cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(1-Octyldodecyl)cyclohexane [4443-61-2] C26H52 MW = 364.70 404

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.8292 10-2 (combined temperature ranges,
weighted), c,uw = 2.2108 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03510 103
B -7.02815 10-1
C 9.31364 10-5

cont.

Landolt-Brnstein
New Series IV/8D
2.17 Alkylcycloalkanes (CnH2n), C26 225

(1-Octyldodecyl)cyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 850.10 0.50 0.03 68-ano-1( ) 333.15 811.30 0.50 0.01


68-ano-1( )
293.15 837.00 0.50 -0.07 68-ano-1( ) 372.05 786.50 0.50 -0.01
68-ano-1( )
310.95 825.60 0.50 0.04 68-ano-1( )
Further references: [59-dix/cla].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 852.13 0.68 300.00 832.63 0.53 350.00 800.52 0.57
280.00 845.61 0.57 310.00 826.17 0.55 360.00 794.15 0.58
290.00 839.11 0.53 320.00 819.73 0.56 370.00 787.81 0.64
293.15 837.07 0.53 330.00 813.31 0.57 380.00 781.48 0.77
298.15 833.83 0.53 340.00 806.91 0.57

Landolt-Brnstein
New Series IV/8D
226 2.17 Alkylcycloalkanes (CnH2n), C26 - 2.18 Alkylcycloalkanes (CnH2n), C27 to C28

Cyclohexacosane [297-16-5] C26H52 MW = 364.70 405

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 1.242.
Coefficient = A + BT
A 1041.48
B -0.650

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

351.15 812.0 0.60 -1.24 30-ruz/sto


385.15 792.4 0.60 1.26 30-ruz/sto
331.15 825.5 3.00 -0.74 34-ruz/hur

Table 3. Recommended values.


T exp 2 est T exp 2 est T exp 2 est
3 3
K kg m K kg m K kg m3
330.00 827.0 3.0 360.00 807.5 2.5 380.00 794.5 2.0
340.00 820.5 3.0 370.00 801.0 3.0 390.00 788.0 3.0
350.00 814.0 2.0

2.18 Alkylcycloalkanes (CnH2n), C27 to C28


(2-Decyldodecyl)cyclopentane [6703-79-3] C27H54 MW = 378.73 406

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.7922 10-1 (combined temperature ranges,
weighted), c,uw = 4.9296 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04299 103
B -7.82119 10-1
C 2.04732 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 844.80 1.00 0.18 47-sch( {) 273.15 844.60 0.50 -0.02 68-ano-1( )
293.15 831.30 1.00 -0.00 47-sch( {) 293.15 831.10 0.50 -0.20 68-ano-1( )
310.93 819.60 1.00 0.01 47-sch( {) 310.95 819.40 0.50 -0.18 68-ano-1( )
333.15 805.40 1.00 0.25 47-sch( {) 333.15 805.20 0.50 0.05 68-ano-1( )
372.04 780.40 1.00 0.06 47-sch( {) 372.05 780.20 0.50 -0.14 68-ano-1( )
cont.

Landolt-Brnstein
New Series IV/8D
2.18 Alkylcycloalkanes (CnH2n), C27 to C28 227

(2-Decyldodecyl)cyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 846.74 0.86 300.00 826.78 0.77 350.00 794.32 0.78
280.00 840.04 0.79 310.00 820.20 0.78 360.00 787.96 0.79
290.00 833.39 0.77 320.00 813.67 0.78 370.00 781.63 0.83
293.15 831.30 0.76 330.00 807.18 0.79 380.00 775.34 0.92
298.15 828.00 0.77 340.00 800.73 0.78

Landolt-Brnstein
New Series IV/8D
228 2.18 Alkylcycloalkanes (CnH2n), C27 to C28

(1-Decylundecyl)cyclohexane [6703-99-7] C27H54 MW = 378.73 407

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0512 10-1 (combined temperature ranges,
weighted), c,uw = 6.0037 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02149 103
B -6.28259 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 837.30 0.40 -0.02 46-par/wes( ){ 310.95 826.10 0.50 -0.03 68-ano-1()
293.15 837.30 0.05 -0.02 49-foe/fen( ) 333.15 812.10 0.50 -0.09 68-ano-1()
273.15 850.10 0.50 0.22 68-ano-1() 372.05 787.50 0.50 -0.25 68-ano-1()
293.15 837.50 0.50 0.18 68-ano-1()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
2.18 Alkylcycloalkanes (CnH2n), C27 to C28 229

(1-Decylundecyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 851.86 0.42 300.00 833.01 0.44 350.00 801.60 0.51
280.00 845.58 0.39 310.00 826.73 0.45 360.00 795.32 0.53
290.00 839.30 0.30 320.00 820.45 0.46 370.00 789.04 0.55
293.15 837.32 0.20 330.00 814.17 0.48 380.00 782.75 0.58
298.15 834.18 0.35 340.00 807.88 0.50

1,3,5-Trimethyl-2-octadecylcyclohexane [55282-34-3] C27H54 MW = 378.73 408

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.4678 10-3 (combined temperature ranges,
weighted), c,uw = 2.4521 10-3 (combined
temperature ranges, unweighted).
T = 293.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03412 103
B -7.30802 10-1
C 1.68875 10-4

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1)

293.15 834.40 4.00 0.00 68-ano-1( )


310.95 823.20 4.00 -0.01 68-ano-1( )
333.15 809.40 4.00 0.00 68-ano-1( )
372.05 785.60 4.00 -0.00 68-ano-1( )
Further references: [58-cla/dix, 59-dix/cla].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 836.39 4.70 310.00 823.80 4.54 350.00 799.03 4.59
293.15 834.40 4.64 320.00 817.56 4.57 360.00 792.92 4.58
298.15 831.24 4.57 330.00 811.35 4.60 370.00 786.84 4.63
300.00 830.08 4.56 340.00 805.17 4.60 380.00 780.80 4.81

cont.
Landolt-Brnstein
New Series IV/8D
230 2.18 Alkylcycloalkanes (CnH2n), C27 to C28

1,3,5-Trimethyl-2-octadecylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(1-Butyloctadecyl)cyclohexane [500028-14-8] C28H56 MW = 392.75 409

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 839.5 0.50 36-mik

Landolt-Brnstein
New Series IV/8D
2.18 Alkylcycloalkanes (CnH2n), C27 to C28 231

(2-Decyldodecyl)cyclohexane [6704-00-3] C28H56 MW = 392.75 410

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.1014 10-1 (combined temperature ranges,
weighted), c,uw = 3.8448 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01860 103
B -6.27710 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1)

273.15 847.20 0.50 0.06 68-ano-1( )


293.15 834.50 0.50 -0.09 68-ano-1( )
310.95 823.40 0.50 -0.02 68-ano-1( )
333.15 809.60 0.50 0.12 68-ano-1( )
372.05 785.00 0.50 -0.06 68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
232 2.18 Alkylcycloalkanes (CnH2n), C27 to C28

(2-Decyldodecyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 849.12 0.57 300.00 830.29 0.53 350.00 798.91 0.58
280.00 842.85 0.55 310.00 824.01 0.51 360.00 792.63 0.60
290.00 836.57 0.53 320.00 817.74 0.55 370.00 786.35 0.58
293.15 834.59 0.51 330.00 811.46 0.52 380.00 780.07 0.65
298.15 831.45 0.52 340.00 805.18 0.55

Docosylcyclohexane [61828-07-7] C28H56 MW = 392.75 411

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 832.7 2.00 36-mik

Cyclooctacosane [297-24-5] C28H56 MW = 392.75 412

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.230.
Coefficient = A + BT
A 1043.27
B -0.660

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

353.15 810.3 2.00 0.11 30-ruz/sto


349.15 813.0 3.00 0.17 30-ruz/sto
331.15 824.3 3.00 -0.41 34-ruz/hur

Table 3. Recommended values.


T exp 2 est
K kg m3
330.00 825.5 3.0
340.00 818.9 3.0
350.00 812.3 3.0
360.00 805.7 3.5

Landolt-Brnstein
New Series IV/8D
2.19 Alkylcycloalkanes (CnH2n), C29 233

2.19 Alkylcycloalkanes (CnH2n), C29


1-(2-Decyldodecyl)- [55429-26-0] C29H58 MW = 406.78 413
2,4-dimethylcyclopentane

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.9939 10-2 (combined temperature ranges,
weighted), c,uw = 3.7280 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01213 103
B -6.34881 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1)

273.15 838.80 4.00 0.08 68-ano-1( )


293.15 826.00 4.00 -0.02 68-ano-1( )
310.95 814.60 4.00 -0.12 68-ano-1( )
333.15 800.70 4.00 0.08 68-ano-1( )
372.05 775.90 4.00 -0.03 68-ano-1( )
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 840.72 4.10 300.00 821.67 4.06 350.00 789.93 4.15
280.00 834.37 4.10 310.00 815.32 4.02 360.00 783.58 4.15
290.00 828.02 4.06 320.00 808.97 4.06 370.00 777.23 4.08
293.15 826.02 4.02 330.00 802.62 4.02 380.00 770.88 4.21
298.15 822.84 4.05 340.00 796.27 4.10

cont.

Landolt-Brnstein
New Series IV/8D
234 2.19 Alkylcycloalkanes (CnH2n), C29

1-(2-Decyldodecyl)-2,4-dimethylcyclopentane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(2-Decyldodecyl)-2,4-dimethyl [500023-53-0] C29H58 MW = 406.78 414


cyclopentane

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.0660 10-2 (combined temperature ranges,
weighted), c,uw = 3.8848 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.04 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.01220 103
B -6.35102 10-1

cont.

Landolt-Brnstein
New Series IV/8D
2.19 Alkylcycloalkanes (CnH2n), C29 235

(2-Decyldodecyl)-2,4-dimethylcyclopentane (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1)

273.15 838.80 4.00 0.08 52-ano( )


293.15 826.00 4.00 -0.02 52-ano( )
310.93 814.60 4.00 -0.13 52-ano( )
333.15 800.70 4.00 0.08 52-ano( )
372.04 775.90 4.00 -0.02 52-ano( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
236 2.19 Alkylcycloalkanes (CnH2n), C29

(2-Decyldodecyl)-2,4-dimethylcyclopentane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 840.72 4.10 300.00 821.67 4.06 350.00 789.91 4.16
280.00 834.37 4.10 310.00 815.32 4.03 360.00 783.56 4.19
290.00 828.02 4.05 320.00 808.97 4.10 370.00 777.21 4.14
293.15 826.02 4.03 330.00 802.62 4.05 380.00 770.86 4.21
298.15 822.84 4.05 340.00 796.26 4.10

2-(1-Decylundecyl)- [55429-27-1] C29H58 MW = 406.78 415


1,4-dimethylcyclohexane

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.5967 10-2 (combined temperature ranges,
weighted), c,uw = 3.3942 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.04 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02436 103
B -6.31938 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1)

273.15 851.80 4.00 0.06 48-ano( )


293.15 839.00 4.00 -0.11 48-ano( )
310.93 827.90 4.00 0.03 48-ano( )
333.15 813.90 4.00 0.07 48-ano( )
372.04 789.20 4.00 -0.05 48-ano( )

cont.

Landolt-Brnstein
New Series IV/8D
2.19 Alkylcycloalkanes (CnH2n), C29 237

2-(1-Decylundecyl)-1,4-dimethylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 853.73 4.10 300.00 834.78 4.06 350.00 803.18 4.16
280.00 847.42 4.10 310.00 828.46 4.02 360.00 796.86 4.15
290.00 841.10 4.06 320.00 822.14 4.10 370.00 790.54 4.08
293.15 839.11 4.02 330.00 815.82 4.04 380.00 784.22 4.21
298.15 835.95 4.05 340.00 809.50 4.12

Landolt-Brnstein
New Series IV/8D
238 2.19 Alkylcycloalkanes (CnH2n), C29 - 2.20 Alkylcycloalkanes (CnH2n), C30 to C32

Cyclononacosane [500028-10-4] C29H58 MW = 406.78 416

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.380.
Coefficient = A + BT
A 1045.34
B -0.660
Table 2. Experimental values with uncertainties and
deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

337.15 823.2 3.00 0.38 30-ruz/sto


306.15 842.9 3.00 -0.38 30-ruz/sto

Table 3. Recommended values.


T exp 2 est
K kg m3
298.15 848.6 3.5
310.00 840.7 3.0
320.00 834.1 3.5
330.00 827.5 3.5
340.00 820.9 3.5

2.20 Alkylcycloalkanes (CnH2n), C30 to C32


Cyclotriacontane [297-35-8] C30H60 MW = 420.81 417
Table 1. Coefficients of the polynomial expansion
equation. Standard deviations (see introduction):
c,w = 8.5363 10-1 (combined temperature ranges,
weighted), c,uw = 2.7598 10-1 (combined
temperature ranges, unweighted).
T = 331.15 to 384.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04482 103
B -6.45931 10-1
Table 2. Experimental values with uncertainties and
deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1)

331.15 830.80 1.00 -0.12 30-ruz/sto( )


342.15 823.30 1.00 -0.52 30-ruz/sto( )
350.15 818.00 1.00 -0.65 30-ruz/sto( )
384.15 797.30 1.00 0.61 30-ruz/sto( )
346.15 821.90 1.00 0.67 34-ruz/hur( )
cont.

Landolt-Brnstein
New Series IV/8D
2.20 Alkylcycloalkanes (CnH2n), C30 to C32 239

Cyclotriacontane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
330.00 831.66 1.80 360.00 812.29 1.20 380.00 799.37 2.30
340.00 825.20 1.30 370.00 805.83 1.70 390.00 792.91 3.00
350.00 818.74 1.00

Landolt-Brnstein
New Series IV/8D
240 2.20 Alkylcycloalkanes (CnH2n), C30 to C32

(1-Dodecyltridecyl)cyclohexane [6697-15-0] C31H62 MW = 434.83 418

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.6490 10-1 (combined temperature ranges,
weighted), c,uw = 6.8543 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02465 103
B -6.33029 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 839.48 0.50 0.40 46-par/wes() 310.95 827.80 0.50 -0.01 68-ano-1( ) {
293.15 839.00 0.30 -0.08 49-foe/fen( ) 333.15 813.70 0.50 -0.06 68-ano-1( ) {
273.15 851.60 0.50 -0.14 68-ano-1( ) { 372.05 789.10 0.50 -0.03 68-ano-1( ) {
293.15 839.00 0.50 -0.08 68-ano-1( ) {

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.
Landolt-Brnstein
New Series IV/8D
2.20 Alkylcycloalkanes (CnH2n), C30 to C32 241

(1-Dodecyltridecyl)cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 853.73 0.55 300.00 834.74 0.54 350.00 803.09 0.55
280.00 847.40 0.53 310.00 828.41 0.50 360.00 796.76 0.58
290.00 841.07 0.51 320.00 822.08 0.53 370.00 790.43 0.55
293.15 839.08 0.50 330.00 815.75 0.50 380.00 784.10 0.66
298.15 835.91 0.53 340.00 809.42 0.53

(1-Butyldocosyl)cyclohexane [500028-15-9] C32H64 MW = 448.86 419

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 837.2 0.50 36-mik

Cyclodotriacontane [297-39-2] C32H64 MW = 448.86 420

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
343.15 826.1 3.00 34-ruz/hur

1,16-Dimethylcyclotriacontane [500032-27-9] C32H64 MW = 448.86 421

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.755.
Coefficient = A + BT
A 1060.96
B -0.700

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

362.45 808.0 3.00 0.76 31-ruz/boe


353.15 813.0 3.00 -0.75 31-ruz/boe

cont.

Landolt-Brnstein
New Series IV/8D
242 2.20 Alkylcycloalkanes (CnH2n), C30 to C32 - 2.21 Alkylcycloalkanes (CnH2n), C34 to C39

1,16-Dimethylcyclotriacontane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
350.00 816.0 3.5
360.00 809.0 3.0
370.00 802.0 4.0

2.21 Alkylcycloalkanes (CnH2n), C34 to C39


Cyclotetratriacontane [297-47-2] C34H68 MW = 476.91 422

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
349.15 822.9 3.00 34-ruz/hur

(1-Tetradecylpentadecyl) cyclohexane [55521-27-2] C35H70 MW = 490.94 423

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.2334 10-2 (combined temperature ranges,
weighted), c,uw = 1.6280 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02165 103
B -6.18392 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1)

273.15 852.70 0.50 -0.04 )


68-ano-1(
293.15 840.40 0.50 0.03 )
68-ano-1(
310.95 829.40 0.50 0.03 )
68-ano-1(
333.15 815.60 0.50 -0.04 )
68-ano-1(
372.05 791.60 0.50 0.02 )
68-ano-1(

cont.

Landolt-Brnstein
New Series IV/8D
2.21 Alkylcycloalkanes (CnH2n), C34 to C39 243

(1-Tetradecylpentadecyl) cyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 854.69 0.56 300.00 836.14 0.54 350.00 805.22 0.57
280.00 848.51 0.54 310.00 829.95 0.52 360.00 799.03 0.58
290.00 842.32 0.52 320.00 823.77 0.55 370.00 792.85 0.56
293.15 840.37 0.52 330.00 817.59 0.52 380.00 786.67 0.65
298.15 837.28 0.53 340.00 811.40 0.55

Landolt-Brnstein
New Series IV/8D
244 2.21 Alkylcycloalkanes (CnH2n), C34 to C39

(1-Hexadecylheptadecyl) cyclohexane [55517-75-4] C39H78 MW = 547.05 424

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.1529 10-2 (combined temperature ranges,
weighted), c,uw = 7.3823 10-3 (combined
temperature ranges, unweighted).
T = 273.15 to 372.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02020 103
B -6.08493 10-1

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1)

273.15 854.00 0.50 0.01 68-ano-1( )


293.15 841.80 0.50 -0.02 68-ano-1( )
310.95 831.00 0.50 0.01 68-ano-1( )
333.15 817.50 0.50 0.02 68-ano-1( )
372.05 793.80 0.50 -0.01 68-ano-1( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
2.21 Alkylcycloalkanes (CnH2n), C34 to C39 245

(1-Hexadecylheptadecyl) cyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 855.91 0.56 300.00 837.65 0.55 350.00 807.23 0.57
280.00 849.82 0.56 310.00 831.57 0.51 360.00 801.14 0.58
290.00 843.74 0.54 320.00 825.48 0.53 370.00 795.06 0.56
293.15 841.82 0.52 330.00 819.40 0.51 380.00 788.97 0.61
298.15 838.78 0.54 340.00 813.31 0.55

Landolt-Brnstein
New Series IV/8D
3. Tabulated Data on Density -
Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2)
3.1 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C4 to C5 249

3.1 Alkylcycloalkanes and Alkenylcycloalkanes (CnH2n-2), C4 to C5


Methylenecyclopropane [6142-73-0] C4H6 MW = 54.09 425

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
273.15 718.0 2.00 53-gra/gre

Cyclobutene [822-35-5] C4H6 MW = 54.09 426

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
273.15 733.0 3.00 07-wil/bru

Ethenylclopropane [693-86-7] C5H8 MW = 68.12 427

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 2.515.
Coefficient = A + BT
A 1011.16
B -1.000

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K 3
kg m kg m3 K kg m 3
kg m3

291.15 723.0 2.00 2.99 22-dem/doj 273.15 741.5 2.00 3.49 22-dem/doj
288.15 726.0 2.00 2.99 22-dem/doj 293.15 716.0 0.80 -2.01 49-van/gre-1
283.15 731.1 2.00 3.09 22-dem/doj

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 741.2 2.6
280.00 731.2 2.5
290.00 721.2 2.5
293.15 718.0 2.5
298.15 713.0 2.5

Ethylidenecyclopropane [18631-83-9] C5H8 MW = 68.12 428

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
291.15 705.2 2.00 1896-gus
273.15 723.5 2.00 1896-gus

Landolt-Brnstein
New Series IV/8D
250 3.1 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C4 to C5

1-Methylcyclobutene [1489-60-7] C5H8 MW = 68.12 429

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
296.15 707.5 2.00 13-phi-1

Methylenecyclobutane [1120-56-5] C5H8 MW = 68.12 430

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.5473 (combined temperature ranges,
weighted), c,uw = 5.5442 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 296.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02166 103
B -9.65797 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

296.15 736.00 1.50 0.36 14-phi-2() 273.15 758.30 1.50 0.44 22-dem/doj1-( ) {
273.15 758.50 2.00 0.64 17-dem/doj() 293.15 735.70 1.50 -2.84 51-slo/sho()
283.15 748.70 2.00 0.50 17-dem/doj() 293.15 740.30 1.00 1.76 66-dya/luk( )
288.15 742.50 2.00 -0.87 17-dem/doj()

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 760.90 2.10 290.00 741.58 1.80 298.15 733.71 1.70
280.00 751.24 2.10 293.15 738.54 1.70 300.00 731.92 2.00

cont.

Landolt-Brnstein
New Series IV/8D
3.1 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C4 to C5 251

Methylenecyclobutane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Cyclopentene [142-29-0] C5H8 MW = 68.12 431

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.0869 10-1 (combined temperature ranges,
weighted), c,uw = 1.4853 10-1 (combined
temperature ranges, unweighted).
T = 259.35 to 308.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.02675 102
B 1.68263 10-1
C -2.09440 10-3

cont.

Landolt-Brnstein
New Series IV/8D
252 3.1 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C4 to C5

Cyclopentene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

279.90 786.40 0.60 0.71 18-von-2( ) 308.15 756.00 0.50 0.35 47-huc/har( )
280.25 786.10 0.60 0.76 18-von-2( ) 293.15 771.80 0.40 -0.21 49-foe/fen()
293.15 776.00 2.00 3.99 18-von-21) 303.15 760.60 0.50 -0.61 49-wei( )
290.35 775.60 0.50 0.64 38-vog( ) 293.15 771.97 0.15 -0.04 50-for/cam( )
291.05 775.30 0.50 1.07 38-vog( ) 298.15 766.51 0.15 -0.15 50-for/cam( )
293.15 773.60 0.50 1.59 38-vog1) 303.15 761.22 0.15 0.01 50-for/cam( )
293.15 771.80 0.30 -0.21 43-ano() 273.15 792.27 0.20 -0.10 55-tim/hen( ) {
293.15 772.40 0.40 0.39 46-ger/van() 288.15 776.71 0.20 -0.55 55-tim/hen( ) {
259.35 804.80 0.50 -0.64 47-huc/har( ) 303.15 761.01 0.20 -0.20 55-tim/hen( ) {
289.35 774.80 0.50 -1.21 47-huc/har( )
1)
Not included in Fig. 1.
Further references: [08-har/tan, 14-phi-1, 18-von-1, 26-doj-1, 27-doj, 30-god/cau, 33-hof/lan, 34-god,
38-car/stu, 42-ano-2, 46-mou, 50-kaz/ter, 56-pla/sta, 60-shu/nar, 65-sam/ogl, 72-sid/mir].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
3.1 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C4 to C5 - 253
3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6
Cyclopentene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
250.00 813.84 0.82 290.00 775.33 0.38 300.00 764.66 0.34
260.00 804.84 0.59 293.15 772.01 0.37 310.00 753.56 0.37
270.00 795.42 0.47 298.15 766.66 0.35 320.00 742.05 0.54
280.00 785.59 0.42

3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6


(1-Methylethenyl)cyclopropane [4663-22-3] C6H10 MW = 82.15 432

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 751.0 1.00 11-kis/kla
293.15 745.0 1.00 29-van
293.15 751.5 0.50 49-sla/wis
293.15 751.4 0.50 49-van/gre
293.15 751.3 1.00 61-luk/zot
293.15 751.3 0.50 Recommended

(1-Methylethylidene)cyclopropane [4741-86-0] C6H10 MW = 82.15 433

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 753.1 1.50 05-ale

Ethylidenecyclobutane [1528-21-8] C6H10 MW = 82.15 434

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 767.8 0.50 49-der/gre

Landolt-Brnstein
New Series IV/8D
254 3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6

1-Methylcyclopentene [693-89-0] C6H10 MW = 82.15 435

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.6454 (combined temperature ranges,
weighted), c,uw = 5.1766 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.05567 103
B -9.40052 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 797.90 0.70 -1.00 28-cha/dev( ) 293.15 780.20 0.50 0.10 43-ano-3( )
286.65 791.20 0.70 4.99 30-god/cau( ) 293.15 780.20 0.60 0.10 46-boo/gre( )
286.65 791.20 0.70 4.99 34-god( ) 293.15 780.20 0.40 0.10 49-boo/hen()
294.15 747.40 0.70 -31.76 34-god1) 293.15 775.80 0.60 -4.30 49-spe( )
293.15 779.00 0.60 -1.10 34-zel/tar( ) 293.15 779.90 0.40 -0.20 51-ano( ){
273.15 798.61 0.15 -0.29 37-tim/hen( ) 293.15 779.50 0.40 -0.60 61-ano-9()
288.15 784.50 0.15 -0.30 37-tim/hen( ) 293.15 780.00 0.60 -0.10 64-shu/kho( )
303.15 770.46 0.15 -0.24 37-tim/hen( ) 293.15 779.50 0.60 -0.60 65-ogl/pot( )
293.15 779.10 0.50 -1.00 39-gro/wac() 293.15 779.50 0.60 -0.60 65-sam/ogl( )
1) Not included in Fig. 1.

Further references: [1899-mar-1, 02-zel, 12-mey-1, 33-hof/lan, 44-tat/mel, 44-tat/ter, 46-mou, 47-
tat/mel, 48-adk/roe, 49-coo, 51-pet/jur, 51-shu/min, 51-zel, 53-lev/mez, 53-pla/lib, 60-shu/nar, 64-
mar/vel, 72-sad/ali].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 801.86 0.75 293.15 780.10 0.51 300.00 773.66 0.62
280.00 792.46 0.70 298.15 775.40 0.48 310.00 764.26 1.14
290.00 783.06 0.56

cont.

