Aiits 2016 HCT Vi Jeem Jeea Advanced Paper-2 Solutions Solutions

1
AIITS-HCT-VI(Paper-2)-PCM(S)-JEE(Advanced)/16
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ALL INDIA INTEGRATED TEST SERIES
ANSWERS, HINTS & SOLUTIONS
HALF COURCE TEST VI
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A A C
4551 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
2. A B A
3. D C B
4. A A D
5. A, C A, C, D A, B
6. A, C B, D B, D
7. A, B, C, D A, C, D A, D
8. A, D A, B, D B, C
9. C A A
10. A B B
11. B C A
(A) (p, q, r, s) (A) (r, t) (A) (s)
(B) (p, q, r, s, t) (B) (p, q, r, s, t) (B) (r)
1.
(C) (q, r) (C) (p, s, t) (C) (p)
(D) (q, r, s, t) (D) (p, q, s, t) (D) (q)
(A) (q, r, t) (A) (q, t) (A) (r)
(B) (q, r, t) (B) (s, t) (B) (q)
2.
(C) (p, s) (C) (p, t) (C) (r)
(D) (q, t) (D) (p, t) (D) (s)
1. 2 4 2
2. 9 4 6
3. 6 4 8
4. 3 9 3
5. 2 4 5
6. 5 4 9
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2
Physics PART I
SECTION A
2
v h
1. tan and tan
Rg d
3. Static friction depends on tendency.
L
g
4. vA 4

3L
g
vB 4

vB 3v A
4
5. Gravitational field inside the cavity is E Gr
3

where is mass density and r is separation between centre of sphere and centre of cavity.
Applying law of Conservation of energy :
1 GMm GMm
mVesc 2 0
2 R 45R
88GM
Solving Vesc .
45R
1
6. T1 > T2 > T3 as 1 < 2 < 3 (Wien's law)
T
Now as the area under the curve E and gives the intensity; so
Ae 4 4
3T3 > Ae 2T2 {Areas of the bodies are same, given}
Now as T3 < T2 e3 > e2.
7. P = V3 , for ideal gas

PV = nRT
(A) relation between V and T
V (3V3) = nRT
nR
V4 = 4
T V T
3
(B) Relation between P and T
1/ 3
P
PV = nRT P = nRT
3
P 4/3 T
(C) For expansion
V increases
work-done : positive
internal energy : increases
Hence, heat will have to supplied to the gas.
(D) As T V4
with increase in temperature, volume increases
Hence work done is positive.
3
8. Both (A) and (D) depend on g.
SECTION B
1. Adiabatic dQ = 0
Isochoric dW = 0
Isothermal dT = 0 dU = 0
2. (A) (q, r, t), (B) (q, r, t), (C) (p, s), (D) (q, t)
SECTION C
T
1. v

T can be calculated by using Hookes Law and on stretching also changes.
340 10
2. f1 = f f
340 34 9
340 20
and f2 = f f
340 17 19
10
f1 19
and = 9
f2 20 18
19
3. For 1st reading of oscillator
f A = (514 2)Hz
f A = 516 Hz or 512 Hz
For 2nd reading of oscillator
f A = (510 6) Hz
f A = 516 Hz or 504 Hz
A has a frequency of 516 Hz
4. x3 x2
y d2y
30 10
N dx 2
dy x 2 x dy
and at x 2; 0
dx 10 5 dx
Mg
d2 y x 1 d2 y
andat x 2; ve
dx2 5 5 dx2 Approximate graph
Hence the particle is at its lowest (minimum) position, in its

path at x = 2 m
d2 y dx dx
2
2x 2
dt dt dt
d2 y
2 20m / s 2
dt at x 2
d2 y
N mg m N 110 20 30N
dt 2
1
P f.v N V 30 10 3 watt
100
4
5. Tension in rod at a distance x from right edge is

x
T = F(3 2 )
L
L
T 2F
net extension in rod = dx = L
0
YA YA
6. The plate is free to rotate about vertical axis yy.

Let v, vcm and be the velocity of particle, velocity of centre of mass of plate
and angular velocity of plate just after collision.
From conservation of angular momentum about vertical axis passing
though O is
a a ma2
mu = mv + ....(1)
2 2 3
since the collision is elastic, the equation of coefficient of restitution is
v v
e = cm =1 ....(2)
u
a
But vcm = ....(3)
2
12 u
solving equation (1), (2) and (3) we get =
7 a
5
Chemistry PART II
SECTION A
1. O2 has one unpaired electron. It is paramagnetic.
2. In, SO32 , S has 3 bond pairs and one lone pair and hence, it is pyramidal in shape not tetrahedral.
Hence (B) is correct.
3. (A). Three possible spin quantum number means an orbital can have at the most three electrons.
So 4th period involves,
3s,3d and 4p subshells.
So, maximum of electrons (and hence elements) = 4s33d154p9 = 3 + 15 + 9 = 27
(B). All elements of VIII group (i.e. 8, 9, 10 groups) are called typical transition metals. Pt also
belongs to 10th group. So it is a typical transition metal.
7 1 2
(C). E.C. of Gd (64) = [Xe]4f 5d 6s
So number of f electrons = 7
(D). Due to ineffective shielding by 3d electrons in Ga, size of Ga is smaller (almost equal) to
that of Al.
Hence (C) is correct.
Dd 40 d
4. 0.5 0.5 0.5 d 40 d
n 1 d 1.5 1 d
1.25d = 40 d = 32
5.
O O
can not exhibit keto enol tautomerism.
6. 2Be OH2 CH4