Landolt-Brnstein
New Series IV/8D
3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6 255

1-Methylcyclopentene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

3-Methylcyclopentene [1120-62-3] C6H10 MW = 82.15 436

Table 1. Fit with estimated B coefficient for 15


accepted points. Deviation w = 3.141.
Coefficient = A + BT
A 1057.83
B -1.000

cont.

Landolt-Brnstein
New Series IV/8D
256 3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6

3-Methylcyclopentene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3 kg m3 K kg m3 kg m3

293.15 785.1 5.00 20.42 1893-sem1) 293.15 768.2 0.70 3.52 49-coo
291.15 766.3 1.00 -0.38 02-zel 293.15 765.4 1.00 0.72 53-pla/lib
293.15 787.4 5.00 22.72 37-von/kam1) 293.15 763.8 1.00 -0.91 60-cam
293.15 770.5 2.00 5.82 38-vog 298.15 758.6 1.00 -1.10 60-cam
292.05 771.5 2.00 5.72 38-vog 293.15 770.9 1.00 6.22 60-nar/shu
293.15 762.2 1.00 -2.48 41-cra 293.15 764.7 2.00 0.02 60-pla/sta
293.15 762.2 0.50 -2.48 45-cra/boo 293.15 760.0 2.00 -4.68 64-bro/ayy
298.15 769.0 2.00 9.32 46-mou 293.15 764.4 1.00 -0.28 64-mar/vel
293.15 761.6 1.00 -3.08 48-lut/bea-1
1)
Not included in calculation of linear coefficinets.

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 767.8 3.1
293.15 764.7 3.1
298.15 759.7 3.1

4-Methylcyclopentene [1759-81-5] C6H10 MW = 82.15 437

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 5.976.
Coefficient = A + BT
A 1062.22
B -1.000

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

292.15 772.6 1.00 2.53 02-zel 293.15 764.0 0.70 -5.07 49-coo
289.15 781.0 2.00 7.93 35-god/mou 293.15 781.0 3.00 11.93 51-ano1)
289.15 784.0 2.00 10.93 35-god/mou 293.15 768.4 2.00 -0.71 60-cam
298.15 778.0 2.00 13.93 46-mou 298.15 763.3 2.00 -0.79 60-cam
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 782.2 6.0
290.00 772.2 6.0
293.15 769.1 6.0
298.15 764.1 6.0

Landolt-Brnstein
New Series IV/8D
3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6 257

Methylenecyclopentane [1528-30-9] C6H10 MW = 82.15 438

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.0279 (combined temperature ranges,
weighted), c,uw = 7.8503 10-1 (combined
temperature ranges, unweighted).
T = 293.15 to 317.95 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.12043 103
B -1.16019

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 778.00 1.50 -2.32 12-von/ell( ) 317.95 751.80 1.00 0.26 38-vog( ) {
293.15 778.70 1.00 -1.62 33-vog( ) 293.15 780.60 1.00 0.28 52-van/koo()
293.95 777.80 1.00 -1.59 38-vog( ){ 293.15 780.30 1.00 -0.02 53-lev/mez()
315.85 754.10 1.00 0.12 38-vog( ){ 293.15 785.20 1.00 4.88 53-sor/ber()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
258 3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6

Methylenecyclopentane (cont.)
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
290.00 783.97 1.14 298.15 774.52 1.07 310.00 760.77 1.09
293.15 780.32 1.10 300.00 772.37 1.06 320.00 749.17 1.23
Cyclohexene [110-83-8] C6H10 MW = 82.15 439
Table 1. Coefficients of the polynomial expansion
equation. Standard deviations (see introduction):
c,w = 3.6310 (combined temperature ranges,
weighted), c,uw = 5.7829 10-1 (combined
temperature ranges, unweighted).
T = 254.15 to 353.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 3.30584 103
B -2.33992 101
C 7.53148 10-2
D -8.36824 10-5
Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

323.15 782.30 0.70 -3.04 38-eva( ) 350.75 756.40 0.60 3.16 47-huc/har( )
293.15 808.80 0.80 -1.74 38-vog1) 293.15 810.94 0.15 0.40 50-for/cam( )
295.85 806.40 0.80 -1.95 38-vog1) 298.15 806.07 0.15 -0.42 50-for/cam( )
314.35 789.60 0.80 -3.61 38-vog1) 303.15 801.39 0.15 -1.07 50-for/cam( )
315.05 789.00 0.80 -3.61 38-vog1) 273.15 828.93 0.20 0.71 55-tim/hen( )
332.95 773.10 0.80 -2.40 38-vog( ) 288.15 815.04 0.20 0.37 55-tim/hen( )
334.25 772.00 0.80 -2.09 38-vog( ) 303.15 801.34 0.20 -1.12 55-tim/hen( )
334.95 771.30 0.80 -2.01 38-vog( ) 298.15 810.40 0.50 3.91 60-wri1) 2)
293.15 810.75 0.20 0.21 41-ano-1() 313.15 790.90 0.70 -3.33 60-wri1) 2)
273.15 831.00 0.70 2.78 44-can( ) 333.15 771.40 0.70 -3.88 60-wri( )2)
293.15 812.90 0.70 2.36 44-can1) 353.15 751.90 0.80 2.22 60-wri( )2)
313.15 793.90 0.70 -0.33 44-can1) 273.15 829.90 0.40 1.68 60-wri( )2)
291.85 810.50 0.50 -1.10 44-fri/har1) 273.15 829.90 0.50 1.68 61-wri( )2)
314.75 789.20 0.50 -3.67 44-fri/har( ) 298.15 805.66 0.20 -0.83 70-har/dun()
323.15 781.90 0.50 -3.44 44-fri/har( ) 299.29 814.50 0.30 8.93 74-let/mar1)
333.35 771.60 0.50 -3.47 44-fri/har( ) 307.25 806.70 0.30 7.56 74-let/mar( )
342.90 762.10 0.50 -1.78 44-fri/har( ) 315.28 799.30 0.30 6.89 74-let/mar( )
352.75 752.50 0.50 2.22 44-fri/har( ) 323.61 790.70 0.30 5.79 74-let/mar( )
254.15 848.10 0.60 -1.85 47-huc/har( ) 298.15 806.00 0.20 -0.49 75-let()
287.85 815.80 0.60 0.87 47-huc/har1) 298.15 805.88 0.20 -0.61 86-tar/dia( ){
319.15 785.50 0.60 -3.51 47-huc/har( )
1) 2)
Not included in Fig. 1. Calculated from equation given by author. cont.

Landolt-Brnstein
New Series IV/8D
3.2 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C6 259

Cyclohexene (cont.)
Further references: [1894-bru-1, 1898-for, 1898-mar, 1898-mar-1, 01-zel/zel-1, 07-eyk, 09-eyk, 10-ipa,
11-ski/rit, 15-rot/von, 15-von/hin, 21-far/gar, 24-nam, 24-zel, 26-mat, 26-wei/hen, 28-tre/sch, 29-bod, 30-
god/cau, 34-god, 35-mam, 37-car/stu, 38-car/stu, 39-gro/wac, 42-gei, 46-gei/can, 48-adk/roe, 49-foe/fen,
49-wei, 51-ano, 60-jef, 69-rod/hsu, 82-gro/ing, 86-cod/mon, 87-let/bax, 89-bec/ric, 89-mat/gon, 93-
jan/xie].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
250.00 855.69 1.60 293.15 810.54 0.44 330.00 778.61 1.75
260.00 842.54 0.85 298.15 806.49 0.46 340.00 767.47 2.60
270.00 831.40 0.58 300.00 805.00 0.47 350.00 754.32 3.30
280.00 821.76 0.46 310.00 796.87 0.67 360.00 738.66 3.60
290.00 813.13 0.43 320.00 788.24 1.10

Landolt-Brnstein
New Series IV/8D
260 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7


(1-Ethyl-1-propenyl)cyclopropane [500030-92-2] C7H12 MW = 96.17 440

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 764.4 3.00 09-bru
293.15 791.5 3.00 29-van

(1-Methyl-1-propenyl)cyclopropane [500030-91-1] C7H12 MW = 96.17 441

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 780.4 1.50 29-van

(1-Propylethenyl)cyclopropane [5809-54-1] C7H12 MW = 96.17 442

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 777.2 1.50 29-van

(1-Methylethylidene)cyclobutane [1528-22-9] C7H12 MW = 96.17 443

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 782.3 0.50 49-der/gre
293.15 784.2 1.00 55-kaz/luk
293.15 782.7 0.8 Recommended

1,2-Dimethylcyclopentene [765-47-9] C7H12 MW = 96.17 444

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.2894 (combined temperature ranges,
weighted), c,uw = 3.8151 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.05315 103
B -8.81671 10-1

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 261

1,2-Dimethylcyclopentene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 792.20 1.00 -2.49 08-kis( ) 288.15 799.50 0.60 0.40 {


38-chi-1( )
286.65 799.10 3.00 -1.32 08-kis-3( ) 293.15 795.00 0.60 0.31 {
38-chi-1( )
293.15 792.20 3.00 -2.49 08-kis-31) 303.15 786.10 0.60 0.23 {
38-chi-1( )
293.15 792.00 2.00 -2.69 12-von/moo-1( ) 293.15 793.00 2.00 -1.69 41-tur/vse( )
293.15 795.30 0.70 0.61 28-cha/dev() 293.15 797.60 0.50 2.91 45-ano( )
288.15 799.80 1.00 0.70 30-cha() 293.15 795.40 1.00 0.71 50-kaz/kop( )
293.15 794.70 0.70 0.01 30-cha() 293.15 796.10 1.00 1.41 52-pla/sav()
273.15 812.80 0.60 0.48 {
38-chi-1( ) 293.15 795.10 2.00 0.41 64-mir/kos-1( )
1) Not included in Fig. 1.

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
262 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

1,2-Dimethylcyclopentene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 815.10 0.57 293.15 794.69 1.11 300.00 788.65 0.65
280.00 806.28 1.86 298.15 790.28 0.71 310.00 779.83 1.81
290.00 797.47 1.44

1,4-Dimethylcyclopentene [19550-48-2] C7H12 MW = 96.17 445

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 771.5 4.00 50-kaz/kop
293.15 771.4 4.00 50-kop/noz
293.15 774.8 4.00 52-naz/kot
293.15 772.6 4.2 Recommended

1,5-Dimethylcyclopentene [16491-15-9] C7H12 MW = 96.17 446

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 7.5335 10-1 (combined temperature ranges,
weighted), c,uw = 8.6155 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04621 103
B -9.07246 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 783.10 3.00 2.85 30-cha() 303.15 771.60 0.60 0.43 38-chi-1( )
273.15 798.50 0.60 0.11
38-chi-1( ) 298.15 771.00 2.00 -4.71 48-adk/roe()
288.15 785.10 0.60 0.32
38-chi-1( ) 293.15 780.90 1.00 0.65 64-mir/kos-1( ) {
293.15 780.60 0.60 0.35
38-chi-1( )

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 263

1,5-Dimethylcyclopentene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 801.25 2.67 293.15 780.25 1.58 300.00 774.03 1.65
280.00 792.18 0.32 298.15 775.71 1.89 310.00 764.96 0.50
290.00 783.10 0.96

3,3-Dimethylcyclopentene [58049-91-5] C7H12 MW = 96.17 447

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 757.9 1.00 08-kis
293.15 758.0 2.00 12-von/moo
293.15 757.9 1.0 Recommended

Landolt-Brnstein
New Series IV/8D
264 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

3,5-Dimethylcyclopentene [7459-71-4] C7H12 MW = 96.17 448

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 4.451.
Coefficient = A + BT
A 1037.60
B -0.800

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

291.15 800.5 4.00 -4.18 1897-kno 291.55 807.4 4.00 3.04 10-von/pet-2
293.75 806.5 4.00 3.90 10-von/pet-2 294.25 797.0 4.00 -5.20 15-von/hin
292.55 806.2 4.00 2.64 10-von/pet-2 288.75 800.9 4.00 -5.70 15-von/hin
291.25 810.1 4.00 5.50 10-von/pet-2 293.15 759.0 20.00 -44.08 51-lev/skv-21)
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 813.6 4.5
290.00 805.6 4.5
293.15 803.1 4.5
298.15 799.1 4.5

Ethenylcyclopentane [3742-34-5] C7H12 MW = 96.17 449

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m 3

293.15 779.6 1.00 50-pla/sha


293.15 783.5 1.00 52-van/koo
293.15 783.4 1.00 53-lev/mez
293.15 782.2 1.2 Recommended

1-Ethylcyclopentene [2146-38-5] C7H12 MW = 96.17 450

Table 1. Fit with estimated B coefficient for 12


accepted points. Deviation w = 0.837.
Coefficient = A + BT
A 1032.07
B -0.800

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 265

1-Ethylcyclopentene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3
kg m3 K kg m 3
kg m3

293.15 797.5 0.70 -0.05 09-wal/mar 293.15 796.8 1.00 -0.75 51-shu/min
293.15 796.0 2.00 -1.55 12-von/moo1) 293.15 796.8 1.00 -0.75 51-zel
288.15 804.1 1.00 2.55 27-cha/bec 293.15 796.3 0.70 -1.25 52-van/koo
293.15 800.0 1.00 2.45 27-cha/bec 293.15 801.5 2.00 3.95 53-lev/mez1)
293.15 792.0 2.00 -5.55 35-huc/kum1) 293.15 797.9 0.40 0.35 59-pla/mel
293.15 805.3 2.00 7.75 39-gro/wac1) 293.15 797.6 0.60 0.05 60-nar/shu
293.15 797.0 0.30 -0.55 43-ano-3 293.15 796.4 1.50 -1.15 65-ogl/pot
293.15 798.2 0.40 0.65 46-ano 293.15 796.4 1.50 -1.15 65-sam/ogl
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 808.1 1.1
290.00 800.1 0.9
293.15 797.6 0.8
298.15 793.6 0.9

3-Ethylcyclopentene [694-35-9] C7H12 MW = 96.17 451

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref. T exp 2 est Ref.
K kg m3 K kg m3
293.15 787.4 2.00 37-von/kam1) 293.15 782.7 0.40 53-ano-1
293.15 783.0 0.50 45-cra/boo 293.15 783.5 1.00 53-lev/mez
298.15 784.0 4.00 48-adk/roe1) 293.15 792.8 4.00 53-lev/tan-11)
293.15 783.0 0.40 53-ano-1 293.15 782.9 0.4 Recommended
1)
Not included in calculation of recommended value.

Ethylidenecyclopentane [2146-37-4] C7H12 MW = 96.17 452

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 802.0 2.00 09-wal/mar
293.15 803.0 1.00 52-van/koo
293.15 802.8 1.0 Recommended

Landolt-Brnstein
New Series IV/8D
266 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

1-Methyl-3-methylenecyclopentane [53366-56-6] C7H12 MW = 96.17 453

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
292.15 773.4 1.00 01-zel-2
289.15 775.0 1.00 02-spe

Methylenecyclohexane [1192-37-6] C7H12 MW = 96.17 454

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.8327 (combined temperature ranges,
weighted), c,uw = 5.3327 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 334.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03175 103
B -7.78988 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 818.40 6.00 -0.57 07-fav/bor( ) 314.05 787.20 1.50 0.09 38-vog( )
288.75 805.50 1.00 -1.31 15-von/hin() 314.65 786.70 1.50 0.06 38-vog( )
290.75 803.60 1.00 -1.66 15-von/hin() 334.15 770.40 1.50 -1.05 38-vog( )
290.95 803.40 1.00 -1.70 15-von/hin() 293.15 801.60 1.00 -1.79 52-van/koo()
293.15 803.40 1.50 0.01 33-ale-1( ) 293.15 805.50 1.00 2.11 53-lev/mez( ) {
293.15 801.80 2.00 -1.59 33-vog1) 293.15 804.30 1.00 0.91 53-sor/ber( )
290.75 809.70 1.50 4.44 38-vog( ) 298.15 798.00 1.00 -1.49 55-bai/hew()
293.15 807.40 1.50 4.01 38-vog( ) 293.15 801.30 0.50 -2.09 62-ano-3( )
1) Not included in Fig. 1.
Further references: [08-wal-1, 12-von/ell].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 821.42 7.65 298.15 799.49 0.87 320.00 782.47 1.85
280.00 813.63 3.28 300.00 798.05 0.89 330.00 774.68 1.68
290.00 805.84 1.58 310.00 790.26 1.35 340.00 766.89 2.00
293.15 803.39 1.02

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 267

Methylenecyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1-Methylcyclohexene [591-49-1] C7H12 MW = 96.17 455

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 3.3595 (combined temperature ranges,
weighted), c,uw = 9.5459 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 315.25 K
Coefficient = A + BT + CT 2 + DT 3 +
A 7.24928 101
B 5.83494
C -1.13084 10-2

cont.

Landolt-Brnstein
New Series IV/8D
268 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

1-Methylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 817.10 3.00 -5.48 04-mar-2( ) 293.15 812.70 1.50 1.50 38-vog1)
293.15 799.80 3.00 -11.40 04-mar-21) 315.25 791.20 1.50 3.10 38-vog( )
293.15 802.90 3.00 -8.30 04-mar-21) 335.25 773.40 1.50 15.72 38-vog1)
273.15 821.00 2.00 -1.58 05-sab/mai( ) 293.15 810.10 0.50 -1.10 43-ano-3()
287.15 812.30 1.00 -3.26 07-eyk( ) 293.15 810.10 0.40 -1.10 49-boo/hen( ) {
273.15 823.00 2.50 0.42 07-sab/mai-4( ) 293.15 811.46 0.05 0.26 60-cam/ros( )
287.95 814.50 0.80 -0.53 12-von/ell() 298.15 806.58 0.05 -0.36 60-cam/ros( )
291.65 811.50 0.80 -0.86 12-von/ell() 303.15 802.28 0.05 0.16 60-cam/ros( )
293.15 810.30 0.80 -0.90 12-von/ell1) 293.15 810.30 0.80 -0.90 61-ano-91)
286.65 825.70 0.80 9.81 30-god/cau( ) 293.15 811.70 0.60 0.50 66-khr/koc()
1) Not included in Fig. 1.
Further references: [02-wal-1, 06-zel/gut, 12-ipa-1, 12-von/moo, 23-nam/bru, 24-zel, 26-gou/hun, 33-
sig/cra, 34-god, 35-huc/kum, 38-kaz/glu, 39-cow/jef, 48-adk/roe, 50-til, 53-lev/mez, 53-pla/lib, 61-shu/tul,
65-sam/ogl].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 269

1-Methylcyclohexene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 823.55 2.78 293.15 811.20 0.39 310.00 794.59 0.60
280.00 819.70 1.75 298.15 806.94 0.12 320.00 781.70 2.79
290.00 813.59 0.66 300.00 805.22 0.08 330.00 766.54 7.24

(+)-(R)-3-Methylcyclohexene [500032-90-6] C7H12 MW = 96.17 456

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
803.0 2.00 38-mou/gra-1
1)
287.15
803.0 2.00 46-mou/ric
1)
287.15
1)
Values included in the fit of 3-methylcyclohexene.

3-Methylcyclohexene [591-48-0] C7H12 MW = 96.17 457

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.9061 (combined temperature ranges,
weighted), c,uw = 7.4361 10-1 (combined
temperature ranges, unweighted).
T = 287.15 to 299.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.45780 102
B -4.91219 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.45 804.80 2.00 3.17 1897-kno( ) 292.65 803.00 1.50 0.97 39-gui()
293.15 800.00 2.00 -1.78 00-kon/sch( ) 299.15 799.00 2.00 0.17 41-ber( )
292.15 803.20 1.00 0.93 01-zel/zel-1() 287.15 803.00 2.00 -1.73 42-ber( )
293.15 801.90 1.00 0.12 01-zel/zel-1() 298.15 799.00 2.00 -0.32 42-ber( )
293.15 805.00 2.00 3.22 12-von/moo( ) 293.15 810.10 0.60 8.32 {
46-boo/gre( )
293.15 800.90 0.80 -0.88 24-zel() 298.15 796.00 2.00 -3.32 48-adk/roe( )
299.15 795.00 2.00 -3.83 26-gou/hun( ) 293.15 800.20 0.20 -1.58
62-ano-3( )
287.15 803.00 2.00 -1.73 34-god/mou( )
Further references: [1895-wal-2].
cont.

Landolt-Brnstein
New Series IV/8D
270 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

3-Methylcyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 808.24 5.00 293.15 801.78 1.25 300.00 798.41 2.00
290.00 803.33 1.60 298.15 799.32 2.13 310.00 793.50 2.16

(+)-(R)-4-Methylcyclohexene [500032-89-3] C7H12 MW = 96.17 458

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m 3

287.15 805.0 2.00 38-mou/gra-1


287.15 805.0 2.00 46-mou/ric

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 271

4-Methylcyclohexene [591-47-9] C7H12 MW = 96.17 459

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.8887 10-1 (combined temperature ranges,
weighted), c,uw = 2.3597 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 293.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 3.62077 102
B 4.23781
C -9.36895 10-3

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 820.60 1.00 -0.01 03-mar( ) 290.75 802.30 0.70 0.09 07-eyk( )
288.15 803.40 1.00 -1.89 03-mar( ) 293.15 800.10 0.60 0.85 23-nam/bru()
293.15 798.50 1.00 -0.75 03-mar1) 286.65 808.60 0.80 1.58 30-god/cau( )
273.15 820.70 1.00 0.09 04-mar-2( ) 286.65 808.60 1.00 1.58 34-god( )
288.15 804.70 1.00 -0.59 04-mar-2( ) 293.15 800.10 0.50 0.85 49-foe/fen()
293.15 798.60 1.00 -0.65 04-mar-21) 293.15 799.20 0.60 -0.05 50-ano-1()
273.15 820.60 1.00 -0.01 04-mar-3( ) 293.15 798.90 0.40 -0.35 {
50-boo/gre( )
293.15 798.50 1.00 -0.75 04-mar-31) 293.15 799.00 0.60 -0.25 {
50-boo/gre( )
293.15 798.90 1.00 -0.35 04-mar-31) 293.15 798.30 0.60 -0.95 61-hue/mau( )
288.25 804.20 0.70 -0.98 07-eyk( ) 293.15 799.30 0.20 0.05
62-ano-3( )
1) Not included in Fig. 1.

Further references: [04-zel, 29-mid/hen, 34-god/mou, 36-dup-2, 61-shu/tul, 65-mus/bar, 66-gan/kha, 74-
aga/aly, 77-fer/lys].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 823.29 1.19 290.00 803.11 0.77 298.15 792.74 0.66
280.00 814.14 1.15 293.15 799.25 0.52 300.00 790.21 0.93

cont.

Landolt-Brnstein
New Series IV/8D
272 3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7

4-Methylcyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Cycloheptene [628-92-2] C7H12 MW = 96.17 460

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.8384 (combined temperature ranges,
weighted), c,uw = 6.1194 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 335.25 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.09030 103
B -9.03934 10-1

cont.

Landolt-Brnstein
New Series IV/8D
3.3 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C7 273

Cycloheptene (cont.)
Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 840.60 2.00 -2.79 1894-mar-1( ) 293.15 825.40 0.60 0.09


36-ruz/sei( )
293.15 823.10 2.00 -2.21 1894-mar-1( ) 291.05 827.20 1.00 -0.01 38-vog()
293.15 823.00 2.00 -2.31 08-har/tan( ) 293.15 825.50 1.00 0.19 38-vog()
293.15 822.80 2.00 -2.51 16-ros( ) 314.55 805.90 1.00 -0.06 38-vog()
293.15 823.90 1.50 -1.41 29-ros-1() 315.25 805.20 1.00 -0.13 38-vog()
286.65 835.90 0.80 4.72 30-god/cau( ){ 335.15 788.50 1.00 1.16 38-vog()
286.65 835.30 2.00 4.12 34-god() 335.25 788.40 1.00 1.15 38-vog()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 846.23 2.10 298.15 820.79 1.29 330.00 792.00 1.10
280.00 837.19 1.75 300.00 819.12 1.26 340.00 782.96 1.20
290.00 828.16 1.47 310.00 810.08 1.12 350.00 773.92 1.36
293.15 825.31 1.40 320.00 801.04 1.07

Landolt-Brnstein
New Series IV/8D
274 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8


3.4.1 3 and 4 Member Rings

[1-(1-Methylethyl)ethenyl]cyclopropane [5405-78-7] C 8H14 MW = 110.20 461

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 773.9 1.00 52-sla-1

3.4.2 5-Member Rings

Ethenylidenecyclohexane [5664-20-0] C8H12 MW = 108.18 462

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1105.74
B -0.870

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 850.7 2.00 0.00 11-jeg-1


273.15 868.1 2.00 0.00 11-jeg-1

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 870.8 2.5
280.00 862.1 2.5
290.00 853.4 2.0
293.15 850.7 2.0
298.15 846.3 2.5

1-Ethylidene-2-methylcyclopentane [98428-04-7] C8H14 MW = 110.20 463

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 799.5 1.50 35-nen/van

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 275

1-Ethyl-2-methylcyclopentene [19780-56-4] C8H14 MW = 110.20 464

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1051.18
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 802.0 2.00 -0.00 31-chi


273.15 819.0 2.00 -0.00 31-chi

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 821.7 2.5
280.00 813.2 2.0
290.00 804.7 2.0
293.15 802.0 2.0
298.15 797.8 2.5

1-(1-Methylethyl)cyclopentene [1462-07-3] C8H14 MW = 110.20 465

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3

293.15 814.1 4.00 14-mee


293.15 818.3 4.00 51-nam/vol
293.15 816.2 4.3 Recommended

3-(1-Methylethyl)cyclopentene [4276-45-3] C8H14 MW = 110.20 466

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 794.1 1.00 45-cra/boo
293.15 794.1 0.40 49-boo/hen

Landolt-Brnstein
New Series IV/8D
276 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

(1-Methylethylidene)cyclopentane [765-83-3] C8H14 MW = 110.20 467

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.0 2.00 07-wal/fle

2-Propenylcyclopentane [3524-75-2] C8H14 MW = 110.20 468

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
296.15 793.0 2.00 35-pia/bou 1)
293.15 794.0 0.60 45-whi/her
293.15 791.2 1.00 53-lev/mez
293.15 793.3 1.2 Recommended
1)
Not included in calculation of recommended value.

1-Propylcyclopentene [3074-61-1] C8H14 MW = 110.20 469

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 806.2 3.00 25-eis-2
288.15 805.6 4.00 27-cha/bec 1)
293.15 801.5 1.00 27-cha/bec
293.15 806.2 1.50 39-gro/wac
293.15 795.9 3.00 53-lev/mez
293.15 802.5 1.00 60-nar/shu
293.15 802.7 1.0 Recommended
1)
Not included in calculation of recommended value.

3-Propylcyclopentene [34067-75-9] C8H14 MW = 110.20 470

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 791.0 0.60 46-boo/gre
293.15 791.0 0.60 49-boo/hen
293.15 791.8 1.00 53-lev/tan-1
293.15 791.1 0.7 Recommended

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 277

1,2,3-Trimethylcyclopentene [473-91-6] C8H14 MW = 110.20 471

Table 1. Coefficients of the polynomial expansion


equation (based on data sets 471 and 472). Standard
deviations (see introduction):c,w = 1.0785 (combined
temperature ranges, weighted), c,uw = 3.2835 10-1
(combined temperature ranges, unweighted).
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A -2.12414 102
B 7.94356
C -1.53551 10-2

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1)
293.15 795.00 3.00 -1.67 {
01-zel/lep-1( )
288.15 803.50 3.00 1.92 10-noy/kyr()
292.55 796.20 4.00 -1.10 19-eyk( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
Data sets 471 and 472 were combined for the graph of 1,2,3-trimethylcyclopentene.
cont.

Landolt-Brnstein
New Series IV/8D
278 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1,2,3-Trimethylcyclopentene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 812.96 7.53 290.00 799.86 3.40 298.15 790.99 3.84
280.00 807.94 3.56 293.15 796.67 3.30 300.00 788.70 4.49

(R)-1,2,3-Trimethylcyclopentene [74190-02-6] C8H14 MW = 110.20 472

Table 1. Experimental values with uncertainties.


T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

290.65 800.80 4.00 1.58 00-tie( ) 293.15 796.10 3.00 -0.57 06-cro/ren()
291.65 798.80 3.00 0.57 {
01-zel/lep-1( ) 298.15 791.60 3.00 0.61 06-cro/ren()
277.15 809.70 3.00 0.01 06-cro/ren() 288.15 803.00 4.00 1.42 09-noy/der( )
283.15 804.60 3.00 -1.13 06-cro/ren() 293.15 797.70 4.00 1.03 10-noy/der()
288.15 800.30 3.00 -1.28 06-cro/ren() 293.15 796.00 2.50 -0.67 37-von/kam( )
292.65 796.50 3.00 -0.70 06-cro/ren()

1,2,4-Trimethylcyclopentene [99363-12-9] C8H14 MW = 110.20 473

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 787.6 2.00 51-slo

cis-1,3,5-Trimethylcyclopentene [500031-65-2] C8H16 MW = 112.22 474

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 775.0 2.00 51-slo

trans-1,3,5-Trimethylcyclopentene [500031-66-3] C8H16 MW = 112.22 475

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 774.5 2.00 51-slo

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 279

1,4,4-Trimethylcyclopentene [54168-64-8] C8H14 MW = 110.20 476

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 768.7 1.00 45-ano-8
293.15 768.7 1.00 51-bir/joh
293.15 767.7 1.00 51-slo
293.15 764.8 2.00 54-aut
293.15 768.1 1.4 Recommended

2,3,3-Trimethylcyclopentene [700000-78-8] C8H14 MW = 110.20 477

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.6187 10-1 (combined temperature ranges,
weighted), c,uw = 1.3720 10-1 (combined
temperature ranges, unweighted).
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03164 103
B -8.51814 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 783.00 2.00 1.07 1895-beh( ) 293.15 781.70 2.00 -0.23 06-cro/ren()
293.15 781.20 2.00 -0.73 01-zel/lep-1() 298.15 777.20 2.00 -0.47 06-cro/ren()
277.15 795.30 2.00 -0.26 06-cro/ren() 288.15 786.70 1.00 0.51 10-kis-3()
283.15 790.50 2.00 0.05 06-cro/ren() 293.15 782.30 1.00 0.37 10-kis-3()
288.15 786.00 2.00 -0.19 06-cro/ren() 293.15 782.00 1.00 0.07 {
18-von-2( )
289.25 785.10 2.00 -0.15 06-cro/ren() 293.15 781.90 0.60 -0.03
45-ano( )

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 801.65 1.82 293.15 781.93 1.48 300.00 776.10 2.60
280.00 793.13 2.31 298.15 777.67 2.10 310.00 767.58 9.17
290.00 784.61 1.53

cont.

Landolt-Brnstein
New Series IV/8D
280 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

2,3,3-Trimethylcyclopentene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

3,5,5-Trimethylcyclopentene [500031-64-1] C8H16 MW = 112.22 478

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 750.6 0.40 51-bir/joh
293.15 750.3 0.60 51-slo
293.15 750.5 0.4 Recommended

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 281

3.4.3 6-Member Rings

1,2-Dimethylcyclohexene [1674-10-8] C8H14 MW = 110.20 479

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.8678 (combined temperature ranges,
weighted), c,uw = 3.9210 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.06372 103
B -8.16712 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 841.10 1.00 0.46 05-sab/mai1() 293.15 823.00 2.00 -1.30 18-mee/fle( )
288.15 826.90 1.00 -1.48 08-zel/gor() 293.15 824.00 2.00 -0.30 33-sig/cra( )
293.15 822.60 1.00 -1.70 08-zel/gor() 288.15 827.30 0.80 -1.08 38-chi()
293.15 824.00 2.00 -0.30 13-wal( ) 293.15 823.20 0.80 -1.10 38-chi()
293.15 824.00 2.00 -0.30 14-mee( ) 303.15 815.00 0.80 -1.13 38-chi()
286.65 831.70 1.50 2.09 15-von/hin( ) 293.15 826.20 0.50 1.90 {
53-ano-1( )
286.85 831.50 1.50 2.05 15-von/hin( ) 293.15 826.50 0.50 2.20
56-ano( )
Further references: [56-goe/mcc].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 843.21 1.30 293.15 824.30 1.25 300.00 818.71 1.24
280.00 835.04 1.29 298.15 820.22 1.18 310.00 810.54 1.50
290.00 826.87 1.32

cont.

Landolt-Brnstein
New Series IV/8D
282 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1,2-Dimethylcyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,3-Dimethylcyclohexene [2808-76-6] C8H14 MW = 110.20 480

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.3399 (combined temperature ranges,
weighted), c,uw = 1.2381 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04523 103
B -8.19450 10-1

cont.

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 283

1,3-Dimethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 821.00 2.00 -0.40 05-sab/mai() 303.15 794.50 1.00 -2.32 38-chi()
273.15 821.00 1.00 -0.40 {
05-sab/mai1( ) 298.15 807.00 2.00 6.08 39-mou/pau( )
293.15 800.60 3.00 -4.41 31-ruz/koo( ) 298.15 807.00 2.00 6.08 46-mou()
288.15 806.80 1.00 -2.31 38-chi() 293.15 805.10 1.00 0.09
50-nic/hei( )
293.15 802.60 1.00 -2.41 38-chi()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 823.98 1.69 293.15 805.01 1.60 300.00 799.40 1.80
280.00 815.79 1.65 298.15 800.92 1.90 310.00 791.20 1.98
290.00 807.59 1.60

Landolt-Brnstein
New Series IV/8D
284 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1,4-Dimethylcyclohexene [2808-79-9] C8H14 MW = 110.20 481

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.7949 (combined temperature ranges,
weighted), c,uw = 4.6178 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.07934 103
B -9.46497 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 820.70 2.00 -0.10 05-sab/mai( ) 295.55 798.50 1.50 -1.10 15-von/hin( )
273.15 820.80 1.00 -0.00 05-sab/mai1() 293.15 802.40 1.00 0.53 24-nam/bry( ) {
273.15 820.70 2.00 -0.10 06-sab/mai( ) 293.15 800.50 1.00 -1.37 24-zel/pav( )
287.15 811.10 2.00 3.55 06-sab/mai( ) 288.15 804.70 1.00 -1.91 38-chi()
293.15 800.50 2.00 -1.37 08-zel/gor( ) 293.15 800.60 1.00 -1.27 38-chi()
293.15 800.50 2.00 -1.37 08-zel/gor1( ) 303.15 792.40 1.00 -0.01 38-chi()
292.65 802.00 1.00 -0.35 13-wal() 293.15 803.00 1.00 1.13 38-kaz/glu( )
295.15 798.90 1.50 -1.08 15-von/hin( ) 298.15 802.00 2.00 4.86 47-mou/win( )
Further references: [30-god/cau, 34-god, 46-mou].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 823.79 1.86 293.15 801.87 1.80 300.00 795.39 2.00
280.00 814.32 1.92 298.15 797.14 1.80 310.00 785.93 2.50
290.00 804.86 2.00

cont.

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 285

1,4-Dimethylcyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,5-Dimethylcyclohexene [2808-77-7] C8H14 MW = 110.20 482

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.7264 (combined temperature ranges,
weighted), c,uw = 8.2257 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04388 103
B -8.18614 10-1

cont.

Landolt-Brnstein
New Series IV/8D
286 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1,5-Dimethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

291.15 800.50 3.00 -5.04 1897-kno( ) 295.75 799.80 1.50 -1.98 15-von/hin()
273.15 820.90 3.00 0.62 07-sab/mai-4( ) 293.15 803.00 2.00 -0.90 33-sig/cra()
285.15 812.20 3.00 1.75 07-sab/mai-4( ) 293.15 805.60 1.00 1.70 38-kaz/glu( )
294.15 802.50 1.00 -0.59 13-wal( ){ 298.15 803.00 2.50 3.19 38-mou/gra( )
295.55 800.00 1.50 -1.94 15-von/hin() 298.15 803.00 2.00 3.19 39-mou/pau()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 822.85 4.11 293.15 803.90 1.97 300.00 798.30 1.94
280.00 814.67 3.04 298.15 799.81 1.86 310.00 790.11 2.80
290.00 806.48 2.16
3,3-Dimethylcyclohexene [695-28-3] C8H14 MW = 110.20 483

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 287

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
288.15 765.00 20.00 31-cha/mil
294.15 797.00 1.00 35-zel/pac

3,4-Dimethyl-1-cyclohexene [2808-72-2] C8H14 MW = 110.20 484

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.460.
Coefficient = A + BT
A 1055.54
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

292.35 807.5 2.00 0.46 20-von-2


293.15 805.9 2.00 -0.46 20-von-2

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 809.0 2.5
293.15 806.4 2.0
298.15 802.1 2.5

3,5-Dimethylcyclohexene [823-17-6] C8H14 MW = 110.20 485

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 3.578.
Coefficient = A + BT
A 1048.98
B -0.850

cont.

Landolt-Brnstein
New Series IV/8D
288 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

3,5-Dimethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.75 805.5 3.00 6.21 10-von/pet-2


292.55 806.2 3.00 5.89 10-von/pet-2
291.55 807.4 3.00 6.24 10-von/pet-2
294.25 797.0 2.00 -1.87 15-von/hin
288.75 800.9 2.00 -2.64 15-von/hin
288.75 800.9 2.00 -2.64 15-von/hin
291.15 800.5 2.00 -1.00 31-kom/kaw

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 811.0 3.6
290.00 802.5 3.6
293.15 799.8 3.6
298.15 795.6 3.6

4,4-Dimethylcyclohexene [14072-86-7] C8H14 MW = 110.20 486

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.4482 (combined temperature ranges,
weighted), c,uw = 7.4386 10-1 (combined
temperature ranges, unweighted).
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.07995 103
B -9.51614 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

277.15 812.90 1.00 -3.31 05-cro/ren( ) 293.15 803.00 2.00 2.02 15-von/lan( )
288.15 803.28 1.00 -2.46 05-cro/ren( ) 294.15 797.00 1.00 -3.03 35-zel/pac()
298.15 794.65 1.00 -1.58 05-cro/ren( ) 289.75 809.20 0.80 4.98 36-hib/lin()
286.65 808.90 1.00 1.73 15-von/lan( ) 293.15 799.90 0.60 -1.08 47-ano-2()
289.35 805.60 1.00 1.00 15-von/lan( ) 293.15 799.90 0.60 -1.08 49-eva( ){
293.15 804.00 2.00 3.02 15-von/lan( ) 293.15 800.80 0.50 -0.18 56-ano( )

cont.

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 289

4,4-Dimethylcyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 823.01 1.60 290.00 803.98 1.10 298.15 796.23 1.30
280.00 813.50 1.40 293.15 800.98 1.10 300.00 794.47 1.51

Landolt-Brnstein
New Series IV/8D
290 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

Ethenylcyclohexane [695-12-5] C8H14 MW = 110.20 487

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 4.252.
Coefficient = A + BT
A 1052.93
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

292.15 816.6 1.50 12.00 36-lev/zur


293.15 813.4 1.50 9.65 37-lev/pot
293.15 801.2 1.00 -2.55 52-van/koo
293.15 809.1 1.00 5.35 53-lev/mez
293.15 801.8 0.40 -1.99 62-sla/mag

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 806.4 5.6
293.15 803.7 5.0

1-Ethylcyclohexene [1453-24-3] C8H14 MW = 110.20 488

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.8719 10-1 (combined temperature ranges,
weighted), c,uw = 1.9325 10-1 (combined
temperature ranges, unweighted).
T = 288.40 to 303.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.97564 103
B -6.89646
C 1.01037 10-2

cont.

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 291

1-Ethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 826.00 1.00 3.78 08-wal/eva1) 293.15 821.50 0.50 -0.72 53-ano-1()
293.15 823.50 1.00 1.28 08-wal/eva( ) 293.15 821.50 0.50 -0.72 54-ano-1()
292.25 823.80 1.00 0.70 12-von/ell( ) 293.15 821.20 0.50 -1.02 56-ano( ){
293.15 823.10 1.00 0.88 12-von/ell( ) 293.15 822.12 0.06 -0.10 60-cam/ros( )
288.40 827.00 1.00 -0.07 15-rot/von( ) 298.15 817.65 0.06 0.04 60-cam/ros( )
288.65 826.80 1.00 -0.00 15-rot/von( ) 303.15 813.48 0.06 -0.02 60-cam/ros( )
293.15 821.70 1.00 -0.52 35-eis( ) 293.15 822.50 0.60 0.28 66-khr/koc()
1) Not included in Fig. 1.
Further references: [33-sig/cra, 38-kaz/glu, 53-lev/mez, 56-ohl/far].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
292 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1-Ethylcyclohexene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 836.76 1.73 293.15 822.22 0.26 300.00 816.03 0.18
290.00 825.38 0.50 298.15 817.61 0.18 310.00 808.70 0.51

3-Ethylcyclohexene [2808-71-1] C8H14 MW = 110.20 489

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m 3

299.15 810.0 2.00 41-ber


299.15 810.0 2.00 42-ber
293.15 810.4 1.00 53-lev/mez

Ethylidenecyclohexane [1003-64-1] C8H14 MW = 110.20 490

Table 1. Fit with estimated B coefficient for 9


accepted points. Deviation w = 0.645.
Coefficient = A + BT
A 1071.20
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 823.0 2.00 0.97 08-wal-1


291.15 823.0 2.00 -0.73 08-wal/eva
293.15 822.5 2.00 0.47 08-wal/eva
293.15 822.0 2.00 -0.03 08-wal/eva
290.45 823.9 1.50 -0.42 15-von/hin
290.75 823.7 1.50 -0.37 15-von/hin
293.15 822.5 1.00 0.47 28-god/cau-1
292.15 823.5 1.00 0.62 28-god/cau-1
293.15 821.1 1.00 -0.93 52-van/koo

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 824.7 2.5
293.15 822.0 2.0

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 293

1-Methylene-2-methylcyclohexane [500030-97-7] C8H14 MW = 110.20 491

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 808.0 2.00 06-wal/bes

1-Methylene-3-methylcyclohexane [500029-67-4] C8H14 MW = 110.20 492

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 9.3748 10-1 (combined temperature ranges,
weighted), c,uw = 4.3247 10-1 (combined
temperature ranges, unweighted).
T = 289.45 to 335.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.04429 103
B -8.45746 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

291.15 797.00 2.00 -1.05 06-wal() 293.15 797.00 1.50 0.64 38-vog( )
293.15 794.00 2.00 -2.36 06-wal() 315.25 777.80 1.50 0.13 38-vog( )
293.15 798.00 2.00 1.64 {
08-wal-1( ) 334.65 761.40 1.50 0.14 38-vog( )
289.45 800.30 1.50 0.81 38-vog( ) 335.05 761.00 1.50 0.07 38-vog( )

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 807.48 2.52 298.15 792.13 1.76 320.00 773.65 1.64
290.00 799.03 2.06 300.00 790.57 1.74 330.00 765.20 1.68
293.15 796.36 1.86 310.00 782.11 1.66 340.00 756.74 1.77

cont.

Landolt-Brnstein
New Series IV/8D
294 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1-Methylene-3-methylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1-Methylene-4-methylcyclohexane [2808-80-2] C8H14 MW = 110.20 493

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.8028 (combined temperature ranges,
weighted), c,uw = 1.0468 (combined
temperature ranges, unweighted).
T = 289.05 to 360.45 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.03424 103
B -8.16240 10-1

cont.

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 295

1-Methylene-4-methylcyclohexane (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

295.15 792.50 2.00 -0.83 06-wal( ){ 289.05 803.30 1.50 4.99 38-vog( )
293.15 792.50 2.00 -2.46 08-wal-1() 293.15 799.60 1.50 4.64 38-vog( )
293.15 790.70 3.00 -4.26 08-wal-5() 334.05 763.40 1.50 1.82 38-vog( )
292.15 791.00 3.00 -4.78 11-per/pop( ) 359.85 741.20 1.50 0.68 38-vog( )
293.15 794.50 2.00 -0.46 33-ale-1() 360.45 740.70 1.50 0.67 38-vog( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
296 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

1-Methylene-4-methylcyclohexane (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 805.70 3.22 300.00 789.37 2.16 340.00 756.72 1.80
290.00 797.53 2.89 310.00 781.21 2.30 350.00 748.56 1.75
293.15 794.96 2.45 320.00 773.05 2.40 360.00 740.40 1.70
298.15 790.88 2.18 330.00 764.88 1.90 370.00 732.23 2.30

3.4.4 7 and 8 Member Rings

Methylenecycloheptane [2505-03-5] C8H14 MW = 110.20 494

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 824.0 2.00 06-wal-4
293.15 825.7 1.00 53-sor/ber
293.15 825.4 1.0 Recommended

1-Methylcycloheptene [1453-25-4] C8H14 MW = 110.20 495

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 2.302.
Coefficient = A + BT
A 1076.48
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

292.65 824.0 2.00 -3.73 06-wal-4 286.65 835.6 0.80 2.77 30-god/cau
288.15 829.4 1.00 -2.16 27-god/bed 286.65 834.4 2.00 1.57 34-god
293.15 826.0 1.00 -1.31 27-god/bed 295.15 824.3 2.00 -1.31 36-ruz/sei

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 838.5 2.8
290.00 830.0 2.3
293.15 827.3 2.3
298.15 823.1 2.5

Landolt-Brnstein
New Series IV/8D
3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8 297

Cyclooctene [931-88-4] C8H14 MW = 110.20 496

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.6900 (combined temperature ranges,
weighted), c,uw = 1.9059 (combined
temperature ranges, unweighted).
T = 273.15 to 293.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.09025 103
B -8.24730 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m
3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 871.00 4.00 6.03 10-wil/was( ) 286.65 849.70 2.00 -4.14 30-god/cau()
293.15 855.00 4.00 6.52 10-wil/was( ) 292.15 848.60 2.00 -0.70 31-ruz/boe()
290.15 848.70 2.00 -2.25 27-god/cau( ){ 293.15 850.00 1.00 1.52 48-rep/sch1( )
293.15 841.50 3.00 -6.98 29-ros-1()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
298 3.4 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C8

Cyclooctene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 867.57 5.00 290.00 851.08 2.00 298.15 844.35 5.50
280.00 859.32 4.50 293.15 848.48 2.71

(Z)-Cyclooctene [931-87-3] C8H14 MW = 110.20 497

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 847.2 2.00 50-zie/eim
293.15 850.1 1.00 65-tre/mit
293.15 849.5 1.5 Recommended

(E)-Cyclooctene [931-89-5] C8H14 MW = 110.20 498

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.700.
Coefficient = A + BT
A 1089.38
B -0.820

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 848.3 2.00 -0.70 50-zie/eim


298.15 845.6 2.00 0.70 53-cop/pik

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 851.6 2.5
293.15 849.0 2.0
298.15 844.9 2.0

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 299

3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9


3.5.1 3 and 4 Member Rings

1,1-Dimethyl-2-(2-methyl-1-propenyl) [33422-32-1] C9H16 MW = 124.23 499


cyclopropane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 767.7 1.50 13-kis-5

(1-Ethylpropylidene)cyclobutane [500030-93-3] C9H16 MW = 124.23 500

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 809.1 1.50 05-kis/amo

3.5.2 5-Member Rings

(2-Butenyl)cyclopentane [5860-29-7] C 9H16 MW = 124.23 501

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
297.65 806.0 2.00 35-gre-1

1-Butylcyclopentene [2423-01-0] C9H16 MW = 124.23 502

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 2.821.
Coefficient = A + BT
A 1029.33
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

288.15 810.1 1.00 -3.11 27-cha/bec


290.95 812.3 1.00 1.19 27-cha/bec
293.15 813.8 1.50 4.34 39-gro/wac

cont.

Landolt-Brnstein
New Series IV/8D
300 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

1-Butylcyclopentene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 819.3 2.9
290.00 811.8 2.8
293.15 809.5 2.8
298.15 805.7 2.8

3-Butylcyclopentene [22531-00-6] C9H16 MW = 124.23 503

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 799.0 0.70 45-cra/boo

1,2-Diethylcyclopentene [500019-09-0] C9H16 MW = 124.23 504

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 4.261.
Coefficient = A + BT
A 1059.07
B -0.840

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 812.3 3.00 -0.52 11-kis1)


298.15 813.6 2.00 4.98 28-cas/rei
273.15 833.1 2.00 3.48 28-cas/rei
293.15 808.8 2.00 -4.02 33-chi
273.15 825.2 2.00 -4.42 33-chi
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 832.3 4.3
280.00 823.9 4.3
290.00 815.5 4.3
293.15 812.8 4.3
298.15 808.6 4.3

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 301

3,3-Diethylcyclopentene [500031-47-0] C9H16 MW = 124.23 505

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 808.3 2.00 11-kis
293.15 808.4 2.00 11-kis
293.15 808.3 2.00 Recommended

1-(1,1-Dimethylethyl)cyclopentene [3419-67-8] C9H16 MW = 124.23 506

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 802.1 1.00 39-gro/wac

3-(1,1-Dimethylethyl)cyclopentene [6189-88-4] C9H16 MW = 124.23 507

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 806.6 0.60 45-cra/boo

2-Ethyl-1,3-dimethylcyclopentene [500031-27-6] C9H16 MW = 124.23 508

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 803.0 2.00 18-von-2

1-Methyl-3-(1-methylethyl)cyclopentene [13828-12-1] C9H16 MW = 124.23 509

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 801.0 2.00 04-sem

Landolt-Brnstein
New Series IV/8D
302 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

3-Methyl-1-(1-methylethyl)cyclopentene [51115-02-7] C9H16 MW = 124.23 510

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 791.0 2.00 03-wal/col

1-Methyl-2-(1-methylethylidene) [500030-94-4] C9H16 MW = 124.23 511


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 810.3 1.50 12-kis-4

(R)-1-Methyl-4-(1-methylethyl) [2699-04-9] C9H16 MW = 124.23 512


cyclopentene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.065.
Coefficient = A + BT
A 1041.54
B -0.840

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 812.0 2.00 -0.10 08-bou/lev


294.15 794.5 1.50 0.04 09-wal-6

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 814.7 2.4
280.00 806.3 2.0
290.00 797.9 1.8
293.15 795.3 1.6
298.15 791.1 2.0

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 303

1-(1-Methylethenyl)- [98880-18-3] C9H16 MW = 124.23 513


2-methylcyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 800.5 1.50 12-kis-4

1-Methyl-1-(2-propenyl)cyclopentane [500023-43-8] C9H16 MW = 124.23 514

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 809.3 0.70 57-nov/khr

1-Methyl-3-propylcyclopentene [500031-16-3] C9H16 MW = 124.23 515

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 792.4 1.00 50-kaz/kop

3-(1-Methylpropyl)cyclopentene [500019-12-5] C9H16 MW = 124.23 516

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 809.2 0.80 45-cra/boo

3-(2-Methylpropyl)cyclopentene [37689-12-6] C9H16 MW = 124.23 517

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 793.6 2.00 41-cra
293.15 793.6 2.00 45-cra/boo

Landolt-Brnstein
New Series IV/8D
304 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

1,2,3,3-Tetramethylcyclopentene [65378-75-8] C9H16 MW = 124.23 518

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 4.0389 (combined temperature ranges,
weighted), c,uw = 2.3612 (combined
temperature ranges, unweighted).
T = 273.15 to 352.05 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.13685 103
B -1.16276

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

287.65 803.40 2.00 1.02 1893-thi( ) 288.15 803.50 2.00 1.70 07-bla-2()
273.15 813.40 2.00 -5.84 1895-beh( ){ 352.05 723.20 3.00 -4.30 19-eyk()
293.15 803.40 3.00 7.42 1897-tie()

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
cont.