Be2 C 4H2 O
4Al OH 3 3CH4
Al4 C3 H2O
7. At larger molar volume, a real gas may behave ideally only to a limit but not always. Hence (B) is
incorrect and others (A, C and D) are correct statements.
8. SiO2 reacts with HF to form H2SiF6 is

SiO2 6HF H2 SiF6 2H2O
Hence A, B, D is correct.
9. Both P & T represents (2R, 3R) 2, 3 dibromobutane.

Hence (A) is correct.
10. (I) Identical & rest of II, III & IV are enantiomers.
Hence (B) is correct.
11. Both Q & S are meso 2, 3 - dibromobutane.

While (R) is (2S, 3S) - 2, 3 dibromobutane & hence optically active i.e. lacks in the plane of
symmetry.
Hence (C) is correct.
6
SECTION C
14
1. A = CO2
C = CO2
F = H2
0.25
2. Weight of Fe in 1 mole of haemoglobin = 98600 224
100
224
number of Fe 4
56
3RTx 2RTy
3.
Mx My
3 400 2 60
, My 4
40 My
4. K sp 4s3
5 1016
S3 5 106
4
6 5
OH 2s 2 5 10 10 , pH 9
5. PNH 2 PH S
3 2
P 1 bar, PNH 2 bar, PH S 1 bar

3 2
Kp = (2)2 1 = 4
6. 5th exited state n2 = 6

Visible radiation means n2 = 2
6 2, 5 2, 4 2, 3 2
7
Mathematics PART III
SECTION A
1. a1, a2, a3 are in G.P.
1 1
1
x1
a1
a1r x2 a1r 2 x3 ... k
1 1 1
loga1 k , loga2 k and loga3 k
x1 x2 x3
Clearly x1, x2, x3 are in H.P.
2x y a 3
2. Equation of tangent will be 1 hence x-intercept is and y intercept is b 3
3a 3b 2
1 a 3 b
b 3 3a 2 4 e2 = 17.
2 2 a
3. For each of the three equations to have equal roots

4a2 = 4b, 4b2 = 4c and 4c2 = 4a
a2b2c2 = abc abc = 1
hence a, b, c cant be integers.
4. We know that in ABC, sin 2A + sin 2B + sin 2C = 4 sinA sinB sinC

sinA sinB sinC = 1 cosA cosB
1 cos A cosB
sinC 1
sin A sinB
cos A B 1 i.e., A = B

Hence C = , A = B = .
2 4
2t 0 2
5. Slope of PV =
t2 0 t
t
equation of QV is y = x
2
2 16 8
solving it with y = 4x, Q 2 ,
t t
1
Now, as (PVQ) PV VQ 20 (given)
2
2 2 2
PV VQ = 40
6. If n = m then equation becomes zn zm and it has infinite solution because any z real will
satisfy it.
If n m, let n > m, then zn zm |z|n = |z|m
|z|m (|z|n m 1) = 0
|z| = 0 or |z| = 1, |z| = 0 z = 0 + 0i
|z| = 1 z = ei e(m + n)I = 1
1
z 1m n
number of solution is m + n + 1.
8
9 9
7.
Let R 3 3 5
R f and 3 3 5 f , then [R] + f f = an even integer,
which implies f f = 0, Hence [R] is an even number
9 9

[R] 3 3 5 3 3 5 = a multiple of 5
Hence [R] is divisible by 10.
8. If n lines divide a plane is L(n) planes, then