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 305

1,2,3,3-Tetramethylcyclopentene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 822.90 4.01 298.15 790.17 4.10 330.00 753.14 9.05
280.00 811.27 3.40 300.00 788.02 4.73 340.00 741.51 9.47
290.00 799.65 2.80 310.00 776.39 7.58 350.00 729.88 5.00
293.15 795.98 3.60 320.00 764.76 8.58 360.00 718.25 6.00

3,3,5,5-Tetramethylcyclopentene [38667-10-6] C9H16 MW = 124.23 519

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 748.4 2.00 51-slo

3.5.3 6-Member Rings

3,3-Dimethyl-1-methylenecyclohexane [52291-22-2] C9H16 MW = 124.23 520

Table 1. Fit with estimated coefficient for 2


accepted points. Deviation w = 0.288.
Coefficient = A + BT
A 1013.95
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

289.65 797.0 1.50 0.29 26-esc-1


283.15 801.3 1.50 -0.29 26-esc-1

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 803.9 1.8
290.00 796.4 1.6

Landolt-Brnstein
New Series IV/8D
306 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

3,5-Dimethyl-1-methylenecyclohexane [85014-36-4] C9H16 MW = 124.23 521

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
287.25 792.2 4.00 15-von/hin
287.75 791.8 4.00 15-von/hin
287.75 792.0 4.00 Recommended

1,4-Dimethyl-2-methylenecyclohexane [500031-06-1] C9H16 MW = 124.23 522

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
287.25 792.2 4.00 15-von/hin

1-Ethenyl-3-methylcyclohexane [500029-68-5] C9H16 MW = 124.23 523

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 813.0 2.00 08-wal-1
293.15 813.0 2.00 08-wal/eva-1
298.15 793.6 1.00 59-ove/mul

1-Ethenyl-4-methylcyclohexane [500029-69-6] C9H16 MW = 124.23 524

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 812.5 2.00 08-wal-1
293.15 811.0 2.00 08-wal/eva-2
292.15 812.5 1.00 08-wal/eva-2

1-Ethylidene-2-methylcyclohexane [500031-01-6] C9H16 MW = 124.23 525

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
273.15 823.0 2.00 14-mur/amo

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 307

1-Ethylidene-3-methylcyclohexane [500031-02-7] C9H16 MW = 124.23 526

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 813.0 2.00 08-wal/eva-1
292.15 812.2 2.00 11-haw/per

1-Ethylidene-4-methylcyclohexane [500031-04-9] C9H16 MW = 124.23 527

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
294.15 810.0 2.00 09-wal/ren
292.15 812.0 2.00 09-wal/ren

1-Ethyl-2-methylcyclohexene [19780-54-2] C9H16 MW = 124.23 528

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 830.3 2.00 33-sig/cra

1-Ethyl-4-methylcyclohexene [62088-36-2] C9H16 MW = 124.23 529

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 1.015.
Coefficient = A + BT
A 1033.45
B -0.750

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K 3
kg m kg m3 K kg m 3
kg m3

273.15 827.8 1.00 -0.79 06-sab/mai 295.15 814.5 1.50 2.41 13-wal/aug
289.15 816.9 1.00 0.31 06-sab/mai 293.15 813.3 1.00 -0.29 24-nam/bry
293.15 814.0 2.00 0.41 12-von/moo 293.15 812.0 2.00 -1.59 33-sig/cra

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 831.0 1.8
280.00 823.5 1.5
290.00 816.0 1.2
293.15 813.6 1.2
298.15 809.8 1.8

Landolt-Brnstein
New Series IV/8D
308 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

2-Ethyl-4-methylcyclohexene [500018-90-6] C9H16 MW = 124.23 530

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 813.0 2.00 33-sig/cra
298.15 812.0 3.00 38-mou/gra

4-Ethyl-4-methylcyclohexene [22665-94-7] C9H16 MW = 124.23 531

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 816.5 2.00 56-pin/esc

(1-Methylethylidene)cyclohexane [5749-72-4] C9H16 MW = 124.23 532

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 836.0 2.00 08-wal-1
293.15 836.0 2.00 08-wal/mal

1-(1-Methylethyl)cyclohexene [4292-04-0] C9H16 MW = 124.23 533

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.253.
Coefficient = A + BT
A 1076.19
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

293.15 829.0 2.00 1.98 08-wal/mal 286.05 832.0 2.00 -1.05 12-von/ell
293.15 826.0 2.00 -1.02 12-von/ell 293.15 828.0 2.00 0.98 33-sig/cra
288.35 830.2 2.00 -0.90 12-von/ell 293.15 821.9 3.00 -5.12 47-nam/vol1)
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 309

1-(1-Methylethyl)cyclohexene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 838.2 2.6
290.00 829.7 2.0
293.15 827.0 2.0
298.15 822.8 3.0

(1-Propenyl)cyclohexane [5364-83-0] C9H16 MW = 124.23 534

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 821.0 2.00 08-wal-1
292.15 821.0 0.80 08-wal/chu

3-Propylcyclohexene [3983-06-0] C9H16 MW = 124.23 535

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
292.15 824.0 2.00 28-fuj

(2-Propenyl)cyclohexane [2114-42-3] C9H16 MW = 124.23 536

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0453 (combined temperature ranges,
weighted), c,uw = 3.8534 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 314.65 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.02642 103
B -7.15170 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 831.20 1.50 0.13 {


10-der( ) 301.65 811.70 0.70 1.02
33-hur/bol( )
286.15 819.60 1.50 -2.17 10-der1) 314.65 801.00 0.70 -0.39
33-hur/bol( )
293.15 816.00 0.70 -0.76
33-hur/bol( )
1) Not included in Fig. 1.

Further references: [27-bou, 36-lev/tra, 53-lev/mez].

cont.

Landolt-Brnstein
New Series IV/8D
310 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

2-Propenylcyclohexane (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 833.32 1.97 293.15 816.76 0.70 310.00 804.71 0.85
280.00 826.17 1.14 298.15 813.19 0.69 320.00 797.56 0.97
290.00 819.02 0.75 300.00 811.86 0.71

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 311

1-Propylcyclohexene [2539-75-5] C9H16 MW = 124.23 537

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
292.15 838.0 3.00 08-wal/chu
293.15 824.0 2.00 33-sig/cra
293.15 827.9 1.00 53-lev/mez
293.15 824.0 1.00 66-khr/koc
293.15 825.7 1.50 Recommended

1,3,3-Trimethylcyclohexene [503-47-9] C9H16 MW = 124.23 538

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 812.3 2.00 54-lev/shu
298.15 788.5 2.00 56-opp/day

1,3,4-Trimethylcyclohexene [186201-30-9] C9H16 MW = 124.23 539

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 812.4 2.00 50-nic/hei

1,3,5-Trimethylcyclohexene [3643-64-9] C9H16 MW = 124.23 540

Table 1. Fit with estimated B coefficient for 10


accepted points. Deviation w = 1.200.
Coefficient = A + BT
A 1045.83
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K 3
kg m kg m3 K kg m 3
kg m3

294.15 796.5 1.50 0.69 13-wal/sch 286.25 805.4 1.50 2.88 15-von/hin
297.85 794.1 1.50 1.44 15-von/hin 287.45 802.5 1.50 1.00 15-von/hin
287.45 802.5 1.50 1.00 15-von/hin 286.65 803.1 1.50 0.92 15-von/hin
286.65 803.1 1.50 0.92 15-von/hin 293.15 795.8 0.40 -0.86 49-ano-1
286.95 804.8 1.50 2.87 15-von/hin 293.15 797.0 1.50 0.34 50-nic/hei

cont.

Landolt-Brnstein
New Series IV/8D
312 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

1,3,5-Trimethylcyclohexene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 807.8 1.8
290.00 799.3 1.5
293.15 796.7 1.5
298.15 792.4 1.6

1,4,4-Trimethylcyclohexene [3419-71-4] C9H16 MW = 124.23 541

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.158.
Coefficient = A + BT
A 1068.11
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

287.95 809.8 1.00 0.85 15-von/lan


288.25 809.6 1.00 0.92 15-von/lan
291.95 803.2 1.00 -2.15 15-von/lan
293.15 804.0 1.00 -0.27 15-von/lan
296.30 802.1 1.00 0.66 15-von/lan

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 816.1 1.8
290.00 807.1 1.4
293.15 804.3 1.4
298.15 799.8 1.4

1,4,5-Trimethylcyclohexene [20030-32-4] C9H16 MW = 124.23 542

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.319.
Coefficient = A + BT
A 1068.41
B -0.900

cont.

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 313

1,4,5-Trimethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

289.30 807.8 1.50 -0.24 20-von-2


293.15 805.0 2.00 0.43 20-von-2

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 816.4 1.6
290.00 807.4 1.7
293.15 804.6 1.8
298.15 800.1 2.0

cis-1,4,5-Trimethylcyclohexene [30631-18-6] C9H16 MW = 124.23 543

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 814.0 2.00 22-ski/sch

trans-1,4,5-Trimethylcyclohexene [87954-39-0] C9H16 MW = 124.23 544

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 805.0 2.00 22-ski/sch

1,5,6-Trimethylcyclohexene [116724-18-6] C9H16 MW = 124.23 545

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 828.5 3.00 47-mou/win

Landolt-Brnstein
New Series IV/8D
314 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

1,6,6-Trimethylcyclohexene [69745-49-9] C9H16 MW = 124.23 546

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 822.5 0.60 47-ano-2

2,3,3-Trimethylcyclohexene [500031-30-1] C9H16 MW = 124.23 547

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.665.
Coefficient = A + BT
A 1086.47
B -0.900

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.45 821.7 2.00 -0.66 15-von/lan


288.15 827.8 2.00 0.66 15-von/lan

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 834.5 2.5
290.00 825.5 2.0
293.15 822.6 2.2
298.15 818.1 3.0

2,4,4-Trimethylcyclohexene [500031-31-2] C9H16 MW = 124.23 548

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 5.507.
Coefficient = A + BT
A 1051.39
B -0.850

cont.

Landolt-Brnstein
New Series IV/8D
3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9 315

2,4,4-Trimethylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

296.15 798.1 3.00 -1.56 1897-kno


294.65 791.1 3.00 -9.83 04-har/wei
288.15 807.8 3.00 1.34 10-cro/gil
290.95 809.4 3.00 5.32 12-von/moo
287.55 811.7 3.00 4.73 12-von/moo

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 813.4 5.5
290.00 804.9 5.5
293.15 802.2 5.5
298.15 798.0 5.5

3,3,5-Trimethylcyclohexene [503-45-7] C9H16 MW = 124.23 549

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 788.6 0.40 50-boo/gre
293.15 788.7 0.40 51-ano-3
293.15 788.7 0.40 Recommended

3,4,4-Trimethylcyclohexene [500031-79-8] C9H16 MW = 124.23 550

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 815.9 0.40 62-ano-3

r-3, t-4, c-5-Trimethylcyclohexene [73156-88-4] C9H16 MW = 124.23 551

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 811.4 0.40 56-bus/gre
293.15 811.4 1.00 62-mah/gre

Landolt-Brnstein
New Series IV/8D
316 3.5 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C9

r-3, t-4, t-5-Trimethylcyclohexene [500031-82-3] C9H16 MW = 124.23 552

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 812.9 1.00 62-mah/gre

3,5,5-Trimethylcyclohexene [933-12-0] C9H16 MW = 124.23 553

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 797.8 2.00 1893-tie/sem
293.15 793.9 0.50 50-boo/gre
293.15 794.3 2.00 51-ano-3
293.15 794.1 0.50 Recommended

3.5.4 7 to 9 Member Rings

1,2-Dimethylcycloheptene [20053-89-8] C9H16 MW = 124.23 554

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 836.0 1.00 55-cri/ker

Methylenecyclooctane [3618-18-6] C9H16 MW = 124.23 555

Table 1. Experimental value with uncertainty


T exp 2 est Ref.
K kg m3
293.15 848.5 1.00 53-sor/ber

(E)-Cyclononene [3958-38-1] C9H16 MW = 124.23 556

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 861.5 2.00 52-blo/liu

(Z)-Cyclononene [933-21-1] C9H16 MW = 124.23 557

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 867.1 2.00 52-blo/liu

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 317

3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10


3.6.1 5-Member Rings

1,3-Diethyl-2-methylcyclopentene [500031-29-8] C10H18 MW = 138.25 558

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 811.0 2.00 18-von-2

1,1-Dimethyl-2-(1-methylethenyl) [500025-86-5] C10H18 MW = 138.25 559


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 794.8 0.80 49-ste/spa

1-(1,1-Dimethylpropyl)cyclopentene [500032-63-3] C10H18 MW = 138.25 560

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 825.6 1.00 39-gro/wac

4-(1-Methylethyl)-2,3- [500031-28-7] C10H18 MW = 138.25 561


dimethylcyclopentene

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.544.
Coefficient = A + BT
A 1043.89
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 804.6 4.00 -4.77 04-tsc-11)


291.65 810.0 3.00 -0.57 15-wal-2
294.15 808.4 3.00 -0.17 15-wal-2
295.15 808.5 3.00 0.73 15-wal-2
1)
Not included in calculation of linear coefficients.

cont.

Landolt-Brnstein
New Series IV/8D
318 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

4-(1-Methylethyl)-2,3-dimethylcyclopentene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 811.9 4.6
293.15 809.4 4.0
298.15 805.4 4.0

1-Ethylidene-3-(1-methylethyl) [500030-95-5] C10H18 MW = 138.25 562


cyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 809.0 2.00 11-wal-4

1-Ethylidene-2,2,3- [500030-96-6] C10H18 MW = 138.25 563


trimethylcyclopentane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
297.15 802.4 1.50 28-von/hey

1-(3-Methylbutyl)cyclopentene [37689-15-9] C10H18 MW = 138.25 564

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
298.15 801.0 1.00 29-har
293.15 815.1 1.00 57-shu/che

3-(3-Methylbutyl)cyclopentene [37689-16-0] C10H18 MW = 138.25 565

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 796.9 1.00 37-von/kam

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 319

1-Pentylcyclopentene [4291-98-9] C10H18 MW = 138.25 566

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 812.8 1.00 39-pla
293.15 805.2 2.00 40-tur/tar
293.15 811.3 3.5 Recommended

3.6.2 6-Member Rings

(2-Butenyl)cyclohexane [500031-03-8] C 10H18 MW = 138.25 567

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.524.
Coefficient = A + BT
A 1062.23
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

294.15 813.0 2.00 0.80 27-bou


286.15 818.0 2.00 -1.00 27-bou
293.15 813.1 1.00 0.05 37-lev/pot

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 824.2 2.8
290.00 815.7 2.5
293.15 813.0 2.5
298.15 808.8 2.6

1-Butylcyclohexene [3282-53-9] C10H18 MW = 138.25 568

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 826.0 2.00 33-sig/cra
293.15 822.9 1.00 66-khr/koc
293.15 823.5 1.5 Recommended

Landolt-Brnstein
New Series IV/8D
320 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

1,2-Diethylcyclohexene [103394-01-0] C10H18 MW = 138.25 569

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
298.15 831.0 3.00 49-dic/lov
293.15 845.1 2.00 50-nic/hei

1,3-Diethylcyclohexene [500031-58-3] C10H18 MW = 138.25 570

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 805.1 1.00 50-nic/hei-1

3,5-Diethylcyclohexene [186201-35-4] C10H18 MW = 138.25 571

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 830.0 1.50 11-hen/boy

1-(1,1-Dimethylethyl)cyclohexene [3419-66-7] C10H18 MW = 138.25 572

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 827.6 1.00 56-goe/ree

3-(1,1-Dimethylethyl)cyclohexene [14072-87-8] C10H18 MW = 138.25 573

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 820.3 2.00 56-goe/ree

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 321

4-(1,1-Dimethylethyl)cyclohexene [2228-98-0] C10H18 MW = 138.25 574

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.261.
Coefficient = A + BT
A 1051.46
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

293.15 831.5 2.00 -0.10 00-pin/ipa


313.15 817.3 2.00 0.70 00-pin/ipa
293.15 831.5 0.80 -0.10 39-gro/wac

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 834.0 2.0
293.15 831.6 1.3
298.15 827.8 1.8
310.00 819.0 2.0
320.00 811.5 2.0

2-Ethyl-4,4-dimethylcyclohexene [500031-35-6] C10H18 MW = 138.25 575

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 832.0 2.00 12-von/moo

3-Ethyl-1,3-dimethylcyclohexene [99191-29-4] C10H18 MW = 138.25 576

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 827.8 2.00 54-lev/shu

Landolt-Brnstein
New Series IV/8D
322 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

1-Methylene-4-(1-methylethyl) [1124-24-9] C10H18 MW = 138.25 577


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 866.7 2.00 37-isk

1-Methyl-1-(1-methylethenyl) [16580-19-1] C10H18 MW = 138.25 578


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 844.7 0.50 55-pin/mar

1-Methyl-2-(1-methylethenyl) [15193-25-6] C10H18 MW = 138.25 579


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 834.5 1.00 66-sad/akh

1-Methyl-2-(1-methylethylidene) [15733-49-0] C10H18 MW = 138.25 580


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 834.5 0.80 08-wal/chu-3

d-1-Methyl-3-(1-methylethenyl) [500031-11-8] C10H18 MW = 138.25 581


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.7 2.00 11-kis/saw

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 323

l-1-Methyl-3-(1-methylethenyl) [500031-12-9] C10H18 MW = 138.25 582


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 818.4 2.00 11-kis-1

1-Methyl-3-(1-methylethylidene) [13828-34-7] C10H18 MW = 138.25 583


cyclohexane

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 825.0 2.00 08-wal-1
293.15 825.0 1.00 08-wal/chu-2
293.15 825.0 1.00 08-wal/chu-3
293.15 821.4 2.00 11-kis/saw
293.15 824.6 1.4 Recommended

1-Methyl-4-(1-methylethylidene) [1124-27-2] C10H18 MW = 138.25 584


cyclohexane

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 5.612.
Coefficient = A + BT
A 1071.51
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 831.0 4.00 8.67 08-wal-1


294.15 831.0 4.00 9.52 08-wal/chu-1
293.65 817.5 3.00 -4.41 10-beh
294.15 819.0 3.00 -2.48 10-beh
295.15 817.3 3.00 -3.33 14-sem/fel-1

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 825.0 5.6
293.15 822.3 5.6
298.15 818.1 5.6

Landolt-Brnstein
New Series IV/8D
324 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

1-Methyl-4-(1-methylethyl)cyclohexene [5502-88-5] C10H18 MW = 138.25 585

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
294.15 821. 0 2.00 11-wal

(R)-1-Methyl-4-(1-methylethyl) [1195-31-9] C10H18 MW = 138.25 586


cyclohexene

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 829.0 5.00 03-sem
293.15 825.8 5.00 08-bac
291.15 824.6 5.00 11-vav
293.15 810.0 4.00 18-bro/hum
293.15 821.2 5.1 Recommended

1-Methyl-4-(1-methylethenyl) [6252-33-1] C10H18 MW = 138.25 587


cyclohexane

Table 1. Fit with estimated B coefficient for 7


accepted points. Deviation w = 7.546.
Coefficient = A + BT
A 1068.92
B -0.850

Table 2. Experimental values with uncertainties.


T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 810.4 6.00 -9.34 06-sem/rim1)


293.15 814.1 6.00 -5.64 11-kis-71)
294.15 821.7 3.00 2.81 14-sem/fel-1
288.15 809.3 5.00 -14.69 36-lev/tra
293.15 823.4 5.00 3.66 66-sad/akh
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 830.9 7.6
290.00 822.4 7.5
293.15 819.7 7.5
298.15 815.5 7.6

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 325

cis-1-Methyl-4-(1-methylethenyl) [1879-07-8] C10H18 MW = 138.25 588


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 816.0 2.00 22-ski/sch

trans-1-Methyl-4-(1-methylethenyl) [1124-25-0] C10H18 MW = 138.25 589


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 792.0 2.00 22-ski/sch

1-Methyl-4-(1-methylethylidene) [500031-10-7] C10H18 MW = 138.25 590


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
294.15 831.0 2.00 06-wal-6

2-Methyl-4-(1-methylethyl)cyclohexene [500031-33-4] C10H18 MW = 138.25 591

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 828.0 4.00 01-sem-1
293.15 820.8 4.00 20-hen/sme
293.15 824.4 4.00 Recommended

3-Methyl-6-(1-methylethyl)cyclohexene [5256-65-5] C10H18 MW = 138.25 592

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 824.0 5.00 09-sem-3

Landolt-Brnstein
New Series IV/8D
326 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

4-Methyl-1-(1-methylethyl)cyclohexene [500-00-5] C10H18 MW = 138.25 593

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
273.15 827.0 2.00 02-sab/sen-1
273.15 823.0 2.00 07-sab/mai-4
273.15 825.0 2.4 Recommended

1-Methyl-3-(1-propenyl)cyclohexane [500029-71-0] C10H18 MW = 138.25 594

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 814.0 2.00 08-wal-1
292.15 814.00 2.00 08-wal/ren

1-Methyl-4-(1-propenyl)cyclohexane [500029-72-1] C10H18 MW = 138.25 595

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
293.15 815.0 2.00 08-wal-1
292.15 813.5 1.00 08-wal/ren-1
293.15 815.0 2.50 08-wal/ren-1

1-Methyl-2-propylcyclohexene [93168-17-3] C10H18 MW = 138.25 596

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 830.0 2.00 33-sig/cra

1-Methyl-3-propylidenecyclohexane [500031-09-4] C10H18 MW = 138.25 597

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 814.0 2.00 08-wal/ren

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 327

1-Methyl-4-propylidenecyclohexane [500031-13-0] C10H18 MW = 138.25 598

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
292.15 813.5 2.00 08-wal/ren
293.15 811.0 2.00 18-wal/aug

3-Methyl-1-propylcyclohexene [500031-59-4] C10H18 MW = 138.25 599

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 813.0 3.00 39-mou/pau

4-Methyl-1-propylcyclohexene [500018-95-1] C10H18 MW = 138.25 600

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 3.231.
Coefficient = A + BT
A 1041.43
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 838.7 2.00 2.13 06-sab/mai


289.15 827.0 2.00 2.43 06-sab/mai
293.15 817.0 2.00 -4.57 33-sig/cra

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 838.9 3.3
280.00 831.4 3.2
290.00 823.9 3.2
293.15 821.6 3.3
298.15 817.8 3.3

Landolt-Brnstein
New Series IV/8D
328 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

4-Methyl-2-propylcyclohexene [500018-91-7] C10H18 MW = 138.25 601

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 814.0 2.00 33-sig/cra

5-Methyl-1-propylcyclohexene [500031-60-7] C10H18 MW = 138.25 602

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 814.0 3.00 39-mou/pau

1,2,3,3-Tetramethylcyclohexene [500032-79-1] C10H18 MW = 138.25 603

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 835.0 2.00 56-opp/day

1,2,4,5-Tetramethylcyclohexene [86436-72-8] C10H18 MW = 138.25 604

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 2.982.
Coefficient = A + BT
A 1034.47
B -0.750

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

273.15 825.0 2.00 -4.61 12-wil/hat 293.15 817.0 2.00 2.39 20-von-2
293.15 811.0 2.00 -3.61 12-wil/hat 293.15 812.2 2.00 -2.41 25-eis/gor
289.65 819.9 1.00 2.66 20-von-2 293.15 812.2 2.00 -2.41 25-eis/gor

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 832.0 3.2
280.00 824.5 3.0
290.00 817.0 3.0
293.15 814.6 3.0
298.15 810.9 3.0

Landolt-Brnstein
New Series IV/8D
3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10 329

1,2, cis-4,5-Tetramethylcyclohexene [500031-36-7] C10H18 MW = 138.25 605

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 828.0 2.00 22-ski/sch

1,2, trans-4,5-Tetramethylcyclohexene [500031-37-8] C10H18 MW = 138.25 606

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 817.0 2.00 22-ski/sch

1,3,5,5-Tetramethylcyclohexene [31465-46-0] C10H18 MW = 138.25 607

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 799.1 2.00 52-von/sch-1

2,3,4,4-Tetramethylcyclohexene [500031-38-9] C10H18 MW = 138.25 608

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 828.0 2.00 01-sem-1
293.15 819.4 3.00 22-maj/kub
293.15 825.4 3.9 Recommended

3,3,5,5-Tetramethylcyclohexene [34265-90-2] C10H18 MW = 138.25 609

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 800.5 2.00 54-chi/maq

Landolt-Brnstein
New Series IV/8D
330 3.6 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C10

3,3,6,6-Tetramethylcyclohexene [50740-76-6] C10H18 MW = 138.25 610

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 789.0 2.00 54-chi/maq

1,1,2-Trimethyl-3-methylenecyclohexane [500031-14-1] C10H18 MW = 138.25 611

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
284.15 832.0 2.00 26-esc-1

3.6.3 7 to 10 Member Rings

1,4,4-Trimethylcycloheptene [4755-36-6] C10H18 MW = 138.25 612

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 818.5 1.00 36-ruz/sei

1-Ethylcyclooctene [49660-70-0] C10H18 MW = 138.25 613

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 846.2 1.00 52-hag

(Z)-Cyclodecene [935-31-9] C10H18 MW = 138.25 614

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 874.3 1.00 52-pre/sch

(E)-Cyclodecene [2198-20-1] C10H18 MW = 138.25 615

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 868.1 1.00 52-pre/sch

Landolt-Brnstein
New Series IV/8D
3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11 331

3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11


1-Hexylcyclopentene [4291-99-0] C11H20 MW = 152.28 616

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 807.9 2.00 33-zel/mic
293.15 815.8 2.00 39-pla
293.15 811.8 3.4 Recommended

4-(1-Methylethyl)-2,3,3- [500032-11-1] C11H20 MW = 152.28 617


trimethylcyclopentene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
292.15 809.5 3.00 34-von/kur

1-Butyl-2-methylcyclohexene [56608-70-9] C11H20 MW = 152.28 618

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 831.0 2.00 33-sig/cra

1-Butyl-4-methylcyclohexene [92143-85-6] C11H20 MW = 152.28 619

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 816.0 3.00 33-sig/cra

2-Butyl-4-methylcyclohexene [500018-92-8] C11H20 MW = 152.28 620

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 818.0 2.00 33-sig/cra

4-(1,1-Dimethylpropyl)cyclohexene [500031-72-1] C11H20 MW = 152.28 621

Landolt-Brnstein
New Series IV/8D
332 3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 841.0 1.00 39-gro/wac

1,3-Dimethyl-3-propylcyclohexene [500031-75-4] C11H20 MW = 152.28 622

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 826.0 2.00 54-lev/shu

2-(1-Methylethyl)-1,5- [500031-42-5] C11H20 MW = 152.28 623


dimethylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 855.0 1.50 29-rea/wat

1-(1-Methylethenyl)-2,3- [16580-20-4] C11H20 MW = 152.28 624


dimethylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 828.4 3.00 66-sad/akh

1-(1-Methylethenyl)-3,5- [16580-21-5] C11H20 MW = 152.28 625


dimethylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 836.0 3.00 66-sad/akh

4,4-Dimethyl-3-(1-methylethyl)-1- [500025-85-4] C11H20 MW = 152.28 626

Landolt-Brnstein
New Series IV/8D
3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11 333

cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 826.0 1.00 49-ste/spa

1-Ethyl-2,2-dimethyl-6- [500031-99-2] C11H20 MW = 152.28 627


methylenecyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
283.15 816.0 2.00 26-esc-1

1-Ethyl-2-propylcyclohexene [500031-74-3] C11H20 MW = 152.28 628

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 843.0 2.00 49-dic/lov

1-Ethyl-1-(2-propenyl)cyclohexane [500019-84-1] C11H20 MW = 152.28 629

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 837.9 0.80 57-khr/bal

1-(1-Methylbutyl)cyclohexene [169265-89-8] C11H20 MW = 152.28 630

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
273.15 856.0 2.00 04-sab/mai

1-(3-Methylbutyl)cyclohexene [3983-04-8] C11H20 MW = 152.28 631

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 824.0 2.00 33-sig/cra
(3-Pentenyl)cyclohexane [6881-53-4] C11H20 MW = 152.28 632

Landolt-Brnstein
New Series IV/8D
334 3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
298.15 832.2 2.00 35-mul/wak
293.11 871.6 3.00 63-gen/pet

1-Methyl-3-methylene-4- [500031-98-1] C11H20 MW = 152.28 633


(1-methylethyl)cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.15 827.3 2.00 22-oga/miz

1-Methyl-3- [500031-97-0] C11H20 MW = 152.28 634


(2-methyl-2-propenyl)cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 812.0 2.00 12-wal/von

1-Pentylcyclohexene [15232-85-6] C11H20 MW = 152.28 635

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 829.0 2.00 33-sig/cra

4-Methyl-2-(2-methylpropyl)cyclohexene [500018-93-9] C11H20 MW = 152.28 636

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 810.0 2.00 33-sig/cra

1-(2-Methylpropyl)-5- [500031-73-2] C11H20 MW = 152.28 637


methylcyclohexene

Landolt-Brnstein
New Series IV/8D
3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11 335

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 810.6 2.00 33-sig/cra

1,3,3,5,5-Pentamethylcyclohexene [500031-81-2] C11H20 MW = 152.28 638

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.125.
Coefficient = A + BT
A 1053.40
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

292.15 805.2 1.00 0.12 52-von/sch


293.15 804.1 1.00 -0.13 54-chi/maq

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 806.9 1.2
293.15 804.2 1.1
298.15 800.0 1.4

(1-Propylethenyl)cyclohexane [500031-15-2] C11H20 MW = 152.28 639

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 822.0 2.00 27-bou

1,1,2,2-Tetramethyl-3- [500032-00-8] C11H20 MW = 152.28 640


methylenecyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
284.15 824.6 2.00 26-esc-1

1,2,4-Trimethyl-4- [73156-90-8] C11H20 MW = 152.28 641


(1-methylethyl)cyclohexene

Landolt-Brnstein
New Series IV/8D
336 3.7 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C11

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 1.709.
Coefficient = A + BT
A 1094.46
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

298.15 842.3 1.50 1.28 11-ric


273.15 860.0 2.00 -2.28 11-ric

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 865.0 2.1
280.00 856.5 1.8
290.00 848.0 1.7
293.15 845.3 1.7
298.15 841.0 1.8

6,6-Dimethylcyclononene [500031-80-1] C11H20 MW = 152.28 642

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 853.1 1.00 55-blo/whe

(E)-Cycloundecene [500033-21-6] C11H20 MW = 152.28 643

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 870.6 2.00 54-zie/sau

Landolt-Brnstein
New Series IV/8D
3.8 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C12 to C13 337

3.8 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C12 to C13


1-Heptylcyclopentene [4292-00-6] C12H22 MW = 166.31 644

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 817.6 2.00 39-pla
293.15 820.6 1.00 56-pet/ser
293.15 820.0 1.5 Recommended

3-Heptylcyclopentene [66553-63-7] C12H22 MW = 166.31 645

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
294.15 807.2 2.00 41-von/rei

1,1-Dimethyl-3-methylene-2- [500032-02-0] C12H22 MW = 166.31 646


propylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
283.15 812.6 2.00 26-esc-1

1,2-Dipropylcyclohexene [100383-97-9] C12H22 MW = 166.31 647

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 868.0 3.00 49-dic/lov

2-Ethyl-1-(1-methylethyl)-4- [500031-44-7] C12H22 MW = 166.31 648


methylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 830.2 1.50 29-rea/wat

(+)-1-Ethylidene-2-(1-methylethyl)-5- [500032-01-9] C12H22 MW = 166.31 649


methylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.15 830.4 2.00 22-oga/miz

Landolt-Brnstein
New Series IV/8D
338 3.8 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C12 to C13

1-Hexylcyclohexene [3964-66-7] C12H22 MW = 166.31 650

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 824.4 2.00 56-pet/ser

1-Methyl-2-pentylcyclohexene [93915-87-8] C12H22 MW = 166.31 651

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 832.0 2.00 33-sig/cra

4-Methyl-1-(3-methylbutyl)cyclohexene [500030-58-0] C12H22 MW = 166.31 652

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1038.16
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

273.15 833.3 4.00 0.00 06-sab/mai


289.15 821.3 4.00 0.00 06-sab/mai
289.15 821.3 3.00 0.00 07-sab/mai-4
273.15 833.3 3.00 0.00 07-sab/mai-4

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 835.7 3.5
280.00 828.2 3.0
290.00 820.7 3.0

1,2,4-Triethylcyclohexene [500031-77-6] C12H22 MW = 166.31 653

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 837.0 2.00 50-nic/hei

Landolt-Brnstein
New Series IV/8D
3.8 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C12 to C13 339

1,1,3-Trimethyl-2-propylcyclohexene [500032-81-5] C12H22 MW = 166.31 654

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 839.4 2.00 56-opp/day

Cyclododecene [1501-82-2] C12H22 MW = 166.31 655

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 877.6 5.00 67-tep/far

(Z)-Cyclododecene [1129-89-1] C12H22 MW = 166.31 656

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 882.3 1.00 65-zak/kor

(E)-Cyclododecene [1486-75-5] C12H22 MW = 166.31 657

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 871.7 1.00 65-zak/kor

1,1-Dimethyl-3-methylene-2- [500032-05-3] C13H24 MW = 180.33 658


(2-methylpropyl)cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
284.15 811.2 2.00 26-esc-1

1-Methyl-4-(1-methylethyl)-3- [500032-04-2] C13H24 MW = 180.33 659


propylidenecyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.65 812.9 2.00 22-oga/miz

Landolt-Brnstein
New Series IV/8D
340 3.8 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C12 to C13 -
3.9 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C14 to C24
1-Isopropyl-2-propyl-4- [500031-45-8] C13H24 MW = 180.33 660
methylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 834.8 1.50 29-rea/wat

1-Octylcyclopentene [52315-44-3] C13H24 MW = 180.33 661

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 826.9 1.00 40-sch/gem
293.15 826.9 0.50 42-sch
293.15 826.9 0.68 49-lut
293.15 826.9 0.50 Recommended

(1-Propyl-2-butenyl)cyclohexane [500032-03-1] C13H24 MW = 180.33 662

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 835.5 2.00 36-lev/zur

3.9 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C14 to C24


1-Octylcyclohexene [15232-87-8] C14H26 MW = 194.36 663

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 841.6 2.00 42-sch/sch

1,3,3,5,5-Pentamethyl-4- [96850-42-9] C14H26 MW = 194.36 664


(1-methylethyl)cyclohexene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.800.
Coefficient = A + BT
A 1071.90
B -0.700

cont.

Landolt-Brnstein
New Series IV/8D
3.9 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C14 to C24 341

1,3,3,5,5-Pentamethyl-4-(1-methylethyl)cyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

290.15 869.6 2.00 0.80 13-mer-1


273.15 879.9 2.00 -0.80 13-mer-1

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 882.9 2.5
280.00 875.9 2.5
290.00 868.9 2.0
293.15 866.7 2.0
298.15 863.2 2.5

4-(1,1,3,3-Tetramethylbutyl)cyclohexene [500031-46-9] C14H26 MW = 194.36 665

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 856.5 1.50 37-nie/smi

1-Decylcyclopentene [62184-75-2] C15H28 MW = 208.39 666

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 829.0 1.00 40-sch/gem
293.15 829.0 0.50 42-sch
293.15 829.0 0.69 49-lut
293.15 829.0 0.50 Recommended

Landolt-Brnstein
New Series IV/8D
342 3.9 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C14 to C24

(1-Ethyl-1,3-dimethyl-1-pentenyl) [500011-27-8] C15H28 MW = 208.39 667


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 866.0 1.00 52-lev/shu-2

Cyclopentadecene [6573-72-4] C15H28 MW = 208.39 668

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.100.
Coefficient = A + BT
A 1097.74
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

341.65 841.6 1.00 0.10 31-ruz/boe


339.65 842.9 1.00 -0.10 31-ruz/boe

Table 3. Recommended values.


T exp 2 est
K kg m3
330.00 850.2 2.5
340.00 842.7 1.0
350.00 835.2 3.0

1-Methylcyclopentadecene [500032-40-6] C16H30 MW = 222.41 669

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
295.15 869.7 2.00 28-ruz/sch

Landolt-Brnstein
New Series IV/8D
3.9 Alkylcycloalkenes and Alkenylcycloalkanes (CnH2n-2), C14 to C24 343

1-Methylene-2,2,6,6- [500032-09-7] C19H36 MW = 264.49 670


tetrapropylcyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.15 861.8 3.00 35-cor/bor

Tetradecylcyclopentene [500031-78-7] C19H36 MW = 264.49 671

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 833.5 0.69 49-lut

1-Methyl-3-octadecylcyclopentene [500032-62-2] C24H46 MW = 334.63 672

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 848.2 1.00 39-gro/wac

1-Octadecylcyclohexene [500031-76-5] C24H46 MW = 334.63 673

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 845.8 2.00 39-sui/gem

Landolt-Brnstein
New Series IV/8D
4. Tabulated Data on Density - Monocyclic Hydrocarbons
(CnH2n-4)
4.1 Monocyclic Hydrocarbons (CnH2n-4), C5 - C6 347

4.1 Monocyclic Hydrocarbons (CnH2n-4), C5 - C6


1,3-Cyclopentadiene [542-92-7] C5H6 MW = 66.10 674

Table 1. Fit with estimated B coefficient for 8


accepted points. Deviation w = 2.246.
Coefficient = A + BT
A 1037.12
B -0.800

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K 3
kg m kg m3 K kg m 3
kg m3

293.15 803.0 3.00 0.40 1891-eta/lam 289.25 807.0 2.00 1.28 10-von/eis-1
291.75 804.7 2.00 1.01 1896-kra/spi 289.25 808.5 2.00 2.78 10-von/eis-1
291.75 814.3 4.00 10.55 1896-kra/spi1) 292.65 798.3 1.00 -4.70 33-zel/lev
287.25 808.3 1.50 0.98 07-eyk 293.15 803.5 0.60 0.90 49-foe/fen
288.85 807.1 1.50 1.06 07-eyk
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 813.1 2.8
290.00 805.1 2.2
293.15 802.6 2.2
298.15 798.6 2.5

1,2-bis(Methylene)cyclobutane [14296-80-1] C6H8 MW = 80.13 675

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 769.8 2.00 13-leb-2

1-Methyl-1,3-cyclopentadiene [96-39-9] C6H8 MW = 80.13 676

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 770.9 1.00 60-nar/shu

Landolt-Brnstein
New Series IV/8D
348 4.1 Monocyclic Hydrocarbons (CnH2n-4), C5 - C6

2-Methyl-1,3-cyclopentadiene [3727-31-9] C6H8 MW = 80.13 677

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 808.5 1.00 63-mir/sob

1,3-Cyclohexadiene [592-57-4] C6H8 MW = 80.13 678

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 8.2028 (combined temperature ranges,
weighted), c,uw = 9.6741 10-1 (combined
temperature ranges, unweighted).
T = 277.15 to 323.43 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.07128 103
B -7.97815 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

277.15 847.60 3.00 -2.57 04-cro( ) 295.15 834.70 3.00 -1.11 38-kaz/vol( )
288.15 836.90 3.00 -4.49 04-cro( ) 293.15 841.10 1.00 3.70 45-arb/zel()
288.55 836.57 3.00 -4.50 04-cro( ) 286.15 840.00 1.00 -2.99 54-dom/bel()
298.15 827.27 3.00 -6.14 04-cro1) 298.18 837.70 0.50 4.31 74-let/mar( )
283.15 845.40 2.00 0.02 27-sen( ) 306.93 828.50 0.50 2.09 74-let/mar( )
291.65 834.00 3.00 -4.60 27-zel/koz( ) 314.32 820.70 0.50 0.19 74-let/mar( )
289.15 842.10 2.00 1.51 29-far/sco( ) 323.43 810.90 0.50 -2.34 74-let/mar( )
293.15 840.00 2.00 2.60 30-cri() 298.15 841.60 0.60 8.19 86-tar/dia( ){
1) Not included in Fig. 1.
Further references: [1898-for, 25-hof/dam, 38-car/stu, 87-let/bax].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 855.87 2.35 293.15 837.40 1.82 310.00 823.96 0.43
280.00 847.89 2.68 298.15 833.41 1.34 320.00 815.98 0.46
290.00 839.92 2.11 300.00 831.94 1.16 330.00 808.00 1.59

cont.

Landolt-Brnstein
New Series IV/8D
4.1 Monocyclic Hydrocarbons (CnH2n-4), C5 - C6 349

1,3-Cyclohexadiene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

1,4-Cyclohexadiene [628-41-1] C6H8 MW = 80.13 679

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 2.2023 (combined temperature ranges,
weighted), c,uw = 5.7412 10-1 (combined
temperature ranges, unweighted).
T = 283.15 to 323.61 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.14463 103
B -9.88394 10-1

cont.

Landolt-Brnstein
New Series IV/8D
350 4.1 Monocyclic Hydrocarbons (CnH2n-4), C5 - C6

1,4-Cyclohexadiene(cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

283.15 860.50 2.00 -4.26 27-sen( ) 315.28 833.80 0.30 0.79 74-let/mar( ) {
293.15 855.40 0.50 0.52 42-ano-2() 323.61 824.80 0.30 0.03 74-let/mar( ) {
293.15 855.70 0.20 0.82 62-ano-3( ) 298.15 851.03 0.40 1.09 86-tar/dia()
299.29 849.70 0.30 0.89 {
74-let/mar( ) 298.15 849.00 1.00 -0.94 91-luk/tim-1()
307.25 842.00 0.30 1.06 74-let/mar( ) {
Further references: [08-zel/gor-2, 35-zel/den, 87-let/bax].

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
280.00 867.88 4.00 298.15 849.94 1.00 320.00 828.34 1.00
290.00 857.99 1.40 300.00 848.11 1.10 330.00 818.46 1.60
293.15 854.88 1.00 310.00 838.22 1.20

Landolt-Brnstein
New Series IV/8D
4.2 Monocyclic Hydrocarbons (CnH2n-4), C7 351

4.2 Monocyclic Hydrocarbons (CnH2n-4), C7


4.2.1 5-Member Rings

1-Ethenylcyclopentene [28638-58-6] C 7H10 MW = 94.16 680

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
291.15 824.0 2.00 34-uri

2-Ethyl-1,3-cyclopentadiene [22516-12-7] C7H10 MW = 94.16 681

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 823.1 1.00 60-nar/shu

Ethynylcyclopentane [930-51-8] C7H10 MW = 94.16 682

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 825.0 2.00 34-gre-2

4.2.2 6-Member Rings

1-Methyl-1,4-cyclohexadiene [4313-57-9] C7H10 MW = 94.16 683

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 845.2 0.30 43-ano-3

2-Methyl-1,3-cyclohexadiene [1489-57-2] C7H10 MW = 94.16 684

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 829.2 2.00 08-zel/gor

Landolt-Brnstein
New Series IV/8D
352 4.2 Monocyclic Hydrocarbons (CnH2n-4), C7

5-Methyl-1,3-cyclohexadiene [19656-98-5] C7H10 MW = 94.16 685


Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
3
K kg m
295.65 825.2 2.00 13-har/sei-1

(R)-5-Methyl-1,3-cyclohexadiene [78939-20-5] C7H10 MW = 94.16 686


Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
K kg m3
293.15 827.4 2.00 08-zel/gor-2

4.2.3 7 to 10 Member Rings

1,2-Cycloheptadiene [6577-10-2] C7H10 MW = 94.16 687


Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
K kg m3
293.15 853.2 2.00 36-fav

1,3-Cycloheptadiene [4054-38-0] C7H10 MW = 94.16 688

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.558.
Coefficient = A + BT
A 1114.40
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

273.15 882.3 2.00 0.08 01-wil


273.15 881.5 2.00 -0.72 01-wil-1
290.75 867.9 2.00 0.64 01-wil-1

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 884.9 2.7
280.00 876.4 2.6
290.00 867.9 2.8
293.15 865.2 2.9
298.15 861.0 3.5

Landolt-Brnstein
New Series IV/8D
4.3 Monocyclic Hydrocarbons (CnH2n-4), C8 353

4.3 Monocyclic Hydrocarbons (CnH2n-4), C8


4.3.1 5-Member Rings

2,4-Dimethyl-3-methylenecyclopentene [500031-05-0] C8H12 MW = 108.18 689

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 813.80 1.00 64-mir/kos

1-(1-Propenyl)cyclopentene [36193-53-0] C8H12 MW = 108.18 690

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
294.15 835.0 2.00 34-uri

1-Propyl-1,3-cyclopentadiene [62247-85-2] C8H12 MW = 108.18 691

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 828.8 1.00 60-nar/shu

(1-Propynyl)cyclopentane [5623-79-0] C8H12 MW = 108.18 692

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 843.0 2.00 34-gre-2

(2-Propynyl)cyclopentane [116279-08-4] C8H12 MW = 108.18 693

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
297.15 828.0 2.00 34-gre-1

4.3.2 6-Member Rings

1,3-Dimethyl-1,3-cyclohexadiene [4573-05-1] C8H12 MW = 108.18 694

Table 1. Fit with estimated B coefficient for 6


accepted points. Deviation w = 1.263.
Coefficient = A + BT
A 1082.07
B -0.850

cont.

Landolt-Brnstein
New Series IV/8D
354 4.3 Monocyclic Hydrocarbons (CnH2n-4), C8

1,3-Dimethyl-1,3-cyclohexadiene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

290.75 827.0 5.00 -7.93 10-von/eis-21) 293.15 832.4 2.00 -0.49 18-pic/kai
289.75 835.6 2.00 -0.18 10-von/eis-2 293.15 830.8 2.00 -2.09 54-lev/shu
289.35 836.5 2.00 0.38 10-von/eis-2 293.15 833.0 1.00 0.11 63-tho/sto
293.15 837.3 3.00 4.41 13-haw
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 844.1 2.5
290.00 835.6 2.3
293.15 832.9 2.3
298.15 828.6 2.3

1,4-Dimethyl-1,3-cyclohexadiene [26120-52-5] C8H12 MW = 108.18 695

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.934.
Coefficient = A + BT
A 1081.56
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

292.15 830.6 2.00 -2.64 10-von/eis


289.45 835.8 1.00 0.27 14-rot/von
288.65 836.6 1.00 0.39 15-von/hin-1

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 843.6 1.5
290.00 835.1 1.0
293.15 832.4 1.0
298.15 828.1 1.8

Landolt-Brnstein
New Series IV/8D
4.3 Monocyclic Hydrocarbons (CnH2n-4), C8 355

1,5-Dimethyl-1,3-cyclohexadiene [1453-17-4] C8H12 MW = 108.18 696

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 1.036.
Coefficient = A + BT
A 1068.12
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

291.15 819.2 2.00 -1.44 03-har/ant


292.95 818.9 2.00 -0.21 10-von/pet-2
291.55 820.5 2.00 0.20 10-von/pet-2
291.15 822.1 2.00 1.46 10-von/pet-2

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 821.6 2.0
293.15 818.9 2.0
298.15 814.7 3.5

2,3-Dimethyl-1,3-cyclohexadiene [4430-91-5] C8H12 MW = 108.18 697

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

293.15 852.1 2.00 13-haw

2,5-Dimethyl-1,3-cyclohexadiene [2050-33-1] C8H12 MW = 108.18 698

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

293.15 822.3 2.00 08-zel/gor

Landolt-Brnstein
New Series IV/8D
356 4.3 Monocyclic Hydrocarbons (CnH2n-4), C8

2,6-Dimethyl-1,3-cyclohexadiene [2050-32-0] C8H12 MW = 108.18 699

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.025.
Coefficient = A + BT
A 1071.70
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 822.5 2.00 -0.02 08-zel/gor


288.15 826.8 2.00 0.03 08-zel/gor

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 833.7 3.5
290.00 825.2 2.0
293.15 822.5 2.0
298.15 818.3 3.5

3,3-Dimethyl-1,4-cyclohexadiene [35934-83-9] C8H12 MW = 108.18 700

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

291.15 842.1 2.00 03-har/ant

5,5-Dimethyl-1,3-cyclohexadiene [33482-80-3] C8H12 MW = 108.18 701

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.6215 10-1 (combined temperature ranges,
weighted), c,uw = 4.9932 10-2 (combined
temperature ranges, unweighted).
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.07458 103
B -9.01931 10-1

cont.

Landolt-Brnstein
New Series IV/8D
4.3 Monocyclic Hydrocarbons (CnH2n-4), C8 357

5,5-Dimethyl-1,3-cyclohexadiene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

277.15 824.60 2.00 -0.01 02-cro/les-1() 293.15 810.30 2.00 0.12 02-cro/les-1()
283.15 819.10 2.00 -0.10 02-cro/les-1() 298.15 805.90 2.00 0.23 02-cro/les-1()
287.15 815.71 2.00 0.12 02-cro/les-1() 288.15 814.60 2.00 -0.09 {
03-har/ant( )
288.15 814.60 2.00 -0.09 02-cro/les-1() 293.15 810.00 1.00 -0.18
10-von/eis2( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 831.06 2.92 293.15 810.18 1.87 300.00 804.00 2.08
280.00 822.04 2.20 298.15 805.67 2.00 310.00 794.98 2.74
290.00 813.02 1.86

Landolt-Brnstein
New Series IV/8D
358 4.3 Monocyclic Hydrocarbons (CnH2n-4), C8

5,6-Dimethyl-1,3-cyclohexadiene [5715-27-5] C8H12 MW = 108.18 702

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 837.3 3.00 14-mee

3-Ethenylcyclohexene [766-03-0] C8H12 MW = 80.13 703

Table 1. Coefficients of the polynomial expansion


equation. References 60-wri and 61-wri for T =
298.15 to 402 K.
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 8.465
B -8.317 10-1
C -4.722 10-4

Table 2. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
298.15 825.4 2.00 340.00 788.8 2.00 380.00 752.2 2.50
300.00 823.8 2.00 360.00 770.7 2.50 400.00 733.4 2.50
320.00 806.5 2.00

4-Ethenylcyclohexene [100-40-3] C8H12 MW = 108.18 704

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8836 10-1 (combined temperature ranges,
weighted), c,uw = 1.5994 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 343.28 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.08518 103
B -8.67508 10-1

cont.

Landolt-Brnstein
New Series IV/8D
4.3 Monocyclic Hydrocarbons (CnH2n-4), C8 359

4-Ethenylcyclohexene (cont.)

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K 3
kg m kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

273.15 848.40 1.50 0.18 11-leb/ska-1() 311.41 815.00 0.40 -0.03 73-var/bul( )
293.15 832.00 1.50 1.13 11-leb/ska-1() 321.58 806.10 0.50 -0.11 73-var/bul( )
293.15 831.00 1.00 0.13 35-leb/ser( ){ 332.89 796.20 0.50 -0.20 73-var/bul( )
293.07 830.40 0.40 -0.54 73-var/bul( ) 343.28 787.20 0.50 -0.18 73-var/bul( )
298.10 826.20 0.40 -0.38 73-var/bul( )

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

cont.

Landolt-Brnstein
New Series IV/8D
360 4.3 Monocyclic Hydrocarbons (CnH2n-4), C8

4-Ethenylcyclohexene (cont.)