L(n) = L(n 1) + n
Hence L(10) = 2 + 2 + 3 + + 10 = 56.
9. For roots of opposite sign a(a 3) < 0, hence 0 <a < 3
10. Discriminate = (2a 1)2 4a(a 3) = 8a + 1

n2 n 2
for a D = (2n + 1)
2
Hence roots must be rational numbers.
11. As per data of previous questions the roots will be

n2 3n n2 n 2
,
n2 n n2 n
Hence both the roots lie in [1, 2].
SECTION B
1. (A) Equation of any curve through the points in which given lines meet coordinate axes will be
(a1x y + b) (a2x y + b) + xy = 0. If these points are concyclic then a1a2 = 1.
(B) Any point on x 2 y 2 a12 will be (a1 cos , b1 sin ).
The chord of contact of the tangents drawn to x2 + y2 = 4 from this point will be a1x cos +
a1y sin = 4. If this touches the circle x 2 + y2 = a22 , then a1a2 = 4.
(C) If the two circles cut orthogonally, then
a1 a1 a2 a2 = 2(1 1) a12 a22 4 .
(D) Centre of the given circle is (2, 3) and radius is 5. Now distance between (8, 5) and the
centre is 10.
Hence a1 = 5 and a2 = 15.
2. (A) cos7 x + sin4 x = 1

cos7x = (1 + sin2 x) cos2x
cosx = 0 or cos5x = 1 + sin2 x
5 2
cosx = 0 x , , cos x = 1 + sin x
2 2
x = 0.

x ,0, .
2 2
(B) 3 cosec20 sec 20
3 1 3 cos 20 sin20

sin20 cos 20 sin 20 cos 20
3 1
2 cos 20 sin20
2 2 4cos 50 4

sin 20 cos 20 sin 40
9
(C) 4 cos 36 4 cos 72 + 4 cos 18 cos 36

55 1 55 1 55 1 55 1
4 4 4
4 4 4 4
=3
(D) cosec x = 1 + cot x
1 sin x cos x
cosx + sinx = 1 and sinx 0
sin x sin x
1
cos x
4 2
3
x 2 or x , x , .
4 4 4 4 2 2
SECTION C
1. Let these lines be given by y = mx for m = m1, m2 & m3

Then substituting y = mx in the given equation gives
m3 cm2 bm + 1 = 0
Now m1 + m2 + m3 = b, m1m2 + m2m3 + m3m1 = c
m1m2m3 = 1 & m1m2 = 1
Hence b + c = 2
2n!
2. C0C1 + C1C2 + + Cn1Cn = 2nCn1
n 1! n 1!
S n 1
2n 2 ! Sn 1 4n2 6n 2 15

n! n 2 ! Sn n2 2n 4
n = 2 or 4.
3. P(2, 4) = (2t2, 4t) t = 1

2
t t t = 3 R is (18, 12)
t
Also tt = 2 gives t = 2 hence Q(8, 8)
Perpendicular bisector of PR : x y = 14 and of PQ : 3x + 2y = 27
solving together gives h = 11, k = 3
h+k=8
4. N = 34x5y
number is divisible by 4 if 5y is divisible by 4 i.e. y = 2, 6
if y = 2 then 3 + 4 + x + 5 + 2 must be divisible by 9 x = 4
if y = 6 then 3 + 4 + x + 5 + 6 must be divisible by 9 x = 0, 9.
5. Note that the two given lines are mutually perpendicular, hence their point of intersection i.e. (1,
1) will lie on director circle of the ellipse.
If centre of the ellipse is (h, k) the equation of direction circle will be (x h)2 + (y k)2 = 25
as (1, 1) lies on this circle hence locus of center will be
(h 1)2 + (k 1)2 = 25
radius of circle is 25.
2 2 2
6. We have a ,b ,c
hA hB hC
2
a = , b = , c =
3
10
1 1 1
a + b + c = 2
hA hB hC
1 1 1 8
2s 2 2
2 2 3 6
4
s
3
Now 2 s s a s b s c
4 2
2
3 3
3 3
8 2 2
1 8 = 81
81
2 2 9 .

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1

Q. No. PHYSICS CHEMISTRY MATHEMATICS

7. P = V3 , for ideal gas

8. Both (A) and (D) depend on g.

Hence the particle is at its lowest (minimum) position, in its

5. Tension in rod at a distance x from right edge is

6. The plate is free to rotate about vertical axis yy.

1. O2 has one unpaired electron. It is paramagnetic.

can not exhibit keto enol tautomerism.

6. 2Be OH2 CH4

8. SiO2 reacts with HF to form H2SiF6 is

9. Both P & T represents (2R, 3R) 2, 3 dibromobutane.

11. Both Q & S are meso 2, 3 - dibromobutane.

P 1 bar, PNH 2 bar, PH S 1 bar

6. 5th exited state n2 = 6

Mathematics PART III

3. For each of the three equations to have equal roots

4. We know that in ABC, sin 2A + sin 2B + sin 2C = 4 sinA sinB sinC

8. If n lines divide a plane is L(n) planes, then

9. For roots of opposite sign a(a 3) < 0, hence 0 <a < 3

10. Discriminate = (2a 1)2 4a(a 3) = 8a + 1

11. As per data of previous questions the roots will be

2. (A) cos7 x + sin4 x = 1

(C) 4 cos 36 4 cos 72 + 4 cos 18 cos 36

1. Let these lines be given by y = mx for m = m1, m2 & m3

3. P(2, 4) = (2t2, 4t) t = 1

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