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 850.95 1.71 298.15 826.53 0.73 330.00 798.90 0.48
280.00 842.28 1.29 300.00 824.93 0.69 340.00 790.23 0.59
290.00 833.60 0.95 310.00 816.25 0.52 350.00 781.55 0.77
293.15 830.87 0.85 320.00 807.58 0.45

Ethynylcyclohexane [931-48-6] C8H12 MW = 108.18 705

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 3.723.
Coefficient = A + BT
A 1094.91
B -0.870

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 842.3 3.00 2.43 11-jeg-1


273.15 860.1 3.00 2.83 11-jeg-1
296.15 832.0 3.00 -5.26 34-gre-2

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 860.0 3.8
280.00 851.3 3.7
290.00 842.6 3.7
293.15 839.9 3.7
298.15 835.5 3.8

1-Methyl-3-methylenecyclohexene [23611-15-6] C8H12 MW = 108.18 706

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
291.95 838.9 2.00 11-von/eis-1
293.15 834.7 1.00 63-tho/sto

Landolt-Brnstein
New Series IV/8D
4.3 Monocyclic Hydrocarbons (CnH2n-4), C8 361

1-Methyl-6-methylenecyclohexene [23611-14-5] C8H12 MW = 108.18 707

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 852.1 2.00 14-haw/fyf

4.3.3 8-Member Rings

1,3-Cyclooctadiene [1700-10-3] C8H12 MW = 108.18 708

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
273.15 884.0 2.00 07-wil/ver

1,5-Cyclooctadiene [111-78-4] C8H12 MW = 108.18 709

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.85 856.4 6.00 02-doe
298.15 881.8 3.00 48-cop/bai
298.15 876.0 3.00 50-cop/hoc

(Z,Z)-1,5-Cyclooctadiene [1552-12-1] C8H12 MW = 108.18 710

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 882.0 1.00 63-zak/zhi
293.15 881.5 1.00 65-tre/mit
814.3 60.00 90-kar/kar
1)
293.15
809.4 60.00 90-kar/kar
1)
313.15
800.7 60.00 90-kar/kar
1)
333.15
794.1 60.00 90-kar/kar
1)
353.15
293.15 881.8 1.0 Recommended
1)
Not included in calculation of recommended value.

Landolt-Brnstein
New Series IV/8D
362 4.4 Monocyclic Hydrocarbons (CnH2n-4), C9

4.4 Monocyclic Hydrocarbons (CnH2n-4), C9


4.4.1 5-Member Rings

(2-Butynyl)cyclopentane [30628-30-9] C9H14 MW = 122.21 711

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
299.15 842.0 2.00 34-gre-1

3-(1-Methylethyl)-1-methyl- [25148-02-1] C9H14 MW = 122.21 712


1,3-cyclopentadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 840.0 2.00 33-tre

4.4.2 6-Member Rings

1,5-Dimethyl-3-methylenecyclohexene [500031-67-4] C9H14 MW = 122.21 713

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
290.25 830.0 2.00 15-von/tre
293.25 828.0 2.00 15-von/tre

1-Ethyl-4-methyl-1,3-cyclohexadiene [62088-32-8] C9H14 MW = 122.21 714

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.123.
Coefficient = A + BT
A 1086.87
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

292.65 837.1 2.00 -1.02 09-von-2


291.95 840.8 2.00 2.08 09-von-2
291.55 839.3 2.00 0.25 09-von-2
288.75 840.8 2.00 -0.63 14-rot/von
288.35 841.1 2.00 -0.67 14-rot/von
cont.

Landolt-Brnstein
New Series IV/8D
4.4 Monocyclic Hydrocarbons (CnH2n-4), C9 363

1-Ethyl-4-methyl-1,3-cyclohexadiene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 848.9 2.2
290.00 840.4 2.1
293.15 837.7 2.1
298.15 833.4 2.2

1-Methyl-2-(1-methylethenyl) [500031-54-9] C9H14 MW = 122.21 715


cyclopentene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 851.5 1.00 13-haw

1-(1-Methylethyl)-3-methyl-1,3- [45676-10-6] C9H14 MW = 122.21 716


cyclopentadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 825.0 2.00 33-tre-1

5-(1-Methylethyl)-1,3-cyclohexadiene [35776-64-8] C9H14 MW = 122.21 717

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 846.0 2.00 33-tre-1

1-(2-Methyl-1-propenyl)cyclohexene [500031-68-5] C9H14 MW = 122.21 718

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 853.7 1.50 14-haw/fyf

1-(2-Methyl-3-propenyl)cyclohexene [500031-69-6] C9H14 MW = 122.21 719

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 860.7 1.50 14-haw/fyf

Landolt-Brnstein
New Series IV/8D
364 4.4 Monocyclic Hydrocarbons (CnH2n-4), C9

(1,2-Propadienyl)cyclohexane [5664-17-5] C9H14 MW = 122.21 720

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 823.9 2.00 36-lev/tra

1-(2-Propenyl)cyclohexene [13511-13-2] C9H14 MW = 122.21 721

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 842.6 1.00 36-lev/tra

(1-Propynyl)cyclohexane [18736-95-3] C9H14 MW = 122.21 722

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
295.15 851.0 2.00 34-gre-2

(2-Propynyl)cyclohexane [17715-00-3] C9H14 MW = 122.21 723

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 2.685.
Coefficient = A + BT
A 1091.93
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 836.0 4.00 -6.76 23-bou-2


291.15 844.0 2.00 -0.46 25-bou
293.15 844.9 2.00 2.14 36-lev/tra

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 845.4 3.5
293.15 842.8 2.7
298.15 838.5 3.5

Landolt-Brnstein
New Series IV/8D
4.4 Monocyclic Hydrocarbons (CnH2n-4), C9 - 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 365

1,3,5-Trimethyl-1,3-cyclohexadiene [1731-26-6] C9H14 MW = 122.21 724

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 846.50 3.00 18-pic/kai

4.5 Monocyclic Hydrocarbons (CnH2n-4), C10


4.5.1 4 and 5 Member Rings

1,2-bis(1-Methylethylidene)cyclobutane [3642-16-8] C10H16 MW = 136.24 725

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w= 0.050
Coefficient = A + BT
A 1062.01
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

293.15 842.2 3.00 0.05 11-leb


273.15 857.1 3.00 -0.05 11-leb

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 859.5 0.7
280.00 852.0 0.2
290.00 844.5 0.3
293.15 842.2 0.5
298.15 838.4 0.8

1,2-Diethenyl-3,4-dimethylcyclobutane [32587-61-4] C10H16 MW = 136.24 726

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 811.3 2.00 13-leb/mer-1

Landolt-Brnstein
New Series IV/8D
366 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

1,1-Dimethyl-2-methylene-3- [24648-34-8] C10H16 MW = 136.24 727


(1-methylethylidene)cyclobutane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.050.
Coefficient = A + BT
A 1035.60
B -0.810

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

273.15 814.3 2.00 -0.05 11-leb


293.15 798.2 2.00 0.05 11-leb

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 816.9 0.7
280.00 808.8 0.2
290.00 800.7 0.3
293.15 798.1 0.5
298.15 794.1 0.8

1,1,2,2-Tetramethyl-3,4- [500032-28-0] C10H16 MW = 136.24 728


dimethylenecyclobutane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 792.7 2.00 13-leb-3

4.5.2 6-Member Rings

1-(3-Butenyl)cyclohexene [1911-19-9] C 10H16 MW = 136.24 729

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

291.15 844.5 1.00 37-lin/wan

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 367

3-(3-Butenyl)cyclohexene [104286-35-3] C10H16 MW = 136.24 730

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 812.0 1.00 57-pla/sta

(3-Butynyl)cyclohexane [500032-34-8] C10H16 MW = 136.24 731

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 846.2 2.00 37-lev/iva

1,5-Diethyl-1,3-cyclohexadiene [500032-21-3] C10H16 MW = 136.24 732

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 864.4 2.00 11-hen/boy

3-Ethenyl-1,5-dimethylcyclohexene [62184-85-4] C10H16 MW = 136.24 733

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
294.45 836.0 2.00 10-von/pet
293.15 833.2 2.00 11-von/eis-1

5-Ethenyl-1,5-dimethylcyclohexene [1611-21-8] C10H16 MW = 136.24 734

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.000.
Coefficient = A + BT
A 1052.86
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

293.15 833.0 3.00 0.00 13-leb-1


273.15 848.0 3.00 0.00 13-leb-1

cont.

Landolt-Brnstein
New Series IV/8D
368 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

5-Ethenyl-1,5-dimethylcyclohexene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 850.4 3.7
280.00 842.9 3.2
290.00 835.4 3.3
293.15 833.0 3.5
298.15 829.2 3.8

1-Methylene-4-(1-methylethenyl) [499-97-8] C10H16 MW = 136.24 735


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 872.0 2.00 37-isk

1-Methylene-4-(1-methylethylidene) [6876-10-4] C10H16 MW = 136.24 736


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
289.15 850.7 2.00 30-ric/wol

3-Methylene-6-(1-methylethenyl) [555-10-2] C10H16 MW = 136.24 737


cyclohexane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 1.680.
Coefficient = A + BT
A 1085.68
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

283.15 855.8 3.00 -3.36 1886-pes


293.15 852.0 1.50 0.84 11-fra/ser

cont.

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 369

3-Methylene-6-(1-methylethenyl)cyclohexane (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 861.7 1.9
290.00 853.7 1.7
293.15 851.2 1.7
298.15 847.2 1.8

4-Methylene-1-(1-methylethenyl) [99-84-3] C10H16 MW = 136.24 738


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
295.15 839.0 2.00 08-wal-7

1-Methyl-3-(1-methylethenyl) [38738-60-2] C10H16 MW = 136.24 739


cyclohexene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.368.
Coefficient = A + BT
A 1094.66
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

290.35 848.6 2.00 0.74 10-von/rot


293.15 845.3 1.00 -0.18 28-asc

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 848.2 0.4
293.15 845.5 0.4
298.15 841.2 0.5

Landolt-Brnstein
New Series IV/8D
370 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

1-Methyl-4-(1-methylethenyl) [138-86-3] C10H16 MW = 136.24 740


cyclohexene

Table 1. Coefficients of the polynomial expansion equation


(based on data sets 740, 741, and 742). Standard deviations
(see introduction):c,w = 2.4024 (combined temperature
ranges, weighted), c,uw = 7.0520 10-1 (combined
temperature ranges, unweighted).
T = 273.15 to 449.65 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.08541 103
B -8.14635 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

2293.14 845.00 3.00 -1.61 1888-wal-2 351.45 796.20 3.00 -2.91 07-eyk( )
277.15 862.66 1.00 3.02 06-kay/per() 291.15 846.40 2.00 -1.83 09-von-2
287.55 854.55 1.00 3.39 06-kay/per() 273.15 865.70 1.00 2.80 10-del()
288.15 854.03 1.00 3.35 06-kay/per() 293.15 853.50 1.00 6.90 10-del()
298.15 846.10 1.00 3.57 06-kay/per() 293.15 845.00 3.00 -1.60 28-tre/sch
294.00 840.20 1.50 -5.71 07-bru-1 293.15 845.00 3.00 -1.60 31-kaf/noz-2
289.75 845.00 2.00 -4.37 07-eyk 293.15 844.60 0.60 -2.00 42-ano-2( ) {
Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 865.46 2.03 330.00 816.58 1.25 400.00 759.56 4.86
280.00 857.31 1.19 340.00 808.44 1.80 410.00 751.41 4.91
290.00 849.17 0.69 350.00 800.29 2.41 420.00 743.27 4.71
293.15 846.60 0.60 360.00 792.14 3.04 430.00 735.12 4.21
298.15 842.53 0.51 370.00 784.00 3.65 440.00 726.97 3.39
300.00 841.02 0.49 380.00 775.85 4.18 450.00 718.83 2.24
310.00 832.88 0.55 390.00 767.71 4.60 460.00 710.68 3.00
320.00 824.73 0.82

cont.

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 371

1-Methyl-4-(1-methylethenyl)cyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)
Data sets 740, 741, and 742 were combined to produce graph of 1-methyl-4-(1-methylethenyl)cyclohexene.

(R)-(+)-1-Methyl-4-(1-methylethenyl) [5989-27-5] C10H16 MW = 136.24 741


cyclohexene

Table 1. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

282.95 853.00 2.00 -1.91 1883-sch-3 291.15 846.40 2.00 -1.83 09-von-2
449.65 713.50 2.00 -5.61 1883-sch-3( ) 287.85 846.80 3.00 -4.12 10-von/rot
273.15 858.36 2.00 -4.54 1899-god/ros( ) 292.75 842.50 3.00 -4.43 10-von/rot
293.15 842.65 2.00 -3.95 1899-god/ros 293.15 846.00 2.00 -0.60 11-per
277.15 857.60 3.00 -2.04 02-per 298.15 837.10 2.00 -5.43 23-von/lem
288.75 853.20 3.00 3.01 02-per 293.15 845.60 2.00 -1.00 31-hen/pag
298.15 841.20 3.00 -1.33 02-per 298.15 840.90 2.00 -1.63 35-pad/jat
294.15 840.20 1.50 -5.59 07-bru-1 293.15 841.90 2.00 -4.70 50-her/ruz
303.15 835.60 2.00 -2.86 08-clo 293.15 842.30 2.00 -4.30 50-her/ruz

Landolt-Brnstein
New Series IV/8D
372 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

(S)-(-)-1-Methyl-4-(1-methylethenyl) [5989-54-8] C10H16 MW = 136.24 742


cyclohexene

Table 1. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m 3
kg m3 in Fig. 1) K kg m 3
kg m3 in Fig. 1)

293.15 846.00 2.00 -0.60 1888-wal-3 293.75 841.70 2.00 -4.41 30-ric/wol-1
283.15 854.64 1.00 -0.11 02-per() 293.15 845.20 0.30 -1.40 90-rib/ber( )
288.15 844.34 1.00 -6.34 02-per() 298.15 841.80 0.30 -0.73 90-rib/ber( )
293.15 846.87 1.00 0.27 02-per() 303.15 838.20 0.30 -0.26 90-rib/ber( )
298.15 842.81 1.00 0.28 02-per() 308.15 833.50 0.30 -0.88 90-rib/ber( )
293.65 840.70 1.50 -5.50 07-bru-1 313.15 830.40 0.30 0.09 90-rib/ber( )
293.15 842.20 2.00 -4.40 23-von/lem 318.15 826.90 0.30 0.66 90-rib/ber( )
287.15 847.20 2.00 -4.29 30-ric/wol-1 323.15 822.60 0.30 0.44 90-rib/ber( )

1-Methyl-5-(1-methylethenyl) [13898-73-2] C10H16 MW = 136.24 743


cyclohexene

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m 3

293.15 848.1 2.00 08-fis/per


293.15 847.6 1.00 24-asc/kro
293.15 847.7 1.0 Recommended

(R)-1-Methyl-5-(1-methylethenyl) [1461-27-4] C10H16 MW = 136.24 744


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
287.15 865.8 4.00 1884-gla

2-Methyl-3-(1-methylethenyl) [500032-35-9] C10H16 MW = 136.24 745


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 846.7 3.00 11-per

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 373

(+)-3-Methyl-1-(1-methylethenyl) [500032-36-0] C10H26 MW = 146.32 746


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
290.15 862.9 2.00 11-haw/per

3-Methyl-1-(1-methylethenyl) [500032-37-1] C10H26 MW = 146.32 747


cyclohexene

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 1.350.
Coefficient = A + BT
A 1108.95
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

293.15 859.4 2.00 -0.33 10-luf/per


293.15 860.9 2.00 1.17 11-haw/per
295.15 854.9 3.00 -3.17 38-god/cau
290.15 862.9 2.00 0.58 11-haw/per

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 862.5 1.4
293.15 859.8 1.4
298.15 855.5 1.4

3-Methyl-4-(1-methylethenyl) [54356-60-4] C10H16 MW = 136.24 748


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
290.15 848.0 2.00 11-per

Landolt-Brnstein
New Series IV/8D
374 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

(3R-trans)-3-Methyl-6-(1-methylethenyl) [5113-87-1] C10H16 MW = 136.24 749


cyclohexene

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.65 838.2 2.00 07-tsc/pok
295.65 838.0 2.00 33-doe

(3S-trans)-3-Methyl-6-(1-methylethenyl) [19956-40-2] C10H16 MW = 136.24 750


cyclohexene

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
3
K kg m
293.15 837.0 2.00 37-pig/kan
292.65 839.0 2.00 37-pig/kan

4-Methyl-1-(1-methylethenyl) [586-67-4] C10H16 MW = 136.24 751


cyclohexene

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.037.
Coefficient = A + BT
A 1065.93
B -0.790

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

283.15 842.2 2.50 -0.00 06-kay/per


288.15 838.2 2.50 -0.05 06-kay/per
293.15 834.3 2.00 0.04 06-kay/per

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 844.7 0.4
290.00 836.8 0.1
293.15 834.3 0.2
298.15 830.4 0.5

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 375

(+)-4-Methyl-1-(1-methylethenyl) [500031-84-5] C10H16 MW = 136.24 752


cyclohexene

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 5.8887 (combined temperature ranges,
weighted), c,uw = 1.8508 (combined
temperature ranges, unweighted).
T = 277.15 to 298.15 K
Coefficient = A + BT + CT 2 + DT 3 +
A 9.48544 102
B -3.00450 10-1

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

277.15 871.20 3.00 5.93 06-kay/per( ) 289.15 864.05 2.00 2.38 {


11-cho/per( )
285.85 864.81 3.00 2.15 06-kay/per( ) 293.15 851.00 3.00 -9.47 33-doe()
288.15 862.62 3.00 0.65 06-kay/per( ) 287.35 858.50 2.00 -3.71
34-gru/rea( )
298.15 854.87 3.00 -4.10 06-kay/per( ) 297.15 867.90 2.00 8.63 37-god/cau()
293.15 858.00 3.00 -2.47 10-per/wal()

Further references: [06-sem/rim].

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 867.42 5.00 293.15 860.47 2.64 300.00 858.41 3.24
280.00 864.42 3.60 298.15 858.97 3.00 310.00 855.40 4.87
290.00 861.41 3.00

cont.

Landolt-Brnstein
New Series IV/8D
376 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

(+)-4-Methyl-1-(1-methylethenyl)cyclohexene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

(+)-4-Methyl-2-(1-methylethenyl) [500031-86-7] C10H16 MW = 136.24 753


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 859.4 2.00 10-luf/per

cis-4-Methyl-5-(1-methylethenyl) [500031-87-8] C10H16 MW = 136.24 754


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 849.3 2.00 11-per-1

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 377

trans-4-Methyl-5-(1-methylethenyl) [500031-88-9] C10H16 MW = 136.24 755


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 846.3 2.00 11-per-1

1-Methyl-4-(1-methylethylidene) [586-62-9] C10H16 MW = 136.24 756


cyclohexene

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.810.
Coefficient = A + BT
A 1108.53
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 854.0 3.00 -5.35 09-sem/sch1)


288.15 862.5 1.50 -1.08 31-hen/pag
288.15 862.5 1.50 -1.08 31-hen/pag
293.15 857.0 2.00 -2.35 31-kaf/noz
293.15 858.3 1.00 -1.05 37-cha/day
298.15 857.7 1.00 2.60 60-mat/sai
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 870.5 1.9
290.00 862.0 1.8
293.15 859.4 1.8
298.15 855.1 1.8

1-Methyl-5-(1-methylethyl)- [16755-34-3] C10H16 MW = 136.24 757


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 850.1 2.00 20-hen/sme

Landolt-Brnstein
New Series IV/8D
378 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

1-Methyl-4-(1-methylethyl)- [99-86-5] C10H16 MW = 136.24 758


1,3-cyclohexadiene

Table 1. Fit with estimated B coefficient for 9


accepted points. Deviation w = 2.874.
Coefficient = A + BT
A 1091.72
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m 3
kg m3 K kg m 3
kg m3

300.15 841.2 4.00 4.61 03-har1) 292.75 836.1 4.00 -6.78 09-von-21)
291.65 841.1 2.00 -2.72 03-har/ant 289.15 840.8 4.00 -5.14 09-von/von1)
293.15 846.0 3.00 3.46 06-wal-5 292.05 835.3 4.00 -8.18 14-rot/von1)
291.15 845.3 2.00 1.06 08-har/maj 291.65 846.1 3.00 2.28 15-har/mor
289.15 847.0 2.00 1.06 08-pic 296.15 851.2 4.00 11.21 29-els/gib1)
293.15 845.0 3.00 2.46 09-sem-2 292.75 837.5 3.00 -5.38 30-ric/wol
293.35 844.3 2.00 1.93 09-sem-3 291.45 838.2 3.00 -5.79 30-ric/wol
1)
Not included in calculation of linear coefficients.

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 853.7 3.0
290.00 845.2 2.9
293.15 842.5 2.9
298.15 838.3 2.9

1-Methyl-4-(1-methylethyl)- [99-85-4] C10H16 MW = 136.24 759


1,4-cyclohexadiene

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 1.207.
Coefficient = A + BT
A 1096.94
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

289.15 850.7 2.00 -0.46 27-ric/wol


293.15 849.0 2.00 1.24 30-ric/wol
288.15 853.0 2.00 0.99 30-ric/wol
293.15 846.0 2.00 -1.76 35-kaf/ike
cont.

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 379

1-Methyl-4-(1-methylethyl)-1,4-cyclohexadiene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 858.9 1.4
290.00 850.4 1.2
293.15 847.8 1.2
298.15 843.5 1.3

2-Methyl-5-(1-methylethyl)- [99-83-2] C10H16 MW = 136.24 760


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
295.15 841.0 2.00 08-wal-4

(R)-2-Methyl-5-(1-methylethyl)- [4221-98-1] C10H16 MW = 136.24 761


1,3-cyclohexadiene

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 1.401.
Coefficient = A + BT
A 1092.73
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

295.15 842.6 3.00 0.75 10-von/eis


290.25 849.0 3.00 2.98 10-von/eis
293.15 842.5 2.00 -1.05 23-smi/hur
298.15 838.7 2.00 -0.60 23-smi/hur

Table 3. Recommended values. *


T exp 2 est
K kg m3
290.00 846.2 1.4
293.15 843.6 1.4
298.15 839.3 1.4
*
Data sets 760, 761, and 762 were combined.

Landolt-Brnstein
New Series IV/8D
380 4.5 Monocyclic Hydrocarbons (CnH2n-4), C10

(S)-2-Methyl-5-(1-methylethyl)- [2243-33-6] C10H16 MW = 136.24 762


1,3-cyclohexadiene

Table 1. Fit with estimated B coefficient for 8


accepted points. Deviation w = 1.286.
Coefficient = A + BT
A 1092.73
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K kg m3 kg m3 K kg m3 kg m3

292.15 844.0 2.00 -0.41 04-wal/bes 290.25 849.0 3.00 2.98 10-von/eis
293.15 844.7 2.00 1.14 05-har/joh 293.15 842.5 2.00 -1.06 23-smi/hur
303.15 832.4 3.00 -2.66 08-clo 298.15 838.7 2.00 -0.61 23-smi/hur
295.15 842.6 3.00 0.74 10-von/eis 293.15 844.0 2.00 0.44 28-tre/sch

Table 3. Recommended values. *


T exp 2 est
K kg m3
290.00 846.2 1.3
293.15 843.6 1.3
298.15 839.3 1.3
310.00 829.2 1.6
*
Data sets 760, 761, and 762 were combined.

(+)-4-Methyl-2-(2-propenyl)cyclohexene [500031-85-6] C10H16 MW = 136.24 763

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 836.1 2.00 15-sai

1-Methyl-4-propyl-1,3-cyclohexadiene [113768-25-5] C10H16 MW = 136.24 764

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 835.3 2.00 14-rot/von

1,2,3,4-Tetramethyl-1,3-cyclohexadiene [500032-22-4] C10H16 MW = 136.24 765

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m 3

293.15 849.1 3.00 18-pic/kai

Landolt-Brnstein
New Series IV/8D
4.5 Monocyclic Hydrocarbons (CnH2n-4), C10 381

1,3,5,5-Tetramethyl-1,3-cyclohexadiene [4724-89-4] C10H16 MW = 136.24 766

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 814.4 1.00 62-lev/sha-1

2,4,4-Trimethyl-3-methylenecyclohexene [500031-89-0] C10H16 MW = 136.24 767

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
294.15 843.0 2.00 34-kuh/hof

4.5.3 7 to 10 Member Rings

1,6,7-Trimethyl-1,3-cycloheptadiene [500031-07-2] C10H16 MW = 136.24 768

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 892.4 1.00 67-kut/tis

3,4-Dimethyl-1,5-cyclooctadiene [21284-05-9] C10H16 MW = 136.24 769

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
286.15 862.3 2.00 02-doe

Cyclodecyne [500019-39-6] C10H16 MW = 136.24 770

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 897.3 1.00 52-pre/sch

Landolt-Brnstein
New Series IV/8D
382 4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12

4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12


4.6.1 C11H18

1-(3-Butenyl)-2-methylcyclohexene [500031-90-3] C11H18 MW = 150.26 771


Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
K kg m3
288.65 876.9 1.00 36-hib/lin

2,6-Diethyl-5-methyl-1,3-cyclohexadiene [91250-79-2] C11H18 MW = 150.26 772

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
295.15 833.9 2.00 64-bla/per

3,5-Dimethyl-5-(1-methylethenyl) [500032-07-5] C11H18 MW = 150.26 773


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 858.5 2.00 29-rea/wat

1,3-Dimethyl-4-(1-methylethyl)- [500032-23-5] C11H18 MW = 150.26 774


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 858.5 1.00 29-rea/wat

1,3-Dimethyl-5-(1-methylethyl)- [91250-83-8] C11H18 MW = 150.26 775


1,3-cyclohexadiene
Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
3
K kg m
293.15 839.8 1.00 62-lev/sha

(-)-1,3-Dimethyl-4-(1-methylethylidene) [500031-95-8] C11H18 MW = 150.26 776


cyclohexene
Table 1. Experimental value with uncertainty.
T exp 2 est Ref.
K kg m3
293.15 840.2 2.00 08-rup/emm-1

Landolt-Brnstein
New Series IV/8D
4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12 383

1,5-Dimethyl-3-(1-methylethylidene) [500031-96-9] C11H18 MW = 150.26 777


cyclohexene

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 6.976.
Coefficient = A + BT
A 1097.26
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m
3
kg m3

292.15 844.8 3.00 -4.14 10-von/pet


294.55 839.5 3.00 -7.40 10-von/pet
295.55 846.5 3.00 0.45 10-von/pet
296.75 856.1 3.00 11.07 10-von/pet

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 850.8 7.0
293.15 848.1 7.0
298.15 843.8 7.0

2,4-Dimethyl-4-(2-propenyl)cyclohexene [500032-06-4] C11H18 MW = 150.26 778

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.490.
Coefficient = A + BT
A 1057.67
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m
3
kg m3

289.15 841.5 2.00 0.69 1896-tie/sch


273.15 852.5 2.00 -0.31 01-gri-2
283.05 845.0 2.00 -0.38 01-gri-2

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 855.2 2.9
280.00 847.7 2.5
290.00 840.2 2.7

Landolt-Brnstein
New Series IV/8D
384 4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12

5-Propyl-1,3-dimethyl- [91250-80-5] C11H18 MW = 150.26 779


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 842.0 1.00 62-lev/sha

1-Ethyl-4-(1-methylethenyl)cyclohexene [500031-94-7] C11H18 MW = 150.26 780

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
291.15 854.5 2.00 07-wal-7

6-Ethyl-1,3,5-trimethyl- [91250-81-6] C11H18 MW = 150.26 781


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.15 917.0 2.00 64-bla/per

(+)-3-Methyl-1-(2-methyl-1-propenyl) [500031-91-4] C11H18 MW = 150.26 782


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 853.1 2.00 14-haw/fyf

(+)-4-Methyl-1-(2-methyl-1-propenyl) [500031-92-5] C11H18 MW = 150.26 783


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 844.5 2.00 14-haw/fyf

(+)-4-Methyl-2-(2-methyl-2-propenyl) [500031-93-6] C11H18 MW = 150.26 784


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 846.0 2.00 14-haw/fyf

Landolt-Brnstein
New Series IV/8D
4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12 385

4.6.2 4 and 5 Member Rings

1,2-Dimethyl-3,4- [500032-29-1] C12H20 MW = 164.29 785


bis(1-methylethylidene)cyclobutane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 824.7 2.00 13-leb/mer

4.6.3 6-Member Rings

4,4-Dimethyl-6-(2-methyl-1-propenyl) [500032-12-2] C12H20 MW = 164.29 786


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
296.15 824.6 3.00 06-kno/sch

4-Ethyl-6-methyl-4-(1-methylethenyl) [500032-13-3] C12H20 MW = 164.29 787


cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 863.1 2.00 29-rea/wat

1-Methyl-3-ethyl-4-(1-methylethyl)- [500032-24-6] C12H20 MW = 164.29 788


1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 863.1 1.00 29-rea/wat

1,2,4-Trimethyl-4-(1-methylethenyl) [16195-58-7] C12H20 MW = 164.29 789


cyclohexene

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 7.955.
Coefficient = A + BT
A 1103.15
B -0.850

cont.

Landolt-Brnstein
New Series IV/8D
386 4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12

1,2,4-Trimethyl-4-(1-methylethenyl)cyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

273.15 872.0 3.00 1.02 11-ric


298.15 835.2 2.00 -14.53 11-ric
273.15 874.1 2.00 3.12 13-leb-1
293.15 859.7 2.00 5.72 13-leb-1
289.15 862.6 2.00 5.22 38-far/pit

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 873.7 8.0
280.00 865.2 8.0
290.00 856.7 8.0
293.15 854.0 8.0
298.15 849.7 8.0

2,3,3-Trimethyl-1-(2-methyl-1-propenyl) [500031-55-0] C12H20 MW = 164.29 790


cyclopentene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.900.
Coefficient = A + BT
A 1061.52
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

273.15 842.1 2.00 -0.90 04-beh


289.15 831.1 2.00 0.90 04-beh

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 845.5 2.5
280.00 837.5 2.5
290.00 829.5 2.5

Landolt-Brnstein
New Series IV/8D
4.6 Monocyclic Hydrocarbons (CnH2n-4), C11 to C12 - 387
4.7 Monocyclic Hydrocarbons (CnH2n-4), C13 to C16
4.6.4 10-Member Rings

1,5-Cyclododecadiene [1502-04-1] C 12H20 MW = 164.29 791

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 885.6 1.00 67-tep/far

Cyclododecyne [1129-90-4] C12H20 MW = 164.29 792

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 901.9 2.00 65-zak/kor

4.7 Monocyclic Hydrocarbons (CnH2n-4), C13 to C16


1,2-bis(1-Methylethyl)-4-methyl- [500032-25-7] C13H22 MW = 178.32 793
1,3-cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 887.2 2.00 29-rea/wat

3-(1-Butenyl)-2,4,4- [500032-16-6] C13H22 MW = 178.32 794


trimethylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 853.0 3.00 11-kis-5

(+)-1-(1-Methylethenyl)-2- [500032-14-4] C13H22 MW = 178.32 795


(1-methylethyl)-5-methylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 855.1 3.00 15-sai

Landolt-Brnstein
New Series IV/8D
388 4.7 Monocyclic Hydrocarbons (CnH2n-4), C13 to C16

4-(1-Methylethenyl)-4-(1-methylethyl)- [500032-15-5] C13H22 MW = 178.32 796


6-methylcyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 887.2 2.00 29-rea/wat

1,2-bis(1-Ethylpropylidene)cyclobutane [500032-30-4] C14H24 MW = 192.34 797

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.65 856.9 2.00 13-mer-1

3,4-bis(1-Methylethylidene)-1,1,2,2- [500032-31-5] C14H24 MW = 192.34 798


tetramethylcyclobutane

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.550.
Coefficient = A + BT
A 1061.71
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

288.75 845.7 2.00 0.55 13-mer-1


273.15 856.3 2.00 -0.55 13-mer-1

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 859.2 2.8
280.00 851.7 2.6
290.00 844.2 2.7

1-(2-Ethyl-1-butenyl)-2,3,3- [500031-56-1] C14H24 MW = 192.34 799


trimethylcyclopoentene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.825.
Coefficient = A + BT
A 1087.09
B -0.750

cont.
Landolt-Brnstein
New Series IV/8D
4.7 Monocyclic Hydrocarbons (CnH2n-4), C13 to C16 389

1-(2-Ethyl-1-butenyl)-2,3,3-trimethylcyclopoentene(cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

273.15 881.4 2.00 -0.83 04-beh


292.15 868.8 2.00 0.82 04-beh

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 884.6 2.5
280.00 877.1 2.5
290.00 869.6 2.0
293.15 867.2 2.0

1,3,3,5,5-Pentamethyl-4- [500032-17-7] C14H24 MW = 192.34 800


(1-methylethenyl)cyclohexene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 1.480.
Coefficient = A + BT
A 1094.44
B -0.780

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K 3
kg m kg m3

273.15 879.9 2.00 -1.48 13-mer-1


290.15 869.6 2.00 1.48 13-mer-1

Table 3. Recommended values.


T exp 2 est
K kg m3
270.00 883.8 2.6
280.00 876.0 2.5
290.00 868.2 2.5
293.15 865.8 2.6

Landolt-Brnstein
New Series IV/8D
390 4.7 Monocyclic Hydrocarbons (CnH2n-4), C13 to C16

3-(1-4-Dimethyl-5-hexenyl)- [500032-18-8] C15H26 MW = 206.37 801


6-methylcyclohexene

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
293.15 855.7 2.00 13-sem/bec
293.15 865.0 3.00 29-ruz/van
293.15 858.6 4.1 Recommended

(-)-(3,7-Dimethyl)-1,6-octadienyl) [500032-33-7] C16H28 MW = 220.40 802


cyclohexane

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 846.8 2.00 13-rup

Landolt-Brnstein
New Series IV/8D
5. Tabulated Data on Density - Monocyclic Hydrocarbons
(CnH2n-6)
5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11 393

5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11


Cycloheptatriene [544-25-2] C7H8 MW = 92.14 803

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
273.15 912.9 3.00 1883-lad
290.65 892.9 2.00 10-von/eis-2
273.15 908.2 2.00 10-von/eis-2

5-(1-Methylethylidene)- [2175-91-9] C8H10 MW = 106.17 804


1,3-cyclopentadiene

Table 1. Experimental values with uncertainties.


T exp 2 est Ref.
K kg m3
290.15 885.8 2.00 00-thi
293.15 881.0 2.00 13-wil/hei

1,3,5-Cyclooctatriene [1871-52-9] C8H10 MW = 106.17 805

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
298.15 897.1 1.00 48-cop/bai
298.15 897.0 2.00 50-cop/hoc-1
298.15 901.3 2.00 50-cop/hoc-1
298.15 897.8 1.70 Recommended

1,3,6-Cyclooctatriene [3725-30-2] C8H10 MW = 106.17 806

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 894.0 2.00 50-cop/hoc-1

5-(1-Methylpropylidene)-1,3- [3141-02-4] C9H12 MW = 120.19 807


cyclopentadiene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.040.
Coefficient = A + BT
A 1112.48
B -0.800

cont.

Landolt-Brnstein
New Series IV/8D
394 5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11

5-(1-Methylpropylidene)-1,3-cyclopentadiene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

294.05 877.2 2.00 -0.04 11-von/eis-1


293.15 878.0 2.00 0.04 13-wil/hei

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 880.5 2.4
293.15 878.0 2.0

3,3-Dimethyl-6-methylene-1,4- [29304-70-9] C9H12 MW = 120.19 808


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.35 843.0 2.00 11-von/mul

5-(1-Ethylpropylidene)-1,3- [7301-16-8] C10H14 MW = 134.22 809


cyclopentadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
289.55 881.2 2.00 11-von/eis-1

1-(1,3-Butadienyl)cyclohexene [500032-93-9] C10H14 MW = 134.22 810

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 885.6 1.00 54-naz/kak-1

Landolt-Brnstein
New Series IV/8D
5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11 395

6,6-Dimethyl-3-ethylidene [500032-39-3] C10H14 MW = 134.22 811


cyclohexadiene

Table 1. Fit with estimated B coefficient for 3


accepted points. Deviation w = 0.936.
Coefficient = A + BT
A 1091.30
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 857.0 2.00 0.22 21-von/zie


288.65 861.4 2.00 1.02 21-von/zie
285.95 861.3 2.00 -1.24 21-von/zie

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 867.3 2.7
290.00 859.3 2.1
293.15 856.8 2.1
298.15 852.8 2.8

3-Methylene-1,6,6-trimethyl-1,4- [94925-96-9] C10H14 MW = 134.22 812


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

283.85 873.5 2.00 21-von/zie

2-Methylene-1,5-dimethyl-3,5- [500032-78-0] C10H14 MW = 134.22 813


cycloheptadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3

293.15 908.1 1.00 67-kut/tis

Landolt-Brnstein
New Series IV/8D
396 5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11

3,3-Dimethyl-6-(1-propenyl)-1,4- [500032-46-2] C11H16 MW = 148.25 814


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
288.35 861.8 2.00 21-von/zie

3-Ethenyl-2,6,6-trimethyl-1,4- [500032-47-3] C11H16 MW = 148.25 815


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
285.85 884.4 2.00 21-von/zie

6-Methylene-1,3,3,4-tetramethyl-1,4- [14069-96-6] C11H16 MW = 148.25 816


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
288.35 880.9 2.00 21-von/zie

5-(Methylethenyl)-2,3-dimethyl-1,3- [103986-54-5] C11H16 MW = 148.25 817


cyclohexadiene

Table 1. Fit with estimated B coefficient for 4


accepted points. Deviation w = 0.645.
Coefficient = A + BT
A 1108.16
B -0.800

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

294.25 872.4 2.00 -0.36 06-kla


288.15 877.6 2.00 -0.04 07-kla
293.15 874.7 2.00 1.06 08-rup/emm
292.15 873.8 2.00 -0.65 10-von/eis-2

cont.

Landolt-Brnstein
New Series IV/8D
5.1 Monocyclic Hydrocarbons (CnH2n-6), C7 to C11 397

5-(Methylethenyl)-2,3-dimethyl-1,3-cyclohexadiene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 884.2 2.6
290.00 876.2 2.1
293.15 873.6 2.0
298.15 869.6 3.0

3-Methylene-1,5,6,6-tetramethyl-1,4- [89549-36-0] C11H16 MW = 148.25 818


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
296.45 876.5 2.00 21-von/zie

2-Methyl-6-methylene-2,7-octadiene [500027-42-9] C11H16 MW = 148.25 819

Table 1. Fit with estimated B coefficient for 8


accepted points. Deviation w = 1.944.
Coefficient = A + BT
A 1047.50
B -0.850

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. T exp 2 est exp calc Ref.
K 3
kg m kg m3 K kg m 3
kg m3

294.15 799.0 3.00 1.53 01-sem 288.15 801.3 3.00 -1.27 07-enk
288.15 802.3 2.00 -0.27 01-sem 293.15 793.7 3.00 -4.62 11-sem/may
288.15 804.6 3.00 2.03 03-cha 293.15 798.2 3.00 -0.12 13-leb
288.95 802.8 3.00 0.91 06-eyk-2 288.15 804.7 3.00 2.13 34-arb/abr

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 809.5 3.0
290.00 801.0 2.6
293.15 798.3 2.5
298.15 794.1 3.0

Landolt-Brnstein
New Series IV/8D
398 5.2 Monocyclic Hydrocarbons (CnH2n-6), C12 to C15

5.2 Monocyclic Hydrocarbons (CnH2n-6), C12 to C15


1,5-Dimethyl-3-(2-methylpropen-2-ylidene) [500032-41-7] C12H18 MW = 162.27 820
cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
295.35 861.9 2.00 10-von/pet-1

3-Ethenyl-2,5,6,6-tetramethyl-1,4- [500032-49-5] C12H18 MW = 162.27 821


cyclohexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
288.55 883.7 2.00 21-von/zie

(E,E,Z)-1,5,9-Cyclododecatriene [706-31-0] C12H18 MW = 162.27 822

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
3
K kg m
298.15 889.5 1.00 63-tak/yam
298.15 889.2 0.40 89-lai/rod
298.15 889.2 0.40 Recommended

2-Ethyl-3-methyl-6-(1-methylethenyl)- [500032-48-4] C13H20 MW = 176.30 823


1,3-cyclohexadiene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 0.075.
Coefficient = A + BT
A 1104.19
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m 3
kg m3

291.15 885.9 2.00 0.07 06-kla/som


288.15 888.0 2.00 -0.08 07-kla

cont.

Landolt-Brnstein
New Series IV/8D
5.2 Monocyclic Hydrocarbons (CnH2n-6), C12 to C15 399

2-Ethyl-3-methyl-6-(1-methylethenyl)-1,3-cyclohexadiene (cont.)

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 894.2 2.8
290.00 886.7 2.2
293.15 884.3 2.5
298.15 880.6 3.5

2-Methyl-5-(1-methyethenyl)-3-propyl- [500032-50-8] C13H20 MW = 176.30 824


1,3-hexadiene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
288.15 880.4 2.00 07-kla

4-(1,5-Dimethyl-4-hexenylidene)-1- [495-62-5] C15H24 MW = 204.36 825


methylcyclohexene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 1.600.
Coefficient = A + BT
A 1090.71
B -0.750

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

288.15 873.0 2.00 -1.60 04-bur/pag


294.15 871.7 2.00 1.60 32-sim-1

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 880.7 2.8
290.00 873.2 2.2
293.15 870.9 2.0
298.15 867.1 2.8

Landolt-Brnstein
New Series IV/8D
400 5.2 Monocyclic Hydrocarbons (CnH2n-6), C12 to C15

1-Methyl-4-(1,5-dimethyl-2,4- [500032-42-8] C15H24 MW = 204.36 826


hexadieneyl)cyclohexene

Table 1. Fit with estimated B coefficient for 5


accepted points. Deviation w = 1.356.
Coefficient = A + BT
A 1119.67
B -0.850

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3 kg m3

293.15 873.1 2.00 2.61 01-sch/kre


293.15 868.4 2.00 -2.09 13-sem/bec
289.15 873.3 1.00 -0.59 22-ruz/mey-1
303.15 860.0 2.00 -1.99 28-mou
290.15 874.0 1.00 0.96 29-ruz/van-2

Table 3. Recommended values.


T exp 2 est
K kg m3
280.00 881.7 2.8
290.00 873.2 2.4
293.15 870.5 2.2
298.15 866.2 2.4
310.00 856.2 3.0

2-(3-Methylbutyl)-3-methyl-6- [500032-51-9] C15H24 MW = 204.36 827


(1-methylethenyl)-1,3-cyclohexadiene

Table 1. Experimental and recommended


values with uncertainties.
T exp 2 est Ref.
K kg m3
293.15 867.9 2.00 17-sem/jon
293.15 870.3 2.00 17-sem/jon-1
293.15 869.1 2.20 Recommended

4-(1-Methylethenyl)-1- [83212-57-1] C15H24 MW = 204.36 828


(4-methyl-3-pentenyl)cyclohexene

Table 1. Fit with estimated B coefficient for 2


accepted points. Deviation w = 10.632.
Coefficient = A + BT
A 1121.80
B -0.800

cont.

Landolt-Brnstein
New Series IV/8D
5.2 Monocyclic Hydrocarbons (CnH2n-6), C12 to C15 401

4-(1-Methylethenyl)-1-(4-methyl-3-pentenyl)cyclohexene (cont.)

Table 2. Experimental values with uncertainties and


deviation from calculated values.
T exp 2 est exp calc Ref.
K kg m3
kg m3

292.15 881.7 3.00 -6.38 31-ruz/bos


293.15 905.0 5.00 17.72 32-die/kai

Table 3. Recommended values.


T exp 2 est
K kg m3
290.00 889.8 8.6
293.15 887.3 8.6

1-(3-Propyl-3-hexen-1-yne)cyclohexene [500032-43-9] C15H24 MW = 204.36 829

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 879.6 2.00 37-nes/mar

Landolt-Brnstein
New Series IV/8D
6. Tabulated Data on Density - Monocyclic Hydrocarbons
(CnH2n-8)
6. Monocyclic Hydrocarbons (CnH2n-8), C8 - C17 405

1,3,5,7-Cyclooctatetraene [629-20-9] C8H8 MW = 104.15 830

Table 1. Coefficients of the polynomial expansion


equation. Standard deviations (see introduction):
c,w = 1.0516 10-1 (combined temperature ranges,
weighted), c,uw = 3.0423 10-2 (combined
temperature ranges, unweighted).
T = 273.15 to 353.10 K
Coefficient = A + BT + CT 2 + DT 3 +
A 1.24187 103
B -1.25701
C 5.32581 10-4

Table 2. Experimental values with uncertainties and deviation from calculated values.
T exp 2 est exp calc Ref. (Symbol T exp 2 est exp calc Ref. (Symbol
K kg m3 kg m3 in Fig. 1) K kg m3 kg m3 in Fig. 1)

273.15 938.20 1.00 -0.05 {


48-rep/sch1( ) 323.10 891.20 0.49 -0.12 55-kus( )
293.10 919.20 0.42 0.01 55-kus( ) 333.10 882.20 0.51 -0.05 55-kus( )
298.10 914.50 0.44 0.02 55-kus( ) 343.10 873.40 0.53 0.12 55-kus( )
303.10 909.00 0.45 -0.79 55-kus1) 353.10 864.40 0.56 -0.02 55-kus( )
313.10 900.60 0.47 0.09 55-kus( )
1) Not included in Fig. 1.

Table 3. Recommended values (fit to the reliable experimental values according to the equations
= A + BT + CT 2 + DT 3 + or = [1 + 1.75(1 - T/Tc)1/3 + 0.75(1 - T/Tc)][c + A(Tc -T )
+ B(Tc - T )2 + C(Tc - T )3 + D(Tc - T )4] ).
T fit T fit T fit
K kg m3 K kg m3 K kg m3
270.00 941.30 1.34 298.15 914.43 0.50 330.00 885.05 0.56
280.00 931.66 0.85 300.00 912.70 0.50 340.00 876.05 0.60
290.00 922.12 0.56 310.00 903.37 0.50 350.00 867.15 0.64
293.15 919.14 0.52 320.00 894.16 0.51 360.00 858.37 0.71

cont.

Landolt-Brnstein
New Series IV/8D
406 6. Monocyclic Hydrocarbons (CnH2n-8), C8 - C17

1,3,5,7-Cyclooctatetraene (cont.)

Fig. 1. The symbols show the deviation of the calculated from the experimental values from Table 2. The curves
above and below the zero line indicate the calculated error region of the recommended values given in Table 3. The
error bars represent the experimental errors. (Error bars smaller than the symbols are omitted for clarity of the figure.)

Methyl-1,3,5,7-cyclooctatetraene [500032-99-5] C9H10 MW = 118.18 831

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 897.8 1.00 52-cop/cam

1,2-Dimethyl-1,3,5,7-cyclooctatetraene [500033-01-2] C10H12 MW = 132.21 832

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
298.15 895.0 1.00 52-cop/cam

Landolt-Brnstein
New Series IV/8D
6. Monocyclic Hydrocarbons (CnH2n-8), C8 - C17 407

1-Ethyl-1,3,5,7-cyclooctatetraene [13402-35-2] C10H12 MW = 132.21 833

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
298.15 899.6 1.00 52-cop/van

Propyl-1,3,5,7-cyclooctatetraene [500033-00-1] C11H14 MW = 146.23 834

Table 1. Experimental value with uncertaintys.


T exp 2 est Ref.
3
K kg m
298.15 887.0 1.00 52-cop/cam

1-(3-Methylene-4,4-dimethyl-1- [500031-08-3] C14H20 MW = 188.31 835


pentynyl)cyclohexene

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
3
K kg m
293.15 876.7 2.00 61-gve/pap

1-(3-Butyl-3-hepten-1-yne)cyclohexene [500032-45-1] C17H26 MW = 230.39 836

Table 1. Experimental value with uncertainty.


T exp 2 est Ref.
K kg m3
293.15 872.4 2.00 37-nes/mar

Landolt-Brnstein
New Series IV/8D
References

Reference codes are those used in the TRC SOURCE database.


A reference code consists of the year prior to 1900, or the last
two digits of the year after 1899, the first three letters of the first
author, the first three letters of the second author. An additional
sequence number is used when more than one reference in the
database has an identical code.
References 411

**-pin/ipa Pines, H.; Ipatieff, V. N.; Unpublished data.

1825-far Faraday, M.; Philos. Trans. R. Soc. London 115 (1825) 440.

1877-wre Wreden, F.; Justus Liebigs Ann. Chem. 187 (1877) 153.

1883-lad Ladenburg, A.; Justus Liebigs Ann. Chem. 217 (1883) 74.
1883-mar/ogl Markownikov, W.; Oglobin; Zh. Russ. Fiz.-Khim. O-va. 15 (1883) 331.
1883-mar/ogl-2 Markownikov, W.; Ogloblin; Zh. Russ. Fiz.-Khim. O-va. 15 (1883) 335.
1883-sch-3 Schiff, R.; Justus Liebigs Ann. Chem. 220 (1883) 71.

1884-gla Gladstone, J. H.; J. Chem. Soc., Trans. 45 (1884) 241.


1884-los/zan Lossen, W.; Zander, A.; Justus Liebigs Ann. Chem. 225 (1884) 109.
1884-ren Renard, A.; Ann. Chim. Phys. 1 (1884) 223.

1886-pes Pesci, L.; Gazz. Chim. Ital. 16 (1886) 225.

1887-kon Konovalov, M.; Zh. Russ. Fiz.-Khim. O-va. 19 (1887) 255.

1888-wal-2 Wallach, O.; Justus Liebigs Ann. Chem. 245 (1888) 191.
1888-wal-3 Wallach, O.; Justus Liebigs Ann. Chem. 246 (1888) 221.

1889-hof Hofmann, A. W.; Chem. Ber. 22 (1889) 699.

1891-asc Aschan, O.; Ber. Dtsch. Chem. Ges. 24 (1891) 2710.


1891-eta/lam Etard, A.; Lambert, P.; C. R. Hebd. Seances Acad. Sci. 112 (1891) 945.

1892-ber Berkenheim, A.; Ber. Dtsch. Chem. Ges. 25 (1892) 686.


1892-wal-1 Wallach, O.; Ber. Dtsch. Chem. Ges. 25 (1892) 916.

1893-sem Semmler, F. W.; Chem. Ber. 26 (1893) 774.


1893-sub Subkov; Zh. Russ. Fiz.-Khim. O-va. 25 (1893) 383.
1893-thi Thiel, W.; Ber. Dtsch. Chem. Ges. 26 (1893) 922.
1893-tie/sem Tiemann, F.; Semmler, F. W.; Ber. Dtsch. Chem. Ges. 26 (1893) 2708.
1893-wis/hen Wislicenus, J.; Hentschel, W.; Justus Liebigs Ann. Chem. 275 (1893) 322.

1894-bru-1 Bruhl, J. W.; J. Prakt. Chem. 50 (1894) 119.


1894-bru-2 Bruhl, J. W.; Ber. Dtsch. Chem. Ges. 27 (1894) 1065.
1894-gue Guerbet, M.; C. R. Hebd. Seances Acad. Sci. 118 (1894) 286.
1894-mar-1 Markownikov, W.; J. Prakt. Chem. 49 (1894) 409.
1894-wag Wagner, G.; Ber. Dtsch. Chem. Ges. 27 (1894) 1636.

1895-beh Behal, A.; Bull. Soc. Chim. Fr. 13 (1895) 841.


1895-dem Demjanoff, N.; Ber. Dtsch. Chem. Ges. 28 (1895) 21.
1895-wal-2 Wallach, O.; Justus Liebigs Ann. Chem. 289 (1895) 337.
1895-zel Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 28 (1895) 780.
1895-zel/rud Zelinskii, N. D.; Rudewitsch, W.; Ber. Dtsch. Chem. Ges. 28 (1895) 1341.

1896-gus Gustavson, G.; J. Prakt. Chem. 54 (1896) 99.


1896-kra/spi Kraemer, G.; Spilker, A.; Ber. Dtsch. Chem. Ges. 29 (1896) 552.
1896-tie/sch Tiemann, F.; Schmidt, R.; Ber. Dtsch. Chem. Ges. 29 (1896) 694.
1896-zel/ref Zelinskii, N. D.; Reformatskii, S.; Chem. Ber. 29 (1896) 214.

Landolt-Brnstein
New Series IV/8D
412 References

1897-kno Knoevenagel, E.; Justus Liebigs Ann. Chem. 297 (1897) 113.
1897-kno-1 Knoevenagel, E.; Justus Liebigs Ann. Chem. 297 (1897) 159.
1897-kno/fis Knoevenagel, E.; Fischer, C.; Justus Liebigs Ann. Chem. 297 (1897) 185.
1897-mar-2 Markownikov, W.; Chem. Ber. 30 (1897) 1222.
1897-tie Tiemann, F.; Ber. Dtsch. Chem. Ges. 30 (1897) 594.
1897-zel Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 30 (1897) 1532.
1897-zel-1 Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 30 (1897) 387.

1898-for Fortey, E. C.; J. Chem. Soc. 73 (1898) 932.


1898-gus/pop Gustavson, G.; Popper, O.; J. Prakt. Chem. 58 (1898) 458.
1898-mar Markownikov, W.; Justus Liebigs Ann. Chem. 302 (1898) 1.
1898-mar-1 Markownikov, W.; Justus Liebigs Ann. Chem. 302 (1898) 19.
1898-rud Rudewitsch, W.; Zh. Russ. Fiz.-Khim. O-va. 30 (1898) 587.
1898-zel/nou Zelinskii, N. D.; Noumow, S.; Ber. Dtsch. Chem. Ges. 31 (1898) 3206.

1899-god/ros Godlewsky, B.; Roshanoivitsch; Zh. Russ. Fiz.-Khim. O-va. 31 (1899) 201.
1899-kur Kursanov, D.; Zh. Russ. Fiz.-Khim. O-va. 31 (1899) 161.
1899-kur-1 Kurssanow, N.; Ber. Dtsch. Chem. Ges. 32 (1899) 2972.
1899-mar-1 Markownikov, W.; Zh. Russ. Fiz.-Khim. O-va. 31 (1899) 214.
1899-mar-3 Markownikov, W.; Justus Liebigs Ann. Chem. 307 (1899) 335.
1899-you/for Young, S.; Fortey, E. C.; J. Chem. Soc., Trans. 75 (1899) 873.

00-gus Gustavson, G.; J. Prakt. Chem. 62 (2) (1900) 271.


00-kon/sch Kondakow, I.; Schindelmeiser, J.; J. Prakt. Chem. 61 (1900) 477.
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00-you/for-1 Young, S.; J. Chem. Soc. 77 (1900) 372.

01-gri-2 Grignard, V.; Ann. Chim. 24 (1901) 433.


01-kur Kursanov, D.; Zh. Russ. Fiz.-Khim. O-va. 33 (1901) 301.
01-kur-2 Kurssanow, N.; Ber. Dtsch. Chem. Ges. 34 (1901) 2035.
01-sab/sen Sabatier, P.; Senderens, J. B.; C. R. Hebd. Seances Acad. Sci. 132 (1901) 1254.
01-sab/sen-1 Sabatier, P.; Senderens, J. B.; C. R. Hebd. Seances Acad. Sci. 132 (1901) 566.
01-sch/kre Schreiner, O.; Kremers, R. E.; Pharm. Arch. 4 (1901) 141.
01-sem Semmler, F. W.; Chem. Ber. 34 (1901) 3126.
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01-wil Willstatter, R.; Ber. Dtsch. Chem. Ges. 34 (1901) 129.
01-wil-1 Willstatter, R.; Justus Liebigs Ann. Chem. 317 (1901) 204.
01-zel-1 Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 34 (1901) 1799.
01-zel-2 Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 34 (1901) 3950.
01-zel/lep-1 Zelinskii, N. D.; Lepeschkin, N.; Justus Liebigs Ann. Chem. 319 (1901) 303.
01-zel/zel Zelinskii, N. D.; Zelikov, J.; Ber. Dtsch. Chem. Ges. 34 (1901) 2856.
01-zel/zel-1 Zelinskii, N. D.; Zelikov, J.; Ber. Dtsch. Chem. Ges. 34 (1901) 3249.

02-cro/les-1 Crossley, A. W.; LeSueur, H.; J. Chem. Soc. 81 (1902) 821.


02-doe Doebner, O.; Ber. Dtsch. Chem. Ges. 35 (1902) 2129.
02-mar Markownikov, W.; Zh. Russ. Fiz.-Khim. O-va. 34 (1902) 904.
02-mar/jak Markownikov, W.; Jakub; Zh. Russ. Fiz.-Khim. O-va. 34 (1902) 914.
02-per Perkin, W. H.; J. Chem. Soc. 81 (1902) 292.
02-sab/sen-1 Sabatier, P.; Senderens, J. B.; C. R. Hebd. Seances Acad. Sci. 134 (1902) 1130.
02-spe Speransky, N.; Zh. Russ. Fiz.-Khim. O-va. 34 (1902) 24.

Landolt-Brnstein
New Series IV/8D
References 413

02-wal-1 Wallach, O.; Ber. Dtsch. Chem. Ges. 35 (1902) 2822.


02-zel Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 35 (1902) 2488.
02-zel-1 Zelinskii, N. D.; Ber. Dtsch. Chem. Ges. 35 (1902) 2677.
02-zel/mos Zelinskii, N. D.; Moser, A.; Ber. Dtsch. Chem. Ges. 35 (1902) 2684.

03-cha Chapman, A. C.; J. Chem. Soc. 83 (1903) 506.


03-eyk Eykman, J. F.; Chem. Weekbla. 1 (1903) 7.
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03-wal/col Wallach, O.; Collmann, Fr.; Thede, J.; Justus Liebigs Ann. Chem. 327 (1903) 131.

04-bal/ang Balbiano, L.; Angeloni, L.; Atti Accad. Naz. Lincei, Cl. Sci. Fis., Mat. Nat., Rend. 13
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04-sab/mai Sabatier, P.; Mailhe, A.; C. R. Hebd. Seances Acad. Sci. 138 (1904) 1321.
04-sem Semmler, F. W.; Ber. Dtsch. Chem. Ges. 37 (1904) 234.
04-tsc-1 Tschugaev, L.; Ber. Dtsch. Chem. Ges. 37 (1904) 1481.
04-wal/bes Wallach, O.; Beschke, E.; Justus Liebigs Ann. Chem. 336 (1904) 9.
04-zel Zelikov, J.; Ber. Dtsch. Chem. Ges. 37 (1904) 1374.

05-ale Alexejewa, D.; Zh. Russ. Fiz.-Khim. O-va. 37 (1905) 419.


05-cro/ren Crossley, A. W.; Renouf, N.; J. Chem. Soc. 87 (1905) 1487.
05-har/joh Harries, C.; Johnson, M.; Ber. Dtsch. Chem. Ges. 38 (1905) 1832.
05-kis-1 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va. 37 (1905) 517.
05-kis-2 Kishner, N.; J. Soc. Chim. St. Petersbourg 37 (1905) 514.
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05-sab/mai Sabatier, P.; Mailhe, A.; C. R. Hebd. Seances Acad. Sci. 140 (1905) 350.
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05-sab/sen-1 Sabatier, P.; Senderens, J. B.; Ann. Chim. Phys. 4 (1905) 358.
05-zel Zelinskii, N. D.; Zh. Russ. Fiz.-Khim. O-va. 37 (1905) 962.
05-zel-1 Zelinskii, N. D.; Zh. Russ. Fiz.-Khim. O-va. 38 (1905) 625.

06-cro/ren Crossley, A. W.; Renouf, N.; J. Chem. Soc., Trans. 89 (1906) 26.
06-eyk-1 Eykman, J. F.; Chem. Weekbl. 3 (1906) 685.
06-eyk-2 Eykman, J. F.; Chem. Weekbl. 3 (1906) 701.
06-kay/per Kay, F. W.; Perkin, W. H.; J. Chem. Soc. 89 (1906) 839.
06-kla Klages, A.; Chem. Ber. 39 (1906) 2306.
06-kla/som Klages, A.; Sommer, P.; Ber. Dtsch. Chem. Ges. 39 (1906) 2306.
06-kno/sch Knoevenagel, E.; Schwartz, R.; Ber. Dtsch. Chem. Ges. 39 (1906) 3441.
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Landolt-Brnstein
New Series IV/8D
414 References

06-sem/rim Semmler, F. W.; Rimpel, C.; Ber. Dtsch. Chem. Ges. 39 (1906) 2582.
06-wal Wallach, O.; Justus Liebigs Ann. Chem. 347 (1906) 316.
06-wal-4 Wallach, O.; Justus Liebigs Ann. Chem. 345 (1906) 139.
06-wal-5 Wallach, O.; Justus Liebigs Ann. Chem. 350 (1906) 141.
06-wal-6 Wallach, O.; Ber. Dtsch. Chem. Ges. 39 (1906) 2504.
06-wal/bes Wallach, O.; Beschke, E.; Justus Liebigs Ann. Chem. 347 (1906) 338.
06-zel Zelinskii, N. D.; Zh. Russ. Fiz.-Khim. O-va. 38 (1906) 473.
06-zel/gut Zelinskii, N. D.; Gutt, J.; Zh. Russ. Fiz.-Khim. O-va. 38 (1906) 476.

07-bla-2 Blanc, G.; C. R. Hebd. Seances Acad. Sci. 145 (1907) 681.
07-bru-1 Bruhl, J. W.; J. Chem. Soc. 91 (1907) 115.
07-enk Enklaar, C. J.; Rec. Trav. Chim. Pays-Bas 26 (1907) 166.
07-eyk Eykman, J. F.; Chem. Weekbl. 4 (1907) 41.
07-fav/bor Favorskii, A. E.; Borgmann, I.; Ber. Dtsch. Chem. Ges. 40 (1907) 4863.
07-kla Klages, A.; Chem. Ber. 40 (1907) 2360.
07-sab/mai-4 Sabatier, P.; Mailhe, A.; Ann. Chim. Phys. 10 (1907) 527.
07-tsc/pok Tschugaev, L.; Pokrowski; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 39 (1907) 1338.
07-wal-7 Wallach, O.; Justus Liebigs Ann. Chem. 357 (1907) 49.
07-wal/fle Wallach, O.; Fleischer, A.; Justus Liebigs Ann. Chem. 353 (1907) 304.
07-will/bru Willstatter, R.; Bruce, J.; Chem. Ber. 40 (1907) 3979.
07-will/ver Willstatter, R.; Veraguth, H.; Ber. Dtsch. Chem. Ges. 40 (1907) 957.
07-zel Zelinskii, N. D.; Chem. Ber. 40 (1907) 3277.

08-bac Bacon, R. F.; Philippine J. Sci. 3 (1908) 49.


08-bou/lev Bouveault, L.; Levallois, F.; C. R. Hebd. Seances Acad. Sci. 146 (1908) 180.
08-clo Clover, A. M.; Am. Chem. J. 39 (1908) 613.
08-fis/per Fisher, K.; Perkin, W. H.; J. Chem. Soc. 93 (1908) 1876.
08-har/maj Harries, C.; Majema, B.; Ber. Dtsch. Chem. Ges. 41 (1908) 2516.
08-har/tan Harries, C.; Tank, L.; Ber. Dtsch. Chem. Ges. 41 (1908) 1701.
08-kis Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 40 (1908) 994.
08-kis-3 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 40 (1908) 676.
08-pic Pickles, S. S.; J. Chem. Soc. 93 (1908) 862.
08-rup/emm Rupe, H.; Emmerich, F.; Ber. Dtsch. Chem. Ges. 41 (1908) 1393.
08-rup/emm-1 Rupe, H.; Emmerich, F.; Ber. Dtsch. Chem. Ges. 41 (1908) 1750.
08-ski Skita, A.; Chem. Ber. 41 (1908) 2938.
08-wal-1 Wallach, O.; Justus Liebigs Ann. Chem. 360 (1908) 26.
08-wal-4 Wallach, O.; Justus Liebigs Ann. Chem. 359 (1908) 265.
08-wal-5 Wallach, O.; Justus Liebigs Ann. Chem. 359 (1908) 291.
08-wal-7 Wallach, O.; Justus Liebigs Ann. Chem. 362 (1908) 285.
08-wal/chu Wallach, O.; Churchill, J. B.; Rentschler, M.; Justus Liebigs Ann. Chem. 360 (1908) 55.
08-wal/chu-1 Wallach, O.; Churchill, J. B.; Justus Liebigs Ann. Chem. 360 (1908) 70.
08-wal/chu-2 Wallach, O.; Churchill, J. B.; Justus Liebigs Ann. Chem. 360 (1908) 75.
08-wal/chu-3 Wallach, O.; Churchill, J. B.; Justus Liebigs Ann. Chem. 360 (1908) 80.
08-wal/eva Wallach, O.; Evans, E.; Justus Liebigs Ann. Chem. 360 (1908) 44.
08-wal/eva-1 Wallach, O.; Evans, E.; Justus Liebigs Ann. Chem. 360 (1908) 51.
08-wal/eva-2 Wallach, O.; Evans, E.; Justus Liebigs Ann. Chem. 360 (1908) 52.
08-wal/mal Wallach, O.; Mallison, H.; Justus Liebigs Ann. Chem. 360 (1908) 68.
08-wal/ren Wallach, O.; Rentschler, M.; Justus Liebigs Ann. Chem. 360 (1908) 59.
08-wal/ren-1 Wallach, O.; Rentschler, M.; Justus Liebigs Ann. Chem. 360 (1908) 64.
08-will/kam Willstatter, R.; Kametaka, T.; Chem. Ber. 41 (1908) 1480.
08-zel/gor Zelinskii, N. D.; Gorskii, A.; Chem. Ber. 41 (1908) 2630.
08-zel/gor-1 Zelinskii, N. D.; Gorskii, A.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 40 (1908) 1399.

Landolt-Brnstein
New Series IV/8D
References 415

08-zel/gor-2 Zelinskii, N. D.; Gorsky, A.; Ber. Dtsch. Chem. Ges. 41 (1908) 2479.
08-zel/gut Zelinskii, N. D.; Gutt, J.; Chem. Ber. 41 (1908) 2431.

09-bru Bruylants, P.; Recl. Trav. Chim. Pays-Bas Belg. 28 (1909) 188.
09-eyk Eykman, J. F.; Chem. Weekbl. 6 (1909) 699.
09-mur Murat, M.; Ann. Chim. Phys. 16 (1909) 108.
09-noy/der Noyes, W. A.; Derick, C. G.; J. Am. Chem. Soc. 31 (1909) 669.
09-sem-2 Semmler, F. W.; Ber. Dtsch. Chem. Ges. 42 (1909) 4171.
09-sem-3 Semmler, F. W.; Ber. Dtsch. Chem. Ges. 42 (1909) 522.
09-sem/sch Semmler, F. W.; Schossberger, E; Ber. Dtsch. Chem. Ges. 42 (1909) 4644.
09-smi Smirnow, V.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 41 (1909) 1375.
09-vav Vavon, M. G.; C. R. Hebd. Seances Acad. Sci. 149 (1909) 997.
09-von-2 Von Auwers, K.; Ber. Dtsch. Chem. Ges. 42 (1909) 2424.
09-von/von Von Auwers, K.; Von Heyden, F.; Ber. Dtsch. Chem. Ges. 42 (1909) 2404.
09-wal-6 Wallach, O.; Justus Liebigs Ann. Chem. 369 (1909) 83.
09-wal/mar Wallach, O.; Martins, V.; Justus Liebigs Ann. Chem. 365 (1909) 272.
09-wal/ren Wallach, O.; Rentschler, M.; Justus Liebigs Ann. Chem. 365 (1909) 269.

10-beh Behal, A.; C. R. Hebd. Seances Acad. Sci. 150 (1910) 1764.
10-cro/gil Crossley, A. W.; Gilling, C.; J. Chem. Soc. 97 (1910) 2218.
10-del Delepine, M.; Bull. Soc. Chim. Fr. 7 (1910) 468.
10-der De Resseguier, B.; Bull. Soc. Chim. Fr. 7 (1910) 432.
10-eng/hal Engler, C.; Halmai, B.; Chem. Ber. 43 (1910) 397.
10-ipa Ipatieff, W.; Chem. Ber. 43 (1910) 3383.
10-kis-3 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 42 (1910) 1211.
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10-luf/per Luff, B.; Perkin, W. H.; J. Chem. Soc. 97 (1910) 2154.
10-noy/der Noyes, W. A.; Derick, C. G.; J. Am. Chem. Soc. 32 (1910) 1061.
10-noy/kyr Noyes, W. A.; Kyriakides, L. P.; J. Am. Chem. Soc. 32 (1910) 1064.
10-per/wal Perkin, W. H.; Wallach, O.; Justus Liebigs Ann. Chem. 374 (1910) 198.
10-von/eis Von Auwers, K.; Eisenlohr, F.; J. Prakt. Chem. 82 (1910) 65.
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10-von/pet Von Auwers, K.; Peters, G.; Chem. Ber. 43 (1910) 3076.
10-von/pet-1 Von Auwers, K.; Peters, G.; Ber. Dtsch. Chem. Ges. 43 (1910) 3094.
10-von/pet-2 Von Auwers, K.; Peters, G.; Ber. Dtsch. Chem. Ges. 43 (1910) 3111.
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10-will/was Willstatter, R.; Waser, E.; Chem. Ber. 43 (1910) 1176.
10-you-1 Young, S.; Sci. Proc. R. Dublin Soc. 12 (1910) 374.

11-cho/per Chou, T.; Perkin, W. H.; J. Chem. Soc. 99 (1911) 530.


11-dra Drapier, P.; Bull. Cl. Sci., Acad. R. Belg. 1 (1911) 621.
11-eyk Eykman, J. F.; Chem. Weekbl. 8 (1911) 653.
11-eyk-1 Eykman, J. F.; Chem. Weekbl. 8 (1911) 651.
11-fra/ser Francesconi, L.; Sernagiotto, E.; Atti accad. Lincei 20 (1911) 329.
11-haw/per Haworth, W. N.; Perkin, W. H.; Wallach, O.; Justus Liebigs Ann. Chem. 379 (1911) 131.
11-hen/boy Henderson, G. G.; Boyd, R.; J. Chem. Soc. 99 (1911) 2159.
11-jeg-1 Jegorowa, W.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 1119.
11-kis Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 1149.
11-kis-1 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 1562.
11-kis-4 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 43 (1911) 582.
11-kis-5 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 43 (1911) 1398.

Landolt-Brnstein
New Series IV/8D
416 References

11-kis-7 Kishner, N.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 43 (1911) 951.
11-kis/kla Kishner, N.; Klawikordow, V.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 597.
11-kis/sav Kishner, N.; Savadosky, A.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 43 (1911) 1132.
11-kis/saw Kishner, N.; Sawadowski, A.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 1137.
11-leb Lebedev. S. V.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 820.
11-leb/ska Lebedev, S.; Skawronskaja, F.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 43 (1911) 1124.
11-leb/ska-1 Lebedev, S.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 43 (1911) 1136.
11-per Perkin, W. H.; J. Chem. Soc. 99 (1911) 727.
11-per-1 Perkin, W. H.; J. Chem. Soc. 99 (1911) 741.
11-per/pop Perkin, W. H.; Pope, W. J.; J. Chem. Soc. 99 (1911) 1514.
11-ric Richard, A. H.; C. R. Hebd. Seances Acad. Sci. 153 (1911) 116.
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11-sem/may Semmler, F. W.; Mayer, E. W.; Chem. Ber. 44 (1911) 2009.
11-ski/rit Skita, A.; Ritter, H.; Ber. Dtsch. Chem. Ges. 44 (1911) 668.
11-vav Vavon, M. G.; C. R. Hebd. Seances Acad. Sci. 152 (1911) 1675.
11-von/eis-1 Von Auwers, K.; Eisenlohr, F.; J. Prakt. Chem. 84 (1911) 1.
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12-ipa-1 Ipatieff, V. N.; Ber. Dtsch. Chem. Ges. 45 (1912) 3205.


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12-mey-1 Meyerfeld, J.; Chem.-Ztg. 36 (1912) 549.
12-ost Ostling, G. J.; J. Chem. Soc. 101 (1912) 457.
12-von/ell Von Auwers, K.; Ellinger, P.; Justus Liebigs Ann. Chem. 387 (1912) 200.
12-von/moo Von Auwers, K.; Moosbrugger, W.; Justus Liebigs Ann. Chem. 387 (1912) 167.
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12-zel/sch Zelinskii, N. D.; Schtscherbak, B.; J. Russ. Phys. Chem. Soc. 44 (1912) 1880.

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13-kis/amo Kishner, N.; Amosow, P.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 45 (1913) 957.
13-leb Lebedev, S.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 45 (1913) 1249.
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13-leb-2 Lebedev, S.; Zh. Russ. Fiz.-Khim. O-va., Chast Khim. 45 (1913) 1357.
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New Series IV/8D
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14-haw/fyf Haworth, W. N.; Fyfe, A.; J. Chem. Soc. 105 (1914) 1659.
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15-hal Halse, O. M.; J. Prakt. Chem. 92 (1915) 40.


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New Series IV/8D
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17-dem/doj Demjanow, N. J.; Dojarenko, M.; Zh. Russ. Fiz.-Khim. O-va., Chast Fiz. 49 (1917) 199.
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18-bro/hum Brooks, B. T.; Humphrey, I.; J. Am. Chem. Soc. 40 (1918) 822.
18-mee/fle Meerwein, H.; Fleischhauer, Cl.; Justus Liebigs Ann. Chem. 417 (1918) 263.
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18-von-1 Von Auwers, K.; Justus Liebigs Ann. Chem. 415 (1918) 142.
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18-wal/aug Wallach, O.; Augspurger, L.; Justus Liebigs Ann. Chem. 414 (1918) 212.

19-cha/sim-1 Chavanne, G.; Simon, L. J.; C. R. Hebd. Seances Acad. Sci. 168 (1919) 1324.
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20-hen/sme Henderson, G. G.; Smeaton, T. F.; J. Chem. Soc. 117 (1920) 144.
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21-far/gar Faragher, W. F.; Garner, F. H.; J. Am. Chem. Soc. 43 (1921) 1715.
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22-cha Chavanne, G.; Bull. Soc. Chim. Belg. 31 (1922) 331.


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27-bau Baurguel, M.; Bull. Soc. Chim. Belg. 41 (1927) 1475.


27-bou Bourguel, M.; Bull. Soc. Chim. Fr. 41 (1927) 1475.
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28-ada/mar Adams, R.; Marshall, J. R.; J. Am. Chem. Soc. 50 (1928) 1970.
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29-bau-1 Baudreghien, J.; Bull. Soc. Chim. Belg. 38 (1929) 172.


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30-cha Chavanne, G.; Bull. Soc. Chim. Belg. 39 (1930) 402.


30-cha/mil Chavanne, G.; Miller, O.; Bull. Soc. Chim. Belg. 39 (1930) 287.
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31-bru/hic-1 Bruun, J. H.; Hicks-Brunn, M. M.; J. Res. Natl. Bur. Stand. (U. S.) 7 (1931) 607.
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35-chi Chiurdoglu, G.; Bull. Soc. Chim. Belg. 44 (1935) 527.


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39-ano Am. Pet. Inst. Hydrocarbon Res. Proj., First Annu. Rep., Ohio State Univ., Aug. 31,
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40-ano Am. Pet. Inst. Hydrocarbon Res. Proj., Second Annu. Rep., Ohio State Univ., Aug. 31,
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55-ano-8 Am. Pet. Inst. Res. Proj. 45, Ohio State Univ., April (1955).
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63-ano-3 Am. Pet. Inst. Res. Proj. 58A, Annu. Rep., June (1963).
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66-bat Battino, R.; J. Phys. Chem. 70 (1966) 3408.


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94-del/fer DeLorenzi, L.; Fermeglia, M.; Torriano, G.; J. Chem. Eng. Data 39 (1994) 483.
94-kri/vis Krishnaiah, A.; Viswanath, D. S.; Toghiani, H.; Experimental Results for DIPPR
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94-toj/ram Tojo, J.; Ramallo, A. V.; Orge, B.; J. Chem. Eng. Data 39 (1994) 480.

95-art/mun-3 Artal, M.; Munoz Embid, J.; Velasco, I.; Otin, S.; J. Chem. Thermodyn. 27 (1995) 475.
95-gaw/dor Gawronska, E.; Dordain, L.; Coxam, J. -Y.; Quint, J. R.; Grolier, J.-P. E.; J. Chem. Eng.
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95-org/igl Orge, B.; Iglesias, M.; Tojo, J.; J. Chem. Eng. Data 40 (1995) 260.
95-osw/pat Oswal, S. L.; Patel, N. B.; J. Chem. Eng. Data 40 (1995) 840.
95-pet/gas Petrino, P. J.; Gaston-Bonhomme, Y. H.; Chevalier, J. L. E.; J. Chem. Eng. Data 40
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Landolt-Brnstein
New Series IV/8D

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